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By H. Hitchen

THE PURPOSE of this paper is to indicate the working capacity of different types of ropes for various engineering and mining duties. ROPE CONSTRUCTIONS There are approximately one hundred different designs of ropes in use today but, normally, only about ten are necessary for mining and engineering duties. The rest are designed for unusual equipments, or are different ways of combining wires of special shapes. Basically, the various designs of mining ropes consist of round, triangular, and oval strands, constructed with one or several layers of wire over a single wire, or a compound construction of sever.al wires. To suit different installations ropes are made with 3, 4, 5, or more of these types of strands over a central core, the ?co re itself being manufactured from either a fibrous material or a combination of steel wires. Nevertheless, in mining, the demand for 'locked coil rope', wl1ich may be considered as a single strand, is steadily increasing, especially for use on vertical shaft winding engines. So far as the locked coil rope is concerned, many constructions have been developed to suit different requirements, such as - in addition to winding ropes - aerial carrying Topes, shaft guide ropes and haulage ropes.

Jan 1, 1957

This paper describes the new iron and steelmaking process recently commissioned at NZ Steel. Ironsand mined and concentrated at Waikato North head is slurry pumped 18 km to the company's Glenbrook works. Ironmaking includes the direct reduction process pioneered at Glenbrook in the 1970s and a new continuous electric melter. The molten, high carbon pig iron produced is then fed to a vanadium recovery unit and on to the KOBM oxygen steelmaking vessel. Steel is cast into billets or slabs. The new plant, which is the first stage of a fully integrated works at Glenbrook, raises New Zealand Steel's production capacity from 150 000 t/y to 750 000 t/y.

Jan 1, 1986

By J. J. Scott

As a Rock Mechanics investigator, the author has, Over his career, attempted to use his best knowledge in developing better rock control fixtures. Based on the experience of nine years of development of friction rock stabilizers, in 1980 he decided to launch a new investigation to develop a unique roof support fixture which would fit the coal mining market. The largest single user of roof bolts in the world is the American coal mining industry, historically using up to 100 million fixtures per year. In 1989 they used approximately 82 million fixtures.

Jan 1, 1990

By H. -F. Krausse

Roof failures in underground coal mines are related to the lithology and geologic structure of the roof. There are two distinct suites of roof rock above the Herrin (No. 6) Coal in Illinois, and each has distinctive patterns of structure and roof failure. In black shale-limestone roof areas, roof instability is correlated with thinning of limestone beds and presence of faults and clay dikes. In gray shale roof regions, the prime roof hazards are posed by rolls, shear bodies, and presence of coal or carbonaceous partings in the roof. Most structural features examined are believed to have formed during early stages of sediment diagenesis and compaction. Structural trends and lithologic patterns are strongly interdependent for this reason. In many cases geologic patterns are so complex and locally variable that prediction of roof stability far in advance of mining is difficult. The need for greater flexibility in roof control planning is apparent.

Jan 1, 1979

By D. D. Hamilton

The ISMS program provided for the development and demonstration of equipment modifications in both conventional and continuous coal mining systems. This report describes activities during the demonstration of the continuous equipment and includes machine performance, results of data gathering, system evaluation, and recommendations for implementing improvements.

Jan 1, 1976

"HISTORY Tube bundle systems have been used in the coal mining industry for gas detection since the 1960’s. At the time there were developments were underway for improved gas monitoring systems. The primary gas detection systems in use were the flame safety lamp, colorimetric stain tubes and the taking of samples for analysis by gas chromatography. The MSA D6 hand held methanometer was approved in the UK for statutory methane measurements in 1972 and became very popular due to its smallness and simplicity of use. In 1973 Sieger Limited also developed a BM1 methanometer which could be installed underground and relay methane concentrations to the surface. Similar developments were underway for carbon monoxide detection and one was developed in 1982 by the Yorkshire Regional Laboratory of the NCB commercial development was undertaken by Sieger Limited who named it the ‘SCO1’. The UNOR 1 carbon monoxide and methane analyzers were approved for underground use in the United Kingdom in the late 1960’s.5 The technique was developed by Dr Luft of Bergbau-Forschung Essen and the equipment was manufactured by Maihak in Germany. The apparatus was flame proof and provided an intrinsically safe output which allowed the result to be telemetered to the surface through colliery communication systems. Both analyzers work on the same principal and each of the gases adsorb a certain wavelengths of infrared radiation. The detector measures the residual transmitted radiation and determines the percentage of gas present in the sample. These flameproof versions had proven to be robust and reliable. The UNOR 1 had been used in the Saar region of Germany and Scotland in the UK. The development of tube bundles for hydraulic controls enabled the development of the tube bundle gas monitoring systems we know today. A bundle of tubes are taken underground through a shaft, a borehole or drift then distributed to the required monitoring points. This enabled the ongoing monitoring of the underground environment when the power was isolated at 1.25% CH4. In 1972 the United Kingdom (UK) National Coal Board (NCB) produced a hand book for tube bundle systems which was subsequently updated in 1974. This is a useful guideline into the operational aspects of tube bundles systems at coal mines6. Many of the processes identified are being followed today. The United State Bureau of Mines (USBM) prepared a circular similar to the NCB handbook on tube bundle systems.7 The circular was prepared by Litton C and it was targeted at the design criteria for tube bundle the systems. The circular also states that “pneumatic monitoring systems can be used to monitor for hazards that develop quite quickly”."

Jan 1, 2016

By E. Essadiqi, P. Poruks, D. Boyd, D. Emadi, I. Yakubtsov, T. Turi

This paper reviews the results of an extensive study of microstructures and mechanical properties in bainitic linepipe steels. The research was carried out as a collaborative project between Queen's, Stelco and CANMET. Basic studies of phase transformations and mechanical properties in these steels established important relationships between processing schedule and microstructure evolution, and between final microstructure and mechanical properties. The best combination of strength and toughness properties is obtained with a microstructure comprising a matrix of intragranularly-nucleated bainite (`acicular ferrite - AF') and small (~ 0.5 µm) dispersed particles of martensite (`M/A'). We describe this as a dual-phase AF+M/A microstructure. An experimental study on 15-mm thick plate determined the window of steel composition and processing parameters which gives the dual phase AF+M/A microstructure. The minimum strength and toughness properties for Grade 621 (X90) linepipe steel can be achieved by either a lean steel composition (0.04C-1.77Mn-0.04Cr¬0.32Mo-0.31Ni-0.29Cu-0.08Nb) with extreme processing parameters, or by a higher alloy composition (0.04C-2.07Mn-0.50Cr-0.51Mo-0.04Nb) with a more industrially realistic processing schedule. It is proposed how this approach could be extended to obtain higher strength linepipe grades.

Jan 1, 2005

By J. L. Furtney, C. Fairhurst

"Although global mineral resources are considered to be adequate to meet the needs of a rapidly growing world population, the United States is becoming increasingly dependent on imports. This could have implications for both the economy and national security. The US is a country with a strong tradition of leadership in science and technology. Impressive advances in autonomous underground mining systems reduce the adverse effects of heat and humidity in deep mines and focus renewed attention on ground control. Developments in computing power open opportunities to develop improved understanding of the important role of discontinuities (faults and fracture systems) and more effective design of deep excavations. Establishment of mining R&D Centers at leading US research universities, jointly funded by industry and US federal agencies is recommended as an effective step for the nation to remain an influential partner in world mining. INTRODUCTION. “None of the arts is older than agriculture, but that of metals is no less ancient.. . for no mortal man ever tilled a field without implements. If we remove metals from the service of man, all methods of protecting and sustaining health and more carefully preserving the course of life are done away with.” Agricola (1558)i Homo sapiens, generally acknowledged as the species from which modern Man has evolved, is considered to have originated in Swaziland some 100,000-200,000 years ago. Evidence of use of minerals in that region has been dated to earlier than 40,000 BC.ii Today, a large fraction of the elements of the Periodic Table are derived from minerals, and finding new applications in development of innovative technologies. Agricola’s comments are as applicable today as ever.iii Metals such as copper, tin, lead, iron and aluminum were mined and smelted several thousands of years BC. It was not until the Industrial Revolution, started in the latter half of the 17th Century in Northern England, where coal was available as an energy source, and iron as the basis for fabricating machinery, that dramatic change to society began to occur. Human toil was replaced by far more powerful machines. Rural communities migrated to work in factories in urban areas. Rapid transportation over long distances became possible, leading eventually to the world of today. The change spread to other parts of the world, bringing wealth and power. Although now well established in some regions, the Revolution has still to arrive in many other parts of the world. This can be seen in Figure 1, which shows the relative wealth, or ‘Standard of Living’ as measured by the GDP/capita, of regions around the world. Regions such as North America, Europe, and Australasia iv are seen to have the highest standard. Thanks to today’s global communications systems, regions with relatively low GDP/capita are well aware of ‘how others live’ – and eager to emulate them."

Jan 1, 2018

By Nan Zhou, Jixiong Zhang, Qiang Zhang

"Mining activities under hard roof could easily induce rock burst. Based on the geological conditions of widespread hard roof in China, this paper discusses the type, mechanism of occurrence and prevention of rock burst caused by hard roof from energy evolution point of view. It analyzed the interaction between the solid backfilled body and roof under different backfilling ratios. And by establishing and applying the mechanical model, the deformation of hard roof and energy evolution of the panel under different backfilling ratios were determined, revealing the control effect of solid backfilling on disaster-causing energy. As a result, an innovative method using the solid backfilling method was proposed as a solution to the hard-roof-induced rock burst hazards. Moreover, mine trial was conducted in Panel 6304-1 of Jisan Mine. The result shows that the stress concentration factor of the front abutment stress was only 1.44; the coal dusts in drill holes didn’t exceed the limits and microseism of large energy didn’t occur during mining mining, indicating that solid backfilling mining could be applied as an effective method for preventing rock burst caused by hard roof.INTRODUCTIONSHard roof refers to the thick strata above the coal seam or thin immediate roof. It is strong with poor joint development. After mining, instead of immediate caving, it will overhang for a large area in the gob, resulting in high stress in front of the face and difficulty in gas dispersion. As a result, the face spalls, the roof exposes and the gas accumulates in the gob. With the continuing advance of the face and increase in area of overhang, the stress in the hard roof will eventually exceed its ultimate strength and cause a large area of caving, followed by quick release of energy concentrated in the roof and coal seam, which may cause rock bursts and other dynamic disasters in the mine as well as serious equipment damage and casualties. Therefore, the hard roof becomes one of the main factors causing rock bursts at the face.Hard roofs in China varies in conditions. It ranges from dozens of meters to hundreds of meters in thickness. However, coal reserve under hard roofs accounts for about 1/3 of the total reserve; moreover, nearly 40% of the fully-mechanized coal mining panels are those with hard roofs and more than 50% of the mining areas are associated with problems of hard roofs. Aiming at this problem, researchers at home and abroad have proposed many solutions, e.g. coal pillar support, strength weakening and forced caving, to prevent rock bursts caused by hard roof. These solutions have been employed in some cases with good results. However, due to the variability in geological conditions of mining and hard roofs, the application of the above solutions is limited."

Jan 1, 2015

By M. E. Buzon, M. E. Gunter, B. D. McNamee

A Google search on talc asbestos yields more than 500,000 hits due to the growing number of civil lawsuits in this area. Historically, the litigation was centered on amphibole-containing industrial talc. There was no debate these talcs contained amphiboles, but the issue was the definition of asbestos and whether the amphiboles had an asbestiform habit. Ultramafic-hosted talcs, however, are formed in such a way as to not favor the formation of amphiboles in the talc, but they can occur in the surrounding black-wall. In these deposits, the serpentinite host rock is in direct contact with the talc, therefore, allegations can be made that non-asbestiform amphiboles or non-regulated serpentine group minerals can occur in the final products. We analyzed talcs from both metamorphosed carbonate- and ultramafic-hosted talc deposits using polarized light microscopy (PLM), scanning electron microscopy (SEM) with energy-dispersive spectroscopy (EDS), electron microprobe (EPMA) with wavelengthdispersive spectroscopy (WDS), transmission electron microscopy (TEM) with EDS, and powder X-ray diffraction (XRD). Compositions of minerals determined by EDS alone are not sufficient to confidently identify asbestos, despite common practices by some researchers. We emphasize, using both historical samples, and analyses of currently contested minerals, the importance of determining both the structure and composition of a mineral, as well as defining its morphology, before concluding whether it is asbestos.

Jan 1, 2018

By E. Swartzman

This paper presents a general re-view of the various methods of briquetting coals, with and without the aid of a binder, with special reference to the production of a suitable briquette from Nova Scotia 'fines' for re-blending with industrial coal. From the economic and technical viewpoints, either small stoker-sized briquettes made with about 4 per cent asphalt in standard low-pressure double-roll presses, or briquettes made without binder in high-pressure double-roll presses, appear to be the most reasonable solution at present.

Jan 1, 1959

By William Gleason

"Komatsu has been on the cutting edge of autonomous mining for the past 30 years and the company remains at the forefront of the technology that is changing from concept to a full-fledged reality.In 1996, Komatsu America Corp. (KAC) purchased a controlling interest in Modular Mining Systems; a move that enabled both companies to expand their product lines. It was through this effort that Modular helped to deploy the first autonomous haulage system (AHS) — the Komatsu FrontRunner system. In January 2008, the first commercial implementation of the FrontRunner system occurred at Codelco’s copper mine in Chile. Since then, Komatsu has put more than 130 haul trucks into seven sites on three continents to haul copper, iron ore and oil sands and its equipment has moved 1.8 Gt (2 billion st) of material with zero lost time incidents attributed to Komatsu’s autonomous trucks. The 1.8 Gt (2 billion st) is the most of any commercial mining autonomous haulage system and there is more to come. In November, Komatsu announced that an additional 150 autonomous haul trucks will be deployed to the Canadian oil sands over the next seven years.Komatsu has continued to pioneer autonomous haulage development, creating a range of autonomous options that includes semiautonomous and teleremote options all the way up to a haulage vehicle that stole the show at the world’s largest mining equipment trade show.In 2016, Komatsu advanced the concept of driverless haul truck to a new level when it displayed its Innovative Autonomous Haulage Vehicle (IAHV) at MINExpo in Las Vegas, NV. The concept vehicle is the first mega class haul truck designed to be fully autonomous, without an operators’ cab included on the vehicle.Unlike other haul trucks, the vehicle was developed exclusively as an unmanned vehicle designed to maximize the advantages of unmanned operation. Among other advancements, it was designed to distribute equal load to the four wheels, both when the vehicle is loaded and unloaded, and adopt four-wheel drive, retarder and steering. Komatsu said it is aiming for high-performance shuttling of this vehicle in both forward and reverse travel directions, thereby eliminating the need for K-turns at loading and unloading sites."

Dec 1, 2018

By Kwangmin Kim, Junnhyeok Park

In the hard-rock mining industry, the generation of fines during blasting is an important issue because it has a significant effect on production processes. Although various approaches have been used to estimate fines generation in recent decades, as a practical matter, measuring the amount of fines is nearly impossible given the technical limitations and the scale of mine blasts. In this study, a dynamic PPV damagemodel was developed and applied to predict fines generation as a result of blasting. This modified version of the crushed zone model (CZM) considers dynamic rock properties and peak particle velocity (PPV), which represents the induced stress in blasting. Dynamic rock-fracturing tests were conducted using a split Hopkinson pressure bar (SHPB) to determine the parameters that represent the relationships between rock strength and strain rate as well as the relationships between fines amount and strain rate in the model. A case study was conducted that entailed determining the radius of the crushed zone for given blast designs and rock properties and then measuring the fines amount within this crushed zone. This case study indicated that the dynamic PPV model can provide a rough estimate of fines generation for given dynamic rock properties and blast design parameters and that this method has the potential to be a useful indicator, or index, of fines generation.

May 16, 2020

By Megha Patel

"The objective of this project was to investigate the application of Prompt Gamma Neutron Activation Analysis (PGNAA) technology to provide real-time on-belt elemental analysis of feed ore in base metal sulphide processing, in this case at the Mount Isa Mines Zinc-Lead Concentrator Heavy Medium Plant (HMP). After initial exploratory testwork proved successful, a Geoscan On-Belt Elemental Analyser was retrofitted onto the existing HMP feed conveyor. Dynamic calibration of the Geoscan was conducted based on laboratory XRF analysis results of the HMP feed conveyor hammer autosampler samples from May to November 2013. Comparison of the Geoscan results to the laboratory XRF analysis results during and after dynamic calibration indicated the technology had acceptable accuracy to be incorporated into HMP process control. The variation between the two sets of data includes all primary sampling, sample preparation and XRF analysis errors as well as the Geoscan errors themselves. The Geoscan instrument precision must be calculated separately through a duplicate sampling campaign and independent laboratory analysis before extending the scope of its range of application beyond HMP process control. The expected benefits of integrating the Geoscan real-time data into HMP process control are optimised HMP metal recovery, improved cost efficiency and improved stability of the downstream processes (milling and flotation). Utilisation of the Geoscan will also enable improved feedback to mines on grade control and dilution, and provide additional information on individual ore types when fed as campaigns to HMP."

Jan 1, 2014

By John Dixon

This paper is one of a series on milling methods and costs being published by the Bureau of Mines. Acknowledgment is made to J. B. Tyrrell, managing director, and Wm. Sixt, manager of the Kirkland Lake Gold Mines, for permission to publish this article. The Kirkland Lake Geld Mining Co.'s mill is located on Government Road at the west end of the productive part of the Kirkland Lake mining area, 1 mile west of the village of Kirkland Lake. The crushing plant is connected to the shaft house of No. 2 shaft, which is now the only operating shaft.

Jan 1, 1931

By F. Boudreault, M. J. Scobie, J. Szymanski, C. Hendricks

The development of new stoping methods and more effective control over dilution, recovery and fragmentation depends on improved accuracy in blasthole drilling. The mechanisms and factors which control accuracy are poorly understood. Canadian blasthole stoping and the practices adopted for monitoring and controlling drilling accuracy are reviewed. The techniques and problems associated with blashole set-up and trajectory surveying are discussed. Four new blasthole trajectory survey systems are evaluated on the basis of their performance in recent underground trials. Conclusions are drawn as to the technological developments required so that more precise control over drilling accuracy can be achieved.

Jan 12, 1992

By M. A. Elliott, H. H. Schrenk, L. G. Berger, John C. Holtz

"INTRODUCTION Interest in the possibility of using Diesel 6/ engines for haulage power in mining and tunneling is increasing in the United States, owing largely to the reported successful use of Diesel locomotives in European coal mines and to the comparatively recent development of automotive Diesel engines in this country. The extent of this interest has been evidenced to the Bureau of Mines by numerous requests for information as to the factors that must be considered if Diesel engines are to be used safely underground.Proponents of the application of the Diesel engine to underground haulage base their claims for its safety upon a comparison with the gasoline engine, assuming that (1) the carbon monoxide content of Diesel exhaust gas is always low and that (2) fire and explosion hazards from Diesel fuel are minimized because of its low volatility. In these respects the Diesel engine appears less hazardous than the gasoline engine, whose use underground has been discouraged by the Bureau of Mines and other organizations interested in safety in mining. However, such generalizations cannot be accepted as conclusive evidence that safety is inherent in Diesel engines in underground service, as European experience indicates that certain hazards may accompany their use. Such hazards were discussed in a previous publication 7/ that reviews developments in the use of Diesel locomotives in European coal mines.The Bureau of Mines has initiated a study of the hazards that may attend the use of Diesel engines underground to obtain first-hand information that may serve as a basis for recommending sale practices under conditions existing in the United States."

May 1, 1940

By Ihsan Berk Tulu, Deniz Tuncay, DYKE MARK ALEXANDER VAN, Ted M. Klemetti

Bleeder entries are critically important to longwall mining for the moving of supplies and miners as well as the dilution of mine air contaminants and must stay open for many years. In this study, standing supports in moderate cover bleeder entries were observed, numerically modeled and instrumented by researchers at the U.S. National Institute for Occupational Safety and Health (NIOSH). The measurements of the installed borehole pressure cells (BPCs), standing support load cells and convergence meters, and roof extensometers are presented in addition to the numerical modeling results and visual observations made by the NIOSH researchers in the bleeder entries. The results include the effects of multiple panels being extracted in close proximity to the instrumented site as well as over one and a half years of aging. As expected, standing supports closer to the longwall gob showed the greatest load and convergence. The roof sag appeared generally independent of the proximity to the longwall gob. The BPC readings were driven by both the proximity to the gob and the depth into the pillar. The results of this study demonstrated that the entry roof can respond independently of the pillar and standing support loading. In addition, the rear abutment stress experienced by this bleeder entry design was minimal. The closer the mine development, pillar or supports are to the gob, the greater the applied load due to rear abutment stress.

By H. M. Stewart, N. F. Dawson, J. P. Beukes, P. G. van Zyl, Q. P. Campbell, A. Jordaan, R. I. Glastonbury, L. N. Sadiki

"SynopsisThe physical properties of oxidative sintered pellets produced from typical South African UG2 ore are compared with the physical properties of pellets produced with conventional South African metallurgical-grade chromite ore (from the Lower Group 6 or the Middle Group 1 and 2 seams). A statistical evaluation of the cured (sintered) compressive strengths proved that pellets prepared from UG2 ore are likely to have the same, or better, compressive strength than pellets prepared from metallurgical-grade chromite ore. The cured abrasion strength of the UG2 pellets was also superior to that of the metallurgical-grade pellets. Scanning electron microscopy (SEM) backscatter, secondary electron, and elemental X-ray mapping were used to determine the reasons for the general superior strength of the UG2 pellets. The case study UG2 ore also required 13 kWh/t less energy for milling to attain the required particle size distribution prior to pelletization, which can lead to substantial cost savings. Results presented in this paper can be utilized by ferrochromium (FeCr) producers to better quantify the advantages and disadvantages associated with the use of UG2 ore for FeCr production.IntroductionChromite, a mineral of the spinel group, is the only commercially viable source of virgin chromium units. Geologically, commercial chromite deposits in the world are found in three forms, i.e. alluvial-, podiform-, and stratiform-type deposits (Murthy et al., 2011; Cramer et al., 2004). Alluvial deposits were formed by weathering of chromite-bearing rock with the subsequent release of chromite and gravity concentration by flowing water. However, these deposits are relatively small and of comparatively minor commercial interest. Podiform-type chromite deposits usually occur as irregularly shaped pods or lenses, and their distribution within a mineralized zone is usually relatively erratic and unpredictable, making the exploration of these deposits difficult and costly (Cramer et al., 2004). Stratiform-type chromite deposits occur as parallel seams in large, layered igneous rock complexes with more regular layering and lateral continuity (Cramer et al., 2004). The largest example of a stratiformtype chromite deposit is the Bushveld Complex (BC) in South Africa, which holds an estimated three-quarters of the world’s viable chromite ore resources (Cramer et al., 2004).Several chromite seams exist in the BC. The seams of economic interest are the Lower Group 6 (LG6), the Middle Group 1 and 2 (MG1 and 2), and the Upper Group 2 (UG2) seams (Cramer et al., 2004). The LG and MG seams are specifically exploited for their chromium content, while the UG2 seam is mined primarily as a source of platinum group minerals (PGMs) (Xiao and Laplante 2004). Extraction of the PGMs from the UG2 ore usually involves the liberation of the sulphide by milling and subsequent recovery of the PGM concentrate through flotation (Xiao and Laplante, 2004). Chromite in the PGM concentrate is undesirable; therefore, PGM recovery circuits are specifically designed to ensure maximum rejection of the chromite to the tailings stream. However, the chromite in the PGM tailings can potentially serve as feedstock for ferrochrome (FeCr) production, after beneficiation to increase the chromium content."

Jan 1, 2015

By Abdelaziz Baçaoui, Imane Aarab, Abdelrani Yaacoubi, Khalid El Amari, Abderahman Etahiri

Phosphate ores upgraded by flotation are widely used as vital raw materials for the sustainable production of phosphate fertilizers to maintain the food supply. High-grade phosphate reserves become more and more depleted. Low-grade phosphate mining and processing are in the spotlight of the fertilizer industries to cope with the exponential growth in the world’s population and meet the increased demand for fertilizers. As part of a series of research works conducted within a major project aiming at upgrading a low-grade phosphate ore never-exploited before, the present work endeavors to optimize the flotation of this ore using the response surface method (RSM) as a follow-up of a screening study. Unveiling new insights on such a strategy paved the way for improving flotation performances. This work demonstrated that an optimum 30.18% P2O5 with 88.07% recovery was achieved using 63.10 g/t of sodium alginate (NaAL) and 2484.72 g/t of sodium oleate (NaOL) at pH 11.40. This maximum was contrasted with a new formulation of fatty acids (FAM). The 30.76% P2O5 grade with a recovery of 89.72% was attained using 50.94 g/t of NaAL and 1455.40 g/t of FAM at pH 11.68. FAM collector markedly outperformed NaOL at low concentrations proving the efficiency of synergists.

Dec 7, 2022