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By R. Mensah-Biney

The loading characteristics of gold-tetrabromide species onto activated carbon have been evaluated using a completely mixed batch reactor system. The overall loading of gold onto carbon was rapid for the first hour but continued slowly without cessation as a result of reduction of gold. Conventional equilibrium considerations were therefore not applicable. Although loading continued slowly after several days, abnormally high loading capacity values of 10-12 meq/g carbon (650-800 kgAu/tonne) could be attained within 72 hours. The loading of gold-bromo species by activated carbon was by the mass transfer of [AuBr4l-onto the carbon surface where reduction to metallic gold took place. Elution of gold from the loaded carbon was feasible provided the carbon had not been loaded to too high capacity values. If loading is carried to high levels, complete elution becomes impractical and the gold may be recovered by ashing the carbon. For the high loading capacities observed, this option would appear to be cost effective. The effect of several variables on the loading capacity of the activated carbon is discussed.

Jan 1, 1992

By Li Qian

Mechanisms of bio-dephosphorization from iron ore was investigated in this Paper. The results show that there are two bio-dephosphorization ways from iron ore, the one is that Acidithiobacillus ferrooxidans directly derive phosphorus from the ore, the other is phosphorus is able to be leached acid produced during metabolizing of Acidithiobacillus ferrooxidans, and the latter is more important than the other. Adding suitable pyrite can enhance the bio- dephosphorization process through providing nourishment and producing acid directly due to S 3oxidized or indirectly due to Fe3 as oxidant. The potential varies in the range of 0.434~0.498V and pH is in the range of 2.5 ~ 1.25 during bio-leaching process. It can be founded that, according 2+to the E-pH graph of Fe-H2O system, Fe wouldn?t be oxidized under sterile system in this potential and pH ranges. It can be obviously concluded that the Acidithiobacillus ferrooxidans are 2+able to reduce the potential for the oxidization of Fe and make the oxidization occur in the above pH and potential zone, so the bio-leaching process can proceed. the investigation of E-pH graph of P-H2O system show that H3PO4 can exist steadily.

Jan 1, 2009

By R. H. Jefferson

An electrochemical method to selectively determine sulfur dioxide in the presence of sulfur trioxide was investigated. A hydrophobic gas-permeable membrane separates the gas sample solution from an internal filling solution containing a fixed quantity of chloride ion and a sufficiently large excess of sodium bisulfite so that its concentration may be considered constant. Sulfur dioxide diffuses through the membrane to dissolve in the internal filling solution and liberates an equivalent quantity of hydrogen ions. The electromotive force between a precision-ground, flat-ended pH electrode, which acts as the sensing element, and a chloride sensing electrode, which acts as the reference element, gives a direct measure of S02 in the gas sample solution. Calibration curves in water, tetrachloromercurate (TCM) , and citrate buffer absorption solutions were closely parallel with slopes in their linear segments, ranging from 57 to 52 mv/decade of S02 concentration. The slopes compare reasonably well with the theoretically expected slope of 58 millivolts at 21° C. The water standard curve was linear with respect to the logarithm of S02 concentration from 1 to 1,000 ppm S02; the TCM standard curve was linear from 10 to 2,000 ppm S02; and the citrate standard curve was linear from 30 to 5,000 ppm S02' The high efficiency and nontoxicity of citrate favor it as a substitute for the conventionally used TCM in the absorption solution.

Jan 1, 1976

By D. W. Bridges

Solvent extraction has become important in recent years as a unit process in extractive metallurgy. The flexibility and simplicity of the technique have attracted widespread attention, and numerous papers describing actual and projected metallurgical applications have been published. However, differences in terminology, procedure, objectives, and standards, as reflected in reports by different operators and investigators, have sometimes made appraisals and comparisons difficult. Consequently, a need appeared for n series of basic reports on the subject. This Bureau of Mines Information Circular is the first of such a series. It deals with the status of solvent extraction in metallurgy, as well as with the rudiments and terminology of the unit operation. In analytical chemistry, extraction of molecular species from aqueous media by immiscible organic solvents has been used for many years to separate and determine chemical elements (61).4 Complex chlorides of iron and other metals are readily soluble in ethers and ketones, as are the nitrates of uranium and thorium. Most metals are extractable as complex salts of some organic reagent, such as dithizone, 8-hydroxyquinoline, or cupferron.

Jan 1, 1962

By Patricia A. Wells

In the remelting of scrap, the ultimate goal is to produce clean aluminum while minimizing metal losses. Recently, it has become more difficult to make significant recovery improvements in Reynolds' Reclamation Plants since metal recoveries were nearing the theoretical maximum. In an effort to gain a better understanding of the factors impacting Reynolds remelting process, a series of experiments using a Taguchi-type design was performed. Specifically, the critical variables and interactions affecting metal recovery of shredded, delacquered Used Beverage Containers (UBC) melted in a side-well reverbatory furnace were examined. This furnace was equipped with plunger-style puddlers and metal circulation. Both delacquecing and melting processes operated continuously with downtime only for necessary mechanical repairs. The experimental design consisted of an orthogonal array with eight trials, each using nominal 500;000 lb shred charge volumes. Final recovery results included molten output and metal easily recovered from dross generated during the test.

Jan 1, 1995

By Andrew McNamara, Stuart Norman, Matthew Dearing, Michael Pelken, Asha Panchal

The deep foundations industry has largely remained unchanged since in the advent of CFA piling in the 1960s. Piles have consequently been designed and constructed following the traditional codes and standards without much regard for optimising in-life efficiency or end-of-life reuse. After existing developments have been demolished there is little motivation to reuse existing piled foundations as their load bearing capacity and structural integrity cannot be verified. Therefore piling contractors are increasingly spending more resources on coring through existing piles, only to be replaced with larger diameter or deeper piles. The hollow element of the HIPER® Pile provides access to the entire length of the pile to permit inspections and a shaft in which the pile can be extended if needed. This paper presents and compares the embodied carbon savings, both during construction and through foundation reuse, from a HIPER® Pile scheme compared with the traditional solid pile scheme. A discussion on the benefits of this technology and its implications on warranties and approvals is also presented to motivate the foundations industry to embrace whole lifecycle assessments and support the journey to net-zero carbon.

May 1, 2022

By U. Dmitrakova, G. Sedelnikova, D. Kim, E. Savari

"The paper presents the results of research on the development of gold and silver extraction technology from refractory gold sulphide flotation concentrate of one deposits of Nord-East of Russia. The concentrate is due to the complex mineral composition. Gold and silver are finely disseminated in sulphide minerals (arsenopyrite and pyrite partially oxidized by 7-11%). These are characterized by high content of silver 219 g/t and sulphide sulfur 32%, the presence of poorly soluble silver minerals (silver sulfosalts, fahlore, finely dispersed hypergenic acanthite in iron hydroxides and jarosite, etc.), and impurity minerals capable of interacting with cyanide (pyrrhotite, marcasite, nonferrous sulphides) and causing higher than normal cyanide consumption. Pretreatment of refractory sulphide concentrate by biooxidation using a mixed association of mesophilic and moderately thermophilic bacteria at a temperature of 36-40 °C for 120 hours oxidized arsenopyrite by 97.5%, pyrite by 93.5%, unlocked refractory gold, and generally oxidized the minerals absorbing cyanide and oxygen before cyanidation. Further oxidation of these minerals-absorbents was facilitated by the aeration in calcareous medium of the solid biooxidation residues of the concentrate. Sorption cyanidation of the solid biooxidation residues with addition of lead (II) of recovered 91.2% of gold and 82.9% silver from biooxidation residue, compared with 80.1% and 46.6%, respectively, for sorption cyanidation without the preceding biooxidation step. Biooxidation of the concentrate prior to cyanidation improves the recovery of precious metals, especially silver, and significantly reduces cyanide consumption from 18.7 kg/t to 3-5 kg/t of concentrate. INTRODUCTION Biooxidation of gold sulphide concentrates using acidophilic microorganisms has been successfully applied worldwide (van Aswegen et al., 2007; Gericke et al., 2009; Sovmen et al., 2007; Sovmen et al., 2009). At least 15 full-scale plants for tank biooxidation of sulphide concentrates are presently in operation, and the construction of new ones is planned (Bulaev et al, 2015)."

Jan 1, 2018

By Edward Cogan

Equilibrium phase diagram studies of zirconium- rare earth metal alloys by the Bureau of Mines at its Albany Metallurgy Research Center prompted the development of a rapid gravimetric method for determining rare earths in zirconium in which the rare earths are absorbed from sulfuric acid solution of the alloy on a cation exchange resin . The sample in 10 percent H2SO4 is introduced into the column , the zirconium is eluted with 10 percent H2SO4 , and the rare earths are eluted with (NH4 )2SO4 solution and precipitated with NH4OH . A tracer technique was employed to determine the efficiency of the procedure . Y203 and europium 154 - 152 (Oak Ridge ) were added to 10 g of zirconium and taken through the entire procedure . Recovery averaged 97.6 percent on 0.002 μg europium in the rare earth fraction . Rare earths were determined in the range 0.10 to 90 percent .

Jan 1, 1964

By Shadia J. Ikhmayies

The SnO2/CdS/CdTe thin film solar cells were fabricated on glass substrates by using the spray pyrolysis (SP) technique for the deposition of the SnO2 and CdS layers and vacuum evaporation for the CdTe layer. The transmittance curves were used to investigate the interdiffusion in the two interfacial regions SnO2/CdS and CdS/CdTe by taking the first derivative of the absorbance as a function of wavelength. The appearance of new bandgaps around the bandgaps of SnO2:F, CdS:In and CdTe layers is a strong evidence on the interdiffusion in the two interfacial regions and/or the formation of quantum dots.

Jan 1, 2010

By S. Duvah Pentiah

The transformation of an open pit coal mine to a horizontal-punch underground mine is subject to a number of challenges. These include scheduling the operation of various sizes of trucks over a long period, as well as updating delivery routes and dump site locations as the mine transformation progresses. In this process, rock is excavated from a quarry through earthworks. The bulk earthwork and quarry material delivery were initially drawn from traditional planning and experienced issues in their early phases. As a result, a traffic simulator was developed in order to validate schedules and predict achievable throughput, likely delays or blockages in the long term. The dynamic traffic simulator was also used to provide traffic density and vehicle arrival data at selected intersections in order to identify possible safety and efficiency issues.

Aug 1, 2013

By J. J. Dowd

1. The Pittsburgh bed is the most important bed in Ohio County, and virtually the entire production of coal in the county comes from this bed. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 tons per acre-foot of-coal in place, are estimated at 365 million short tons as of January 1, 1954. Of this total, 356 million short tons is in beds 28 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1955

By L. Byszynski

The results of a three month evaluation of the application of EMEW® technology at the KGHM Glogów II Smelter tank house bleed stream are presented. The current, conven¬tional electrolyte decopperization process has some limitations, including: only a fraction of its production is commercial grade cathode copper, significant operating costs, low current efficiency, low current densities resulting in low copper depletion rate, and arsine gas and sulphuric acid emission. The EMEW® cell technology developed by Electrometals Technologies Ltd. can overcome many of these limitations. Tests were performed on a pilot EMEW® installation comprising 30 cells at ambient temperature on electrolyte bleed, using current densities between 100 and 600 A/m2 , with copper concentrations between 45 and <1g/dm3. Results showed that a high grade copper can be obtained to the level of 7 g/dm3 of copper concentration in electrolyte. The use of EMEW® technology allows the direct and efficient recovery of over 85% of the copper contained in the bleed electrolyte. Glue & thiourea addition were tested in order to improve the parameters of the copper depletion process. The behavior of Arsenic and Bismuth was observed and a means for their elimination from the system proposed. On-line copper concentration monitoring is proposed to improve control and performance.

Jan 1, 2007

By A. W. Bryson, K. C. Lenthall

"With the growth in the use of cobalt in industry, interest in its extraction and recovery has increased. With this increased interest comes the need for a fundamental knowledge of the processes involved in the recovery of cobalt metal. This paper examines the effects of cobalt concentration, catholyte pH, operating temperature and current density on cobalt electrowinning with respect to the current efficiency, cell potential and nature of the cobalt deposit. It is found that the cobalt concentration and catholyte pH affect the current efficiency, while current density and temperature affect the cell potential and thus the specific power consumption. Pitting on the deposit is affected by the catholyte pH and the operating temperature. Furthermore, the effect of feed flow-rate on catholyte pH, and thus current efficiency, is investigated. A model to predict the cell performance, which includes the flux of hydrogen ions through the diaphragm, is proposed.IntroductionCobalt metal is a silvery transitional metal found between nickel and iron on the periodic table. Due to its resistance to corrosion and other properties under high temperatures and its good work-hardening characteristics, it is favoured in alloys used in high temperature applications. These include aerospace, aircraft and high speed tools. Other applications include its use as a colourant in glass and ceramics, a drying agent in paints, a nutrient for livestock, a catalyst in the petroleum industry and, in the medical field, in prosthetics and radiology.The main deposits of cobalt are found in Central Africa, specifically Zaire and Zambia, although deposits also occur in Morocco, Canada and Australia. The cobalt is generally associated with other transitional metals including nickel, iron and copper. It is generally extracted by hydrometallurgical means and recovered from solution by electrowinning or hydrogen reduction. Little data [1-2] exists in literature on the electrowinning of cobalt from aqueous solutions. This paper investigates the effects of various operating conditions on the current efficiency, cell potential and deposit nature under continuous operation."

Jan 1, 1997

By Essie Esterhuizen, John Ellenberger, Dennis Dolinar

"Underground stone mines in the United States use the room-and- pillar method of mining. The stability of the roof between pillars determines the mining dimensions and size of equipment that can be used. The findings of a survey of roof span stability issues and design practices are presented, and the observed factors contributing to roof instability are discussed. Identified stability issues are evaluated, such as maximum roof span, horizontal stress, and roof beam stability. The results of field observations, roof monitoring, and numerical analyses are used in the evaluation. The importance of the first roof beam thickness and its impact on roof stability and support requirements is presented. An evaluation of the current experience with stone mine roof spans relative to international experience is presented. A step-by-step design procedure is suggested which emphazises the need to collect adequate geotechnical data, understand the immediate roof stability, select a mining direction, and meet support requirements.INTRODUCTIONIn room-and-pillar mines, the roof between the pillars is required to remain stable during mining operations for haulage as well as access to the working areas. Roof and rib falls account for about 15% of all reportable injuries in underground stone mines (Mine Safety and Health Administration, 2009). Therefore, the stability of the roof is an important safety consideration. The size of the rooms in underground stone mines is largely dictated by the size of the mining equipment. Large mining equipment is used, requiring openings that are on average 13.5 m (44 ft) wide by approximately 7.5 m (25 ft) high to operate effectively (Esterhuizen et al., 2007). The dimensions of the roof spans are largely predetermined by the equipment requirements, and design is focused on optimizing stability under the prevailing rock conditions. If the rock mass conditions are such that the desired stable spans cannot be achieved cost effectively, it is unlikely that underground mining will proceed. In addition, large roof falls can extend across the full width of a room and may extend more than 5 m (16 ft) above the roof line. These large falls are a safety hazard and can have a significant impact on mine access and production. The National Institute for Occupational Safety and Health (NIOSH) research into stone mine roof stability has focused on identifying both the causes of roof instability and techniques to optimize stability through design."

Jan 1, 2010

By B. Weyerman

U. S. Steel&apos;s Oak Grove Mine experienced several top hinge failures on their caving shields. It was determined that all the caving shields needed to be replaced with new caving shields before more thilures occurred. The cost and amount of time needed for several scenarios of caving shield change outs were compared. This paper discusses how Oak Grove Mine decided to and did change 126 caving shields in six specially designed jig stations underground during a longwall move using their own UMWA employees.

Jan 1, 2001

By Marco Olper

The CX-EW technology, developed by B.U.S Engitec, is improved introducing besides the battery paste electrowinning, the direct electrorefining of metallic lead (grids and poles) obtained from CX breakers. This new concept of electrorefming the antimonial lead scrap is aimed to the production of 99.99 lead and of slimes with high antimony content, avoiding gaseous emissions in melting lead scrap, and expensive and pollutant thermic refining operations. In this way, practically all lead content in the battery is available as 99.99 lead, hence with a wider market for the lead recyclers. This paper will describe the tests performed on a pilot plant scale with special reference to the relatively low energy consumption of the process.

Jan 1, 1993

By R. W. Huber, R. C. Wiley, V. C. Petersen

"Three arc- melted ingots, two of a t itanium-7 percent manganese all oy and the third of unalloyed titanium, were forged and rolled into 3/ 4-inch plate; comparative data were obtained on these processes. The finished plate, part of which was used by the Naval Bureau of Ordnance, was tested for mechanical and other properties.These properties were correlated with sponge purity, forging technique, rolling temperature, and cooling rate from the rolling temperature. For the alloy material, transformation data were obtained, and their age-hardening characteristics were studied. The temperature-impact relationship was established for rolled sections from all three ingots.INTRODUCTIONArc -melted ingots of unalloyed titanium and a titanium-manganese alloy were fabricated into plate under closely controlled conditions by personnel of the Metals and Alloys Section, Physical Metallurgy Branch, Bureau of Mines, College Perk, Md. This program was cosponsored by the Naval Bureau of Ordnance. Bureau of Mines interest lay in correlating the processing procedures with the mechanical properties of the finished plate.Considerable data have been published recently on constitution diagrams and properties of titanium-manganese alloys in genera1. 3/ 4/5/6/ However, little if any correlation between processing schedules and end results has been published, particularly with respect to the present commercial production of the proprietary titanium manganese alloys . Several factors in the production of titanium and titanium alloys have a pronounced influence on the physical and mechanical properties of the finished product: (1) The degree and nature of impurities in the base materials, ( 2) the amount of impurities introduced during the melting cycle and their distribution, (3) the homogeneity of the alloy, (4) forging, (5) rolling, and ( 6) final heat-treating cycles. All of these item£ are important from a metallurgical standpoint in producing the desired end properties in the metal."

Mar 1, 1955

By S. A. Pirzada

A thermal plasma assisted laminar flow reactor has been used to evaluate the kinetics of converting alumina to sodium aluminate in flight. Free energy minimization calculations were used to determine experimental conditions. The experimental variables include: alumina particle size, alumina/sodium nitrate molar ratio, temperature and residence time. A mathematical model for the conversion was developed and validated. Experimental and mathematical results are presented.

Jan 1, 1996

By E. T. Turner

Introduction 1n assembling material for this paper on Wood Refuse Burning 1 turned first to the records of our early studies of the problem in order to learn how and why certain basic decisions were arrived at and also how it came about that the completed central steam plant differed so much from the original plans. It may be of interest, therefore, to outline the engineering problems as they presented themselves in the early part of 1948, and to indicate the economies involved. Although the principle of using wood refuse as boiler fuel instead of burning it to waste was quite sound, and in fact the practice had been in use for a long time in the boilers of many lumber companies, there was some guesswork as far as Hollinger was concerned in deciding how best to handle the large quantities of wood refuse involved and as to the type of boiler equipment necessary to .burn it efficiently. These problems will be examined first. Hollinger Boiler Equipment in 1948 Hollinger had four separate boiler houses, at Main, No. II, and No. 19 shafts, and a small unit at the compressor plant for heating purposes. Main and No. Il boiler houses operated all the year round; No. 19 and the compressor plant only in the winter. At Main there were four 36-year-old HRT boilers with total available h.p. of 500, at No. II, three 30-year-old HRT boilers with 195 available h.p., and at No. 19 two old field-type locomotive boilers capable of producing 95 h.p.

Jan 1, 1951

By E. A. Hewitt

This paper describing the mining practices at the Park Utah mine in the Park City district is one of a series being prepared by the United States Bureau of Mines on mining practices, methods, and costs in the various mining districts of the United States. The Park Utah mine is situated at Keetly, Utah, about 5 miles east of Park City. The Park City district lies on the eastern slope of the Wasatch Mountains, 25 miles southeast of Salt Lake City. The district embraces a tract located between the crest of the main range on the west and the mountain meadows along the eastern foothills. The elevation of the Union Pacific Railroad station at Park City is 7,000 feet above sea level. The town and mines are served by two railroads; one 28 miles long is a branch of the Union Pacific Railroad and connects with the main line at Echo Junction, east of Ogden; the other is 35 miles long and joins the Denver & Rio Grande Western Railroad at Salt Lake City. The district and mines are also accessible by excellent automobile roads from Salt Lake City and surrounding points (fig. 1).

Jan 1, 1930