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By I. B. Cadoff, J. C. Bilello, R. Rosenberg

Diffiusion of magnesium into the surface of LiF crystals to controlled depths and subsequent heat treatments provided a wide range of surface zone harahesses and structure, The bend strength of the LiF crystals was increased by as much as an or-dev of magnitude. Ductility was achieved when dislocation generation occurred in the diffusion zone or when dislocations penetrated to the surface from the intevior. A critical surface hardness of 130 to 140 kg per sq mm was found helozu which generation could take place in the diffusion zone and ahoue which the zone was impenetrable, This hardness was obtainable by several methods, among them the aging of quenched MgF2 -LiF solutions to produce MgF, precipitation. Maximum hardness was ohtained in quenched specimens with no visihle evidence of MgF,. Diffusion-zone formation followed a parabolic rate law and an activation energy of 20.9 kcal per mole was obtained for the process. RECENTLY, the properties of ionic crystals as related to surface condition have been receiving much attention, specifically the transitions between ductile and brittle behavior. Originally Joffe 1 showed that NaCl crystals could be made ductile by immersion in water and related this to the elimination of surface microcracks. Aerts and DeKeyser 2 and Gorur 3' have subsequently shown that ionic crystals are inherently ductile and are embrittled through contact with air. Machlin and Murray4 hypothesized that a layer of NaCIO3 produced by contact of ozone with NaCl induced embrittlement by acting as a barrier to outward dislocation flow. westwood,' Rosenberg and Cadoff,9 and Bilello and cadoff' have reported surface strengthening of LiF crystals by coating with a magnesium compound and then heat treating for adherence. The major effect of the coat was to inhibit dislocation-slip lines from reaching the specimen surface. westwoods showed microcrack formation and fracture to be caused by slip-band interactions at the surface. The material presented in this paper is an extension of the work reported earlier by Bilello, Rosenberg, and cadoff'6,7 and illustrates the wide range of surface properties and bulk behavior obtainable by use of heat-treated magnesium-diffused surface regions in LiF crystals. EXPERIMENTAL PROCEDURE The LiF single crystals were obtained from the Harshaw Chemical Co. Some batch to batch variation was observed; therefore all specimens for a given test series were cleaved from the same crystal. The typical dimension used was 1 by 0.1 by 0.40 in. Surface damage resulting from cleavage was removed by chemically polishing in a 2 pct NH4OH solution. Each group of specimens was given a vacuum anneal at 700°C for 4 hr to provide a base standard for measuring comparative effects of various surface treatments. To produce the reacted surface zone, the annealed specimens were immersed in a boiling suspension of MgF, in doubly distilled HzO, agitated slbwly for 30 sec, removed, and dried at room temperature. Uniform coatings of MgF, were deposited with a thickness of approximately 5 mils. It should be noted that this technique can be modified for use with crystals which are soluble in water by using boiling absolute alcohol as the dissolving medium. This was found effective for the coating of NaCl with MgF2. The diffused surface zone was obtained by annealing the coated samples at elevated temperatures in a vacuum of lob4 mm Hg. Penetration depth was controlled by varying the annealing time from 1/2 to 28 hr. After heat treatment, the samples were tested for bend strength and hardness. Load was applied by four-point bending in a hard-beam testing jig. Four-point rather than three-point bending was used to provide a wide area of constant stress and to minimize the effect of localized inhomogenities in the specimen. The deflection rate was 8 x min-' and the distance between knife edges was 1/4 in. Load-time curves were obtained from a chart recorder coupled to the machine and converted to resolved shear stress on the shear plane vs deflection, as plotted in the figures. The unstressed portions of the sample outside of the two outer knife edges were used for the microhardness studies. Microhardness measurements were made with a Bergsman tester attached to a Reichert metallograph. All hardness impres-

Jan 1, 1964

By S. M. Shelton, A. L. Engel

"This report presents the results of investigations of ore-testing projects assigned to the Ore-Dressing Section, Metallurgical Division, Bureau of Mines, at the Mississippi Valley Experiment Station, Rolla Mo. During the fiscal year ended June 30, 1941.The manner of approving ore-testing projects has been explained in a previous reports. 4/ The testing procedures likewise have been described. 5/The treatment methods described are based upon laboratory experiments with small amounts of sample and naturally are subject to the inherent, normal, limiting conditions of such procedure. It is not intended to describe treatments in detail, but rather to indicate applicable methods. Local operating conditions, when the laboratory results are applied to plant operations, may require further study. Large-scale pilot-plant tests should be made before commercial operations are begun, so that translation from the experimental stage will yield satisfactory results."

Mar 1, 1942

By G. Van Weert

Refractory ores and concentrates containing silver tend to form Ag-jarosite during autoclave oxidation. Silver extraction from the oxidation products is therefore low, unless a hot lime treatment step to decompose Ag-jarosite precedes cyanidation. Since silver iodide is very stable but soluble in cyanide solutions, the formation and decomposition of Ag-jarosite in the presence of iodine species was studied. Results indicate that Ag-jarosite formation could be prevented in favour of H3O-jarosite and AgI while oxidizing Ag2S under industrial autoclaving conditions, when the total iodine species to Ag mole ratio exceeded 5. Lower ratios gave proportionally more Ag-jarosite and less AgI. Under these conditions existing Ag-jarosite was also found to decompose in H30-jarosite and AgI.

Jan 1, 1993

By James A. Deeks

"Motor failures and equipment bearing failures are responsible for reduced productivity.With the introduction of computers and data acquisition systems, users are now able to monitor, report and trend deteriorating conditions and take corrective action before a critical shutdown occurs.This paper discusses the monitoring and trend analysis of' motors, and motor and equipment bearings. With today's digital electronics technology users are now able to monitor their equipment, detect deteriorating or abnormal conditions quickly, alarm the condition locally and or remotely, and decide if immediate corrective action is necessary or if it can be delayed until the end of a work Shift. All of this can be done long before any damage is done to the equipment.Monitoring Trend AnalysisIt is no longer necessary to compromise in selecting products, since state-of-the-art designs allow the adjustment in such small increments that the users are able to detect minute changes in a system's performance.Monitoring and trending of motors and equipment bearings is now available in economical packages which can be expanded as a system grows. Simply select the information you need, set the parameters, choose the scan time, and decide on the degree of reporting.Buffer storage of short-term monitoring of a number of analogue channels permit the user to view the recent history of motor data such as: motor average load, unbalance, motor current, ground fault, reserve thermal capacity, plus all of the settings of the protective device.A decision can be made to freeze the stored information after the motor stops or after the motor starts. Then the user is able to recall the conditions and diagnose the performance and the cause of the abnormal condition. Typical scan times range from ¼ second to 5 seconds ."

Jan 1, 1992

The topic of the relationships between energy and particle size has had two very active periods -the first in the early thirties, when the relative merits of Rittinger's and Kick's proposals were vigorously debated; the second in the early fifties, when Bond's Third Theory was published. This second stage has produced several contributions that have provided a clearer picture of energy /size correlations in comminution. Derivations of a general relationship have been made from single-fracture experiments and from the rate of comminution, and both methods arrive at an equation of the type E = AK-11? The constant A in the equation may be regarded as a grindability parameter. In some respects, an understanding of the phenomena associated with comminution is still lacking, and research in this field should therefore be expanded. T HE SEARCH for a relationship between the energy consumed in comminution and the size of the broken product has been long and varied, and many

Jan 1, 1964

Shane is enjoying his new work. Six months ago, he was stocking shelves at his local supermarket and decided to make the big move to a job in mining with more challenge and, of course, more dollars. He's been through his inductions, received his training tickets and is now working in a crew of eight underground at a fly-in, fly-out (FIFO) operation. There are many more systems and processes here than in his retail job, and Shane's comfortable that his safety is being looked after. He is enjoying the continually changing work and conditions, it makes the job interesting. It's taking some time to get used to the roster and he is worn out by changeover, but he gets more time with friends and family during R & R.   Generally, the mining industry has a maturing safety culture and well developed systems. This sometimes lulls people into a false sense of security. Safety systems cannot anticipate every possible situation, nor can they replace people's perception, thinking and decision-making. To manage safety, it's critical to find the right balance between dependence on systems and a healthy fear and respect of risks we face.   As safety standards are raised, systems tend to get more thorough and complex. When a new person joins a mining crew, we induct and train them to provide the information they need. As labour availability again becomes short, and many new people join our industry, we shouldn't assume they know the fundamentals. We need to explain not only what they are expected to do, but why doing what we ask and expect will keep them safe. We must equip people to deal with both the routine and the unexpected.   This presentation explores the challenges of balancing a structured, systematic approach to safety with the need to also equip people to deal effectively with risks everyday in dynamic and extraordinary situations.   Session purpose Introduce participants to a way of looking at risk from a different perspective, as a force for change and progress, if managed well. Demonstrate that risk is something we need to engage with emotionally as well as physically, if we want our risk management efforts to be successful. This purpose will be achieved through an entertaining and engaging presentation, using photos and case studies. The session will initiate interest to explore new ways of thinking about risk and generate discussion about the balance between people and systems. What is the right balance and why getting it right enhances the safety culture, while getting it wrong can impact on safety, business performance and sustainability.

Jun 1, 2010

By Ruiqing Li

It is possible to purify some liquid metals by exploiting the difference between the vapour pressure of the bulk metal and the minor constituents or impurities. The rates of purification can be improved by carrying out the process under reduced pressure, that is, so called, vacuum. Some commercial examples of vacuum refining are the purification of molten tin to eliminate trace amounts of lead and the refining of cobalt, also to remove lead. The objective of this paper is to review the basic theory behind vacuum refining technology in order to show how the feasibility of vacuum refining can be determined simply for a particular system by evaluating Olette's Volatility Refining Criteriont.

Jan 1, 1991

By G. H. Enzian

W. C. Ellis—The intergranular fracture observed by these authors in brass seems to be characteristic of metals when tested under similar conditions. It has been observed by us in room temperature tests on lead alloys subjected to constant stress when the stress has been low enough to afford a small strain rate. If, however, the test be carried out at a high stress and therefore at a large strain rate, a characteristic, tapered, transcrystalline fracture is obtained. The same change of fracture has been observed by others with decrease of strain rate and increase of temperature for other metals—for example aluminum—and may be presumed, as the authors point out, to be general for metals. These findings suggest a plastic flow mechanism under conditions of small strain rate and high corresponding temperature differing from classical block slip. The required conditions point to a process fundamentally diffusive in nature—a less organized process than block slip. Nabarro18 has shown that plastic flow can occur by stress induced diffusion of vacant sites— a process of self-diffusion. Movements of a pseudo-viscous nature at grain boundaries are suggested in the work of Ke.15 Deformation near to a grain boundary by other than a slip mechanism appears necessary to Boas and Hargreaves.19 Wood and Rachinger20 report a cellular structure in slowly deformed alumi- num—the cell size is larger, the higher the temperature and the slower the strain rate. Presumably in the latter case diffusive movements occurred in the cell boundaries. In any case the nonslip mechanism seems somewhat obscure and further work is indicated. Such studies will undoubtedly clarify the nature and behavior of lattice imperfections—the very core of the strength and plastic properties of metals. F. H. Wilson and E. W. Palmer (authors' reply)—It is certain that the metallic behavior which has been termed "creep" includes many interdependent phenomena of which a nonslip type of plastic flow may well be one. The reports to which Mr. Ellis refers are illustrative of the many different observations that must be correlated for a complete understanding of creep. The list could be extended considerably. For example, we ourselves have been impressed by the sensitivity of creep phenomena to the presence of minor impurities and feel that this aspect of the problem warrants more thorough study than it has yet received. References 18 F. R. N. Nabarro: Report of Bristol Conference on Strength of Solids. P. 75, (1948) London. 19 Boas and Hargreaves: Proceedings Royal Society. (1948) 193. 89. 20 wood and Rachinger: Journal Institute of Metals. (1949) 17, 237.

Jan 1, 1951

By Shuoshi Lu

The Cu-Co ore studied here belongs to the oxide type. The oxidation rates of copper and cobalt are69.30% and 78.78%, respectively. The content of Cu in ROM is 1.34% and that of Co is 0.096%. The ore contains 4.64% carbon.Based on the process mineralogy and previous metallurgy tests, the principalprocess flow-sheet of ?grinding fines 80% -0.074mm, sulphide flotation followed by oxide flotation, and flash flotation for oxides? has been determined.The handling of carbon is determined through tests. The depressant PNL-1 depressed carbon effectively, improved the recovery of sulphide minerals and reduced the reagents consumption.The operation of the flow-sheet was also changed to better at the same time. Keywords: Cu-Co oxide ore, process mineralogy, carbon depression, efficient depressant of carbon

Sep 1, 2012

By John D. VandeKraats

Yielding rock bolt systems have been developed to provide ground support while accommodating shifting, creeping, or swelling ground movements. The Dywidag Systems, Inc. (DSI) Slip Nut System is one such system. It has been tested in the laboratory and installed and monitored in the interbedded halite and anhydrite at the Waste Isolation Pilot Plant (WIPP) since 1994. The Slip Nut System is installed on a point anchored threaded bar or on a threaded bar coupled to a cable bolt. At a pre-engineered load the nut acts as a die and cuts through the thread on which it rests, thereby reducing the load and coming to rest on the next thread where the process repeats. Two types of laboratory tests were performed using slip nuts on DSI's threaded bars and their Tensionable Cable bolts. Straight pull tests exceeding 0.3m (1 ft.) of displacement were performed on the systems. Also, offset tests were performed on these bolt systems in a test frame designed to simulate WIPP geologic conditions. A room scale test area consisting of 186 threaded bars began in 1994. Select bolts were instrumented to track bolt load. All bolts were tracked through time for operation. Through three complete years since installation over twelve slips, corresponding to approximately 0.15m (6 in.) of ground movement, have been observed in some areas. Since installation strata offset has exceeded 0.08m (3 in.) at a supported clay layer in the roof. No bolt failures have been observed. Slip loads observed underground generally approximate those observed in the lab. To date, the slip nut systems tested and installed have performed as expected.

Jan 1, 1998

By H. C. Cooke

Geological examination of the underground workings of the Horne and Aldermac mines during the summer of 1927 has brought out the following facts: (1) That the ores tend to replace bodies of breccia or tuff rather than massive lava or dyke material; (2) That the faulting and folding at the Horne has had a pronounced effect in localizing the ore-bodies; (3) That there is a tendency in cert?-in cases for ore-bodies to be localized beneath gently dipping dykes, which acted as impervious roofs; (4) That there is a great difference in age between the chalcopyrite part of the ore-bodies and the pyrite-pyrrhotite portion. A statement of the development to date at the Aldermac mine is also included in the paper. ALDERMAC MINE The Aldermac property is made up of eight claims in the western half of Boischatel township, Quebec, including 747 acres in all. The mine itself is approximately three miles, 25 chains from the west boundary, and four miles, 55 chains from the north boundary, of the township.

Jan 1, 1928

By William J. Shampine

This map shows general trends of the chloride concentration of water in the upper part of the Floridan aquifer. Below this part of the aquifer, high chloride water can be found everywhere in the State. The accompanying cross section shows the depth to salty water across central Florida. In the center of Florida, fresh water may be found as deep as 2.000 feet, whereas, along the coast it may extend no deeper than about 200 feet. Chloride concentration in small local areas may deviate from the values represented on both the cross section and the main map. This map shows general trends of the chloride concentration of water in the upper part of the Floridan aquifer. Below this part of the aquifer, high chloride water can be found everywhere in the State. The accompanying cross section shows the depth to salty water across central Florida. In the center of Florida, fresh water may be found as deep as 2.000 feet, whereas, along the coast it may extend no deeper than about 200 feet. Chloride concentration in small local areas may deviate from the values represented on both the cross section and the main map.

Jan 1, 1966

By D. W. Olson

The estimated value of natural gemstones produced from U.S. deposits during 2004 was $12.9 million. This was a 3-percent increase from that of 2003. U.S. gemstone production included agates, amber, beryl, coral, garnet, jade, jasper, opal, pearl, quartz, sapphire, shell, topaz, tourmaline, turquoise and other gem materials. More than 60 varieties of gemstones have been produced commercially from U.S. mines. But commercial mining of gemstones has never been extensively undertaken in the United States. Most of the deposits have been relatively small compared with other mining operations. In the United States, much of the current gemstone mining is conducted by collectors, gem clubs and hobbyists rather than business organizations.

Jan 1, 2005

This is the eighth in a series of reports en properties of commercial meter fuels, made in accordance with a cooperative agreement between the Cooperative Fuel Research (C. F. R.) Committee and the Bureau of Mines of the United States Department of the interior. The first report gave data en meter gasolines sold during the winter of 1935-36.3/ The present report, covering 1,679 samples, represents the products of 118 companies plus these from the Pacific coast, which were averaged by the Pacific Coast Technical Group before being submitted and are published exactly as they were submitted. The throe groups of data en samples of regular, premium, and third-grade gasolines arc averaged separately. The number of samples and brands representing each grade are as follows: Regular price, 869 samples, 76 brands; premium price, 452 samples, 45 brands; third-grade, 358 samples, 82 brands. In this report the same marketing districts are retained as were used in the preceding report, and as far as possible the actual sampling points in each area arc indicated on table 1.

Jan 1, 1940

By Witold M. Pytel

A simplified, three-dimensional, time-dependent, mechanistic model of the overburden-coal seam-floor interaction has been developed and validated at two Illinois coal mines. The model based on the thin plate theory can involve any complex layout of mine workings, time-dependent sequence of extraction and, rheological properties of immediate floor strata. The model output data consist of spatially distributed surface subsidence and its slope and curvature, as well as load acting on pillars in one or more panels. A comparison of calculated and monitored surface subsidence or in-mine convergence measurements has proven the model's effectiveness for surface subsidence and load transfer prediction.

Jan 1, 1992

By C. W. MacLeod

LOCATION The Goudreau gold area in Ontario extends from a point a short distance south of the main line of the Canadian Pacific railway, at Lochalsh, in a south-westerly direction to the Magpie river. It crosses the Algoma Central & Hudson's Bay railway at Goudreau station, 177 miles north of Sault Ste. Marie. The area is roughly 25 miles in length by 6 miles in width. The potential gold formation is much more extensive but little prospecting has been done outside of the limits mentioned. The actual continuous area of Keewatin formation, in which gold has been found, is one of the largest in Ontario. ACCESSIBILITY Probably no mining area in a similar stage of development has had the excellent transportation facilities which Goudreau enjoys. This field is traversed in part by the main lines of the Canadian Pacific and Algoma Central railways. The Provincial Government has constructed 22 miles of road through the heart of the camp. Sixteen miles of this road is suitable for motor car traffic and several cars and trucks are in constant service.

Jan 1, 1926

By Pengbo Chu, James Finch

Bubbles around 1 mm diameter provide the high interfacial area for capture and transport of hydrophobic particles in flotation. The formation of such fine bubbles is commonly achieved by addition of frothers that appear to simultaneously retard coalescence and promote break-up. High inorganic salt content in process water can substitute for frother. In this work we focus on the action of salt (sodium chloride) on formation of bubbles by break-up. An experimental setup that isolates break-up from coalescence was employed. A pocket of air is exposed to controlled mechanical turbulence to produce single bubbles by the induced deformation of the air and the events imaged. The presence of salt is shown to produce smaller bubbles than in water alone. Comparison with a similar study on frothers is made. The argument is advanced that the presence of frother and salt creates surface tension gradients at the air/water interface which add to the mechanical energy of the deformation and break-up process.

Jan 1, 2014

By Colin Dessemond

Since 1950, the traditional process has been dominating the production of lithium compounds from spodumene ores to sustain the lithium market because of its economic viability and the markets need for technical grade (99.5% purity) product. This traditional process includes thermal conversion, acid roasting and lithium leaching. However, this process has not been challenged and very few studies have tried to explain its limitation (95% lithium yield) or optimize the thermal treatment. Here, α to β spodumene conversion and lithium extraction were performed in a rotary kiln on a 2 mm to 2 cm spodumene concentrate instead of a micrometric one using a 1050 °C, 30 min conversion treatment and 250 °C, 30 min, 30% H2SO4 excess leaching treatment. X-Ray Diffraction analyses were performed on the converted material to determine the conversion rate by Rietveld analysis. It was observed after thermal treatment that the α-spodumene particles fractured and divided while the impurities remained compact. A sifting was performed after thermal treatment and it was determined that 65% of the initial mass became finer than 180 μm. X-Ray diffraction analyses and lithium content measurement were performed on both fractions and it was determined that the finer fraction had a very high lithium content of 3.24 wt%. Lithium extractions were performed on both fractions separately. While the coarser fraction’s lithium yield was only 61% the finer fraction’s lithium yield went up to 99% without any additional treatment. These observations may open more economical ways for the traditional process by potentially bypassing two third of costly steps such as grinding.

By A. M. Elmahdy, T. Hirajima, M. Farahat

"Separation of molybdenite from chalcopyrite is mainly achieved through flotation technique to raise their grades up to 25% to be extracted in smelters. However, molybdenite recovery and grade obtained from this process is not satisfactory in most cases due to the natural hydrophobicity of both minerals. The influence of conventional heat treatment on pure chalcopyrite and molybdenite minerals was investigated. X-ray diffraction, TG-DTA and XPS techniques were applied before and after heat treatment. The results showed phase changes for both minerals. Magnetic separation experiments of single and mixture of both minerals at several magnetic intensities were made. For single mineral experiments, 100% molybdenite recovery was obtained at all experimental conditions as non-magnetic fraction whereas ca. 100% chalcopyrite recovery was achieved under certain conditions. In case of 1:1 binary mixture, 87% and 83% molybdenum and copper recoveries, respectively, were obtained. The increase in chalcopyrite magnetic recovery is related to the formation of more magnetic phases as confirmed by characterization techniques.The objective of this study is to increase the magnetism of chalcopyrite to make its separation from molybdenite by magnetic separation possible and to understand the mechanism behind it. These results indicate that it may be possible to upgrade molybdenite ores using heat treatment followed by magnetic separation to the required grade by smelters which is difficult to attain by froth flotation and the other techniques."

Jan 1, 2016

By Florian Kongoli

New operating conditions and process parameters are often necessary in today's industrial practice of non-ferrous smelting and converting in order to accommodate various new chemical compositions of mineral charges and environmental requirements or to conceive new and more efficient industrial technologies. An important parameter in non-ferrous smelting and converting is the liquidus surface of multicomponent slags. This surface is affected by multiple factors such as temperature, gaseous potentials, the content of each component in the slag, etc., and cannot be quantified by the existing ternary liquidus diagrams. In this work a new type of representation of the liquidus surface of multi component systems has been presented by means of a thermodynamic model. This representation waives the need of the multidimensional representation of multi component systems and yields practical two-dimensional diagrams, which can be easily used in the industrial practice.

Jan 1, 2000