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By A. Koizhanova

Kumistinskoye gold- and silver bearing ores (Republic of Kazakhstan) as well as standardized test solutions containing gold, silver, copper, zinc and iron were studied. The best results in silver and gold recovery from Kumistinskoye gold- and silver bearing ores were achieved through use of complex cyanide-thiosulfate solutions as compared to individual cyanide solutions and thiosulfate solutions. It was found that such complex solutions substantially step up leaching process herewith increasing precious metals recovery rates. Thermodynamics of studied chemical processes was calculated. Reaction order, kinetic constant and activation energy of gold leaching process through use of cyanide-thiosulfate solutions were identified. We managed to prove that the sorption rates and holding capacity in process of gold anions recovery with anionite AM-2B are comparable to sorption characteristics for cyanide solutions. Keywords: gold, silver, copper, zinc, iron, cyanide-thiosulfate solutions, anionite AM-2B

Sep 1, 2012

By L. H. Robinson

Triaxial compression tests on Indiana limestone indicate that chemical additives in the pore fluids can increase or decrease the strength in plastic failure but not in brittle failure. Tests using a series of the sodium salts of dicarboxylic acids show that odd-number carbon-atom chains decrease the yield strength as much as 3.0 x 10 3 psi, and even-number carbon-atom chains increase the yield strength as much as 9.0 x 102 psi. ,The most effective chemical (sodium citrate) decreased the yield strength of Indiana limestone from 16.0 x 103 to 12.0 x 103 psi. The chemical additives investigated have no influence on microbit drilling rate when drilling with zero differential pressure. However, when drilling at a 2.0 x 103-psi pressure differeniial and using an odd-number carbon chain compound as the circulating fluid, the roller bit drilling rates were slower than with water whereas the drag bit drilling rates were faster. One even-number carbon chain compound added to the circulating fluid produces the opposite effect: the roller bit drilling rate is slightly faster than with water and the drag bit slower than with water. INTRODUCTION A Russian book by Rehbinderl published in 1944 generated much interest in the possibility of aiding and accelerating the destruction of solids by the action of a liquid in which the solids are deformed. This book describes a process in which microcracks are generated during elastic deformation. To describe this process, the rock is divided into three zones: (1) the zone in which the destruction takes place, (2) the predestruc-tion zone (an affected area immediately below the destroyed zone) and (3) the undisturbed specimen. Consider a load applied normally to a surface of an infinite slab of rock. Immediately below the point of application of the load, the rock is destroyed by compression or shear forces. Below this area of destruction, because of a great number of discontinuities ranging from defects to weak points in crystals of discontinuities in crystal latices, very small cracks are created in or between the crystals (often referred to as microcracks). Upon removing the load, the broken rock in the destroyed zone could be removed. In the lower predestruction zone, however, the microcracks in and between the crystals could disappear by the process of rehealing, i.e., the molecular attraction from one side of the crack to the other side being sufficient to completely eliminate the crack. Thus, a large number of these microcracks possibly exist only for a relatively short period of time. The concept of small cracks being generated within the crystals of a rock is not unreasonable. If the rock matrix is deformed below the yield point, some of the defects present within the crystalline structure could start small cracks through the interior of the grains. Upon removal of the load, these microcracks reheal (or the newly generated surfaces come back together) so that all evidence of cracks completely disappears. Under various types of loading, and in various types of fluids, the rehealing of these cracks would be time dependent. If a liquid adhered to the surface of a rock, it could penetrate into the microcracks and thus delay or prevent the rehealing process. This suggests that the prevention of healing of the microcracks may be dependent upon the wetting characteristics of the solid. Thus, rocks which are water-wet should be more easily destroyed in water than in nonpolar hydrocarbon liquid. Adsorption of a liquid could also reduce the free surface energy which could explain the decrease in strengths of materials under nonrepetitive-type loading. Rehbinder's work prompted Boozer, Hiller and Serdengecti 2 to examine the effects of pore fluids on the deformation of rocks subjected to triaxial compression over a range of confining pressures, temperatures and strain rates. Fluids which strongly adsorbed on the rock grain surfaces decreased the strength of sandstone and limestone, which deformed plastically. For certain strain

By Donald S. Macdonald

"I AM thankful for this opportunity to address the Toronto Branch of The Canadian Institute of Mining and Metallurgy. The Members of your Institute can have a great influence on the direction in which the mineral policies of Canada will evolve, and to assure that optimum benefits from our country's vast mineral resources will accrue to the nation as a whole and to all its citizens. Today, I want to: (1) offer an outlook on the mineral industry for 1973; (2) talk briefly about the role of minerals in the total economy; and (3) outline some of our thinking with respect to a national minerals policy for Canada."

Jan 1, 1973

By R. B. Harkness

Many of us are familiar with the history of oil in the Province of Ontario, but for the benefit of those who have never heard the story I will repeat it. In 185 7 J. H. Williams, of Hamilton, an old-country Scotchman, who had the advantage of experience gained from the primitive methods used for refining the oil collected at seepages in Roumania, heard of the "gum beds" along Black creek in Enniskillen township, Lambton county. He erected a small plant in the bush and refined illuminating oil, where the village of Old Springs now stands. The labor of collecting this thick ?gummy substance from the sluggish water of the creek, prompted him to dig a well, the next year ( 1858), in the hope of obtaining a greater quantity. When his excavation reached a gravel bed on top of the rock, oil, resembling "lubricating oil of commerce", rose several feet. Several of these wells were dug and his refining business flourished. The following year the Drake well, in Pennsylvania, was drilled into rock, resulting in an oil find which encouraged one James Shaw to make a similar attempt on Black creek. With a spring-pole drill he completed his well in the spring of 1861 to a depth of 160 feet, and at that depth struck a gusher that flowed uncontrolled for several days. Great excitement followed and the village of Oil Springs had a mushroom growth. The Petrolia field was discovered in 1865. Lick followed up the Thames with a spring-pole rig testing the formations along that river and discovered the original Bothwell field in 1865. During the sixties wells were drilled in many counties in southwestern Ontario.

Jan 1, 1924

By S. S. Clarke

Late in 1942, the increasing demand for zinc, coupled with the growing shortage of miners and the knowledge that some abandoned mines would have to be reopened for prospecting and development, led to considerable thought as to the possibilities of further mechanization in order to conserve man power. The ore bodies, locally termed "sheet ground," are an important ore bed in some mines and are in the lower part of Boone formation of the Mississippian Series. Some mines contain interbedded layers of nearly pure galena and sphalerite in horizontal sheets ranging in thickness from a thin seam to several inches and is persistent over large areas. This type of ore body offered the best opportunity for study and experiments. The use of Jumbo drill carriers was advanced but some doubt was expressed as to the adaptability of Jumbos as then in use to mine headings as compared to post and arm mounting (Fig I). Another consideration was the introduction of truck haulage when several mines were trackless. A drill frame, built to carry 2 4-in. drifters, was mounted on a truck chassis. This design proved a failure as it was not rigid and the resiliency of the tires and springs allowed too much play. Long screw jacks were then used to hold the truck firmly in place, but placing the jacks and securing the truck required more effort and time than setting up post drills, so the truck carrier was abandoned. The use of a bull dozer underground had been under consideration for some time to be used in "brunoing" the broken dirt from behind pillars and other inaccessable places so the slusher drags could load without double dragging the dirt. A dozer with hydraulic blade lift was purchased and R. I. Tuthill, Superintendent of Section 30 Mines, suggested that a long drill arm be substituted for the blade, and the drills mounted on the cross member. The hydraulic lift would permit drilling holes at any required spacing. The "cat" was very mobile and answered the problem of a trackless mine. The initial tests showed that the "cat" would make a good carrier, but the hydraulic controls were not positive enough to keep the drills in alignment while drilling. The next step was to build a small hoist. This hoist was attached to the power take-off on the "cat" and by means of sheaves and a double line of 3/8-in. hoist cable, a positive control for raising and lowering the boom was obtained. To avoid serious injuries to the drillers should the cable break, a safety chain was fastened to the drill boom and hooked into a slot in the back of the "cat" frame. A different power unit was obtained for the "cat," as a state law prohibited the use of internal combustion engines in mines. A custom machine shop had just placed on the market a small hoist powered by a Model A Ford engine that had been very ingeniously converted to a slide valve engine using compressed air. To use this unit on a "cat," our master mechanic de-

Jan 1, 1949

By Wataru Inagaki, Kozo Kawano, Tetsuya Ando

Cu–Ni–P alloys are the typical precipitation-hardening material. Thus, Cu–Ni–P alloys is expected to apply alternative materials for heat-exchanger tubes. Therefore, it was investigated that the effect of the heat-treatment simulated brazing on mechanical properties of Cu–Ni–P alloy in this study. The hardness of specimen as heat-treatment simulated brazing after solution heat treated (sht) was shown approximately 105 HV. The peak hardness and tensile strength of the specimen as performed aged at 498 K for 43.2 ks following the heat-treatment simulated brazing achieved at approximately 140 HV and 260 MPa, respectively. From these results, it is expected the application to higher-strength tube for heat-exchanger after brazing in a furnace. INTRODUCTION Copper prices have increased dramatically with high in recent years. At the same time, manufacturing industries are required to reduce the environment load by reducing the wall thickness of the copper tubes used in heat exchangers. High-strength copper alloys are developed for reducing the wall thickness, while achieving high strength, of the copper tubes. Moreover, excellent workability and corrosive durability are also required by these copper tubes. Furthermore, the brazing, which are carried out at about 1050 K during the assembly process of heat exchangers, leads to grain growth and re-solving of additive elements. Nomura et al. achieved a tensile strength and Vickers hardness of approximately 260 MPa and 110 HV, respectively, after aging at 723 K for approximately 36 ks. Tamagawa et al. studied that the strength of Cu–Ni–P alloy rapidly increased at about 125 HV during the cooling process after the heat brazing due to the Ni2P precipitates sized 5–10 nm. Furthermore, Inagaki et al. achieved a Vickers hardness of approximately 130 HV by aging at 498 K for 10.8 ks. In the present study, we focused on the lowest aging temperature of 498 K in the previous study, and investigating the effect of heat-treatment simulated brazing on the mechanical properties of the Cu–0.93 mass%Ni–0.24 mass%P alloy.

Jan 1, 2019

The Cleveland Mine has an annual ore production of 400,000 tonnes at a grade of 0.79 per cent tin and 0.30 per cent copper. It is achieved by an open stoping method, mechanised overhead sub-level benching. The operation is trackless with a ramp access from all working places to the surf- ace. Broken material is loaded from the stope and development headings into diesel trucks and hauled to the surface crushing plant.

Jan 1, 1977

By Phillip N. Yasnowsky

The thrust of this Bureau of Mines report is to relate the size of automobiles to the price of gasoline, and the use of minerals in automobile manufacture to the size of automobiles. Only one of the many plausible scenarios of public reaction to higher gasoline prices, a switch to economy size automobiles, is developed. No account is taken of other potential impacts such as improvements in public transportation or increased occupancy per vehicle. Furthermore, a gasoline price increase is the only incentive to the greater utilization of economy cars that is considered. A gasoline price increase to $0.60 per gallon would reduce the amount of minerals required to produce the automobiles sold in the United States by an estimated 15 percent. Gasoline prices of $0.80 and $1 per gallon would cause declines in mineral requirements for U.S. automobile sales estimated at 26 percent and 35 percent, respectively.

Jan 1, 1974

By H. R. Maggard, C. M. Bollinger

Solving the problem of detecting underwater explosions from "dynamite fishing" can be done by using a system of sonobuoys programmed to detect the acoustic waves from underwater explosions. The system includes three anchored sonobuoys, which have radio communication to a central station. Each sonobuoy will detect the direction the blast occurred, and then send the magnitude of the acoustic waves and the blast direction to the central station where the blast distance will be calculated. The central station can the send the coordinates to the authorities who can find the location using GPS systems onboard their boats.

Jan 1, 2004

By A. -M. Cadieux

During the geological synthesis of the Réservoir Pipmuacan area (NTS 22E) by the Ministère des Ressources naturelles (Québec), several ilmenite-apatite occurrences, some well-known and some recently discovered, have been examined. These occurrences are hosted in the Lac-Saint-Jean and Labrieville AMCG anorthositic suites. The Lac-Saint-Jean Anorthositic Suite (1160-1140 Ma), composed of multiple intrusions covering an extensive surface area, is characterized by labradorite plagioclase. The Labrieville Anorthositic Suite (1010-1008 Ma) is characterized by andesine plagioclase. It was previously known as the Labrieville Anorthosite, which was composed of a small isolated pluton located east of the Lac-Saint-Jean Anorthositic Suite. However, new geochronological data and field observations indicate that the Labrieville Anorthositic Suite in fact includes several intrusive bodies, namely the La Hache Monzonite and the Mattawa Anorthosite. A series of major structures (Saint-Fulgence, Pipmuacan, and Chute-des-Passes deformation zones) and their conjugate faults played an important role in the emplacement of the Lac-Saint-Jean Anorthositic Suite. The Saint-Fulgence deformation zone appears to have been involved in the emplacement of the Labrieville Anorthositic Suite. Oxide mineralizations are abundant in both anorthositic suites. Ilmenite, magnetite (± titaniferous), and apatite assemblages are found mostly in the labradorite-type anorthosites, while hemo-ilmenite, magnetite and apatite assemblages are associated only with the andesine-type anorthosites. Field works has revealed ilmenite-apatite mineralizations in a variety of settings, with grades reaching 48% TiO2, 16.2% P2O5, and 71.7% Fe2O3 (tot). Numerous oxide-bearing gabbronorites, often accompanied by or located near massive apatite-oxide accumulations (nelsonites), were discovered. Among these oxide-rich zones, breccia zones with anorthosite enclaves in an oxide matrix (ilmenite-magnetiteapatite) have been observed. Locally, ilmenite-apatite mineralization occurs as cumulate concentrations in ultramafic rocks. Evidence has been observed for immiscible magmas, for magmas differentiated from a mangerite or jotunite parent, and even for late magmas differentiated from the anorthosite magma itself (apatite-bearing anorthosite). Finally, the northern part of the Lac-Saint-Jean Anorthositic Suite hosts sulfide and vanadium mineralizations associated with ilmenite-apatite enriched zones, with grades reaching 1.48% Cu, 1.22% Ni, 1.6% Cr2O5, 0.25% Co, and 0.52% V2O5.

May 1, 2003

By Robin J. Batterham

We still need to innovate, but it is getting harder. The real price of metals is declining, return on shareholder value is lower than other industries, and there is a shorter-term focus on staying viable in a capital-intensive industry where timeframes for implementation of new technologies can be long (+I5 years). In this environment, the levels of R&D spent by major minerals companies are remaining steady at around 0.2%-0.5% of revenue. This is not large and to remain viable in the future, we need to be smarter about the way in which we do R&D. The mining industry is a knowledge-based industry. Driving down the cost curve demands innovation, which demands knowledge. To be smarter and more effective in our approach to innovation, a new paradigm is required Generating, capturing and using knowledge has evolved from Mode 1 (discipline based and clear distinction between basic and applied research) to Mode 2 (multidisciplinary, team-based approached with flow between basic and applied activities). Mode 2 is now seen to be much more efficient and to deliver better appropriability (Tegart 2003). To survive, we need to innovate, and the best way to do this is collaboratively. Some examples and pointers for the future will be given in this paper. THE CURRENT SITUATION The Rand report and other recent studies have painted a grim outlook for the mining industry. The real price of metals continues to decline (Figure 1) and profit margins remain thin. This is reflected in shareholder returnwhich are well below other industries (Figure 2)-and current management strategies-which reflect something of a "survival mode." The current focus for most mining companies is on short-term, incremental gains

Jan 1, 2004

By M. Abumiya, N. Onodera

Stabilization of arsenic via the precipitation of large-sized scorodite (FeAsO4·2H2O) particles usually involves the use of expensive autoclave systems operated under high temperature and pressure conditions. Alternatively, DOWA developed a novel scorodite synthesis process (DMSP®) wherein the Fe(II) ions in solution containing As(V) ions were oxidized by O2 gas under atmospheric pressure. In this process, crystalline scorodite particles were formed via the formation of a gel-like precursor containing Fe(II). Based on this concept, in this study, we have demonstrated the synthesis of scorodite particles by the addition of Fe(III)-containing solution to the experimental solution containing Fe(II) and As(V) ions, without the O2 gas oxidation process. Ferric sulfate (Fe2(SO4)3) was used as the source of Fe(III) ions. Results indicate the precipitation of scorodite particles, comparable to that of the O2 gas oxidation method.

Jan 1, 2014

By W. P. Diamond, B. M. Bench, C. M. McCulloch

Coalbeds exhibit a directional permeability, with the maximum permeability oriented parallel to the face cleat. Thus, the most efficient pattern of vertical degasification holes for a coalbed is dependent upon cleat orientation. Surface joints, infrared photolinears, and Ronchi grating photolinears were investigated as potential estimators of subsurface cleat orientation. Cleat orientations were masured in 18 mines, in the Pittsburgh coalbed in southwestern Pennsylvania and northern West Virginia to be used as a standard against which prediction techniques would be evaluated. Two cleat systems with a strong geographic segregation were measured in the study area: N 67° W - N 28° E (95° separation) for the north, and N 76° W - N 17° E (93° separation) for the south. Directional data obtained from the three techniques investigated yielded satisfactory regional predictions of cleat orientation. Analysis of surface joints was the only technique considered sufficiently reliable on a local basis. Prediction of cleat orientation is based on the pairing of the principal directional sets into all reasonable combinations of fundamental systems. The system or systems composed of the most dominant sets nearest to 90° separation are likely to be a reliable prediction of cleat orientation. The most dominant set of the system selected is likely to be the face cleat.

Jan 1, 1976

By M. Mortada

Nonsteady-state flow of slightly compressible liquids in porous media of non-uniform properties has been the subject of a number of recent studies. Most of these studies considered one-dimensional flow in systems with cylindrical geometry and with the properties of the porous medium varying with radial distance only. A. Houpeurt' studied the problem in its general form by examining the solutions of the differential equation, In Eq. 1, the permeability k and the porosity + are arbitrary functions of radial distance. Houpeurt concluded that, except for special forms of the functions k and the problem is not well suited for mathematical treatment, but lends itself to high-speed digital computation. Carslaw and Jaeger' discussed the solution of Eq. 1 for the case in which the permeability varies as a power of the radial distance. P. Albert3 studied analytically the pseudo steady-state solutions in systems of finite radial extent and non-uniform properties. He also obtained some numerical solutions for nonsteady-state flow using a high-speed computer. William Hurst4 examined the interference pressure drop due to a point sink located in an infinite system consisting of two permeability regions in series. In this case, the permeability changed at a radial distance r from the point sink. INTERFERENCE BETWEEN OIL FIELDS IN A NON-UNIFORM AQUIFER The interference pressure drop for oil fields located in an extensive aquifer of uniform properties is discussed in a number of places in the literature. This work considers the interference pressure drop for oil fields located in a non-uniform extensive aquifer comprising two regions of different properties as shown in Fig. 1. Region I of the aquifer extends from which is the radius of Oil Field A, to ar,,, where a>1. It has permeability k,, porosity +, and effective compressibility c,. Oil Field B is located in Region II which extends from ar, to infinity and has different properties from those of Region I, but the same formation thickness h. Region II has permeability k2, porosity and effective compressibility c2. The choice of this type of aquifer should not imply that it is of frequent occurrence. It is chosen primarily to illustrate the effects of non-uniform aquifer properties on oilfield interference. It is of interest to point out that a non-uniform radial aquifer in which both the permeability and the porosity are inversely proportional to the radial distance can be treated in a manner similar to a linear aquifer of uniform properties. The situation where only the permeability varies as the inverse of the radial distance is also amenable to analytical treatment. Both aquifers behave quite differently from a radial aquifer with uniform properties so far as the water influx and the interference pressure drop are concerned. METHOD OF SOLUTION The expression for the interference pressure drop in Oil Field B due to a constant rate of water influx in Oil Field A is developed in the Appendix. This is accomplished by the simultaneous solution of two partial differential equations describing the pressure in Regions I and 11. The two differential equations are solved subject to the following conditions: (1) at r,, the pressure gradient is constant; (2) at ar the pressure and

By S. Kahraman

The correlations between the modulus ratio and penetration rate of rotary and percussive drills were statistically investigated using the raw data obtained from the experimental works of different researchers. An inverse power law was found between the modulus ratio and the penetration rate of rotary and diamond drills. The penetration rate of rotary drills and diamond drills decrease with an increasing modulus ratio. The penetration rates of percussive drills increase with an increasing modulus ratio. There are significant linear correlations between the penetration rates of percussive drills and the modulus ratio. In one of the cases of percussive drilling, a strong correlation between the penetration rate and the modulus ratio was found for the rocks having a porosity value lower 1.23 %. It can be concluded that the modulus ratio might be a representative measure of rock drilling efficiency. However, further study is necessary to check the validity of the derived equations for other rock types. The effect of porosity on the correlations between the modulus ratio and penetration rate needs to be further investigated.

Jan 1, 2003

By W T. Pate, A V. Potapov, J K. Lichter

Even though flotation is one of the most important unit operations of mineral processing, accurate modelling of this process for plant performance prediction has remained elusive. In the last four to five years dramatic changes have occurred in our ability to make credible model based predictions. This paper briefly traces the history of flotation modelling from simple (lumped pulp-froth) æchemical kinetic analogueÆ models for single cells to more detailed multi-phase, multi-component population balance models for banks of cells. It then focuses on recent developments in physics-based modelling tools. This includes current efforts to model the forces of attachment and detachment at the individual event level as well as multi-event levels in individual cells and circuits. Two examples of these tools are presented. The first is DEM modelling of the mechanics of motion of bubbles in froths. The second is population balance modelling of the dynamics of flotation circuits describing how they are influenced by upstream processes (such as crushing and grinding) as well as internal process variables (such as aeration, agitation and reagent addition). Applications of each of these tools are discussed.

Jan 1, 2005

By R. Pandher, R. Schonewille, N. Tripathi

Advanced process modelling tools were developed for the Xstrata Nickel Sudbury Smelter flow sheet using a combination of FACTSAGE TM METSIMTM and ARENATM software. These tools were employed to assist with plant optimisation, emission control, process design, troubleshooting and case studies as applied to the smelter. The development of process modelling tools in pyro-metallurgy commonly involves an in-depth study of the therm o-chemical properties (heat capacity, liquidus temperature, etc.) of all high temperature phases, usually matte and slag. The preferred tool for this purpose is FACTSAGETM, a well-known then-no-chemical modelling software package. The results from the therm o-chemical model have been subsequently incorporated into the development of a process model for the entire smelting facility using the METSIMTM platform. Such process model also includes a number of special features adopted to effectively simulate the complex industrial phases; matte and slag systems. To ensure the robustness and reliability of the process model, several process parameters and assumptions were verified with laboratory and plant data. Consequently, the model includes the ability to examine the impact of a number of plant parameters on potential plant performance. Primary variables are the percent sulphur elimination during concentrate roasting, furnace matte grade and degree of matte metallization. Key output parameters include operating temperature, furnace coke requirement, sulphuric acid production, CO2 emissions and overall energy requirements. Selected outputs from the process model (for example blowing time, slag production rate and matte converting rate) can then be utilised in the development of a discrete event model (DEM) for the smelter using ARENATM software. Incorporation of reliable and validated mass balance parameters enhances the robustness and reliability of the DEM model. The integration of then-no-chemical, process and DEM modeling tools has a distinct advantage in planning plant trials and examining process design initiatives at Xstrata Nickel's Sudbury Smelter. The present paper discusses the development of these three models and the synergies existing among them. Typical results from all three models are also presented.

Jan 1, 2011

By R. Pandher, R. Schonewille

Advanced process modelling tools were developed for the Xstrata Nickel Sudbury Smelter flow sheet using a combination of FACTSAGETH METSIMTM and ARENATM software. These tools were employed to assist with plant optimisation, emission control, process design, troubleshooting and case studies as applied to the smelter. The development of process modelling tools in pyro-metallurgy commonly involves an in-depth study of the therm o-chemical properties (heat capacity, liquidus temperature, etc.) of all high temperature phases, usually matte and slag. The preferred tool for this purpose is FACTSAGETM, a well-known then-no-chemical modelling software package. The results from the therm o-chemical model have been subsequently incorporated into the development of a process model for the entire smelting facility using the METSIMTM platform. Such process model also includes a number of special features adopted to effectively simulate the complex industrial phases; matte and slag systems. To ensure the robustness and reliability of the process model, several process parameters and assumptions were verified with laboratory and plant data. Consequently, the model includes the ability to examine the impact of a number of plant parameters on potential plant performance. Primary variables are the percent sulphur elimination during concentrate roasting, furnace matte grade and degree of matte metallization. Key output parameters include operating temperature, furnace coke requirement, sulphuric acid production, CO2 emissions and overall energy requirements. Selected outputs from the process model (for example blowing time, slag production rate and matte converting rate) can then be utilised in the development of a discrete event model (DEM) for the smelter using ARENATM software. Incorporation of reliable and validated mass balance parameters enhances the robustness and reliability of the DEM model. The integration of then-no-chemical, process and DEM modeling tools has a distinct advantage in planning plant trials and examining process design initiatives at Xstrata Nickel's Sudbury Smelter. The present paper discusses the development of these three models and the synergies existing among them. Typical results from all three models are also presented.

Jan 1, 2011

By Charles H. Jacoby

The solution mining of evaporites has a history of approximately 5,000 years. The insitu leaching of metalliferous ore will have many of the same characteristic problems which have confronted industry for years in the production of evaporite minerals. Basically we will be converting the less soluble forms of valuable metals into their more soluble salts and producing these in much the same manner as, for example, sodium chloride. There are a number of problems which we are faced with that are more complex and complicated and, therefore, will require a higher degree of sophistication than previously employed. One of our most important undertakings will be the clearcut definition of the problems involved. While a great deal of expertise can be drawn from the solution mining of evaporites and the oil industry, problems peculiar to the hydrometallurgical field will need to be solved. One of these is the introduction of permeability into an impermeable rock so as to expose the sought after values of metals which by volume are infinitesimal when compared with sodium chloride, potash or other type water soluble mineralization. After establishing this permeability which will be miniscule when compared to a solution cavity, there will be the maintenance of this permeability. In general, salt deposits are of a somewhat uniform chemical composition and thus their chemistry was relatively simple. Each metalliferous ore body is somewhat unique in its chemistry and will need to be treated accordingly.

Jan 1, 1974

By A. Hayatdavoudi, E. Apande

Introduction Troublesome shales have plagued the petroleum industry for more than 50 years. Unstable boreholes have been experienced when drilled into shale formations; sane have been studied almost at the beginning of rotary drilling. A little progress has been made since then, but much is still to be learned. No simple solution exists so far, but good drilling practices combined with good mud practices have been helpful. It is well known that shales in general have a strong affinity for water, and when water is adsorbed, the stability of the shale section of a well is reduced; cohesive strength will be re- bed, properties will be altered and shale will generally expand and/or crumble. The amount of water a shale will adsorb depends on the characteristics of its clay mineral and the ionic concentration of surrounding fluid. Fluid loss and the resulting hydration of an unstable formation can lead to serious downhole problems. The rate of fluid loss depends greatly on the permeability of the deposited cake. In impermeable formations, however, there is no loss of fluid into the formation. As such, shale, because of its very low porosity and almost no permeability, could be termed impermeable. Yet there is strong evidence that shale surfaces are wetted by an invasion of fluid into the formation through microfractures and jointed planes. It is this wetting that causes the shales to swell and slough into the hole, resulting in problems such as increased mud volume and treating costs, bridges and fill-up, stuck pipe, overgauge hole, poor cement jobs and increased cement requirements, and logging and completion difficulties. Drilling operations have been defeated by severe shale problems, resulting in & hole being plugged and abandoned after several weeks of drilling. Shales are we1l known as being difficult and costly to drill. Numerous fishing jobs have plagued drilling operations, and the cost of reaming tight holes ad weighting up the drilling mud to control shale sloughing has been high. The concept of controlling water loss to stop sloughing was introduced in the 1920's. It was known-then that calcium in fresh water re- strains clay £ran excessive swelling (theory of osmosis) . This reinforced the belief that calcium-based muds such as lime, gypsum and calcium chloride should minimize hydration of clays. Lime muds were then introduced for this purpose and others in the 1930-1940 decade1. They were used for shale inhibition but were not effective. In an attempt to improve them, a special calcium-type mud beam popular during the 1950's. Hole enlargement continued and they too were considered ineffective. During & early 1960qs, papers were published claiming that shale swelling could be prevented by using high concentrations of chemical thinner called Chrane Lignosulfonate1. This began the era of highly treated lignosulfote muds. Unfortunately, the hole enlargement problem continued. During & mid-1960’s, oil based muds were used for the purpose of inhibition of shales. Not until 1966 did Mondshine2 suggest that the water phase be saturated with calcium chloride. The cost of using oil based mud was considered by most operators not worth the additional hole stability. The potassium chloride-polymer muds were also used in many fields in the United States and western Canada. The use of these muds has been claimed to prevent clay swelling by inhibition and encapsulation in sane areas of western Canada. They are also expensive and their ueneral application is still experimental. To reduce filtrate loss when sloughing shale becomes a problem during drilling is a reasonable practice. This study will investigate the use of cationic organic additives to mud to form a protective barrier between the shale - which are primarily composed of clays - and water that will keep water from entering the microfractures and will also prevent them from hydrating. In so doing, an understanding of modern clay chemistry and & dispersive properties of cationic additives in water based systems will be our most valuable tools. This study will also present and solve a mathematical model for simulating cation transport phenomena in fractured shales using the Framdlich equilibrium adsorption isotherm. The studies will analyze wellbore failure and stability as affected by cationic organic material.

Jan 1, 1986