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By N. S. Dalal, X. Shi

It has been known for more than a decade that vanadium (V) stimulates the oxidation of NADH by plasma membranes (1) but the underlying mechanism is still not fully understood. This effect has been attributed to a membrane-associated NADH-dependent vanadium (V) oxidoreductase (1). Subsequent studies suggest that vanadium ( V) can accept an electron from fiavoprotein dehydrogenase that oxidizes NADH (2). The phenomenon ofNAD(P)H oxidation coupled to vanadium(V) reduction has also been demonstrated in other biological systems (3-6). A recent electron spin resonance (ESR) study from our laboratory reported on the accumulation of vanadium (IV) duringthe reduction ofvanadate (vanadium(V)) by the ftavoenzymes glutathione reductase (GSSG-R),4 lipoyl dehydrogenase, and ferredoxin-NADP+ oxidoreductase in the presence of NAD(P)H (7). It was concluded therein (7) that these ftavoenzymes function as NAD(P)H-dependent vanadium(V) reductases. More recently, however, Liochev and Fridovich (8) have argued that the ESR data (7) do not demonstrate that the investigated fiavoenzymes act as vanadate reductases. They suggest an alternative mechanism in which the fiavoenzyme simply serves as a generator ofsuperoxide (02) radical, which acts as a propagator of the radical chain reaction leading to NAD(P)H oxidation (9, 10), as summarized below:

Nov 1, 1995

By P. F. Mataich

"Why bother with computer control?" This question and others like it have been heard over and over again by those who have tried to convince operating men that there are sound merits to installing a process control computer. At IMC we have done a great deal of thinking and talking about computer control. In the course of these discussions the operating people have asked a number of questions about computer control. These questions and our answers to them make up the main part of this article. Obviously, the answer as to whether or not to go into computer control will be an individual problem conditioned by your company's circumstances. What I hope to do here is raise some questions, give you an idea of our thinking on the subject, and lay out some general guidelines for you to consider.

Jan 1, 1965

By Frédéric Flament, Mary Goldman, Gille Barbery

"Pilot plant testwork on autogenous and semi-autogenous grinding was conducted at the Centre des Recherches Minérales du Québec (CRM) to investigate the effect of ball addition, solids concentration in the feed, specific energy consumption and feed size distribution.A mathematical model that incorporates breakage and surface mechanisms of loss of mass was developed to predict load size distribution of autogenous and semi-autogeneous mills. An empirical model was used to predict product size distribution of autogenous and semi-autogeneous mills.IntroductionAutogenous (AG) and semi-autogenous (SAG) grinding circuits offer potential capital and operating cost savings when compared with conventional grinding. Empirical relationships have been developed to calculate specific power consumption for SAG mills using pilot plant test results (Mular et al., 1989; Barrett and Allan, 1986). Empirical models can be obtained from plant practice data but are applicable only to the particular ore and set of operating conditions used in the model. Grinding mechanisms have to be taken into account in order to develop a model that can be applied to different ores and mills.In AG and SAG, the ore itself acts as grinding media, with the finer sizes being crushed by the coarser ones. Surface mechanisms of loss of mass, in which the inner core of the particle remains intact, also take place. In SAG milling, the effect of balls also has to be taken into account. The role of each one of these mechanisms changes with particle size and the model has to account for such changes."

Jan 1, 1991

By Walter G. Perkins

As this particular product holds a place by itself, it seems desirable to give a paper dealing especially with it as a corollary to my paper entitled " The Litharge Process of Assaying Copper-Bearing Ores and Products, and the Method of Calculating Charges."* The process is first to convert the metallic copper into matte by the addition of sulphur, allowing the two elements to combine at the bottom of the crucible when heat is applied. The

Jan 1, 1903

By L. A. Stinnett

An investigation of hazardous surface openings of abandoned and inactive underground mines in the Black Hills area of South Dakota has revealed: (1) tracing legal ownership of mineral claims via county courthouses is confusing, complex, and oftentimes misleading, (2) in general, the selected mine openings in this investigation are to be considered relatively high in risks and hazard potential which poses a threat to the general public, (3) mine closure procedures and designs can generally be categorically implemented depending on the overall situation of the particular mine opening with subsequent unit costs estimates, (4) few preventive state or federal legal measures exist to date concerning mine closures, and (5) liability damages relating to mine opening accidents usually involve expensive and complex common law cases.

Jan 1, 1979

By C. Mick Lownds, Dale S. Preece, Ali Bhuiyan

FDM (Fracture Density Model) is a three-dimensional mechanistic model of blast induced rock fragmentation. FDM uses several computational mechanics algorithms to simulate the effect of blasting in different rock types. Earlier, FDM was successfully exercised to simulate 29 small scale shots from the United States Bureau of Mines (USBM), and 6 full-scale bench blasts at the Bararp dimensional stone quarry in Sweden. Excellent agreement was obtained for those shots, and the results were documented in earlier publications. One of the drawbacks of previous ver- sions of FDM was its inability to predict the fines, specifically in Bararp quarry simulations. Ac- curate predictions of fines can be very useful in reducing energy consumptions during down- stream comminution processes and improve the mine-mill operation efficiencies. In this paper, we propose a newer algorithm that can predict the fines as well as the coarse fragments in Bararp with reasonable accuracy. The model was also applied to an open-pit Copper mine with heavily jointed rocks, and it produced very good fragmentation predictions for the full range of fragment sizes. Comparisons with the sieved fragmentation data (for both Bararp stone quarry and the open- pit Copper mines) show great potential for this updated version of FDM in modeling the entire range of fragment size distributions in mining and quarrying applications.

Feb 6, 2023

By M. V. Chari

A prime objective of physical coal cleaning is the separation of raw coal into a clean coal product with the required low ash and pyritic sulfur content and a high ash refuse. The refuse should also contain a minimum amount of combustible matter. In order to be effective, cleaning processes require that the mineral matter in the feed, including pyrite, be largely discrete and free particles, liberated so that the particles are not attached or embedded in coal. Liberation of mineral matter from coal, particularly pyrite, was investigated by Bechtel as part of two fine coal cleaning research programs sponsored by the Department Of Energy (DOE), Pittsburgh Energy Technology Center (PETC). Two proof-of-concept (POC) plants, each with a capacity of 900 kg per hour, were installed and tested to evaluate production of ultra-clean coal using microbubble flotation and spherical agglomeration technologies. The plants were designed to produce clean coal with 2 percent ash and pyrite content lower than that achievable by conventional methods. Also, the quality targets were to be attained at energy recoveries above 80 percent. Bench-scale flotation and agglomeration tests indicated that it would be practical to grind the 6 mm top size feed coal to a mean particle size (050) of 10 micrometers in the POC test plant. In this part of the paper, the steps taken in the grinding circuit to maximize liberation of mineral matter are described.

Jan 1, 1991

By Geoffrey G. Hunkin

This is a brief state of the art paper describing current (1975) Uranium recovery plant flowsheets, some notes on system selection, design philosophies, and materials of construction. The in-situ, or borehole solution mining, of Uranium is a process which has been developed over recent years to better match Uranium mining and milling technology with the size, shape, grade and territorial distribution of the remaining identified Uranium deposits of western United States. Solution mining recovery plants are pure hydrometallurgical units ideally suited to automation, modular design, and mobility. Similar to conventional Uranium mills, two basic flowsheets, one acid and one carbonate, are in use, but the predominance is reversed so that the majority of plants employ the alkaline carbonate flowsheet, All plants incorporate resin bead ion exchange Uranium recovery for both acid and alkaline circuits.

Jan 1, 1976

By Charles Camsell

At the last annual meeting of this Institute the programme very properly was drawn up and carried out with the special object of calling attention to the Dominion's position and problems with regard to fuel supplies. That subject, always one of serious concern, was a source of considerable anxiety twelve months ago. It is still so, but in a decidedly less degree than at that time. So far as the immediate fuel situation is concerned our anxieties have been relieved. And I think we can safely say that such a consciousness of our difficulties and determination to overcome them, has been developed in the minds of our people that there will be no slackening of the offensive until a final solution is reached. In selecting a subject of major importance for the present occasion I have felt free to digress from the pressing problems of last year and to go back, for a starting point, to the presidential address of two years ago .. I do not, however, wish to enter the controversy that has developed as a result of that address, though in spite of my own failure to amass a fortune from participation in certain mining ventures, I am decidedly inclined to the optimistic view that Dr. Corless presented of the future of our mining industry. You will perhaps have observed that in its general wording the title of my paper bears a marked resemblance to that of that address. This simila1ity of titles is not accidental. It is intentional on my part.

Jan 1, 1924

By Shaik Jeelani, Esperidiana A. B. Moura, Vijaya K. Rangari, Roberta A. Lima, Rene R. Oliveira

This work present the preparation and characterization of biodegradable nanocomposites based on aliphatic-aromatic copolyester (PBAT)/polylatic acid (PLA) blend reinforced by TiO2 nanoparticle. The biodegradable polymeric nanocomposites were prepared by melting extrusion process using a twin-screw extruder machine. The influence of the TiO2 nanoparticle addition on mechanical and thermal properties of PBAT/PLA blend was investigated by tensile and impact tests, SEM, DSC and XRD analysis and the correlation between properties was discussed.

Jan 1, 2015

By David W. Wisecarver

This report describes a tool to engage and/or place a Bureau of Mines type gage to measure borehole deformation in a horizontal , 1½ - inch - diameter , stress relief borehole . The tool was successfully used at a borehole depth of 105 feet . Practical usage up to borehole depths of 200 feet might be realized . The tool was designed to work inside EX- size ( 1½ - inch ID ) diamond - drill drive casing used as drill rod and through which the deformation gage is guided into an EX- size stress relief borehole . Through laboratory experiments it was found that by exercising a reasonable amount of care the deformation gage could be placed at a point within a ± .01 foot distance of a predetermined depth in a horizontal EX- size hole and that the deformation measuring piston or plunger of the gage could be oriented in the borehole within 0.5 ° of a preselected angle of orientation in a vertical plane .

Jan 1, 1964

By G. S. Rice

The recommendations of the Bureau of Mines on rock dusting practices are embodied, except in a few details, in the Recommended American Practice for Rock-Dusting Coal Mines to Prevent Coal-Dust Explosions, approved by the American Engineering Standards Committee. December 30, 1925. It is specified that the dust to be used is of a elm that all will pass through a sieve having 20 meshes per linear inch and that 50 per cent or more will pass through a sieve having 200 meshes per linear inch. Thus the coarsest size of dust and the minimum proportion of fine dust are specified, but the specification does not indicate whether a larger proportion of fine dust would be desirable. There have been advocates of the use of that size of rock dust of which the particles would all approach 200-mesh in fineness. Explosion tests were made in the Experimental mine in the earlier period of testing which indicated that the finer rock dust is somewhat more effective under test conditions, but not sufficiently so to Justify the cost of finer grinding of the dust; also there are some disadvantages of finer dust described hereafter.

Jan 1, 1930

By AIME AIME

TRADITIONALLY, the Annual New York Meetings of the A.I.M.E. cover four days, but the program is growing on each end as well as in the middle, and this year it lasted from 3 p. m., Sunday, Feb. 16, when the Education Division got under way, to 8:40 p. m., Friday the 21st, when a trainload of electrical inspectors, pro tern, got back fro111 the General Electric plant at Schenectady. The meeting has ceased to be a mere three- ring circus: on Wednesday afternoon eight sessions were being held simultaneously in the Engineering Societies Building, if one includes the Woman's Auxiliary, and according to frequent testimony one should include the W. A. as one of the most important units in Institute affairs.

Jan 1, 1936

By Howard W. Kilau

The U.S. Bureau of Mines is investigating surfactants added to water sprays to enhance the control of dust during coal mining operations. The objective of the present work was to establish the general applicability of adding sulfate ion to anionic surfactant solutions in order to improve wetting action. This was pursued through laboratory wettability testing of four anionic surfactants and one nonionic surfactant in combination with various concentrations of sulfate ion. The experimental results demonstrated that the addition of sulfate ion enhanced the wetting characteristics of all the anionic surfactants when applied to hard-to-wet coals, while easy-to-wet coal showed more complex wetting behavior. Sulfate ion in the presence of nonionic surfactant enhanced wetting only slightly or not at all. Surface tension measurements of the dilute aqueous surfactant-sulfate anion solutions indicated this property was not important in coal-wetting phenomena, as long as the value was below the critical value for coal. Sulfate ion helps surfactant reduce surface tension but primarily appears to affect wetting action by altering the adsorption characteristics of surfactant on the coal surface.

Jan 1, 1990

Design models for belt conveyors used in mines predict both the belt power requirements and belt tensions. Conveyors with slightly downhill profiles are more complex to predict due to the way that models such as CEMA interpret friction. Performance of a particular conveyor in relation to other conveyors in the same system requires an analysis of natural stopping times, braked times and take-up location. A review of CEMA-based PC models is presented for design of underground multi-flight belt systems.

Jan 1, 1995

By A. A. Jr. Smith, J. S. Smart

Numerous investigations of the effects of the various impurities common to commercial coppers have been published, and the data have found wide use in industry. Naturally, emphasis has been placed on the oxygen-bearing coppers of the tough-pitch variety, but need is now evident for data covering the oxygen-free condition as well. Furthermore, relatively few of the important reactions between oxygen and the various impurities are well understood, and often the data at hand are not applicable to the low concentrations encountered in commercial coppers. This paper presents the changes in conductivity and softening temperature derived from individual additions of the group VIII triad, iron, cobalt and nickel, to high-purity copper, and constitutes a portion of the copper-research program being conducted at the Central Research Laboratory of the American Smelting and Refining Co. The method of preparation of high-purity copper and its alloys in either the oxygen-free or oxygen-bearing form has been described previous1y.l The purity of this material, and the methods developed to produce it, provide the means for direct investigation of the very low concentration range in which the various impurities generally exist in commercial coppers. The usual necessity for extrapolation to this range using the results obtained from higher concentrations, and the interfering effects of extraneous impurities, are thus simultaneously circumvented. Since previously published data have adequately presented the effects of higher concentrations of iron, cobalt and nickel, the present investigation has been confined to the composition range o to 0.05 per cent. All alloys were initially prepared in the form of oxygen-free continuous cast rod, the weighed alloying additions in suitable form being charged with the pure copper to the continuous casting crucible. The best of the available high-purity alloying materials were used, and spectrographic analyses confirmed the absence of interfering elements from the alloys formed. Each series was compounded in the direction of increasing concentration, starting with pure copper in a new crucible and finishing with the 0.05 per cent alloy. Composition was closely controlled by adding the alloying element in the form of a carefully compounded and analyzed master alloy rendered uniform by continuous casting. The accuracy of this method of synihesis was proved by chemical analysis of the more concentrated alloys, and, accordingly, there is every reason to credit the stated composition of the very dilute alloys in the range where chemical analysis becomes highly uncertain. Oxygen-free samples for measurements of conductivity and softening temperature Were obtained by drawing the continuous cast rod to wire of 0.08I-in. diameter. employing a number of intermediate anneals to refine the grain structure. The

Jan 1, 1942

By A. A. Jr. Smith, J. S. Smart

Numerous investigations of the effects of the various impurities common to commercial coppers have been published, and the data have found wide use in industry. Naturally, emphasis has been placed on the oxygen-bearing coppers of the tough-pitch variety, but need is now evident for data covering the oxygen-free condition as well. Furthermore, relatively few of the important reactions between oxygen and the various impurities are well understood, and often the data at hand are not applicable to the low concentrations encountered in commercial coppers. This paper presents the changes in conductivity and softening temperature derived from individual additions of the group VIII triad, iron, cobalt and nickel, to high-purity copper, and constitutes a portion of the copper-research program being conducted at the Central Research Laboratory of the American Smelting and Refining Co. The method of preparation of high-purity copper and its alloys in either the oxygen-free or oxygen-bearing form has been described previous1y.l The purity of this material, and the methods developed to produce it, provide the means for direct investigation of the very low concentration range in which the various impurities generally exist in commercial coppers. The usual necessity for extrapolation to this range using the results obtained from higher concentrations, and the interfering effects of extraneous impurities, are thus simultaneously circumvented. Since previously published data have adequately presented the effects of higher concentrations of iron, cobalt and nickel, the present investigation has been confined to the composition range o to 0.05 per cent. All alloys were initially prepared in the form of oxygen-free continuous cast rod, the weighed alloying additions in suitable form being charged with the pure copper to the continuous casting crucible. The best of the available high-purity alloying materials were used, and spectrographic analyses confirmed the absence of interfering elements from the alloys formed. Each series was compounded in the direction of increasing concentration, starting with pure copper in a new crucible and finishing with the 0.05 per cent alloy. Composition was closely controlled by adding the alloying element in the form of a carefully compounded and analyzed master alloy rendered uniform by continuous casting. The accuracy of this method of synihesis was proved by chemical analysis of the more concentrated alloys, and, accordingly, there is every reason to credit the stated composition of the very dilute alloys in the range where chemical analysis becomes highly uncertain. Oxygen-free samples for measurements of conductivity and softening temperature Were obtained by drawing the continuous cast rod to wire of 0.08I-in. diameter. employing a number of intermediate anneals to refine the grain structure. The

Jan 1, 1942

By Arthur B. Cummins

Diatomite is a siliceous rock of sedimentary origin, which may vary in degree of consolidation, but which consists mainly of the fossilized remains of diatoms. These are microscopic algae of the order Bacillaria. Diatomite is a unique form of silica, there being nothing else found in nature or produced by the manufacturing arts, that has its characteristic physical structure. There are numerous sediments which contain some diatom residues, admixed with a substantial amount of other materials-clay, carbonates or silica. While these are classified as diatomaceous silts, shales, or mudstones, they are not properly diatomite, a designation which is restricted to material of such qualities that it is suitable for commercial uses. The terms diatomaceous earth and kieselgur are synonymous with diatomite. The expressions infusorial earth and tripolite are obsolete. Diatomaceous silica is a definition best used to distinguish the basic component of diatomite, that is, the substance of the silica shell itself and is the major constituent of beneficiated diatomite or processed diatomaceous products. Some highly indurated materials, such as cherty shale, porcelanite, and opaline cherts which have resulted from diagenetic changes cannot be considered as diatomite although they may have been derived therefrom. On the other hand, diatomaceous oozes or loose sediments consisting mainly of diatom residues with or without much organic matter are source materials in process of becoming diatomite. Composition and Properties Pure diatomite is composed of opaline or hydrous silica, with small amounts of associated inorganic components-alumina, iron, alkaline earths, alkali metals, and minor constituents, all of which may occur in solid solution or as an essential part of the opal complex. Crude diatomite on the other hand may contain variable amounts of organic matter and soluble salts, and the usual contaminants of sedimentary formations-particles of rockforming minerals, sand, clay, or carbonates. As occurring in nature, diatomite contains an unusual amount of free water, which may vary from 10 to 60 pct or more. Diatomite, in the dry deposits which are characteristic of most of the important world deposits, occurs as a lightweight, comparatively light colored, "chalklike" material. The apparent density (dry basis) in situ varies from 20 to 40 lb per cu ft. The structure may be either massive or finely stratified. The earth is highly porous, usually soft and easily friable. It is nonreactive with acids and may be tentatively identified by the above characterizations. Confirmation is by microscopic examination which readily reveals the nature of the material. In deposits which contain organic matter the appearance of the material is totally different. The color may vary from light tan or gray to brown, greenish or nearly black. There is frequently difficulty in distinguishing it in the field from peatlike materials, but the difference is readily apparent after calcination. Powdered diatomite or diatomite products have an apparent density (loose weight) of 5 to 16 lb per cu ft, wet densities of 10 to 30 lb per cu ft, specific gravities 1.9 to 2.35, index of refraction 1.42 to 1.48. Diatomite is essentially micro-amorphous, but does show some tendency toward orientation in structure after a cristobalite pattern. Amorphous silica has been considered as a random association of cristobalite crystallites, the size of which are only slightly larger than a unit cell.20 The prop-

Jan 1, 1960

By F. Fournier Dit Chabert, F. Tancret, J. François Castagné, R. Le Gall

During the repair of turbine blades by a laser cladding process, it is observed that interdendritic cracking occurs in the heat affected zone (HAZ). Auger electron spectroscopy, performed on sample broken at high temperature, reveals interfacial sulfur segregation, which is known to be one of the main causes of microcraking in the HAZ during welding processes. Moreover, thermal gradients generated by the process are responsible for important thermomechanical stresses. In the present work, the finite element code Comsol Multiphysics is used to simulate the laser cladding process in order to determine both the thermal field and, using an elastoplastic law, the stress field inside the component. The originality is that the temperature history calculated in the thermomechanical model is extracted then injected in a segregation model in order to calculate the local segregation behavior. This model can be eventually used to predict the risk of cracking as a function of process parameters and alloy chemistry.

Jan 1, 2006

By M. S. Badollet

"IntroductionAsbestos as received by the manufacturer of asbestos products is •in the •form of either crudes or milled fibres processed to different degrees of texture. Frequently, the manufacturer finds that l:ihe fibres as he buys them are not adaptable to his plant processes, and, therefore, it is necessary for him either to contact the mine supplying the material and request a specific texture for the :fibre or to reprocess the fibre in his own plant.When the mine or mill manager is requested to change his milling equipment to produce a special grade of fibre with a specific texture, he would like to comply. However, if he began to make special fibre grades for each customer, he would be in the position of constantly rearranging his milling technique, adding more equipment, or building a new mill. In the end, his mill would he producing hundreds of different fibre grades of varying degrees of texture, which is a difficult accomplishment if he desires to maintain any quantity of production."

Jan 1, 1950