Search Documents

By R. Hagemeyer

In North America, the paper industry is by far the largest consumer of coating and filler mineral pigments. Present use is at an annual rate of 5.5 million metric tons with a value of $660 million. Current estimates are 65 percent is used in coating and 35 percent in filler applications. During the past decade, the switch to alkaline papermaking has provided the opportunity to substantially increase filler levels while maintaining paper strength. As a result filler consumption has been growing at a late in excess of 15 percent yearly. Unfortunately, within a few years, mandated recycling could slow or even reverse this trend. The critical issue is finding an economically viable method for recycling the mineral pigment and/or minimizing the disposal problem

Jan 1, 1994

By H. Huang, R. N. Gow

"Previously, Gibbs’ phase rule was applied to mass-balanced EH-pH diagrams for the Cu-As-S-H2O system. Diagrams were generated using the stoichiometry of enargite as a basis. In this study, the calculations were expanded to cover the stoichiometries of three other Cu-As-S minerals (tennantite, sinnerite, and lautite) and compared to enargite. Stability regions within the resulting EH-pH diagrams were found to change with stoichiometry such that a particular mineral would predominate if its stoichiometry was used in the calculation. Solution speciation was also found to vary, with thioarsenate being the best example. This stoichiometric effect helps to explain results reported in the literature and would be difficult to realize if it were not for mass-balanced calculations. INTRODUCTION A comprehensive thermodynamic review has recently been conducted on the aqueous copper-arsenic-sulfur system (Gow et al., 2014a-d). The free energies of over 100 species were collected from various authors and thermodynamic databases to produce mass-balanced EH-pH diagrams, using the thermodynamic equilibrium calculation software, STABCAL (Huang, 2014). The full database was listed and discussed by Gow et al. (2014A). Resulting diagrams were generated for enargite and confirmed with Raman spectroscopy using bulk mineral electrodes in order to identify reactions spectroelectrochemically. Theoretical calculations agreed well with the experimental results under alkaline conditions (Gow et al., 2014a), acid conditions (Gow et al., 2014b), and alkaline sulfide leaching conditions (Gow et al., 2014c). In this study, additional mass-balanced EH-pH diagrams are generated by changing the copper-arsenic-sulfur stoichiometry from enargite (Cu3AsS4) to tennantite (Cu12As4S13), sinnerite (Cu6As4S9) and lautite (CuAsS). Regions for the thermodynamically stable species are shown to change with the four different mineral compositions. Potential leach conditions, both for co-dissolution and selective dissolution techniques, were examined for differences in predominant species according to changing copper-to-arsenic ratios, sulfur compositions, and sulfur oxidation states."

Jan 1, 2015

By K. Thirumalai

The feasibility of breaking hard rock by thermal weakening and subsequent mechanical impacting was tested, Field tests at a basalt quarry in Dresser, Wis., demonstrated that large hard-rock blocks (5 by 5 by 5 ft) could be effectively reduced in size by this method. A series of secondary breakage tests, using air-propane heating, resulted in an average heating cost of $0.36 per ton. This combination energy approach provides an alternate means of size reduction of large hard-rock boulders for quarry and for underground are chute and grizzly operations where mechanical methods, used alone, are ineffective.

Jan 1, 1975

By C Armstrong, B Wentzinger

Upstream embankment raises often represent the lowest cost option for increasing the capacity of tailings storage facilities (TSF), but also pose the highest stability risk due to constructing on top of previously deposited tailings.This paper presents an overview of key aspects in the geotechnical investigation and design of upstream raises and some recent lessons learnt from experience across a number of TSFs in Australia. A summary of recommended field investigation and laboratory testing methods is provided with a focus on collecting quality information for design purposes. A strong focus is given in developing an accurate assessment of pore water pressures, which, if not correctly understood can have disastrous consequences on tailings strength parameter interpretation and wall stability assessment in static and post-seismic conditions.The assessment of the contractive or dilative shearing behaviour of the tailings material and rigorous interpretation of design characteristic values are presented. Some comments on stability analysis options and proposed methodology are also provided.CITATION:Wentzinger, B and Armstrong, C, 2018. Lessons learnt in geotechnical investigation and stability analysis for upstream tailings storage facility raise design, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 333–348 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By D. M. Hausen

Applications of process mineralogy to the exploitation of molybdenum ores begins with early exploration and continues through the evaluation of mineralized prospects, to amenability testwork and pilot plant studies, to the development of a mineable orebody and to the development of a viable process for recovery. After plant construction, a broad range of products from a wide selection of sampling locations, i.e. grinding circuit, flotation cells, smelters and roasting kilns. etc., are evaluated analytically and microscopically, followed by periodic troubleshooting of problem points. The various crystalline phases of molybdenum that occur naturally and throughout various hydrometallurgical and pyrometal1urgica1 processes are identified and characterized by a variety of instrumental methods, including XRD-XRF, optical and electron microscopy, infrared spectrographic and differential thermal analysis.

Jan 1, 1989

By Charlene Gokhale

Geopolymerisation has emerged during the last few years as an industrial and ecological approach to construction and waste management. By utilizing waste materials and their reactive properties, it is now possible to create geopolymers systems that not only mechanically durable enough to be used as construction materials but are also potential stable immobilisation systems for toxic waste. Previous studies by Van Jaarsveld et al. (1997) and Van Jaarsveld et al. (1998) have reported on the numerous applications of geopolymers in the immobilisation of toxic metals. Research into the possible utilisation of geopolymers as an encapsulation media for organic waste has however been rare. This paper therefore provides an insight into the possible utilisation of geopolymers as a binder for hazardous organic materials.

Jan 1, 2003

By Donald C. Violetta

During 1963 more than 200 million tons of coal was consumed by the public utility industry. Ash residual, from the burning of this coal has caused disposal problems. In order to prevent air pollution, dust collection systems have been installed to suppress the fine ash emitted from boilers before it is discharged into the atmosphere. The collected ash, called fly ash, must be removed from the dust collection facilities and disposed in some manner, usually at a substantial cost to the utility. Many years ago fly ash disposal was not a serious problem because the demand for power was relatively low and coarse coal was burned on stoker type traveling grate machines. The low burning rates utilized on these grates did not produce large quantities of air-borne coal ash while the mechanics of this system of burning resulted in a clinkered residue of cinders. Both of these conditions resulted in the production of only small quantities of fly ash. As the demand for electricity increased, a method of burning pulverized coal was developed and was introduced to the public utility industry in 1918 at Milwaukee, Wisconsin.1 This method of firing was considered a significant advance in steam electric generation as it (1) permitted the use of coals that could not be economically fired by other methods and (2) has generally resulted in improved efficiency, greater generating capacity and lower costs.2 The utilization of larger generating units using pulverized coal substantially increased the quantity of fly ash which resulted in a' more severe disposal problem.

Jan 1, 1966

By Thais Cristina da Costa Caldas, Carlos Mauricio Fontes Vieira, Alline Sardinha Cordeiro Morais, Sergio Neves Monteiro

"This work has as its objective to evaluate the effect of the incorporation of a glass powder waste obtained from discarded and Hg-cleaned fluorescent lamp into clayey ceramics used to fabricate bricks and roofing tiles. Formulations were prepared with incorporation of the waste in amounts up to 10 wt.% into the clayey body. Rectangular specimens were prepared by uniaxial mold-press at 20 MPa to fire at 850 and 1050°C. The physical and mechanical properties evaluated were: linear shrinkage, water absorption and flexural rupture strength. The microstructure of the fired ceramics was evaluated by optical microscopy. The results showed that the waste incorporation significantly improved the evaluated properties mainly at 1050°C.IntroductionFluorescent lamps use mercury as a main component for its operation. This metal is potentially toxic and can contaminate soils, animals and water bodies. The problem is aggravated if considerations are made with respect to the amount of lamps that are commercialized and discharged in emergent countries like Brazil [ 1].By using appropriate recycling processes applied to discharging fluorescent lamps it is possible to reuse most constituents of these lamps into new productive processes. A study has shown that one million common fluorescent lamps can generate 900,000 tubes of clean glass [2]. Moreover, this Hg-cleaned gloss may be recycled in different products.In fact, to recovery and recycle all materials that constitute the lamp instead of discharging them. This action protects the soil avoiding the formation of environmental passives [3]. It is also relevant to mention that the glass from fluorescent lamps is 100% recyclable while its permanence in the environment would correspond to very long time pollution, since its decomposition time is undetermined [4]."

Jan 1, 2011

By Julijan Bratun, Joze Kortnik

Production of technical stone is an important economic branch in Slovenia. In 2009, we had 95 dolomite quarries, 27 limestone and 6 silicates quarries, according to the Ministry of Economic Affairs. Together they produced nearly 15 million tons of aggregates. The production in quarries is mostly performed with drilling and blasting method and only a minor part with other method like mechanical mining method.

Jan 1, 2011

By E. T. Knight, John D. Gill

IN ITS capacity for service to the public the oil industry is truly gargantuan. But it is only in this respect that the industry is the voracious, many-headed, many-armed and many-handed creature it has been so often painted by those who know it not too intimately and only from the outside. Contrasted sharply with the immensity of the service rendered is the relatively modest share of the national income which has gone to those who provided the tools and the mental and manual labor with which the service was performed. No doubt the relative meagreness of the re- ward was the result of a combination of fortuitous circumstances respecting the nature and accessibility of the industry's raw material and the extensive development and application of the most advanced technology, spurred by an intense competition.

Jan 1, 1940

By R. J. McCarthy

In-pit Crushing and Conveying (IPCC) is increasingly being considered by mining companies as a means to reduce their dependence on trucks and thus, fuel, tires, labour, etc. There is potential for great savings in operating costs which ultimately can mean better economics for a mining project. Vale has considered the application of IPCC at its Moatize coal project in Mozambique. Up to three studies have been conducted with the latest, at a pre-feasibility level, showing some promise. This paper explores the mine planning and IPCC engineering elements required in an IPCC study, their application to the Moatize project, and the drivers which most impact the viability of IPCC at Moatize.

Aug 1, 2013

By N. A. Karl, D. R. Wilburn

"This summary of international mineral exploration activities for the year 2015 draws upon information from industry sources, published literature, SNL Metals & Mining (SNL) (Charlottesville, VA) database and specialists in the U.S. Geological Survey (USGS) National Minerals Information Center. The summary provides data on exploration budgets by region and mineral commodity, identifies significant mineral discoveries and areas of mineral exploration, discusses government programs affecting the mineral exploration industry, and presents analyses of exploration activities performed by the mineral industry.Three types of information are reported and analyzed in this annual review of international exploration: budgetary statistics expressed in U.S. dollars provided by SNL; regional and site-specific exploration activities that took place in 2015 as compiled by the USGS; and regional events that affected exploration activities including economic, social and political conditions, which were derived from published sources and discussions with USGS and industry specialists. Commodity and regional compilations are presented in this summary. Because multiple sources were used to develop commodity and regional compilations, statistics may vary depending on the source and type of data that are being reported.The SNL data summarize planned company budgets for worldwide exploration activities in 2015 for 24 nonfuel mineral commodities and metal alloys and are based on company surveys. Surveys focused on precious metals (gold, platinum-group metals and silver), base metals, (cobalt, copper, lead, molybdenum, nickel, tin and zinc), bulk commodities (bauxite, chromite, iron ore, manganese, phosphate and potash), and other commodities (diamond, graphite, heavy-mineral sands, lithium, niobium, rareearth elements (REE), tantalum, tungsten and uranium).USGS data compilations and analyses are based on information provided by USGS mineral commodity and country specialists, as well as industry contacts and published trade journals. The USGS data summarize exploration site data collected for more than 80 minerals and materials, with a focus on base metals, diamond and precious metals. The USGS analyzed available information to assess the level of exploration activity in 2015 and to report trends in mineral exploration activity for the period 2005 through 2015. These analyses identify where mineral exploration is occurring by commodity and region and the intensity of activity that is taking place in each region for selected mineral commodities, and determines those factors that most affect changes in exploration activity."

May 1, 2016

By A. A. Beland, R. J. Dawson, S. Shewchuk

"Shovel buckets, scraper blades, dipper teeth, mine car wheels and hammermills are examples of equipment which require routine maintenance due to abrasion. Service life can be extended by the use 0/hard/acing and buildup materials. Mining and milling applications are described and field welding procedures discussed.A high-stress abrasion test used to select hard/acing and buildup materials/or hammers in a hammermill is described in detail. Field tests of the selected alloys confirmed their performance, and maintenance records showed a significant saving in down time and cost.The relationship between the abrasion resistance of the alloys and their hardness, work hardening, composition and microstructure is summarized. IntroductionLarge volumes of ore are handled daily by the mining industry. The abrasive nature of most ores results in extensive wear to both handling and processing equipment. If such wear is neglected it may cause lost production time and also, in extreme cases, require the complete replacement of expensive equipment. The well-planned maintenance of components subject to abrasive wear by means of buildup materials and hard facing can result in substantial economic benefits. Such benefits can , however, only be realized through the correct choice of welding process, consumables and deposition methods available to maintenance personnel. Hardfacing MethodsHardfacing is applied by a variety of methods; the three most widely used being arc welding, oxyfuel gas and thermal spraying. Table 1 summarizes the major processes used within each method. Filler metals in the form of rod, wire or powder are necessary to fulfill the individual requirements of each process. The filler rods are available in the cast form or, in the case of ductile metals or alloys, as wrought rod or tube. All types are supplied bare or flux covered. Wire is supplied in two forms, drawn flux cored and drawn solid. Powder filler metals are available in many metals or alloys; they may be simple mechanical mixtures or prefused and atomized alloys made to a specific size range and shape for optimum results for each applicable process."

Jan 1, 1980

By Lin Li, Ahmad Ghahremaninezhad

"In this paper, the electrochemical behavior of ferric and ferrous couple on the pyrite surface was studied by application of the chronoamperometry technique in an acidic solution at room temperatures and atmospheric pressure. The effects of the pyrite origin, ferric and ferrous ions concentration on the electron transfer kinetics of Fe3+/Fe2+ reaction were probed. Tafel behavior of all the test conditions were developed. The results showed that the ferric-ferrous reaction on pyrite electrodes with different origins have a common mechanism, despite different reaction kinetics. The exchange current densities of the redox reaction have the same magnitude of about 10-5 A·cm-2, which is far lower than the value reported for the gold and platinum electrodes, but larger than that of the chalcopyrite electrode. The cathodic transfer coefficients are between 0.4 and 0.5, while the anodic transfer coefficients appear unusual with the lowest value being 0.23. It was also demonstrated that an increase of one order of magnitude of iron concentration has no clear effect on the exchange current density and cathodic transfer coefficients of Fe3+/Fe2+ redox reaction.INTRODUCTIONPyrite, FeS2, is mostly considered as a gangue mineral which frequently coexists with valuable minerals and metals, such as gold, copper and nickel. Its separation from valuable minerals can be a costly process (Chandra & Gerson, 2010). In refractory gold ores, the fine gold particles are locked inside the pyrite structure. Oxidative leaching of pyrite is a hydrometallurgical method to destroy the structure of pyrite and expose the fine gold particles to the cyanide solution in the downstream cyanidation circuit. Pyrite oxidative leaching can be achieved by oxidation of pyrite via oxygen and ferric ion(McKibben & Barnes, 1986). In fact, pyrite oxidation by oxygen and ferric is a significant source of acid mine drainage(AMD), which adversely causes serious environmental problems(V. P. Evangelou, 1995).The pyrite oxidation mechanism is accomplished in three consecutive steps: (i) pyrite is oxidized by oxygen and ferrous ion formation (Eq. 1); (ii) ferrous oxidation by oxygen and ferric ion formation (Eq. 2); (iii) pyrite oxidation by means of ferric ions (Eq. 3). Hence, both oxygen and ferric participate in the pyrite oxidation process (Moses & Herman, 1991):"

Jan 1, 2016

By A. Bezama

For over a decade European countries have addressed contaminated sites by developing technologies for managing both polluted soil and groundwater. This development has not only been driven by health and environmental aspects, but also because of economic pressures, as the remediation and redevelopment of derelict areas can be a meaningful alternative to undeveloped areas for the establishment of new industrial, recreational, housing and service locations. In most developing countries, however, the subject of contaminated sites is a new environmental issue that authorities have recently started to deal with. Among these countries, Chile has just started to prepare the country's legal context as well as to foster the formation of research and investigation groups that will deal with the exploration, investigation and management of contaminated sites. That requires a comprehensive technical, scientific and legal support in this stage. Goal of this article is to present the state-of-the-art technologies for site remediation currently applied in industrialized countries, in order to identify the most interesting approaches that can be implemented within the Chilean situation, especially considering the influence of the copper mining industry on the soil and groundwater quality of the environment surrounding their production facilities.

Jan 1, 2007

By Andreas Stieben, Pierre Lutomski, Wolfgang Bleck, Martin Fischer

"For steel investigation and development, exact knowledge about the microstructural state is required. The information gained from 2D images often can't properly reflect the real 3D microstructural properties. In order to gain reliable information for meaningful models, simulations and correlations, it is necessary to accompany standard metallography with 3D information, which, unfortunately, is very difficult to access. This article presents a procedure for serial sectioning in combination with light optical microscopy. Only standard metallographic tools are employed in combination with image manipulation freeware. 3D microstructural data were extracted from three multiphase steel grades and in two cases virtual 3D-models of microstructural phases were generated.Three Dimensions Of MicrostructuresSince the invention of steel, craftsmen, inventers and engineers tried to improve its properties and tailor them to the requirements of new developments. For systematic development and enhancement of steels, the capability to investigate its inner structure is highly important, because it represents the linchpin between material production and properties. By having an in-depth understanding how production conditions form the microstructure and also how the microstructural state determines the material properties, steel design can be drastically improved. With this knowledge, microstructures can be designed to provide target material properties and process conditions can be identified that form these structures. Due to the key role of microstructure, the capability to gain accurate information about it is indispensable. It is the task of metallography to access and extract descriptive quantitative microstructural data like fractions, sizes, shapes and distributions of the different constituents. The most commonly used investigation tool in metallography is the light optical microscope (LOM). Besides this tool, additional high resolution techniques like Scanning Electron Microscopy (SEM) or Transmission Electron Microscopy (TEM) have become increasingly important. With these and other available methods, extensive information on the microstructural state of a material can be gained. Unfortunately, most metallographic methods have a major loss of information systematically built in. Analyses of microstructures are usually performed on surfaces, i.e. on 2D areas that emerge by cutting through the 3D material structure. This means, a complete dimension of information is not taken into account. How serious this reduction of information is and how it can affect interpretation of structures is exemplarily demonstrated in figure 1, which displays the planar structure emerging from a random cut through a simple 3D structure. It is very difficult to deduce or even imagine the original spatial structure from which this projection emerged and it is impossible to reconstruct it with absolute certainty without further information. The image has emerged from a random cut through a 3D structure of stacked cubes that is displayed in figure 2. The area shown in figure I is outlined. Although artificially constructed, this example demonstrates how distorted and misleading the view on structures can become by ignoring a spatial dimension."

Jan 1, 2012

By Lon Santis, Michael Swisdak, David Leidel, John Tatom

The Institute of Makers of Explosives (IME) and A-P-T Research, Inc (APT) have developed and released a quantitative risk management tool, IMESAFR (IME Safety Analysis For Risk), for the commercial explosives industry. Consequence algorithms in IMESAFR are considered state-of-the-art. Generally, they mirror those in SAFER (US Department of Defense Explosives Safety Board quantitative risk management software). The science behind the software has now been assessed for its maturity. Results have identified areas where additional test consequence data could improve predictions. To address these areas, full-scale testing programs to provide the needed data have been formulated. Proposed testing efforts include work to: (1) improve characterization of explosive articles now absent from SAFER, and (2) refine modeling of the Potential Explosion Site (PES) types, particularly small metal structures, also not found in SAFER. Goals of each program as well as requirements for conducting the tests have been established. Testing results are to be used to improve the algorithms and to further the state-of-the-art in risk-based explosives safety.

Jan 1, 2012

By V. Loya

Metallic foams (MF) are relatively new materials with a combination of attractive properties (permeability, high surface area, thermal and chemical stability, etc,), They can be produced from different materials and can be manufactured using various processes, Due to their unique properties, they find applications in different sectors of engineering, such as energy absorption, filtration, heat dissipation, etc, For many applications, the permeability is an important parameter to characterize and optimize, Most of the recent literature on the subject studied the permeability in the low velocity range. The present study was carried out to have a better understanding of permeability for greater velocity ranges, An equipment was designed and built for this purpose, Pressure drop measurements were made across the thickness of open-cell nickel foams, Pore and window sizes were measured by image analysis on SEM micrographs, The experimental results are in relatively good agreement with the Hazen-Dupuit-Darcy model (R2>98%), The permeability is affected by pore size, porosity and the normalized projected area of the connecting pores (ie. windows).

Jan 1, 2005

By J. G. Kirby, F. S. LOTT

The mmber of petroleum refineries in the United States decreased during 1949 from 375 to 367 while the total crude-oil charging capacity of refineries continued to increase. A gain in the through-put capacity of 257,305 barrels daily raised the total to a new high level 6,696,300 as of January 1, 1950. The capacity of the average refinery to process crude-oil increased during 1949 from 17,171 barrels daily to 18,246. The four coastal refinery districts accounted for 178,900 barrels or 70 percent of the total capacity increase and the Illinois-Indiana- Kentucky district 57,950 barrels, or 23 percent. Slight declines in capacity were reported in the Texas Inland and the Arkansas-Louisiana Inland districts. The capacity building on January 1, 1950, 145,600 barrels daily, was less than half the amount under construction a year earlier. Most of the new construction involved enlargement of existing refineries and was confined to the East Coast and Indiana-Illinois-Kentucky districts. Two new refineries, however, were under construction, one in Oklahoma and the other in Texas. The shut-down capacity increased for the first time since 1946, and the 473,302 barrels daily reported on January 1, 1950, was the largest recorded since January 1, 1938. The only refining district showing a decline in the shut-down capacity was the Appalachian No. 2 district. The largest increases were reported in the Texas Gulf, Indiana-Illinois- Kentucky, California, and East Coast districts. The operating ratio of the petroleum refining industry, as indicated by dividing the January 1950 runs to stills of 5,483,000 barrels daily by the total installed capacity January 1, 1950, was 81.9 percent, compared with a ratio of 87.8 percent at the beginning of 1949.

Aug 1, 1950

By E. -U. Reuther

To improve the climatic environment underground the German coal mining industry has installed refrigerators with a capacity of 300 MW cooling power. One third of this total is accounted for by central refrigeration plants with more than 5 MW capacity. The central refrigeration comprises three stages: mechanical cooling, transport and distribution of chilled water via pipelines and exchange of heat in the air coolers. Of these three stages only the mechanical generation of chilled water has been resolved satisfactorily. Transport (including distribution) and exchange require further technical research. The Mining Institute of the Aachen University of Technology has done extensive studies on this subject, concentrating on controlling the flow of chilled water according to demand in the mine. Additionally, the favourable exchange in the air coolers is taken into account. The studies are based on a model mine which simulates the conditions in deep coal mines in Germany. The simulation program represents firstly the condition of the mine air at the location of the air being cooled, then the heat exchange in the air cooler itself, and finally the transport of the chilled water from the central refrigerator to the consumer. The program also reproduces the seasonal and operational changes in conditions of mine air as well as different air cooler designs. A regulated distribution of chilled water is also suggested. Finally, estimations of costs can be made as an aid for further planning.

Jan 1, 1987