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By Riki Kobayashi, D. L. Katz

The conditions at which methane and water form solid hydrates have been extended from 4,000 to 11,200 pounds per sq. in. The curve at high pressure had been in doubt because of Villard's report of a critical decomposition temperature. The paper explains the nature of the hydrate curve at high pressure and its dependence on fluid phase behavior. Extropolation of the methane hydrate curve indicates a pressure of 40,000 pounds per sq. in. will cause hydrates to form at a temperature of 100" F. INTRODUCTION The conditions under which natural gases form hydrates when liquid water is present have been studied by several investigators up to pressures of about 4,000 pounds per sq. in. The early work by Villard on hydrates of methane and ethylene13, ethane'', and propane14 included references to critical decomposition temperatures of the hydrates. Villard's work raised the question as to whether the pressure-temperature curve for methane-water hydrate continued above a temperature of 70.7°F. or whether this was the maximum temperature at which hydrates would form. This paper extends the experimental data on methane hydrate to 11,200 pounds per sq. in. A discussion of phase relations in the hydrate region for the hydrocarbons and of the methane-water system at high pressures is included. PREVIOUS WORK Villard suspected that methane hydrates could not be formed at temperatures above 21.5°C. (70.7°F.)la irrespective of the pressure of the liquid-vapor system. However, he was limited in his studies by his apparatus in 1888 to pressures not greater than 300 atmospheres (4,410 pounds per sq. in.) so that there has remained some doubt as to the existence of such a maximum temperature in this region. For the case of ethylene hydrates, however, Villard does specifically state the occurrence of what he terms a "critical temperature for the decomposition of the hydrates"13. Fig. lB shows a pressure-temperature projection of the three-phase locus, hydrate-ethylene rich liquid-vapor (H-L2-V) terminating at the critical locus in which L² and V assume similar properties. Throughout this paper the following phase designations will be used: H for hydrate, Ll for the water rich liquid. L2 for the

Jan 1, 1949

By Riki Kobayashi, D. L. Katz

The conditions at which methane and water form solid hydrates have been extended from 4,000 to 11,200 pounds per sq. in. The curve at high pressure had been in doubt because of Villard's report of a critical decomposition temperature. The paper explains the nature of the hydrate curve at high pressure and its dependence on fluid phase behavior. Extropolation of the methane hydrate curve indicates a pressure of 40,000 pounds per sq. in. will cause hydrates to form at a temperature of 100" F. INTRODUCTION The conditions under which natural gases form hydrates when liquid water is present have been studied by several investigators up to pressures of about 4,000 pounds per sq. in. The early work by Villard on hydrates of methane and ethylene13, ethane'', and propane14 included references to critical decomposition temperatures of the hydrates. Villard's work raised the question as to whether the pressure-temperature curve for methane-water hydrate continued above a temperature of 70.7°F. or whether this was the maximum temperature at which hydrates would form. This paper extends the experimental data on methane hydrate to 11,200 pounds per sq. in. A discussion of phase relations in the hydrate region for the hydrocarbons and of the methane-water system at high pressures is included. PREVIOUS WORK Villard suspected that methane hydrates could not be formed at temperatures above 21.5°C. (70.7°F.)la irrespective of the pressure of the liquid-vapor system. However, he was limited in his studies by his apparatus in 1888 to pressures not greater than 300 atmospheres (4,410 pounds per sq. in.) so that there has remained some doubt as to the existence of such a maximum temperature in this region. For the case of ethylene hydrates, however, Villard does specifically state the occurrence of what he terms a "critical temperature for the decomposition of the hydrates"13. Fig. lB shows a pressure-temperature projection of the three-phase locus, hydrate-ethylene rich liquid-vapor (H-L2-V) terminating at the critical locus in which L² and V assume similar properties. Throughout this paper the following phase designations will be used: H for hydrate, Ll for the water rich liquid. L2 for the

Jan 1, 1949

By Ademar Lopes, Victor Silva, Heitor Silva, Gustavo Usero, Roberto Rolo, Lucas Pereira, Gabriel Moreira, João Lague, Arthur Endlein, Matheus Feitosa

Grade control models are supposed to provide a higher resolution than long-term or interim models. However, available grids from diamond or reverse circulation drilling do not provide that required resolution. In this study, a geostatistical workflow is proposed to integrate available grade data from production blastholes with its operational parameters taken when drilling downhole. The step of geological logging can be replaced by machine learning models for classifying blastholes into lithologies and hardness classes. Next, indicator and ordinary kriging use the classified blastholes and previous data for estimating the model domains and the grades within each one. The workflow is applied in a world class iron ore mine in Brazil.

Jun 25, 2023

By J. Andres, M. Cross

"Freeport-McMoRan’s Sierrita operations has two natural gas-fired molybdenum roasters for converting molybdenum disulfide into molybdenum trioxide. When these roasters were compared to other similar units within the company during a benchmarking exercise, it showed that increased throughput from the roaster units at Sierrita was possible. A team of site metallurgists, technical experts from other sites, and engineers from the Climax Technology Center was formed to study the potential in more detail. The team investigated many parameters in the roaster, including temperature profiles, roaster chemistry profiles, rabble and drop hole patterns, and operational strategies. The results of these studies and the associated throughput improvements are described in this paper. INTRODUCTION Molybdenum, a vital component for the steel industry, is typically found in nature as molybdenum disulfide (MoS2). MoS2 is typically recovered via flotation processes and is purified through leaching processes. While molybdenum disulfide is a commercial product, it is not the form of molybdenum that the steel industry requires. They require molybdenum in the form of molybdenum trioxide, MoO3. There are multiple ways to refine molybdenum disulfide into molybdenum trioxide. The primary method is the oxidation of molybdenum disulfide in a multiple hearth roaster. The chemistry of converting molybdenum disulfide to molybdenum trioxide is very favorable at increased temperatures, oxidizing the molybdenum through a range of exothermic reactions to ultimately produce MoO3. The chemical reactions that occur in molydenum roasting occur in three zones. These three zones correspond with four different reactions."

Jan 1, 2015

By F Owusu-Mensah, F Nsarko

The Obuasi Mine has been in operation for the past 100 years. Within this period a host of mining methods have been employed during its various changing phases. The causes for the changes are multiple, ranging from orebody capability, dynamics, technology, safety, economics, production levels, geotechnical, etc. Mining methods applied have also ranged from timber square setts, conventional cut-and-fill, shrinkage stoping, sublevel caving, mechanised cut-and-fill, longitudinal and transverse open stoping, and lately longitudinal retreat mining method (LRMM).The Obuasi Mine has a world class underground resource potential of about 27 million ounces. A third of this is in reserve. The orebody is subvertical, with multiple lodes and with widths ranging from 1.5 - 40 m. It stretches along 8.5 km N/S strike. A cursory statistical analysis on the various resource ore widths show a higher percentage (60 per cent) of the resource being within the range of about 1.5 - 10 m. Thus a high proportion of the resource is amenable to narrow vein mining methods. This has enhanced the choice of LRMM as an alternative method. Also, with the increasing cost of mining over time, LRMM, which eliminates expensive and time consuming footwall drives, will become far more advantageous as compared to the transverse/longitudinal open stoping methods which currently constitute about 40 per cent of the total underground production.The LRMM currently delivers about 20 per cent of the Obuasi Mine production. Plans are underway to improve total underground production from the current average of 160 000 tpm to about >180 000 tpm in the next few years and about 20 - 40 per cent more in the foreseeable future. Recoverable ounces will also increase from 26 000 to about 34 000 ounces per month. The proportion of LRMM in the business plan is also expected to increase from the current modest level to about 50 per cent. Despite its tremendous advantages in terms of economics and productivity, the method is facing some challenges during its inception. The objective of this paper is to highlight some of the emerging challenges and their effect on production and offer possible remedies that could mitigate the current and possible future challenges.CITATION:Nsarko, F and Owusu-Mensah, F, 2012. The Obuasi mine - longitudinal retreat mining method application and challenges, in Proceedings Narrow Vein Mining 2012 , pp 59-70 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By Youze Xu

The effect of oxalic acid, acetic acid, citric acid and EDTA on extraction of Cr (?) in soils contaminated by chromium- containing slag was investigated using a batch of incubation experiment. The results show that the pH value decreases more obvious with the increase of the amount of organic acid. The amount of Cr (?) extracted increases with increasing the amount of organic acid. When the ratio of organic acids to total Cr was 5:1, citric acid revealed the highest extraction effectiveness, followed by EDTA, oxalic acid and acetic acid, respectively. The amounts of Cr(?) extracted by citric acid, EDTA, oxalic acid and acetic acid increased by 439%, 244%, 215% and 162%.

Jan 1, 2009

Supercritical fluids are gases compressed to near liquid densities and, as such, have unique properties compared to liquids: low viscosity; zero latent heat; high diffusivity and pressure-dependent, solvation characteristics. These properties are being utilised in new processes and current research is delineating areas where such processes may be applicable to extractive metallurgy. The processes and areas of interest are as follows: Supercritical Fluid Extraction in which substrates are dissolved at high pressure and fractionated at successively lower pressures. Areas of interest include extraction of organic materials for regeneration of activated carbon for the CIP process and for upgrading alumina industry products and, separation of transition metal chlorides. ò Supercritical Water Oxidation in which high pressure gaseous water acts as a medium in which substrates are oxidised while suspended or dissolved. This process may be of use for oxidation of organics in Bayer liquor and oxidation of mine waters etc. ò Supercritical Fluid Reactions where reactions occur in a supercritical fluid medium, particularly when the medium itself is a reactant. This may be of use in treating refractory or carbon-aqueous auriferous ores and in lower-temperature chlorination of transition metal oxides. Research is described which is aimed at chlorination and separation of transition metal oxides by two supercritical operations.

Jan 1, 1991

By Henk van Muijen

From an interesting and intriguing scientific research topic, deep sea mining has altered into an interesting mining prospect over the last years. Ten years ago most of the focus was on geological investigations, searching for typical deep sea deposits and getting answers on where we can find them and how these deposits were formed. At this moment we know much more about the interesting deposit possibilities and with our quest for minerals, metals and other materials to feed global economic growth, answers as to the technical and economic feasibility to mine these deposits are sought. This is not a new phenomenon as we already witnessed such question late 1970?s and early 1980?s. Most of the focus was on mining manganese nodules and brines in the Red Sea driven by the report of the Club of Rome that predicted shortages in near future at that time. Development went different, but later in the 1990?s a rival of interest could be noticed for mining deep sea deposits.

Jan 1, 2010

By M. L. Haider

Introduction I Appreciate very much the opportunity of discussing with you tonight oil developments in western Canada. These developments are of importance to all of us, first because of their great economic significance to all of Canada, and second because of the location of the new oilfields. Situated as they are in the west and northwest, they are of considerable strategic value from the standpoint of continental defence. The story of oil development in Canada covers a span of almost a century, during which time success in finding reserves of petroleum was barely sufficient to maintain interest in continuing the search. Finally, in 1947, a well of the first importance was completed in Alberta and, judging by discoveries made since then, it appears that Canada, at long last, is to become an important producer of petroleum.

Jan 1, 1950

By A. R. Farkoosh

Al-Si based alloys have been recently used by automotive industry for highly stressed engine applications. Due to severe working conditions of the engine parts, existing alloys hardly endure high pressures at high temperatures. This necessitates alloy modifications to enhance the elevated temperature performance. In this study, the effects of trace nickel additions on the microstructural and mechanical properties of A356+0.5Cu alloy have been investigated at different aging conditions. Electron probe microanalysis (EPMA), scanning electron microscopy (SEM) and X-ray diffraction (XRD) are used to study the microstructural changes. Aging curves have been obtained by hardness measurement. It was seen that the presence of additional nickel introduced many complex intermetallic phases within the microstructure which led to improved high temperature mechanical and aging response.

Jan 1, 2011

The current boom being experienced by mining, coupled with a shortage of professionals, will mean those in the industry will have many choices. It may be easy to become carried away and run with the highest bid or the biggest promise. Without planning, however, the ærightÆ opportunity may be missed and there may be some long-term consequences. There are many choices of paths in the industry to suit work preferences, life cycles and to achieve a balanced life. People in mining have changed jobs and companies frequently û which means new leaders need to take greater responsibility in charting their own direction. Career options need to be carefully assessed and aligned to personal values and preferences. Emphasis is given on gaining site experience early on.This paper examines strategies for career planning, which incorporate life cycles, education and what is meant by a balanced lifestyle. Two tools are identified as being helpful in ensuring strategies can be successfully executed. They are ævisioningÆ and æinfluenceÆ.To make the mining industry more attractive, we need more creative solutions around advances in technology and organisation of work. It also needs the input and leadership of new entrants in to the industry to assist in its survival. New leaders are encouraged to voice a vision and effectively influence their companies. New leaders have little authority and need to learn how to effectively influence. We as a mining industry need to listen, be open-minded and give it a go.

Jan 1, 2004

By Alvin Kaufman

Geothermal plants are competitive with conventional units. A geothermal plant can produce electric energy for 6.70 mills per kwhr, compared with 6.96 mills for coal, 6.74 mills for oil, and 7.04 mills for gas. These costs include fixed and variable charges. Potential for geothermal power exists in the Western United States, Alaska, and possibly Hawaii. Assuming that the current downward trend in cost per kilowatt of coal will cease and that the relative cost of gas and oil, already trending upward, may rise considerably more, geothermal energy will be utilized where available, in producing electric energy. It will be used in California first because it is directly competitive with gas-and oil-fired installations there. A long-term appraisal is difficult because little is known about the sources of geothermal power and the electric generating capacity which the steam fields will support. However, a market for geothermal steam-generated electricity exists within the Western States.

Jan 1, 1964

By Alvin Kaufman

Geothermal plants are competitive with conventional units. A geothermal plant can produce electric energy for 6.70 mills per kwhr, compared with 6.96 mills for coal, 6.74 mills for oil, and 7.04 mills for gas. These costs include fixed and variable charges. Potential for geothermal power exists in the Western United States, Alaska, and possibly Hawaii. Assuming that the current downward trend in cost per kilowatt of coal will cease and that the relative cost of gas and oil, already trending upward, may rise considerably more, geothermal energy will be utilized where available, in producing electric energy. It will be used in California first because it is directly competitive with gas-and oil-fired installations there. A long-term appraisal is difficult because little is known about the sources of geothermal power and the electric generating capacity which the steam fields will support. However, a market for geothermal steam-generated electricity exists within the Western States.

Jan 1, 1964

By Christoph Aichinger

A smart combination – Primetals Technologies developed the Circular Pelletizing Technology (CPT), which is a combination of the well-proven travelling-grate pelletizing technology with the design of a circular dip rail cooler of modern sinter plants. The overall space requirement and the installed weight for a CPT plant is significantly less compared to conventional technologies and by that CPT is a very attractive alternative for new projects.

Aug 16, 2017

By Sandvik

Fine grinding in an air-swept ball mill working in closed circuit with a forced vortex air classifier has been investigated first in continuous laboratory and then in industrial scale. Results from the laboratory circuit have shown significant influence of mill load (powder filling) on the capacity of the circuit. In laboratory scale the mill load was measured and controlled by a weighing platform placed under the complete mill set-up. The mill load of the industrial air-swept ball mill has till now been controlled by measuring the power consumption of the mill motor. Thus, it was necessary to operate far from the range of optimal mill filling. To improve the circuit performance, alternative ways of mill load measurement were investigated. An important factor was investment cost, as many fine grinding mills operate in relatively small circuits that do not wan-ant large investment. In this case the task was accomplished by using a piezoelectric strain transducer, which detected strain changes in the mill shell. It was installed in the midpoint of the shell, where the highest deformation was obtained. As the transducer was on the top position, it indicated compression, and on the bottom position it measured tension. By taking the difference between the readings, it was possible to calculate total strain variations, directly proportional to the mill load. The signal from the transducer was sent to a control room via a cordless infrared communication system, employing a microprocessor control card, which could further regulate other operating parameters of the circuit according to the software model. The installation required very low investment cost and provided simplicity of application as well as stability and reliability of characteristics under severe industrial condition. The measurement system made it possible to optimise the mill load and thus increase the production from 3.2 to 3.7 dh (15 per cent), and stabilise the circuit operation.

Jan 1, 1995

By Camilo Quintero, Frank Cesario, John Kinnear, Brian Boye

In this paper, an innovative approach was adopted to automatically calculate the effects of tunnel induced settlement on buildings and utilities. The approach resulted in increased output quality, consistency, reduced time, cost savings and a greater ability to respond quickly to design changes. The techniques described have been applied to the Fairbank Silverthorn Storm Trunk Sewer System project, located within the City of Toronto. The automation allowed a very large area of topography, tunnels (6 km), buildings (9000) and utilities (over 1000) to be rapidly evaluated. Visualization of the settlements and impacts also allowed the project design team to optimize the system design to mitigate the settlement impacts.

Jun 13, 2021

By A. R. Calawa, T. C. Harman, M. Finn, P. Youtz

A study has been made of the growing, annealing, and diffusion parameters in PbSe, Pb1-ySnySe, and Pb1-xSnxTe. Single crystals of these materials have been grown using the Bridgman technique. For all of the above materials the as-grown crystals are p type with high carrier densities. To reduce the carrier concentration and increase the carrier mobility, the samples are annealed either isothermally or by a two-zone method. From isothermal anneals, the liquidus-solidus boundary on the metal-rich side of the stoichiometric composition has been obtained for some alloys of Pb1-xSnxTe and on both the metal- and seleniunz-rich sides for PbSe and alloys of Pbl-ySnySe. In Pbo.935 Sno.065 Se carrier concentrations as low as 5 x1016 Cm-3 and mobilities as high as 44,000 sq cm v-1 sec-1 at 77°K have been obtained. Inter diffusion parameters mere also studied. The ddiffusion experiments mere identical to the isothermal or two-zone annealing experiments except that the samples were removed prior to complete equilibration. The resulting p-n junction depths were determined by sectioning and thermal probing. Inter diffusion coefficients for various temperatures were calculated for both PbSe and Pb0.93Sn0.0,Se. RECENTLY, there has been considerable interest in the PbTe-SnTe and PbSe-SnSe alloys with the rock salt crystal structure. The unusual feature of these systems is the variation of energy gap EG with composition. Several investigations1-3 have shown that EG for the lead chalcogenides decreases as the tin content increases, goes through zero, and then increases again with further increase in tin content. The possibility of obtaining an arbitrary energy gap by selecting the composition is an especially attractive feature of these alloys for applications involving long-wavelength infrared detectors and lasers. In addition, some unusual magneto-optical, galvanomagnetic, and thermomag-netic effects should occur for alloys with low band gaps. If uncompensated low carrier density crystals can be obtained, then a small carrier effective mass, a large dielectric constant, and the resultant high carrier mobility should yield enormous effects at low temperature in a magnetic field. The relative variation of the energy gap with pressure should also be very large for these low gap materials. The primary purpose of this paper is to provide some information concerning the preparation of low carrier concentra- tion, high carrier mobility, and homogeneous single crystals with a predetermined alloy composition. I) DETERMINATION OF ALLOY COMPOSITIONS In all of the work described in this paper, the composition of lead and tin chalcogenides in the alloys was determined by electron microprobe analysis. Separate X-ray spectrometers are used to make simultaneous intensity measurements of the Pb La1 and Sn La1 lines emitted by the sample under excitation by a beam of 25 kev electrons focused to a spot about 2 µm in diam. These intensities are compared to the intensities of the same lines emitted by standards under the same conditions. The standards used are the terminal compounds of each pseudobinary system, i.e., PbTe and SnTe for Pbl-xSnxTe alloys, PbSe and SnSe for Pbl-ySnySe alloys. The composition of the sample is then obtained from theoretical calibration curves which relate the weight fractions of lead and tin in the alloy to the measured ratios of X-ray intensities for the sample and the standards. The lead and tin calibration curves for each alloy system were calculated by using corrections for backscattered electrons,4 ionization,5 and absorption,6 and assuming that the atom fraction of tellurium or selenium in the sample and standards is exactly +. Results obtained by using the microprobe are in good agreement with those obtained by wet chemical analysis. II) CRYSTAL GROWTH FROM THE VAPOR Early work on the vapor growth of PbSe was carried out by Prior.7 He used small chips of Bridgman-grown single crystals as the source material and frequently converted the whole charge of a few grams into one crystal. In the present work, vapor growth occurred using a metal-rich or chalcogenide-rich two-phased alloy powder as the source material. Small, nearly stoichiometric crystals are formed on the walls of the quartz tube. The procedure will now be described in detail. Initially, a 100-g charge containing (metal)o.51(chalco-genide)o 49 proportions or (metal)o.49(chalcogenide)o. 51 proportions of the as-received elements in chunk form are placed in a fused silica ampoule. After the ampoule is loaded, it is evacuated with a diffusion pump and sealed. The sealed ampoule is placed in the center of a vertical resistance furnace. The region containing the ampoule is heated to about 50°C above the liquidus temper-ature for the particular composition used. After about one-half hour at temperature, the elements are reacted and the molten material homogenized. The ampoule is quenched in water. The quenched ingot is crushed to a coarse powder for vapor growth experiments and to a fine powder for the isothermal annealing experiments which are discussed in a later section. Vapor growth experiments were carried out using the powdered, metal-rich or chalcogenide-rich alloys

Jan 1, 1969

By R Blin, R Walde, R Belli, D Inaudi

A fiber optic distributed sensing system allows the monitoring of parameters useful to determine the short- and long-term behaviour of the structure in response to the external actions, including, eg seismic activities as well as long-term phenomena such as seepage, tunneling, sinkholes, and other geo-structural movements. Monitoring of large retaining structures with such a system provides direct strain/deformation and temperature measurements on the broad interior area with an arrangement of several sensing cable lines, enabling early detection, localisation and sizing of subsurface damages. Measurements are provided every meter along the entire sensing cable, this is particularly important in such cases where the location of defects and damages cannot be predicted. Fiber optic distributed sensing cables are generally available for retrofit installation inside the dam structure using trenches on the downstream face or laid during construction below the geomembrane liner within the bedding sand layer. Mapping the cable route enables exact correlation between a linear coordinate on the cable length and a position in the dam. Cable installation is envisaged to be carried out during further raising of the embankment; additional cable sections are plugged to the previously installed cables and measured with the existing measurement system, requiring only an update of the mapping. The measurement system is placed remotely from the sensing area since a section of sensing cable can be used to link to the sensing area at the storage facility several kilometers away. The system is available for on-line, 24/7 real-time operational data management. Such fiber optic distributed sensing systems allow storage facilities to be monitored with long, accurate, continuous and precise data for geotechnical diagnostic purposes. This contribution will introduce the principles, benefits, and limitations of this technology.

Jul 1, 2021

By Nn Li

Energy consumption in commercial buildings has been increasing rapidly in the past decade. The knowledge of future energy consumption can bring significant value to commercial building energy management. For example, prediction of energy consumption decomposition helps analyze the energy consumption patterns and efficiencies as well as waste, and identify the prime targets for energy conservation. Moreover, prediction of temporal energy consumption enables building managers to plan out the energy usage over time, shift energy usage to off-peak periods, and make more effective energy purchase plans. This paper proposes a novel model for predicting heating, ventilation and air conditioning (HVAC) energy consumption in commercial buildings. The model simulates energy behaviors of HVAC systems in commercial buildings, and interacts with a multiagent systems (MAS) based framework for energy consumption prediction. Prediction is done on a daily, weekly and monthly basis. Ground truth energy consumption data is collected from a test bed office building over 267 consecutive days, and is compared to predicted energy consumption for the same period. Results show that the prediction can match 92.6 to 98.2% of total HVAC energy consumption with coefficient of variation of the root mean square error (CV-RMSE) values of 7.8 to 22.2%. Ventilation energy consumption can be predicted at high accuracies (over 99%) and low variations (CV-RMSE values of 3.1 to 16.3%), while cooling energy consumption accounts for majority of inaccuracies and variations in total energy consumption prediction.

Aug 1, 2013

By Lía Martínez, James J. LoCoco

Borehole geophysical logging has developed and improved many measurements for mining exploration in the past decade. Imaging tools such as the acoustic and optical televiewer are now being used to collect real time, high resolution, oriented fracture and bedding data. Drill holes 100’s of meters deep can be processed very quickly using automated structure picking software and borehole core samples can be digitally logged instead of using paper and pencil.

May 1, 2008