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By J. S. Lee

Alkyl hydroxamates are well known collectors for oxide copper minerals as evidenced by the large amount of published literature. Our studies on a wide variety of copper ores from around the world have shown that alkyl hydroxamates will recover most of the "floatable" oxide copper minerals from an ore. They are available commercially, and they offer many advantages over alternative technologies for oxide copper recovery. In spite of this, the full potential of hydroxamates has not been exploited in the industry. The objective of this paper is to provide relevant practical aspects and guidelines to facilitate successful application of hydroxamates in operating plants. A critical analysis of the available information and data, based on several case studies, notation testing, and microscopic analysis indicates that alkyl hydroxamates can effectively recover well-defined oxide minerals of copper, but not copper occurrences such as Cu-bearing goethite (often misidentified as cuprite) which report as Acid Soluble copper in chemical assays. Prior to any notation testing with hydroxamates, it is necessary to assess the various modes of occurrence of Acid Soluble copper using microscopic and microprobe analysis.

Jan 1, 1998

By M. J. Kovalik

The effect of oxidation by air at temperatures ranging from 200° to 390° C on the change of chemical and physical properties of Pittsburgh-bed coal was studied as a function of processing time and temperature. The goal was to prepare a nonagglomerating fuel from a strongly coking coal for use in continuous carbonizing processes and in fixed-bed gasifiers. The oxidized coal was carbonized in a bench-scale apparatus, and the coke strength was evaluated in a Roga tumbler. Strength of the coke was progressively reduced with time of oxidation until the coking power of the coal was apparently destroyed. Time requirements to obtain an essentially nonagglomerating product were inversely related to processing temperature. Gaseous products released from the coal during oxidation reduced the yield of the desired nonagglomerating product, which decreased with time of oxidation at constant temperature and with increase in processing temperature at equal time. Oxidation at a temperature slightly above the lower limit of the plastic temperature range of Pittsburgh-bed coal was most effective because of the short processing time required and moderate processing losses.

Jan 1, 1963

By L. Bbosa

Paper written on project work carried out in partial fulfilment of BSc (Hons) (Eng) (Mechanical) degree Discrete element methods (DEM) are being used to provide detailed impact histories of the particles in comminution devices, such as mills. To match this immense detail of information, far more informative breakage tests than those that are generally conducted are now required. The split Hopkinson pressure bar apparatus is used in this study, as it allows the calculation of breakage forces and absorbed energies. The geometry of rock particles has been identified as significant, so this project undertook to identify the influence of shape on the breakage pattern of blue stone. Comparisons are then made between the breakage pattern of angular rocks and rounded, milled rocks for single impact fracture and consecutive impact loading at low energy. Results of this experiment indicate that although breakage for both geometries occurs over a similar energy range, rounded particles have the greater probability of fracture because they absorb more of the impact energy for a given loading. Size distributions of progeny show that five pebbles or more are sufficient to predict the distribution of most particles in small energy regimes. Cumulative impact testing shows that considerably more energy is required to break a rock through cumulative damage than through a single impact?this is of considerable importance in the light of the indications from DEM simulations that most breakage in a mill will be from cumulative damage rather than single impact breakage.

Jan 1, 2006

By Robert F. Kehrman

As part of the Bureau of Mines research on the In-Situ Uranium Leaching, various geophysical resistivity measuring techniques were -evaluated to identify a rapid reliable method for detecting the underground migration of lixiviant outside of the planned limits. Surface and downhole galvanic resistivity and controlled source audio-magnetotelluric (AMT) methods were tested at an in-situ uranium mine in Northern Wyoming during start-up of a new mining area. Downhole galvanic and AMT were the most promising techniques.

Jan 1, 1980

By Shunli Zhang

Metals recovery from electronic scrap by physical separation may provide an alternative to the current recycling approach, through which halogenated flame retardants can result in hazardous dibenzo-p-dioxins and dibenzo-furans. On the basis of a complete sink-float analysis of personal computer and printed circuit board scrap, and in view of the advantages of dry processes for electronic scrap recycling by mechanical separation, air table separation is prioritized in an attempt to separate metals from plastics and glass involved. In the present paper, theoretical and practical considerations of air table separation have been detailed. It has been shown that air table separation is effective for recovering copper and precious metals from this specific waste stream. With the feed rate of 60 kg per hour, the combined grade and recovery of copper, gold, and silver attainable for the two heavy products produced by the air table used in the present study was shown in the following table:

Jan 1, 1998

By A. Wahab Khair

This paper presents an analysis of fracture mechanisms in coal subjected to bi-axial state of stresses, indentation of laterally con- fined coal specimen. Coal specimens were loaded to failure by the straight wedge indenters at various lateral confinement pressures. Strain distribution and acoustic emission characteristics of coal specimens under stress were recorded. The influence lines of vertical forces acting on the horizontal straight boundary of the coal specimen for each type of wedge indenter have been established using holographic interferometry technique. The effects of wedge indenter angle, confinement pressure, and coal anisotropy on fracture types, failure modes, and post-failure conditions were studied. The results indicated that combined application of holographic interferometry and acoustic emission monitoring techniques is not only suitable for studying deformability of heterogeneous and microscopically discontinuous material under stress but it also enhances the mode of fracture during the post failure stage.

Jan 1, 1984

By Chuanyao Sun, Zhenguo Song, Aijun Ren

"Lead-Zinc sulfide ore containing carbon is one of typical refractory resource. Because organic carbon has natural floatability, it has a great negative influence on flotation of lead-zinc sulfide ores. It is difficult to obtain qualified lead concentrate by flotation using conventional reagent system. In order to reduce the influence of organic carbon on lead and zinc flotation, two alternatives, i.e., removal carbon by pre-flotation or adding carbon depressant in lead and zinc flotation, can be adopted. If the flowsheet of removal carbon by pre-flotation is adopted, the lead and zinc recovery which are lost in the carbon tailings is often higher. If conventional carbon depressants are used in lead and zinc flotation, it has a certain depression effect on lead minerals. In the paper, the ore grading 1.49% Pb, 5.73% Zn, and organic carbon 3.14% has been carried out by flotation tests. In the bulk flotation of carbon and lead minerals, Pb concentrate is only about grading 21.00% Pb. In the pre-flotation of organic carbon, it’s hard to remove most of carbon, and the loss of Pb and Zinc recovery is too much in carbon tailings. New carbon depressant BK547 and three conventional carbon depressants including sodium lignosulphonate, Fe-Cr-lignosulfonate, and dextrin, are used in comparative tests of Pb flotation, and results show that BK547 have a good depression on organic carbon, and have almost no effect on Pb flotation. Using BK547 as carbon depressant, cycle test in flowsheet of two-stage Pb and Zn selective flotation and coarse concentrate regrinding have been carried out, and results show that concentrates grading 62.51% Pb and 41.33% Zn are obtained at recoveries of 70.24% Zn and 83.58% Zn.INTRODUCTION Lead and zinc mineral resources are still the main source of lead and zinc metal. For lead-zinc sulphide ore, lead concentrate and zinc concentrate are obtained by flotation. Minerals separation by flotation is a complex process and is dependent, along with other factors, on the relative distribution of hydrophobic (e.g. collector, polysulfide, elemental sulfide) and hydrophilic (e.g. metal hydroxide) species between different particles of the same mineral phase and between mineral phases (Piantadosi & Smart, 2002; Boulton, Fornasiero & Ralston, 2003). Organic carbon has natural floatability and is often associated with lead-zinc sulphide ores. If the content of organic carbon in the ore is more, the flotation index will become worse. The main problem is that the concentrates has too low grade to be qualified grade products for sale. At the same time, the consumption of reagents is more than ordinary ores without organic carbon. In order to solve the influence of organic carbon on the flotation of lead and zinc and other sulphide ores, a lot of research works have been carried out."

Jan 1, 2018

By Yuhe Tang, Jun Zhang, Jianguo Liu

"The nature high carbon graphite with fine particle size has low commercial value because of its narrow application range. In order to improve its value, this paper has studied the methods for nature spherical graphite. The nature spherical graphite can be used as the battery material in the field of electronic product battery and new energy automobile battery, basis on the physicochemical characteristics and particle feature of graphite. In this research, the Fixed Carbon (FC) grade of the graphite sample is more than 95.0% and the particle size of the graphite sample is from +325 mesh to -100 mesh. There are many methods for nature spherical graphite, including the fluidized bed airflow mill, the hydro-spheroidization mill and micropowder mill. The testing results indicate that the method of ACM micropowder mill is the best because the spherical shaping ratio and production yield of spherical graphite are both the best.According to the testing results of the ACM micropowder mill, the best process includes two stages of coarse crushing, four stages of fine crushing and twelve stages of shaping. And two kinds of spherical graphite products can be got, which are the product of D50=22.85 µm and the product of D50=15.43µm, and the whole yield of them is up to 54.43%. So, it lays a foundation for the high value utilization of this kind of graphite resources.INTRODUCTION Graphite is isomer of the diamond. Graphite ore resources are mainly concentrated in China, Brazil, India, followed by Czech, Korea, Mexico, Canada and other countries. Graphite ore has lots of characteristics by itself crystal structure, such as good resistance to high temperature, electrical conductivity, thermal conductivity, thermal shock resistance, good lubricity, plasticity, chemical stability and so on. So, Graphite is widely used in metallurgy, machinery, electrical, chemical, petroleum, nuclear industry, defense industry and other areas. [1,2,3] Natural graphite ore has low geological Fixed Carbon (FC) grade. FC grade should be enriched to more than 94.0% by mineral processing. [1,2] The particle size composition of this high carbon graphite affects its application value. The part of +100 mesh particle size has high application value. The part of -100 mesh particle size has low value because of its limited application field. In order to improve the value of-100 mesh particle size, this part high carbon graphite can be made into spherical graphite. And the value of the spherical graphite is great, it is more than 8 times of the feed. This paper has lots of tests for spherical graphite preparing with the fine particle size natural high carbon graphite. And it lays a foundation for the high value of this kind of resource."

Jan 1, 2018

By Weiran Zuo, Emmy Manlapig, Fengnian Shi

The effect of metalliferous grains on electrical comminution efficiency was investigated by comparative experiments using natural rocks and synthetic samples. The result indicated that the existence of metalliferous grains affects the breakage probability and product size distribution of electrical comminution. On average, metalliferous grains increased the breakage probability of particle in the first pulse discharge by 55% and generated finer product at the coarse end. As a result, particles with metalliferous grains exhibited higher energy efficiency than that without metalliferous grain in electrical comminution. A positive linear relation between product fineness and specific energy in electrical comminution was observed. With the assistance of numerical simulation on the electrical field distribution of ore particle, the role of metalliferous grains in electrical comminution is confirmed and the mechanism of metalliferous grains effect is elucidated. Understanding of the effect of metalliferous grains on electrical comminution is important to evaluate the feasibility of applying electrical comminution to ores with different mineral composition, and to understand the breakage behavior in electrical comminution.

Jan 1, 2014

By G. P. Wong

"In the Inco matte separation process, a slow-cooled converter matte is separated into three main discrete mineral phases: chalcocite (Cc), heazlewoodite (Hz) and a Cu-Ni-Fe alloy. After magnetic removal of the alloy, Cc and Hz are separated by flotation at pH>12 with diphenyl guanidine (DPG) as both collector and frother. High selectivity is achieved in rougher flotation. However, in later flotation stages such as in the middlings circuit, as oxidation takes place, Hz becomes highly floatable, resulting in a very poor separation between Cc and Hz.Starch and dextrin as Hz depressants were evaluated on the middlings circuit feed and showed no positive impact on Cc/Hz separation selectivity. Ethylene diamine tetra-acetic acid (EDTA) extraction showed the existence of abundant surface Cu and Ni ions. The use of triethylene triamine (TETA) or EDTA in flotation did not improve Cc/Hz separation selectivity. Microflotation tests were carried out on pure synthetic Cc and Hz minerals. It was found that Hz did not float in the presence of DPG. However, Hz conditioned with either copper sulfate solution or in contact with Cc floated readily in the presence of DPG. It is concluded that the major reason for Hz flotation in the middlings circuit is due to Cc oxidation releasing Cu ions that adsorb on the Hz surface making it reactive with DPG thus rendering the Hz floatable."

Jan 1, 2003

By B P. Scott

Podsol soil horizons developed on Pleistocene glacial sediments overlying the Coronation Mine orebody were analyzed for copper and zinc spectro-photometrically, using biquinoline-isoamyl alcohol and dithizone carbon tetrachloride reagents. Copper and zinc are concentrated in the A. and C horizons, whereas the A1, A2 and B horizons are leached. Of economic significance is the fact that the C horizon contains a copper anomaly, in excess of 100 times back-ground, directly over the orebody. Due to the erratic distribution of high copper concentrations in the Ao horizon with respect to the orebody, that horizon is not considered as a reliable prospecting datum. U NDER certain conditions, metallic ore deposits are accompanied by primary halos of trace elements in unweathered rock surrounding the orebodies or by secondary halos in weathered rock, alluvium, soil, or vegetation above or near the mineralized zones. Where such halos occur, chemical analysis, as applied to the detection of trace elements, is a valuable prospecting aid, permitting the detection of mineralization of possible economic value.

Jan 1, 1965

By K. J. Powers

The Mine Accident, Injury, Illness and Employment Database at the Mine Safety and Health Administration's Health and Safety Analysis Center is a computerized system that stores accident, injury, illness and employment data about all coal and metal/nonmetal mines in the United States. The paper discusses the system for collecting, storing, analyzing, and reporting this information and how these data are used in the ongoing effort to increase the health and safety in this nation's mines.

Jan 1, 1983

By Waterhouse BJ

Occurrence data of Tastubian,Sterlitamakian, and Aktastinian (all of Sakmarian Stage of Early Permian) brachiopod genera are analysed by Q-mode cluster analysis, principal component analysis, and discriminant analysis based on presence or absence of genera. Five faunal provinces and their corresponding generic associations persisted throughout the Sakmarian Stage. The additional Sasian Province incorporating the Lhasa and Shan-Thai terranes became recognisable in Sterlitarakian and strengthened in òAktastinian, implying a Tastubian-Sterlitamakian rifting event, followed by subsequent northward drift and divergence from Gondwana, and convergence with Laurasia. The nature of Permian 'Tethys' is discussed on the basis of faunal migration and abrupt changes of faunal provinciality in Lhasa and Shan-Thai terranes.

Jan 1, 1990

By Sina Z. Yekta, Zhangwei Ning, Pierre Frappin

This paper describes a DC (direct current) electrical resistivity method, which uses the contrasts in resistivity measurements to estimate the diameter of jet grouted columns as soon as they have been completed, with varying depth and water table, and without excavation. The measurement procedure is illustrated by several examples of application sites, including the Grand Paris tunneling works during the last 3 years where the method was systematically recommended in quality control for jet grouting works.

Sep 8, 2021

By Steve Kral

Improved metals and other commodity prices have caused the mining industry to open new mines, re-evaluate development opportunities at potential mines and increase production at existing ones. This sense of renewed optimism is being seen at operations and development projects around the world. Except in the United States. The regulatory structure there has not allowed the domestic industry to share much in mining’s resurgence. It can still take up to 10 years to permit a new mine. And, while Clinton-era regulations regarding mill sites have been put on hold, existing mines that wish to expand operations still face significant regulatory and environmental hurdles. But things may begin to improve in the United States.

Jan 1, 2005

By Michael Hoch, Walter C. Wyder

The Cr-Ni system was investigated between 900" and 1400°C and 45 to 100 wt pct Cr. The Cr-Fe system was studied between 1200" and 1385°C and 70 to 100 wt pct Cr. Powdered alloy compacts were produced from high-purity chromium, nickel, and iron poulders. The compacts were sintered in an argon atmosphere and then machined into small, 0.030-in. diam cylindrical specimens. These were then heated by induction in the high-temperature X-ray diJfractwn camem under a helium atmosphere and irradiated with copper Ka radiation. From the results of the high-temperature X-ray diffraction patterns it can be concluded that chromium exists only in the bcc form, and that no eutectoid reaction occurs in the Cr-Ni system in the temperature interval 900" to 1400°C. The X-ray diffraction patterns are in agreement with the Cr-Ni phase diagram of Bechtoldt and Vacher, and Williams. It is possible that chromium undergoes one or more allotropic transformations between room temperature and its melting point. Most of the evidence was gathered from the study of the chromium-rich ends of the Cr-Ni and Cr-Fe binary systems. All the investigations rely heavily on indirect methods: thermal analysis, electrical resistivity, and micro-graphic inspection of quenched samples. In the present work the chromium-rich side of the Cr-Ni and Cr-Fe binary systems is studied, using high-temperature X-ray diffraction techniques. Thus the coexistent structures can be observed directly at temperature. PREVIOUS INVESTIGATIONS ~ansenl shows two possible Cr-Ni phase diagrams 1) a simple eutectic [Liquid =a-Cr(bcc) + y-Ni(fcc)], 2) a eutectic [Liquid+ P-Cr(fcc) + y-Ni(fcc)] and euctectoid [p-Cr(fcc) ==a-Cr(bcc) + yNi(fcc)]. The latter is based on the work of Grant and co-workers.2 Stein and rant'" placed the eutectoid composition at 1215°C and 68 wt pct Cr; their diagram is shown in Fig. l. Similarly, Sully3 also discusses the two proposed diagrams. Price and Grant,4 working on an isothermal section of the Cr-Ni- Fe ternary diagram at 1300°C, made no mention of a ß-chromium phase (fcc). The ß-chromium structure was also reported by Misencik 5 in the Cr-Nb(Cb) system. Williams 6 studied the Cr-Ni system using precipitation techniques. His work included the chromium and nickel solvus lines below 1250°C. He reported no ß structure nor any eutectoid reaction. The solvus lines which he produced were very similar to those of Jette, et al 7 below 1000°C. He concluded that Grant and coworkers2 had misinterpreted their data, and that effects which they had reported were actually due to the rapid and extensive precipitation of the nickel-rich phase. Bechtoldt and vacher8 used sintered powdered alloy compacts in an attempt to find the ß phase. They used metallographic and room-temperature X-ray diffraction techniques and also failed to detect the fcc chromium phase. They attributed the low slope of the chromium solvus at approximately 1150°C as the probable cause of the abundant precipitation obtained. They also stated that the precipitation was the probable cause for the abrupt discontinuities in the thermal analysis and electrical resistivity data which led to the conclusion that a eutectoid reaction existed. Fig. 1 also shows their diagram. Grigor'ev and coworkers9 investigated the polymorphic changes of chromium in the Cr-Ni phase diagram. Using standard microstructural and thermal analysis techniques, they published a phase diagram which contained five polymorphic forms of pure chromium and four eutectoid reactions. They stated that the room-temperature bcc chromium transformed to a fcc structure at 930°C, to bcc at 1300°C, to hcp at 1650oC, and then finally to bcc at 1830°C. The eutectoid reactions were placed at 850°, 960o, 1140°, and 1220°C. Also to be noted was the fact that the uppermost phase, the bcc above 1830°C, was different from the upper phase of Grant and coworkers,2 the fcc above 1840°C. Their eutectoid reactions, temperatures and compositions fall

Jan 1, 1963

By Kevin Stuffle, James E. Sharp, Sean Premeau

Two process enhancements for the biological oxidative pretreatment of sulfidic gold ore for subsequent treatment with cyanide are discussed. These are the use of a high areal density ring and pin packing (BioBalls™) as substrate, and the use of a novel biological ferric generator. The BioBall™ packing when coated with concentrates for heap leach processing offers higher areal densities, while leaving more open volume for fluid flow than more commonly used substrates such as aggregate. An oxidation rate study was performed on crushed auriferous arsenopyrite whole ore to demonstrate the benefits of using the packing. The auriferous arsenopyrite grading 2.9% Fe and .212 OPT gold was 50 percent oxidized in 24 days. The biological ferric generator is a passive air-side trickle bed reactor that efficiently converts ferrous to ferric in a process stream. Conversion rates of .8g/L h ferrous to ferric are routinely obtained. Although the biologically generated ferric solutions have not yet been tested on gold ores or concentrates, prior work has demonstrated that the high ferric solutions which will result in rapid oxidation of sulfidic gold ores or concentrates.

Jan 1, 1997

By B. Amadei, A. Squassabia

This paper introduces the Rock Mass Median (RMM) index, a statistical measure of the mechanical quality of a rock mass thus is obtained through a mechanistic interpretation of the Poisson stochastic process. This process is the theoretical foundation of the Exponential Model, a probability distribution successfully used in practice to describe the spacing of discontinuities in rocks. Building on the Exponential Model, a simple method to compute RMM based on a widely accepted mechanical quality index is also presented. Verification is per formed through the analysis of two sets of core samples. Hypothesis testing at the 5% level of significance supports the validity of RMM for these samples.

Jan 1, 1994

By E. Stolarski

The circulating fluid bed (CFB) technology can proudly point to its history of more than a quarter of a century of commercial operations. Over 80 CFB units operate in aluminum calcining, coal combustion and gold roasting. This paper describes the invention of the circulating fluid bed and chronicles its development and evolution from calcining through coal combustion to gold roasting. It presents performance data of Lurgi's CFB units in operation and highlights the six gold roasting plants currently operating throughout the world.

Jan 1, 1998

By Matthew E. Meyer

Renovation, rehabilitation, restoration and expansion of existing residential, retail, commercial, hospital facilities and historic structures requires assessment and evaluation of foundation systems of various ages. The concept of demolition and reconstruction in urban areas is often more challenging, costly, and even prohibitive in some cases due to historic regulations. The authors have been involved with numerous projects related to existing foundation assessment and retrofit, including: hotel and hospital expansions, historic Art-Deco hotel renovations and expansions, garage structure expansions, additions to prominent auction houses, casinos, printing facilities; high-rise structure foundation retrofitting; forensic evaluations of existing building and highway structure foundation systems, and marine bulkhead sheeting systems. The use of non-destructive testing techniques, high-strain dynamic load testing, full scale pile cap load testing and 3-D laser scanning technology has proved to be vital in the assessment and evaluation process, as well as design of foundation retrofit alternatives. This paper presents various methods and techniques to facilitate a phased approach for optimization of existing foundations and subsequent re-use of foundation systems. These methods and techniques are illustrated through the author?s experience and selected case histories from projects with varied foundation and geologic conditions.

Jan 1, 2011