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By E. G. SINCLAIR

DRILLING wildcat wells in Wyoming differs a little from methods used in any other field. Here it is always advisable to start the hole as large as is convenient in order to carry each string of pipe as far as possible, so that drilling can be continued a thousand feet deeper if necessary, as there is always sand a few hundred feet ahead that really ought to be tested. This plan may seem ambitious, but if it is adhered to, it will save a great deal of trouble before the well is completed. In making the location, one representative from the operating department and one from the geological department should work together, so that the well may be in the best possible place for obtaining oil and the most feasible place to drill for the operating department. In Wyoming nearly all wells are drilled with standard tools, as with them a better log can be kept and better time made in completing the hole. The shales of Wyoming are very hard and do not mix well in a wet hole. The shale cuts into large pieces, too large to be circulated out of the hole, and forms a mat on the rotary which soon cuts off circulation. Then if this mat cannot be jarred from the bit, the drilling string has to be pulled and the mat cut off from the bit with a pick or an axe. I have seen standard tools come out of a wet hole with 10 to 16 in. of mat on the bottom of the bit. Rotary tools have drilled wells satisfactorily in the Big Muddy field and at Billy Creek, but in the other fields the wells have been drilled much more economically with cable tools.

Jan 1, 1926

By William Y. Holland, Roger M. Cook

In view of the increasingly widespread deterioration of concrete structures as the result of the interaction of the alkalies sodium and potassium released by hydration of portland cement and susceptible rocks and minerals in aggregates, it is believed that a paper summarizing the geographic distribution of these aggregates will be of interest to producers and users of concrete, concrete products, and concrete-making materials. THIS paper reviews the problem of alkali-aggre-gate reaction in concrete and describes the geologic and geographic occurrence and distribution of alkali-reactive sand and gravel in western United States. It includes no discussion of crushed stone or synthetic aggregates. Most deposits of sand and gravel are accumulations of particles of rocks and minerals from a variety of sources, and it is not unusual for at least one or two varieties of the rocks to contain some form of reactive material. Examination by petro-graphic methods of many sands and gravels, as well as manufactured aggregates, has shown that a comparatively high proportion of the deposits does contain, in greater or lesser degree, rocks and minerals known to be deleteriously reactive with the alkalies of cement. Fortunately the amount of reactive materials is commonly less than that necessary to cause deleterious effects in concrete. As investigation of unsound concrete structures progresses, it becomes evident that the alkali-aggre-gate reaction is even more widespread than supposed, Figs. 1 and 2. Even though some parts of the country appear at present to be immune, further investigations will probably show that the effects of alkali-aggregate reaction can be seen in many structures in these areas, although only on a small scale in most of them. Many concrete structures will, of course, have lived their useful life before disintegration from this cause is serious, and in others the alkali-aggregate reaction may never become significant even though the microscopic evidence of reaction is present. The alkali-aggregate reaction first was reported to be a cause of deterioration of concrete in 1940 when Stanton1 described expansion of concrete pavements in California. Similar expansion and deterioration of concrete was recognized during succeeding years in concrete structures located in many parts of the country, but particularly in the western states. A number of concrete laboratories2 became interested in the problem. It was soon determined that only certain combinations of aggregate and cement caused the alkali-aggregate reaction to take place, and moreover that the reaction progresses only in the presence of water. Further research proved that cements containing more than 0.60 pct total alkalies (pct Na,O + 0.658 x pct K2O), when used with aggregates containing appreciable amounts of reactive ingredients, caused the reaction to take place, usually with subsequent deterioration of the concrete. During the last few years this limitation has been adhered to in both government and private construction as the maximum allowable alkali content of cement to be used with aggregates of known alkali reactivity. Because of this limitation, it appears that deleterious reaction either has been reduced or eliminated in many recently built structures in which it probably would otherwise have occurred. Recent tests have shown that the degree of expansion obtained with any particular cement-aggre-gate combination depends not only on the alkali content of the cement but also upon the relation of this alkali content to the amount and degree of reactivity of reactive constituents in the aggregate.' In laboratory mortar bars, opal and cements with alkali content of as low as 0.2 pct (as equivalent of Na2O) have produced deleterious expansion as the result of alkali-aggregate reaction. These experiments demonstrate that aggregates containing even 0.1 pct of opal are deleteriously reactive. It was soon determined that alkali-silica gels were formed by the interaction of the alkalies of the cement and the reactive aggregate, Figs. 3 and 4. Osmotic or swelling pressures produced by the continued hydration of these gels cause expansion of the concrete with resulting cracking, warping, and dislocation. Evidence of the alkali-aggregate reaction can be seen by a petrographic study of the deteriorated concrete. Among the first structures studied by this method was Parker Dam on the Colorado River, California-Arizona. In the concrete from this dam pebbles of rhyolite, andesite, siliceous limestone, and chalcedonic chert were found to be reactive.

Jan 1, 1954

By J. D. Aitken

"DEFINITION OF THE REGIONTHE REGION considered in this paper is bounded on the south by the 60th parallel, on the north by the Beau-fort Sea and Amundsen Gulf, on the east by Archean rocks or by highly deformed Proterozoic rocks of the Canadian Shield (certain weakly deformed Proterozoic strata being regarded as belonging to the Great Plains), and on the west mainly by the Mackenzie and Richardson Mountains.Only the unmetamorphosed strata of the region are considered; that is, the geology of the crystalline basement is ignored.SIGNIFICANCE OF THE REGIONThe region is significant from three points of view -namely, the economic, the scientific and the social. It constitutes 46 per cent of the area of the Western Canada Sedimentary Basin."

Jan 1, 1970

The efficiency of a coal mine ventilation circuit is usually measured by the ratio of the sum of the face quantities divided by the quantity supplied by the fans. Other types of systems use the power delivered to the power supplied to measure efficiency. This paper argues the case that the current measure may be inadequate and that by also looking at the power ratio, ventilation may be better managed. Problems associated with failing ventilation systems would be highlighted earlier so that crisis management could be avoided.

Jan 1, 2009

By L. J. Demer, W. W. Walker

AMONG several variables of the indentation hardness test is the effect of loading time on the measured hardness of a material. The most generally recommended duration of loading is 10sec.1-3 Although this short loading duration is undoubtedly satisfactory for harder metals, it is questionable that it is sufficient for very soft metals,4 or for certain plastics.5 The effect of duration of loading on the measured hardness of ionic crystals is largely unknown, although Onitsche and Mitsches found that the indentor (under a very low load) had not yet reached equilibrium after 60 sec in a variety of ionic crystals. To extend further the data of Onitsche and Mitsche, a systematic study was made of the effect of duration of loading for longer periods, up to 50,000 sec, on the 136 deg Dph of synthetic lithium fluoride. For comparison, less extensive tests were made on synthetic magnesium oxide and copper single crystals. The general procedure used was to indent a cleaved and polished (100) face of a lithium fluoride crystal using a Leitz Durimet microhardness tester. In certain cases, the indentor was so oriented as to align the diagonals of the 136 deg diamond pyramid indentation parallel to a (100) edge. In other cases the diagonal of the indentation was aligned at 45 deg to a (100) edge of the crystal. After indenting, the surface tested was etched in the acid etchant recommended by Gilman and Johnston.' This revealed the position of dislocation lines which intersected the surface tested. At these points of emergence were formed the usual sharp, pyramidal etch pits as shown in Fig. 1. The specific procedure used in studying duration of loading was as follows. The surface of the crystal was indented, and the load was left on the indentor for a predetermined time. This duration of loading was varied systematically from 1 to 50,000 sec. After the desired amount of time had elapsed, the indentor was removed from the crystal and the size of the resulting indentation was determined using a micrometer eyepiece. The surface was then etched to reveal the dislocation etch pit pattern around the indentation. Procedures used for lithium fluoride, magnesium oxide, and copper were similar. Preliminary studies revealed that, although an indentation was enlarged by increasing loading time, no corresponding changes occurred in the surface etch pit pattern. Since no evidence of dislocation movement was observed on the surface, it was assumed that the plastic deformation indicated by the indentor sinking into the surface was a result of dislocation movement inside the crystal. This movement was studied bf making a series of surface indentations in a crystal corresponding to various lengths of time, cleaving the crystal vertically through the indentations, etching the freshly

Jan 1, 1964

By Carl Zapffe

JUST as 85 per cent of the total ore produced annually in the United States comes from the Lake Superior region, so does one of its six producing districts-the Mesabi --dominate that region both as to production and total reserves; also in ore Treatment, Mesabi practice is dominant. Therefore, in discussing future reserves or ore treatment one may visualize one big district with five smaller districts as so many satellites. In considering the future less thought need be given to processes than to, economic policies. For thirty years experimental work has now been in progress and every possible ore-treatment process now known has been given attention. This work was started when there was no recognizable danger of running short of ore because of rapid consumption. Thirty years ago the annual production had just progressed beyond the twenty-million bracket for the first time. Today fifty million tons is considered a small production, and last year the aim was for 65 million. At the recent rate of production the life of the estimated reserves of good ore is about 35 years. All who know the local terrain are convinced that, unlike thirty years ago, the chances for discoveries of new big deposits are nil; treatment of lean ores obviously is to become an all-important topic.

Jan 1, 1938

By K. Maruyama, T. Nagasaka, R. d. Chairaksa-Fujimoto, T. Miki

Electric arc furnace dust or EAF dust is considered as a hazardous waste but contains a significant amount of economically attractive non-ferrous metals especially zinc as zinc ferrite (ZnFe2O4) and zincite (ZnO). The hydrometallurgical process is one alternative choice because it has the advantage of low energy consumption. The leaching of ZnO from the dust is very easy. However, the complex major zinc compound in EAF dust is ZnFe2O4, which is very stable and insoluble in alkaline or acidic media under delicate conditions, and causes the low zinc recovery yield by hydrometallurgical process. Moreover, halogens and heavy metals in the dust are also problematic. In order to develop a new effective EAF dust treatment process, the authors have proposed "CaO addition process" as pre-dust treatment to transform all of ZnFe2O4 in the EAF dust to ZnO and Ca2Fe2O5. In this study, the selective zinc leaching from the CaO treated EAF dust with NaOH and NH4Cl solutions was carried out. The effect of temperature, reaction time and solute concentration were systematically investigated. All of zinc in CaO treated EAF dust was successfully leached into both solutions.

Jan 1, 2014

By Nathaniel Wollman

About nine years ago the President's Materials Policy Co commission under the chairmanship of William Paley released its report entitled "Resources for Freedom." Not long ago the Senate Select Committee on National Water Resources under the chairmanship of Senator Kerr released a study entitled Water Supply and Demand. Both reports contained projections of future water user the report for 1975, and the Select Committee print for 1980 and 2000, It is my task to compare the two reports. In the initial letter from Mr. Kazmann arranging for thus session he suggested that I present "a critical evaluation of the Paley Report's section on water ?ten years later,? which might include a comparison of predicted and actual water-use rates and would spotlight the assumptions which lead to errors in the predictions , . ." It is possible to compare the results of both studies, and it possible to explain art of the differences that can be found between them. The remainder must remain shrouded in doubt, since the Paley Report did not give all details of the methods used in estimating the com¬ponents of water use.

Jan 1, 1961

By M. Kozlowski, I. Candy, S. Kashani-Nejad

The production of ferronickel and matte from nickel laterite ores is dominated by the Rotary Kiln, Electric Furnace (RKEF) process. Over time, major improvements have been made to kiln operation. In particular, kilns are now required to perform substantial amounts of reduction of the metallic oxides, thereby reducing the load on the electric furnace and substituting less expensive fossil fuel for electrical energy. To the basic refractory lined cylinder have been added: internal features such as dams and lifters, aimed at changing residence times in different sections of the kiln and enhancing gas/solids interaction, on-board fans to introduce tertiary air and on-board scoop mechanisms to allow reductant coal additions to be made at advantageous locations along the kiln. Many of these advances in design have been made on a trial and error basis and by 'borrowing' technology from related kiln processes, supplemented by proprietary modeling to various levels of sophistication. This paper presents a conceptual review of modeling components for the development of a computational model for granular material flow, combustion and heat and mass transfer in a nickel laterite kiln. These components include: granular material flow and segregation models for the simulation of bed motion, heat transfer models that simulate heat transfer by turbulent diffusion and radiation and the distribution of this thermal energy within the bed, and fluid flow models for the prediction of combustion aerodynamics.

Jan 1, 2005

By R. G. Meara, O&apos

The land-pebble district of Florida, which in 1928 supplied 96.7 per cent of the phosphate production of that State and 82 per cent of the domestic requirements of the United States, is centered in Polk and Hillsboro Counties about 30 miles east of Tampa The deposits are unconsolidated sediments occurring as beds of phosphate matrix overlain by a mantle of barren sands and clays. The matrix consists of a mixture of Sand (quartz grains), clay, and phosphate rock in which the coarsest sand is much finer than the coarsest phosphate; that is, the sand is segregated in the fine material. Before the introduction of classifiers the concentration consisted of log washing, and screening at about 20-mesh, which was usually the finest size that could be taken to maintain commercial grade, 66 per cent B. P. L. (bone phosphate of limey or more. When classifiers were introduced some of the fines that had escaped at the head of the washery and some of the minus 20-mesh material isolated during the rushing and formerly lost supplied the feed.

Jan 1, 1931

By Zhou Haizuo, Diao Yu, Zheng Gang

"The conventional design method for the embankment supported by DM columns usually assumes the simultaneous failure of all the columns. However, the progressive failure may occur in practice, especially considering that many researches have justified the critical load of DM columns is bending moment. In this study, a finite difference method was adopted to simulate the embankment on soft clay improved by DM columns. An increasing surcharge was applied on the embankment surface to investigate the mechanism of the progressive failure of columns beneath embankment. To capture the brittle bending failure of the DM columns, the model employed a cut-off method, in which the column was separated on failed section as long as the ultimate bending failure was reached. Furthermore, high-strength DM columns were used to enhance the global stability of embankment in this study. The numerical results showed that the ultimate bending failure was first reached at the column beneath embankment toe, and then a continuous collapse extended to the column beneath the embankment shoulder. It is found that the reinforcement could be obviously effective when the reinforced area of high-strength DM columns was extended to a certain area.INTRODUCTIONDeep mixed (DM) columns have been commonly used as a soil-improvement technique to increase stability and to reduce settlement of embankment. Research on failure modes of DM columns owing to embankment fill and surcharge has been the subject of interest for a number of investigators (Miyake 1991; Kitazume 2000; Han 2005; 2006).The potential failure modes of DM column include bending, inclination, shearing, rotating, soil flowing and a combination of these modes (Kitazume and Terashi 1991; Broms 1999). Many researchers have found that bending failure of DM columns was more critical than the shear failure. A centrifuge test was performed by Kitazume (2000) and the results showed that the columns failed in bending before shear failure. In addition, several numerical computations illustrated that design method using the shear strength overestimated the stability of embankment over DM columns (Han and Huang 2005; 2006; Navin 2006; Liu 2007; Wang 1996). In practice, an equivalent shear strength method based on bending failure could better reflect the stability of embankment (Zheng 2010; China Code JGJ79-2011)."

Jan 1, 2015

By K L. Silversides, A Chlingaryan, A Melkumyan

Multiple data sources can be fused to improve boundary modelling in stratified deposits such as the banded iron formation (BIF) hosted deposits in the Pilbara Region of Western Australia. Accurate boundaries are essential to produce high quality geological models. Initial models are based on the widely spaced exploration hole data. This creates a high level of uncertainty in areas between the holes, with different interpretations of the boundary equally probable. Including directional information collected in these holes in the models can reduce the number of possibilities. Including data collected during mining, such as blastholes and bench measurements, can further guide the model. This research demonstrates a Gaussian Processes based method of fusing these disparate data sources to better inform the boundaries. Our results demonstrate that when only exploration points are used the model creates a smooth boundary with minimal variation between the holes. Each additional data source refined the model and added additional detail to the boundary. For the blast data, the new detail projects down to the bench below the current bench to allow for a better prediction before mining commences on that bench.

Mar 22, 2022

The General Purpose Simulation System (GPSS) is a computer simulation language that has been used for simulations of open pit haulage operations since the 60's. It is easy to learn, simple to use, and has a block-diagram structure that is amenable to load-haul systems. However, due to its lack of flexibility, there are situations where another language should be chosen. This paper reviews the characteristics and capabilities of both GPSS and FORTFAN with regard to open pit shovel and truck simulation. The relative advantages and disadvantages are highlighted and a case study presented along with comparative results from two computer models (one written in GPSS and the other written in FORTRAN).

Jan 1, 1986

By E. P. Evert

Profitable marketing of most minerals is dependent upon the total delivered cost to the user. Transportation costs are often greater than the value of the mineral f.o.b. the mine or processing facility. In some cases, transportation costs are three to five times the mineral cost. For many years, transportation costs were controlled by a complex system involving the transportation companies and supervised by regulatory agencies. This paper will deal with the effects of deregulation on rail costs and outline the major changes in transportation economics.

Jan 1, 1985

By A. L. Garassino

Dans cet article on parle sortout de l'approche de calcule pour les pieux charges horizontalement avec particuliere reference aux curbes p-y et è une solution semi-empirique qui prende en consideration les variations typiques du module du sol avec la deformation obtenue par les données expérimentales. 1. INTRODUCTION The analysis of the piles under lateral loads depends very strictly from the pile stiffness and geometry, from the soil type and from the strain field. Different approaches were adopted in solving the problem. Some Authors developed methods for estimating the ultimate lateral resistance of piles and pile groups by conventional static approaches, as the Brom's widely known (1964) or by the plane strain solution developed by Davis (1961) or by empirical engineering con­siderations l

Jan 1, 1994

By A McKay

The Great Artesian Basin (the Basin) is a large aquifer system underlying more than 20 per cent of continental Australia and most of Queensland. The aquifers of the Basin are an important water source for many industries, including the mining sector. The Queensland Great Artesian Basin Water Resource Plan (the Plan) was released in March 2006. The Plan provides a framework for the long- term holistic management of the aquifers in the Queensland Section of the Basin, in a manner that is consistent with the strategic management plan for the Basin as a whole. The paper describes the Basin and summarises trends in the demand for water in the Queensland section of the Basin. It describes the broad framework for management of the Basin by the individual Australian states, as well as the planning entitlement framework for water resource management in Queensland. The paper discusses the content of the Plan. This includes: the division of the aquifers into management areas and management units for management purposes, provision for protection of the flow of water to springs, limits on further allocating water, provision for a competitive process for access to new water and provision for water trading. Under the Queensland planning and entitlement system a resource operations plan is prepared to specify operational arrangements to implement a water resource plan. A resource operation plan for the basin is expected to be finalised before the end of 2006. The paper summarises the likely content of the plan.

Jan 1, 2006

By P. D. Arumairaj, B. Vani

"Micropiles are small diameter cast insitu reinforced grouted piles and it has been effectively used in many applications of ground improvement. It increases the load carrying capacity of soil and reduces the settlement. It is also used in strengthening existing foundations. In this study, the effect of Solid and Hollow micropiles on the load carrying capacity of footing resting on sand is studied. The effects of solid Micropiles are investigated by conducting experimental model studies. The parameters involved in this study include the position of pile, pile length and pile spacing. Load test was carried out on a model footing resting on sand with solid and hollow micropiles. Load test trail is repeated for footing on Micropiles with varying lengths of 10, 20, and 30 times the diameter and spacing equal to 5, 4, 3, 2 times the diameter. The load-settlement behavior of each case is compared. Optimum length and optimum spacing of both the solid micropile and hollow micropile are determined. It is also observed that the effect of micropiles in the peripheral of footing resists lateral displacement of soil underneath the footing. The micropile beyond significant depth becomes redundant.INTRODUCTIONA micropile is a small diameter (less than 300 mm) drilled and grouted pile that is typically reinforced - FHWA-NHI 2005 (Federal Highway Administration-National Highway Institution). It is constructed by drilling a borehole, placing a steel reinforcing element into the borehole and grouting it. Hollow micropiles are typically reinforced by solid central bar that occupies about onethird of the hole volume. The grout is placed by gravity, under pressure methods or by a combination of both (post grouting). Thus, micropiles can be considered as small drilled-shafts that are specially drilled and grouted.Historically, micropiles have been introduced in Italy as a foundation system mainly for retrofitting and underpinning of structures that had sustained damage during World War II and access for conventional piling equipment was not possible (Bruce, 1988). The second generation of micropiles is a pressure grouted piles with a central mono all thread bar (with diameter up to 89 mm). They are installed by using either an open or cased hole drilling method.A new generation of micropiles, termed Grout injection bore micropiles (IBOR), was developed in the 1980s. The IBOR, currently named hollow bar micropiles, utilizes a continuous all-threaded hollow steel bar as the drilling and grouting conduit, which allows drilling and grouting simultaneously without the need of a casing during drilling. A sacrificial (lost) bit with openings that allow for pressure grouting of the hole is threaded onto the end of the hollow bar and is left in place following drilling. A drilling fluid (air, water, or grout) is introduced through the hollow bar and allows the spoils to flush from the borehole opening. Upon reaching the required depth, neat cement grout is then injected under high pressure into the drilled hole to fill the annulus between the bar and the soil from the bottom to the top. Due to the grouting method employed, the shape of the hollow bar micropile is expected to have a bulb shape with an enlarged base."

Jan 1, 2015

By F. W. Schremp, J. W. Chittum, T. S. Arczynski

This paper describes a laboratory study of causes of external casing corrosion and the test work that led to the use of oxygen scavengers to prevent this attack. External casing failures are classified as water-line, casing-casing, collar and body failures. A corrosion mechanism based on principles of differential oxygen availability is developed that is consistent with facts known about each kind of failure. The field use of oxygen scavengers is depicted as a direct result of the laboratory study. A part of the paper is devoted to reporting on the field use of hydra-zine to control external casing corrosion. Results of field measurements made over a period of several years are presented as evidence of the efectiveness of the hydrazine treatment. The first conclusion reached is that the use of hydrazine materially reduces the cathodic protection requirements for treated wells. This result is interpreted to mean that a reduction is taking place in the amount of corrosion on the casing. Results indicate also that hydrazine shows its greatest usefulness within the first 12 to 18 months after a well is completed when pitting corrosion is likely to be most active. INTRODUCTION According to surveys sponsored by the National Association of Corrosion Engineers,' the cost of repairing casing leaks caused by external corrosion may exceed $4 million per year. In addition, well damage and lost production resulting from casing leaks probably costs the petroleum industry an additional $5 to $6 million per year. Concern about the cost of external casing corrosion led to an extensive laboratory study of factors causing this external corrosion and to the development of a new approach to its prevention. This paper presents a discussion of various causes of external casing corrosion, details of laboratory studies and the results of the field use of an oxygen scavenger in well cementing fluids to prevent the external corrosion of oil-string casing. Measurements on test wells over a period of several years show that cathodic-protection current requirements are greatly reduced when hydrazine is used in cementing mud. Reduction of current requirements can be interpreted to mean that removal of oxygen by hydrazine has greatly suppressed corrosion cells on the external surface of the casing and thereby, has reduced corrosion. To date, hydrazine has been used by the Standard Oil Co. of California in more than 200 well completions. KINDS OF CASING FAILURES A survey of a large number of casing leaks disclosed four types of external casing failures — water-line, casing-casing, collar and body failures. These types are identified largely by their location on the casing. Water-line failures are found just below the surface of water or mud in the casing annulus. Casing-casing failures occur on the oil string just below the shoe of the surface string. Collar failures are found in the threaded ends of casing joints where they are screwed into casing collars. Body failures may occur at any point on the body of a casing joint. Ex- amples of each kind of failure have some of the general characteristics that are shown in Fig. 1. Water-line failures usually result in the circumferential severance of an oil-string casing. The corrosive action causing a water-line failure usually is sharply defined and is limited to a short length of the casing. Casing-casing failures usually are accompanied by pitting corrosion distributed around the oil-string casing for distances up to 100-ft below the shoe of the surface string. Casing-casing failures may also sever the casing. Collar failures seem to start on the first thread at the bottom of recesses between collar and casing joint. Corrosion proceeds across the threads by what appears to be a normal pitting mechanism. Both casing and collar are severely attacked. Body failures are the result of highly localized pitting at any point on a casing wall. Besides the pit that perforates a casing, a large number of other pits usually are found along one side of the casing joint. The pits occasionally are filled with corrosion products consisting largely of oxides and sulfides.' Frequently, the mill scale is largely intact on the rest of the casing. Examination of a casing failure does not always reveal the cause of the failure. Frequently, the necessary details are destroyed when the failure occurs. For example, formation water flowing through a perforation at high velocity may enlarge the hole and destroy any remaining evidence of the cause of the failure. One way to obtain undistorted information about a failure is to study the nature of other pits on the casing in the vicinity of the failure. A study of such pits frequently suggests that they are characteristic of an attack resulting from the differential availability of molecular oxygen.

By Rolf Hindstroom

Outokumpu Mintec started development of the pressure filter in 1991, and the first unit was delivered to Tara Mines Ltd. Ireland in 1992. The filter replaced a conventional disc filter and a thermal dryer. The replacement of the thermal dryer has improved both environmental and working conditions. The filter is currently dewatering 80,000 tons per year of lead concentrate, producing a cake with less than 6 wt % residual moisture.

Jan 1, 1995

By Thom Mambe, Angelo Fernando

The objective of this work was to identify key parameters related to the reduction of the sulphur content in ammonium diuranate (ADU), and the identification of solid products being formed under various operating conditions. A laboratory-scale, continuous ADU precipitation circuit was assembled using a glass reactor vessel immersed in a temperature-controlled water bath. A pre-prepared uranium feed solution was fed continuously using a peristaltic pump. Anhydrous ammonia mixed with compressed air was metered and pumped using a double-headed peristaltic pump. An over-head mixer was used to keep the solids in suspension. The precipitated ADU slurry was removed from the reactor at the same flow rate as the feed solution. The slurry was sampled to generate ADU solids for chemical and physical analysis after four hours of continuous operation to ensure steady-state conditions. The following variables were studied to determine their influence on the sulphur content in the resulting ADU. (a) sulphate:uranium molar ratio in the reactor (1:1, 1:5, 1:10 and 1:20) (b) precipitation pH ( pH 6, 6.5, 6.9, 7.5 and 9) and (c) precipitation temperature (40C and 60C) A total of 18 tests covering the above parameters were conducted, and the results indicated that the sulphur content in the resulting solids was highly dependent on the reaction pH. Out of the pH levels tested, tests completed at pH 6.9 and 7.5 generated solids containing the lowest sulphur contents, between 0.5 to 1.5% S uranium basis (UB). The sulphur content in solids was found to vary linearly with the sulphate:uranium ratio in the feed solution, showing a statistically valid correlation. The impact of temperature was minor between 40°C and 60°C, with a slight advantage at higher temperatures. Tests at a sulphate:uranium ratio of 1:1 produced solids with the lowest sulphur contents. The influence of pH or temperature on sulphur content in solids was almost non-existent at this sulphate:uranium ratio. Precipitation pH is the major factor influencing ADU sulphur content, followed by the uranium to sulphate ratio.

Jan 1, 2020