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By D. B. Johnson

Acidic, metal-rich waters generated at working metal mines and abandoned mine sites are generally considered to be major pollutants of the environment. However, the metals they contain often have significant value of their own, or as sources of useful mineral products. We have developed novel bioreactor systems that facilitate the selective recovery of various transition metals (e.g. copper, zinc and iron) as defined minerals that can be recovered and recycled. The bioreactors use novel species of acidophilic bacteria. Ferrous iron is oxidised by Ferrovum myxofaciens, a specialist bacterium that forms large amounts of exopolymers and grows as filamentous streamers in flowing mine waters, and the ferric iron generated is precipitated as the mineral schwertmannite, a small proportion of which is used to remove any arsenic present in mine water. Copper and zinc are precipitated as sulphides using H2S generated by consortia of acidophilic and acid-tolerant sulphate-reducing bacteria in a continuous flow, on-line low pH bioreactor. Transition metal sulfides can be segregated by precipitating them, either on-line or off-line, at different pH values. The modular units that have been developed can be configured to treat mine waters of different chemistries. A hypothetical acidic (pH 2.5) mine water stream containing 500 mg/L iron, 100 mg/L of copper and zinc, 50 mg/L of aluminum and manganese, 2 mg/L of arsenate, and discharged at a rate of 10 L/s, is used as an example of the potential application of the mineral-generating bioreactors. The environmental benefits and economic implications of considering mine waters as resources rather than wastes are discussed.

Aug 1, 2013

Teamwork: The famous first sentence of an essay en- titled Aphorisms, by Hippocrates, is as follows: "Life is short, the Art long, opportunity fleeting, experience treacherous, judgment difficult." The future of science does not depend so much on the number of scientists or the number of colleges, but rather on the individual qualities and the degree of perfection of a limited group of leading scientists and colleges. These are individual factors which require inherent talent which in turn is a condition evolved after generations of culture. Thus, very elaborate higher education for indiscriminate masses of humanity or students may not necessarily show the expected results. In other words, it is possible that higher specialized education should be given only to the few talented individuals, and their capacity and worth should be judged by as highly qualified and talented teachers. Quality is the greatest of all competitive aids. An essential qualification that must be possessed by a quality mineral industries college is a high caliber teaching staff, for the mineral sciences will advance in the coming years only if the leading minds of today are made avail- able as the mental springboards for our scientists of tomorrow. Mineral industries schools are finding it increasingly difficult to maintain a high caliber staff of instructors and administrators in competition with private business and governmental demands for similar

Jan 1, 1950

By Ronald P. Hollenbeck

The value of mineral production in Alabama increased 1 percent above the record high set in 1965. Alabama ranked second among the States in the production of bauxite, third in the production of masonry cement, native asphalt, and scrap mica, sixth in the production of portland cement, ninth in the production of iron ore, and tenth in the production of lime. The mineral industry of Alabama was dominated by the mining and processing of coal and stone, the manufacturing of cement, and the production of crude petroleum. These industries accounted for 87 percent of the State's total value of mineral production, compared with 85 percent in 1965.

Jan 1, 1967

By Perry N. Halstead

This report describes two goniometers that, by simple manipulation, can be used to ascertain the attitude of a joint, vein, or fracture plane observed on the planar projection of a borehole photograph taken with an NX borehole camera of the type developed by the U.S. Army Corps of Engineers. One goniometer was designed to interpret photographs taken in vertical drill holes and the other for photographs taken in inclined drill holes. In practice, several measurements are made on each photograph with the goniometer. These data are then substituted into mathematical equations, which are derived in this report and the attitudes of fracture planes are determined.

Jan 1, 1968

By C. Andrews

Fuel cell testing requires fully automated operation, on-site configuration of tests, and real-time monitoring for performance and failures. Balancing the flexibility and programmability of a test station with reliability, cost, and user interface can be a daunting challenge to the test equipment engineer. Endurance testing of fuel cells requires the highest level of reliability for test stand hardware and software without compromising automation capabilities or users interface. Techniques for implementing an ultra-reliable test platform addressing hardware limitations, sophisticated watchdog monitoring to prevent inadvertent shutdowns, and software limitations (e.g., balancing a highly-functional graphical users interface with reliability) are presented.

Jan 1, 2005

By W. M. Scheding

"There has recently been a resurgence of interest in unit flotation of mill discharges. At the Kidd Creek concentrator, this technique has been successfully applied to silver flotation in a 3050 mtpd silver-copper-lead-zinc division. The major incentive has been improved silver payment through increased overall recovery and better distribution between the sequential copper, lead and zinc concentrates. A large, but variable fraction of the silver in the ore is present as native silver and, being dense and malleable, is susceptible to overgrinding. Grinding circuit surveys showed high concentrations of silver in both primary and secondary circulating loads. Laboratory testwork confirmed that this was selectively flotable, identified the secondary ball mill discharge as the best feed stream and optimized flotation conditions. A 10 t/h pilot plant campaign confirmed that the rate of accumulation of silver was sufficient to sustain continuous production of a silver concentrate and that flotation of the whole stream was not necessary.The present 30 t/h production circuit recovers from 5 to 50% of the silver in the ore at a concentration ratio between 25 and 250. The circuit also contributes to a better understanding of ore mineralogy, as an 'on-line' indicator of elemental silver content."

Jan 1, 1985

By Falbo A, Quarestima S, Cozza C, Barbaro M

A new synthetic reagent of the mercaptobenzoxazole class, 5- methyl-2-mercaptobenzoxazole, has been studied. This reagent exhibits powerful selective collecting action towards copper sulphides present in several complex ores, as demonstrated both by laboratory and pilot plant tests. Industrial production is expected to start in the near future. The way this reagent reacts with pure chalcocite has been studied utilising in situ FTIR techniques, adsorption tests, electrokinetic potential measurements and Hallimond cell flotation tests. The FTIR studies have indicated the nature of the surface phase. Adsorption isotherms obtained by the rest method have revealed the quantitative evolution of surface products, permitting the determination of surface coverage at various reagent concentrations. The electrokinetic potential has been utilised to verify the stability of individual species in diverse concentration ranges. Correlation of the results obtained has provided indications on the chemical interaction of this reagent with the surface and on the surface Arrangement.

Jan 1, 1993

By M. J. Nicol

The kinetics of the dissolution of colloidal silver in aerated cyanide solutions has been investigated with the aim of developing a relatively rapid and convenient method for monitoring the ?leaching power? of solutions typically used in the cyanidation process. Experimental results obtained are consistent with an electro-chemical model, in which the mixed potential is set up in the active region of the polarization curve for the anodic dissolution of silver, giving rise to a rate of dissolution which is controlled by the rate of mass transport of either cyanide or oxygen to the surface of the silver. The rate of dissolution of colloidal silver was found to respond to variations in the reactant concentrations in a similar manner to gold (and silver) in a typical free-milling ore. The use of this technique for the monitoring and control of the cyanide leach process is discussed.

Jan 1, 1998

Avoid accidents that can occur when applying belt dressing from an aerosol can, particularly when can pressure has dropped or when spraying against wind. Approach Use a garde-type sprayer. How It Works Commercially available garden-type sprayers can be used for applying conveyor belt dressing from 12 feet away, or more. Pressure is easily raised and maintained at about 50 psi. Most sprayers have a hand pump, but a battery-powered cordless model is also available. Garden-type sprayers are available in various sizes from 11/2 to 18 gallons, with the larger models wheel mounted. The 3-gallon model evaluated by the Bureau has a shoulder carrying strap, which gives additional safety advantages. Use of the strap frees both hands for climbing ladders or holding onto catwalk rails. When spraying, one hand can remain on a handhold to lessen the chances of touching a moving belt.

Jan 1, 1980

By W. M. Weigel

The rapid advance, during recent years, in the manufacture of articles that have been in common use for generations and the development of new materials entering into appliances and devices unheard of fifty years ago have created a demand for some of the more common non-metallic minerals. To supply this demand there has quietly developed a branch of the mining industry of which little is known by most mining engineers —the mineral-filler industry. In this paper, and generally in the trade, the term mineral filler is applied to a mineral used in its natural state after mechanical preparation only (such as grinding, milling and washing), without undergoing any chemical change and without exerting any chemical action on the substance with which it is incorporated. The consumption of mineral fillers is confined chiefly to large manufacturing centers in the Eastern and Northern Statcs. Where available, materials originating near the place of consumption are used, as most fillers bring a comparatively low price and, frequently, the freight may equal the cost of the finished filler at the mine. The Southern States have abundant deposits of non-metallic minerals suitable for fillers, which supply the manufacturing industries in adjacent states. Many of these deposits are equal to, or superior, in quality to those mined in the North, but they can not compete with them because of the freight rates. The mineral-filler industry has felt the present depression, but it has suffered less than most mining industries, for as a rule the mills are simple, the overhead expenses are low, and the labor is entirely local and can revert to farm work when the plant closes down. Many other deposits in the southern district will undoubtedly be developed when business revives and freight rates are adjusted. Most of the non-metallic mines are small and the tonnage handled is low in comparison with the tonnage involved in modern large-scale mining of coal, iron, copper, etc. On the other hand, at nearly all non-metallic

Jan 1, 1923

By W. M. Weigel

The rapid advance, during recent years, in the manufacture of articles that have been in common use for generations and the development of new materials entering into appliances and devices unheard of fifty years ago have created a demand for some of the more common non-metallic minerals. To supply this demand there has quietly developed a branch of the mining industry of which little is known by most mining engineers —the mineral-filler industry. In this paper, and generally in the trade, the term mineral filler is applied to a mineral used in its natural state after mechanical preparation only (such as grinding, milling and washing), without undergoing any chemical change and without exerting any chemical action on the substance with which it is incorporated. The consumption of mineral fillers is confined chiefly to large manufacturing centers in the Eastern and Northern Statcs. Where available, materials originating near the place of consumption are used, as most fillers bring a comparatively low price and, frequently, the freight may equal the cost of the finished filler at the mine. The Southern States have abundant deposits of non-metallic minerals suitable for fillers, which supply the manufacturing industries in adjacent states. Many of these deposits are equal to, or superior, in quality to those mined in the North, but they can not compete with them because of the freight rates. The mineral-filler industry has felt the present depression, but it has suffered less than most mining industries, for as a rule the mills are simple, the overhead expenses are low, and the labor is entirely local and can revert to farm work when the plant closes down. Many other deposits in the southern district will undoubtedly be developed when business revives and freight rates are adjusted. Most of the non-metallic mines are small and the tonnage handled is low in comparison with the tonnage involved in modern large-scale mining of coal, iron, copper, etc. On the other hand, at nearly all non-metallic

Jan 1, 1923

By T. E. Davidson, C. G. Homan

This report deals with a study of the effects of extreme hydrostatic pressure on a polycrystalline material which exhibits a high degree of elastic anisotropy. Metallographically prepared polycrystalline bismuth samples were subjected to pressure levels up to 20,000 atm in a piston type gas-liquid system. The observed structural changes consisted of deformation localized along the grain boundaries, which appears to be a boundary migration phenomena, and widespread slip and cross slip. Subsequent deformation is progressive with increased pressure, and is substantially different in type from the deformation characteristic of uniaxial compression. A large amount of interest has been shown in recent years in the effects of extreme pressure on metals. In this connection, many investigations into the effects of pressure on physical and mechanical properties and reactions have been undertaken. Due primarily to the experimental difficulties involved, there has not been a great deal of study of the structural changes resulting from exposure of metals to extreme pressure. It has been difficult, for instance, to produce a true hydrostatic stress state in many of the extreme pressure devices used, and also to directly examine specimens metallographically before and after pressurization. The results of a preliminary investigation into one of the effects of extreme pressure, and its associated true hydrostatic stress state, on the structure of metals are discussed herein. Metals exhibit varied degrees of anisotropy in their physical and mechanical properties. Significant among the anisotropic properties is the modulus of elasticity, which varies by a factor of as much as three in some of the fcc metals, and by much larger factors in some of the less symmetrical elements. As a result of the variation of the modulus of elasticity with crystallographic direction, shear stresses will be induced in polycrystalline samples under true hydrostatic compression. Depending on several factors, these shear stresses could become of suffi- cient magnitude to cause localized plastic deformation. Presented herein are some of the structural changes observed in polycrystalline bismuth as a result of exposure to hydrostatic pressures of up to 20,000 atm. Although several other materials in both bicrystal and polycrystalline form are also currently under investigation, bismuth was chosen initially, due to its low symmetry and moderately high degree of anisotropy in the elastic properties. The fact that extreme hydrostatic pressure can induce structural changes in some elements in the polycrystalline state is of importance in itself. However, it may also be a factor in many of the other extreme pressure effects. For instance, this localized plastic deformation could substantially lower the recrystallization temperature, thus altering the effects of extreme pressure on this phenomenon. Also, as commented on by ridgman,' the hysteresis in the polymorphic transition of polycrystalline bismuth under extreme pressures could possibly be attributed to structural changes brought about by unequal compressibility. Therefore, to accurately determine the true effects of extreme pressure on metallic substances, one first must determine if any structural changes due to hydrostatic compression are also simultaneously occurring. The purpose of this work has been to determine whether the shear stresses induced by hydrostatic pressure in an anisotropic polycrystalline material, such as bismuth, could reach a magnitude great enough to cause plastic deformation and to study the resultant structural changes and effects. THEORY In a metallic crystal, the elastic properties are dependent upon the crystallographic direction and plane. Depending upon the degree of anisotropy of the elastic properties and other factors, internal shear stresses of sufficient magnitude to cause localized plastic deformation may be induced in polycrystalline material by true hydrostatic compression. The following highly simplified two-dimensional model of two adjacent grains in a polycrystalline aggregate under hydrostatic pressure serves to schematically demonstrate how these shear stresses arise in an anisotropic material.

Jan 1, 1963

By Alain Simard, Sylvain Lacroix, Louis-Martin Dubé, Pierre Pilote

"The Harricana-Turgeon belt (HTB) is a poorly known volcano sedimentary belt in the NW part of the Abitibi Sub-province; it includes the Matagami, Joutel, Brouillan and Casa-Berardi mining districts. The HTB is dominated by volcanic rocks, which covers 65% of its surface area, followed by sedimentary (18%) and plutonic (17%) rocks. It is also transected by numerous deformation zones located either at the contacts of volcano-sedimentary units and granitoid bodies or cross-cutting them. A preliminary geological synthesis shows that mineral deposits are associated with certain regional geologic elements.The volcano-sedimentary units are grouped here into twelve band-shaped lithotectonic domains, most of which extend for more than 150 km E-Win the HTB. Each domain is defined by lithologies and facies associations, and gradiometric and electromagnetic signatures.Eight domains are composed of basaltic or basaltic to komatiitic associations, interlayered with thin pelagic sediments, representing sub-marine lava plains. Two domains are composed of basaltic to rhyolitic associations that are interpreted as volcanic arcs formed by one or several central volcanic complexes.The sedimentary rocks are grouped into two lithotectonic domains. Each is composed of rhythmic sequences of turbiditic sandstone- siltstone-shale, Algoma-type banded iron formations and conglomerates bearing plutonic and volcanic pebbles. These three facies come partly from mass flow at the bottom of a slope in a moderately deep marine environment. In each domain, a conglomerate sandstone- siltstone sequence, containing poly genetic pebbles of local provenance, is similar to Timiskaming-type alluvial deposits.The nineteen granitoids, found within the HTB and at its border, belong to numerous petrographic suites, and have been grouped into four structural families: pre-tectonic, pre- to early-tectonic, syn- to late-tectonic, and late- to post- tectonic. The pre- to early-tectonic plutons are presumed to be sub-volcanic and are generaly associated with the volcanism of central complexes.The HTB mineral resources consist essentially of polymetallic (Cu-Zn-Ag-Au) and gold (Au-Ag) deposits. The polymetallic deposits are located exclusively in the two lithotectonic domains composed of basaltic to rhyolitic associations (Matagami-Brouillan and Joutel Raymond). All gold deposits are associated with deformation zones superimposed on lithotectonic domain contacts and highlighted by graphitic units. Most of the deposits are hosted in the Casa-Berardi and Douay deformationzones, located at the contact of the Cartwright basaltic to komatiitic domain and the Taibi sedimentary domain"

Jan 1, 1990

By L. Adler

A fairly complex analysis is required to select, or evaluate a piece of excavating and bulk handling equipment and obtain its performance. At present there is little agreement as to what specific points should be considered, and even less on what procedure to follow. This paper provides both of these in a consistent and direct form. The analysis applies to all types and sizes of equipment from the bulldozer and the continuous miner, to the B.W.E. The importance of the equipment characteristics, job activities, and work conditions are stressed and separate analytical stems are established in a flow chart for these. They are combined using suitability tests in the following steps: 1) problem statement, 2) natural conditions, 3) suitability guidelines, 4) appropriate equipment types, 5) operational activities, 6) encumbered space, 7) geometric design, 8) equipment sizing, 9) failure and limits, 10) performance and consumption, 11) public policy checks, and 12) costs and profitability. Public policy and economics while considered throughout receive emphasis towards the end. The procedure is iterative, containing distinct feedback loops. Specifying the steps and sequence provides a necessary structure which has long been overdue.

Jan 1, 1983

By C. Mueller

Automation of mining operations is pushed by cost pressure and cyclical product prices. However, until now the different types of equipment were not able to communicate electronically with each other or with central computer systems. Therefore, the International Rock Excavation Data Exchange Standard (IREDES) was launched by major players in the industry. The task of this initiative is to define a ‘common electronic language’ for easy and standardized data exchange. As in other industries, this standard is expected to have significant impact on the use of automation in general and on the markets for third party components and software. The standard’s technical architecture is open and flexible for future applications. It consists of an ‘horizontal’ structure defining ‘Application Profiles’ for different types of data sets. An additional ‘vertical’ structure (‘Equipment Profiles’) implements equipment dependent definitions for each of the applicable Application Profiles. First profiles will be available for Drill Rigs. The standard bases on the XML language thus enabling easy data exchange with commercial databases. IREDES data sets may use storage media as well as networking infrastructures for information exchange. The IREDES work is carried out by the initiative members working jointly together in the IREDES work groups. It is open for participation of all interested organizations. First prototyping applications are expected to start during 2001, the first products may be available in the following year. Key words: Mine Automation; Machine Automation; Data Exchange; Rock Excavation; Standard; Remote Control; Teleoperation; Ethernet; TCP/IP; Internet Technology; Service; Quality Assurance; Control Centre;

Sep 1, 2001

By Michael Altepeter

Big River Zinc Corporation, located in Sauget, Illinois, operates a neutral leach residue circuit. The residue produced in the circuit is sold to lead smelters for subsequent recovery of valuable metals. A research program was initiated several years ago to find a means of treating the residue at Big River Zinc to recover the valuable metals. The Ausmelt submerged lance reactor was selected as the best alternative for the first step of the process. Pilot scale tests were conducted at Ausmelt's facilities in Melbourne, Australia. Separations were excellent. 99%+ of the Zn, Pb, Cd, and Ag contained in the residue reported to the oxide fume. 99%+ of the SiO2,, Fe, Mg, and Ca in the residue reported to the slag which passed the EPA TCLP test. Subsequent leaching of the oxide fumes and purification of the leach solutions using conventional procedures produced solUtions suitable for zinc electrowinning and an upgraded lead sulfate cake for sale.

Jan 1, 1992

By Kenji Monden

A thermal solution composite is made by incorporating dense inorganic fillers with high thermal conductivity into a resin. Silica, alumina, aluminum nitride, silicon nitride, and boron nitride are used for fillers of thermal solution composite. The thermal conductivities of composites are measured and the effect of inorganic fillers’ volume fraction is analyzed. The influence of percolation on thermal conductivity is considered. When percolation by random filling is assumed, the thermal conductivity of composite materials is expressed by the predictive expression using the effective thermal conductivity of filler. The relationship between the effective thermalconductivity of filler and its mean diameter is estimated by the equation. In the case of irregular AlN filler with average particle size 45 lm, the effective thermal conductivity of filler becomes 20 Wm−1 K−1. When the volume fraction of the fillers is 0.75, the thermal conductivity of the composite has been reported to 8 Wm−1 K−1. If the thickness of the interfacial region can be lowered, an effective larger thermal conductivity of the filler appears to set in and the thermal conductivity of the composite can be largely improved. The thermal conductivity of BN can approach 600 Wm−1 K−1. The BN constitutes the matrix of composite by causing percolation without interfacial region; high thermal conductivity of 55–100 Wm−1 K−1 has been achieved.

Mar 1, 2017

By Anylmore M, Walker A, Fletcher A

Roasting of sulphide and sulph-arsenide gold ores produces unwanted emission of sulphur and arsenic oxides, and a less than complete recovery of gold. Pyrite loses sulphur and arsenopyrite loses arsenic at a useful rate at temperatures of 600¦C and above in an inert atmosphere. Sulphur and arsenic driven off can be condensed before entering the atmosphere. During the process, solid-solution gold redistributes itself on internal surfaces of the resulting iron sulphide. Two subsequent processing options may be used; direct cyanidation of the porous sulphide resulting from the anoxic pyrolysis, or a second-stage roast to oxidise the remaining iron sulphide. The first option may be viable under certain conditions of pyrolysis. The two-stage option has an environmental advantage over the traditional roast because it reduces oxide vapour emissions by 50 per cent. The second stage may provide nearly enough energy to sustain the entire process.

Jan 1, 1992

By John J. Egan

THE present list of problems relating to the physical chemistry of steelmaking has been prepared by the Committee on the Physical Chemistry of Steelmaking, from answers to a questionnaire Submitted to a number of metallurgists engaged in both industrial and educational work throughout the United States. The purpose of the project is to make available to research laboratories a list of problems, all reduced to their simplest terms, the solution of which would aid in creating a better understanding of the steelmaking process. It is not intended to restrict the problems to practical steelmaking. The list also includes the study of the properties, and their correlation, as well as the physical and chemical reactions, of all Substances that occur or that may be in any way associated with steelmaking operations, Such as metallic substances, refractories, nonmetallic inclusions, and the constituents of slags. Many of the problems can be carried out in university or other research laboratories. Others may be most successfully attacked by cooperation of the research men with the operating personnel. It is the Committee's earnest wish that this cooperation be fostered. It is requested that investigators who are working on any of the problems listed and who anticipate future publication of their results, notify the Secretary of the Committee that such investigation is in progress. Suggested additions to the present list are also requested. The Committee is undertaking to act as a clearing house for information regarding the topics in this field that are being actually studied. Interested persons are invited to correspond with the Secretary. I. Data involved in the state of equilibrium for the various systems (laboratory work, almost entirely). A. SPECIFIC HEATS, HEATS OF FORMATION, ENTROPIES AND FREE ENERGIES OF VARIOUS PURE ELEMENTS OR COMPOUNDS; ALSO CERTAIN TYPICAL SLAGS AND REFRACTORIES. I . Determination of specific heats and entropies of oxides, sulphides, nitrides, etc. over a wide temperature range. 2. Determination of free energies of oxides, sulphides, nitrides, etc. over a wide temperature range. 3. Determination of the heats of formation of the oxides, sulphides, nitrides, etc. 4. Determination of the thermodynamic properties of the more important mineralogical constituents of the basic open-hearth slags such as calcium silicates, calcium phosphates, calcium ferrites, manganese silicates, FeO and Fe2O3. 5. Determination of the specific heats of open-hearth slags, including liquid silicates, if possible.

Jan 1, 1941

By Hervé Le Bissonnais, Jean-Pierre Janin, Anne Bergère, Pierre Renier

"The most important impact on the environment of a tunnel excavation is the creation of surface settlements. Nowadays, the mechanized tunneling allows minimizing the settlements, applying a confinement pressure which counterbalances the ground de-confinement. It is thus essential to determine the correct amount of confinement pressure. In this paper, the authors present a 3D numerical study simulating the EPB-TBM excavation of a water tunnel, in the Flanders clays (north of France). Firstly, a simplified 3D simulation, based on the concept of instantaneous longitudinal settlement curve, was performed to predict the surface settlements for different values of heading confinement pressures. Secondly, the same pressures were tested by the EPB-TBM in a monitoring zone. The comparison between the prediction settlements and the measurements was very satisfactory and allowed validation of the numerical approach and the choice of the optimal confinement pressure value for a sensitive area of the project. INTRODUCTION The excavation of a tunnel can create displacements of the surrounding soil which may affect existing structures and generate unacceptable dysfunction. The development of the closed shield tunneling has permitted to reduce the volume loss generated around the excavation and consequently the surface settlements. In this case, as explained by different authors (Clough et al., 1985; Kastner et al., 1996; Mair and Taylor, 1997), the ground movements are influenced by the TBM works: the heading confinement pressure, the shield overcutting and conicity, the annular void grout injection parameters, the segment concrete lining rigidity, the consolidation of the grout. Hence, in the tunnel design, it is important to take into consideration these different processes of the excavation works to simulate correctly the tunneling process."

Jan 1, 2016