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By James E. Lawver

Response surface methodology is a well-known and powerful technique for determining optimum conditions in flotation systems. One disadvantage is the onerous task of the numerical calculations and curve platting. This paper describes a system in which the investigator simply selects the range of several flotation variables after which the design of the experiment, data analysis, generation of response surface equations, and response surface plats are automatically carried out using a digital computer and a computer-driven curve plotter. Several typical response surfaces of important variables in phosphate flotation are presented as examples. An overview of the flow charting of the system is provided in the addendum.

Jan 1, 1978

By J. J. Cai

The status of fossil fuel and secondary resource in metallurgy industry in China were reviewed, and conversion efficiency of fossil fuel, utilization technologies of secondary energy were studied. Fossil fuel, accounting for over 90% of energy structure in metallurgy industry, took in the highest flight in China, and a great deal of which was converted to secondary energy through the equipment of blast furnace and coke oven. These secondary energy which were mostly made of blast furnace gas(BFG), coke oven gas(COG) and Lindz Donawitz gas(LDG) occupied about 30% of total secondary energy. The way enhancing fossil fuel conversion efficiency, secondary resource recovery and the secondary energy such as BFG, COG, LDG utilization promoted to save fossil fuel was discussed in this paper. And efficient use of lower caloric value fuel was studied, such as preheating combustion air and fuel, generating electricity power etc. and regeneration purposes of high-caloric fuel was also researched, for producing hydrogen, methanol or direct reduction iron etc. The using model of secondary energy at iron and steel works was presented as fuel and chemical materials. The results suggest that utilization of these energy efficiently and reasonably could help to energy saving and environment protecting.

Jan 1, 2014

By I. James, R. J. Durrheim, M. S. D. Manzi, O. Valeshin, J. Lepine, L. V. Socco, C. Colombero, A. Malehmir, M. K. Rapetsoa, M. Sihoyiya

The FUTURE project aims to enhance seismic surveying in South African mining by integrating advanced acquisition technologies. In this paper, we detail surface and underground seismic surveys at the South Deep gold mine as part of the project. Surface seismic acquisition used co-located broadband micro-electromechanical sensors, one and three component recorders connected to geophones, distributed acoustic sensing using a straight fibre optic cable, along with a 6 ton broadband seismic vibrator operating with 4–180 Hz linear sweeps. In addition, underground surveys employed a combination of straight, and helically wound fibre optic cables, cabled-based and nodal sensors, along with a 500 kg drophammer mounted on a skid steer bobcat. The surface and underground seismic arrays were time synchronised using a GPS-time transmitter to allow for accurate seismic data recording in a GPS-denied environment. Results show the efficacy of these techniques in acquiring high-resolution seismic data, revealing detailed subsurface geological structures and mineralisation down to 3500 m below ground surface. Surface data revealed clear seismic reflections corresponding to the Black Reef and Ventersdorp Contact Reef. An underground P-wave velocity model exhibits low velocity anomalies that are associated with fracturing, while a P-wave reflection stack section shows significant reflections and a degree of faulting below the tunnel floor that was not observed on the surface reflection seismic data. We highlight the potential of these technologies to enhance safety, efficiency, and sustainability in mining. This study sets a benchmark for future reflection seismic surveys, paving the way for safer, more efficient, deep mineral exploration and extraction practices.

Jan 12, 2025

By M. Sokoto, H. Hata, K. Nishina, K. Haiki

Fluoride ions in zinc electrolyte cause corrosion to aluminum cathode plates at zinc electrowinning process, so we have developed an iron compound as a fluoride ion adsorbent used in zinc sulfate solution. The iron compound is synthesized from FeC13 solution with a small amount of sulfate ion by neutralizing reaction with Na2CO3 solution. The fluoride ions adsorbed on the surface of the iron compound are desorbed in alkaline solution and the iron compound can be reuse as a fluoride ion adsorbent. Moreover, if adsorption capacity of the iron compound decreases, it can be dissolved in HCl solution and re-synthesized.

Jan 1, 2008

By Fredrik Søreide

Several potential marine mineral deposits of various types have been identified within the Norwegian EEZ. The Norwegian University of Science and Technology has recently designed and built a new remotely operated vehicle (ROV) system for scientific investigations of the deep-ocean and seafloor. A program to locate and investigate the most interesting of the identified marine mineral deposits using the new ROV system is underway. The ROV has been designed for detailed survey and sampling tasks. Although initially built for a major marine archaeology project, the design is equally suited to locate and investigate marine mineral deposits. The ROV is equipped with a high precision multi-sensory package that consists of various high quality cameras and lighting systems (together with state-of-the-art video and photo mosaic systems), several sonar systems, magnetometer and various other sensors. The ROV is also equipped with a 7-function manipulator arm and an excavation system. Internal collection baskets are used to store material for retrieval to the surface. A closed-loop control dynamic positioning system is used for detailed positioning of the ROV. Position data and other information are stored in a digital data management system. The ROV will also be used together with a specially developed remotely operated tool (ROT). The size and shape of this benthic lander can be adjusted before it is carefully lowered to the seafloor. The ROV can be docked on a moving platform on the ROT, to do detailed scientific investigations. The ROT can also be equipped with a separate sensor and system package, including drilling, excavation and coring units. This paper will present the new remotely operated system and the planned projects in Norway.

Jan 1, 2004

By Yusuke Kimura, Ken-ichi Yamaguchi

"Secondary materials have long been processed at the S-furnace of the Mitsubishi continuous copper smelting and converting process at Naoshima Smelter and Refinery. Intensive recycling in the recent years has formed concerns that impurities in the secondary materials may cause drastic changes in the chemical properties of the CL-slag, which is separated from matte in the smelting stage. Among various impurities included in secondary materials, the authors have studied the influences of sodium oxides in the CL-slag because the behavior of sodium oxide has scarcely been studied with respect to the copper smelting slag. The examinations have been applied experimentally on the distribution between slag and matte of arsenic whose acidic characteristics suggest strong affinity to sodium-oxide of basic characteristics in silicate melts. The results have been discussed by thermodynamic evaluations and the results of pyro-tests at the commercial furnace.IntroductionAt Naoshima Smelter and Refinery, the existing line of the Mitsubishi continuous copper smelting and converting process has been operated since 1991. The Mitsubishi Process consists of three furnaces namely the S-, CL- and C-furnace as shown in Figure 1. In the S-furnace, copper concentrate and powdery secondary materials (scraps, sludges, etc) are charged through the top lances with oxygen enriched air. The other secondary materials of lumpy shapes are charged through the chute installed on the furnace roof. Charged materials are smelted by the reaction heat in accordance with the oxidization of copper concentrate. The mixed melt of matte and slag overflows through the launder into the CL-furnace, where the melt is separated into slag and matte by the difference of their specific gravity. Matte is siphoned out and sent to the C-furnace and converted to blister copper continuously. The CL-slag overflows continuously through the slag outlet to be water-granulated. Granulated slag is sold as a raw material used for the cement production and so on. Various secondary materials have been processed at the S-furnace of Naoshima Smelter and Refinery. Intensive recycling in the recent years has formed concerns that the chemical properties of the CL-slag may change drastically due to impurities originating from secondary materials. Among various impurities included in secondary materials, the authors have studied the influence of sodium oxide in the CL-slag because the impact of sodium oxide has scarcely been studied with respect to the copper smelting slag. The examinations have been applied experimentally on the distribution between slag and matte of arsenic whose acidic characteristics suggest strong affinity to sodium-oxide of basic characteristics in silicate melts."

Jan 1, 2012

By Saeid Pournaderi, Ahmet Geveci, Ender Keskinkilic, Yavuz A. Topkaya

"This study investigated calcination behavior of one of the Turkish laterite deposits, which was recently found in Sivrihisar region. Representative limonitic laterite samples (1.26% Ni) taken from Yunusemre Karasivritepe and Kucuksivritepe location were first subjected to drying. Removal of chemically bound water and other volatiles were then studied, in detail. In the calcination experiments, temperature and time were the main experimental variables. Thermal treatment was conducted at the specific temperatures in 250 °C - 800 °C range. The weight losses due to elimination of chemically bound water and other volatiles were reported to be approximately 10 per cent of the weight of the ore. For the particle size used in the current work, 700 °C and 40 minutes were determined to be the optimum calcination temperature and time, respectively.IntroductionThe nickel ores that are economically valuable can be grouped into two categories: sulphide type nickel ores and oxide type nickel ores, namely laterites. Over all reserves in the world, 40% are sulphide nickel ores and the remaining 60% are laterites [1]. Pyrometallurgical nickel extraction from sulphide type nickel ores is conducted via matte smelting. More recently, laterite ore bodies have been subjected to nickel extraction. Depending mainly on the chemical composition of the laterite and the process economics, various extraction techniques have been implemented: pyrometallurgical route involves ferronickel smelting. High pressure acid leaching (HPAL) is the commercial method for hydrometallurgical nickel extraction, while ammonia leaching (CARON Process) is a combination of pyrometallurgical and hydrometallurgical processes [2]. With the improvements in these processes, it is predicted that laterite’s share in the world nickel production will rise to 50% in 2012, while it was reported to be 42% in 1,200,000 tons of annual production in 2003 [3]."

Jan 1, 2011

By Yosep Han

Mechanically-induced chemical reactions between natural beach ilmenite (FeTiO3) and silicon (Si) have been examined by a combination of X-ray diffraction (XRD) and scanning electronic microscopy (SEM) analyses. The effect of various milling time on the phase transformation, crystallite size, and lattice strain of a beach sand ilmenite with silicon, and on their leaching behavior in hydrochloric acid (HCl) has been investigated. For mechanically activated FeTiO3, the crystallite size decreased and lattice strain increased monotonically with time of milling. However, the mechanochemically synthesized ilmenite with silicon showed a relatively smaller crystallite size and greater lattice strain compared with the mechanically activated ilmenite under the same milling condition. In accordance with the elapse of milling time, the intensity of both pure FeTiO3 and mechanically activated FeTiO3 gradually decreased. However, in case of the mechanochemically synthesized ilmenitereduction of FeTiO3 by silicon resulted in formation of rutile TiO2 at the milling time of 20 h and afterwards. Additional leaching experiments were carried out at an HCl/ilmenite (wt%) ratio of 20:1. The concentration of HCl was 3 M and the reaction temperature ranged from 70 to 90 oC. Mechanical activation was observed to significantly enhance the dissolution rates of both iron (Fe) and titanium (Ti) in HCl. Particularly, effects of both milling time and silicon addition on the dissolution rates of titanium and iron were significant, while those of temperature were relatively minor under the conditions investigated in this study. Keywords: mechanochemical treatment, natural beach ilmenite, silicon, leaching behavior

Sep 1, 2012

By M. Maeda, H. Sasaki

"Precious metals such as platinum, palladium, and rhodium are commonly used for automotive catalyst converters. To recover these metals with lower environmental load and cost, exposure to zinc vapor was proposed as a pretreatment prior to acid leaching. Alloying with zinc is expected to enhance dissolution of precious metals and reduce the amount of toxic chemical agents required for the leaching. This study examined the effect of the alloying pretreatment using model catalysts. Catalysts were immersed in leaching solutions for a predefined time with or without zinc vapor pretreatment, and the amount of dissolved metals was then evaluated. INTRODUCTIONAutomotive catalysts account for large portions of the world consumption of platinum (Pt), palladium (Pd), and rhodium (Rh) (Butler, J., 2011). Because of their limited production and high prices, recovery of the precious metals from spent catalysts is obviously an important issue. A representative structure of an automotive catalytic converter can be described as a monolithic ceramic support with a honeycomb structure which is coated with porous oxides such as those of aluminum (Al2O3), cerium (CeO2), and zirconium (ZrO2) (Heck & Farrauto, 2001; Matsumoto & Shinjoh, 2007). Small particles of precious metals, originally several nanometers or less, adhere to the oxides.Typical recovery processes for precious metals from scraps are shown in Figure 1 (a)-(c) (Habashi, 1997; Yoo, 1998; Shibata & Okuda, 2002). Precious metals can be recovered by using non-ferrous smelters as Figure 1 (a) shows. Smelted along with metals such as copper (Cu), precious metals and ceramics in the scraps are absorbed into the metal phase and slag phase, respectively. Because the metals separate from Cu as anode slime in successive electro-refining, such a process can recover precious metals as co-products of Cu. However, in order to prevent negative effects on the principal process, a specialized procedure is needed. Figure 1 (b) is a specialized approach in which scraps are melted at elevated temperature with Cu called the Rose process. Here Cu works as a collector metal, and the absorbed precious metals are then concentrated by oxidation of Cu. Such a process can separate precious metals from ceramics constituting catalyst converters. Smelting at high temperature, however, requires extensive equipment as well as a high amount of energy. On the other hand, hydrometallurgical processes may be effective to separate precious metals from ceramics into an aqueous solution, because chemical agents can act on these metals selectively (Figure 1 (c)). Leaching of precious metals, however, requires strong acid and oxidizing agents because of their corrosion resistance; this makes liquid waste disposal and the large environmental load controversial. To solve the problem, a metal vapor pretreatment was proposed (Okabe, Yamamoto, Kayanuma, & Maeda, 2003a, 2003b; Kayanuma, Okabe, Mitsuda, & Maeda., 2004; Kayanuma, Okabe, & Maeda, 2004; Itoh, Kayanuma, Miyake, Kimura, & Maeda, 2005). A flow diagram of the process using zinc (Zn) vapor is shown by Fig. 1(d). Exposed to Zn vapor, precious metals are expected to form alloys which dissolve more easily than pure precious metals, thus reducing the use of chemical agents and environmental load involved with successive leaching. In previous research (Sasaki, Miyaki, & Maeda, 2010; Sasaki & Maeda, 2010, 2012), dissolutions of precious metal alloys formed by Zn vapor treatment were examined in hydrochloric acid (HCl) using an electrochemical method, and it was confirmed that these metals dissolved at higher rates from the alloys than from their pure states (Figure 2). In this study, the availability of the alloying pretreatment was demonstrated by testing on model catalysts in leaching solutions."

Jan 1, 2012

By William Reisz

Many different types of drills coming in a wide range of sizes and configurations are used in the blasting industry today. While each system may have its own unique attributes and capabilities, it may hold its own perils as well. This article will focus primarily on hazards that are mutual to most every type of drilling system.

Jan 1, 2013

By Xiang-yang Zhou

Keywords: Low-Grade Dolomite, Low CaO Content, High Specific Surface Area, MgO. A low energy consumption preparation technology of magnesium oxide with low calcium oxide content and high specific surface area from low-grade dolomite has been investigated. The optimum technical conditions for the preparation of magnesium oxide are the followings: dolomite is partially calcined at 750-800° for 2 h; the optimum solid-liquid ratio range in calcined dolomite slurry is 20-30 g?l?1; carbonation temperature, carbon dioxide pressure and end point pH value of carbonation are less than 40°, 0.4-0.6 MPa and 7 respectively during carbonation process; decomposition temperature of Mg(HCO3)2 solution is near 100°; calcination temperature of the precursor (i.e. precipitated basic magnesium carbonate) is less than 850°. More than 90% of magnesium can be extracted by the technology. The MgO product (CaO < 0.38%) with a specific surface area of near 50 m2?g?1 also can be obtained by the technology.

Jan 1, 2005

By Jr. Jones

This paper is derived from a document that compiles autogenous and semi-autogenous mill installations worldwide, through the end of 2010. Updates have been solicited from all major mill manufacturers and most have responded. A review of AG/SAG mills sold to date and in the last five years indicates that the AG/SAG mill market is very healthy and the trend is larger diameter mills with high diameter-to-length ratios. Ring motors (gearless) are the preferred drives for large mills even though the power transmitted through a gear drive is expected to near 11,000 kW per pinion in the near future.

Jan 1, 2012

By M. B. Freeman

Acrylic polymers have been found to be effective dispersants and stabilizers in a wide variety of mineral processing applications including rheology control in concentrated slurries. This paper will describe these low molecular weight, water-soluble polymeric dispersants and provide a basis for how they function in concentrated slurries based on computer molecular modeling and applications results. Data on homopolymers as well as copolymers of acrylic acid will be presented to demonstrate the optimization of a polymeric dispersant in preparing high solids slurries of inorganic materials such as kaolin, calcium carbonate, lime, and magnesium hydroxide.

Jan 1, 1996

GENERAL CONTRACTOR: ALEXANDER CONSTRUCTORS, INC. STRUCTURAL ENGINEER: CAGLEY & ASSOCIATES, INC. GEOTECHNICAL ENGINEER: F.T. KITLINSKI & ASSOCIATES, INC. PILE FOUNDATION CONTRACTOR: L.G. BARCUS AND SONS, INC. PROJECT PROFILE: 108-10 in. diameter AugerPiles installed to an approximate depth of 32 ft. Piles were installed through Stiff Clayey Fill and Medium-Dense Sands to Decomposed Shale. Piles were drilled to a refusal criteria of 1 ft. / 3 min. Piles were installed using a Barcus Mantis AugerPile rig which is large enough to install piles 25 to 50 ft. long outdoors. The Mantis is also ideal for indoor and low overhead installations. On top of being extremely versatile, the Mantis is also very economical to mobilize. The existing structure is supported on H-Piles. The AugerPiles were furnished and installed for less than the material price of the H-Piles. Design loads were under 40 tons which eliminated the need for a load test. AugerPiles were selected for minimal vibration, limited noise, and economy.

Jan 1, 2001

By M. B. McClenaghan, O. P. Lavin, Ian Nichol

"Abstract-Exploration in most areas of Canada has to contend with problems posed by glacial overburden. In many areas exploration for gold has been based on the sampling of tills, frequently by deep overburden drilling, and analyses of heavy mineral concentrates. Notwithstanding the significant role that till geochemistry has played in the discovery of some important gold deposits over the last few years, increased appreciation of the nature of the glacial history and stratigraphy and the character of gold within till has led to the recognition of a number of ways whereby the effectiveness of exploration can be improved upon.In order for till geochemistry to be useful in exploration, a number of conditions must be fulfilled, including:1. mineralization, or alteration halo related to mineralization, subcropping at the bedrock /over­ burden interface; 2.glacial erosion and dispersal of a recognizable signature of mineralization into the glacialsediments; 3, preservation of glacial sediments containing this geochemical component (trace metal or mineral) at positions subsequently selected for sampling (normally drill sites); 4. correct identification of specific till units and associated ice movement history; 5. collection of adequately large and representative samples; 6. appropriate sample preparation and processing; 7, appropriate geochemical analyses; and 8. correct data processing and interpretation.While we have no control over the first two geological conditions, and only limited controlover till availability, we can control the quality and thoroughness of sampling, sample identification, sample preparation, analysis and interpretation. In particular attention needs to be focussed on obtaining a large enough sample to be adequately representative, an unbiased sample must be collected, together with appropriate sample processing, analysis, data processing and interpretation. It is considered that by modifying or extending existing approaches to gold exploration the chances of exploration success can be increased. In particular, analyses of both the heavy mineral and minus 63 ?m fractions of till is recommended because gold in till may occur in different size fractions."

Jan 1, 1992

By M. G. Fleming, F. Warner, R. W. Boswell, M. J. Cahalan

The annual dinner of the Institution was held at the Savoy Hotel, London W.C.2, on 22 April, 1971. The President, Mr. M. J. Cahalan, was in the Chair; members and guests numbered 320. The toasts of The Queen and Queen Elizabeth The Queen Mother, Prince Philip The Duke of Edinburgh, The Prince of Wales, and the other Members of the Royal Family were proposed and loyally honoured. R.W. Boswell proposed the toast of the Institution of Mining and Metallurgy, the president responded, Professor M.G. Fleming proposed the toast of the guests and Sir Frederick Warner replied

Dec 1, 1971

By Ruirui Wei, Mingrui Yang, Xuewei Lv

Calcium ferrite, as the main bonding phase in the sintering process, greatly influences the property of sintered ore. Ultrasonic vibration has been widely applied to the treatment of metals to improve the properties of metals. In this work, ultrasonic vibration was introduced into the calcium ferrite and numerical simulation was carried out by solving the Rayleigh-Plesset equation to investigate the influence of ultrasonic conditions, including frequency, power and initial radii of cavitation bubbles on the cavitation bubbling behavior in calcium ferrite melt. The results indicated that lower ultrasonic frequency, higher power, and an appropriate initial radius of bubble promotes ultrasonic cavitation.

Mar 1, 2018

By C. G. Bieber, R. F. Decker

The effects of minor constituents on the malleability of nickel alloys are described. These effects are related to the atomic diameter, valence, and position on the Periodic Table. The basic methods for removal or neutralization of deleterious elements are then reviewed. Finally, practical methods for melting nickel alloys are described in detail and related to minor constituent control. L HE first malleable nickel was produced by Fleit-man in about 1870 by the addition of manganese and magnesium to the molten metal to counteract the harmful effects of sulfur. Merica and Waltenbergl explained the mechanism by which these elements accomplished the desired result. They showed that sulfur in concentrations in excess of about 0.005 pct produced films of a brittle low melting eutectic of nickel-nickel sulfide which completely surrounded the grains. When manganese was added to molten nickel it reacted with the sulfur to form manganese sulfide which precipitated as widely scattered globules in the grain boundaries. The further addition of small amounts of magnesium converted the sulfur to a very stable sulfide of magnesium which was relatively insoluble in both the liauid and solid states and therefore occurred as finely divided particles within the grains where it had relatively little detrimental effect upon the malleability of nickel or its alloys. The practice of treating nickel with manganese and magnesium came to be called "deoxidation" and was employed without appreciable modification for the commercial production of wrought nickel and high nickel alloys (in this paper—50 pct or more nickel) until about 1930 even though the results were never entirely satisfactory. At that time a more extensive study was made of the effects of minor constituents on malleability and metallurgical quality. The results, small portions of which have been published,2-4 are presented here with other pertinent data. EFFECTS OF MINOR CONSTITUENTS UPON NICKEL Systematic additions were made of 0.5 pct or less of each of most of the elements of the periodic ta- ble. It was established in this study that some minor constituents other than manganese and magnesium were extremely influential. The malleability, as evaluated by the reduction of area in tension tests, depended roughly on temperature as shown in Fig. 1. Four temperature zones are of interest; the cold malleable zone (up to about 1000° F), the red short zone from roughly 1000° to 1500&apos; F, the hot malleable zone around 2000° F and the incipient melting zone. Most of the malleability problems are associated with the red short zone and the discussion will concern this mainly. The reduction of area in normal tensile tests on high-purity nickel (see curve A of Fig. 1) appeared to have no

Jan 1, 1962

By John P. Turner, Benjamin J. Turner

"Tieback anchors are now used routinely for landslide stabilization in the USA and abroad. It is generally understood by design engineers that friction loss over the unbonded length of a tieback anchor is inherent to the system, and such loss is permitted as long as it does not exceed a certain threshold, typically 20 percent of the post-tensioning load. However, recent experience from projects utilizing tieback anchors with unbonded lengths in excess of 150 feet has demonstrated that this criterion may be difficult to achieve, particularly in certain ground conditions. Furthermore, anchor friction loss, even if below the 20-percent threshold, has important implications for the stability of the slope that are often ignored in practice. This paper presents the results of a study in which friction loss is quantified from load test data for projects in a variety of ground conditions by means of a “wobble coefficient.” Factors that may influence the wobble coefficient are examined, and recommendations for addressing this issue in practice are presented. A recent instrumented load-test program for a landslide stabilization project in Southern California is examined, demonstrating that with appropriate monitoring controls, uncertainty with regard to friction loss can be minimized. IntroductionSteel-strand tieback anchors have been used by the geotechnical community to support shoring systems for many decades, and more recently as a means to stabilize landslides. For strand encased in grease-filled plastic sheathing, which is intended to allow the strand to elongate freely, some load can still be transferred by friction between the strand and the grease and between the grease and sheathing. The sheathing then transfers load to the surrounding grout and, in the case of ground anchors, to the surrounding soil or rock. The resulting decrease in load over the length of the unbonded zone is known as “friction loss.”A widely used criterion for ground anchor acceptance based on load testing is that the measured anchor elongation must achieve a minimum value of 80 percent of the theoretical elastic elongation, or in other words the actual elongation can be up to 20 percent less than the theoretical value. This ensures that the majority of the load applied at the anchor head is reaching the bond zone behind the assumed failure surface, since load shed within the failure mass does not contribute to stability. This criterion acknowledges that friction loss is an inherent feature of the anchor system which cannot be eliminated completely, only minimized."

Jan 1, 2017

By S. Lin

A new hydrogen production process, named the HyPr-RING, has been proposed. Fundamental concept of the HyPr-RING is integration of water carbon reaction, water-gas shift reaction and CO2 absorbing reaction in a single reactor. Firstly, thermodynamic analysis was done to judge the possibility to realize the process. It was found that high pressure and temperature condition, such as 20 MPa and 1000 K, is required to promote this integrated reaction. Next, experimental verification of the new process was done under the high pressure and temperature reaction conditions. As the results, integration of above three reactions in a single reactor can be done successfully and produced a large amount of hydrogen as estimated by thermodynamic analysis. Experiments showed that organic materials including coal, heavy oil, biomass, plastics can be used in this process. In the gaseous phase, no pollutants such asH2S, SO2, COS are detected so that gas cleanup system is not required for power generation when this process is used. Finally, a process design was made to estimate process efficiency. Theoretically, 1 mole of carbon can generate 2 moles of hydrogen and cold gas efficiency of this process estimated as more than 80 per cent. The process potentially reduces hydrogen production cost compared with the conventional hydrogen production methods. Keywords: Hydrogen, Fossil fuel, Energy, Process, Supercritical water

Jan 1, 2001