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By E. D. Eastman

The basic character of the free energy r data relating to water and the oxides of carbon makes it desirable that the most representative values that can be obtained should be constantly available. The calculations of Lewis and Randall3 retain much of their of original value, but appear to require some modification in the light of more recent work. This paper has been written to incorporate the newer information and to present some estimate of the reliability of the resulting figures. The data upon which the calculations are mainly based are, for these substances, the equilibrium constants of the various reactions involved. The original work relating to these equilibria has, been reviewed and, where possible, weighted to correspond with its probable reliability. The differences in the results of the present from the earlier calculations are partly the consequence of this appraisal and partly of the inclusion of more extensive data, as will be indicated in detail in the succeeding sections.

Jan 1, 1929

By Felipe Beluche Lima, Caio Augusto Silva Santos

Brazil is the largest producer of crude steel in the Americas by BOF process and many challenges come along with the increasing market demand. In the BOF, a tubular wall hood structure has been showing premature failures related to the overlay welded tube technology placed in the hood wall. The main root causes were: thermal fatigue at 1800°C, hot spot formation, high heat-affected zone (HAZ) leading to susceptibility of stress cracking, carburizing corrosion and superficial wearing. Based on that, co-extruded tube technology (named composite tube by Sandvik) was the alternative chosen to enhance hood performance without compromising BOF process. In order to rises safety and productivity, composite tube has 100% metallurgical bond assuring stable expansion, high heat exchange efficiency, better corrosion resistance and less rough surface finishing. It was highly suggested to many others mills due to similar and already existing reported cases.

Oct 1, 2019

By I. Barin

The thermodynamics of cyclone smelting of sulphidic copper ores is described using as example the production of copper matte with 75 wt % Cu. Equilibrium calcualtions and material and energy balances show that an increase in process temperature from 1600 K to 1900 K results in the extensive transfer of minor elements such as As, Sb, Bi, Pb, Zn,.... to the gas phase. A pilot plant for carrying out the cyclone smelting process is described. Calculations of material and heat transfer for the reaction of ZnS show that the smelting reactions of sulphides in the cyclone take place very rapidly at high temperatures. The dissociation of the sulphides with subsequent oxidation reactions in the gas phase plays an important part in. the process and is mainly controlled by heat transfer.

Jan 1, 1983

By R. T. Erskine

"The No. 6 orebody is located 6 miles from the main op.eration of Brunswick Mining and Smelting Corporation Limited and includes open-pit and primary gyratory crushing facilities. Ore is transferred by truck to the secondary crushing facility at the main plant. About 3,500 tons of ore per day are crushed to minus % in. and ground to 68 per cent minus 400 mesh in rod and ball mills for flotation feed. Conditioning and aeration precede rougher flotation, and four stages of cleaning bring concentrates to a grade of 42 per cent Pb + Zn + Cu. Middling products are reground and refloated in a secondary flotation circuit, producing a cleaner feed and a final tails product. Primary bulk concentrate is treated with sulphur dioxide and steam-heated to l 70°F and the majority of the gangue is floated off, leaving a product that assays 57 per cent combined Pb + Zn + Cu and is suitable for marketing. This material is thickened, filtered, dried and loaded into railway cars for shipment to the smelter. Reagent use on flotation is conventional, with many compromises in dosage required to maintain the recovery of lead and zinc in the most advantageous proportions. Many refinements in the flowsheet have been made since start-up in 1966, and more may be made as laboratory and plant testwork indicate possible improvements."

Jan 1, 1971

By Luther W. Bahney

(San Francisco Meeting, October, 1911.) LIME is the alkali that is almost universally added to the solutions in the cyanide process of gold- and silver-extraction for maintaining the so-called, protective" alkalinity. It is produced by the burning of limestone. The value of lime for this purpose depends upon the percentage of calcium oxide contained, which is determined by three factors : 1, purity of the limestone used; 2, degree of the burning-temperature and the period of burning; and 3, length of time of storage of burned material and the condition stored, and whether it has been damp or wet during the storage. These three factors render uncertain the quality of lime bought in the open market. In the United States, lime bought from reliable manufacturers, who thoroughly burn a pure limestone and deliver at once to the consumer from the kilns, may be of a fairly-high and uniform composition ; but in Mexico and Central America, where it is purchased from many small producers, who often start with a poor grade of limestone and burn it in small crude kilns with as little fuel as possible, the quality of the product is quite variable. In consideration of the foregoing, it is apparent at once that there is a great need for a rapid technical method for the valuation of the lime to be used in a cyanide-plant. The determination of calcium by the gravimetric method, with the necessity of determining also the proportion of carbon dioxide, silica, and iron, requires too much time, and is usually out of the question for an isolated plant unequipped with a skilled chemist and, the necessary apparatus. The calculating of all the calcium so found to calcium oxide, although sometimes done, is manifestly very inaccurate.

Nov 1, 1911

By E. G. Joe

"Recent trends in Canadian mineral processing were reported in seven areas of interest covered by seventeen technical papers at the 1976 Annual Meeting of the Canadian Mineral Processors, held at Energy, Mines and Resources' Camsell Hall, Ottawa. New milling equipment included the Enviro-Clear thickener, large-volume Outokumpu flotation machines and abrasion-resistant polyurethane screens. Grinding experiences from a variety of milling operations were reported. Opportunities for increased sizing and grinding efficiency were presented. Flotation control by digital computer and by chemical additions were described in two mill operations. Slurry pumping and sampling techniques were described for various operations. Environmental control in milling was reported concerning dust suppression, arsenic removal and tailings disposal. Several aspects of gold milling were described by the most recently commissioned gold mine and by CANMET. Potash operations were reported showing the similarity of processing and process control to that of metallic minerals."

Jan 1, 1976

By R. M. Santmyers

Thorium and cerium are two of the group of elements known as "rare earth metals," and are obtained from the mineral monazite. Previous to the employment of thorium and cerium in incandescent gas mantles these elements were nothing more than laboratory curiosities, as the rest of the rare-earth metals are to-day. The most important salts of these rare earths are the nitrates. In the manufacture of gas mantles, thorium nitrate is the principal ingredient and forms prom 92 to 99 per cent of the impregnating material; the other 1 or 2 per cent is largely cerium nitrate and is quite as necessary, for without it there would be little luminosity to the mantle when in use. When the mantle is "burned off," the nitrates are changed to oxides. The monazite used as a source of thoria contains from 6 to 9 per cent of thorium oxide (Th02) and 24 to 32 per cent of cerium oxide (Ce203). As only the thoria and a very small hart of the ceria from the monazite could be used in gas-mantle manufacture, for a time the residues consisting mostly of ceria with somewhat smaller quantities of other rare earths found no commercial application. Later, however, they came to be utilized in several ways, the most important being: (1) the manufacture of cored flaming arc carbons, a great, irmprovement over the plain arc carbons used in electric lighting; (2) cerium metal used in the manufacture of pyrophoric or sparking alloys or "flints" for automatic pocket lighters and miners' lamps; and (3) the production of special kinds of optical and art glass.

Jan 1, 1930

By J. E. Cleveland

The major health concern for uranium miners is the release of radon gas and the resultant ingrowth of the short lived daughters in the mine atmosphere. Present methods of control are the utilization of mine ventilation systems for dilution and control of ingrowth time to maintain working levels below those set by regulations. This study examined pressure cycling efforts on the radon emanation. The mechanical ventilation systems were altered to allow pressure changes throughout the mine to increase radon influx during the off shifts and thus deplete the sources of radon gas. Continuous radon working level and environmental monitors, developed by the Bureau of Mines, were employed to monitor radiation and physical parameters in the mine workings. The mine ventilation system was then varied to induce radon flows during off shifts, thus, depleting the radon sources during normal production shifts. Electro-static precipitators were also tested to determine radon daughter collection efficiencies. Both radon and radon daughter concentrations were monitored and evaluated. Major problems were found in the simple mechanical operation of cleaning these units.

Jan 1, 1982

By L. G. Marshall

This report is one of a series published by the Federal Bureau of Mines describing mining methods and performance at individual operations throughout the United States. The objective of these papers is to promote development and conservation of our mineral resources by disseminating reliable technological information on mining methods, practices, and results that may be applied to the engineering analysis and solution of mining problems. SUMMARY Operation of a limestone quarry producing flux for the steel industry and crushed stone for production of concrete is described in this report. The deposit being mined is a flat-lying limestone formation under a thin overburden 2 to 25 feet thick. The height of the quarry face varies from 9 to 60 feet, averaging 40 feet. Production rate ranges from 4.5 to 5 million long tons per year.

Jan 1, 1959

By Shigehisa Endoh, Hitoshi Ohya, Atsushi Inaba, Shigeki Koyanaka

"Recycling should be promoted to keep the global environment. However, it is difficult to detennine the quantitative impact. A life cycle assessment is one of the most reliable methods to estimate the global environment impact.Exergy is useful like entropy when considering the sustainable development. All of our activities have been obtained exergy resources and/or energy itself and throw away waste and/or waste heat. We are trying to use exergy to estimate the quantity of energy and matter for resource accounting. For recycling plastic, plastic has two aspects; material and energy source.The environmental assessment of plastic recycling suggests that the exergy reduction of the entire system is estimated by the yield of matter and the process efficiency. The material recycling is better than the thennal recycling when the process efficiency is high. However, the thennal recycling is much better for the low efficiency. The transition point is able to be decided by the efficiency of the manufacturing and the electric power generation.IntroductionRecently, many of the global environmental problems have become conspicuous like global wanning, ozone layer depletion and acid rain. Some of the methods like life cycle assessment for solving these problems have been presented. Anxiety concerning the proble1ns of energy and resources has led to a rapid increase in the interest in describing and understanding the conversion processes of energy and other resources in today's society. All human activity is supported by obtaining power and products of high exergy from the environment and throwing away the waste material and the waste heat of low exergy back the environment. However, the total exergy in the whole system becomes absolutely smaller than before.The rate of obtaining high exergy products and energy itself by human activity and the speed, by which waste and waste heat having low exergy are thrown away are too fast to attribute to environmental problems [1-3].A material's use by recycling was often common in a circulating society mainly. A significant amount of energy is consumed during circulation. An environmental impact assessment method for the process or the system has not been devised when both of them are taken into consideration. Even if the life cycle assessment evaluation, which has been correctly used up to now, is applied, it is not sufficient for an overall evaluation concerning matter and energy.The real sustainable development is that the exergy reduction value by all human activities on the earth is kept within the range of the exergy reduction in order to consider the earth as closed stationary system. It is important to evaluate the process or the system by using the exergy, and design them so that the exergy loss may decrease as much as possible. We have to consider what process improvement is the most effective."

Jan 1, 2000

By Donald L. Freed

Design, development, factory test, and in-mine evaluation plans are presented for an Automated Extraction System (AES) that has been designed to fill needs which are present in the Mining Industry. The philosophy of design and proposed operation of the machine, as well as the relationships between these factors, and final machine configuration are reviewed. The AES is designed to overcome production problems resulting from the regulation of roof control, clean-up, ventilation, dust suppression, and operator protection required by the Federal Coal Mine Health and Safety Act of 1969. The design permits more continuous operation and greatly improves operator safety. The machine is a full-face drum-type continuous miner which includes self-advancing, continuous temporary roof support. Onboard self-advancing face ventilation, dust suppression, and air scrubbing equipment are also included in the design. A further improvement over existing equipment is the incorporation of an automatic programmed cutting cycle control system. All mining functions including movements of the roof support system are handled by this automatic system.

Jan 1, 1977

By Elaine T. Bowers

The Sunnyside single-entry project pioneered the use of single entries for longwall development in this country. During the 10-year course of the project, an immense amount of information was gathered. Over three miles of entries were observed primarily through instrument groupings placed in strategically located areas or "rooms." Nearly 1,200 instruments were monitored to gain information on the behavior of coal entries during development stages and through the mining of two longwall panels. This was one of the most extensively documented projects undertaken by the Bureau, The data gathered has a great potential for scientific research especially in the area of longwall mining. This Bureau of Mines report presents the ground control data gathered, in the form of computerized plots. Roof-to-floor deformation and load on cribs and roof bolts make up the bulk of the data, which is presented as load or deformation versus time. The plots are organized, generally, by the three main entries involved and, specifically, by the individual areas or rooms in those entries. No major attempt will be made, in this paper, to analyze the data other than to identify its source arid its history.

Jan 1, 1983

By Paul C. Hyndman

The U.S. Bureau of Mines inventoried Federal mineral lands in Idaho and classified them in detail, section by section, according to their availability for mineral exploration and development as affected by legal restrictions and agencies' management practices. The Bureau also identified known mineral deposit areas (KMDAs) and areas conducive to oil, gas, and geothermal resources. This information is shown on maps (developed in part by geographic information system technology) that spatially compare the availability for mineral entry of Federal land with these KMDAs to demonstrate the extent and severity of restrictions on mineral entry. Idaho contains 53.1 million acres, 35.7 million (67%) of which is Federal mineral land. About 7 million acres of this land is within KMDAs that host medium-to high-value locatable mineral deposits; 36% of this land is available, 27% is slightly to moderately restricted, and 37% is severely restricted or unavailable. For the leasable minerals, about 1.8 million acres are within KMDAs that host medium-to high-value phosphate deposits, about 5.4 million acres are favorable for oil and gas resources, and 3.9 million acres for geothermal resources. The percentages of land availability are 30%, 45%, and 25% for the phosphate acreage, 38%, 34%, and 28% for the oil and gas acreage, and 43%, 30%, and 27% for the geothermal acreage.

Jan 1, 2012

By Leykam Chris J., Jacobs Scott. A.

"Construction of the New NY Bridge over the Hudson River 25 miles north of New York City is one of the largest civil infrastructure projects presently underway in the United States (formerly Tappan Zee Hudson River Crossing). The $3.14 billion Design-Build contract is also the largest ever awarded by the state of New York using an Alternative Project Delivery method, and the first major public project to use Design-Build. The new 3.1 mile long bridge will replace the existing Governor Malcolm Wilson Tappan Zee Bridge with a modern twin crossing featuring: Iconic side by side cable stay main spans; significant deck widths accommodating eight lanes of regular traffic, wide shoulders, and a shared use pedestrian and bike path; foundation with excess capacity to fully support a future rail bridge; more than 1,000 large diameter pipe piles driven in deep glacial deposits; drilled shafts installed through steep blast-rock slopes on the east shore landings. Geotechnical challenges included varied bedrock and glacial till surfaces with steep slopes and depths in excess of 750 ft.The purpose of this paper is to highlight major features of the New NY Bridge project with specific focus on the design and construction of the foundations supporting the approach and main span structures from abutment to abutment, provide background on alternative project delivery in NY, as well as provide an overview of the design-build process as it was applied to foundation delivery.The 3.1 mile Governor Malcolm Wilson Tappan Zee Bridge was constructed across the Hudson River connecting Nyack and Tarrytown (Rockland and Westchester Counties). Construction started in March 1952 and was completed in 1955 for a cost of $81 million. The seven lane crossing first opened to traffic on December 15, 1955 and coincided with the opening of a 28 mile segment of highway I-87 / I-287 between Suffern NY and Yonkers NY. The bridge is part of the extensive 574 mile New York State Thruway road system owned and operated by the New York State Thruway Authority (NYSTA)."

Jan 1, 2016

By A. B. Cecala

The Bureau of Mines performed a study to determine optimal locations for longwall face methane monitoring equipment. Longwall face ignitions continue to be a concern to the U.S. coal mining industry. Gains in ignition control technology have been somewhat negated by advances in longwall productivity. More reliable, heavy-duty longwall face systems generate higher production rates and increase methane liberation rates. These rates will likely continue to rise in the future as further coal production increases occur. Efforts will continue in the areas of methane drainage, methane containment, and methane dilution. In addition, more effective face methane monitoring is needed. As technology continues toward automated longwall panels, the importance of monitoring for methane at the shearer becomes even more significant. Since the primary face ignition source is the shearer mining machine, the Bureau ran tests to determine the best location to take methane readings on the shearer. This information, in conjunction with data obtained from field studies, provides a knowledge base for selecting optimum face methane monitoring locations.

Jan 1, 1993

1. Theory of Wet Dust Suppression Techniques Wet dust suppression is the utilization of a liquid for the control, reduction or elimination of airborne dust, or the suppression of such dust at its source. Effective control involves: a. The confinement of the dust within the dust producing area by a curtain of moisture. b. The wetting of the dust by direct contact between the particles and droplets of moisture. c. The formation of agglomerates too heavy to remain airborne, by combining small dust particles with each other and with the droplets of liquid. From the standpoint of economy, availability and safety, water is the ideal fluid. From the standpoint of effectiveness, however, it leaves much to be desired. As a result, a tech¬nique has been devised in which very small percentages of specially formulated dust control compounds are blended with water to greatly enhance its dust suppression qualities. The terms "dust control compounds, wetting agents and surface active agents" are frequently used interchangeably. Although dust control compounds represent a specific type of wetting agent, a great many wetting agents are far from satisfactory for dust control. "Wetting Agents" is a broad category which covers such items as emulsifiers, solubilizers, detergents, foamers, penetrants, thickeners, etc. Dust control compounds, on the other hand, are carefully formulated blends in which one or more special surface active agents have been incorporated.

Jan 1, 1972

By Nozomu Hasegawa

The phase diagrams and microstructures of the slags in the Mitsubishi Continuous Copper Smelting and Converting Process were studied for the prevention of the magnetite troubles such as accretion build-up on furnace hearths and launders, blockages at the melt outlet, slag viscosity increases and so on. According to the results of those studies, the silica and lime contents in the silicate slag at the smelting furnace, and the lime content in the lime-ferrite slag at the converting furnace were changed, resulting in lower and more consistent copper levels in the discard slag, with much less need for operators to clean melt outlets and launders. However, these changes may decrease the desirable amount of accretion-coating inside the furnaces and thereby reduce furnace campaign lives. Therefore, a method of estimating the magnetite level in the melts was developed, and slag compositions and temperatures have been controlled within the appropriate ranges to prolong furnace lives and also prevent magnetite troubles.

Jan 1, 2003

By Jyri Talja, Shaolong Chen, Hannu Mansikkaviita

"Drying (water removal) prior to smelting is always economically feasible. Unnecessary heating of vapour can thus be eliminated resulting in savings of5-15 MUSD every year.Thermodynamically removal of one ton of water out of copper concentrate at 100 °C (with 10 % moisture) requires approximately 3150 MJ/tH2o, consisting of heating of the water (377 MJ), heating of the concentrate (509 MJ) and water evaporation (2260 MJ). This is quite independent of the selected drying technology. In reality some more heat is needed as higher temperature is practiced to enhance the drying performance and to reduce the equipment size.Major nominator in drying energy efficiency is amount of gases, which depends greatly on the drying technology. Dryers based on direct heating with fossil fuels have high gas flow rates, and thus they require additional energy of about 1400-1600 MJ/tH2o, compared to indirect modemsteam drying at 250-400 MJ/tH2o.Significant benefits in energy consumption (900-1300 MJ/tH2o) with additional potential for a bonus profit of 2-4 MUSD/y year, together with full elimination of some 40 000 tpy CO2 per mid-size dryer is available by selecting sustainable, energy efficient steam drying.IntroductionRemoval of water from the concentrate is very energy intensive thus having a significant environmental impact. However, drying prior to smelting is always economically feasible and very often viable also from the perspective of process operations. This environmental impact of drying can, however, be decreased or even fully eliminated with proper selection of the drying technology.Energy incorporated in drying consists always of a number of phases like liquid (water), solids (concentrate) and gases (water vapour, purging I dilution air, combustion gases). Each phase is heated to a specific temperature during the drying process.Heating of water, heating of the concentrate and water evaporation consumes more or less the same amount of energy despite of the drying technology (3150 MJ per ton of water). In conventional drying this amount of energy is achieved by combustion of fossil fuels wirg subsequent CO2 emission. Alternatively, chemical energy derived from sulphide smelting can be utilized in a form of steam thus generating zero emission ofCO2, in modem steam drying."

Jan 1, 2012

By John F. Papp

The objective of this U.S. Bureau of Mines study is to calculate an accurate, reliable estimate of chromium and nickel content of stainless and heat-resisting steel produced in the United States. The columbium, manganese, molybdenum, titanium, tungsten, and vanadium contents of this steel are also calculated. Such contents are required for estimating the quantity of alloying element recovered from recycled stainless steel and consumed by market sectors. In this investigation, the elemental fraction of stainless and heat-resisting steel was calculated as the ratio of the weight of element contained in stainless steel to the weight of stainless steel produced. The elemental fraction has been calculated as a time-averaged, grade-averaged value. The elemental fraction was averaged from 1962 through 1983, and averaged over the grades for which production was reported by the American Iron and Steel Institute during that time period. The 1962-83 average elemental fraction of U.S.-produced stainless and heat-resisting steel was calculated for chromium to be about 0.17 ± 0.01; columbium, 0.00014 ± 0.00003; manganese, 0.015 ± 0.005; molybdenum, 0.004 ± 0.001; nickel, 0.07 ± 0.01; silicon, 0.009 ± 0.001; titanium, 0.0004 ± 0.0001; tungsten, 0.0001±0.00003; and vanadium, 0.00003±0.0000l.

Jan 1, 1991

By A R. Bye

The mining industry is facing some key challenges that provide a compelling case for geometallurgy initiatives. Over the last 30 years, the average grade of Australian orebodies being mined has halved while the waste removed to access the minerals has more than doubled. In the last eight years, the industry’s energy consumption has increased 70 per cent while multi-factored productivity has fallen 24 per cent. The paper documents a broad range of industry case studies which demonstrate strategies for gaining value from geometallurgy.The mining industry constantly faces the key questions of how significant ore variability is on mine valuation and how would knowledge of the variability change the mining schedule, mine to mill design and operation. Using case studies the paper describes the methods used for incorporating mineral extraction attributes into orebody models and their technical integration into daily operation as well as mine planning optimisation. While pit optimisation from a fully attributed geometallurgical model highlights areas of opportunity and risk it is shown that during the scheduling phase of mine planning that significant value can be added. The benefits from these projects included reducing geotechnical and environmental risk, improving mine to mill performance, option analysis and quantified cash flow risk. There is growing acceptance within the minerals industry that ‘realistically assumed modifying factors’ defined by a competent person/s are not sufficient to mitigate the risk of funding mining ventures. Geometallurgy is moving away from factored ore reserves to data-rich block models providing reliable information for mining, metallurgical and environmental considerations.

Sep 5, 2011