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By Trevor Saldanha, Nawshad Haque, Will Sikora

This study reported life cycle assessment (LCA) of six copper mines in Australia, Papua New Guinea and Portugal. Inventory data was sourced from published papers, sustainability reports by mining companies, independent technical reports and previous CSIRO studies. Sima Pro software and various databases were used to evaluate life cycle based environmental impacts. The impact indicators were: global warming potential (GWP), acidification potential, water footprint, ecotoxicity potential, ozone depletion potential and human toxicity potential (carcinogenic and non-carcinogenic), abiotic resource depletion potential (minerals and fossil fuels), particulate matter and ionizing radiation. Generally, open pit mines were found to have a GWP of approximately 1.0 t CO2-eq/t Cu concentrate while underground mines had approximately 1.3 to 1.8 t CO2-eq/t Cu concentrate. Environmental impacts varied between mines considerably due to several factors, most notably: ore grade, mining method, flowsheets and ore mineralogy. Energy consumption and sources were significant contributors to most impact categories.

Mar 1, 2018

By E. R. Parker, E. A. Smith

Metallurgists and engineers have always been interested in the mechanism of high-speed deformation because metals are rapidly deformed in various applica-tions and manufacturing processes. The deformation of metals by impact loads has recently engaged the attention of a number of investigators. Many of their results have not been disclosed but some of the published investigations1-8 have shown that the tensile strength, yield strength and elongation generally increase with increasing strain rate. The investigation reported herein is an attempt to determine the reason for this increase in strength and elongation. found to depend upon the strain rate. In the bars broken at high speeds, the slip bands appear to be more numerous. This might account for the higher strength as well as the greater elongation. Experimental Procedure Single crystals of copper (approximately 99.98 per cent) were made in graphite molds by the conventional method of lowering the mold out of the hot zone of a hydrogen furnace at a rate of one inch per hour. Solidification progressed from the bottom upward, forming a single crystal. The crystals were about 0.30 in. in diameter and 4 in. long. They were

Jan 1, 1944

By E. A. Smith, E. R. Parker

Metallurgists and engineers have always been interested in the mechanism of high-speed deformation because metals are rapidly deformed in various applica-tions and manufacturing processes. The deformation of metals by impact loads has recently engaged the attention of a number of investigators. Many of their results have not been disclosed but some of the published investigations1-8 have shown that the tensile strength, yield strength and elongation generally increase with increasing strain rate. The investigation reported herein is an attempt to determine the reason for this increase in strength and elongation. found to depend upon the strain rate. In the bars broken at high speeds, the slip bands appear to be more numerous. This might account for the higher strength as well as the greater elongation. Experimental Procedure Single crystals of copper (approximately 99.98 per cent) were made in graphite molds by the conventional method of lowering the mold out of the hot zone of a hydrogen furnace at a rate of one inch per hour. Solidification progressed from the bottom upward, forming a single crystal. The crystals were about 0.30 in. in diameter and 4 in. long. They were

Jan 1, 1944

By F. Ntuli, T. V. Nyangadzayi

Chromium green is an essential metal with various applications in the paints, construction, electronics, and aerospace industries. The main source of chromium green is the carbo-thermic reduction of chromite ores, however, chromite ores are being heavily depleted on a global scale, hence the need to find alternative or secondary sources for the chromium. In order to meet the global demand for chromium there is a need to implement principles of the sustainable circular economy to keep chromium within the material loop. Ferrochrome slag and stainless steel slags are secondary resources that are potential sources of chromium. In this work, recovery of chromium from ferrochrome slag was investigated. The ferrochrome slag was alkaline leached using sodium hydroxide- sodium hypochlorite solution to reduce the use of potent reagents that have a potential negative environmental impact. The leachate produced by oxidative alkaline leaching of ferrochrome slag contained hexavalent chromium, which was used to recover the extracted chromium through a two-stage process involving reduction and precipitation. Reduction of hexavalent Cr to trivalent Cr was investigated using anhydrous FeSO4 at concentrations of 5 g/L, 10 g/L, and 15 g/L. Precipitation was conducted by dosing the reduced leach solution with 1 M sodium hydroxide at dosages of 5 ml/L, 10 ml/L, and 15 ml/L. The experiments were designed using the Taguchi (L9) orthogonal array and analysed according to the ANOVA, general linear model. The optimized conditions for the reduction step were ferrous sulfate dosage of 5 g/L with a pH of 12, and for the precipitation step, 1 M sodium hydroxide at a dosage of 15 ml/L with a setting time of 90 minutes and pH of 7. Physical changes were observed during the two-step chromium recovery, with solution changing from a yellowish colour to dark green colour indicating completion of the reaction. The chromium recovery was found to be 93.3%.

Dec 11, 2024

By Robert J. Anderso

Few elements have received more attention and developed greater interest in the last ten years than titanium. The substantially pure metal has been din...ie. cult to isolate, and so far has been little employed oommercially, but the use af alloys and chemical compounds of titanium has increased markedly in recent years. The earlier attempts at preparing pure titanium resulted in various impure forme which, from their metallic appearance, were always mistaken for the metal. Hunter in 1910 isolated pure titanium by the reduction of titanium tetrachloride with sodium. This brief statement is issued by the Bureau of Mines in response to numerous inquiries which have been received concerning titanium. More complete in. formation on the metal may be had by consulting the referenpes appended. The Literature is voluminous and only the more important references are Riven. It has been drawn upon freely in preparing this report; also information was supplied by M. g. Hunter, Arthur Braid, M 1. Schmid, C. M. Johnson, N. B. Hoffman, and de Courny Browne. The pioneer investigator in titanium is A. IL Rossi.

Oct 1, 1922

By Thomas M. Barczak

The success of longwall mining can largely be traced to the development of powered roof support systems. The most significant improvement in powered support design has been the shield support, which improved kinematic stability and promoted the application of longwall mining in difficult-to- control caving conditions where chock and frame supports were inadequate. The most obvious trend in shield design has been an increase in shield size and capacity. This U.S. Bureau of Mines report examines shield design and operation practices and their consequences for the utilization of high-capacity shield support systems. An optimization goal is to minimize support loading by selecting an active shield setting force that is compatible with strata behavior and shield loading characteristics. Shield stiffness is an important design parameter that is often overlooked. A consequence of increasing shield capacity by incorporating larger diameter leg cylinders is a proportional increase in shield stiffness. Setting forces have also increased in direct proportion to the increase in shield capacity. The increased stiffness and higher setting force cause the available capacity to be consumed more quickly, severely limiting the ability of high-capacity supports to last longer and provide reserve capacity for difficult mining conditions.

Jan 1, 1992

By J. R. Bridge, D. A. Vaughan

The phase diagram of the Zr-H system over the range 0 to 65 atomic pet was determined by high temperature X-ray diffraction methods. Results show a eutectoid between a zirconium and the hydride phase. The eutectoid temperature was established at 560±10°C with a eutectoid composition of 42*3 atomic pet H. The hydride phase of the lowest hydrogen content is stable only above the eutectoid temperature, but is formed and retained in a metastable state during reaction of zirconium with hydrogen at temperatures below 560°C. One hydride phase is indicated that exists over the composition range 55 to 65 atomic pet H. RECENT increase in the industrial importance of zirconium has stimulated several investigations of the reaction of zirconium with hydrogen. Review of the literature on interpretation of absorption isotherms' ' shows that attempts were made to relate the observations to the room temperature hydride phases reported by Hagg.3 However, more recently Schwartz and Mallett' reported the existence of a new hydride phase, isomorphous with the lower hydride in the Hf-H system described by Sidhu.4 This phase was found adjacent to the metal in a diffusion gradient sample. In addition to the new phase, Schwartz and Mallett reported on only two of the five hydrides found by Hagg. Gulbransen" confirmed the existence of only three hydrides of

Jan 1, 1957

By J. Griesel, P. H. F. Bouwer, K. Bisaka

Transalloys produces 160 000 tons of SiMn per annum from five AC submerged-arc furnaces. The lime-ore melt from two AC open-arc furnaces is contacted with SiMn to produce 50 000 tons of medium carbon FeMn per annum. Metallics in the slag are reclaimed in a jigging plant, which has been in operation since 1999. The flow of materials between the jigging plant and furnaces has been optimised. The amount of recycle slag in the feed of the SiMn furnaces has been decreased by more than 30% which still provides satisfactory stability of the furnace operation. The jigging plant has absorbed all the additional slag generated, to recover SiMn metal. A review of the raw materials used and operating parameters for SiMn production was also undertaken. Slag to metal ratios were decreased by more than 30% by reducing the slag recycle, removing magnesite from the recipe and introducing high-grade ore. Electrode penetration was improved by reducing coke levels and by utilising more reactive coal. The pitch circle diameter (PCD) was reduced to get a better operating stability on furnace no 5 using the MINSTRAL Control System. Energy consumption on the furnaces improved by more than 15% while SiMn production increased as a result by more than 18%.

Jan 1, 2004

By D. C. Kaliampakos, A. G. Benardos

The existence of quarries near or even within the boundaries of urban centres is the cause of many environmental problems, despite their significant contribution to the cities’ development. Hence, the question arises as to how quarrying activities can be compromised within the spirit of sustainable development in big cities. In the case of Athens, two dominant, though opposite opinions have been formed. The first argues that all quarries must be forced to suspend their activities as soon as possible; the second presses for the continuation of quarrying. Consequently, the question is transposed on the dilemma between improved environmental conditions and economic development. This paper demonstrates that if a complete redesign is employed to specific, nonvisible quarrying sites, the continuation of quarrying activities is acceptable. It is a good compromise between the economical demand and environmental protection.

Jan 1, 2000

By E. Hinton, L. Bloomquist

"This paper describes a guidance system for autonomous underground mining vehicles, which does not require any infrastructure or inertial positioning systems to aid the guidance process.BackgroundINCO Limited mines approximately ten million tons per annum through 12 operating mines in the Sudbury, Ontario, area (Fig. 1). With challenges from operating in a cyclical marketplace as well as new technologies making alternative nickel ores more competitive to refine, the Mines Research department embarked on a strategy that pointed toward automation as a tool to help the company become even more economical in mining.The mining industry has been looking for ways and means to mine orebodies more and more inexpensively. Automation and the lessons learned from manufacturing had a great influence in the direction of research at INCO Limited over the past ten years. Guidance systems have evolved over the years but the majority of commercially available systems rely on some form of infrastructure. This, in part, has caused some resistance from operators to install and maintain automated or semi-automated systems for guidance of underground machinery.Internal industrial studies cited travel time to and from the workplace as one of the major time sinks in the shift of underground miners. Depending on the mine, it may be as much as two hours moving in and out of an area. Some work areas have accommodated this by having “hot changes” at the work place. However, at some point in time, there are two people tasked with the same job and on site at the same time to make this overlap occur.Tele-operation of underground hard rock equipment eliminated this overlap and also provided a comfortable environment in which to work. By taking advantage of the communications network installed, the miners proved that they could operate three machines with relative ease. This was accomplished by a vision-based, “painted line,” autonomous guidance system termed the light rope system.With a few years’ experience with the system, some issues have arisen, including the cost of the rope itself (Fig. 2).The vehicle’s route is limited to the paths defined by the light rope, and a system of switching power to the light rope to select different routes is required. The rope itself is subject to damage from nearby blasts. Also, the system offers no obstacle detection; the vehicle may be switched off as a means of shutting the machine down thus protecting personnel in the area."

Jan 1, 2001

By Nasr Sheta

"After Hurricane Sandy, the stability of an earth slope in the Atlantic Highlands, New Jersey in the United States was deteriorating due to slumping soils and erosion from flooding. A slope stability evaluation indicated the slope did not satisfy the requirements of the local building code. A triple-tier, pile-supported and mechanically stabilized earth wall was designed and constructed to stabilize the slope. The construction was planned from a 3-m-wide roadway and, because of rough terrain and limited work space at the site, a cast-in-place drilled-pile construction was deemed impractical due to slow pile production. An alternative procedure was utilized by pre-drilling holes, and installing precast tip-and-shaft-grouted (PCTSG) piles, which extended to competent soils to improve slope stability. A grade beam, connecting the PCTSG piles along with soldier beams and concrete lagging were used to form the lowest tier of the slope stabilization, while the middle and higher tiers were built as mechanically stabilized earth. The stability of the proposed stabilization was analyzed using 2-D non-linear finite elements. After construction, monitoring of the wall continued for about 8 months to check its performance, and indicated lateral and vertical wall movements were less than 25 mm and 6 mm, respectively, indicating effective slope stabilization.INTRODUCTIONStabilizing earth slopes using piles to connect near-surface unstable soils to underlying stable ground masses has been investigated by many researchers, who presented various approaches to evaluate the contribution of the pile system towards improving the stability of the slope. Some of these approaches consider the piles as structural elements receiving forces from the upper sliding ground mass and transmitting these forces to the underlying stable one. The force from the top sliding mass is applied at between one third and one half of the pile embedment into the top sliding mass, Anagnostopoulos et al. (1990), Fukuoka (1977) and Matsui et al. (1988). The point of application of the sliding force was explored based on successful case histories while addressing the safety factors for both geotechnical and structural design, Vessely A. et al. (2007). The development of numerical analysis techniques utilizing the method of finite elements (FE) also enabled better analysis and design of slopes stabilized using piles. A FE-based approach was successfully utilized to design slope stabilization with target safety factor based on the shear and bending demands and the spacing of the piles, Pradel D. et al. (2010).After Hurricane Sandy in October 2012, the stability of many properties constructed atop earth slopes located along the coast of the Atlantic Ocean has become a concern due to storm-induced erosion. This paper presents the analysis, design and construction of a hybrid slope stabilization system utilized at one of these storm-impacted properties, which is located in the Atlantic Highlands, New Jersey in the United States. The subject property consisted of a two-story residential dwelling and a parking structure, and was built on top of an about 8-m-high earth slope having crest at about elevation 10 m (el 10) and toe at about el 2."

Jan 1, 1900

South Africa?s primary electricity supplier, Eskom, provides incentives to reduce power demand during critical times by granting capital through a Demand Side Management programme. DSM encourages the end user to review and optimize energy consuming systems and use capital, provided by Eskom, to purchase or modify the equipment required to achieve a load-shift. As part of the DSM agreement the mine ultimately acquires the capital equipment and benefits from reduced power costs, but in return is required to sustain the load-shift tactic for up to five years. The paper focuses on one DSM tactic, main fan energy management. In this case, reduced air flows during selected peak and off peak periods, results in a substantial reduction in peak power demand. DSM incentives provided capital for automated main fan control as well as improved control of the mine ventilation systems. To examine the work in detail Gold Fields Ltd Driefontein gold mine near Johannesburg was chosen as a case study.

Jan 1, 2009

By J. S. Diller

In 1827, chromite was discovered near Baltimore by Isaac. Tyson, Jr., who initiated the mining of chrome ore and later (1845) the manufacture of chromium compounds in this country. From 1828 to about 1560 the United States, supplanting Russia, supplied chromite for most of the world. Chrome deposits were found also in California, and the Tyson Company shipped ore to Philadelphia by way of Cape Horn. In 1848, J. Lawrence Smith, an American in the employ of the Porte, discovered large bodies of chromite in Asia Minor. They were developed in 1865 and became the chief source of the world's supply for a number of gears. The discovery of the large high-grade bodies in New Caledonia., and later in Rhodesia, with other foreign sources, gives at present an abundant supply for all demands. For a number of years before the great war. the United States produced only a few hundred tons of chromite annually, for local use, but during the war the demand for domestic ore resulted in a production of more than 82,000 long tons of crude ore in 1918, and it was demonstrated that the United States has reserve deposits equal to a war demand of several years' duration. Now that the war is over, the country is con-serving its domestic supplies by employing higher-grade but cheaper ore from foreign countries.

Jan 9, 1919

By S. A. Spachner

An analysis of the powder patterns of the omega transition phase in three binary titanium alloys containing 8 pct Cr, 13 pet Mo, and 15 pet V, respectively, showed that all could be indexed on an orthorhombic unit cell. The unit-cell dimensions were all quite similar. There is evidence for the occurrence of more than one transition phase in Ti-Cr and Ti-V alloys. FOLLOWING the discovery of a new brittle phase in certain titanium-chromium alloys by Frost, Parris, Hirsch, Doig, and Schwartz,' named ? by these investigators, much interest has developed concerning the identification of alloy systems in which this phase exists, kinetics of the transformation in such systems, and the crystal structure of the ? phases appearing. Omega has been found in alloys of titanium-manganese, titanium-molybdenum, titanium-iron,' and titanium-vanadium.' In the present work, a study was made of the powder patterns of the ? phase occurring in alloys of Ti-8Cr, Ti-13Mo and Ti-15V in an effort to obtain a basis of comparison for ? phases appearing in these different alloys. Comparison of Alloys for ?-Phases Two hundred mesh powders of Ti-8Cr, Ti-13Mo and Ti-15V were prepared. A portion of powder sufficient for three x-ray powder specimens was placed in a Vycor tube, evacuated to less than 0.1 µ pressure, filled with argon, and sealed. The tubes were then heated to 900°C, held at this temperature for 30 min, and water-quenched. Following this transformation to the ß phase, the specimens were quenched in lead or solder pots, held at the desired temperature for varying lengths of time and water-quenched. The heat-treatments used and the phases identified are listed in Table I. The intermediate water quench was used in lieu of direct downquenching from 900°C to the bath temperature desired to circumvent the possibility of transformation of the powder specimen from ß to (ß + a) while it was being moved from the homog-enization furnace to the lead bath. To check the possibility that upquenching to the bath temperature might bring into play a different mechanism than downquenching to this temperature, resistivity measurements were compared on Ti-8Cr rod specimens which were transformed isothermally at 400°C by downquenching from the solution-treatment temperature and those which were transformed at 400" C by upquenching ß specimens from room temperature. The results are shown in Fig. 1. No difference in transformation mechanism was noted. It soon became apparent that sufficiently detailed Debye-Scherrer photograms of the ? phase in the alloys which were to be used could not be obtained by the use of copper radiation. Although satisfactory photograms of ß and ß + a phases were obtained with this radiation, the ? phase appeared to exhibit mild fluorescence, making interplanar spacing computation virtually impossible. Molybdenum radiation appeared to offer promise in cutting down this fluorescent effect, the mass absorption of titanium for molybdenum radiation being 23.7 in contrast to 204 for copper radiation. The reduction in the accuracy in determining the location of the photo-gram lines caused by the shorter wave length of molybdenum characteristic radiation did not appear to be a significant factor. Utilizing a camera of 57.3 mm radius, best results were obtained for exposure times ranging between 30 and 40 hr. Tube potential

Jan 1, 1959

By Sidney Cornell

THE technical- advantages of adding oxygen to air and producer gas, or using it as a reactive agent, producing 400 B.t.u. gas instead of. the present 150 B.t.u., with higher flame temperatures and a reducing flame possible, with a smaller volume of gases passing through a furnace, will result in quicker melting, sharp working, and the production of a higher quality steel. Probably electric-furnace quality steel can be produced in an open-hearth furnace using oxygen. A modern, standard, 100-ton open-hearth furnace, with all equipment, costs from $350,000 to $500,000; there are about 1000 open-hearth furnaces in this country. When considering the use of oxygen in the open-hearth furnace, it is necessary to study: (1) The use of oxygen in the present furnaces, such that modification of existing furnaces and equipment cost the minimum, although the full advantages of oxygen are not thus obtainable. (2) The use of oxygen in a furnace designed for its use, producing quality and quantity steel at the lowest possible cost. This entails the junking of approximately one-half the value in existing equipment-writing off $250,000,000. The basis of such an estimate is the present cost of manufacturing open-hearth steel. Objection may be taken to some of the unit prices here given, but while some companies obtain their ores for much less, the prices quoted are -market price. They are used to show the maximum economy obtained by oxygen at that point.

Jan 11, 1924

Common practice in mineral resource estimation consists of partitioning the orebody into several domains defined by grade intervals, prior to the geostatistical modelling and estimation/simulation at unsampled locations. This paper shows the pitfalls of grade domaining through a case study in which we compare the performance of several estimation schemes and demonstrate that the use of domains defined by grade cut-offs implies a deterioration of the resource estimates, mainly in what refers to precision and conditional bias. Then, several conceptual limitations of the grade domaining approach are stressed, in particular the fact that it does not account for the spatial dependency between adjacent domains and for the uncertainty in the domain boundaries. Also, this approach is shown to be sensitive to the cut-offs that define the domains, to provoke artifacts in the kriging maps, histograms and scatter grams between true and estimated grades, and to lower the kriging variance, a feature that may impact the mineral resource classification. An alternative approach is finally proposed to overcome these limitations, based on a stochastic modelling of the grade domains and a co-kriging of the grades using information from all the domains. Keywords: geostatistics, kriging, conditional bias, geological control, grade zoning.

Jan 1, 2005

By G. V. Sullivan

The Bureau of Mines conducted preliminary beneficiation studies of a gold-bearing graphitic schist from Blue Hill, Tallapoosa County, Ala. The average analysis of the material was 0.08 oz/ton gold. Tabling of minus 35-mesh material recovered 83 to 94 percent of the gold at grades of 6.925 to 2.165 oz/ton, respectively. A combination of jigging and tabling resulted in a concentrate assaying 24.3 oz/ton gold and contained 87 percent of the total gold. Treatment of the material by jigging, tabling, and amalgamation recovered 86.5 percent of the gold.

Jan 1, 1969

By A. Y. Senchenko, Y. V. Kulikov

"Different methods aiming at specific energy calculation and design of AG/SAG circuits are used in mining. They include JK DWT/SMC test, SAGDesign test and CWi/RWi/BWi tests. The simplest methods with no secret equations and giving energy required for grinding in kWh/t were proposed by F.?. Bond and J.H. Starkey. D.J. Barratt proposed to use results of CWi/RWi/BWi tests for AG/SAG mill sizing. The present paper gives an alternative for forecast of specific AG/SAG energy. The principle is similar to the theory proposed earlier and consists in cumulative AG/SAG energy calculation using indices of rod and ball grinding (RWi+BWi) without impact crushing index (CWi). Then total energy is divided between two grinding stages using special formulas based on extensive statistical information. The forecast indices of AG/SAG and ball grinding are similar to the SAGDesign testing results. Hereinafter the predicted indices are used for mill sizing of the whole grinding circuit. The method considered in the paper enables prediction of AG/SAG energy based on the test results according to Bond method. The proposed method version was not widely published earlier. The aim of the work was to elaborate cost-effective, reliable and accessible way to determine specific AG/SAG energy. At this stage of method development, it is recommended to use it only for works at preliminary Geometallurgy stage (Scoping, Pre-Feasibility). At design stage the obtained data should be confirmed by appropriate testing using alternative JK DWT/SMC and SAGDesign methods.INTRODUCTIONAppropriate crushing and grinding testing is required to design efficient comminution circuits. It is obviously important to obtain accurate information about ore hardness properties since the main energy consumption at the plant is associated with comminution processes. Moreover, it is required to apply the processes that make it possible to minimize operating costs and efficiently use capacity of the installed equipment installed.When studying ore hardness properties, it is required to take into account that breakage of the material is performed using different equipment. That is why accurate selection of the equipment and the circuit calculation without relevant testworks is impossible. Ideally, the testworks should provide answers to the following questions: determination of ore hardness properties, determination of specific energy consumption for comminution as well as obtaining of sufficient amount of statistically significant results from the tests. The results from crushability and grindability testworks in the first place provide assessment of ore hardness properties and in addition correlate with throughput of the respective equipment. The data obtained can be used for modeling of comminution circuits at the stage of the technology development"

Jan 1, 2016

By Mingyang Li, Yan Lv, Xiaolong Ma, Xudong Gao, Jie Zhao, Yingyi Zhang

The reduction process of pre-oxidized ilmenite concentrate powder in 30%CO–70%N2 atmosphere was characterized by thermogravimetric and differential thermogravimetric (TG-DTG) analysis system at the temperature from 1073 to1223 K. The isothermal reduction results show that the reduction process is divided into three stages and the corresponding apparent activation energies are obtained by iso-conversional method and model-fitting method, respectively. For the first stage, the conversion degree increases sharply with increasing time, and the reduction process is controlled by the random nucleation and subsequent growth model (A2 model). For the second stage, the conversion degree increases slowly with increasing time, and the reduction process is controlled by the diffusion of carbon monoxide in the reduced layer (D1 model). For the third stage, the reduction processes at different temperatures are controlled by the diffusion of carbon monoxide in the reduced layer (1073 K and D1 model), phase boundary chemical reaction (1123 K and R2 model), random nucleation and subsequent growth (1173 to 1223 K, A2, and A3 models), respectively. For the whole reduction process, the apparent activation energies obtained by iso-conversional method and model-fitting method are 71.72 and 31.92 kJ mol−1 , respectively

By M. Mikhaylenko

The most common methods of processing of uranium ores is sulfuric or carbonate leaching with conversion of hexavalent uranium to uranyl carbonate or sulfate anionic complexes followed by sorption of the later by strong base anion (SBA) exchange resins. It is known that chloride anion has high affinity for SBA resins so that it depresses sorption of anionic complexes of uranyl. Application of the SBA resins becomes impractical for recovery of uranium when chloride concentration in pregnant leach solution exceeds 3-5 g/l [1-3].

Jan 1, 2012