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By G. H. Khoe

Although some hydrometallurgical process liquors contain significant amounts of ferrous and arsenate ions, no reliable thermochemical data for the aqueous complexes and the solubility of the ferrous arsenate precipitate are available. The complexation of iron(11) with arsenate has been investigated using the potentiomemc titration method. The results indicated that virtually no complexation of iron(@ with arsenate has been observed. This is in contrast to the significant complexing reported for iron(1n) with arsenate. The solubility product of the precipitate was calculated using the concentrations of appropriate arsenate species pertaining to the observed precipitation pH's. The fit of the observed precipitation points on the solubility curve of the computed stability diagram was used to assess the appropriateness of the equilibrium model.

Jan 1, 1991

By Donald Christofferson

This report documents the program conducted to demonstrate the application of a flywheel-powered propulsion system to underground mining shuttle cars. Such application can replace the present electrical trailing cable common to most shuttle cars and thereby eliminate those safety hazards, maintenance problems, and haulage route limitations inherent in the trailing cable. Described are the activities undertaken to specify and design a flywheel of optimum size, shape, and material; to identify the best concepts of input and output systems; and to achieve installation of the power package into a shuttle car. The resultant Flywheel-Powered Shuttle Car is an FMC Model 6L shuttle car, 6-ton capacity, 20-ton gross vehicle weight, powered by a flywheel system with 4.5-kilowatt-hour usable energy. The completed vehicle was delivered to the Bureau of Mines in Bruceton, Pennsylvania, for testing and evaluation.

Jan 1, 1986

Jan 1, 1988

By Ron F. Schritt

Over the many years since the development of the steam powered shovel, various powering and control techniques have been employed for the various shovel functions. While volumes have been published on this subject, this paper will be limited to a very brief discus-sion of one of the latest of these and its application to a unique machine. The evaluation of the subject machine is far beyond the scope of this discussion, which will be limited to the techniques and equipment employed, and the considerations involved in their choice. The basic requirements for any power and associated control system for any power shovel function have remained relatively un-changed over the years. To the extent possible, such an equipment grouping must be: Easy to install during fabrication Easy to maintain and repair by available personnel Life cycle cost competitive Adequately reliable Adequately responsive And as may be expected these factors are arranged in various orders of priority by different manufacturers and users. All the various time honored approaches have to some extent fulfilled these require-ments but were discarded or fell into disuse when more effective approaches were developed. The latest in this long line of develop-ments and perhaps the most promising is that of electro-hydraulic controls and hydraulic drive.

Jan 1, 1977

By Karl Dufresne

Blasting in geothermally high temperature ground and/or extremely reactive ground is an increasing common challenge for surface and underground mines. Many current PETN based non-electric and electronic detonators have manufacturer published in-hole temperature limits ranging from 55°C to 65°C (131°F to 150°F). When confronting blasthole temperatures above the manufacturer published limits, operations may request site-specific guidance and qualification for use. The advised safe loading window for in-hole PETN based detonators is often too short to be practicable for production blasting. To overcome limitations of PETN based initiation systems, surface mines with high temperature ground and/or reactive ground are known to load blastholes with a qualified high temperature bulk emulsion that are top primed with a cartridge of temperature qualified detonator sensitive emulsion plus an RDX detonating cord downline. As there is no in-hole delay detonator in this system, blasthole timing is accomplished with surface delays. Although this system is safe, top priming and surface delaying does influence floor quality and top size fragmentation, and safe loading windows times reduce blast block size and increase blasting frequency. A mining company with a site characterized by geothermally high temperature ground plus highly reactive ground employed a blasting system like the one described above. The site desires to improve blasting performance by moving to an in-hole delay initiation system that can withstand the site ground conditions. At the request of the mining house, DynaEnergetics developed an electronic initiation system for application in geothermally high temperature ground and/or extremely reactive ground conditions. The DynaEnergetics IGNEO high temperature electronic initiation system is rated for in-hole use in ground up to 150C (302°F) for 48 hours. The detonator consists of a high strength detonator with an HMX base charge and thermally resistant downline. To make up a primer, the detonator is inserted into a booster charge assembly that is fitted with a small HMX shape charge. This high energy primer is designed to be compatible and reliable for firing bulk emulsions, including those with high percentages of urea inhibition to combat reactive ground. Up to 1000 detonators may be programmed in 1ms increments up to 1500ms. The system is controlled by a digital firing panel that can be used with either a wired or wireless trigger.  The system enables high temperature and/or reactive ground sites to utilize in-hole delay initiation and realize the associated performance benefits. Conclusions and Future Work 1] The HMX based electronic initiation system permits bottom in-hole delaying in ground temperatures above 80°C (175°F). As compared to top priming and surface delaying, in-hole bottom delaying is known to improve floor quality, muckpile fragmentation uniformity and reduce oversize. 2] Field evaluation of the HMX initiation system at the Lihir Mine is continuing. 3] Work on the next generation of the HMX initiation system is underway and will bring with it expanded application range and flexibility. 

Oct 1, 2024

By P. K. Hofmeyr

Traditional fire assay dates back over 3000 years and has changed very little over that time. The only improvement is to replace the gravimetric finish with dissolution of the Precious Metal bead followed by AA or ICP analysis of the solution. The newly developed FIP A (Fast In-line Fire Assay) method allows full automation of the fire assay process from sample preparation to spark analysis of the Pb button. This results in fully quantitative analyses for Pt, Pd, Rh, Ru, lr, Au and Ag in typically less than an hour after a sample is entered into the system. Detection limits are theoretically Pt 0.08 ppm, Pd 0.002 ppm, Rh 0.002 ppm, Au 0.08 ppm and Ag 0.002 ppm but in practice the lower measurable limits are about double these figures. Few opportunities have been available to present data obtained using the FIFA system as all FIFA laboratories have been in the domain of a Pt mining company which prefers to keep all Pt analytical matters confidential. However, IMP has recently participated in the round robin exercise to establish recommended values for a new series of Merensky Reef and UO-2 Layer reference materials produced by African Mineral Standards. The precision of the results was excellent being on average Pt 2.05%, Pd 1.25%, Rh 4.08% and Ru 4.94% being expressed as Relative Standard Deviation. The excellent precision is a reflection of the efficient collection of POEs in the Pb buttons and the homogeneity of the Pb buttons. However, the accuracy was not as good. The poorer accuracy is interpreted as the calibration of the spectrometer not being as good as desired due to the difficulty in acquiring a suitable range of standards with reliable recommended values for the PGEs. The most recent spectrometer was calibrated with the greatest care and produced slightly better results for Pt, Pd and Rh and slightly worse for Ru.

Jan 1, 2014

By Gabriel G. Walton

Conventional numerical modelling tools for analyses of underground excavations are well suited for modelling elastic behaviour and yield response of geomaterials with very simple constitutive behaviour. Non-dilatant elastic and perfectly plastic behaviour is most commonly used for preliminary analyses in the absence of the data required to consider more complex behaviours such as strainweakening and dilation. For truly brittle models, this deficiency is more acute. Current state of practice allows only for reliable estimation of the volume of failure, but not for any prediction of displacement. In fact, there is no consensus in rock engineering regarding the most accurate approach or most suitable tool to model the magnitude of the plastic deformation that strain-weakening or brittle rocks experience at tunnel boundaries, particularly when support is incorporated into these models. This problem is largely a function of a poor understanding of how inelastic dilation occurs in different types of rockmasses, the rate controls on strength loss and volume change during yield, and the complexities of rock-support interaction in yielding conditions.

Jun 1, 2012

By Andrew Hyett

Over the last 30 years, a transition away from end-anchored bolts to fully grouted rock bolt systems has occurred in many underground mines. It seems geomechanically intuitive that the success of such bolts, which interfere with rock movements around underground excavations through a variety of complex interactions, is precisely why they remain challenging to instrument and monitor. Whereas measuring the load profile for an end-anchored mechanical bolt is trivial, for a fully grouted system, the load may vary dramatically due to discrete rock movement at cracks and joints. Despite the challenges, measuring the strain (i.e., load) along fully grouted rock bolts remains very appealing, and a lot of valuable research has been conducted using foil resistance strain gauges, particularly in US coal mines (Signer and Jones, 1990). Despite good intentions, more widespread adoption of this instrumentation remains unlikely for the following reasons: (i) The technology is expensive, partly because Intrinsically Safe (IS) requirements limit the number of suppliers and solutions. (ii) The technology is perceived as challenging to successfully implement except by those who are skilled in the art. (iii) The reliability of the technology is questionable in harsh environments. (iv) The technology relies on discrete pairs of strain gauges that may not capture the complete strain distribution along the bolt. No existing alternative technology can offer a solution to all of these limitations. However, in this paper, we introduce results from a new Distributed Optical Sensing technology that promises significant potential. Since the technology is capable of distributed sensing, our results suggest that this new technology can, for the first time, reveal the detailed strain profile along fully grouted rock bolts.

Jan 1, 2013

By L. C. So, S. Faucher, S. Mostaghel, D. Sauter, S. -Y. Oh, S. K. Lee

"Molten material from pyrometallurgical furnaces is tapped at high temperature, carrying a large amount of heat. Traditional handling methods of slow air cooling or water granulation do not allow for the recovery of heat from slag and matte. Furthermore, water granulation adds an inherent safety risk of explosions. Recently, there have been numerous studies into processes attempting to recover waste heat. However, most of them have never been commercialized due to numerous challenges including scalability, cost, low heat recovery efficiencies, and difficulties in heat utilization. Ecomaister-Hatch has recently developed and commercialized a reliable and simple dry atomization system that allows for heat recovery while eliminating the use of water. Comparisons of pilot and commercialized dry atomization and heat recovery technologies will be presented and challenges of these technologies will be highlighted.INTRODUCTION Slag has traditionally been regarded as an undesired waste product from smelting operations with slag management focused on removal and disposal of “waste”. Over 500 million tonnes of slag are produced per year, carrying with it ~220 TWh of energy (Barati, Esfahani, & Utigard, 2011). Depending on the process, the energy content of slag ranges from 10-90% of the total energy input (Barati, 2011, Rodd, 2010). There has therefore been great interest in recovering energy from slag. Slag handling methods can broadly be classified into three categories: (1) dumping and slow cooling, (2) wet granulation and (3) dry granulation. As discussed below, only dry granulation routes are amenable to heat recovery. Slag dumping involves the slow cooling of molten material and crushing of the resulting solid. In this process, slag is dumped on the ground directly from furnaces or transferred to slag pots that are moved by rail or haulers and then dumped on the ground. The molten material is left to cool and solidify until it can be broken and handled by heavy machinery."

Jan 1, 2017

By K. Chomyn, R. Veenstra, P. Zangeneh, Hatch Ltd., C. Van der Woude, H. Ghorbani

"The furnace is the heart of smelting operations, and therefore the performance, reliability, and campaign life of the furnace are critical considerations. Furnace refractory is exposed to high temperatures and other harsh operating conditions causing brick erosion, crushing, and cracking, typically limiting the furnace campaign life and requiring costly furnace shut-downs for refractory re-lining. Despite extensive study, the in-service thermal / mechanical stresses in these complex refractory systems are not generally well understood. Hatch has developed a thermal-mechanical finite element analysis (FEA) based furnace refractory modeling approach that allows for the quantification of refractory movements, load distribution, and thermal / mechanical stresses.Due to the complexity of the refractory system, a range of models are used to identify and assess damage mechanisms and design improvements, including: 2D models, to capture expansion and movement of individual bricks, changes to load paths, and thermal stresses; and 3D models, to include the effect of differential expansion between bricks in each course, and assess overall load distributions. The 2D and 3D analyses include the effect of nonlinear temperature-dependent properties, thermal expansion, movement of individual bricks with frictional contacts (i.e., gaps can open, bricks can slide), and brick tensile or compressive failure. Both as-built and damaged conditions can be investigated (e.g., after bath zone brick erosion), for circular and rectangular furnaces. 3D models also include papering and brick joint & interface action.Analyses using these models have shown the importance of thermal stresses, papering, and geometry / arrangement of individual bricks. Results have been used to identify and assess damage mechanisms, showing good alignment with furnace autopsy observations. By using this FEA-based approach to quantify the refractory design, the risk of damage can be significantly reduced, low-cost design changes can be identified, and the furnace campaign life can be extended.INTRODUCTIONThe furnace is the heart of smelting operations and therefore the performance, reliability, and campaign life of the furnace are critical to the success of the smelting operation. Furnaces are inherently exposed to high temperatures, often in excess of 1600°C (Holappa, 2004), and furnace operating power has progressively increased over time (Voermann, Gerritsen, Candy, Stober, & Matyas, 2004). The refractory system must withstand high temperature, high heat flux, and other harsh operating conditions. These conditions are particularly significant for the furnace hearth, and can lead to damage including brick erosion due to molten material flows, crushing due to thermal expansion loads, and cracking due to severe thermal gradients within the bricks. Refractory damage typically limits the furnace campaign life, requiring costly furnace shut-downs for refractory re-lining (repair or replacement). In some cases the refractory may lose integrity causing damage to nearby equipment and harm to personnel."

Jan 1, 2016

By A. A. Berk

In the course of a study of the formation of external deposits on tubes in water-tube boilers it became desirable to determine the sulfur dioxide (SO2) and sulfur trioxide (SO3) in the Due gases. Determinations made by the A.S.M.E. method for SO2 and SO3 in gaseous products of combustion did not give accurate results. It was found that minute quantities of copper, present in the flue gases from the coal in use, caused oxidation of sulfite in the absorption bottle and that the carbon dioxide (CO2) in the flue gases caused high values for SO2. The A.S.M.E. test procedure was revised to prevent oxidation of sulfite in the absorption bottle and to allow for the effect of CO2; subsequent analyses of flue gases produced reliable results. The revised procedure is described.

Jan 1, 1950

By Michael Murphy

A multi-stage triaxial procedure has been developed for the enhanced servo controls and feedback systems at the National Institute for Occupational Safety and Health (NIOSH) rock mechanics laboratory. Due to the difficulty of preparing multiple rock specimens for single-stage triaxial tests at different confinements, multi-stage testing provides a huge advantage if only a few samples of coal measure rocks can be prepared from the drill core. A multi-stage test can provide mechanical properties, post-failure properties, and a complete failure envelope for a single specimen. For the multi-stage test procedure, a parameter used to define the slope of the stress-radial strain curve was developed and monitored in real time in order to successfully predict peak strengths at different confining stages. For this paper, multi-stage tests have been conducted on sandstones of varying strengths, including Berea sandstone which has well-documented properties, and fine-grained and coarse sandstone from a western US coal mine. For the tests conducted on the fine-grained sandstone, it was found that the ramp rate was an important factor in the success of obtaining peak strengths during the multi-stage tests. For each rock type, a table including Young?s modulus, Poisson?s ratio, unconfined compressive strength, friction angle, cohesion, residual friction angle, and residual cohesion are reported. The values from these tables have been used as input parameters for projects at NIOSH requiring numerical model input parameters.

Jan 1, 2014

By A. J. Barry

A practical method has been developed and field tested which provides an estimate of the bearing capacity of mine roof and floor. The relationship between penetration of the strata and imposed loads is determined by in situ tests. Information of this type is needed to determine the maximum allowable pressure that may be applied by self-advancing supports on roof and floor of a longwall face without causing a punching type of failure.

Jan 1, 1970

By A. A. Brant

BECAUSE of its simplicity, the dip needle is widely used for locating magnetic rock formations in drift-covered areas. Although it responds only to strong magnetic disturbances, it has the advantage that surveys with it can be carried out rapidly, at relatively low cost, by untrained operators. More accurate surveys can be made with a much more sensitive instrument known as the magnetometer, but this must be operated by a specialist and the resulting survey costs are much higher. Mining men use the dip needle for the location of magnetic ores or mineral deposits associated with magnetic rocks. In certain districts, a survey with the dip needle may aid in solving geological structure. In the Little Long Lac and Crow River gold camps of Ontario, it has recently been used for these purposes. In interpreting the results of a dip needle survey, an understanding of the chief magnetic and mechanical factors determining the dip recorded by the needle is definitely necessary. For example, many observers locate a magnetic body by the highest dip values, apparently unaware that these frequently may not lie directly above the body. It should also be realized that a careful dip needle survey may yield information regarding the dip, breadth, and perhaps depth, of the magnetic body. Moreover, the observer should know when numerous closely-spaced dip readings are necessary, and when the dip may be measured at more widely separated intervals. The purpose of the following article is primarily to describe the factors affecting the registration of the dip needle, with a view to aiding investigators in a more accurate and complete interpretation of their results. To explain the cause of magnetic disturbances (anomalies) and the action of the dip needle, a knowledge of certain fundamental magnetic terms is necessary.

Jan 1, 1938

By Immo H. Redeker

Introduction In October of 1961 Texas Gulf Sulphur Company contacted the Asheville Minerals Research Laboratory, of the North Carolina State University, and requested assistance in the development of a phosphate ore body in Beaufort County. The main: objectives of the work at Asheville were defined as follows. The Laboratory should try to determine on the basis of drill core samples, submitted by Texas Gulf Sulphur Company, the highest grade of phosphate concentrate that could be obtained with high recoveries from North Carolina ore, the thickness of the ore body that could be treated economically in one section, and the quantity of concentrate that could be obtained per acre. The results should be compared with data obtained from the treatment of Florida ores. It was important to use mineral preparation methods during the initial laboratory work that could be verified later by continuous pilot plant operation and could be scaled-up for a commercial plant. The writer was in charge of the project at the Asheville Minerals Research Laboratory and participated in the development of one of North Carolina's greatest mineral resources from the first drill core examination to the production of the first poundage and tonnage quantities of flotation concentrates. The Lee Creek phosphate mine and mill was put in operation in early 1966 and can produce three million tons of phosphate concentrate a year. Sulfuric- acid, and phosphoric acid plant, diamonium phosphate plant and triple super phosphate plants came on stream in 1967; at that time they were the world's largest. Now that a phosphate industry has been established in the State, it]

Jan 1, 1971

By Florence L. Feicht, H. H. Schrenk, Carlton E. Brown

This report describes the dropping - mercury electrode , its use in analysis , and the procedure of the Health Division of the Bureau of Mines in determining lead , cadmium , and zinc . The dropping - mercury electrode or polarograph is an electrolytic device , one electrode of which consists of mercury issuing in small drops from a capillary tube . Such electrodes have been in existence for more than 50 years, but they were not used for analytical purposes until about 1922.6/ Developments since have been rapid , especially in Czechoslovakia , Germany , Italy, and Japan and more recently in the United States . A recent bibliography / contains references to, 825 articles issued from 1903 through 1940. In 1939 Kolthoff and Lingane presented the first comprehensive critical review, in English , of the device and its use in analysis . They have recently issued a book on the same subject. Similar information also is included in a recent book10/ by Kolthoff and Laitinen . Much of the information in this and the two following sections on this device and its use in analysis was obtained from these three publications . The use of the dropping - mercury electrode in analysis is based upon the fact that the kind and amount of electro - reducible and electro - oxidizable constituents in solution can be determined from the current -voltage relationships revealed by this electrode or electrolytic device .

May 1, 1942

By E. D. Eastman

There are three researches upon the specific heat of water vapor by the method of explosion that are sufficiently advanced in technique and suitable in plan to justify careful study of their results , with the double purpose of fixing the best available experimental values and indicating the attainable accuracy of the method. These three researches comprise the work of Pier , Bjerrum , and Siegel.5 The work of earlier date than Pier's suffers from obvious inaccuracy of measurement , while the experiments more recent than Siegel's , such as those of Womersley6 , of Bone and his collaborators , and of Maxwell and Wheeler , 8 are for the most part not well designed for the accurate determination of the heat capacities in question . Some of the errors to which they are especially subject have been discussed by David and by David and Thorp.

Sep 1, 1930

By E. Jong, E. Watkins

"The application of passive tracer gas sources in underground mines is particularly useful for long-term tracer gas studies, as well as for studies in permissible areas of underground coal mines. The use of passive perfluoromethylcyclohexane (PMCH) sources have previously been demonstrated in mines, but this new work details the development and testing of multiple, distinct tracer compounds that can be used in passive sources. A description of their potential application in mine ventilation systems is also provided. Three tracer compounds are detailed, which are PMCH, PECH and PMCP. The release rates of these tracers were examined over a 180 day period at multiple temperatures. The advantages and disadvantages of these sources are presented, along with potential applications in understanding complicated ventilation circuits, flow through gob, and leakage. INTRODUCTION The use tracer gases for ventilation applications is an established practice, with various research projects being perform with Sulfur Hexafluoride (????6) in the past. Perfluorocarbon tracers (PFTs) however are relatively new compared to ????6, which is proven to be useful in ventilation and air modeling experiments along with other PFTs (Watson, Wilke, Dietz, Heiser, & Kalb, 2007). These liquid tracers are characterized by low background presence in air, inert behavior with other gases, high detectability with a gas chromatograph and low toxicity. A design was proposed called a permeation plug release vessel (PPRV), which initially introduced by Brookhaven National Laboratory to meet those requirements. The PPRV works by allowing the gaseous form of the tracer to diffuse through the permeable silicone stopper and evaporate into the open air on the other side. The PFTs inside the vessels are injected as a liquid but instantly begin to convert to their gaseous phases at room temperature due to high vapor pressures (Zhang, H., Cloud, A.,2006). Previous studies have detailed how release rates change based on plug thickness across various temperatures (Jong et al., 2015), but not on the release rate stability based on temperature across multiple tracers. For use in underground mines passive release sources need to be durable, be simple to manufacture, have customizable and reliable release rates as well as a long operating life. The PPRV vessel provides a steady release of tracer gas that is essential for long term passive release experiments, making it a viable vessel for the PFTs being tested. The PPRV design also allows for vessels to be bundled together to achieve release rates at detectable levels and allows for the capability to run ventilation surveys with multiple tracers simultaneously. The ability to conduct ventilation surveys with multiple tracers using the PPRV bundling design and detection of the PFTs makes testing the tracers and design together a promising potential for complex and long term mine ventilations studies."

Jan 1, 2017

By E. Wraith, W. W. Culver, B. Wesstrom, P. J. Mackey

Electrodeposited copper of the 1860s was of unprecedented purity, although the profound significance of this achievement was not fully realised until the dawn of the electrical age a decade or so later. By the 1870s there were three somewhat large (4 to 4.5 tonnes Cu/day) electrolytic copper refineries in Germany based on J. B. Elkington’s process, first patented in the United Kingdom in 1865. More such refineries were planned throughout Europe. At the same time, copper output in the U.S.A. was starting to expand and with the spread of European electrolytic copper refining technology across the Atlantic, the door opened to major increases in North American output. The technology was first taken up in 1879 by James Douglas at the Chemical Copper Company in Phoenixville, Pennsylvania, where he was Superintendent. Douglas was assisted in this pioneering work by Edward Weston. The copper refinery at the Chemical Copper Company was small, not unlike the first plants in Europe. The present authors contend that the electrolytic copper refinery at the Chemical Copper should be regarded as the first copper refinery in the United States. The Balbach Copper Refinery in New Jersey, which commenced operations in 1883 with an initial production of about 2 tonnes Cu/day, has been erroneously considered as the “first commercial refinery”; it rightly belongs in second place. The early developments at these plants are discussed in this paper. INTRODUCTION In the mid-1800s, the main uses for copper were as sheathing on the wooden sailing ships of the day to protect from marine growth, boiler components in locomotives and steam engines, along with some construction uses. Copper ores were generally smelted, and further fire-refined for market. The recovery of gold and silver, if present in payable amounts, was a slow and relatively expensive step. This situation regarding copper would change by the 1870s with advances in the generation and use of electricity. The introduction of the dynamo led to major developments in electrorefining. First demonstrated in principle by Faraday in 1831 (Faraday, 1832), the dynamo was subsequently adapted and further developed by J.S. Woolrich for electro-metallurgical applications in 1842 (Woolrich, 1842; Napier, 1845). It provided a new source of power with the unprecedented potential to significantly change the scale of metal production by electrometallurgy. Interestingly enough, copper would be needed for the electrical age just beginning. By 1869, advances in dynamo design offered relatively reliable large machines, which enabled J. B. Elkington in the United Kingdom to use the dynamo in the radically new Pembrey copper electrorefinery — the first copper electrorefinery in the world (Wraith, 2013). Initial production at Pembrey was small — in the range of 1 to 2 tonnes/day — while gold and silver were recovered more readily by the treatment of the slimes than with methods used hitherto.

Jan 1, 2019

By N T. Moxon, L W. Armstrong

Explosive manufacturers have for many years provided a service to the mining industry which has,until recently, been unchallenged by mine operators. Today mine operators are more aware of the properties of explosives required to perform particular tasks within their operations. These properties can be reliably quantified using the test procedures described in this paper for emulsion adn ANFO based explosives. Details of an end-user sampling programme desgined to provide quality checks on explosives supplied to a mine site are also discussed.

Jan 1, 1991