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By Satu Strömberg

A single-particle laminar-flow technique was used to study oxidation of two nickel concentrates and a granulated nickel matte (43 wt% of Ni). Experimental conditions were: reaction gas from N2 to N2 + 75 vol% O2; gas preheating temperatures ranging from 500 to 1100°C. The major nickel-bearing minerals in the two concentrates were pentlandite and violarite, respectively. Chemical analysis of the particles was used to determine the oxidation degree of the materials, and optical and scanning electron microscopy were used to detect their morphology and mineralogy. Total desulfurization of the nickel concentrates was achieved under the most oxidizing conditions, while the sulfur removal from the nickel matte was not as efficient, especially with the coarse size fraction. Pentlandite-based concentrate was found to be less reactive than the violarite-based.

Jan 1, 1995

By Arthur La Motte

I NDUSTRIAL explosives, as distinguished from military explosives, include high explosives and blasting powder. The high explosives which are best known are straight dynamite, gelatin dynamite, ammonia dynamite and permissibles. There are two kinds of blasting powder, saltpetre blasting powder and nitrate of soda blasting powder. Blasting powders are mechanical mixtures of nitrate of potash or nitrate of soda with sulfur and charcoal, highly compressed, granulated and glazed. They ignite from a spark and burn with relative slowness, the rate of burning and hence the rate of conversion into gases depending upon the size of the granulation and upon the degree of. confinement under which the powder is placed. High explosives, on the other hand, are chemical compounds which detonate; that is, when the explosive is subjected to a violent shock, provided in practice by a blasting cap or an electric blasting cap, the molecule of the essential ingredient, usually nitroglycerin, is disrupted and the energy and heat released cause any other explosive ingredients which may be present, such as ammoniuin nitrate or T.N.T., to decompose with a resultant evolution of gases at an extremely rapid rate varying from 6000 to 20,000 ft. per second.

Jan 1, 1924

By Ezra Ballinger, Matthew R. Glisson

Located in downtown Fargo, North Dakota, the Block 9 Redevelopment project site contains highly- compressible soils in the upper 100 feet with groundwater about 10 to 15 feet below the existing ground surface. The owner prohibited using driven piles to avoid disturbing neighbors of the project and historically, drilled shafts are used in Fargo as a reduced noise and vibration alternative to driven piles. However, developments over the last 20 to 30 years in drilling equipment, load testing and integrity testing resulted in the project team identifying augered cast-in-place piles as a suitable alternative for this project. To reduce the risks associated with using a relatively unproven foundation system in the area, the project team used the design-build delivery method for foundation design and construction. The team also specified compression load testing and higher-than-normal integrity testing. A successful bi-directional load test validated the design parameters for the augered cast-in-place pile while thermal integrity profiling gave the team confidence that these piles would perform similarly to the test pile. PROJECT DESCRIPTION The Block 9 Redevelopment project goal was to turn an existing, at-grade parking lot in downtown Fargo, North Dakota into a public outdoor plaza, a mixed-use building and a parking ramp. The project provides new offices, retail spaces, a hotel, a restaurant and private apartments. Situated in the southeast quadrant at the intersection of Broadway and 3rd Avenue North, the project site wraps around a bank building that was to remain. According to aerial photographs, the eastern portion of the site contained a public parking ramp that was constructed between 1952 and 1976, and subsequently demolished between 2009 and 2010. The western portion of the site had some combination of buildings and surface parking visible in aerial photographs taken between 1952 and 1979. Since 1984, aerial photographs show the western portion of the site being entirely surface parking. The redevelopment included the construction of three structures: the Tower, the Podium and the Parking Ramp, as shown in Fig. 1. With plan dimensions of roughly 100 feet by 100 feet, the Tower has 1 level of below-grade parking and 19 above-grade levels rising to a height of about 230 feet above grade. The Tower contains eight levels of commercial office space, four levels of hotel, six levels of residences and a mechanical level. This configuration resulted in column service loads ranging between 435 and 2,685 kips. The Tower core area has a total service load of about 30,000 kips.

Jan 1, 2019

By I. R. Stevenson, J. G. Dunn, T. N. Smith, L. C. Mackey

An experimental flash reactor has been developed to simulate the operation of an industrial flash-smelter reaction shaft. Four concentrate materials of differing mineralogical compositions were characterised and then oxidised in the reaction shaft. The products were examined by chemical analysis to determine the extent of oxidation and by electron-probe microanalysis to determine the fate of individual particles. This programme of work enabled the influence of mineralogical composition and particle size on the extent of oxidation to be assessed

Jul 1, 1991

By I. A. Kovalevska

Considered problems: elaboration and implementation of resource-saving technologies, low-cost support systems improvement, openings security and support, based on wallrock condition control with supreme implication into the rock pressure occurrence counteraction work. Results of analytic and underground investigations using computer simulation of the finite elements in order to calculate stressstrain state of the multivariable geomechanical systems are presented. Solutions of concrete objectives are found using spatial geomechanical model of solid motion around openings, considering real geomechanical parameters formation of support forms with proper conditions of their contact and real mechanical characteristics. Ultimate solutions of resource-saving technologies implementation based on the analysis of multivariate vertical, horizontal, and reduced stresses components calculation and also near-contour rock, support bearing components and security constructions movements are found. Results of experimental investigations of combined supports and security constructions, which increase openings' stability in difficult conditions of flat coal seams are presented.

Aug 1, 2013

By K Nakashima, K Aya, T Sumita, N Saito

Electro slag remelting (ESR) is one of the methods used to produce high-cleanliness steel. In the ESR method, the product steel electrode is immersed in flux, and the electrode is melted by the Joule heat of the flux generated by high current. CaF2-based melts are mainly used as fluxes, but the electrical conductivity of CaF2-based melts varies widely among researchers and measurement methods. Therefore, this experiment aims to measure the electrical conductivity of CaF2-based melts based on the van der Pauw-Ohta method, which does not require the cell constant that is a fundamental error factor in electrical conductivity measurement at high temperatures. The measurement temperature was set at 1450–1600°C, and dehydrated Ar flowed through the furnace at 200 mL/min. Electrodes were fabricated by Pt-30mass per cent Rh alloy, and the electrodes were connected to an impedance analyser using a four-terminal probe. The electrodes were immersed in the melt, and the impedance and phase angle were measured by AC frequency sweep (50 Hz to 200 kHz). The electrical conductivity was then calculated by utilising the impedance’s real part values when the impedance’s imaginary component was zero. The electrical conductivity showed a positive temperature dependence. The electrical conductivity of 60(CaO⋅Al2O3)-40CaF2 melt increased with increasing temperature but was found to be roughly one-third of those of the previous studies. In the conductivity measurement of 60(CaO⋅Al2O3)-40CaF2 melt, the AC frequency with a phase angle of 0° was found to be different depending on the temperature and immersion depth. By sweeping the frequency, the impedance at the phase angle of 0° can be obtained, which enables us to measure the electrical conductivity more accurately.

Jun 19, 2024

By Francis Martino

Just as coal producing mines are faced with various handicaps which control the quantity of coal produced and sold, the subsequent user of that product is faced with parameters that impact the optimum utilization of coal. Traditionally, the industry focused on the quantity of mineable coal in a reserve. The mine planning development was primarily concerned with two important criteria: (1) safety and (2) the productive efficiency in a quest to produce the lowest cost coal.

Jan 1, 1982

By Harry Asche

Tunnels are frequently specified by owners to be designed to a structural code, often a bridge code. In the USA, AASHTO have created a tunnel code, based on structural principles, the AASHTO LRFD Tunnel Design Specification. The Load Resistance Factor Design method (LRFD) described in the AASHTO title is an approximation to the probabilistic design of structures, based on the independence of load and resistance. This methodology is well known to be problematic in geotechnical design, but it is widely used. The paper considers the difficulties of this approach and describes alternative approaches that would result in more appropriate designs for tunnels.

Jun 13, 2021

By G. Bonnivard

"A complete laboratory process for the treatment of lateritic ores containing a high proportion of iron, as well as chrome and alumina, has been established. The ores treated originate from the tropical zones and result from superficial climatic alteration. According to recent estimates, the known reserves of such ores reach many billions of tons, thus representing huge potential reserves for the elements they contain.The process used is based on the alkaline roasting of pelletized ore in the presence of sodium carbonate. This treatment results in the separate recovery of pellets of upgraded iron ore, pure chrome oxide and hydrated alumina. The research described in the paper aims at determining the best experimental conditions for obtaining the highest extraction of the required oxide from this type of ore."

Jan 1, 1967

By M Paakkunainen

Sampling is often the most critical part in process analysis. When the mean of a continuous lot, such as a process stream within a given time interval, is estimated by calculating the mean of several samples, the uncertainty of the estimated mean depends usually on the sampling strategy. Three different strategies can be used: systematic, stratified or random sample selection. The standard deviation of the lot mean is different for these methods so that systematic sampling usually gives the smallest and random sampling the largest standard deviation. Pierre Gy developed a method where the sampling errors of one-dimensional lots for these three strategies can be estimated from a variogram, which is calculated from a variographic experiment, ie from a set of one-dimensional time series measurements with fixed sampling interval. While variogram is an excellent tool for characterising and displaying the variability of autocorrelated processes as function of time, the sampling error estimation from it is quite laborious, however. In this work an alternative method for estimating the sampling errors was developed. The process is divided into strata of equal sizes, varying the length of strata similarly to variographic analysis. For stratified sampling the standard deviation estimates are obtained by analysis of variance and for systematic sampling by fitting a linear regression line to each stratum and calculating the residual variances. By pooling the individual variance estimates the variance estimates that are corrected for autocorrelation are obtained. The new method was tested with simulated and real data sets having periodic, random and/or drift fluctuations. For stationary processes the results agreed well with the results of the GyÆs variographic method. The method can probably be generalised to estimate the sampling variance of higher-dimensional lots.

Jan 1, 2005

By Jiaqi Jin, Jan D. Miller, Chen‑Luh Lin, Amanda N. Erskine, Shijie Wang

Recovery of metals from coarse ore particles is a great challenge for heap leaching operations of low-grade precious metal resources. Internal fractures of ore particles like micro-cracks can facilitate subsurface transportation of solution inside particles and leaching of valuable minerals. A plant-scale high-pressure grinding roll (HPGR) unit at Coeur Mining’s Rochester mine was operated at selected specific pressures to crush and prepare various products for crack analysis using high-resolution X-ray computed tomography (XCT). 3D shapes of cracks inside ore particles for selected size fractions reveal different damage mechanisms during HPGR crushing regarding particle size and crushing pressure. Close-to-surface cracks formed by abrasion were found in small 2.5 mm particles. Impact cracks with a high aspect ratio were found in particles of larger size and higher HPGR pressure. The volumetric percentage of internal fractures and the specific crack surface areas of selected ore particles are compared to give quantitative conclusions on particle damage by compression during HPGR crushing.

Apr 20, 2024

By N. A. Gokcen, J. Chipman

Aluminum and oxygen dissolved in liquid iron were brought into equilibrium with pure alumina crucibles and atmospheres of known H2O and H2 contents to study the reactions: 1—Al2O3(s) = 2 Al + 3 0; 2—Al2o3(s) + 3H2(g) = 2Al+ 3H2o(g); and 3—H2(9) +O = H2O(g). Aluminum strongly reduces the activity coefficient of oxygen and similarly oxygen reduces that of aluminum. Values of the product [% All" • [% O]3 are much smaller than those found in previous experimental studies and are of the order of magnitude of the calculated values. ALUMINUM is the strongest deoxidizer commonly A used in steelmaking, but the extent to which it removes dissolved oxygen has been debatable. The relationship between aluminum and oxygen has not been determined reliably not only on account of the usual experimental difficulties at high temperatures but also because of uncertainties in the analyses of very small concentrations of oxygen and aluminum. The earliest experimental attempt of Herty and coworkers' was followed by a more systematic study of Wentrup and Hieber.' These authors added aluminum to liquid iron of high oxygen content in an induction furnace and considered that 10 min was sufficient to remove the deoxidation products from the melt. Parts of the melts thus obtained were poured into a copper mold and analyzed for total aluminum and oxygen (soluble plus insoluble forms), assuming that the insoluble parts were in solution at the temperatures from which samples were taken. It is conceivable that the furnace atmosphere in their experiments, consisting of mainly air at 20 mm Hg pressure, was a serious source of continuous oxidation and therefore that their oxygen concentrations were correspondingly high. Scattering of their data was explained to be well within the maximum inaccuracy of 10°C in the temperature measurements and errors of ±0.002 pct each in the oxygen and total aluminum analyses. Maximum and minimum deoxidation values, i.e., values of the product [% All' . [% O] differed by factors of 10 to 15; mean values of 9x10-11 and 7.5x10-9 ere reported at 1600" and 1700°C, respectively. Hilty and Craftsv determined the solubility of oxygen in liquid iron containing aluminum, using a rotating induction furnace. Pure alumina crucibles used in their experiments contained the liquid iron which in turn acted as a container for slags of varying compositions consisting mainly of Al2O3, Fe2O3, and FeO. The furnace was continuously flushed with argon, and additions of aluminum and Fe2O3 were made in the course of each experimental heat. The inner surfaces of their alumina crucibles were covered with a substance other than pure Al2O3, containing both iron oxide and alumina. Although frequent slag additions can change the composition of slag in the liquid iron cup formed by rotation, the inner surface of the crucible must depend upon the transfer of oxygen or aluminum through the liquid iron for any adjustment in composition. It is not clear that their metal was in equilibrium with the crucible wall, but it is clear that it was not in equilibrium with Al2O3. Their deoxidation product, [% A].]" • [% O]3, varied by a factor of more than 50; the average values of 2.8x10- and 1.0x10-7 were selected for temperatures of 1600" and 1700°C, respectively. Aside from the experimental determinations, attempts have been made to calculate the deoxidation constant for aluminum indirectly from thermody-namic data. Schenck4 combined the thermodynamic data for Al2O3 and dissolved oxygen in liquid iron by assuming an ideal solution. His calculated values are 2.0x10-15 and 3.2x10-13 at 1600" and 1700°C, respectively. Later, Chipman5 attempted to correct for the deviation from ideality and derived an expression which led to deoxidation values of 2.0x10-14 and 1.1x10-12 at 1600" and 1700°C, respectively. The errors in these treatments originate mainly from inaccuracies of thermal data and uncertainties regarding the activity coefficients of dissolved oxygen and aluminum. The purpose of this investigation was to study the equilibria represented in the following reactions in the presence of pure alumina: Al2O3(s) = 2Al + 3O K = aAl2.ao3 [1] Al2O3(s) + 3H2(g) = 2Al + 3H2O(g) H2O K2 = aAl2(H2O/H2 ) [2] H2(g) +O = H2O(g) K3 = 1/ao (H2) [3] The experimental method consisted of melting pure electrolytic iron, usually with an initial charge of aluminum, in pure dense alumina crucibles under a controlled atmosphere of H,O and H2 and holding

Jan 1, 1954

By H. J. Struth

AN unusual engineering achievement in the Gulf Coast last year was the drilling of a wildcat well in the swamps of Louisiana, using direct current. More unusual was the fact that it was necessary to house a diesel engine and generator on a barge in order to supply power. The remoteness of the well made it necessary to transport living quarters and drilling equipment to the location by means of barges, and involved the digging of a canal from a lake to the location, approximated one mile. The drilling equipment used on this well consisted of two generating units, each having one 210-hp. six-cylinder @$-in. bore type VDMA, 600 r.p.m. diesel engine, direct connected to a type CD-169, 125-kw., 250-volt direct current generator, which in turn is direct connected to a type CD-105, 15-kw. 250-volt exciter. One of these motors operates the draw works, one the mud pump, and one a duplicate spare. The generating equipment on the barge was approximately 250 ft. from the derrick, the control wires being brought from the derrick to the generator barge enclosed in a standard fire hose. This is an original idea for confining the con- 11.01 wires in one cable; obtaining minimum space and ample protection. Both control and power lines were suspended on poles. This well was at Lake Grande Ecaille Dome, which was located by seismograph in 1928. Fig. 1 shows the derrick, power barge and living quarters where direct G. E. current was used with rotary drilling equipment.

Jan 1, 1932

By Erik Bengtsson

Phenol was discovered in coal tar by Runge (1)1/ in 1834 and was isolated (2) in 1841 as pure phenol by distilling the tar, extracting with caustic soda, acidifying the extract, and fractionating the tar acids. Later, o-cresol was isolated (3) through careful fractional distillation of the tar-acid mixture. The m-and p-cresols distilled within a boiling range of about 1.50 c. and had to be separated by other means. Raschig (4) fractionated the tar-acid mixture to obtain pure o-cresol, sulfonated the mixture of m-and p-cresols, and treated the cresol-sulfonic acids with superheated steam at 1200 to 1300 c. to hydrolyze the m-cresol sulfonic acid, the p-isomer was not affected at that temperature. He also attempted to make use of the different crystallizabilities of the m-and p-cresol sulfonic acids (5). When treated with sodium bisulfate and sodium pyro-sulfate at 100° to 110° C. or with sulfuric acid (90/0) at 20° C., only the m-cresol was sulfonated (6). Hoffman-La Roche (7) treated the meta-para mixture with concentrated sulfuric acid at 40° to 100° C., when m-cresol and part of the p-cresol was sulfonated, and precipitated the m-cresol sulfonic add by diluting with water. The same sort of separation may be carried out by means of 80 percent sulfuric acid at 35° C. and 35 mm pressure (8).

Jan 1, 1950

By H. C., Simpson

MANY metals by virtue of their place of occurrence as ore, and their uses are travelers! Iron and steel, for instance, is one of the greatest of travelers in the form of ships and the romance of iron in this respect is only just beginning to be superseded by the stories which can be told of the travels of aluminum and its alloys, used in the building of airplanes. Tin is a traveler from the Straits Settlements to this country and Europe, for use in the canning industry; afterward traveling all over the civilized world as a part of the container for preserved foods. Silver is somewhat of an aristocrat, when its uses are measured against those of the baser metals. From earliest times it has been used for adornment (first perhaps o4 the person and later for the embellishment of weapons and' buildings), for the making of fine ar¬ticles used in the household, and as money. While its uses have been widened by the discoveries in chemistry, electricity and other sciences, its early uses are still much in evidence in our modern life.

Jan 1, 1928

By L. C. Brichta

During a study of the Badger-Peacock area from October 1950 to June 1953, the Federal Geological Survey and the Federal Bureau of Mines completed nearly 98 miles of resistivity profiling and drilled 96 test holes aggregating 17,628 feet of bore, In addition, seismic profile measurements were made along 8 traverse lines for an aggregate length of about 16,600 feet. The geophysical surveys were conducted by the Geophysics Branch of the Geological Survey; the drilling was done by the Bureau of Mines. Electrical-resistivity measurements disclosed 21 low-resistivity anomalies and 1 high-resistivity anomaly. Correlation of the resistivity data with the geological information revealed by the drilling disclosed that the low-resistivity anomalies indicated either slumped shale deposits in limestone sinks or undisturbed deposits of shale lying in erosional depressions in the limestone. The high-resistivity anomaly indicated hard, undisturbed limestone at or near the surface.

Jan 1, 1958

By J. H. Corrigan

A series of six papers describing the Falconbridge Dominicana Ferronickel project were presented at the International Laterite Symposium held as a joint project of TMS-AIME in February 1979 at New Orleans. A review of the ore mineralogy, as well as. the processing and environmental practices as they exist today at Falcondo with emphasis on modifications put into practice since 1979 are presented in two papers: Part I.- Mineralogy and Ore Dressing E.W. Lithgow - General Superintendent ? Mines Falconbridge Dominicana, C. por A. Bonao, Dominican Republic Commercial volumes of nickeliferous laterite ores overlie part of a 90 km long belt of peridotites in central Dominican Republic. Protores are serpentinized harzburgites and dunites, with lesser serpentinite. The ore mineralogy consists mostly of goethite, serpentine-group minerals, quartz and poorly crystallized, X- ray amorphous materials. Minor constituents are hematite, gibsite, olivine and enstatite. In the Ore Dressing plant, the mine feed is subjected initially to proper sizing and blending to produce a homogenized mix. Subsequent drying and upgrading, by selective crushing and screening of rock kagments through a Barmac circuit, complete preparation of the ore for pyrometallurgical processing. Part II.- Pyrometallurgy, Fuel and Power Generation J.H. Comgan - Manager ? Production Falconbridge Dominicana, C. por A. Bonao, Dominican Republic Falcondo's energy requirements are based on oil which is refined on site to provide distillate to carry out drying and selective reduction of the nickeliferous ore in the shaft furnaces, plus bunker oil to produce electrical power for process melting, refining and ancillary use. The dryer product at 1.68% Ni is briquetted and passed counter current to hot reducing gas in 12 vertical shaft furnaces. The hot calcine discharge is melted in two high power electric furnaces at very high secondary voltage. The crude ferronickel is ladle refined and cast as 15 kg ingots or 125 gm ferrocones.

Jan 1, 1993

By Terry A. Kirk

"This paper describes Derrick High Frequency Vibrating Screens and their process performance in grinding circuit applications. The benefits of screen sizing in closed circuit grinding are illustrated by case histories from a wide spectrum of mineral industries.INTRODUCTIONHigh capacity, reliable wet screening equipment is increasingly in demand by the mining and allied industries for separations finer than 1/.7 5mm (I/ mesh). The continuing search for improved energy efficiency and reduced steel consumption in comminution has Jed to greater scrutiny of every aspect of circuit design and operation, including the classifier efficiency (selectivity) function.Derrick Manufacturing Corporation has been developing high frequency screening machines designed specifically for grinding circuit applications since 1973. Successful installations are currently operating in iron ore, copper, coal, uranium, phosphate and other extractive industries."

Jan 1, 1984

By C. V. Corless

THE origin of various types and groups of ore deposits was some years ago a subject of much controversy. To this statement the copper-nickel deposits near Sudbury afforded no exception. Not since the Report of the Ontario Nickel Commission, in 1917, has there been any serious discussion of the origin of this very important group. This may be because, from the opening-up of Murray mine by the British America Nickel Corporation until the recent work at Frood mine, no new ore-body of importance has been developed in the district. The controversy fifteen or twenty years ago between those who favoured the theory of magmatic segregation, among whom Dr. A. P. Coleman was the leading exponent, and those who considered that most, if not all of the Sudbury deposits could more satisfactorily be accounted for by the theory of replacement, will be remembered by many members of the Institute. Perhaps, as too often happens in controversial discussion, each side tended to overemphasize the importance of those geological phenomena which seemed to be most easily accounted for by the theory it favoured. A more balanced view would perhaps admit that replacement was probably predominant in the formation of most of the offset deposits, and magmatic segregation in that of most of the marginal deposits . But there is danger in generalization. Each body of ore should be studied by itself, and no general conclusion of this kind should be allowed to warp the judgment in making such a study.

Jan 1, 1929

By Egonk Arriagada, Brindel Barzola, Peter Leckie, Greg Zwolak, Gilmar Guzmán, Germán Chen

Newmont’s Yanacocha operation in Peru presented an especially challenging environment for reliable cyanide measurement and control, processing 3 semi-distinct complex ore types with feed Cu ranging from below 250ppm (as CuCN) to more than 5000ppm, and feed S ranging from low to 5%, resulting in cyanide consumption from as low as 1.5 kg/t to as high as 3.1 kg/t, and gold recovery ranging from approximately 57% to about 78 % (average plant performance based on the type of ore). A literature search by the authors to identify a method for accurate cyanide determination that was also suitable for automation settled on the work of Breuer et al (2011) as a basis. Early challenges in adapting the laboratory technique for the ‘real solutions’ and the range of variability experienced in the plant are discussed, as are other operational challenges due to the complex and changing solution chemistry.

Sep 30, 2022