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By Tianfei Liao

Extensive site investigations revealed that abandoned shallow mine workings exist under a site planned for construction of a major new facility. Since the mine voids were susceptible to collapse, they were stabilized by grouting. After completion of the mine remediation, three types of deep foundations (micro-piles, auger-cast piles, and drilled piers) were considered for this site. Micro-piles spread the load via the bond between the pile and the bedrock. Without significant length socketed in rock, the axial load of auger-cast piles and drilled piers has to be concentrated on end bearing. Although spreading the load is preferable in this environment, economic consideration dictated the choice of drilled piers for construction.

Jan 1, 2009

By C. Don Sullivan

Paraphrasing the poetic repetition of Gertrude Stein - "Research is research, is research, is research --- ad infinitum." But research takes many forms and involves many facets. Perhaps the most simple of definitions is that attributed to the late "Boss" Kettering of General Motors who in advising a young trainee said, "Research is an intelligent effort to satisfy the curiosity of the human mind." Reclamation research is complex and requires a diversity of scientific knowledge. The overall aim of land reclamation research is directed to finding practical ways to develop efficient methods to restore mined lands to productive use, compatible with use of adjacent lands, as soon after mining as possible; and, finding practical ways to reduce or prevent damage to surrounding resource areas, which may be affected by the mining process. Research in the field of mined land reclamation is not entirely new, although in some respects we are exploring new areas each day.

Jan 1, 1967

By Hermann A. Derbuch

Twin Mining made a conscious decision when it changed from gold mine explorer and developer to become a diamond explorer in Canada?s Arctic. It was a decision of survival in an environment that saw junior gold companies either disappear or turn into dot com companies. Twin Mining learned fast and staked within weeks of that decision the first 50 sq. km of claims on, what became, its TORNGAT property at 59½° latitude on the east coast of the Ungava Bay in northern Quebec. This land position, 724 diamonds later (including 322 macro diamonds of gem quality, white and transparent) grew to 507 sq. km today. The 74° latitude called when Twin Mining exercised the option to acquire 3 claims owned by Helix Resources Inc. which revealed exceptional diamond potential. A gem quality 5.4 mm (0.768 carat white and transparent) diamond and the discovery of 16 pipes on 15.2 ha convinced Twin Mining?s board to sanction the deal. Both properties have outstanding features. Kimberlite Dykes and Pipes are in outcrop. The property locations have deep-sea access near existing infrastructure. Their locations are in an environment that is stable and development friendly and has a positive track record with successfully operating mines near-by.

May 1, 2001

By Minji Jun

Leaching of the surface-coated metals from waste acrylonitrile butadiene styrene plastics (WABSP) has been investigated in the ammoniacal solution. The ammoniacal leaching of WABSP (typically containing 4.1 wt% Cu, 1.3 wt% Ni, 0.03 wt% Cr) efficiently dissolved copper and nickel, leaving unleached chromium as fine particles. The results indicate that the anions of different buffer media for metals leaching follow the order: CO3 2− > Cl− > SO4 2−. A declined leaching with high NH4OH–(NH4)2CO3 ratio (8:1) and a steep rise in extraction with high pulp in solution revealed the influence of anion (CO3 2−) and cation (Cu2+) present in the system. The leaching performed in carbonate solution by maintaining 5.0 M total NH3 concentration as NH4OH–(NH4)2CO3 ratio, 4:1; pulp density, 200 g/L; agitation speed, 400 rpm; temperature, 20 °C and time, 120 min yielded the maximum extraction (>99%) of copper and nickel. The study reveals a plausible recovery of the surface-coated metals from the WABSP without altering the properties of polymer material that can be recycled separatel

By Gerald Sherman

MINING asbestos ore by caving at Thetford Mines, Quebec, has been described in the Transactions of the Canadian Institute of Mining and Metallurgy in papers presented by the staffs of The Asbestos Corp. Ltd., in 1934, and Johnson's Co. Ltd., in 1941. The production by caving prior to 1949, in round figures, has been 14,500,000 tons of ore by The Asbestos Corp. and 5,500,000 by Johnson's Co. They are the only caving operations in asbestos at the present time. The Jeffrey mine of the Canadian Johns-Manville Co. at Asbestos, 40 miles southwest of Thetford, is well along in preparations for caving, and The Bell Asbestos Mines Ltd. at Thetford Mines, will follow their examples later. GERALD SHERMAN, Member AIME, is Consulting Engineer, Johnson's Co. and Canadian Johns-Manville Co., New York, N. Y. AIME San Francisco Meeting, Feb. 1949, and New York Meeting, Feb. 1950. TP 2828 A. Discussion (2 copies) may be sent to Transactions AIME before May 31, 1950. Manuscript received Nov. 2, 1949. Nearly all of the asbestos produced by the western hemisphere is mined in those districts of Canada. Since it has been the subject of a number of technical papers, this contribution is offered as a review of progress. Some introductory information seems appropriate, for few members of the American Institute of Mining and Metallurgical Engineers are familiar with the mineral, or how asbestos deposits differ from others in caving characteristics. Asbestos is found in peridotite, a basic intrusive rock irregularly altered to serpentine and erratically fractured, well enough to cave in bulk, but leaving many blocks of solid ore of all sizes scattered through the deposit. Chrysotile is the variety of asbestos produced in Canada. Its fibers are the most valuable commercially, having a good proportion of long fibers, strong, silky, flexible, and suitable for spinning. The fibers occur in all lengths, from the microscopic to 3 in., or more, the shorter are more abundant. Their values depend on length combined with other qualities noted above. They occur as veinlets filling fissures in the peridotite, with crystals compactly arranged in parallel across the cracks. They are sometimes lightly frozen to the walls but the partings are distinct, often marked by particles of magnetite adhering to the fiber ends. Sometimes they break away from the rock in slabs an inch or more in thickness. In wide fissures the fibers are not always continuous, the "broken fibers" being separated by lines of parting with occasional scattered grains of magnetite, which is an injurious mineral to be elirninated when possible. In addition to the chrysotile ''Cross fiber," some "slip fiber" is found in fault fractures in limited quantities of less valuable character. With the exception of the Asbestos Corp, ore, in which the content is said to be more uniform, asbestos is eccentrically distributed through the peridotite. It is the general impression that the higher grades are more often found in hard rock. There are rich pockets and leaner areas which range down through various grades to minor barren sections. Wholesale mining is necessary to make sure of recovering all the high grade for there are no reliable indications of its existence. Ore selection only appears in constructing assay-grade limits for caving. The mill yield of the Thetford ore body in 1934 was 6 to 10 pct of the ore milled, made up of all classes, with occasional runs up to 15 pct or so. Quotations for Canadian asbestos* are as follows: Per Ton No. 1 Crude (% in. and longer) $896 @ $960 No. 2 Crude (Y8 to % in.) 350 @ 545 Spinning (less than % in.) 204 @ 378 Other classes, price diminishing with length. Shorts or "refuse" 24 @ 46 • From Eng. and Min. Jnl., Nov. 1948. Asbestos of even superior quality for electric insulation is found in Arizona limestone. It is white, containing very little combined iron, but occurs only in small quantities.

Jan 1, 1951

By Gerald Sherman

MINING asbestos ore by caving at Thetford Mines, Quebec, has been described in the Transactions of the Canadian Institute of Mining and Metallurgy in papers presented by the staffs of The Asbestos Corp. Ltd., in 1934, and Johnson's Co. Ltd., in 1941. The production by caving prior to 1949, in round figures, has been 14,500,000 tons of ore by The Asbestos Corp. and 5,500,000 by Johnson's Co. They are the only caving operations in asbestos at the present time. The Jeffrey mine of the Canadian Johns-Manville Co. at Asbestos, 40 miles southwest of Thetford, is well along in preparations for caving, and The Bell Asbestos Mines Ltd. at Thetford Mines, will follow their examples later. GERALD SHERMAN, Member AIME, is Consulting Engineer, Johnson's Co. and Canadian Johns-Manville Co., New York, N. Y. AIME San Francisco Meeting, Feb. 1949, and New York Meeting, Feb. 1950. TP 2828 A. Discussion (2 copies) may be sent to Transactions AIME before May 31, 1950. Manuscript received Nov. 2, 1949. Nearly all of the asbestos produced by the western hemisphere is mined in those districts of Canada. Since it has been the subject of a number of technical papers, this contribution is offered as a review of progress. Some introductory information seems appropriate, for few members of the American Institute of Mining and Metallurgical Engineers are familiar with the mineral, or how asbestos deposits differ from others in caving characteristics. Asbestos is found in peridotite, a basic intrusive rock irregularly altered to serpentine and erratically fractured, well enough to cave in bulk, but leaving many blocks of solid ore of all sizes scattered through the deposit. Chrysotile is the variety of asbestos produced in Canada. Its fibers are the most valuable commercially, having a good proportion of long fibers, strong, silky, flexible, and suitable for spinning. The fibers occur in all lengths, from the microscopic to 3 in., or more, the shorter are more abundant. Their values depend on length combined with other qualities noted above. They occur as veinlets filling fissures in the peridotite, with crystals compactly arranged in parallel across the cracks. They are sometimes lightly frozen to the walls but the partings are distinct, often marked by particles of magnetite adhering to the fiber ends. Sometimes they break away from the rock in slabs an inch or more in thickness. In wide fissures the fibers are not always continuous, the "broken fibers" being separated by lines of parting with occasional scattered grains of magnetite, which is an injurious mineral to be elirninated when possible. In addition to the chrysotile ''Cross fiber," some "slip fiber" is found in fault fractures in limited quantities of less valuable character. With the exception of the Asbestos Corp, ore, in which the content is said to be more uniform, asbestos is eccentrically distributed through the peridotite. It is the general impression that the higher grades are more often found in hard rock. There are rich pockets and leaner areas which range down through various grades to minor barren sections. Wholesale mining is necessary to make sure of recovering all the high grade for there are no reliable indications of its existence. Ore selection only appears in constructing assay-grade limits for caving. The mill yield of the Thetford ore body in 1934 was 6 to 10 pct of the ore milled, made up of all classes, with occasional runs up to 15 pct or so. Quotations for Canadian asbestos* are as follows: Per Ton No. 1 Crude (% in. and longer) $896 @ $960 No. 2 Crude (Y8 to % in.) 350 @ 545 Spinning (less than % in.) 204 @ 378 Other classes, price diminishing with length. Shorts or "refuse" 24 @ 46 • From Eng. and Min. Jnl., Nov. 1948. Asbestos of even superior quality for electric insulation is found in Arizona limestone. It is white, containing very little combined iron, but occurs only in small quantities.

Jan 1, 1951

By Lorraine Brandt Yde

This paper describes development of a cost report that is descriptive, logically oriented, and concise. Since the costs involved relate to mining, this reporting technique could help bridge any possible communications gap between "mining men" and computer personnel, at the same time giving the computer-oriented mining individual information to assist him in his job performance. As computers become entrenched in the mining world, meaningful report assimilation becomes a major task. No one should be more capable of defining required results than the man requesting a report. If he is able to clearly state his needs and has researched his problem, it will be reflected in the computer output. During 1970, The Anaconda Company's Berkeley Pit Operation, at Butte, Montana, received many different computer-generated equipment cost reports. Up to thirty-six different components for each type (class) of pit equipment contributed cost data to the Berkeley Pit cost system files for both operating and repairs during current month, year-to-date and accumulation-to-date time periods. This reporting approach was taken to facilitate analyzing this voluminous data. SUMMARY A Major Component Cost Analysis (Exhibits 6-A thru 6-C) developed by arranging the top ten operating and repair percentages (component cost divided by total cost) in descending order, and then accumulating these percentages to a possible one-hundred percent. While tabulating the operating and repair cost percentages by equipment unit number in the current month, year-to-date and accumulation-to-date time periods, a frequency chart is constructed for each equipment

Jan 1, 1971

By Timothy G. Shuttleworth

In the late1970s, mineral processing plants producing copper sulfide concentrates and oxide leaching feedstocks went online with operating tonnages that exceeded traditional installations. This created a need for larger capacity belt conveyors and apron feeders. Apron feeders are slow moving, heavily loaded conveyors that feed a deep bed of ore from a bulk holding location (a bunker) as a controlled stream, often into a large capacity crusher. Apron feeders use sprockets and caterpillars, while belt feeders use rubber belts with motorized head pulleys to convey the material. The damaging of belts and clogging of transfer points from tramp iron required larger magnetic separators and the removal of tramp metal cannot prevent these serious problems. Corrective action at this location is important for two reasons: Removing tramp iron early in the ore stream protects downstream equipment from potential costly damage. Installing apron feeder magnets before the primary large capacity crusher means that secondary and tertiary crushing steps (made up of multiple parallel units) operate more efficiently, since tramp metal is removed at the onset.

Jan 1, 2011

By A. Mcdonald, F. W. Breaks, T. F. Morris, S. A. Averill, D. C. Crabtree

Gahnite, a zinc-bearing spinel, is a resistate mineral that may be used as an indicator mineral of polymetallic deposits in high-grade metamorphic terrain. The Ontario Geological Survey recently completed sur?cial mapping and sampling programs in the Separation Lake area of north-western Ontario and Kinniwabi Lake area of northeastern Ontario in which gahnite was recovered from samples of sur?cial sediments. Ternary plots of the composition (ZnO, MgO, FeO[t]) of gahnite recovered from these sur?cial studies reveal three distinct groups: Group 1 is characterized by low (< 1 wt%) MgO values; Group 2 by higher (>1 wt%) MgO values; and Group 3 by higher FeO(t)values than Groups 1 and 2. The composition of in situ gahnite recovered from volcanogenic massive sul?de mineralization, Zn-rich Sedex-type mineralization and peraluminous rare-element mineralized granite and pegmatite also was determined. The composition of the gahnite obtained from sur?cial samples was compared with that of in situ material. Gahnite from the peraluminous rare-element granite and pegmatite overlapped very well with sur?cial gahnite of Group 1. Gahnite from volcanogenic massive sul?de mineralization and Sedex-type mineralization overlapped well with sur?cial gahnite of Group 2. These results suggest that determination of gahnite composition in indi-cator mineral surveys may be useful in exploration programs when assessing the mineral potential of a region.

Jan 1, 1997

By Walker. P. W. A.

Abstract -The Riviera tungsten occurrence in the Cape Province of South Africa was discovered in October 1979 as a result of stream-sediment panned concentrate sampling. The Cape age granite and late Precambrian Malmesbury Group carbonates and chlorite schists which it intrudes and which host the mineralization are covered by between 10 m and 30 m of Tertiary/Recent alluvium and clay. The scheelite/powellite and molybdenite mineralization occurs in a greisenized granite cupola with an overprint of porphyry-type alteration as well as in minor skarns. The ore reserve is estimated to be 46 million tonnes at an average grade of 0.2160Jo W03 and 0.020% Mo. The deposit is uneconomic at current tungsten prices.

Jan 1, 1994

By F. H. Edmunds

I N presenting this paper, the writer wishes to point out some of the difficulties and problems of geological work in that part of Saskatchewan in which outcrops are few. These problems are well known to all geologists who have made investigations in this region, but may not be so well known to those outside. A table of the strata as known in certain areas of Saskatchewan and the adjacent provinces is given, with a brief discussion of some of the formations and beds about which there is little knowledge due to their being deeply buried and not exposed in the region. Comment with regard to possible oil and gas structures is made and some features of the structures in the Battleford and Simpson districts are described. The writer wishes to make acknowledgment to members of the Geological Survey of Canada to whose work in Saskatchewan and the adjacent provinces reference is made, and to others who have made, or are making, valuable contributions to the stratigraphy of Saskatchewan. Mr. G. C. Webb has kindly furnished information regarding and materials taken from a well bored recently in the Paynton district. Special thanks are due to the Simpson Oil and Gas Company for permission to use much valuable information with regard to their wells and for the generous way in which the officials and staff co-operated with the writer. The opportunities the writer has had to visit many parts of the Province have been in connection with investigations for the Provincial Department of Natural Resources and through facilities provided by the Department of Soils of the University of Saskatchewan. To these Departments the writer accords his thanks. For the purposes of this discussion, Central Saskatchewan may be considered as that portion of the Province extending from Township 16, with Regina, Moose Jaw, and Swift Current situated on or near the southern boundary, to Township 48, with Prince Albert and Lloydminster on the northern boundary. This region includes territory underlain by Cretaceous sediments and excludes the southern portion of the Province, where Tertiary beds underlie the surface and are exposed to an extent sufficient to permit a measure of systematic mapping.

Jan 1, 1937

By David S. Shatzer, Michael R. Purcell

Current world events have demonstrated the use of commercial vehicles, other unconventional modes of transportation and unusual materials as explosives or incendiary weapons, affecting commerce, disrupting cities and even entire societies. Since the implementation of the Organized Crime Control act of 1970 the Bureau of Alcohol, Tobacco, Firearms and Explosives (ATF) has been investigating and studying explosives and incendiary devices and their related effects.

Jan 1, 2004

By Steve Kral

The power industry throughout the world is in the midst of a significant transition that will result in a major restructuring. Deregulation of utilities in the United States is continuing, resulting in increased competition among power providers. The traditional ways that electric power is globally bought, sold and delivered will also change. However, according to the Department of Energy&apos;s (DOE) Pat Godley, one thing is clear: "Those who provide the power during the 21 st century will be those who are willing to change - those who are willing to accept new ways of doing business and willing to employ new technologies." Godley is assistant secretary of fossil energy with DOE. Her comments came during the opening remarks at the Fourth Annual Clean Coal Technology Conference, held in Denver, CO, Sept. 5-8, 1995. The conference was sponsored by DOE and the Center of Energy and Economic Development. Under the theme "Global Opportunity," more than 300 coal and utility executives spent three days discussing the new face of the electric-power industry throughout the world and the new, mostly clean coal technologies (CCT) that will be available to power providers.

Jan 1, 1995

By M. Pelser, C Aldrich

"The presence of calcium and magnesium in the hydrometallurgical processing of base metals, results in a number of process difficulties. These problems range from the contamination of the final product (where the final product is a precipitate) to high energy consumptions and large bleed streams during electrowinning. Calcium poses an additional problem in sulphate solutions owing to the low solubility of its sulphate salts. This can easily lead to a process stream that is supersaturated with calcium sulphate, resulting in unwanted solids formation within the process equipment.Several processes are reviewed for the control of calcium and magnesium. Of these, fluoride precipitation was selected for experimental investigation. This method involves the addition of a soluble fluoride to precipitate CaF2 and MgF2. The experiments showed high selectivity for calcium and magnesium over the base metals. The experiments also showed magnesium precipitation to dominate for calcium to magnesium molar ratios greater than 1:3.To avoid the domination of magnesium precipitation, a flow sheet is proposed whereby only a portion of the base metal stream is subjected to fluoride precipitation. For the precipitation, a 10% excess of ammonium fluoride is used to remove the maximum amount of calcium and magnesium. After precipitation and solid-liquid separation the split-stream is returned to reduce the overall calcium and magnesium concentration of the base metal stream."

Jan 1, 2003

By Tatiana Tronda

"The territory of Belarus is characterized by nonhomogeneous ground conditions. In some cases soft ground layers can reach tens of meters in depth. Application of piles and other conventional foundations is rather difficult and expensive in such complicated conditions. Alternatively for the first time dry concrete columns were applied to improve the saturated soft soils at two sites. As there is no design methods for calculation of bases improved by dry concrete columns static penetration and static load tests were carried out to check the bases on availability. Considerable increase of toe resistance and Young modulus was achieved for all types of soil. Practical application, technology and test results are described in the paper. According to comparative calculations the cost of foundations on the base improved by dry concrete columns can be 32-75% lower than the cost of conventional pile foundations depending on ground conditions.INTRODUCTIONPile foundations, sand cushions or dewatering are usually applied in complicated ground conditions which are caused by presence of saturated soft soils. If the depth of soft soils reaches 20 m or more, conventional foundations have limited application, high labor and construction cost. A rational solution in such conditions is a ground improvement of upper soft soils. It allows the loads to be transferred on upper ground layers and the stresses to be dissipated considerably before reaching underlying soft ground layers.One of the effective ground improvement methods for saturated soft soils is the reinforcing by dry concrete columns (Fig. 1). The method allows saturated soft soils to be compacted and be drained at the same time. As a result strength and deformation characteristics of natural soils improve (Tronda 2013, ?????? 2014).Unfortunately, there is no design and computing methods for the ground improvement by means of dry concrete columns. However, at present the methods are under development on the basis of theoretical and experimental researches.TECHNOLOGYThe dry concrete columns are fulfilled in pressed wells according to technology of vibrostamped piles. Wells are pressed by vibratory hammer with the closed ended casing (Fig. 2) that provides compaction of surrounding soft soils. Then the casing is filled with dry concrete mix (Fig. 3). The casing end remains on the design depth and the casing is removed by vibratory hammer. The removing of the casing with vibration enables compaction of dry concrete mix inside the well. Dry concrete mix drains surrounding saturated soft soils improving its properties and the compaction speeds up the consolidation process. Over time the dry concrete columns fasten absorbing water from surrounding saturated soft soils that is need for hydration of cement (Fig. 4, 5)."

Jan 1, 2016

By W. P. Dyrenforth, W. E. Horst

Although, separating or concentrating minerals, based on differences in. their magnetic properties has been practiced for years1 the early industrial applications of magnetic separators were involved with the most highly magnetic materials. These early separators were used to concentrate magnetite, separate metallic iron from furnace products, and separate iron and brass turnings. Next, the addition of a pretreatment operation, such as roasting or calcining, to transform certain iron-bearing minerals into a highly magnetic compound that could readily be separated from the altered mineral mixture using existing magnetic separation machines was added to the flowscheme. As the number of magnetic-separator installations grew, steady development of better equipment evolved including the design and implementation of induced magnets having high-intensity fields, These developments of course greatly expanded the field of magnetic separation and made it possible to commercially separate or concentrate very weakly magnetic minerals which previously had been considered as nonmagnetic minerals. A number of different designs of magnetic separators were well developed and the unit operation of magnetic separation was gaining wide acceptance in mineral processing operations when two events occurred that dampened these developments. First, the Mesabi iron range with its direct-shipping iron ore was discovered and placed into operation. This of course significantly reduced the need for magnetic separation to meet the raw material requirements of the iron and steel industry. Second, the advent of selective froth flotation, was so successful in solving many mineral process problems that electrical concentration techniques being developed at that time, including magnetic-separation methods, were either terminated or received low priority ratings. During the past two decades interest has been renewed in the use of electrical concentration methods to solve mineral separation problems. As the direct-shipping iron ore reserves are depleted more emphasis has been placed on magnetic upgrading of lower value iron ore available throughout the world. In addition, magnetic separation techniques have found numerous applications in the non-metallic and industrial minerals industry to supplement froth flotation and thus add to the variety of beneficiation methods available.

Jan 1, 1971

By E. C. Rien

When the electrical system for a surface or open pit mine is designed, four major considerations should be satisfied in the following order: safety, reliability, flexibility, and cost. Careful planning initially will make expansion for future growth economical as well as possible without extended shutdown of operations. Electrical requirements in surface and open pit mining can be divided into three categories: main substation, plant power, and pit distribution. These systems are integral to each other, but will be dealt with separately here. 11.2-1. Main Substation. A main substation for a mining operation may vary from a 500 kva transformer supplying 480-v power to motor-driven pumps and conveyors, to a 50,000 kva substation serving a large beneficiation plant or a large strip mining operation. Regardless of size, it should be designed with the realization that a failure of the main substation will totally shut down the operation (Fig. 11.2-1.). Location of a main substation usually is a compromise between expense of running the incoming high-voltage transmission lines and the voltage drop of long secondary runs. Based on a geological survey for immediate and future areas of excavation, the main substation should be located as near to the center of load as possible. The site should be out of the blasting area, readily accessible to authorized personnel, and situated where prevailing winds will keep it free from dust or snow. DISCONNECTS AND OVERLOAD PROTECTION. The main substation should have a primary disconnecting device-either a pole top gang-operated switch and fuses of adequate interrupting capacity or, preferably, an oil circuit breaker with properly coordinated relay protection.

Jan 1, 1968

By V. T. Dow

This report describes construction details and methods used in driving the 5490 tunnel at the Kennecott Copper Corp, property, Bingham, Utah. The tunnel will provide railroad access to the world-famous open-pit copper mine at the projected 5490 level. This publication is one of a series prepared by the Bureau of Mines to depict mining operations and techniques in various mining districts in the United States. Utah Construction and Mining Go. (formerly Utah Construction Co.), contractor on the tunnel project, began work during September 1956 and completed the project in February 1959. The tunnel is 18 feet wide, 24 feet high, and about 18,000 feet long, It will accommodate a railroad locomotive on standard- gage track. With the exception of the last 1,700 feet, the tunnel is supported by steel sets embedded in concrete lining. The 1,700-fact segment of the tunnel is supported by timber sets that will eventually be removed as the pit is deepened.

Jan 1, 1962

By Gaither H. Kitchell

Introduction Fire assaying is an ancient method of determining the amount of gold and silver in geological materials. Today&apos;s commercial, mining, school, and private fire assaying laboratories still use this basic assaying method. One of the primary reagents used to collect gold and silver from the ore is litharge (PbO), or lead oxide. The Federal Occupational Safety and Health Administration&apos;s (OSHA) and the Nevada Division of Occupational Safety and Health&apos;s (OSH) have a lead standard. It states that a person exposed to airborne lead at concentrations greater than 50 µg/m3 (1.4 µg per cu ft) of air over an eight-hour period has gone beyond the permissible limit for health safety. It is not uncommon to get airborne lead concentrations of 1400 µg/m3 (40 µg per cu ft) in the flux/sampling area or 900 µg/m3 (25 µg per cu ft) around the gas/ electric furnaces during the fusion and cupelling phases. Therefore, any individual working in these areas for more than 30 days per year without proper protection is a likely candidate for lead poisoning. Lead In A Human Lead enters the body as a toxic substance by breathing it into the lungs and upper respiratory tract and by getting lead particles into the digestive system through ingestion. Smoking, eating, drinking, chewing tobacco and gum, or wiping a lead-contaminated hand across the mouth are all potential ways forgetting lead into the body. Lead taken in large quantities can actually kill a person in a matter of days. This is rare, however. The real hazard of lead overexposure is for the unsuspecting person who works in an unsafe lead environment for months or years. This individual can slowly receive damage, sometimes permanent, to the central nervous system, gastrointestinal tract, kidneys, blood, gums, and reproductive system. Safe Blood-Lead Level The Lead Standard states that the maximum safe blood-lead level is 40 µg/100 g (40 µg per 3.5 oz) of whole blood. It recommends 30 µg/100 g (30 µg per 3.5 oz) if a person is of child-bearing age. People not working around lead products normally have a blood level of less than 10 µg/100 g (10 µg per 3.5 oz). A person not adequately protected can exceed 40 µg/100 g (40 µg per 3.5 oz) in a few weeks by fire assaying only 100 samples per day per week. Studies show that some individuals have developed lead-related diseases with blood-lead levels less than 80 µg/m3 (2.3 µg per cu ft). Lead Poisoning Symptoms There is a long list of symptoms associated with lead poisoning. The most common are: a prolonged, sweet, metallic taste in the mouth; loss of appetite; anxiety and irritability; weakness and dizziness; nausea and tremors; and insomnia. Preventive Measures Based on the lead standard, a number of preventive measures can be taken to ensure that fire assay laboratory personnel frequently exposed to lead are protected against overexposure. First, the actual lead concentration within the assaying area should be determined. In Nevada, one can contact the Department of Industrial Relations, Division of Occupational Safety and Health for assistance in monitoring any laboratory. The agency will also recommend ways to protect against lead. This agency does the monitoring and provides an educational class on lead safety. This type of agency can be found in other states. Commercial consulting firms are also available, but they are expensive. Regardless of the technique used to determine lead concentrations, it is most likely that the average fire assay area exceeds the 50 µg/m3 (1.4 µg per cu ft) lead concentration limit. This is considered unsafe.

Jan 8, 1985

By ANA E. BOHE, MICCO GEORGINA DE, GASTON G. FOUGA, JUAN P. GAVIRIA, FEDERICO J. POMIRO

To the best of our knowledge, this paper comprehensively summarizes a thorough study to determine the thermodynamic viability of the reactions between light rare earth oxides and chlorine with and without carbon. The kinetics and mechanisms of light rare earth oxide chlorination and carbochlorination reactions are analyzed and discussed according to results in the literature. Lanthanides between lanthanum (La) and gadolinium (Gd) are considered as light rare earth elements (LREEs) in agreement with previous literature and the results detailed in this review. Both laboratory- and industrial-scale light rare earth chlorinations and carbochlorinations, starting from oxides and ores, are reviewed.