Search Documents

By Shen Shen, Paul R. Ohodnicki, Samuel J. Kemion, Vladimir Keylin, Alex Leary, Joseph F. Huth, Michael E. McHenry

"Recent DOE workshops highlight the need for advanced soft magnetic materials leveraged in novel designs of power electronic components and systems for power conditioning and grid integration. Dramatic weight and size reductions are possible in these applications through operating at increased frequencies. This manuscript discusses processing and composition design approaches for optimizing FeCo-based nanocomposites for higher frequency operation at 100 kHz and above. The proposed strategy involves starting with prior compositions known to exhibit high inductions, optimal field crystallization induced anisotropy, and excellent mechanical and high temperature magnetic properties. Proposed alloy modifications for the applications of interest would include increased amorphous phase resistance, optimum induced anisotropy, and minimized or carefully engineered magnetostriction. Relevant process developments would target reduction of ribbon thickness by optimizing the casting process or post-processing treatments such as chemical thinning or rolling. Three archetypes FeCo-based nanocomposites are described including near equiatomic FeCo-based, Fe-rich and Co-rich alloys.MotivationSilicon steels are widely applied for 60Hz utility-scale transformers [1]. For applications at high frequencies, however, Si-steels exhibit unacceptable losses and ferrites are typically used due to their high electrical resistivity and good soft magnetic properties [2]. However, the low inductions offerrites have limited their applications in power electronics. Developments in rapid solidification have led to amorphous metal alloys and controlled nanocrystallization processing has resulted in state-of-the-art amorphous/nanocrystalline nanocomposite soft magnets [3-5]. Commercial utility-scale transformers made with Fe-based amorphous materials have been demonstrated to result in significant energy savings with an associated reduction in greenhouse gas emissions [6]. DOE workshops held in 2010 emphasized a need for advanced soft magnetic materials for the next generation of power electronics. For advanced power conditioning and grid integration applications, frequencies of 20 kHz up to -1 MHz are of interest depending on the power level [7]. Here, we review previous work and discuss the approaches to optimize FeCo-based nanocomposite materials for high frequency applications."

Jan 1, 2012

By Zhiqiang Zhou, Shengnan Zhou, Zizong Zhu, Yuchuan Ding

The effect of silicon on removal of phosphorus from high phosphorus Si–Mn alloy was investigated at 1673 K by CaO-based slag. It was found that the dephosphorization efficiency increases significantly as increasing the silicon content, which is due to the reaction between silicon and CaO at slag/alloy interface. The relation between silicon content with oxygen activity and phosphorus activity coefficient of Si–Mn melt was determined respectively as follows: lg aO = -1:55xSi - 1:67; ln rP = 9:26e xSi 0:0433 + 11:0839 The carbon content in Si–Mn melt decreases continuously with the increasing silicon content, meanwhile, the decreasing rate of carbon content becomes rapid when the mole fraction of silicon is about 0.32. Si addition is beneficial for both dephosphorization process and low carbon Si–Mn alloy production.

Mar 1, 2017

By Shilai Yuan, Huimin Lu, Zhijiang Gao, Panpan Wang

"Solvent refining of silicon through using Si-Al melts is a valid method to remove the impurities from metallurgical grade silicon (MG-Si) melt. The thermodynamic behavior of impurities Fe, Al, Ca, Ti, Cu, C, B and P in MG-Si during the solidification of MG-Si was studied based on the available thermodynamic parameters and experimental data. The morphology of inclusions was investigated by Scanning Electron Microscope (SEM). The chemical composition of inclusions in MG-Si and Al-Si melt was analyzed by EPMA. It is found that the amount of white inclusion reduces and most impurities are solved into the Al-Si melts. After solidification of Si–Al alloy using induction heating and acid leaching, impurities can be effectively removed. The solidification of silicon from the Si–Al melt is found to be more effective for purification than general silicon solidification.IntroductionPhotovoltaic energy is one of promising energy resources in a sustainable society because of its inexhaustibility and cleanliness. Although the production and installation of solar cells have increased significantly during the last decade, the cost of solar cell installation is still high. Multicrystalline silicon has now become the main material in the photovoltaic market because of its low production cost and because of the relative high conversion efficiency of solar cells made from this material, which has been studied for a long time [1-3].Electronic grade (EG) silicon (99.9999999% Si) is commonly used as the raw material to produce SOG-Si (99.9999% Si). Silicon produced from the chemical routes restricts the development of solar cells due to environment threaten, high energy consumption and low productivity. Purification of metallurgical grade silicon (MG-Si) is a low cost, environment friendly method. Although several metallurgical processes such as directional solidification, vacuum refining and electron beam melting [4], have been developed, the cost reduction and refining efficiencies for manufacturing silicon is still have to be further optimized.In the purification process, it is difficult to remove boron and phosphorus by the conventional metal refining method. The refining efficiency depends on the segregation behavior of different elements in solid silicon and the liquid phase. The segregation ratios of all investigated impurities were found to be much smaller than the segregation coefficients between solid and liquid Al-Si melts [5]. For instance, the segregation coefficient of B in Si is 0.8 at the silicon melting point (1687K), whereas it is around 0.2 when silicon is solidified from Si-Al melt at 1273K. For phosphorus the segregation coefficient is 0.06 when silicon is solidified from Si-Al melt at 973K°C, which is much less than 0.35 for recrystallization from liquid silicon. Since the segregation coefficient of boron in silicon is 0.8, it cannot be removed by directional solidification."

Jan 1, 2014

By T. Mutoh

Tellurium in raw slime has recently been recovered as copper telluride in Onahama Smelter & Refinery. The slime is decopperized with sulfuric acid solution in conventional leaching tanks. The pregnant leach solution containing 45 g/l of copper and 1 g/l of tellurium is introduced to a copper telluride recovering reactor. The tail solution from the reactor containing less than 20 mg/l of tellurium is recycled directly to circulation tanks of copper electrolysis. The impurities of the product copper telluride is kept below 1% without any purification.

Jan 1, 1990

By Ernst F. Eurich

(Cleveland Meeting, October, 1912.) ALEXANDER PARKES patented in England in 1851-52-53 a process for desilvering lead by means of zinc, making use of the greater affinity of silver for zinc than for lead, discovered by Karsten in 1842. The efforts in England to develop it commercially were not particularly successful, nor was the attempted introduction into the United States. This last was not surprising, as it was about the beginning of our Civil War, and at that period there was very little lead-bullion produced in the united States and there was no field for the process here. There was at that time on Staten Island an establishment that pattisonized lead, probably from Rossie, N. Y., and Chester, Pa., and possibly some Spanish lead, but the production of lead-bullion in the Far West had not yet begun. In 1864, Edward Balbach, of Newark, N. J., patented in this country a process for desilvering lead by means of zinc, and in 1867 Edward Balbach, Jr., patented a " movable black-lead retort with a neck, placed in a furnace," for the purpose of distilling the alloy of zinc, lead, and the precious metals. A brief comparison of the Parkes and the Balbach processes is interesting. The Parkes process as practiced in England consisted in stirring into silver-bearing lead, melted in a kettle, from 1 to 2 per cent. of zinc, cooling, skimming the alloy of lead, zinc, and silver that rose to the surface, liquating it in an iron retort, distilling the residual rich alloy in fire-clay retorts, thus regaining the zinc, and refining the desilvered lead at a low heat in a shallow cast-iron pan that formed the hearth of a reverberatory furnace. If the lead was too impure, it was first softened * Presented also at the Joint Meeting of the Institute and Section IIIa, Metal¬lurgy and Mining, of the Eighth International Congress of Applied Chemistry, New York, September, 1919, and here published by mutual agreement.

Dec 1, 1912

After considerable input from the mining industry, the Canadian Securities Administrators (CSA) finalised National Instrument 43-101: Standards of Disclosure for Mineral Projects. This Instrument, which became law across Canada on 1 February 2001, applies to all technical public disclosure on mineral projects and requires all technical disclosure to be based on the work of a æqualified personÆ (QP). While the QP is quite similar to the Competent Person in Australia there are important differences when it comes to all disclosure. This paper will summarise the main areas in which the Instrument introduces major changes to Canadian disclosure standards on mineral projects including the role and responsibility of the qualified person; the increased requirements to file technical reports; the incorporation by reference of the October 2000 CIM definitions of resources and reserves and additional rules governing written disclosure of scientific and technical information. In October 2001, eight months after the implementation of NI 43-101, the CSA compiled a list of frequently asked questions (FAQs) and CSA responses to assist mining industry participants and their advisors in understanding and applying NI-43-101. This document has been well received by industry. The CSA plans to update the FAQs when further guidance is requested. Two industry committees have been established to provide the CSA with technical advice on the application of NI 43-101. As recommended by the Ontario Securities Commission/Toronto Stock Exchange Mining Standards Task Force, the CSA has established an external industry advisory committee û the Mining Technical Advisory and Monitoring Committee (MTAMC) û to monitor the application of NI 43-101 and advise the CSA on industry and professional developments. The role of the CSA-Canadian Institute of Mining, Metallurgy and Petroleum (CIM) Working Committee on Reserves and Resources is to ensure that the future changes and updates to the CIM Standards can be efficiently and effectively incorporated in NI 43-101. During this first year, the Canadian securities regulators have seen an improvement in the quality of disclosure on mineral projects, which will increase investor confidence in the industry.

Jan 1, 2002

By J. R. Mackie

Reserve Mining Company, the first large-scale taconite pellet producer in the United States, mines it's crude ore at the Peter Mitchell Mire located on the eastern end of the Mesabi Iron Range near Babbitt, MN. The ore is processed at Reserve's beneficiation plant on the north shore of lake Superior at Silver Bay, M. The mine and plant are linked by a 47 mile, double track, railroad which is owned and operated by Reserve. (see Fig 1). At rated capacity, the mine can produce 33 million It/yr of crude ore, 15 million It/yr of waste rock and 1.0 - 1.4 million yd3/yr of glacial till stripping. Haulage of all mined material is accomplished using trucks. Ore is transported by tractor-trailer side dump units which have capacitys ranging from 83 to 110 long tons. Waste rock and glacial till is transported in end dump units of 50 to 120 LT capacity. Loading is accomplished by 11/13 yd3 power shovels and 7/10 yd3 front-end loaders.

Jan 1, 1985

By lndu S. Das

An analytical simulation of the material characteristics of Inconel 718 is developed and bounds for mechanical and microstructural stability are obtained for isothermal and temperature-dependent cases. Experimental flow stress data using hot compression tests are reported for a wide range of temperature and strain at various strain rates. A parametric study of strain rate sensitivity, dissipation and entropy are presented. A complete set of processing maps delineating the stable and unstable regions are developed to help define the most efficient means of manufacturing an Inconel product.

Jan 1, 1992

By Daniel Augusto Godinho de Carvalho

At thyssenkruppCSA, a positive heat balance at BOF process is faced, mainly because of low utilization of scrap and plant design. A singular logistic concept for hot metal transport between blast furnace and steel plant was established to optimize transportation and energy balance. Up to 80 kg of iron ore pellets/t steel is necessary for 340t BOF heat balance. In order to accomplish this challenge a stable blowing process, intensive operational development have been successfully executed: slopping rate reduction of 80% achieved without changing the blowing time. This paper describes steps and results of this development.

Oct 30, 2017

By P. Bonadia, A. Tabereaux

Nearly all aluminium smelters are increasing the potline amperage to achieve higher aluminium production. In some instances the higher amperage operation has a significant negative impact on shortening the lifetime of aluminum electrolysis cell cathodes due to loss of the protective sidewall cryolite ledge freeze and too rapid penetration of the cell bottom refractory lining by cryolitic bath components due to the higher temperature isotherms. Thus Cathodes require careful thermal modeling of the cathode relining designs and improved refractory materials to allow greater heat loss from the sidewall to preserve a stable sidewall ledge freeze at higher amperages, and the selection of optimum refractory barrier materials to control the penetration and reaction of bath into the cathode bottom refractory and insulation lining. This requires an understanding of the reaction mechanisms and product formation for molten NaF enriched bath and alumino-silicate refractories. It is desirable to use dense, low porosity refractory fireclay firebricks, or similar materials with a sufficiently high silica content to promote the formation the mineralogical phase albite, NaAlSi3O8, that significantly increases the viscosity of the melt which slows the diffusion of reactive species in the melt and thereby retards further bath penetration.

Jan 1, 2004

By B McFadzean, N P. Lima, D A. Deglon

The reverse flotation of Itabirite iron ore is typically performed after a desliming step in which most of the sub-10 µm particles are removed. This is done to limit processing problems such as poor flotation recovery of SiO2 due to slime coatings and increased slurry viscosities, unmanageable froths and increased losses of hematite particles due to entrainment. However, the rejection of ultrafine particles contributes to large losses in iron recovery and may contribute to the instability of tailings dams. The aim of this study is to decouple the effects of ultrafine particles in the pulp and froth phases to better understand the processing capabilities of the fines fraction. The flotation test work was performed in a special-purpose continuously operated laboratory flotation cell that has a deep froth section to simulate plant-scale froth conditions. Five conditions of fines addition were investigated at three different froth heights and a solids concentration of 50 per cent. The behaviour of the pulp and the froth were decoupled using froth stability and froth recovery tests. This showed that, even though there is an exponential increase in froth stability at increasing fines quantities, the performance of the pulp has the overriding effect on the overall SiO2 recovery. Pulp zone, froth zone and overall SiO2 recoveries showed that overall recoveries increased by about 3.6 per cent for every 1 per cent decrease in fines content. This meant a large increase of 20 per cent in SiO2 recovery when going from undeslimed to deslimed feed. This was driven largely by increases in the pulp zone recoveries, which were about 4 per cent for every 1 per cent decrease in fines content. The froth recoveries, on the other hand, decreased by between 0.75 per cent and 2.5 per cent for every 1 per cent decrease in fines content, depending on froth height. This paper explores further insights into iron ore flotation processing at different slimes concentrations.

Aug 24, 2022

PRESIDENT MOSES.: The meeting will please come to order. Will you kindly state your names prior to making any statements, in order that we may deep the record straight? The first paper this morning is a joint one on vocational training, by D. W. Rockey, H. A. Tiemann and Wm. Moorhead. Mr. Rocdey. (Applause.) D. W. ROCKEY (State Superintendent, Industrial Education, Santa Fe, New Mexico) (Mr. Rocdey's notes not received in time for publication.) MR. TESCHER: I would like to ask you, Mr. Rocdey, you say you gave the Phelps-Dodge Corporation financial assistance; to just what extent was the State obligated, and how much assistance was given, etc.?

Jan 1, 1927

By B Vietnieks, N Widmer, L White, E Tata, J Natukunda, D C. Ilouga, J P. Tyler

The Republic of Uganda aims to exploit its’ significant, un-developed iron ore resources to supply the required raw material for developing its’ iron and steel industry across all the stages of the supply chain. Large prospects of iron ore exists in Uganda in the eastern (Tororo) regions and southwestern (Kisoro-Kabale) regions of the country. The Kisoro-Kabale iron ore projects covers mineralisation in hematitic banded iron formation (itabirite) in the north-eastern Congo-Tanzania Craton; covering ten Iron ore prospects. The prospects include Kamena, Karukara, Nyamiringa, Kyanyamuzinda, Rugando, Katagata, Rwengongo, Kijuguta, Kihumuro and Katuna. High-grade hematite ore prospects in south-western Uganda have known grades ranging from 55 per cent to 68 per cent iron ore content with an exploration target estimated at over 500 million tonne (Mt). Small scale production of iron ore from the south-western regions provide raw material to existing steelmaking and direct reduction iron ore plants located in the Jinja and Iganga districts of eastern Uganda. Large quantities of iron ore and other steelmaking raw material, however, are required to be imported into Uganda due to the limited exploration and development of their own iron ore mining operations. A joint collaboration between the European Union (EU), the Department of the Geological Survey and Mines (DGSM), Ugandan Ministry of Mines in partnership with Australian drilling and mining consultancies, ADT Africa and Kalem Group as a EU funded project was undertaken during November 2022 and September 2023. Exploration and evaluation of the ten iron ore prospects in south-western Uganda was undertaken through geological mapping, drilling, assaying, and technical studies with the view to attract investment for the development of Uganda iron ore mining and steelmaking industry. The collaboration developed mineral exploration policy, guidelines and standards, an iron ore exploration manual, a geological data management policy, and to support the sustainable development of iron ore mining in Uganda through building the capacity of local Ugandan geology and mining personnel through the transfer of knowledge and expertise from experienced iron ore experts. The quantification of these resources is an important first step in assessing their economic potential and attracting mining investors. This paper presents an overview of the investigation program and the preliminary results as an important first step in attracting mining investors to this exciting new iron ore province.

Sep 18, 2023

By J. A. Batista-Rodríguez, F. J. López-Saucedo

A new methodology is proposed for the preliminary assessment of coal blend quality, which combines gamma-ray spectrometry and magnetic susceptibility measurements. This methodology does not replacethe conventional methods of assessing coal quality, but can help to control the quality of the coal blending process, as well as reduce the amount of proximate analysis required and the determinations of calorific value and total sulphur. The methodology includes five steps. First, both geophysical measurements aremade with handheld equipment. The samples with magnetic susceptibility ≤ 1 × 10-3 SI are then separated. From these samples, those with total gamma intensity ≤ 20 nGy/h are separated. These samples have a higher calorific value and lower ash and moisture content. To separate the samples of better quality and with lower total sulphur content, in step four the samples with total gamma intensity > 20 nGy/h are separated from those with magnetic susceptibility ≤ 1 × 10-3 SI. This last group includes samplesthat will cause less total sulphur-related environmental pollution. In the final step, the quality of both radioactive sample groups is corroborated from the calorific value measurement and ash, moisture, andtotal sulphur contents in at least 10% of all coal blend samples from both groups. In this study, more than1000 samples were analysed with this new methodology, and the results are remarkably similar to the ASTM classification of the Sabinas Basin coals.

Apr 2, 2022

By Steve O. Green

Introduction The US coal mining industry is in the midst of a serious economic crisis. To overcome increased operating costs, operators must take advantage of technological advancements in mining systems and equipment. A relatively new concept available to underground operators is that of extending the cutting depth for continuous mining machines (continuous miners). This system is referred to as deep-cut mining, and may be described as mining cuts to depths greater than the standard 6 m (20 ft). Productivity is increased through the reduction in continuous miner tram time since the machine stays longer in each working face. To successfully implement a deep-cut mining system, three problems must be overcome: Exposing personnel to unsupported roof, methane removal, and controlling respirable dust. Remote control cutting The solution to the unsupported roof problem is remote control. Recent advances in remote operation, especially in radio remote controls, have resulted in what is generally accepted as a safe and reliable tool. By installing remote control on the continuous miner, the operator and helper can now be stationed in a supported area. This allows for improved visibility while cutting coal. With this in mind, the limiting factor now becomes the position of the haulage equipment operator. North River No. 1 uses Joy 21SC shuttle cars and Jeffrey 4110 diesel ramcars. These cars are pulled against the bumper of the continuous miner. Thirteen meters (43 ft) can be cut with the shuttle car and 14 m (45 ft) with the Ramcar before the operator of the car is inby permanent supports. By loading away from the bumper, about 1.5 m (5 ft) can be added, bringing total cut depths up to 14.5 and 15 m (48 and 50 ft), respectively. Methane removal The second problem involves methane removal, and the line curtain-to-face distance. In other words, how to maintain the line curtain to allow sufficient ventilation to remove methane and not expose workers to unsupported roof. The solution, in most cases, is to use a blowing-type ventilation system. Unlike the exhausting system that, to be effective, must be installed within 3 m (10 ft) of the working face, the blowing system can be effective at greater distances from the face. Numerous studies have documented the advantages of a blowing-type ventilation system over an exhausting system. Furthermore, a blowing system can be significantly improved by in¬creasing the velocity of the air delivered without increasing the volume of air. With this greater ventilation efficiency, it is possible to secure ventilation plan approval from the Mine Safety and Health Administration (MSHA) for a greater curtain set-back distance. This eliminates the need for personnel to travel inby permanent supports to extend the face brattice. The distance from the face MSHA will approve, however, is on a mine-by-mine basis. MSHA will evaluate the particular mine's face methane liberation rates, along with the specific proposals regarding face ventilation volumes and velocities. Dust control The third problem is controlling respirable dust. This is actually a result of the solution to the second problem. In the blowing system, while mining on the slab cut, both the continuous miner and haulage units are located on the dusty side of the line curtain (Fig. 1). In the early 1970s, underground operators virtually abandoned this system, in order to comply with the 2 mg/m3 (0.87 gr per cu ft) federal dust standards. The blowing face curtain did offer increased face ventilation efficiency. With that, greater curtain-to-face distances were also

Jan 8, 1987

By B. Simonian

"The Mount Milligan mine, located in central British Columbia, began operation in September 2013 with a design nameplate capacity of 62,500 dry metric tonnes per day, using a conventional SABC grinding circuit followed by bulk sulphide flotation. Over the last few years, many changes have been implemented in order to debottleneck and optimize the comminution circuit to meet and exceed the nameplate design capacity as well as improve the metal recovery of the flotation circuit. This paper discusses changes, grouped into mechanical modifications, projects, and operational changes. The implementation of these changes as well as ongoing challenges and potential solutions will also be discussed.INTRODUCTION The Mount Milligan mine began production in the fall of 2013. It is a conventional truck-shovel open pit gold and copper mine and concentrator with a 62,500 tpd design capacity copper-gold flotation processing plant. The average head grades for the life of mine are 0.18% Cu and 0.39 g/t Au. At full capacity, the mine produces an average 400 dry tonnes per day of copper-gold concentrate containing approximately 21.5% Cu and 50-60 g/t Au. Current mine life is 21 years. This paper will discuss a selection of the operational, engineering, and administrative changes that have been made at the site since the publication of An Update on Reaching Nameplate Throughput and Continuous Improvement at Mount Milligan (Yue, 2017). PLANT FLOWSHEET CONFIGURATION Run-of-mine ore is crushed through a 60-110 gyratory crusher to a top size of seven inches. Up to 100% of the gyratory crusher product is diverted to the secondary crushing circuit by a moveable gate. The material diverted to the secondary crushing circuit is fed to a vibrating double-deck screen. The screen oversize is placed on a surge pile and reclaimed by four vibrating feeders to feed two 1250 kW standard head cone crushers in open circuit. The screen undersize is combined with the crusher discharge and returns to the conveyor feeding the coarse ore stockpile along with primary crusher product that by-passes the diverter gate."

Jan 1, 2019

By Thomas P. Forbath

THE sudden realization that known sulphur reserves amenable to mining by the Frasch hot water process are nearing exhaustion focused attention on widely scattered surface deposits throughout the world. These deposits are not necessarily of lower sulphur content than ores located underneath Louisiana or Texas salt domes which usually average about 30 pct sulphur disseminated in limestone matrix. Their near surface occurrence, however, renders exploitation by the Frasch process impossible. As is well known, the Frasch process depends on the presence of 500 to 1000 ft of overburden and cap rock above the sulphur deposits to permit melting underground sulphur in place by diffusing hot water under pressures of 200 to 600 psig in the formation and raising the molten sulphur to surface by air lift. This process renders possible the production of pure sulphur which is 99.5 pct pure without any subsequent treatment. Surface deposits contain sulphur in the same range of concentrations as the salt dome deposits, i.e., from 10 to 50 pct sulphur, associated with various gangue materials such as silica, limestone, and gypsum. The pirincipal distinction, then, does not lie in the percentage of sulphur contained in the ore, but in the geological nature of the deposit. A recent study' of the world sulphur supply situation estimated 1950 sulphur production in the free world countries at 5.6 million long tons, of which the United States produced 5.2 million tons, or 93 pct of the total. While America's domestic needs alone would have been covered by national production, about 1.4 million tons were exported during the same year. Despite all the steps which are being taken to restrict use of elemental sulphur and to force the fullest possible development of alternate sulphur sources here and abroad, the deficit in elemental sulphur production will probably increase with time. As a result of intensive prospecting for oil throughout the Gulf Coast area discovery of significant new salt domes is held unlikely. With the growing scarcity of sulphur and what appears to be an inevitable rise in price, recovery from deposits not amenable to Frasch-process mining assumes greater economic importance. Untapped Reserves The most important deposits in this category are located in Sicily, where elemental sulphur occurs in Miocene limestone and gypsum formation. Sulphur content of these ores ranges from 12 to 50 pct with an estimated average of 26 pct. Although quantitative estimate of these reserves is not available it is held that they exceed 50 million tons of sulphur. Similar deposits occur also on the mainland which contribute about one-third of Italy's total current annual production of 230,000 tons, but these are known to be nearing exhaustion. Significant surface deposits of volcanic origin are located in South America, Japan and western United States, silica being characteristic gangue con-stituent. The largest of these deposits are in South America. More than 100 extend over a zone 3000 miles long, paralleling the west coast of South America. 'Total sulphur content of these deposits has been estimated to be as high as 100 million tons. The main islands of Japan also possess at least 40 known volcanic sulphur deposits with probable reserves of 25 to 50 million tons.' Prospected reserves in western United States might amount to 2 million long tons, principal deposits being located in the northwestern part of Wyoming, southern Utah, and eastern California. Volcanic deposits of lesser importance are found around the Mediterranean, in Turkey and Greece, and in Africa, Egypt, Abyssinia, and Somaliland. Beneficiation Methods Different methods of beneficiation have been used in these various locations. In Italy the Calcarone kiln and Gill regenerative furnaces are used exclusively. Both utilize heat liberated by burning part of the sulphur in the ore to liquify or vaporize the remaining sulphur, which is recovered by solidification or condensation. The Calcarone kiln is of conical shape, generally 35 ft in diam at base and 18 ft high. A kiln of 25,000 cu ft capacity burns for about two months and yields about 200 tons of sulphur. The Gill furnace consists of a series of chambers with domed roofs. Sulphur is burned and melted in one chamber at a time and the hot combustion gases are used to preheat the ore charge in the subsequent cell. These furnaces operate on a cycle of 4 to 8 days. The recovery yield of both systems is about 65 pct. Sulphur losses amount to 25 pct through the combustion to sulphur dioxide; about 10 pct is retained in discarded calcines. Ores containing less than 20 pct are not considered suitable as furnace feed. These methods are not only wasteful because of the low recovery obtained, but represent a serious atmospheric pollution problem. Sulphur produced ranges from 96 to 99 pct purity and thus does not match Texas or Louisiana sulphur. Owing to the present shortage, sulphur in the Middle East sells

Jan 1, 1954

By A. T. Sutaone

"In the Dongri Buzurg Manganese Mine of M/s Manganese Ore (India) Ltd., high grade lumpy manganese ore required for iron and steel industries is produced through multi-stage crushing and screening. This has resulted in accumulation of 50,000 tonnes of low grade fines over the years. This production of such fines is still going on. The fines create environmental problems, like air and water pollution and siltation in adjoining fields. Besides containing lot of manganese values, they occupy large space which is very scare in mining area.The Indian Bureau of Mines under one of its statutory functions has suggested the company to explore the possibility of recovery of additional values under conservation and environmental aspects. Hence the company has sponsored a bulk sample for beneficiation studies in the Modern Mineral Processing Laboratory and Pilot Plant of Indian Bureau of Mines at Nagpur, India. The main manganese minerals present in these mine rejects have been identified as pyrolusite and psilomelane. The purpose of this study was to explore the possibility of evolving a suitable beneficiation flowsheet to obtain manganese concentrates assaying over 72% MnO2 to be used as raw material for the manufacture of dry cell batteries.The sample/material was subjected to characterisation studies in terms of chemical analysis, granulometry and mineralogical compositions. Based on these characterisation studies, the beneficiation process developed comprised of desliming, jigging and low intensity magnetic separation mainly to reject quartz, silicates and jacobsite. The manganese concentrate thus produced assayed 70.2% MnO2 with MnO2 recovery of 78% and weight per cent yield of 63.5. This natural concentrate could be mixed with the electrolytic manganese dioxide produced by the company and this blend can thus be used as a raw material for the manufacture of dry cell batteries by the end users. The paper deals with the details of test work carried out in evolving the process flowsheet."

Jan 1, 2003

By G. Van Weert, A. van Sandwijk, O. W. J. S. Rutten

"Cathodic and anodic reactions in an acidic nitrate medium were studied in reference to the production of electrolytic manganese dioxide from pyrolusite' (Mn02) ores by reductive leaching. Two USA ores were investigated. The reductant for the pyrolusite ore is produced cathodically in an electrolytic cell and can either be nitrous acid (HN02) or nitric oxide gas (NO). In this work emphasis was placed on the nitrous acid leach. In a high-temperature leach in a nitrous/nitric acid medium, manganese and silver are solubilized and iron is not. Anodic electrowinning of manganese dioxide from the acidic manganese nitrate electrolyte yields flaky y-Mn02, similar to that produced from sulfate and chloride electrolytes. Cathodic regeneration of nitrorts acid was studied in a membrane cell in 1.0 M nitric acid and 0.0 to 0.1 M nitrous acid on a' platinized titanium cathode. At cathode potentials ranging from +950 to +700 mV (SHE), cathodic reduction to nitrous acid takes place, at cathode potentials < +700 mV, cathodic reduction of nitrous acid to nitric oxide takes place. A conceptual process is presented and discussed.IntroductionManganiferous-silver oresLarge reserves of manganiferous-silver ores are present in the Southwestern United States and Latin America. These ores are generally refractory to hydrometallurgical methods of treatment, due to the insolubility of the higher oxides of manganese (Mn 4+) in all common lixiviants such as cyanide solutions, dilute sulfuric acid, nitric acid, ammonia, salt solution, thiosulfates, etc. The silver is either bound by the insoluble manganese, or is rendered inaccessible to cyanide leach solution by the surrounding manganese mineralization.Higher oxides of manganese will dissolve if they are first reduced pyrometallurgically to manganous oxide (Mn2+). This is a widely used pretreatment for manganese dioxide ores and subsequent dissolution in sulfuric acid is common. In order to avoid the pyrometallurgical pretreatment with its large energy requirements and gaseous emissions, fully hydrometallurgical processes have been proposed. These processes are based on the presence of a reductant in solution, in order to reduce the insoluble higher oxides of manganese to soluble lower oxides. Aqueous S02 has been proposed and tested on industrial scale by the U.S. Bureau of Mines. After washing, silver could be extracted by cyanidation. The neutralization of the pulp prior to cyanidation however causes problems in filtration and the reagent consumptions are high [1]. More recently, acidified thiourea and bacteria were proposed for the solubilization of both manganese and silver in a single leach step. High extractions were obtained, but drawbacks of these methods are high reagent consumption or slow kinetics [2,3]. For the options of manganese recovery from the leach filtrate, precipitation with persulfate or ammonium carbonate and ion exchange have been proposed. The proposed options for silver reclaim are precipitation with either zinc or Na2S and adsorption onto activated carbon."

Jan 1, 1997

By Christopher Newman, Robert Dupuy, David Newman

"The development of a multiple level underground mine is a complex task in which geology, engineering, ground control, and unit operations are integrated into a single mine design. The components are inter-dependent and must function cohesively to ensure a profitable underground mining operation. To optimize reserve recovery, mine planning should begin from the lowest level and progress up. This limits any misjudgments or oversights of a given level affecting the underlying levels and ensures the ability to maximize recovery from each level.Mine planning should start with the exploration and characterization of the geologic setting. Once the reserve geology and quality is well understood, then mine planning can begin with respect to the following:,Orientation of mine works with respect to horizontal stress,,Access to the reserve,,Determination of opening widths,,Selection of back, floor horizons and pillar centers,,Selection of development and secondary mining heights,,Appropriate interburden thicknesses, and,Examine the stability of the multiple level mine through numer¬ical modeling.The multiple level mine design process and decisions are presented through a case history example. The theme is that there is one opportunity to “get it right” as well as many chances to overlook a small aspect within the design that will plague the mine throughout all levels and through the entirety of its operating life.INTRODUCTIONAs surface quarries reach their economic stripping limit and encroach on mineral and/or reserve boundaries, they approach the end of surface mineable reserves. Furthermore, modern urban sprawl has placed previously remote surface quarries within suburban development and neighborhoods, leading to significant increases in noise, dust, and vibration grievances by the community and regulators (Newman, 2017). Many mining operations have begun year-round production of underground reserves to meet growing market demands. This does not permit the typical sequence of stripping overburden in the winter to provide limestone to mine during the construction season. Underground stone mining operations in the United States commonly utilize a room-and-pillar mine layout with drill-and-blast production methodology for the development of the reserve. Within the Midwest and Eastern regions, thick and flat-lying limestone formations lend themselves to the utilization of multiple level mining layouts. While a multiple level mine plan will increase the overall recovery of the reserve, greater overburden depths, multiple level geometry, and the presence of discontinuities all require an emphasis on ground control for the planning and development of a safe and productive multiple level underground stone operation."

Jan 1, 2019