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By Wils L. Cooley

Several aspects of coal mine safety-ground system operation are studied. Evaluations of two sophisticated ground-wire monitors are presented, along with a detailed report of development work on a modular ground-wire monitor. A portion of the report covers stray current flow in the safety-ground system, analyzing in detail conditions surrounding the generation of both dc and ac ground wire current. Considerable detail is provided concerning studies of mine ground beds. Additional progress is reported in the development of a. continuous ground-bed monitor, and new techniques are developed for the design of ground beds and their resistance measurement. New methods of accurately measuring electrical parameters of finite layered conducting structures are also reported. The effects of stray currents in ground beds is included. Touch-and step-potentials associated with mining equipment are analyzed, and methods are presented for determining earth voltage gradients around structures contacting earth. Instrumentation to determine gradients easily is suggested. Finally, an extensive effort is described dealing with lightning transients on open-pit coal mine ground systems. The nature of the transients, their expected frequency of occurrence, and the ways in which they damage equipment are analyzed in detail.

Jan 1, 1977

By J. D. Steenkamp, G. E. Williams

Keywords: Ilmenite, titania slag, pig iron, rutile, zircon Located on the eastern shores of South Africa, 180 km north of Durban, Richards Bay Minerals (RBM) produces approximately 2.0 million metric tonnes of product annually making RBM a leading producer of titania slag, high purity pig iron, rutile and zircon. Heavy minerals are extracted from the nearby dunes by dredging and concentration on a floating gravity separation plant, followed by separation of the ilmenite, rutile and zircon at the mineral separation plant located at the smelter site. The ilmenite is processed through an oxidizing roast followed by magnetic separation and is then partially reduced to an 85 per cent TiO2 slag in one of four six-in-line a.c. electric arc furnaces. The slag is milled and then classified into two product sizes suitable as a raw material for both the sulphate and chloride pigment processes. The high quality iron produced during the reduction process is further processed to produce various grades of low-manganese iron. Around 95 per cent of the products are exported, yielding a world market share of about 25 per cent of titania slag, rutile, high quality pig iron, and zircon.

Jan 1, 2006

By J. E. Murphy

Purification of samarium metal by sublimation and by vaporization from a low-melting metal flux, at the same temperature, were compared. Vaporization proved more effective for removing impurities such as magnesium, calcium, and manganese. Recovery of samarium, however, is more rapid by sublimation because of its constant rate of distillation.

Jan 1, 1970

By Donald J. Keefe

The Remote Working Level Monitor (RWLM) is an instrument used to remotely monitor the Rn-daughter concentrations and the Working Level (WL). It is an ac powered, microprocessor based instrument which multiplexes two independent detector units to a single central processor unit (CPU). The CPU controls the actuation of the detector units and processes and outputs the data received from these remote detector units. The remote detector units are fully automated and require no manual operation once they are set up. They detect and separate the alpha emitters of RaA and RaC' as well as detecting the beta emitters of RaB and RaC. The resultant pulses from these detected radioisotope; are transmitted to the CPU for processing. The programmed microprocessor performs the mathematical manipulations necessary to output accurate Rn-daughter concentrations and the WL. A special subroutine within the program enables the RWLM to run and output a calibration procedure on command. The data resulting from this request can then be processed in a separate program on most computers capable of BASIC programming. The calibration program results in the derivation of coefficients and beta efficiencies which provides calibrated coefficients and beta efficiencies.

Jan 1, 1977

The Calypso geothermal field, mapped by the R V Sonne (cruise SO-135) in 1998, includes four main sites, the Northern Vent Area (centred on 37¦ 36.7'S, 177¦ 06.2'E, area 1.5 km2), Central Vent Area (37¦ 39.4'S, 177¦ 05.2'E, 1 km2), Southern Vent Area (37¦ 41.7'S, 177¦ 06.0'E, 1 km2) and Mercury Vent Area (37¦ 41.3'S, 177¦ 07.3 'E, 0.5 km2). Hydrothermal activity at the vent sites is controlled by minor, sub-parallel NE-trending normal faults. Gas bubble trails (C02) and shimmering hot water vent from fractures and joints between large blocks of silicified volcaniclastics and in depressions in the sediments at the base of these outcrops. Measured maximum vent temperatures are between 180¦C and 201¦C. Venting fluids are at, or just below, boiling for water depths of 200 m. Rock samples recovered by dredge from the sites include massive anhydrite, clay-altered pumiceous ash, silicified volcaniclastic sediments and volcaniclastic breccias cemented by sulphur. Clay-altered samples, dominated by randomly interstratified illite-smectite and accessory chlorite, indicate formation environments of 70¦C to 90 ¦C. Native sulphur is abundant throughout the samples. Fine-grained (<1 mm) disseminated pyrite and vein pyrite occurs in the clay-altered pumiceous volcaniclastics and argillites. In the Southern and Mercury Vent Areas, fine-grained orpiment, realgar and cinnabar have deposited in the sandy matrix of volcaniclastic breccias. Amongst the cinnabar, small (<2 mm) beads of native Hg formed on the surface of several rocks following their recovery. These samples also contained abundant light hydrocarbons, which coat the rocks with an oily sheen.

Jan 1, 1999

By Appendix by A. S. Goldoni, R. E. Tate, E. M. Cramer

The diffision coefficient for self-diffision of plutonium in the temperature range 350" to 440°C has been measured by using puZ3 as the tracer isotope. Autoradiopaphic techniques were used to inzlestigate the possibility of grain boundary diffusion, hut only evidence for volume diffusion was found. The least-squares fit of the data gives the .following equation for the diffision coefficient: The computer least-squares technique for fitting the nonlinear equations is outlined. DETERMINATION of the self-diffusion coefficient of the fcc 6 phase of plutonium is in principle a straightforward experimental task. However, the chemical reactivity, the intense @ activity, and the toxicity of plutonium put limitations on the experimental techniques. The technique selected included roll bonding for preparation of the diffusion couples and pulse-height analysis of the @-particle activity to determine the distribution of the PU tracer in the diffusion couples. EXPERIMENTAL PROCEDURE Couple Preparation. Cylinders about 0.5 in. in diam were cast from two special stocks of plutonium, one of which had been enriched in puZ3', as shown in the isotopic analyses listed in Table I. For each roll-bonded composite sheet, a cylinder 0.437 in. in diam and 0.190 in. thick was turned from each kind of plutonium on a lathe in a 98 pct He atmosphere. The two freshly machined cylinders were positioned face to face in a tube of commercially pure aluminum which had been sealed at one end by welding and the assembly was evacuated on a vacuum manifold overnight. The elapsed time between machining the faces of the plutonium cylinders and evacuating the loaded tube was about 15 min. After overnight evacuation of the assembly the indicated vacuum was 1 X 10"5 torr or better. The aluminum tube was then warmed and pinched off with a cold-welding tool. The pinched-off weld was also fusion-welded as an additional precaution against leakage of air into the evacuated assembly. The assembly was immediately heated for 30 min in a 250°C furnace and reduced in thickness by being passed through a rolling mill with rolls heated to 200°C. The rolling schedule (four passes of 100 mils each with a 10-min reheat after two passes) reduced the thickness of the assembly to 100 mils. The rolled assembly was allowed to cool normally in air. The rolled assembly was sheared at the edges and the aluminum peeled from the composite plutonium sheet. The elliptical sheet was about 0.060 in. thick and usually three 0.383-in.-diam disks could be punched from its central portion. The sheet was heated on a hot plate to the ductile low 0 range (140°C as measured by temperature-indicating pellets) before each disk was quickly punched. The quality of the bond in the disks was evaluated by metallographic examination of the scrap sheet adjoining the hole left by the punch. Only well-bonded specimens without oxide in the interface (as indicated by metallography) were considered satisfactory for further use. More than half of the specimens so examined contained sufficient oxide in the interface to be rejected. Diffusion Anneal. Each disk to be diffusion-annealed was wrapped in 1-mil-thick tantalum foil and sealed within a Pyrex capsule evacuated to 1 x 10~5 torr or better. This capsule was then sealed within another Pyrex capsule at a similar pressure. The diffusion anneals were carried out at temperatures between 350" and 440°C in Marshall furnaces adjusted to have a temperature gradient of not more than *1/2"C over a 5-in. length. This gradient was then further smoothed by using a nickel tube as a liner in the furnace. The liner was divided into three longitudinal cavities by a septum of nickel sheet to which two calibrated Chromel-Alumel thermocouples were attached. One thermocouple was used for controlling the furnace temperature by means of a Brown Pyrovane controller equipped with a Capaciline anticipation circuit; the second thermocouple was monitored twice daily with a Leeds and Northrup K-2 precision potentiometer.

Jan 1, 1964

By W. E. Rice

The ceramic industry has to do with forming or molding articles of clay, and imparting to them their characteristic properties of permanence, strength and color by subjecting them to heat treatment in kilns. This heat treatment is commonly known as "firing" or "burning." The art of firing clay ware antedates the industrial use of coal; hence wood was the fuel first used, and the earliest kilns were built to burn wood. The majority of the clay ware produced today is fired in periodic kilns that are essentially enlarged structures similar to the earliest enclosed kilns; a kiln consists of a large chamber 16 to 32 ft. dia. (or rectangular) in which the ware is charged and fired either in direct contact with flame or hot gases from the fuel, or in saggers which shield the ware from direct contact with the gases. The fuel is burned in a number of small furnaces built in the thick wall that encloses the chamber; these furnaces are from 16 to 36 in. wide and from 3 to 5 ft. long; some of them have horizontal or sloping grates, but many have no grates; the last are called "dead-bottom" furnaces. The temperature necessary to mature the charge in the kiln varies for different clays; for some it is as low as 1800°, and for others as high as 2700" F. Wood was an ideal fuel for the low temperatures that were used in early kilns; it burns freely and produces a long, clean flame, which promotes uniform distribution of the heat in the kiln; it does not coke and so restrict the passage of air through the fuel bed; the ash does not melt in the fuel bed to form clinker; and the ash that is carried into the chamber and deposited on the charge does not contain iron and sulfur to discolor the clay. The extent of the ceramic industry now precludes the general use of wood in kilns, so that today this industry is one of the large users of bituminous coal, burning more than eight million tons annually in kilns. Manufacturing plants usually are at or near the source of clay, with deposits of coal suitable for kilns occurring near the clay. The cost of coal is the largest single item of expense in the manufacture of clay ware, and, because all coals are not equally suitable for the process, the careful selection of coal is important. In this selection the desidera-

Jan 1, 1932

By Lori Kormos, Jhonny Carrión De la Cruz, Dominic Fragomeni, Elizabeth Whiteman, Jorge Oliveira

"Process diagnosis, flowsheet design and optimisation are most effectively and efficiently achieved through the use of metallurgical testwork combined with more modern quantitative mineralogical techniques. Integration of the mineralogical data in testwork programs provides a resolution that cannot be obtained from assays alone and can direct the flow of work to result in optimized conditions more quickly than would otherwise be possible. At Xstrata Process Support (XPS), QEMSCAN (Quantitative Evaluation of Materials by Scanning Electron Microscope) and EPMA (Electron Probe Micro Analyser) information can be employed to diagnose specific issues in a plant or lab scale test and are routinely combined with other metallurgical data sets to benchmark performance, design and optimise flowsheets. Representative sampling protocols for ore bodies or test products, the use of geometallurgical unit classification and high confidence metallurgical test programs are key components of the strategy. Two case studies from Xstrata Zinc’s Antamina Mine and Concentrator in Perú, and Xstrata Nickel’s Nickel Rim South Mine in Sudbury are described to show how the use of quantitative mineralogy were used to diagnose a plant issue and how the data can be integrated into metallurgical programs to assist mineral processing engineers to design and optimise flowsheets.INTRODUCTIONOver the past decade, there has been a shift away from metallurgical testing that employs only chemical assays to quantify performance; the use of empirical observation in order to optimise a flowsheet; and the extraction of bulk samples for testing or piloting. The integration of geological information into the planning and execution of testwork programs including the use of quantitative mineralogy has improved the overall quality and predictability of metallurgical programs. At the same time, improvements to metallurgical testwork protocols such as rigorous statistical assessment of results, the use of factorially designed experimental strategies (DOE), and replicate flotation with appropriate quality controls, has improved the confidence level in these results.Process diagnosis, which utilizes quantitative mineralogy, can clearly define the root cause of the metallurgical issue. Whether used on its own to diagnose an issue or in combination with other metallurgical testwork, the use of mineralogical data has become the standard in the mining industry."

Jan 1, 2010

By Clyde E. Eilliams

In recent ye.ars much intere,t has been centered on the possibility of pro­ducing alumina from clq, a.nd proposed methods tor the recove:r,v of alumina are appearing constantly in parent lit,erature, As a good· grade of clay contains from 30 t<> 40 per cent of al"WDina, the prospect of tecovering it is alluring, al though obviously ditfieul t. A patent typical of m projected thermal processes is that 0£ Paul Migu.et, (U, S, Patent No, l,376,563) entitled nprocess for the preparation of pure alkaline alu:ninates.'' Re proposes to prepare alkaline a.luminate by fusing clay, lime, and acrap iron with a reducing aget in the electric furnAce, thereby reducing the silica a.r.d formin1s calcium alumina.te and ferrostlicon, The calcium aluminate, being lighter, would. float on top substantially free from foreign oxides, It could. then be tapped ott, cooledf ana later crushed and leached with aodium carbonate solution to torm, by double decomposition, sodium aluminate, and calcium carbonte. The fonMr is soluble and yields readily aluminum hydroxicie. 'l'he ferrosilicon wo'Uld be r,covered as such and sold at a profit.

Aug 1, 1922

By T. S. Golosinski

Typical dragline rigging includes several sets of ropes: hoist ropes, drag ropes, dump ropes and boom suspension ropes. The drag and hoist ropes contribute most to the dragline operating cost, and significantly influence dragline productive time. Both work in very difficult conditions and wear out rapidly. As a result frequent rope changes are required at a substantial cost and time loss to the operation. Although performance of rigging has a profound impact on dragline performance, there are no industry-wide standards related to its selection, operation and maintenance. Little information on the subject is available and the practice differs widely throughout the industry. The life of drag and hoist ropes depends on: (1) rope construction, which should closely match requirements of the specific application, (2) correct definition and application of the rope discard criteria, so that full advantage of the rope can be taken without endangering safety of operation, and (3) rope operating conditions and its maintenance. The study presented in this paper was intended to address the above points, based on a survey and assessment of the present industry practice.

Jan 1, 1993

By John H. Fowler

Nova Scotia has been mining and exporting industrial minerals for over two hundred years. As an industrial mineral producer, this province continues to rank as the number one gypsum mining and exporting region in North America. Mining of many other commodities is ongoing, supplying many local and export markets. In all, excluding aggregate producers, there are nineteen industrial mineral producers operating at thirty sites producing nine commodities including anhydrite, barite, clay and shale, dolomite, gypsum, limestone, salt, silica sand and stone (Fig. I). Numerous aggregate producing operations supply all the province's aggregate requirements and export some of these materials to other regions of Atlantic Canada and as far away as Bermuda (Fig. 2) . Production value of industrial mineral commodities in Nova Scotia for 1982 was $105 million , representing 39% of the total value for all mineral production for the year. Because of the general improvement in the economy, indications are that the 1983 value of production will be higher.

Jan 1, 1984

By E. I. Vargha-Butler

The determination of surface tensions and contact angles of coal particles is of great interest for coal beneficiation processes such as froth flotation and oil agglomeration and for the inclusion of coal particles into oil droplets as a means of enriching the fuel. Methods for contact-angle measurements on small irregularly shaped solid particles have not been available in the past. Therefore, we recently developed a novel technique to determine contact angles and surf ace tensions of coal particles. Two types of bituminous and one type of subbituminous coal particles have been tested. The technique used is called the freezing-front technique and it considers the behaviour of the test particles (in the range of 20-250 pm) at the solidification front of carefully selected, well-defined solidifying melts (matrix materials) such as thymol, biphenyl, naphthalene, salol and 2-phenyl phenol.The results show that the technique works well, providing quantitative and detailed information on the wettability of coal particles. The sensitivity of the method is so high that a difference in contact angle of approximately 4 degrees between the smaller and the larger particles is clearly registered.

Dec 1, 1981

By Owsiacki. Leo

Both the 8 and A-C ore zones of the Heath Steele Mine contain extensive areas of brecciated ore. This texturally distinct ore type has been tentatively defined as a fragmental or conglomerate massive sulphide. It consists of subangular and round fragments of pyrite up to 30 em in diameter, smaller quartz clasts and chloritized, mineralized, lithic fragments in a faintly banded matrix of pyrrhotite and chalcopyrite. The chalcopyrite is concentrated in the pressure shadows of the fragments and appears to reflect remobilization and recrystallization during a deformation which postdates the formation of the clasts. A generally conformable relationship with the underlying banded pyrite-sphalerite ore, discordancy with the host banded argillites, spatial distribution and similarity to Kuroko ores suggest that the fragmental ore is of primary origin and that breccia formation is probably due to soft-sediment slumping or sliding initiated by volcanic explosions, as hypothesized for similar massive sulphides in various Japanese mines. It is nevertheless recognized that certain structural features in some clasts may result from deformation preceding the formation of the breccia, and at this stage a tectonic origin cannot be completely eliminated.

Jan 1, 1979

By Gjergj Dodbiba, Toyohisa Fujita, Li Pang Wang, Masashi Yamane

"The platinum-group metals (PGMs), are currently receiving worldwide attention as they have major industrial uses. PGMs, i.e. ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Ir), and platinum (Pt), are widely used as catalysts in petroleum and chemical processes. In addition, they find wide applications in automotive exhaust-gas control converters and are of immense importance to the electronic industry. Broadly speaking, PGMs are extracted in minute quantities from a limited number of ores, found mainly in South Africa and Russia. As the PGMs are both costly and almost indestructible, they are usually recycled from various forms of scrap. In other words, the recycling of the PGMs is an essential factor in the overall management of the PGM economy. In addition, the ever-increasing user areas have created renewed interest in the search for new sources or deposits of PGM, which in turn requires an in-depth knowledge of its characteristics. In this work, the emphasis is placed on the need to analyze the composition and microstructure of blast-furnace slag for recovering PGM metals. In other words, chemical composition, surface analysis and microstructure analysis of the DC arc furnace slag have been carries out. The aim is to provide a detailed analysis of this material for anyone with an interest in gaining further knowledge of its specific content for recovering PGMs."

Jan 1, 2014

By Clyde N. Garman

The Homestake-New Mexico Partners consist of Homestake Mining Company of Lead, South Dakota; Rio de Ore Uranium Mines, Inc; United Western Minerals Company; White, Weld and Company; J.H. Whitney; San Jacinto Petroleum Corporation; and Clyde Osborn, Homestake Mining Company is the general partner, the others are limited partners. The Rio de Ore Uranium Mines, Inc. has. a mine in the Ambrosia Lake area; this was the first mine to go into production in this area. The United Western Minerals Company also has a mine in the Ambrosia Lake which is operated as a "farm out" from the San Jacinto Petroleum Corporation. These mines are the principal sources of ore for the mill. This group was the first to obtain a contract with AEC to make uranium concentrate from Ambrosia Lake ores and the first to have a mill in operation specifically for these ores. With Clyde Osborn as the sparkplug and co-ordinator holding the ore suppliers of, this group together, a contract with AEC was agreed on as to its essential points by mid-summer, 1956, At that time, there was no general partner and no financing, so me formal contract could be signed. By December, 1956 when the contract was signed and the present partnership officially formed, much of the basic engineering was done and purchasing of main elements of the mill waited on the formalizing of agreements, at the specifications and sizes agreed on previously. Ground for the mill was broken in April, 1957. The sampling plant went into operation in October and ore was first fed to the ball mills on February 5, 1958, ten months after construction actually started. Filling of the circuit with sodium carbonate bicarbonate solution had begun a week before that.

Jan 1, 1959

By Maurice Bottiau

The recent evolution of the piling market clearly shows a growing demand for screw piles with soil displacement. The recently developed Omega Screw pile ful-fill these new expectations, combining the advantages of vibration-free systems and the behaviour of a displacement pile. The paper describes recent experience and new applications with this very promissing pile. Full-scale load tests were carried out in different countries as U.K. or Sweden. A very attractive and innovative piled embankment is also described, using geogrids in order to transfer the loads from the superstructure to non-reinforced Omega-piles.

Jan 1, 1996

By C. Harold Riches

This article is directed co a commentary on the patent system in its relation to the public interest. As man gained supremacy over his environment, he could devote progressively increasing portions o his time to improving his standards of living. In the history of the human race, we have advanced from the hollowed floating log to the modern steamship of the present age; from the sickle and flail to the reaper and combine; from the trumpet and drum as a means of communication co the telegraph, telephone, and radio; from the horse and ox cart to the automobile, truck, aeroplane, and train; and so on ad infinitum through the list of inventions on which are based the industrial and political economies and standards of living we enjoy today. It has also been a long road from the day of the alchemist and his closely guarded secrets to the era of the patent system and its storehouses of knowledge open to the world. The alchemist and the craft and merchant guilds closely guarded their secrets. In fact, they largely opposed innovations on the grounds that they might injure profits and restrict employment. In these days of unrest, with great clamour out of doors for radical changes in our political and industrial economies, it may not be untimely to examine one of the keystones which support the economic structure we know as the free enterprise system, the system which is predicated upon the right of the individual to own property. Many, through impractical idealism, ignorance, confused thinking, or blind political prejudice, advocate the substitution of ownership by the State ? for the right of ownership by the individual. As civilization has advanced to the high standards of living we enjoy today through the efforts of a comparatively few inventors, the patent system which has provided the incentive that created the inventions on which our industries and our employment are based is fully understood and appreciated by a comparatively small percentage of our people. As a result, the patent system, as a keystone in our free enterprise economy, is an apt target for destructive criticism, with the thought, possibly, that by eliminating or drastically restricting the several rights to individual ownership one by one, ownership by the State will progressively replace ownership by the individual.

Jan 1, 1949

By Torrico Mesa

El presente artículo describe la etimología, historia, posición, superficie, límites, división política, población, geología y los asientos minerales de la provincia de Cajatambo, Junín. Entre los principales asientos están: Chanca, Raura, Quichas, Izguez, Pomahuín, Auquimarca, Santa Rosa, Rosario e Irismachay. Asimismo, se describen los yacimientos mineros, amalgamación, lixiviación por prodecimiento, metalurgia, fundición y las oficinas metalúrgicas.

May 1, 1956

By Gavin Ritson, Chris Ward

"The oil sands industry is still fairly young with the first viable oil sand operation having been started in Alberta in 1960. Since then numerous modifications and improvements have been tried and implemented. The current process makes use of high velocity pumping of oil sands slurry with hot water (hydrotransport) to achieve separation of bitumen from the sand.A number of the oil sands processes have been adapted from unit operations that are used in mineral processing, such as crushing, screening, flotation, cycloning and thickening. This paper outlines a typical oil sands process flowsheet and investigates the differences and similarities in technologies and costs to other mineral processing industries. It also considers the very large throughputs required, and presents some of the difficulties and challenges currently faced by the industry as a result of high demand for oil and environmental pressures.INTRODUCTIONOil sands (also known as tar sands) deposits are found throughout the world. The Athabasca Oil Sands deposit in Aberta is the largest of these. Oil sands consist of a mixture of crude bitumen (a semi-solid form of crude oil), silica sand, clay minerals, and water. The Athabasca, Peace River and Cold Lake deposits cover 141,000 square kilometers and contain about 1.7 trillion barrels (270×109 m3) of bitumen in-place, comparable in magnitude to the world's total proven reserves of conventional oil"

Jan 1, 2009

By A. Steiner, K. L. Komarek

Activities of aluminum in solid Ni-A1 alloys have been determined between 20 and 60 at. pet Al and 1200" and 1400°K by an isopiestic method in which nickel specimens, heated in a temperature gradient, are equilibrated with aluminum vabor in a closed all-alumina system. The activity of aluminum shows a strong negative deviation from Raoult&apos;s law at low concentrations but increases by three orders of magnitude within the ß(NiAl) phase. The partial molar enthalpy and entropy of mixing are negative. Using Wagner and Schottky&apos;s theory of ordered compounds, a degree of disorder of 4 x 10 -4 for NiAl and 1.25 X 10-2 for FeAl has been calculated THE Ni-A1 system has been studied by a great number of investigators, and the results, as far as the phase diagram is concerned, have been compiled by Hansen.1 The phase boundaries from 0 to 50 at. pet Ni are well-established. At higher nickel contents the boundaries are still in dispute and an additional phase, A12Ni3, has been reported.&apos; The phase diagram is dominated by a very stable high-melting compound, NiA1, with a relatively wide range of homogeneity. Heats of formation of solid alloys have been determined calorimetrically by Oelsen and Middel3 from 20 to 95 at. pet Ni and by Kubaschewski4 from 25 to 80 at. pet Ni. According to the most recent compilation5 no other thermodynamic investigations have been reported for the Ni-A1 system. Due to the corrosive nature and the low vapor pressure of aluminum, a method has been employed for determining activities of aluminum which was previously developed for the Fe-A1 system.= Nickel specimens, heated in a closed evacuated alumina system in a temperature gradient, were equilibrated with aluminum vapor from a source within the system kept at constant temperature. After complete equilibration the specimens were analyzed and activities calculated from the known vapor pressure of aluminum. APPARATUS AND EXPERIMENTAL PROCEDURE Materials. The nickel specimens were made from wafers of electrolytic nickel (International Nickel Corp.) of 99.99 pet purity which were rolled to a 0.001-in.-thick foil by Driver-Harris Co. and to a 0.005-in.-thick sheet in our laboratory. The aluminum (Aluminum Corp. of America) had a purity of 99.99+ pct. The alumina tubes and crucibles were made of impervious recrystallized alumina with an alumina content of 99.7 pet (Triangle RR, Mor-ganite Inc.). Experimental Procedure. Annular specimens were punched from the sheet, the punching burrs removed, and the specimens degreased in carbon tetrachloride and acetone and weighed on a micro-balance to within an accuracy of ±0.01 mg. The specimens were positioned with alumina spacers along an alumina tube, and the positions measured. Aluminum metal was machined into cylindrical shape, and placed into an alumina crucible. The tube with the specimens was then inserted into a hole drilled into the aluminum metal. An alumina tube with its closed end at the top was slipped over the specimens so that its lower end fitted snugly into the alumina crucible. The assembled reaction tube was inserted into a mullite tube with a water-cooled brass head which had an opening for a quartz thermocouple protection tube and a metal-to-glass connection to a conventional vacuum system. A Pt-Pt 10 pet Rh thermocouple could be raised and lowered in the quartz tube which was placed along the outside of the alumina reaction tube. The mullite tube was heated by two separately controlled resistance-tube furnaces so that in the experimental temperature range an over-all temperature gradient of approximately 150o to 250°C could be imposed on the reaction tube. The position of the mullite tube was adjusted so that the surface of the aluminum metal was always at the temperature minimum. The reaction tube was thoroughly evacuated before and during slowly heating the assembly up to the melting point of aluminum. A pressure of less than 2 µ (Hg) was maintained during an experiment. Once the aluminum had melted, it isolated the contents of the alumina tube from the surroundings. Several times during an experiment the temperature gradient was carefully measured. An experiment lasted from 3 to 6 weeks and it was terminated by air cooling the evacuated mullite tube. For further details of the experimental procedure the paper on the Fe-A1 system6 should be consulted.

Jan 1, 1964