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By W. C. Phalen

E. G. SPILSBURY; New York, N. Y.-I would like to emphasize what Mr. Phalen says in his paper regarding the possible utilization of the waste acids in the West for the acid concentration of phosphate rock, and to call attention to the fact that this is already being done by Mr. Laist at Anaconda, who is producing concentrated phosphoric acid from these low-grade rocks. During the last year, he has not been able to carry this along to the extent he, had expected, owing to the tremendous demand which they have had for all the acid they can produce, so instead of having a. surplus of acid, as was expected, they are really short of this material for their electrolytic copper and zinc work.

Jan 4, 1917

By Earl L. H. Sackett

Barite, although not a glamour mineral and probably little known to many of those in the mining business, is produced in the US. in very respectable quantities and is an important factor in the mineral economy of this country. The scope of the various uses of this mineral is perhaps one of the most misunderstood things about it, for it is surprising how many of those with a casual knowledge of the subject speak of its primary utilization in terms of paint pigments and barium chemicals. The life blood of barite utilization, however, is the petroleum industry by virtue of its dependence on this high specific gravity, inert mineral as the weighting material in its drilling fluids. From 80 to 85% of barite usage in the U. S. is accounted for in this manner-in fact, its role in oil well drilling is the only excuse for some of the large-scale barite production facilities which have been developed. Other uses are important and widely varied, but comparatively they are of small scale. They include fine crushed barite of low iron content as a component in glass manufacture, barite as a source material for manufacture of barium chemicals, finely divided barite as a component of some rubbers and ground, bleached barite in pigments. The formerly substantial use of barite in lithopone, however, has declined markedly because of replacement of lithopone by titanium pigments

Jan 5, 1962

I HAVE previously demonstrated to you as well as I knew how in what way ores are treated and then how the separated metals are brought to their pure and ultimate limit of perfection by means of smelting and other artificial fires; all except gold, which remained incorporated in the silver. Because the method used for the others does not serve for this, and if indeed it did serve it would be a great labor and could not be done without a great loss of the thing, it is therefore necessary to proceed with the practice of another art if you wish finally to extract gold from the bonds of the intrinsic substance of silver, for it exists bound and scattered in this like the soul in the body of living creatures. In this, unlike the other works where you make direct use of the vigor of the fire, you use a substance that is like water, drawn by the force of fire from a very powerful composition of two materials. This is a very marvelous thing to consider as a liquor because of its powerful effects. It is made by artificial distillations and it has an acid property and the power of corroding and reducing into itself silver and any other metal placed in it, with the exception of gold. Nothing is apparent in it except a pure water. It is indeed a very ingenious thing for which we must be greatly indebted to that philosopher, alchemist, or whoever else was its discoverer. The silver that contains gold is put in this water, and from its former quiet state you will see it change as if forced to combat and breathlessly devour and consume that silver in itself and change it into water. This happens in a very short time and with very little help from the heat of the fire. All the gold that was united in the silver you will see like sand at the bottom, and when the water is taken off by decantation it will freely give you all the gold without any loss. Nor is it so ill-mannered as to fail to restore the silver to its place if you wish; and though it seems to have consumed and spoiled it as it was before, it returns it to you without loss. Since the process of this art is a very useful thing for anyone who knows

Jan 1, 1942

By J. V. Gluck

In the present paper," as in earlier publications, V1'2"1 the authors present experimentally obtained relations for the free energy of solution of oxygen in various metals as a function of temperature. The relations are linear and given in slope-intercept form. The authors give values for the "probable error" of the slope and intercept, citing Birge's method17 for obtaining these quantities. Birge discussed these methods as early as the period 1929-32.25726 In Ref. 25 the probable error is defined as "the numerical value which the true error is as likely to exceed as not", i.e., 50 pct probability. Ref. 26 is even more detailed and includes a lengthy discussion of the applicability of the Gaussian distribution to experimental data. However, the use of the "probable error" has come under some question. For example, Ezekiel'~ states that "the use of the probable error tends to make the results appear rather more accurate than the standard error". Moroney28 stated (in 1951) that "the term 'probable error' was used in former times to denote 0.67450 (50 pct confidence using the normal distribution)....the term, a poor one, is now very much obsolescent. It has been said that 'it is neither an error nor probable' ". Bennett and Franklin in 1954" in discussing statistical confidence levels mentioned that "the customary use of the 5 and 1 pct levels is not completely a matter of chance; these levels probably represent a balance between the desire to be correct and the desire to be specific. Also in most people's minds the borderline between something that could possibly happen and something that is not likely to happen is somewhere in this region. Certainly 5 or 1 pct confidence limits are to be preferred to limits such as the 'probable error' which has only a 50/50 chance of including the correct value." It may readily be seen that the 95 pct confidence level, which is given by 1.960 (assuming large sample size), thus corresponds to approximately three times the "probable error". Indeed, limits of one standard deviation correspond only to about 68 pct probability. Even if we triple the tolerances given by the authors in the equations of their Table 111, the deviations do not become excessive and would not detract from their excellent results. It could then be said with a high degree of confidence (95%) that the precision of the slope and intercept values is about *3-5 percent of their absolute levels rather than the 1-2 percent implied in Table 111. This is then compatible with an earlier suggestion of Gokcen~' of a probable accuracy of 5 pct in dissolved oxygen measurements by the technique employed. Alternatively, the authors could have

Jan 1, 1967

By N. W. Xu, C. Sha, F. Dai, Y. G. Zhu, B. Li

Underground caverns stability and excavatability of rock masses are of significance in geotechnical engineering, in both design and construction stages. Risks associated with underground group caverns of Houziyan hydropower station in southwestern China are growing as a result of continuous excavation-induced unloading. To improve our understanding of the underground caverns instability and resolve the complex subsurface conditions of the highly fractured rock mass, a high resolution microseismic monitoring system was established in the deep underground caverns, pursuing the relationship between the measured data about microseismic activity and excavation damage zones of surrounding rock mass. Through analyzing the tempo-spatial distribution of microseismic activity, excavation damage zones and potential risk regions in underground caverns were identified. Furthermore, the correlation between microseismic activity and pre-existing geological structures, as well as traditional monitoring was analyzed. In order to validate the correlation between seismicity and potential slip surface of underground caverns, a model was implemented into numerical code to further evaluate the deformation and stability of surrounding rock mass. The monitoring results demonstrate that microseismic events mainly occur at high stress concentration regions, which coincides with the results obtained from numerical analysis. Therefore, the comprehensive method incorporating microseismic monitoring and numerical analysis, as well as traditional monitoring and filed observation has been proven to be very promising in deformation and even instability prediction of surrounding rock mass in underground caverns subject to delineation of potential slip surfaces and excavation damage zones.

Jan 1, 2015

By K. E. Stanfield

Asphalts from. Wyoming "black oils" are being studied at the Petroleum Experiment Station of the Bureau of Mines at Laramie, Wyo., in cooperation with the University of Wyoming. These black oils are characterized by their high-asphalt, high-sulphur, and low-gasoline content and are difficult to refine by present methods into high-octane motor fuels, burning oils, and lubricants. Accordingly, their principal use, at present, is for the manufacture of road oil and asphalt. The present production of black oil could be increased to meet a greater demand. During 1937 the daily production of these crude oils in Wyoming was slightly over 13,000 barrels, while, the estimated potential production from existing wells was 56,000 barrels.

Jan 1, 1939

By E. P. Youngman

This paper is one of a series of digests of foreign mining legislation and court decisions that is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines in various foreign countries . This interpretation of the mining laws of French Indo - China is a translation of an article published by the Department of Mines of Indo - China ; 4 and it is released subject to correction and amplification by the proper American foreign- service officers .

Mar 1, 1933

By J. Menuge, G. Barker

"Liberation (QEM-SCAN) and surface chemical (time of flight secondary ion mass spectrometry -ToF-SIMS) analyses have been undertaken on plant Pb circuit flotation samples with the aim of defining the factors resulting in sub-optimal recovery. Lead flotation circuit feed, cleaner concentrate and tails samples were examined on a size-by-size basis using QEM-SCAN. Sulfide minerals accounted for approximately one third of the flotation feed with pyrite making up 16 wt.%, followed by sphalerite (13 wt.%) and galena (3 wt.%). Non-sulfide gangue minerals comprised calcium carbonates calcite (26 wt.%), dolomite (14 wt.%) with quartz, feldspars and barite all contributing > 5 wt.%. QEM-SCAN analysis indicated that liberation was not the primary cause of the poor flotation response. Principal component analysis was applied to the ToF-SIMS data derived from five samples (as for QEM-SCAN plus rougher concentrate and tails) to enable identification of correlated surface chemical components. Although a significant range of correlations were observed we focus here on those that show a discernible pattern throughout the float circuit. It was found that for the flotation feed the surface of galena were largely obscured but where Pb was observed there was a strong correlation to surface Fe. For the rougher and cleaner concentrates the galena surfaces were relatively clean with no correlation to Fe for the rougher concentrate and minor correlation in the cleaner concentrate. However, in the rougher and cleaner tails the clear correlation of galena with Fe was again apparent. These results suggest, in combination with prior studies of pyrite morphology, that the principal factor effecting grade is the rapid oxidation of the framboidal pyrite resulting in the contamination of the galena surface with a high loading of hydrophilic oxidised Fe species, thus depressing flotation."

Jan 1, 2014

By Milford L. Skow

Utilization of domestic ores in the winning of metallurgical alumina requires a convenj.ent method of treating siliceous bauxites and other aluminous materials. In the United states there are only small reserves of high-grade bauxite but considerably larger tonnages of low-grade material. In addition, there are large deposits of high-alumina clays. If these high-silica bauxites or high-alumina clays could be beneficiated, either by are dressing or by chemical dissolution to remove a large proportion of the silica, then the potential reserves of aluminum ores would be increased materially. Faced with a similar situation, the German industry, chiefly dependent on high-grade French bauxites prior to World War II, was compelled during the war to Use lower-grade ores. For desilicating the lower-grade bauxites before the Bayer treatment, a method was developed in which the bauxite was calcined and then given a dilute caustic leach preliminary to the pressure digestion. It was planned to regenerate the caustic by treatment of the desilication liquor with lime. As European bauxites are mineralogically different from those found in this country, preliminary work was undertaken to determine whether this process might be applied to domestic materials. The results of this work, along with a review of the German process, are presented in this report.

Jan 1, 1950

By Ting-Wei Wang, Yung-Wen Chen

Artificial ground freezing is commonly used globally during excavation of shield tunnels and for groundwater control. It is a special construction method for temporary ground improvement that involves introducing coolant into underground pipes to freeze water in the soil. The frozen soil is cemented together as a result to form a frozen wall, which provides high strength and low permeability. Once the thickness of the ice wall reaches design requirements, underground excavation can be conducted with the coolant removed afterward to return the soil to its original state. This technique is cost-effective in scenarios where complete groundwater cut-off and excavation support are required; where work is deep underground and faces difficult ground conditions and where access restrictions limit the use of other displacement-type ground improvement techniques. Due to the demand for shield tunnel construction for utilities in Taiwan, ground freezing has become an important soil stabilization method there. In this article, we will share two brine freezing case studies and an in situ liquid nitrogen experiment that was conducted to develop this technique.

Feb 1, 2022

By J. Jacobs

The three-product cyclone was originally developed in Russia and is now extensively used in China. The cyclone has recently entered the South African coal industry, and with the obvious advantages that this item of process equipment offers our ever-evolving industry it is safe to assume that it will add value to dense medium circuits in South Africa. Some of the possible applications include: ? Producing multiple products using a single dense medium circuit. These can typically be a primary product with calorific value of 27.50 MJ/kg and a secondary (middling) product with a calorific value of 22 MJ/kg ? High-density separation with a low circulating medium density. Anglo Thermal Coal and Exxaro have pioneered the use of these units at Umlalazi and New Clydesdale respectively. Extensive test work has been performed at Umlalazi to determine the efficiency of the unit and to determine how it compares with the conventional DSM (Dutch School of Mines) cyclone. Some people in the coal industry were initially sceptical and expected the performance of the three-product cyclone to be inferior to that of the conventional dense medium cyclone. The results of the test work have, however, shown that the efficiency of the unit is comparable to that of the cyclones currently employed. A valid concern expressed is the control over the cut-point density of the second stage separation, and work is on-going to find the optimal way to control the secondary separation density. Theoretically, the secondary separation density can be manipulated by changing the orifices of the unit, especially the spigot of the secondary stage. This remains to be proven, and a series of tests is currently being planned. Whatever the result of these tests may be, the three-product cyclone definitely has a place in the South African coal processing industry as it offers a low OPEX and CAPEX solution for producing multiple products from a single circuit, as well as the ability to operate at very high separation densities, while making use of low-density circulating medium. Keywords dense medium separation, DSM, three-product cyclone, coal processing.

Nov 1, 2013

By J. Sammarco

Proper illumination is critical to a miner?s ability to detect hazards in underground mines. Moving hazards are often located in the miner?s peripheral field-of-view, while slip/trip/ fall hazards are often located in the forward field-of-view. The objective of the research described in this paper was to determine if light-emitting diodes (LEDs) improve visual performance as compared to traditional incandescent (INC) cap lamps. The research presented focuses on comparative studies of a National Institute for Occupational Safety and Health (NIOSH) prototype LED, a commercial LED and an INC camp lamp. Thirty subjects participated in these studies, with ten subjects in each of the following age groups: 18 to 25 years, 40 to 50 years and 51+ years old. Visual per­formance was quantified by the subjects? speed and accuracy in detecting hazards, while visual performance for disability glare was quantified by the use of contrast sensitivity tests. Results suggest that LEDs with a visible spectrum containing a higher concentration of the shorter wavelengths can enable visual performance improvements with respect to disability glare, the detection of moving hazards in the peripheral field-of-view and the detection of floor hazards in the forward field-of-view. The NIOSH prototype LED cap lamp provided the best visual performance improvements for the older age groups in every test.

Jan 1, 2009

By Marta Cabral, C. A. Nogueira, F. Margarido

"Physical processing of spent batteries which includes shredding and sieving operation is the first step for chemical treatment by hydrometallurgy. A laboratory study was carried out to evaluate physical processing efficiency, by analysing the resulting particle size, of alkaline and saline mignon-type Zn-MnO2 batteries. After shredding with a tip shredder, results obtained showed that alkaline batteries were more efficiently size reduced than saline batteries. Difference in particle size distribution was larger for granulometric fraction -20+11.2 mm and also higher for saline batteries. Average diameters (d50) for saline and alkaline batteries were respectively 9.1 and 6.2 mm. Chemical composition carried out on several granulometric fractions allowed to identify metals distribution through size categories. This analysis showed that zinc concentration with the grain size was almost constant, while manganese decreased when particle size increased. More than 95% of iron scarp from the battery cases had a particle size higher than 5.6 mm.IntroductionRecycling process of spent batteries includes physical unit operations which involves a fragmentation step in order to open the battery cases and to allow the access of chemical reactants to the electrode materials, on further chemical unit operations. Shredders are usually used for that purpose, using cutting mechanisms and allowing efficient fracture of residues in order to promote further processing of the contained materials. Batteries are complex products with a large variety of sizes and shapes which causes serious difficulties for predicting and carrying out its fragmentation.Domestic-type batteries are essentially of the Zn-Mn systems and with cylindrical shape, varying from the large size Mono (or D) type to the small size Micro (or AAA) type [1]. Recycling of batteries involves collection, sorting [2] and metallurgical processing [3, 4]. In some processes, the first step of metallurgical processing is dismantling and size reduction by shredding. Research work on spent batteries considering grinding/shredding and physical separation of fractions is scarce [5-7], but investigation in this domain is very necessary."

Jan 1, 2008

By J Ross

The foundation of effective leadership is communication. You can have all the leadership theories, models and training you want, but in the end it is all about leaders talking to, listening to and understanding the point of view of those below and above them.The foundation of effective safety is peoples’ behaviours. Every incident, every near miss and every safe act comes down to what one person does and how that affects themselves and others. We tend to focus these behavioural considerations on the people at the ‘coal face’, those most in harm’s way. But it is the individual behaviours of everyone in the organisation, particularly those at the top, which are just as (if not more) important. The foundation of effective safety leadership in the mining industry is that it starts at the top, with the individual behaviours of leaders. The behaviours of each and every leader will be reflected in their teams. And where their teams are made up of leaders, these leaders will pass these behaviours on to their teams and so on. It’s the sum total of what people see their leaders do and what they do as a result, that creates the ‘culture’ of the business – and it’s this culture that makes or breaks how safely people work.

Mar 21, 2011

By A. Pezzuto

"Pipes are used on mine sites in a variety of applications including transport of slurry, conveying clean and processing water, and in mine dewatering. Mine waters and slurries can cause pipe wear and failures via several mechanisms (or combinations thereof) such as abrasion, scaling, and corrosion. Polyethylene (PE) pipe materials have grown in popularity over the past several decades due to their chemical and mechanical properties (e.g., inertness, flexibility, relatively low density) and low cost. While PE is generally resistant to corrosion, it is subject to abrasion. To combat this, a novel, rubber-like liner is in development. In addition to comprehensive abrasion testing, however, the liner must be evaluated to see how it performs under other conditions. Here, a brief field study is described that tested PE pipes with the new liner against traditional PE pipes to specifically assess mineral scale buildup. The study was conducted in the Reiche Zeche study mine in Freiberg, Germany in six different locations with varying water qualities and flow conditions. INTRODUCTION Water and slurry conveyance are major operations on and around mine and mill sites, from mine dewatering, to tailings transport, to water treatment processes. Conveyance systems in such applications can include great lengths of pipe materials along with pumps and monitoring instruments, and thus represent significant capital investments. Due to the variability of the physical and chemical properties of water and slurries, pipe materials are subject to a wide range of conditions. These can cause pipe wear and eventually failure leading to serious economic, environmental and social, consequences. While pressure-induced pipe failures (e.g., ruptures or ""bursts”) can be immediate, most failure mechanisms involve gradual processes. Scaling and sedimentation can present major problems for pipe systems conveying highly mineralized waters. Sedimentation generally refers to the deposition of suspended solids, such as sand, clay, silt, or organic matter onto pipe surfaces. This phenomenon can occur due to a decrease in water velocity or particle collisions with the pipe wall. Scaling, on the other hand, commonly refers to the deposition of precipitated mineral salts (including oxides and hydroxides) onto pipe surfaces. Mine waters often have extremely high ion concentrations (i.e., high dissolved solids content) due to their interaction with enormous surface areas of minerals, which are exposed during mining and processing operations (Brown and Barley, 2002). As these waters are transported, slight changes in temperature, pressure or chemistry (e.g., pH or ORP) can cause instability with respect to ion solubility such that salt precipitation begins to occur. “Seed” crystals can rapidly grow and attach to pipes, either due to local surface phenomenon near the pipe wall (e.g., which can promote coagulation) or sedimentation of the precipitated solid. Whether due to suspended or precipitated solids, as the solids begin to stick to pipe walls, “aging” or hardening processes can commence; and the build-up of scale can become self-perpetuating as the scale itself provides an attractive “nucleus” for further attachment of particles or crystal growth (Muryanto et al., 2014). Over time, scale-buildup reduces the effective pipe diameter, which can ultimately result in decreased flow velocity, clogging and, in some instances, bursting (Dirany et al., 2016)."

Jan 1, 2017

By James C. Cawley

The Bureau of Mines has empirically determined ignition probability versus current for resistive circuits in an 8.3% methane-air atmosphere. Simple ignition probability, defined as the number of ignitions divided by the total number of sparks, was determined, and the corresponding currents were recorded. The experiment was designed to minimize the probability of not observing an ignition that should occur during a series of tests. For resistive circuits in 8.3% methane-air mixtures, the experimental results indicate that ignition was not achieved below 2,000 rnA at 20 V dc, 350 rnA at 30 V dc, 150 rnA at 40 V dc, and 175 rnA at 50 V dc. The simple probability of ignition corresponding to these currents is esti-mated to be, respectively, 1.0 x 10-6, 1.7 x 10-7, 3.0 x 10-7, and 1.0 x 10-5 The ignition mechanism seems to break down below this point, implying that a threshold current value exists below which spark ignition does not occur.

Jan 1, 1987

By S. Setayeshgar

The identification of potential accidents on construction sites has been a major concern in the construction industry and it needs a proactive safety plan to reduce the risk of accidents. There are no efficient methods for checking if safety measures are taken properly on construction sites. Consequently, workers on site are not given enough awareness about dangerous areas. In addition, construction sites are dynamic and on-site situations are changing in terms of permanent and temporary structures and facilities. This information can be represented using Building Information Modeling (BIM). This paper proposes the integration of BIM and safety risk analysis by considering the risk levels associated with the work spaces of different construction tasks. Work spaces are generated in a BIM model according to the Work Breakdown Structure (WBS) of the project, reference objects in the BIM, and the schedule and resources of the task. Each work space is assigned to one or more tasks or functions, e.g., work spaces for specific tasks, shared spaces (paths), storage spaces, or spaces prohibited to workers. The assignment of work spaces is based on the workers, equipment and materials involved in the task. All the work spaces are associated with a specific duration according to the schedule of the project. Then risk evaluation of the construction site is applied in order to evaluate safety risks based on their severity and the degree of exposure of workers. For example, work spaces for storing hazard materials and for heavy construction equipment have higher risks than other work spaces. The results of the risk evaluation can be visualized in a 4D BIM model.

Aug 1, 2013

By I. K. Choi

In a recent paper by Smith and Wen(1) the adsorption of sodium dodecylsulfate and trimethyldodecylammonium chloride on kaolinite was studied. As would be expected considering the general negative character of kaolinite, except perhaps at quite' acid pH values (2,3,4), it was found that trimethyldodecylammonium chloride adsorbed strongly on kaolinite at basic pH values. Furthermore, it was found that sodium dodecylsulfate adsorbed strongly on kaolinite at acid pH values, particularly at initial 1H values below pH 3 (final pH values near pH 4). It is interesting to note that adsorption of the anionic surfactant was strong under conditions where the kaolinite was apparently slightly negatively charged (2). The present paper reports on an extension of the work by Smith and Wen. In this paper the effects of the presence of dodecyl alcohol and sodium hexametaphosphate on adsorption of sodium dodecylsulfate and trimethyldodecylammonium chloride on kaolinite are considered.

Jan 1, 1967

Nauru Phosphate, which is one of the world's highest grade deposits discovered to date, contributed in 1969, 2.2 million tons of the total world production of 77.7 million tons. Phosphate production, which is the major source of revenue for the island nation, is carried out by the Nauru Phosphate Corporation, headed by a Government appointed Board of Directors. The complete mining operation, including ship loading techniques, is discussed along with proposals at present being investigated to upgrade the Quality of the product.

Jan 1, 1971

By G. Sachs, E. J. Ripling, S. I. Liu, J. J. Lynch

INTRODUCTION IT is a generally recognized fact that by repeated straining the fracture stress of any metal is reduced to a fraction of its value for static loading. The value of this fatigue strength depends upon numerous factors, such as the states of strain and stress, the limits of straining, and the number of repeated loadings or cycles.1.2,3 The large volume of previous investigations on fatigue is concerned entirely with large numbers of cycles, say exceeding 10,000 and up to 500,000,000. However, the changes in fracture stress and fracture strain occurring after a small number of repeated loadings have attracted little attention. Apparently the only investigations of this type are those byLudwik4,5 who subjected steel, copper, and aluminum wire to repeated torsion. In each test the torque was varied between identical values in the two directions of twisting. Depending upon the magnitude of the moment, fracturing occurred after a number of cycles, up to 10,000. The results of Ludwik's tests will be discussed later. Such torsion does not readily yield actual stress and strain values. Therefore a preliminary study was made of the effects of repeated direct stresses, i.e., tension and compression stresses. Because such tests are considerably more tedious than torsion tests, only high stresses were used in the preliminary work, yielding definite changes in metal properties after a few cycles. It was found in these tests that strains could be controlled more readily than stresses in the investigated range of high stresses. This paper, consequently, deals with the effects of strains of equal magnitude but different signs. The metal was first prestrained in static tension by a certain amount then subjected to compression to yield the same amount of strain after unloading. This loading cycle was repeated up to a maximum of seven times. After various cycles, the stress-strain curves in tension were determined, up to fracturing. As material for these tests, the aluminum alloy 24ST was selected because it exhibits a comparatively small amount of necking in the tension test. This alloy permitted, therefore, rather accurate control at the high strains necessary to produce fatigue failures at less than seven cycles. The results of this investigation appear sufficiently interesting to extend the method of attack in various directions. It is intended to study (I) the effects of cycles up to a few thousands and (2) the effects of strains of different magnitude in tension and compression, respectively. The latter variable also includes as a special case the effects of compressive strains.

Jan 1, 1948