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By Sunil Jayasekera

This paper describes the results of a study carried out to examine the feasibility of electrolytic recovery of silver from cyanide leach liquor generated from a Western Australian silver mine tailings using a novel high mass transfer electrowinning cell. The proposed circuit involves heap leaching and electrowinning in a closed loop. The filter-press-like closed electrode arrangement of the cell allowed much improved mass transfer of metal ions to the cathode surface, making direct electrowinning of metals from dilute solutions feasible. The tests were conducted both in the laboratory and at large scale using a prototype with ~1.0 m2 cathode area. The results showed that the recovery of silver from as low as 250 mg L-1tenor was feasible. The silver deposit produced with the prototype cell was non-adherent and powdery and could be readily removed from the closed cell. A system was developed so that silver powder was discharged continuously during the run.

Jan 1, 2003

By W. R. Dearman, N. Turk

A seismic fissuration index (K) is defined as the ratio of the difference in the P and S wave velocities obtained when a dry rock specimen is tested both under a load equal to half the uniaxial compressive strength of the rock (Vo) and without an applied load (Vd) to the velocity obtained without an applied load (Vd), as K = (Vo - Vd)/Vd. A similar seismic fissuration index is also proposed for classifying the dry rock mass in terms of field seismic velocities. The field equation is extended by including the intact rock seismic velocities. K is found to be related to the porosity of rocks. The proposed equation can equally be used for characterizing saturated rocks, using S-wave velocities. However, the time average equation should be used for characterizing saturated rocks, using P-wave velocities, even though this equation gives upperbound estimates of the rock material and fracture porosities.

Jan 1, 1986

By W. J. Miles

At the beginning of the 20th century, barite was a mineral of minor importance in the United States. Its primary use was to extend lead oxide in white paint. Barite also added the special qualities of hiding power and flatness to paint. Because white lead sometimes turns black or yellow and barite does not, ground barite became a pigment on its own merit. Barium chloride was added to bricks before fi ring to stop efflorescence when exposed to weather. Barium carbonate or nitrate added luster and brilliance to glass. Barium chemicals were added to refining sugar, enameling iron, making oilcloths and paper collars, and in the manufacture of paper, artificial ivory, rubber and lithopone. Lithopone became a major paint ingredient in the 1920s; its use lasted until the 1950s, peaking at 150 kt (165,000 st) of barite in 1937 and 1947 for the manufacture of lithopone. Later in the 20th century, titanium dioxide replaced lead oxide, barite and zinc oxide in the coatings industry. In the 21st century, barite is used as a filler, extender or weighting agent in products such as paints, plastics and rubber. Some specific uses include its use in brake and clutch pads for automobiles, automobile paint primer for metal protection and gloss, to add weight to rubber mud flaps on trucks and to add weight to the cement jacket around petroleum pipelines under water. In the metals casting industry, barite is part of mold release compounds. Because barite significantly blocks X-ray and gamma ray emissions, it is used as aggregate in high density concrete for radiation shielding around X-ray units in hospitals, nuclear power plants and university nuclear research facilities. Ultra-pure barite consumed as liquid is used as a contrast medium in medical X-ray examinations. Barite is the raw material for barium chemicals, such as barium carbonate, which is an ingredient in faceplate glass in the cathode-ray tubes of televisions and computer monitors. In the 21st century, barite industrial uses accounts for an estimated 78 kt/a (86,000 stpy) in the United States.

Jan 1, 2009

By S. Le Fevre

THE application of electricity to the mining and beneficiation of the magnetic iron ores of the Mineville, N. Y., district, on Lake Champlain, has resulted in economies and enhanced quality of product, without which only a comparatively small quantity of the present output could be marketed. The output of the Witherbee, Sherman & Co. mines is about 700,000 tons per annum, and of this about four-fifths is treated by magnetic separation to increase the iron content and reduce the phosphorus. The use of electricity for the magnetic separation of the ore from the gangue is therefore of primary importance, and makes possible the application of electric power for mining and preparing the ore for concentration: The fact which speaks loudest in favor of the application of electricity is this: It is possible for about 25c. per ton of shipping ore to furnish all the power required to put the ore on cars. This includes mining a hard ore underground, from a depth of 900 ft., hoisting to surface, crushing to 4 or s in. in size, and separating from the gangue. This also includes lights about the works, and all miscellaneous power, such as about the shops. The first plant for the generation of electric power for use at Mineville was completed in 1903, and was one of the first for the application of electricity to mining iron ore. This was a Nordberg compound condensing steam engine, direct connected to a 750-kw. alternating-current generator, 3,300 volts, 3 phase, 25 cycles. All the plants added later use the same-current but with higher voltage. The map, Fig. 1, shows the power plants and the transmission system; Figs. 2 and 3 are views of the shaft houses and the mills.

Jan 6, 1914

By João Carlos Jânio Gigolotti

Foram estudadas experimentalmente as relações de fases do sistema Nb-Ti-Si na seção isotérmica a 1200 °C. Ligas fundidas em forno a arco em atmosfera de argônio a partir de Nb, Ti e Si de alta pureza (? 99,9 %), foram tratadas termicamente a 1200 °C durante 264 h em forno tubular, em atmosfera de argônio, encapsuladas em tubos de quartzo. As ligas tiveram sua microestrutura caracterizada por difração de raios-X, microscopia eletrônica no modo elétrons retroespalhados e por microsonda. Ficaram determinados os campos ternários Nb5Si3 + (Nb, Ti)3Si + (Nb, Ti, Si), Nb5Si3 + (Nb, Ti)3Si + Ti5Si3, Ti5Si3 + (Nb, Ti)3Si + (Nb, Ti, Si), Nb5Si3 + Ti5Si4 + Ti5Si3, Nb5Si3 + Ti5Si4 + NbSi2, NbSi2 + Ti5Si4 + TiSi, NbSi2 + TiSi2 + TiSi e NbSi2 + TiSi2 + SiSS. Existe boa concordância dos resultados com as propostas calculadas e experimentais existentes na literatura para essa seção isotérmica do sistema Nb-Ti-Si. Pequenas alterações composicionais são sugeridas para a locação dos campos ternários observados.

Aug 16, 2017

By Li Qihou, Li Yuhu, Liu Zhihong, Liu Zhiyong, Yang Xiaofeng

Scorodite samples were synthesized, in adding or without crystal seed respectively by using Atmospheric Scorodite Process (ASP), Hydrothermal Scorodite Process (HSP), and Improved Atmospheric Scorodite Process (IASP) individually; and their crystal structure, crystallinity, morphology, particle size, specific surface area, Fe/As mole ratio, as well as the leaching stability were characterized, aimed to reveal the relationships among the synthesis methods, the compositional and structural properties, and the leaching stabilities of scorodite. The results show that synthesis methods have significant effects on the compositional and structural properties of scorodite. Scorodite samples of high crystallinity, small specific surface area, and low Fe/As mole ratio, possess high leaching stability. The order in the leaching stability of scorodite samples synthesized in this study is as follow: ASP<HSP<IASP. Scorodite particles in the sample synthesized by IASP without crystal seed are in large sizes and of pyramidal morphology enclosed mainly by crystal planes of {111}; and the sample possesses the crystallinity of 84.5%, the particle size (D50) of 28.2 m, the BET specific surface area of 3.72 m2/g, and the Fe/As mole ratio of 1.05; after leaching this sample by using acetate buffer solution of pH 4.95 for 10 days, the total arsenic concentration in the leaching solution is merely 1.14 mg/L.

Jan 1, 2015

By Yongjun Peng, Yufan Mu, Rolf A. Lauten

"Chalcopyrite, a major source of copper, is commonly found associated with iron sulfides, particularly pyrite. The separation of chalcopyrite and pyrite by flotation is difficult due to the galvanic interactions between pyrite and chalcopyrite during grinding and flotation. Galvanic interactions may cause oxidation and dissolution of chalcopyrite, copper activation of pyrite and the formation of hydrophilic iron hydroxide coating. The overall effect may change the floatability of the components and lead to the misplacement of pyrite into chalcopyrite concentrate. The objective of this study was to investigate the effect of lignosulfonate-based biopolymers on the depression of pyrite in the flotation of chalcopyrite with xanthate as collector and the mechanism responsible for the selective depression of pyrite. The flotation results showed that biopolymers depressed the flotation of both copper-activated pyrite and chalcopyrite in single mineral flotation although to different extents. In the flotation of mixed mineral systems, biopolymers significantly depressed pyrite flotation but had a less influence on chalcopyrite flotation. The selective depression of pyrite by biopolymers was due to the preferential adsorption of biopolymers on copper-activated pyrite surface. Galvanic interactions between pyrite and chalcopyrite surfaces promoted copper activation on pyrite. Presence of cuprous ions on pyrite surface favored biopolymer adsorption by the formation of a complex between the cuprous ions and biopolymer molecules. The same galvanic interactions also facilitated chalcopyrite oxidation leading to the formation of hydrophobic polysulfide that enhanced the hydrophobicity on chalcopyrite surface. The biopolymer structure controlled the depression effect. The results showed that the biodegradable biopolymers are promising depressants for pyrite.INTRODUCTIONCopper sulfide minerals, such as chalcopyrite (CuFeS2), bornite (Cu5FeS4), chalcocite (Cu2S) and covellite (CuS), are the major mineral source for copper. They are often found finely interlocked with iron sulfides, especially pyrite (FeS2) (Owusu, Brito e Abreu, Skinner, Addai-Mensah, & Zanin, 2014). Pyrite, as the most abundant sulfide mineral, is perceived as gangue in most cases and should be removed from the associated sulfides to minimize its contamination of the copper concentrate (Owusu, Addai-Mensah, Fornasiero, & Zanin, 2013; Wang & Forssberg, 1991). The commonly used strategy to remove pyrite is flotation (Wang & Forssberg, 1991)."

Jan 1, 2016

By N. Ahmed

The collection of hydrophobic particles in the froth phase in flotation has been studied. A continuous flotation cell was developed, in which the froth phase could be isolated from the pulp zone. Hematite particles, d80 = 87 µm, were floated in the pulp, using a conventional oleate collector, while glass spheres of similar diameter, d80 = 82 µm, were introduced in wash water added to the froth. Four samples of glass spheres, with contact angles between 0 and 82 degrees, were used. The results indicate that the efficiency of collection of the hydrophobic particles in the froth can be very high. The process is strongly influenced by the hydrophobicity of the particles and the surface area available for attachment in the froth. Recommendations for the flotation of particles in the froth phase are made, especially regarding the desirable hydrophobicity as reflected in the contact angle, the froth depth, the solids concentration in the feed to the froth, the air rate and the wash water rate.

Jan 1, 2001

By Harold L. Walker

ENGINEERING educators have recently been discussing the advisability of extending the undergraduate curricula to five or six years, and a plan has also been proposed requiring a preliminary period of study in the liberal arts college before admission to the engineering college. Extension of the undergraduate curricula has been suggested as a means of more fully covering the subject matter in the major field of study. Interest in this proposed plan of requiring a preliminary period of study in the liberal arts college has been heightened through a bill recently introduced in the legislature of the State of New York. This plan intends to give a more professional status to engineering, and credit for these additional years of study would be allowed to those engineers applying for professional licensure. As a result of the interest in engineering curricula and due to the impetus given by these proposed plans a general reexamination of curricula has been conducted by a large number of schools with the stated purpose of determining if the present curricula are meeting the aims and scopes of engineering education.

Jan 1, 1940

By A. W. Fahrenwald

CELL depth has been for many years a controversial question in a flotation-machine performance. In the impeller type of machine, we are really talking about impeller submergence-i.e., the depth in the pulp at which the impeller is required to produce aeration. THE FLOTATION MACHINE A COMPRESSOR A flotation machine can be considered as an air compressor or blower in which the aeration mechanism takes in air under atmospheric pressure[t] (14.7 lb. per sq. in.) and blows it into the pulp (the pulp being the receiver) against a head of 14.7 plus cell depth in feet times 0.4333 lb. per sq. inch. In commercial machines the impeller is submerged in the pulp to depths ranging from about 2 ft. in the smaller machines to as much as 5 ft. in some of the larger ones. In the 2-ft. cell, the hydrostatic head on the impeller is (2 X 1.25 =) 2.50 ft. (assuming a pulp density of 1.25), equal to (2.50 X 0.4333 =) 1.078 lb. per sq. in. For the 5-ft. cell, the hydrostatic head against which the impeller must make air is (5 X 1.25 X 0.4333 =) 2.708 lb. per sq. inch. In the small 2-ft. machine, the volume reduction is (1.078 [-] 0.147 + 0.01078 =) 6.85 per cent and in the large, 5-ft. machine, the volume reduction is (2.708 [=] 0.147 + 0.02708 =) 15.5 per cent. It is obvious that for unit volume of free air intake the larger machine receives a lesser (8.65 per cent less) volume of aeration* than the smaller machine. The bubbles in escaping from the pulp expand and are greater in volume at the surface than at the moment of their formation in the pulp; 7.33 and 18.4 per cent larger, respectively, in the small and large machines. Just how this situation affects flotation is not known. It is interesting to note, however, that the bubbles are smaller in the zone of the coarsest particles and largest in the upper zones of the finer, more easily suspended mineral particles. It would seem that the relationship might be reversed advantageously. The deep cell is at a greater disadvantage in this respect than the shallow cell. Nothing, however, presumably can be done about this situation. The shallow cell is a partial corrective. Not only does the compression ratio of aeration increase with impeller submergence but the hydrostatic head against which the impeller must operate also increases. THE FLOTATION MACHINE AS A PUMP Since, in impeller machines that rely upon their own operation to produce aeration, pulp passes through the im-

Jan 1, 1946

By A. W. Fahrenwald

Cell depth has been for many years a controversial question in a flotation-machine performance. In the impeller type of machine, we are really talking about impeller submergence—i.e., the depth in the pulp at which the impeller is required to produce aeration. The Flotation Machine a Compressor A flotation machine can be considered as an air compressor or blower in which the aeration mechanism takes in air under atmospheric pressure† (14.7 Ib. per sq. in.) and blows it into the pulp (the pulp being the receiver) against a head of 14.7 plus cell depth in feet times 0.4333 lb. per sq. inch. In commercial machines the impeller is submerged in the pulp to depths ranging from about 2 ft. in the smaller machines to as much as 5 ft. in some of the larger ones. In the 2-ft. cell, the hydrostatic head on the impeller is (2 X 1.25 =) 2.50 ft. (assuming a pulp density of 1.25), equal to (2.50 X 0.4333 =) 1.078 Ib. per sq. in. For the 5-ft. cell, the hydrostatic head against which the impeller must make air is (5 X 1.25 X 0.4333 =) 2.708 Ib. per sq. inch. In the small 2-ft. machine, the volume reduction is (1.078 ÷ 0.147 + 0.01078 =) 6.85 per cent and in the large, 5-ft. machine, the volume reduction is (2.708 0.147 + 0.02708 =) 15.5 per cent. It is obvious that for unit volume of free air intake the larger machine receives a lesser (8.65 per cent less) volume of aeration* than the smaller machine. The bubbles in escaping from the pulp expand and are greater in volume at the surface than at the moment of their formation in the pulp; 7.33 and 18.4 per cent larger, respectively, in the small and large machines. Just how this situation affects flotation is not known. It is interesting to note, however, that the bubbles are smaller in the zone of the coarsest particles and largest in the upper zones of the her, more easily suspended mineral particles. It would seem that the relationship might be reversed advantageously. The deep cell is at a greater disadvantage in this respect than the shallow cell. Nothing, however, presumably can be done about this situation. The shallow cell is a partial corrective. Not only does the compression ratio of aeration increase with impeller submergence but the hydrostatic head against which the impeller must operate also increases. The Flotation Machine as a Pump Since, in impeller machines that rely upon their own operation to produce aeration, pulp Passes through the im-

Jan 1, 1947

By A. W. Fahrenwald

Cell depth has been for many years a controversial question in a flotation-machine performance. In the impeller type of machine, we are really talking about impeller submergence—i.e., the depth in the pulp at which the impeller is required to produce aeration. The Flotation Machine a Compressor A flotation machine can be considered as an air compressor or blower in which the aeration mechanism takes in air under atmospheric pressure† (14.7 Ib. per sq. in.) and blows it into the pulp (the pulp being the receiver) against a head of 14.7 plus cell depth in feet times 0.4333 lb. per sq. inch. In commercial machines the impeller is submerged in the pulp to depths ranging from about 2 ft. in the smaller machines to as much as 5 ft. in some of the larger ones. In the 2-ft. cell, the hydrostatic head on the impeller is (2 X 1.25 =) 2.50 ft. (assuming a pulp density of 1.25), equal to (2.50 X 0.4333 =) 1.078 Ib. per sq. in. For the 5-ft. cell, the hydrostatic head against which the impeller must make air is (5 X 1.25 X 0.4333 =) 2.708 Ib. per sq. inch. In the small 2-ft. machine, the volume reduction is (1.078 ÷ 0.147 + 0.01078 =) 6.85 per cent and in the large, 5-ft. machine, the volume reduction is (2.708 0.147 + 0.02708 =) 15.5 per cent. It is obvious that for unit volume of free air intake the larger machine receives a lesser (8.65 per cent less) volume of aeration* than the smaller machine. The bubbles in escaping from the pulp expand and are greater in volume at the surface than at the moment of their formation in the pulp; 7.33 and 18.4 per cent larger, respectively, in the small and large machines. Just how this situation affects flotation is not known. It is interesting to note, however, that the bubbles are smaller in the zone of the coarsest particles and largest in the upper zones of the her, more easily suspended mineral particles. It would seem that the relationship might be reversed advantageously. The deep cell is at a greater disadvantage in this respect than the shallow cell. Nothing, however, presumably can be done about this situation. The shallow cell is a partial corrective. Not only does the compression ratio of aeration increase with impeller submergence but the hydrostatic head against which the impeller must operate also increases. The Flotation Machine as a Pump Since, in impeller machines that rely upon their own operation to produce aeration, pulp Passes through the im-

Jan 1, 1947

By G. Kim

The influence of bacterial growth phase on the flotation behavior of malachite has been investigated in a well-controlled Hallimond tube system. The microflotation tests were conducted for malachite (45?53 µm) using different amounts (bulk phase concentration=1×108?5×109 cells/mL) of Rhodococcus opacus (R. opacus) as a collector, which was grown at mid-exponential versus stationary phase, at a constant speed (340 rpm), pH (6), and malachite-bacteria interaction and flotation time (each 10 min). Hug differences between R. opacus cells in mid-exponential and stationary phase was observed from the results for electrophoretic mobility and flotation tests. Specifically, the isoelectric point of the cells in the stationary phase was lower than that in the mid-exponential phase, suggesting that the amount and distribution of surface functional groups onto cell surfaces are likely different. Additionally, the cells in stationary phase led to significant increase in the flotability compared to those in mid-exponential phase over the background bacterial concentration level of 1×108?5×109 cells/mL. Furthermore, the flotation efficiency tended to increase with increasing cell dosage for stationary phase cells while no distinct difference was observed for mid-exponential cells.

Feb 27, 2013

By Arthur L. Murray

The first thought in the case of an accident or contagious disease is naturally that aroused by our humane instinct , how serious is the case and will the person recover ? The economic effects of such cases , owing to their many ramifications , are seldom realized either by those directing mining operations or those engaged in the labor of producing . This paper is based on the accident experience of the State of Utah and the number of cases of two well known preventable diseases , typhoid fever and smallpox , in that State for the fiscal years 1917-1918 , 1918-1919 , 1919-1920 , and 1920-1921 . The data and figures presented are from coal -mining camps only . W. W. Adams , mine- accident statistician of the bureau, contributed valuable corrections and suggestions . The economic results of accidents are considered first , and those of the two preventable diseases later .

Apr 1, 1922

By John A. Folinsbee

Placer Dome Canada owns and operates the Campbell mine and mill at Balmertown, in the north western corner of Ontario. The mine operates at 1.3 kt/d (1,500 stpd). It produced more than 9.3 t/a (300,000 oz/year) of gold during the last three years. Changes to the gravity concentration circuit have resulted in a 10% to 15% increase in gravity recovery. The mill head grade at the Campbell Mill is relatively high, averaging 18.5 g/t (0.54 oz/st) over the total reserve tonnage. During the past several years, the head grade was averaging close to 20 g/t (0.6 oz/st). Before 1994, gravity concentration was achieved by using a combination of conventional mineral jigs and tables. Jig concentrates were upgraded on shaking tables to produce a concentrate, which was refined to bullion. In May 1994, management decided to buy two Knelson CD 760-mm (30-in.) concentrators. The objective was to replace the existing jigs and increase gravity gold recovery by up to 15%. Gravity recovery with jigs averaged between 30% to 35%. Gravity recovery was anticipated to increase to about 50% with the Knelsons.

Jan 1, 1997

By Thomas T., Read

IN this survey of the progressive development (of education for the mineral industries throughout the United States, the review of .the history of each school has usually been completed wherever it is first mentioned, but the history of the schools in the cities of the eastern seaboard was not carried beyond 1870. It is necessary now to cover what happened during the period of approximately the last quarter of the nineteenth century in several of the schools in the east. Philadelphia Of Philadelphia, it has been related in chapter 4 that the Polytechnic College of Pennsylvania began offering a curriculum leading to the B.S. in mining in 1853; that the school did not prosper, and finally closed about 1890. The establishment of a Department of Mining, Arts, and Manufactures at the University of Pennsylvania in 1855-56 was also mentioned, but its history was not carried beyond 1860. In 1859 J. Peter Lesley was appointed professor of mining in the University of Pennsylvania. The son of a cabinetmaker, born in Philadelphia Sept. 17, 1819, he had taken his A.B. degree at the University of Pennsylvania in 1838 and then secured a position on the Geological Survey of Pennsylvania under H. D. Rogers. When the Survey was discontinued, in 1841, he went to Princeton to study theology, was ordained a Presbyterian minister and followed that career until 1852, when the Pennsylvania, Geological Survey was again started and he rejoined its staff. He published "A Manual of Coal and its Topography" in 1856, and studied at the École des Mines, Paris, in 1856-57. He published an 800-page "Iron Manufactures Guide" the year that he was appointed to the staff at the University of Pennsylvania. In 1863-64 a College of Agriculture, Mines, Arts and the Mechanic Arts was established, but it was not a separate school

Jan 1, 1941

By Billy J. Thorne

The damage model in PRONTO simulates the dynamic fracture behavior of brittle rock. It is based on work started by Kipp and Grady, [lg] continued by Taylor, Chcn and Kuszmaul [I91 [20] and recently.modified by B. J. Thorne (first documented here). The essential feature of this model is the treatment of the dynamic fracture process in rock as a continuous accrual of damage in tension, where the damage mechanism is attributed to microcracking in the rock medium. The fundamental assumption of the damage model is that the material is permeated by an array of randomly distributed microcracks which grow and interact with one another under tensile loading.

Jan 1, 1989

By Cheryl Hill, Michael Keane, Pamela Mike, Raghoottma Pandurangi, William Wallace, Mohindar Seebra, Val Vallyathan

"Dipalmitoyl glycerophosphorylcholine (lecithin) dispersed in physiologic saline, a model of the primary component of pulmonary surfactant, is adsorbed by respirable quartz and aluminosilicate dusts. Dust cytotoxicity as measured by erythrocyte bemolysis and pulmonary macrophage enzyme release is suppressed by this adsorption. The degree of suppression of hemolytic potential versus specific adsorption of lecithin from dispersion in saline by respirable quartz and kaolin dusts are compared with dusts' BET specific surface areas to interpret the prophylactic effect of lecithin adsorption. Dust hemolytic potential versus medium pH is presented. Fourier transform infrared spectroscopy and photo-acoustic spectroscopy of lecithin on quartz and of lecithin on kaolin are presented and reviewed with results of studies of the time course of removal of lecithin adsorbed on mineral surfaces by digestion by phospholipase enzyme. Results are discussed in terms of a model of prompt neutralization of respired mineral dusts by pulmonary surfactant, and a gradual re-toxification by digestive processes acting on the adsorbed prophylactic surfactant coating following phagocytosis. INTRODUCTIONQuartz dust of respirable size is well known to cause fibrotic lung disease, but numerous questions persist in the understanding of the initiation and progression of this disease. Our approach concentrates on physical and chemical aspects of mineral dusts early-on in their interactions with living organisms, and we have chosen simplified models to investigate that interaction.In the alveolar ·spaces of the lung, tissue is coated with a surface-active material (pulmonary surfactant), which, among other functions, mechanically stabilizes the lung from collapse by reducing the surface tension of water in the alveolar sacs.1 This surfactant is also the material that is first contacted by a mineral particle that is transported to an alveolus and is impacted there. This surfactant material has been studied extensively. The primary components are known to be proteins (about 11 % in dog lavage fluid), and phospholipids (about 88%).2 Pbosphatidyl cholines constitute roughly 80% of the phospholipid fraction; about 70% of the phosphatidyl choline fraction is dipalmitoyl lecithin (DPL).2 Respirable aluminosilicate particles are capable of adsorbing dipalmitoyl lecithin from dispersion in physiologic saline, a model for a possible initial event occurring upon deposition of a particle in a pulmonary alveolus. As may be seen from Figure 1, the DPL molecule has several fixed charges at neutral pH; a positive charge on the trimethylamine (choline) moiety, and a negative charge on the phosphate group. Also evident are the two fatty acid residues of palmitic acid, which are bonded through ester likages to the glycerol segment of the molecule. The fatty acid moieties of phosphatidyl choline make the molecule inso1uble in aqueous solutions under normal conditions, but a colloidal unit of aggregated molecules called a micelle is usually formed spontaneously above a certain minimum concentration. Small micellar vesicles are generally formed in the laboratory by using ultrasonic agitation or by solvent evaporation methods."

Jan 1, 1990

By Chinmay Shingote, Robert Visintainer, Renjie Ke, Jaikrishnan R. Kadambi, John Furlan

Hydrocyclone separators are widely used in various industrial applications in the oil and mining industries to sort, classify, and separate solid particles or liquid droplets within liquid suspensions, which are considered to be multiphase systems. Numerous valuable studies have been conducted in recent years to investigate the flow fields inside hydrocyclones. However, much of the information regarding the performance of cyclones in the literature has limitations and much of it cannot be considered as completely applicable to most real-world applications; many of the studies investigated the flow fields within extremely simplified hydraulic designs that are not representative of the complex geometries or large sizes which are typical in industry. Therefore, in this study, the two-phase flow system inside the actual hydraulic geometry of a milling circuit hydrocyclone is explored with the aid of both computational and experimental techniques (particle image velocimetry (PIV)). More specifically, the flow field with an air core has been investigated. In addition, the air-liquid two phases flow in a hydrocyclone might cause some challenges on both the computational and experimental sides. Two turbulence models are utilized in the numerical calculations: the Reynolds stress model and large eddy simulation. The computational studies are mainly focused on the local flow behavior and the prediction of the dimensions and shape of the air core. Different section planes of hydrocyclone are selected as planes of interest and divided into several fields of view (FOV) for PIV measurements. Two-dimensional experimental velocity vector maps are obtained in each of the fields of view. The computational results are validated globally using pressure and flow rate readings at the boundaries and locally by comparison to the PIV velocity vector maps and profiles.

By Susanne Pignolet-Brandom

Fourteen samples of crushed Duluth Complex rock were characterized by the QEM?SEM automated scanning electron microscope image analysis system to evaluate the application of the system to mining waste rock characterization. The system can reliably distinguish the iron sulfides, the copper-iron sulfides and the nickel-iron sulfides. Calcite was distinguished from all other minerals except fluorite. The volumetric abundances were verified by comparing elemental abundances calculated using the QEM"SEM volumetric percentages and appropriate mineral compositions with elemental abundances determined by standard laboratory procedure. The pH and sulfate concentrations of rinse water from laboratory leach experiments correlated well with the mineralogical data.

Jan 1, 1989