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By Koji Matsubara, Yoshiaki Iguchi, Shoji Hayashi

Iron ore particles of a limonite iron ore were reduced completely with H2 at 1023K to 1273K in a fluidized bed. Then, at 973K, the formed iron was exposed to HrH2S mixtures (sulfur activity, as=0.5) for 3.6ks and carbidized with CO-H2-H2S· mixtures at 0.1 MPa. During the carbidization, the particles of about 150mg were sampled at every 600s interval. The sampled particles were analyzed by XRD and chemical analysis for C and S to evaluate the content of Fe3C, Fe5C2, Fe and free carbon. The reaction extent is defined as fo=Xfc3C +xFc5c2; x is the molar fraction of Fe in Fe3C. The carbidization curves can be fitted very well to -ln(l-f0)=g(pb T)t; g(p; T) is the carbidization rate, i.e. the carburization rate on the pore surface of reduced iron. The rate is found to be nearly proportional to the specific surface area of reduced iron, a P 0 , which decreases with increasing the reduction temperature. The value of a P 0 does not change by the carbidization and the stability of the iron carbide product in the atmosphere increases with the temperature.

Jan 1, 2000

By A K. Ghosh

"Inrush of water is always an issue, especially for mines located in heavy rainfall areas. Nowadays, mining companies and research institutes have developed many advanced technologies for study and analysis of hydrological processes. In this paper, an advanced method is introduced, which uses the Shuttle Radar Topography Mission Digital Elevation Model (SRTM DEM) data in the Geographical Information System (GIS) platform to simulate the stream distributions around two specific mines: Super Pit and Griffin coalmine in Western Australia. The impact of this approach is important because it reduces the time and economic cost by creating a high spatial resolution hydrological map in the specific areas. The study identifies the flow path of the run-off water, which helps in adopting a suitable water management plan surrounding the case study mines. The results match with the ground reality. Based on the results, the stream structure around Griffin coalmine is more complicated than that of Super Pit. The bifurcation ratio and drainage density are computed to estimate the subsoil permeability characteristics of the two mines. Recommendations have been put forward to prevent and reduce the potential risks of water accumulation around the open pit mines.Citation:Ghosh, A K, 2016. Application of Shuttle Radar Topography Mission Data in Hydrological Analyses of Super Pit and Griffin Coal Mine, in Proceedings Ninth AusIMM Open Pit Operators' Conference 2016, pp 162–169 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 15, 2016

By N. S. Dalal, Xiaoya Sun, Xianglin Shi

"The in vivo toxicity of vanadium(V) has been found to correlate with the depletion of cellular glutathione and related non-protein thiols. With a view to understanding the mechanism for this observation, we have investigated the oxidation of glutathione, cysteine N·acetylcystcinc and pcnicil· lamine by vanadium(V), using electron spin resonance (ESR) and ESR spin trapping methodology. The spin trap used was 5,5-dimethyl-l-pyrroline I-oxide (DMPO). It is found that the oxidation of these thiols by vanadium(V) generates the corresponding thiyl radicals and vanadilim- (IV) complexes. The results suggest that free radical reactions play a significant role in the depletion of cellular thiols by vanadium(V) and hence in vanadium(V) toxicity. 1. INTRODUCTIONThis communication reports on the identification of thiyl radicals formed as intermediates in the reaction of vanadium(V) with glutathione (GSH) and related nonprotein thiols. This study was undertaken because the biochemical mechanism of vanadium toxicity is still not fully understood,. despite being a topic of current research activity [1-20). As to possible clues, it is known that vanadium is most toxic when administered in its pentavaient state [21), and that vanadium(V) administration into laboratory mice reduces cellular levels of NAD(P)H and GSH [22). While the oxidation of NAD(P)H by vanadium has been studied extensively [16-20), that of glutathione and related non-protein thiols has been paid less attention. On the other hand, GSH and related thiols are important cellular antioxidants [23). Their functions include decomposing lipid peroxides and protecting cell membranes [23-25). Thus any reduction in the cellular contents of such nonprotein thiols after vanadium exposure may result in the accumulation of lipid peroxides which might ultimately lead to tissue injury. With a view of finding the mechanism for this thiol depletion process, we have investigated reactions of non-protein thiols with vanadium(V). Particular attention has been paid to the detection of thiyl radicals, since it has been postulated [l] (but not experimentally proven) that the glutathionyl radical (GS·) might be an intermediate in the reaction between vanadium(V), NADH and GSH. We have used electron spin resonance (ESR) and ESR spin trapping methodology for investigating the reactions of GSH, cysteine, N-acetylcysteine and penicillamine with vanadium(V). The results show that the corresponding thiyl radicals are indeed formed in the one-electron reduction of vanadium(V) by all of the above mentioned thiols."

Jan 1, 1990

By D. A. Stanley

Researchers at BCD Technologies and the University of Alabama have applied three statistical techniques to the information contained in a large database of measurements from a phosphate ore processing plant. The rust, Principal Components Analysis (PCA), replaces many measured variables with a few fundamental and un-correlated variables. The second technique, Projection to Latent Structures (PLS), is an extension of PCA that explores the relation between variables identified as either independent or dependent. The third technique, Cluster Analysis (CA), is applied to the results of the PCA or the PLS calculations, and identifies individual data clusters that represent uniform operating conditions in the plant. All three statistical methods can be seen as geometrical operations on the data viewed as points in space. A Viewer gives a corresponding graphical presentation of the data points. This paper describes the use of the above three techniques and the Viewer to explore part of the phosphate flotation database.

Jan 1, 1998

By Áureo Del Vecchio, Lídia Dely Alves de Sousa, José Pereira

The potassium demand for agriculture purposes has increased in Brazil, which has great deficit of internal demands. Potassium-rich rocks have been used as fertilizers as technological alternatives for agriculture aimed to reduce the amount of chemicals and the sector dependence for such products. Vermiculite tailings from União Brasileira de Mineração - UBM, at Santa Luzia - PB, was studied aiming their application in agriculture by potassium release. The sample was analyzed by XRF and XRD; studies on release kinetic with particles smaller than 2 mm added of organic acids (citric and oxalic) at 10-2 mol/L concentration; samples were analyzed by XRD after kinetic assays. The work was conducted using a shaker incubator at 300-rpm agitation and time variation to better understand the potassium availability in the ground. Results show the presence of K2O at 3.46% concentration. Citric and oxalic acids increased the release speed to almost the same level with speed coefficients (k) of 2.61x10-2 h-1/2 and 2.55x10-2 h-1/2 respectively. In statistical terms for both acids, the linear equation represents more than 99.0% of the experimental assays. Stonemeal was applied to banana seedlings in experiment conducted in a greenhouse. The use of vermiculite tailings in banana seedlings promoted potassium absorption, which influenced its growth. The amount of potassium liberated from vermiculite tailings could be used as a long-term alternative to fertilizers in agriculture cultures.

Jan 1, 2014

By M. V. Sowmya

Batch biosorption experiments were carried out for the bio-remediation of Cr (VI) ions from aqueous solutions using Serratia marcescens, a Gram negative, heterotroph and Gram positive bacterial isolates from a chromite mine. The influence of various experimental parameters such as contact time, pH, concentration of Cr (VI) ions and amount of biomass was evaluated with respect to the uptake of Cr (VI). The bio-sorption of Cr (VI) was found to be quite rapid and the percentage biosortion was found to increase with increase in the equilibrium chromium concentration. The free energy of biosorption of Cr (VI) was estimated to be in the range of -23 to -25 kJ/mol for the chosen bacteria. The uptake of chromium by the bacteria was confirmed by EDX and FTIR spectroscopy. As a follow up of this study, bacterial strains resistant to hexavalent chromium were isolated from a chromite mine in Karnataka, India and identified as Arthrobacter sp., Micrococcus sp. and Exiguobacterium sp. using 16s rRNA sequencing. The efficacy of the bacterial isolates for Cr (VI) uptake was assessed and over 90% bioremoval could be achieved for Serratia marcescens and Micrococcus sp. isolate. Possible mechanisms of chromium uptake by the microorganism are discussed. Keywords: bioremediation, hexavalent chromium, biosorption, bioreduction

Sep 1, 2012

By Landy Stinnett

"When performing a valuation of a mineral property, a developing mine or perhaps an ongoing operation, the appraiser is typically provided with a range of information prepared by the property owner. This information can include ownership records, geological interpretation, assay data, an estimate of the reserves or resources believed to be on site (tons and grade), mine plans, production forecasts, capital and operating cost projections, and so forth.The appraiser familiarizes himself with the data, analyzes the various reports and then prepares the appraisal. There is usually a site visit, and there may be some effort at comparison of the particular mineral deposit with others in the region or with those of similar depositional characteristics, but for the most part, the appraiser is relying on the corporate documents, tempered by his/her experience in the field. Time is usually of the essence, the cost for the assignment has been trimmed, and therefore independent verification of the various components comprising the underlying data base (legal review, redrilling portions of the deposit, collection of new samples, re-assaying, etc.) is unlikely in most situations.In the case of high-value commodities — gold, silver, diamonds, perhaps the platinum-group elements — there have been numerous examples of the property owners attempting to increase the value of their holdings by nefarious methods. Most of these involve salting the deposit in some fashion; i.e., introducing small amounts of the commodity into samples being sent to a laboratory for analysis so that the resultant assay shows a higher grade (Donaldson, 2002; Greeley, 2001; Lechler et al., 2008 and Meech, 2001). Other schemes to enhance the apparent worth of a property include the use of nonstandard assay procedures, incorrect handling or withholding of the underlying information, and false reporting."

Sep 1, 2016

By Myron W. Mellor

Much has been published concerning the subject of coal preparation as related to electric power generation however it is always a most vital topic for both utilities and coal producers, It also constitutes a field of study that is never finished since new concepts and changing demands continually require altered perspectives. One graphic illustration that has been used to emphasize the rapidity with which times are changing is the fact that during World War I, a station that consumed 1000 tons per day was looked upon as a large central station, while today some single generators require 1500 tons during the same period, For further emphasis, at that time a 20,000 horsepower turbo-generator was a mighty large machine; today, a unit of this size is planned for driving the boiler water feed pump required for a single large main unit. During the past ten years alone, electric utilities have more than doubled their percentage of coal consumed as compared to the total market. They now account for approximately 40% of the United States consumption and one-third of all production including export, Conversely, approximately 70% of all U. S. steam electric generation is by coal and this percentage is expected to increase. It is further predicted that utility consumption will increase from the current 160,000,000 tons per year to between 400 and 500 million tons in 1975 which is approximately equal to todays total production

Jan 1, 1959

By V. M. Sokolov, Jr. DuPlessis

The technology for recycling fine wastes, grinding sludges or swarf, and solids such as slag that contain a high content of metallic material needed improving. The objective was to produce a master alloy that met the tight requirements of the Western manufacturers and achieve improved yields of the valuable elements, nickel and cobalt, to over 90%. The alloys from the production of Alnico. magnets were chosen for this work. A process is proposed .that is able to recycle all kinds of Alnico wastes. This process is able to reduce all detrimental elements, which are contained in the wastes, to within acceptable levels. Molybdenum, if present, is an exception. Depending on the levels of contamination of undesirable elements different recycling strategies are proposed. The majority of the wastes can be recycled by melting and refining with a liquid slag layer using unique melting furnaces that are relatively unknown in Western nations. The proposed technologies allow the reelamation of over 95% of the cobalt and nickel from any kind of Alnico waste, and there are no limitations on the proportion of different kinds of wastes in the charge. The proposed processes and technologies could also be applied to the recycling of grindings, turnin

Jan 1, 2000

By A. P. Pavia

Investigation on profitable ways to recover significant quantities of silver remaining dissolved in highly concentrated chloride solutions frequently pass through the development of solvent extraction (SX) routes. In this work, the general pathways involving Ag(I) extraction by dibutylthiourea (DBT) or tetraethylthiuram disulfide (disulfiram, DSF), from concentrated acidic chloride solutions, are investigated. With this purpose, the dependence of Ag(I) distribution coefficient on ligand and chloride concentrations has been analysed. Furthermore, in order to check whether there is some protonation at any site of DBT or DSF after contact with adequate chloride phases, lH NMR has also been used. The collected spectroscopic data suggest that anionic Ag(I) extraction reactions are not likely to occur. Based on the overall results achieved, proposals for the most probable Ag(I) extraction reactions are made.

Jan 1, 2001

By Erik C. Westman

Knowledge of the orientation and relative magnitude of in-situ stresses at the mine scale is important for safe and efficient production from an underground mine. With this knowledge, stope location and scheduling can be optimized. Passive seismic tomography was used for imaging horizontal stress distribution at the mine scale. Microseismic measurements from the Creighton mine were used as input for the tomography calculations. The double-difference tomography algorithm was used, which provides the most precise results. The results clearly show a low velocity zone in the previously mined areas bounded by two high-velocity lobes located adjacent to the mined openings at locations consistent with those expected due to the horizontal stresses at the mine. The overarching goal of the research is to provide a tool that can augment both numerical modeling results and underground geotechnical measurements to allow the mine operator to produce in the safest and most efficient manner possible.

Jun 1, 2012

By D. Gagnon, B. Dubreuil, J. -M. Lalancette, D. Lemieux

"The pilot scale extraction of gold with a brine of sodium chloride and bromide at 30 ºC, in an atmosphere of halogens at atmospheric pressure, leads to gold chloride with 95% gold recovery. The use of dilute hypohalites (1 – 3%) instead of free halogens, which is strong enough to oxidize hypobromite into bromine, simplifies the recycling of halogens by electrolysis. With the recycling of water and brine, the regeneration of hypohalites and with a barren solid that is inert and stable. The Nichromet Extraction technology is a green process where the protection of the environment does not preclude profitability.INTRODUCTIONThe use of chlorides for the extraction of gold predates the discovery of chlorine by Scheele in 1774. In the Plattner chlorination process (Christy, 1888) sodium chloride and copper salt were used to promote gold recovery by amalgamation with variable results. The introduction of the cyanide technology in 1889 has led to a general use of this method for gold recovery. In the last decades, a return to chlorine in extractive processes has been noted (Ferron, Fleming, O’Kane and Dreisinger, 2002), mostly because of environmental pressure for non-cyanide technologies.This paper describes a closed circuit proprietary approach (Lalancette, 2009) developed and piloted by Nichromet Extraction Inc. for the extraction of precious metals with recycled mixed halogens; chlorine and bromine from hypohalites. DESCRIPTION OF THE PROCESSThe attack of gold by halogens can vary significantly. The rate of reaction is substantially higher with bromine (Br2) than with chlorine (Cl2), by a factor of more than five, although the oxidation potential of Cl2 is higher than Br2, as shown in Equation 1a and Equation 1b (Latimer, 1952)."

Jan 1, 2012

By Ravindra M. Chhatre

Uranium associated with phosphate deposits has been the subject of numerous investigations (1-8). In the land-pebble phosphate deposits of central Florida, uranium is found in the phosphate matrix (ore) and in the leached zone between the over-burden and matrix (1). Between 0.01 to 0.02 percent uranium is found in the leached zone, which consists of apatite and aluminum phosphate minerals (crandallite, wavellite, millisite) (Z). The primary phosphate mineral in the matrix is apatite, and the 0.005 to 0.01 percent uranium typically found in the matrix is associated with this mineral (1). It is generally believed that uranium substitutes for calcium in the apatite structure (3-5). Clay and quartz phases associated with phosphate deposits contain little uranium (1, 6), and no descrete uranium minerals have been detected in these deposits (4). A typical phosphate matrix consists of quartz, slimes (-150 mesh material) and recoverable phosphate. When the matrix is beneficiated, partition of uranium and radium takes place (9, 10). Although considerable data exists on how uranium is distributed in the phosphate deposits, no systematic study has recently been reported on the distribution of uranium during phosphate rock beneficiation. The purpose of this study was to determine how uranium is distributed in the various strata which comprise the overall land-pebble phosphate deposits, as well as how the uranium is redistributed during beneficiation of phosphate matrix. To obtain this information studies were carried out on matrix samples obtained from three different mines in central Florida. Using pilot-plant scale beneficiation, an analysis was performed on how uranium in the matrix is distributed among the pebble fractions, flotation concentrates, flotation tails, and slimes. The uranium level profile for an active mining area was also obtained. Also, since thousands of acres of slime ponds may someday become a source of both phosphate and uranium, a depth versus uranium content profile was determined for an inactive slime pond.

Jan 1, 1978

High pressure grinding mills have been successfully introduced in the industry. They offer the possibilities for capacity increase of existing plants and reduction of operating costs. Further metallurgical advantages in gold and copper are possible. The plants in operation are running in different applications and modes of operation. They can be installed in a combination with SAG and ball mills or in a stand-alone mode. In combination with other grinding mills, it has to be investigated how the HPGR can be installed to reach the full efficiency. This paper describes the possibilities to implement high pressure grinding rolls and shows by case studies the potential of savings which could be reached

Jan 1, 1996

By Christian Redl

"The Lattice Boltzmann Method (LBM) solves fluid dynamics problems based on a discrete mesoscopic approach. It is based on the Lattice Boltzmann equation which is a special discretisation of the continuous Boltzmann equation. Its principle advantage is that it can handle complex physical phenomena (like interaction between different components and surface effects), complicated boundary and initial conditions very well, free from many gridding and stability constraints that plague conventional numerical methods used for fluid flow simulations. Complex structures like porous media can be resolved directly. The LBM algorithm has a simple structure and acts locally, which is favourable for parallel computing. Its potential for metallurgical process simulation is demonstrated in the present study which is concerned with the simulation of the fluid flow in a copper winning electrolysis cell. The electrolyte is modelled as the carrier fluid and the oxygen is considered via a so called active scalar equation. The modelling of buoancy, momentum exchange and the free surface requires special effort. The results of the simulation are validated against experimental data obtained by Laser-Doppler-Anemometry. Despite the simplifications made, good agreement between the simulation and the experiments was found.IntroductionThe hydrodynamics in an electrometallurgical cell is a complex, highly non-linear phenomenon. It includes the simulation of a two component system with high density ratio, gravity driven flow and a free surface. A general solution to this problem is currently unknown.The flow field is a result of the combination of various hydrodynamic effects [18]. Metal deposition at the cathode yields in a decrease in the ion concentration, which reduces the density of the electrolyte. At the anode molecular oxygen is formed as a consequence of the oxidation of water molecules. The oxygen is solved in the electrolyte and again the electrolyte density is decreased. Both effects lead to a free upwards directed convective flow, refered to as natural convection."

Jan 1, 2001

By J. O'Leary, R. Cannell, D. Honsberger

"The Scully Mine deposit lies within the group of metasediments that together comprise the rocks of the Labrador Trough. The ore itself still retains the bedding characteristics of the parent rocks and on this basis has been divided into three main members, namely: Upper, Middle and Lower. The Upper and Lower both show many of the bedding characteristics of the cherty taconites of the northern U.S.A.; the Middle member is a coarse-grained friable specularite rock. The ore minerals are hematite (normally present in the specular variety) and magnetite, although the latter rarely occurs in concentrations greater than 20 per cent. Gangue minerals are quartz and the hydrated iron oxides. Manganese oxides also occur as accessory minerals. The outcrop area of the orebody is in excess of 2 square miles, displaying a complex pattern of faulting and folding, which has been formed as a result of at least two orogenic periods."

Jan 1, 1972

By John J. Deutsch

"1T is a great pleasure for me to be present at the Annual Dinner of the C.I.M.; a pleasure which is combined with a mutual opportunity that I value highly. First of all, this occasion gives me a chance to meet again many Members of your Institute and to become more fully informed of the special problems of the mining industry. This alone is ample reason for me to welcome the invitation to join you tonight. In addition, this occasion provides me with an opportunity to tell you something about the work of the Economic Council which might be of particular interest to your industry.In the mining industry, keen competition and constant change are basic facts of life. The continuing prosperity of the Canadian mining industry depends fundamentally on how successfully it is able to adapt both to the changing conditions within the industry and to major trends which operate throughout the world.First of all, the scale and organization of the industry are evolving to new and different dimensions. As one authority has put it, ""The cream of the small high-grade, easy-to-mine ore deposits of this world have been consumed and mining is becoming more and more an industry of very large scale, complex operations. It has already become in most countries a capital intensive industry and its problems, scientific, technical and economic, are growing in difficulty."""

Jan 1, 1966

By C. Abbruzzese, F. Vegliò, S. Ubaldini, R. Massidda

"Gold solubilised during cyanidation can be recovered by precipitation (Merrill-Crow process) or by adsorption onto activated carbon, these being the techniques applied in industrial plants.Precious metals (Au, Ag) adsorbed onto activated carbon are extracted during a subsequent stage in aqueous phase, by various technologies, such as hot elution (70-80°C) or under pression desorption (100-130°), with hydro-alcoholic solutions.This stage is of great interest from an economic point of view, due to the high energy costs. Temperature represents the critical kinetic factor.The aim of this paper was to study the influence of different water/organic solvent mixtures (isopropyl alcohol, ethanol and ethylene glycol) on the desorption process.The experimental work was carried out on laboratory scale, using activated coconut carbon with different temperatures and extraction times, without adding cyanide.Best results have been obtained in this order: isopropyl alcohol > ethylene glycol > ethanol. Starting from gold concentration of about 5 g Au per kg of carbon, best kinetics resulted in 97-100% of gold extraction, after 8 hours of desorption, at a temperature of 80ºC."

Jan 1, 2003

By Lauren Shields

This paper discusses the application of current fragmentation models for underground blasting, establishes a conceptual fragmentation model for underground operations, and discusses the applicability of the mine-to-mill approach for underground blasting. Additionally, this paper also discusses selected case studies where the mine-to-mill approach is applied to underground mining operations.

Feb 1, 2020

By Harvey N. Davis

MUCH has been written and said during the last twenty years about the place of the engineer in modern life, about the fundamental role that he plays both in developing and in maintaining the material foundations of modern civilization, about the advantages, and also the dangers, of the machine age that he has inaugurated, about the Frankenstein problems that he has unconcernedly foisted upon a generation utterly unable to cope with them, and about the obligation that rests upon him to stop inventing machines and turn his almost legendary energy and skill to inventing institutions that will constitute a solution of the problems he has raised, and contrariwise about his utter inability to offer wise or useful counsel in fields outside the narrow boundaries of his technical training.

Jan 1, 1938