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By Caisa Samuelsson, Taishi Matsushita, Hannes Holmgren, Sina Mostaghel

"Rönnskär Smelter of Boliden Mineral AB, Sweden, is a large end-processor of secondary raw materials and waste, including electronic scrap. Electronic scrap may introduce various impurities to the smelter's flow-sheet, among which alumina is a common and significant one. This article summarizes the results of an ongoing research at Luleä University of Technology, Sweden, to study the influences of alumina on different properties of slag from the zinc fuming process at Rönnskär smelter. A combination of different experimental techniques and thermodynamic calculations have been used to investigate properties such as density, surface tension, effective thermal diffusivity, viscosity, and melting/leaching behaviors. Results show that the addition of alumina to this slag increases the degree of polymerization of the melt, and physical properties vary correspondingly. Mineralogy of the semi-rapidly solidified samples is also changed due to alumina addition. A correlation between mineralogy and leaching behavior can be observed.IntroductionBoliden's Rönnskär Smelter is a base- and precious-metals producer located in north of Sweden. Its main products are copper, zinc clinker, lead, gold, and silver. Sulphuric acid, liquid sulphuric dioxide and iron sand (granulated slag) are some of its main by-products. In order to optimize the overall outcome of the process, different refining units are integrated in the smelter's flow-sheet (Figure 1). Copper concentrates and fluxing materials (mainly silica sand) are charged to the process. The produced matte is sent to the converter and the generated slag is charged to the fuming furnace, where it is treated by reducing gases to produce zinc clinker. The converter's slag is charged to the electric furnace, while the fumed slag is tapped into the settling furnace for further cleaning, where matte, slag and speiss (residual metals) are separated. The matte from the settling furnace is also sent to the converters; its speiss is sold to external customers; and its slag is water granulated and sold as construction material, which is known as iron sand."

Jan 1, 2012

By S N. Nyoni, K C. Corin, C T. O’Connor

Considering future water scenarios, as influenced by the increasing scarcity of water and the move towards sustainable process engineering etc, the closed water circuit becomes an important point of study in metallurgical operations, such as in milling and flotation. However, a deterrent in the use of recycled process water is often a lack of understanding of the effects of the accumulation of dissolved ions and other process chemicals. Recovery of the valuable minerals may be impacted by the concomitant complex mineral-pulp chemistry interactions. Literature indicates that these interactions are not necessarily antagonistic to process outcomes. Wet milling using steel media results in the dissolution of Fe from the media, the rate of which is dependent, inter alia, on the type of media and the chemical conditions of the aqueous environment in the mill. The pulp-phase interactions of dissolved ions with sulfide minerals may result in significant changes to the chemical conditions in the mill, which may subsequently impact negatively on the flotation recoveries. To understand the effect of these interactions in the context of the processing of sulfide minerals, this study seeks to consider the effect of three factors, viz mineral type – pyrite (Py) and galena (Gn) -, milling media of different compositions – forged steel (FS), 21 per cent high chrome and ceramic media -, and water chemistry, viz, deionised water (DI) and synthetic plant water (SPW). Ceramic media and galena are used for the respective control cases where the milling media and sulfide mineral contribute no Fe species. Using DI as a control case, a high ionic strength case is used to mimic the changes in water chemistry for a closed water circuit. Batch flotation tests are used as a diagnostic tool to determine the effects of these media-water-mineral interactions to investigate correlations between the chemical reactions occurring and chemical species present during the milling process and the ultimate flotation performance.

Aug 24, 2022

By Alastair Torrance, Gary Cavanough

Over the past two years a research project has been performed on reactive and hot ground. A key finding is that host materials including carbonates and coal are inhibitors to the reaction of sulphide and nitrates. The mechanism of this inhibition is pH buffering and isolating the surface of sulphide from reactants. It has been identified that acidity is a key driver of the reaction with a pH of 2 required for a reactivity event. A series of decomposition experiments confirmed that reactive and hot ground are essentially the same phenomenon with the heating produced either by the reaction of sulphide with nitrates or an external heat source. The results indicate that the key driver of detonation in reactive ground is energy and heat released from the acid induced reaction of sulphide and nitrate with no indications of sulphide being a catalyst or contributor to detonation apart from being a heat source. There must be sufficient sulphide and thermal insulation to provide and retain enough heat for detonation to occur. A pathway to detonation is postulated whereby the heat travels upwards and results in evaporation of water in the explosive. When the temperature reaches approximately 200°C (400°F) the ammonium nitrate starts to decompose, decreasing the mass of the reacting species. The material in the top layers has reduced density and specific heat hence the temperature of the top region rapidly increases up to >1000°C (1800°F) and may initiate detonation. Field tests on loaded blast holes support this proposed mechanism. Case studies are presented whereby the research findings are used to provide an analysis of historical reactive ground events.

Jan 21, 2025

By M. Fafard, F. Chevarin, D. Ziegler, H. Alamdari, M Kavand

"Carbon anodes, used in the Hall-Heroult process, are consumed by the electrochemical reaction to produce metallic aluminum. It is also consumed by parasitic reactions with air and CO2. The carbon anode is made of petroleum coke with different particle sizes, butts (recycled anodes) and coal tar pitch. The mixture of fine particles (less than 150 µm) of coke together with the pitch material forms a matrix, binding the large coke particles together. It is generally thought that the binder matrix is more reactive than the other anode constituents. This conjecture was not clearly proved in the literature. The present study is focused on the CO2 reactivity of binder matrix and anode constituents at 960°C, both under chemical regime (100% of CO2) and under a concentration gradient (diffusion). The apparent reaction rates of these materials were measured. The role of the binder matrix in anode consumption and its disintegration (dusting phenomenon) was discussed.INTRODUCTIONThe metallic aluminum production is one of the most important industries in Canada. The Al metal is obtained by the Hall-Héroult process. The principle of this process is the electrochemical reduction of alumina in molten cryolite carried out by an electrical current between carbon anodes and cathode at 960°C (Equation 1). The carbon anode is typically composed of calcined petroleum coke (65 wt.%) and recycled anode (called also butt, 20 wt.%) with coal tar pitch (15 wt.%), playing the role of cement to ensure the cohesion of the anode block."

Jan 1, 2016

By A Suwandhi, H Utama

PT. Indo Muro Kencana (PT.IMK) is a gold mine that is located in Central Kalimantan, Indonesia. Drilling and blasting activity is applied in order to support mining production. Drilling and Blasting (D&B) planning is conducted by its engineers. A drilling and blasting contractor conducts drilling and blasting activity. The objective of this paper is to evaluate the implementation of the scaled depth of burial (Chiappetta and Treleven, 1997) in explosive charging sheet application to increase blast efficiency. The function of the scaled depth of burial is to maintain stemming height above explosive charge in order to prevent the ‘over energy’ condition, to reduce the excessive fly rock possibility, to maintain rock fragmentation (digger’s productivity) and to increase blast efficiency. The focus of this paper is to implement the scaled depth of burial as a reference in D&B planning and practice, especially in designing stemming height. The purpose of this paper is to validate that the scaled depth of burial can be used as an engineering tool in D&B practice in PT.IMK. However, scaled depth of burial cannot applied as an engineering tool to determine stemming height above explosive charge for trim blastholes and secondary blasting area. In general, the implementation of the scaled depth of burial in PT.IMK is applicable for production blastholes (ore and waste blasting). In conclusion, it is clear that scaled depth of burial can be used as an engineering tool to create explosive charging sheet and also to increase blast efficiency (ore and waste blasting) in PT.IMK.

Jun 22, 2022

By Robert Lee, Pertti Paavola

Automated vibration monitoring and web-based data distribution has proven itself on the largest single construction project ever undertaken in Finland. The excavation for the Kamppi Center Project in the center of Helsinki was completed in November of 2003 and involved the removal of over 200,000 m3 (260,000 yd3) of rock and over 1,700 individual blasts. A system was installed, incorporating 37 discrete monitoring points located throughout an underlying metro station, and other surrounding underground and surface facilities. After every blast, vibration data was automatically transferred from the monitoring network to a server database. Stakeholders were able to access and review vibration reports on a password-protected website within 90 seconds of each blast. This allowed engineers to verify that recorded levels were in compliance with established limits, before proceeding with subsequent blasts. The data was also imported into a semi-automated Scaled Distance tool for analysis using linear regression techniques. This was used to determine, and adjust for trends in blast-induced vibration.Copyright

Jan 1, 2004

By Marc Legault

The Duparquet mining camp situated along the Quebec segment of the Porcupine-Destor Fault was the site of gold exploitation from 1933 to 1956 and 1988 to 1991. Numerous gold showings and deposits straddle the fault. An ongoing regional metallogenic study by the Quebec Geological Survey has identified five main types of gold mineralization, each showing a distinct style, alteration, control, metal content, and timing. In order to maximise the impact of this study, a 3D regional common-earth-model was constructed along a critical segment of the Porcupine-Destor Fault with the gOcad® technology. The realisation of this model required the maximum use of the public SIGEOM numerical database, as well as the recovery of significant private data from exploration company partners. The 3D model is also a powerful new dynamic exploration tool, which can be queried using geological criteria characteristic of the different gold deposit types. This 3D model can be modified and improved continuously by adding data from new drilling, mapping or geophysical surveys. The case of the Porcupine-Destor Fault illustrates the importance of 3D common-earth-modelling in delivering refined technological geological syntheses likely to attract significant investments from the mining exploration industry, especially for deep exploration programs within mature mining camps.

May 1, 2004

By L. C. IlsLey

Most State enacting bodies have deemed it necessary to specify a maximum speed at which men may be hoisted or lowered in mine shafts. Since most mine cages are not closed in, as are passenger elevators in office buildings, and since, ordinarily, neither the starting tin g nor stopping of the cage is as general as that of these elevators, such regulations are all the more necessary for the comfort and safety of the men. It is also quite generally recognized that it is dangerous to over-crowd cages. Hence, a number of States have limited the number of men that may be on cage at one time.

Jan 1, 1939

By O. Q. Leone

Excellent metal quality, with lower power requirement, is attained in electrorefining titanium by using internal heating of the fused-salt bath. An internal heater provides more effective heat utilization, simplifies structural components in cell design, and prolongs cell life by eliminating direct application of heat to the cell container. This Bureau of Mines report covers one phase of the research in progress at the Electrometallurgical Experiment Station at Boulder City, Nev., for improving the techniques and lowering the total power requirement for electro-refining titanium metal.

Jan 1, 1959

By Dale E. Berner

A new navigation dam at Olmsted on the Ohio River will be built "in-the-wet" using a lift-in construction method by the Washington Group/Alberici Joint Venture for the U.S. Army Corps of Engineers, Louisville District. Up to 4,000-ton precast concrete dam shell segments will be prefabricated on the Illinois riverbank and lowered into the river on a marine skidway and cradle. A 4,500-ton capacity catamaran crane barge will lift the precast concrete shells and lifting frames from the cradle, and transport them partially submerged to a piled foundation pre-installed underwater. Tremie concrete will be used to compositely connect the shells, piles and sheet pile cut-off walls. This paper focuses on the pipe-pile foundations for this half-mile long navigation dam, and for the temporary precast yard and marine skidway. The dam foundations are designed to resist large ground motions from the New Madrid Fault Zone, and selected production piles are designed to serve as landing piles to support the shells during the construction process. Specific foundation issues addressed in the paper include: pile load tests; production field testing requirements; controlled fixity 24-inch diameter pipe-pile design including seismic considerations; cut-off wall design; sheet pile cellular fixed weir design; isolation jOint design; and temporary works foundation designs for both the precast yard and the marine skidway, including testing of 42-in diameter pipe piles.

May 11, 2007

By Malcolm T. Hepworth

RECENT interest in thermoelectric devices has been directed toward studies of the properties of thermoelectric materials of semiconducting solid compounds with little attention given to ionic and semiconducting liquids such as aqueous solutions, fused salts, and mattes. One type of thermoelectric system is the thermocell: a nonisothermal galvanic cell with two identical electrodes at different temperatures connected by an electrolyte bridge. An electromotive force, v, is generated which is a function of the electrode reactions and the properties of the electrolyte according to the Eastman' equation: where S* is the entropy change of the system arising from the electrode reactions and by heat transferred by ion migration and by thermal conduction. The quantity nF is the product of equivalents passed and Faraday's constant. A value of S* of 23.06 cal per "C is equivalent to 1 mv-Faraday per "C. The symbol, a, is used for dV/dT in analog to the See-beck coefficient of solid-state thermoelements. de Bethune2 has calculated the temperature coefficients of the electromotive force of a large number of nonisothermal aqueous cells from measurements on the nonisothermal temperature coefficients of the standard hydrogen electrode, combined with data on the isothermal temperature coefficients of half-cells tabulated in the literature. Values of these coefficients (a) in de Bethune's compilation ranged up to 3 mv per C. In particular he reported a value of +2.059 mv per "C at 25'C for the cell: Fe (aqueous, unit activity) (aqueous, unit activity) written for the hot-electrode reaction. The positive sign indicates that the hot electrode is positive (an "n-type thermocell"). In analog to a solid-state p-n system, it would be possible to couple two thermocells together to form a system in which the figure of merit could be calculated by adding the temperature coefficients according to the relationship described by offee:' where a is the Seebeck coefficient in volts per "C, p is the specific resistivity in ohm-cm, and K is the thermal conductivity in watts per cm "C. Even though ionic systems have rather high electrical resistivities compared with semiconducting and metallic systems, it was felt that a preliminary study of one ionic system should be made to establish some basis for evaluating the possibility of a p-n thermocell for energy conversion. Accordingly the Fe", Fe"' system was studied as a possible component for a p-n system. A glass system was constructed consisting of two vertical water-jacketed tubes connected by a horizontal tube, Fig. 1. Platinum-black electrodes 1 cm by 1 cm in dimension were inserted in each vertical tube with thermometers to register the electrode-compartment temperatures. The temperature of the electrode compartments was controlled by circulating water from thermostatted baths around the electrode compartments. The electromotive force of the cell was then read by a potentiometer for zero current as a function of the temperature of the hotter electrode. Current output of the cell for varying external loads was also measured. The cell resistance was measured by means of a bridge circuit with 10,000 cps signal and oscilloscope. Resistance measurements were converted to specific resistivity by calibrating the cell with a solution of known conductivity.

Jan 1, 1965

By Howard I. Young

WHEN so many statements are being made relative to the requirements of zinc metal, it is difficult for some of us who are acquainted with the industry to visualize how it is possible to step up production so as to supply some of the fantastic requirement figures that are published from time to time. I shall attempt to approach this subject from the standpoint of existing conditions which affect production, also keeping in mind the price ceiling under which the industry operates. Total production of primary and secondary zinc in the United States for 1941 will be about 878,000 tons, to which should be added about 36,000 tons of Mexican slab zinc available for consumption or export from the United States, giving a total available of 914,000 tons. Production of slab zinc of all grades in 1942 should be 953,000 tons. Adding the available Mexican supply should bring the total to 989,000 tons.

Jan 1, 1942

By J. Castaneda, J. Schmidt

"INTRODUCTION Chino is an open-pit copper mining complex faced with intricate material routing requirements. Historically, this was challenging at the mine, in part because the shovel dig plan, haul plan, and dump plan were prepared completely separately. The mine now uses an integrated workflow for faster evaluation of schedules, which facilitates preparing balanced cutoff grade-to-equipment requirements, supports better mineral production, and improves schedule viability, while considering operational implications. Located in the state of New Mexico, Chino is one of nine Freeport-McMoRan mining operations in North America. This presentation discusses the benefits of implementing an integrated approach to tactical mine planning, and shares practical examples that were learned as Chino implemented an integrated tactical planning method. This includes improvements in completion time for preparing a schedule, minimal risk from manipulating Excel macros, data integration required to make short-term planning decisions, and better understanding of the mine plan’s effect in relation to the business’s key performance indicators. Ultimately, the integrated approach to tactical mine planning at Chino has led to production forecasts which are more achievable and reduced planning and execution variance. PROJECT OVERVIEW Chino mine is a porphyry copper deposit wholly owned by Freeport-McMoRan, the largest publicly traded copper producer in the world. Chino mine is located in Grant County, New Mexico, a short distance east of Silver City. Ore material mined from the pit today includes oxides, primary sulfides, and secondary sulfides. The mineralized material is sent to a mill, with a rated throughput of 42,000 tons per day, or to ROM leach pads with variable dumping capacities. At Chino, the short-range objective is to maximize total copper pounds sent to the mill, but no fixed cutoff grade accomplishes this for all periods. Instead, 12 different material classifications, including four sulfide classes that can feed either the mill or other destinations, and 38 cutoff bins, are aligned with the needs from operations, leaching, and the concentrator to create a schedule. Cutoffs vary from one week to another to cope with a highly intermittent ore body."

Jan 1, 2018

This list is part of the long-range conservation program of the Bureau of Mines and is intended for use by those interested in the Bureau's publications dealing with oil shale and shale oil. The items included represent 51 years of research by Bureau of Mines employees on oil shale and shale oil and are available at any U.S. depository library. DISTRIBUTION U.S. Bureau of Mines report series contain both free and sales publications. An asterisk (*) designates publications for sale. Such publications can be obtained from Superintendent of Documents U.S. Government Printing Office Washington, D.C. 20402

Jan 1, 1969

By F. P. Haver

The Bureau of Mines is developing a leach-electrolysis procedure to produce Special High Grade (SHG) zinc from sulfide concentrate without the generation of sulfur oxide gases. Chlorine-oxygen leaching of the concentrate yields zinc chloride (ZnCI2) which, after purification, is electrolyzed in a fused-salt cell to obtain molten zinc metal and chlorine gas for recycle. This paper describes a laboratory-scale investigation made to develop a procedure for electrowinning zinc metal from ZnC12. Zinc chloride by itself is not a suitable electrolyte because it fumes badly above its melting point and is a poor conductor of electricity. Other salts therefore must be added to prevent fuming and improve the conductivity. Optimum results were obtained with a KC1-LiCl-ZnCl2 bath at 500° C, using a current density of 5 amp/in2 and an electrode spacing of 0.5 inch. Under these conditions, SHG zinc was produced at a current efficiency of 94.3 pct and an energy requirement of 1.16 kwhr/lb. Fused-salt electrowinning eliminates the need to handle and melt cathodes and increases the production of metal per unit cell volume through the use of higher current densities than are possible with aqueous electrolysis.

Jan 1, 1976

By Jake Beale, Joe Wickline, M. Van Dyke, Ted M. Klemetti

A longwall coal mine in southwestern Virginia mining the Pocahontas #3 Coal Seam experienced a history of mining-related seismic events. The events were never large enough to cause concern until three major events occurred recording 3.4, 4.3, and 3.4 ML in 2005, 2006, and 2007 respectively. Two of the seismic events generated an air blast which damaged stoppings which fueled a mine fire in 2005 and 2007. The mine responded to the events by narrowing the longwall widths, changing ventilation controls, installing a 7-sensor seismic system around the active panel, and creating a mining hazard map to avoid similar geology in the future. All of the actions taken have prevented seismic activity from impacting mining operations, but it did not prevent other large seismic events from occurring (Van Dyke et al., 2018). In 2016, another large seismic event, measured at 3.7 ML, occurred in the gob that was reported by the local media and recorded by the United States Geological Survey (USGS). While the event did not directly impact mining operations, mine management wanted to know where and under what conditions could large seismic events occur in the future. The National Institute for Occupational Safety and Health (NIOSH) became involved to help understand what conditions precipitated these events so that future mine design could more accurately assess seismic hazards and reduce the risk to mine worker safety. Researchers at NIOSH and mine management created a seismic forecasting map that combined three factors: (1) overburden thickness, (2) sandstone thickness, and (3) the expected caving height of the gob. The criteria were developed based on the geologic data the mine collected from core drilling, e-log analysis, and fiberscope observations. The forecast map was able to provide an accuracy of 72%–85% of events 1.5 ML or greater and 100% accuracy of events that were 3.0 ML or greater based on historical data. The seismic forecasting map was applied to the entire future mining area to show areas where seismic potential could be the greatest based on current mine design planning, ultimately improving the ability of the mine operator to assess the seismic hazards surrounding active and future mining areas (Van Dyke et al. 2018). Following this research, the seismic forecasting map was implemented into the mine’s hazard recognition program and is continuously updated and evaluated prior to mining each longwall panel. This paper will cover in more detail how the seismic and lithologic data was processed and how the mine implemented a new seismic mitigation program based on the forecasting results.

Apr 26, 2022

By N Pirouznia, F Rashidi Nejad, S Naraghi

Sungun Copper Mine, which is the second largest copper mining operation in Iran has a large tailings storage facility with a seepage control dam located downstream of the main dam. Surface and groundwater in surrounding area of the tailings storage facility has been monitored for ten years. This paper will discuss the results of the surface and groundwater monitoring and seepage control at the Sungun Copper Mine. The results of the study show that if the tailings storage facility influence the water quality of the rivers, this effect is not significant, so that the prevailing parameters of the measured parameters were within the permissible standard of drinking water in Iran.CITATION:Rashidi Nejad, F, Naraghi, S and Pirouznia, N, 2018. Surface and groundwater monitoring and seepage control at the Sungun Copper Mine, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 439–453 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Gino Vogt

In mechanized tunnelling operations, performance, consumption and safety are main factors for jobsites. One of the most important components effecting these factors, especially in slurry TBM operations, are Slurry Treatment Plants (STPs). Inadequately dimensioned and designed STPs create bottlenecks for tunnelling operation and jeopardize time schedules and performance. Inefficiently planned STPs could drastically increase consumption figures such as electrical power, bentonite, water polymers, etc. Inaccurately selected and treated suspension properties can cause a high-risk potential for the whole project. This paper debates the relevant key parameters for STPs from start to finish of a project and its results in influencing factors from the manufacturer’s point of view.

Dec 1, 2022

By P. M. Mashaba, S. O. Bada

An advanced high internal phase water-in-oil (HIP W/O) emulsion binder and flotation with an internal dispersed water phase of 95 vol% was used to beneficiate South African weathered coal from discard dumps. Five coal samples with calorific values ranged from 8.48 MJ/kg to 20.94 MJ/kg were utilized. The performance of the HIP W/O emulsion was compared to that of kerosene in terms of the physicochemical properties of the clean coal products. A 5 kg/t emulsion binder addition produced a high-quality coal concentrate with 11.76% ash and a heating value of 28.61 MJ/kg from a sample containing 29.34% ash. Using the same dose and coal sample, kerosene resulted in a clean coal concentrate with 17.47% ash and a calorific value of 26.42 MJ/kg. Further samples were also beneficiated using 5 kg/t of W/O emulsion. The highest increase in calorific value was achieved from the beneficiation of a sample containing 48.71% ash, from 8.48 MJ/kg to 18.16 MJ/kg. It has been established that emulsion binders can upgrade coal samples dumped many decades ago.

Aug 2, 2022

By R. E. Mitchell

The environmental impact assessment (EIA) is the accepted method for evaluating proposed mining and other industrial projects to obtain regulatory approval and to help companies plan for responsible development. Another increasingly common evaluation system for proposed projects is the environmental, social and health impact assessment (ESHIA). An ESHIA differs from an EIA for its generally more comprehensive and inclusive approach to evaluating potential impacts, such as on public health, and other features such as an ecosystem services approach to assessing biophysical and community impacts. An ESHIA may also be required by certain lenders for financing major projects. In this paper, EIA standards for the province of Alberta, Canada are discussed and compared to ESHIA. It concludes with several recommendations for consideration.

Jan 1, 2012