Search Documents

By T. Feldmann

Despite the ubiquity of applications for germanium, there is a lack of practically useful solubility data in acidic solutions. Previous studies were done at ambient temperature and only for commonly used acids (H2SO4, HCl). Hence, an investigation of the solubility of GeO2 in different acids was undertaken. Several inorganic and organic acids were studied in the concentration range of 1–11 mol/L and at 23, 40, and 60 °C. In the case of H2SO4 and HCl previous data was confirmed. Lower acidity resulted in a higher solubility for Ge at all tested temperatures. Tests done at 40 and 60 °C and low to moderate acidity levels, gave slightly increased solubility values at higher temperatures compared to 23 °C. This wasn’t the case at higher acidity levels, i.e., the solubility curves at different temperatures converge at high acidity. Lastly, a relationship of water activity and GeO2 solubility in different acid media was established.

By W. J. Langford

"Conventional design criteria assume that the fracture strength of a structural material exceeds its yield strength. Fracture below the design load is not expected, y et many structures have failed in this way. The causes of the fractures are almost always discontinuities such as cracks and welding defects. Linear Elastic Fracture Mechanics (LEFM or simply 'fracture mechanics') provides an analytical framework for assessing the influence of sharp defects on the load-bearing capability of a structure. Fracture mechanics techniques have reached the point of acceptance by ASME Design Codes for nuclear components, and ASTM Standards now include well-defined rules for measuring fracture toughness. Starting with a simple equation which relates applied stress and crack size, the influence of the material's thickness and yield strength can be calculated. Thus, the size of defect which will cause failure under the applied stress may be determined. Armed with this information, the metallurgist can assess the safety of a structure from the viewpoints of non-destructive testing standards, construction standards and conditions of operation throughout its service life."

Jan 1, 1976

By G Stovpchenko, G Jianjun, L Medovar

Electroslag remelting (ESR) today and into the future, will still be the main process for producing high-quality ingots by suppressing segregation, not just refining chemical composition from impurities. This paper analyses state-of-the-art electroslag refining with a focus on ESR with consumable electrodes, and recent technology with liquid metal supply (ESR LM) in view of their refining abilities and development trends, taking into consideration that the size of the ingots required by industry continues to grow, and the composition of new materials sophisticates to withstand increasingly higher mechanical and temperature loads . The yield of suitable metal in large ingots produced by conventional casting is low due to problems of element segregation by height and crosssection. For example, conventional ingots for nuclear powerplant rotors today reach nearly 700 t in weight. Attempts to directly replace such giant ingots with big-diameter ESR ingots weighing approximately 400 t were also unsuccessful because of growing segregation. Modern ESR equipment and technologies produce 200–250 t of ingots of satisfactory quality, reaching 2.5 m in diameter, implementing the change of consumable electrodes during remelting to increase ingot length. Another way to mitigate segregation is to enlarge the smaller diameter ESR ingot by a 500– 800 mm coaxial layer to the desirable diameter by ESR in the current-supplying mould (CSM). Modelling and experiments prove that refining from impurities and non-metallic inclusions at ESR most effectively occurs at the slag bath and liquid metal pool interface because the ESR LM has provided the same desulfurisation. ESR’s special refining capabilities in CSM come from the much longer time of LM residence shown at titanium purification from hard-melting nitride inclusions that are unremovable in vacuum arc remelting (VAR) and electron beam melting (EBM). Implementation of ESR technologies in CSM, especially with LM supply, is prospective to produce heavy enlarged and hollow forging ingots with prevented development of segregation due to dividing cross-section and reducing overheat of solidifying metal.

Jun 19, 2024

By A J. Morrison, M Yahyaei, J S. Siong, J Wang, K Runge

The flotation cells used to upgrade ultrafine metallurgical coal (-250 µm) are usually poorly controlled leading to unnecessary loss of combustibles from the flotation system. This is mainly because coal flotation cells are typically controlled for process stability rather than optimisation of flotation performance. This is especially true for a flotation device commonly used in coal applications in Australia – the Jameson Cell. This then provides an opportunity to improve the flotation performance by shifting from a stabilising control strategy to a proactive optimising control strategy. For an optimising control strategy, the control system will require a means of relating and then measuring in real-time, the effect of changing operating conditions on the coal flotation performance. Hence, the major aim of this work is to propose a possible model-informed process control strategy that could be used for real-time performance optimisation. In this study, industrial site work was conducted on an industrial-scaled Jameson Cell at a Coal Handling and Preparation Plant (CHPP) in Central Queensland, Australia where superficial gas velocity was controlled to six different levels. At the same time, other process variables such as froth depth and flotation feed properties were measured. The empirical models developed from this study suggested that combustible recovery is a function of superficial gas velocity, froth depth, feed solid content and feed ash content and that a peak in combustible recovery existed as a function of superficial gas velocity. This led to the development of a model-informed control strategy that aimed to maximise the combustible recovery by determining and then operating the cell at the superficial gas velocity at which the peak occurs. This peak superficial gas velocity was found to be only a function of feed solid content. Based on these findings it would seem possible to operate a Jameson cell at peak performance by online measurement of feed solid content, prediction of the optimum superficial gas velocity and stabilising control to maintain operation at that superficial gas velocity set point. The development of this modelinformed control strategy can serve as a basis for the development of a more sophisticated modelpredictive control (MPC) system. However, more work will need to be done to improve the predictivity of the combustible recovery model by measuring and modelling performance over a wider range of operating conditions.

Aug 24, 2022

By G. M. J. van Heerden, R. C. W. Webber-Youngman

"This article describes the re-engineering principles applied in the design of a personnel transportation system for the Bafokeng Rasimone Platinum Mine in the Rustenburg area of South Africa. It incorporates conveyor belt travelling, chairlift operation, and also includes consideration of proposed changes/modifications to the existing conveyor belt infrastructure.The purpose of the project was to identify, through a process of evaluation, the appropriate option and/or combination of transportation options that would be safe in terms of personnel transportation as well as cost-effective. Alternative measures for transporting personnel (not using belt riding) would have a significant positive spin-off, increasing the availability of the belt and thereby increasing production. This paper explores the feasibility of interventions that would improve safety through eliminating risk associated with personnel transportation as well as contributing towards improving the mine’s position on the cost curve.The design in consideration at the Bafokeng Rasimone Platinum Mine consists of two shaft systems, namely the North Shaft and South Shaft, each comprising twin decline shafts. One of the decline shafts is equipped with a conveyor belt for rock and personnel transportation, and the other with a winder for trackbound material transport. The conveyor belt has been used for personnel transportation since the commissioning of the shafts. The conveyor belt is equipped with platforms for personnel getting off and on the belt and a number of safety devices designed to ensure safety while travelling on the belt. Intensive training in the practical aspects of belt riding is given to every person, and unsupervised riding on the belt is permitted only once belt riding competence is demonstrated. Despite this, the safety results were poor, with 106 injuries between 2006 and May 2013. Fortunately, no fatalities were reported during this period.An investigation of alternative means for personnel transportation or engineered solutions to the current conveyor belt infrastructure in the safest, most effective, and most economical way was therefore needed. There was a major risk of safety-related stoppages being imposed following another belt accident/incident. This would prevent the mine from transporting personnel underground by belt and result in major production losses. From the commissioning of the Phase 2 shaft deepening project on both shafts, dedicated chairlifts have been used for personnel transportation as opposed to the conveyor belt installed in the Phase 1 area. The chairlifts have been in operation since 2004 and no chairlift-related incidents have been recorded thus far. According to safety statistics, it is clear that the chairlift is the safer method for the transportation of people in the shaft.To fulfil the objectives/scope of this study, it was recommended that both primary (new chairlift decline with infrastructure) and secondary options (modifications to the current conveyor belt infrastructure) be considered for implementation on both the North Shaft and South Shaft to reduce or eliminate accidents/incidents as a result of belt transportation. The associated capital expenditure would be approximately R200 million. Considering the future impact on the business as a whole, this would definitely be capital well spent."

Jan 1, 2016

By D. Su

This paper presents the details and results of a preliminary investigation into the response of borehole pressure cells (BPCs) in soft coal. Two parallel approaches, laboratory calibration and nonlinear finite element simulation, were adopted for deter- mining the BPC K-factor, which was defined as the ratio of cell pressure change to the corresponding change in external pressure. Results from both the laboratory calibration and the nonlinear finite element simulation revealed a nonlinear response of cell internal fluid pressure to external loading. The K-fact& also is shown to increase with increasing setting pressure and decreasing medium modulus. -Depending on the setting pressure, the K-factor for coal having a Young's modulus of 1.6 x lo5 psi ranges from nearly 1.2 at 2,000 psi of external pressure to 1.485 at 8,400 psi of external pressure. The improved under- standing of BPC behavior leads to the more accurate calculation of BPC K-factor in coal which significantly improves the correlation between pillar pressures measured in underground coal mines and those predicted by nonlinear finite element simulations of these pillars.

Jan 1, 1990

By Lloyd B. Underwood

In the event of a sudden nuclear attack upon the United States, it is imperative that vital command and control centers have a high probability of survival. One such vital facility is the North American Air Defense Command Combat Operations Center at Colorado Springs, Colorado. Known briefly as NOW, this installation when completed will be housed in large chambers excavated out of granite beneath the eastern slope of Cheyenne Mountain (Figure 1). The NORAD COC, a U. S. Air Force sponsored project, will serve as the primary collection and evaluation center for data concerning unknown aircraft, missiles, or space vehicles, which might bring destruction to North America. The data will be fed into high-speed computers and electronic equipment from outpost sources - radar, ballistic missile early warning stations and picket ships throughout the world. Electronically controlled display boards will make it possible to evaluate the tracking data instantaneously and to take appropriate defensive action1.

Jan 1, 1965

By Ziyuan Liu, Xun Zhang, Yan Wei, Hang Qiu, Shaomin Lei, Yubiao Li, Yu Meng, Min Lin, Bin Liu

High-purity quartz (SiO2) is an important material widely used in many industries, including semiconductor technology, telecommunication, and optics. The content and distribution of impurities in quartz significantly affect the processing methods. This paper provides an insightful review on the processing of high-purity quartz, covering the analytical techniques, separation methods, and the critical procedures used to assess the quality of quartz ore. More importantly, the critical review of the thermal phase transition separation method for fine-grained mineral inclusions, micron-grade fluid inclusions, and lattice-bound trace elements is notably opened for the first time. It is proposed that the research field as a monopolized industry would benefit by expounding the critical problems that occur during the preparation of high-purity quartz.

Jun 22, 2020

By Jos. R. Guiteras

This paper is one of a series describing; mining and milling methods and costs being published by the Bureau of Mines. It deals with the mineral resources of western South Dakota and describes the mining and milling of tantalite and associated amblygonite by the Black Hills Tin Co. and the Fansteel Mining Corporation. ACKNOWLEDMENTS Acknowledgment is made to Earl C. Schultz and Arthur I. Johnson, respectively superintendent and engineer for both the Black Hills Tin Co. and the Fansteel Mining Corporation, who contributed the information on mining and milling operations.

Jan 1, 1939

By William G. Pariseau, Mark K. Larson, Heather E. Lawson

Rational design based on engineering fundamentals is essential for the layout of safe, stable shafts and tunnels. Shafts and tunnels including winzes, raises, adits, and crosscuts are lifelines to the underground and must be secure. The contribution of this paper describes a significant extension in existing software previously developed for five important design problems in strata-bound mines such as coal, trona, salt, potash, and some large, lead-zinc mines. This extension in software allows analysis to proceed in three easy steps: (1) preparation of a strata properties file, (2) generation of the finite element model, a mesh, and (3) finite element program execution. Circular, elliptical, and rectangular shaft sections are available for a single shaft, twin shafts, and shafts in a row. Spacing of twin shafts and shafts in a row is a free parameter (pillar width). Tunnel shapes are the same as shafts but include the conventional arched back section. Dipping strata of variable thickness, depth and orientation relative to the excavation of choice are allowed. The analyses are three-dimensional. An elastic-plastic material model based on associated rules of flow and an N-type yield condition for isotropic, transversely isotropic, or orthotropic rock are used for all strata. Example analyses from several hardrock mines are provided to illustrate the three-step process including mesh plotting and plotting of selected results. The goal of this software is to advance mine design technology for improved miner health and safety.

By I. Filippova, L. Filippov

"The by-product potential of light rare-earth elements (LREE, La, Ce, Nd) and rare-metals (W, Nb, Sn) within the St Austell kaolin deposits (UK) is related to the kaolinisation process, which liberates the accessory heavy minerals of the host granite in the clay matrix and allows their separation in the waste streams. As a consequence these minerals are pre-concentrated in the micaceous residue which displays relatively high LREE content (around 170 ppm) hosted by monazite which is mainly distributed (up to 95%) in the -100 µm fraction. A combined gravity/flotation concentration flowsheet, starting with classification of the residue into 3 size fractions (+150 µm, 150-53 µm and -53µm) was developed. This study presents the results of the clay-rich -53 µm size fraction beneficiation by flotation using sodium oleate and hydroxamate as collectors.The effect of dispersant addition during de-sliming operations on flotation efficiency was also investigated. The LREE grade in the floated product obtained with sodium oleate increased from 3370 ppm to 5350 ppm and recovery from 30% to 80% with dispersant which is attributed to clay coating. Comparison of flotation performance and Falcon Ultra-Fine (UF) concentration of monazite to previous results obtained with Falcon Semi-Batch (SB) gravity concentrator on the unscreened raw residue clearly shows that flotation of the fine residue is more efficient than Falcon UF and Falcon SB. Indeed Falcon UF produced high recoveries (87-95%) but with almost no enrichment (1.3-1.4 ratios) whereas Falcon SB concentration of unscreened residue produced higher grades (up to 0.6 % LREE) but with low recoveries (17-22 %). These preliminary results show that LREE can be pre-concentrated suggesting that the micaceous residue stream (and the associated tailings dams) could be considered as a potential resource for these metals."

Jan 1, 2016

By Daniel J. Brunner

The U. S. Department of Energy (D.O.E.) requires that the prospective nuclear waste repository in Basalt at Hanford, Washington, comply with State of California mine and tunnel safety orders. These regulations require that all main fans be installed in such a manner as to permit prompt reversal of airflow. This paper evaluates the requirement of air reversal and the appropriateness of imposing such regulations on the proposed nuclear waste repository in Basalt.

Jan 1, 1988

By J. J. Dowd

1. The Pittsburgh bed is the most important bed in Marshall County, and virtually the entire production of coal in the county comes from this bed. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 tons per acre-foot of coal in place, were estimated at 3,158 million short tons as of January I, 1954. Of this total, 3,071 million short tons is in beds 28 inches and more thick. Areas in each bed except the Pittsburgh were omitted from the estimate because available data relative to the bed characteristics are too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1956

By Peter Zhang, Daniel Su, Bo Kim, Zoheir Khademian

Building on the research results and knowledge obtained from the ongoing National Institute for Occupational Safety and Health (NIOSH) Gas Well Stability Research, researchers from the NIOSH provided detailed analyses on potential longwall mining and gas well casing interactions at an unconventional shale gas well pad in a West Virginia longwall mine. Following the recommendations from recent research findings, the 5-1/2-inch production casings in all five wells were left uncemented from 4,200 feet below the surface to the surface. Prior to the first longwall panel excavation, NIOSH researchers conducted sophisticated three-dimensional numerical modeling to predict longwall-induced deformations and gas well casing stresses, which were compared with post-first panel and post-second panel mining 40-arm caliper surveys. The pre-mining predictions and comparisons with post-mining 40-arm caliper surveys were presented to all parties involved, including the coal and gas operators, Mine Safety and Health Administration (MSHA), Pennsylvania Department of Environmental Protection (PADEP), and West Virginia Department of Mines (WVDOM), prior to the re-entry operation on December 13, 2022. To date, the re-entry operation is a resounding success.

Jul 1, 2023

By N Petropoulos and M J Thurley, E Righetti, M Wimmer

Fragmentation in sublevel caving (SLC) is vitally important. Both gravity flow and any downstream processes are affected. Reasonably coarse fragmentation may lead to larger draw bodies (isolated extraction zones) and hence potentially higher primary ore recovery and depressed/delayed waste rock inflow from above. Fewer flow disturbances are expected by mitigating oversize. In addition, it requires less boulder handling and reduces wear and possible hang-up problems in orepasses. To assess the present-day functionality of large-scale SLC, a multiyear, comprehensive measurement program was initiated. It covers the main elements for SLC, namely blast function, fragmentation and gravity flow. The present paper focuses on fragmentation measurements. An image acquisition system was used to document the drawpoint and the load-haul-dump (LHD) bucket for each mucking cycle. At the beginning, four buckets (about 70 t total) were sieved to validate the results of both 2D and 3D image analysis techniques. The fundamental and specific problems are discussed herein. At the moment, fragmentation of the SLC rings is evaluated using a quick rating system and a 2D fragment delineation software. The results enable a description of fragmentation and its variation during mucking but also – combined with the gravity flow measurements – conclusions on the fragmentation for different parts of the SLC ring. Possible influences on flow disturbances and ore recovery/dilution are investigated. The recent findings allow a better understanding of breakage and flow and support future process improvements.CITATION:Wimmer, M, Nordqvist, A, Righetti, E, Petropoulos, N and Thurley, M J, 2015. Analysis of rock fragmentation and its effect on gravity flow at the Kiruna sublevel caving mine, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 775–792 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

Mill #4 processes mildly refractory ore from Carlin Trend deposits. Diagnostic analysis of plant operating data was used to generate a mathematical model containing the key parameters influencing the gold recovery. The model was used to direct modifications to plant operating practice. The cyanide dosing strategy was changed to reduce preg-rob gold losses and cut reagent consumption A finer grind was achieved without capital investment. The density in CIL was lowered, and tighter control was exercised over plant throughput. These changes resulted in a recovery increase of at least 2%, worth $111,000/month at $300/oz, and concomitant reagent cost savings of $55,000/month.

Jan 1, 1999

By Kevan J. R. Ford, Chris A. Fleming, Robert D. Henderson

"Kinross Gold Corporation’s Maricunga mine in Chile presents an ideal opportunity to apply the SART process to a heap leach operation. Given increasing levels of cyanide complexed copper in current pregnant solutions from Maricunga heaps (over 300 ppm Cu), there is a need to reduce these levels and decrease cyanide consumption and cost. Additionally, a means of disposing of this copper is required, preferably as a saleable product. The well published SART process applied to gold-copper cyanide solutions was selected as it allows rapid precipitation of cyanide soluble copper as a relatively pure copper sulphide. The process also allows effective recovery and recycle of cyanide back to the heap leach operation.This paper reviews the SART process chemistry and presents a summary of SART bench-scale and pilot plant testwork completed by Kinross. Key design parameters and engineering aspects of the proposed plant at Maricunga are discussed. SART plant operating costs and net revenue analysis are included and illustrate the compelling economics of installing a SART process plant. INTRODUCTIONMaricunga OperationCompañia Minera Maricunga (CMM), fully owned by Kinross Gold Corporation, operates the Maricunga mine (formerly Refugio) which is located 120 km due east of the city of Copiapó at an elevation of 4,200m above sea level in the Andes mountains of northern Chile. Figure 1 shows a map of the location of the Refugio mine relative to other gold and copper mines in the region."

Jan 1, 2008

By K. Dufresne

Blasting in geothermally high temperature ground and/or extremely reactive ground is an increasing common challenge for surface and underground mines. Many current PETN based non-electric and electronic detonators have manufacturer published in-hole temperature limits ranging from 55°C to 65°C (131°F to 150°F). When confronting blasthole temperatures above the manufacturer published limits, operations may request site-specific guidance and qualification for use. The advised safe loading window for in-hole PETN based detonators is often too short to be practicable for production blasting. To overcome limitations of PETN based initiation systems, surface mines with high temperature ground and/or reactive ground are known to load blastholes with a qualified high temperature bulk emulsion that are top primed with a cartridge of temperature qualified detonator sensitive emulsion plus an RDX detonating cord downline. As there is no in-hole delay detonator in this system, blasthole timing is accomplished with surface delays. Although this system is safe, top priming and surface delaying does influence floor quality and top size fragmentation, and safe loading windows times reduce blast block size and increase blasting frequency. A mining company with a site characterized by geothermally high temperature ground plus highly reactive ground employed a blasting system like the one described above. The site desires to improve blasting performance by moving to an in-hole delay initiation system that can withstand the site ground conditions. At the request of the mining house, DynaEnergetics (hereafter “the company”) developed an electronic initiation system for application in geothermally high temperature ground and/or extremely reactive ground conditions. The DynaEnergetics IGNEO high temperature electronic initiation system is rated for in-hole use in ground up to 150°C (302°F) for 48 hours. The detonator consists of a high strength detonator with an HMX base charge and thermally resistant downline. To make up a primer, the detonator is inserted into a booster charge assembly that is fitted with a small HMX shape charge. This high energy primer is designed to be compatible and reliable for firing bulk emulsions, including those with high percentages of urea inhibition to combat reactive ground. Up to 1000 detonators may be programmed in 1ms increments up to 1500ms. The system is controlled by a digital firing panel that can be used with either a wired or wireless trigger. The system enables high temperature and/or reactive ground sites to utilize in-hole delay initiation and realize the associated performance benefits

Jan 1, 2024

By Uwe Wyink, Guenther Thiele, Isabel Gollnick, Klaus Thyrock

"The application of a thin spray on liner was implemented in longwall T-junction sections in 2009 for the first time. The development of the material and the application is based on a technical cooperation between RAG Deutsche Steinkohle AG and BASF Corporation. The report gives an overview of the first trials. The underground test occurred in a seam with a height of 1.5 m (5 ft) in a depth of 1,100 m (3,609 ft). The roadway is dual-use entry and the roof strata is composed of shale and sandy clay. In some sections geological faults impact the surrounding strata. The poor conditions induce separating and loosening of roof rock. Several remedial actions have to be implemented for decreasing deformations at the face entrance.The application of thin spray on liner (TSL) provides simplification and cost reduction of supporting work at longwall T-junction. The installation of TSL to avoid roof and coal fall operations for lagging are omitted.INTRODUCTIONFor safe operation of face retreat in dual-use roadways, the processes of securing and stabilizing the face end area are very important in order to minimize deformation and stress. Avoiding roof and coal fall are the main concerns for safe operation. For that reason different methods of reinforcement are tested in underground operation. In this paper the application of TSL is presented.The specifications of TSL are described, followed by the case study results. The underground study is located in one mine of RAG Deutsche Steinkohle. The extraction of the hard coal in this mine is characterized by great depth and high stress. There are poor geological and geotechnical conditions. The roadway used for the underground application was headed with the support system combination type A, which will be described later in the paper. After the first face retreat, deformation of steel arch support and bagging destroyed the roadway, so for the second face retreat remedial actions had to be undertaken. For this a new system of reinforcement, simplifying the supporting work at the longwall T-junction was tested. The reinforcement consisted of different parts that are described in the following report. Furthermore two different versions were applied. One method is the operation with TSL and the other one is the use of concrete for sealing. Both methods are compared in the text."

Jan 1, 2010

By Michael J. Miller

The demand and supply of wollastonite has gone through a dynamic period in the 1990's. A 10% -15% growth rate of demand stimulated interest in evaluating new projects. However, the mid-1990's brought declining prices for commodity applications and natural barriers to entry for technical applications, making many of these potential projects uneconomic. Successful projects that were brought to market were done so by incumbent producers. This work examines the competitive structure of the wollastonite market by evaluating the strategic decisions of the industry leader, NYCO Minerals Inc., and a new market entrant, Orleans Resources, in an attempt to identify the environmental threats and opportunities of this industry. Results suggest new entrants like Orleans Resources face significant entry barriers for technical applications, while NYCO Minerals could improve its profitability by having less exposure to commodity applications.

Jan 1, 1999