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By Zhuo Sheng

We have designed a high-temperature Raman micro-furnace and cell that is suited for the electrochemical process study of the NO3 − in molten NaNO3– KNO3 (fraction of NaNO3 50 wt%) salt. During the cycle voltammetry and constant potential electrolysis process, the Raman laser beam was focused near the electrode; subsequently, the Raman spectra are obtained and the reduction process of NO3 − is analyzed. In the CV cathodic scan process, the new peak attributed to the ν1 mode of NO2 − emerges, and the peaks assigned to superoxide ions (O2 −) and peroxide ions (O2 2−) are not found. In the constant electrolysis process, the peaks at 1130 and 800 cm−1 appear when the potentials are between −2.0 V and −3.2 V (vs. Pt). The results show that when the NO3 − is reduced in molten the NaNO3–KNO3 mixtures, the reduction product O2− cannot stably exist, and O2− will react with NO3 − to form of superoxide ions (O2 −) and peroxide ions (O2 2−).

By Douglas R. Piteau

"Assessing the stability of a slope cut in rock is basically a problem of engineering geology - geology, because it involves a sound understanding of the important aspects of geology, such as geological structure, ground water, weathering and other natural phenomena, which all relate to or exist in a geological environment, and engineering, in that quantitative evaluations and calculations are necessary, these being based on mechanics and relating to the strength of the geological materials and the forces causing instability of the slopes. The engineering geologist must make every attempt to. provide, in a quantitative way, information on those geological factors which are necessary for making calculations of the probable stability of the slope. These include numerical assessments of quantities relating to the characteristics of structural discontinuities, rock types, topography, hydrogeology, tectonic history and other environmental factors. Based on the development and extension of these general principles, both preliminary and final slope stability studies of some open pits in South Africa, Swaziland and Zambia have been conducted. Some of the basic concepts and techniques developed to carry these studies out are described."

Jan 1, 1972

By Diana K. Schimmelpfennig

Assessment of revegetation success on mined lands is a difficult, time consuming task and has been the subject of a number of controversies. Present regulations require that both plant cover and aboveground plant biomass be measured for use in making that assessment. Of these two variables, biomass is the most time consuming to measure and requires destructive sampling, a most undesirable requirement on fragile, recently revegetated areas. On the other hand, plant cover can be estimated using the point-frame method which is relatively nondestructive. In addition, vegetation can be sampled more uniformly with the point frame and in less time if species composition measures are to be made. A study was done to evaluate the predictability of aboveground biomass production on revegetated mined sites and adjacent native prairies using plant cover estimates made with the point frame method. The predictability of biomass production by cover estimates bears on the need for both measurements in assessing revegetation success. In general, a positive, statistically, significant correlation was demonstrated between plant cover (estimated by the point frame) and aboveground biomass (estimated by the harvest method) regardless of community type (mined or native), species composition, diversity or level of biomass production. However, the latter did have their effects on the relationship and must be accounted for in any predictive equations (that is to say, the predictive equations must be considered site-specific). Considering the relationship observed between the two parameters, cover estimation may be a sufficient indicator of revegetation success, especially where time and minimization of disturbance are critical.

Jan 1, 1982

By W. K. Hitchcock

Hydrogen is regarded as being a high temperature indicator of spontaneous combustion. It is currently used in underground coal mines to detect advanced heating?s. Previous work has mostly consisted of small scale tests with high air flow to mass ratios. A large-scale test rig has been used to investigate the gas indicators of coal self-heating. In particular, the relationship of gas evolution, the location of its evolution and the temperature at which it is evolved has been examined. It has been found that there are two distinct zones of hydrogen production: one at the hot spot and the other in an oxygen deficient moist zone downstream from the hot spot which is at a relatively low temperature of approximately 100°C. This has implications for the interpretation of mine atmospheres.

Jan 1, 2009

By C. Perez-Rosales

A simplified method for evaluating specific surface of porous media is described. The theory takes as its point of departure a previous statistical method. Due to its simplicity, it is considered that the proposed method has certain advantages over methods currently used. By making some simplifications, the procedure for estimating specific surface is reduced to superposing, on an enlarged reproduction of a section of the sample to be analyzed, an evenly spaced grid and counting the number of intersections of the grid lines with the perimeter of pores. An indirect test of the theory is presented and the advantages of the method are discussed. INTRODUCTION The specific surface of a porous medium, defined as the surface area of the pores per unit bulk volume, is an important parameter with regard to flow of fluids through porous materials. In particular, it has long been recognized that specific surface is closely related to permeability. Since the internal surface of any porous material is extremely complex, the measurement of specific surface can only be accomplished by indirect means. It is considered that the best method' in current use for determining specific surface is the statistical method of Chalkley, Cornfield and Parka who originally applied it for estimating volume-surface ratios of morphologic components, such as cells or nuclei. This method will be outlined later. A method which has been used extensively in determining specific surface is based on the adsorption of a vapor by the internal surface of porous media. However, this method does not yield the surface pertinent to fluid flow, since it includes the tiny molecular interstices which do not influence the permeability of the porous material.' This method has been employed by Brooks and Purcell measure internal surface area of sedimentary rocks. The Kozeny equation, which relates the specific surface to the permeability of a porous medium, has found wide use in determination of specific surface. However, the KOzeny equation is not strictly correct. Large discrepancies have been found between theory and experiments.' Consequently. the specific surface estimated by this method is subject to serious uncertainties. Finally, there are other methods for specific surface measurements which are based upon a variety of physical and chemical properties: the heat conduction by a gas, ionic adsorption phenomena and direct chemical reactions of the surface with other substances. This paper describes a simplified statistical method for determining specific surface of porous materials. It is considered that, due to its simplicity, it has certain advantages over the methods presently used. For its validity, it is required that the porous structure of the material under study be of a spatially random nature. This is not a serious limitation since the naturally occurring porous media have this characteristic. THEORY The method proposed in this paper takes as its point of departure the interesting result obtained by Chalkley et al The method shows that if a line of length r is dropped repeatedly at random over a section of a porous medium, and counts are made of the number of times the two end points fall within pore areas (denoted by h for "hits") and the number of times the line intersects the perimeter of pores (denoted by c for "cuts"), then in a very large number of throws where S is the internal surface of the sample (surface of pores) and V, the volume of the pores (Fig. 1). Since the specific surface S, and the porosity 4 are given, respectively, by S. = Sl V, and 4 = V,l V,, where V, is the total volume of the sample, it follows from Eq. 1

By F. S. LOTT

The number of petroleum refineries in the United States decreased from 399 on January 1, 1947, to 390 on January 1, 1948. On the latter date two additional refineries were under construction , a large one in New Jersey and a small one in Texas . This Crude oil charging capacity, based on complete facilities only , increased in 1947 from 5,569,482 barrels to 6,034,252 barrels per day , owing to material gains reported in all of the larger refining districts . great increase in effective capacity is only in part the result of the completion of major new units for crude-oil processing . Much of it is due to rearrangement and minor additions to existing facilities to permit more efficient and complete utilization . Recent experience has apparently demonstrated that many processing units are capable , with greater emphasis upon maintenance and precise controls , of sustained operations at higher volumes than were indicated in their old rated capacities . This situation doubtless has caused some upward revision in capacity data .

Aug 1, 1948

By Arthur S. Huey

AS the end of the collegiate year approaches, the problem of student employment again becomes acute. This subject divides itself into two phases: (1) employment prior to graduation and (2) employment following graduation. "Experience is the best teacher," according to the old adage, and the student needs all that he can get. He is afforded every opportunity to reap from his books the theories and principles of scientific and engineering practice, and occasionally he is privileged to make field trips to observe the practical side of the subject. But it is not enough for one to know the theory and to observe its application; it is also desirable for the student to get the feel of the tools during his training Such opportunities can only be afforded the student if the major companies cooperate with the universities in giving the student part-time and vacation work.

Jan 1, 1932

By I. R. Kramer

In his technical note entitled "Specimen Temperature During Electropolishing of Aluminum Crystals" Dr. Nakada 1 reported that the temperature of his aluminum specimen increased 65°C when it was polished electrolytically; he therefore concluded that the temperature of the specimens used in our work (Nakada's Refs. 4 and 5) similarly increased by this amount. From this he further concluded that the change in plastic-flow characteristics associated with the removal of the surface by electropolishing during deformation were due solely to a temperature effect. We believe that these conclusions are not justified. It is, of course, realized that the amount of the temperature increase is associated with the total heat transfer of the entire system, including the efficiency of the stirring action, heat flow through the grip on the specimen, and so forth. Of great importance is the type of electrolyte used for polishing. For example, in Dr. Nakada's experiment a methanol-perchloric acid solution was used. This solution has a relatively low conductivity and for the current densities of 0.3 amp per sq cm the electrical input appears to be 30 to 40 w. In our research a methanol-nitric acid solution was employed and for the size of specimen employed by Dr. Nakada the power never exceeded 7 w. There are major differences in his test apparatus which also appear to affect the temperature rise. In our case a steel specimen holder was used in order to provide a good heat sink and conduction path. The cathode was a coiled aluminum tube through which a coolant was passed to provide additional cooling capacity near the specimen. The stirrer was placed in a position to obtain maximum cooling efficiency. On the other hand Dr. Nakada used a teflon grip to support the specimen at one end only and a flat copper cathode, thus providing a much less efficient heat sink as compared with the metal grips used in our studies. The relationship between current density and the temperature increase for two sizes of aluminum crystals tested in our tensile apparatus is shown in Fig. 1. The temperature measurements were determined from a thermocouple spot-welded to the surface of the specimen. The thermocouple was protected from the acid by means of a thin film of stop-off lacquer which covered just the outer surface of the thermocouple junction. Whereas Dr. Nakada reported a time delay of 8 min to obtain thermal equilibrium, our temperature change occurred in less than 15 sec. This emphasizes the importance of the heat transfer in the entire system. However, readings were taken over a period in excess of 5 min to assure thermal equilibrium. The data given in Fig. 1 were also confirmed by determining the thermal expansion of the specimen in a sensitive creep apparatus. As may be seen, for the smaller specimen the increase in temperature is 8°C for a current density of 1.5 amp per sq in. The majority of our data on the effects of surface removal on the plastic behavior of aluminum were obtained at current-density values at or below this value. Above 1.5 amp per sq in. the temperature rise is uncertain; for under certain conditions, especially in the vicinity of 2 amp per sq in., the anode can become polarized and the current flow is erratic. This condition is easily recognized because wide fluctuations in the creep and stress-strain data make it virtually impossible to obtain reliable results, a condition which was always avoided in our work. The temperature increase for the larger specimen is less than that of the smaller specimens below a current density of 1.5 amp per sq in. At a current density of 2 amp per sq in. the temperature increased 13°C. The above temperature data are in accord with observations made during creep experiments. Using a transducer capable of detecting strain in the order of 10 -6, temperature changes in excess of 8°C were not detected when the current density was increased to as high a value as 1.5 amp per sq in. Finally we wish to point out that our experimental data cannot be explained solely in terms of a heat effect. For example in Fig. 1 of Ref. 2, the change in slope of Stage II as a function of the rate of re-

Jan 1, 1965

By M. Fener, S. Kahraman, O. Gunaydin, M. Alber

Falling into the weak rocks category, fault breccias have extremely poor engineering properties. These pebbles typically cause issues with slopes, subterranean construction, and building projects. Professionals will benefit from the creation of some predictive models for fault breccia triaxial strength, as smooth specimen preparation is typically challenging and timeconsuming. The purpose of this study is to develop some predictive models for the differential stress (Δσ) based on physical and textural properties. Artificial neural networks were used to analyse data related to Misis fault breccia. Initially, models with moderate (noticeable, but not good) correlation coefficients were created using multiple regression analysis. After that, the regression models and three distinct artificial neuron network models were contrasted. Regression models are weaker and less trustworthy than artificial neuron network models, as demonstrated by this comparison. Pointed out is the practicality and ease of use of the artificial neuron network model with S-wave velocity and volumetric block proportion. Ultimately, it can be concluded that artificial neuron networks analysis provides a reliable indirect method for predicting the differential stress of Misis fault breccia.

Sep 1, 2025

By C. Adcock, R. Farnfield, G. Adderley

The use of explosives to create special effects in the film industry is a well-known past time. A recent production required simulation of a large scale water splash from the effect of a statue falling from a cliff edge and impacting on an open body of water. This was to be achieved through the use of precisely delayed explosions detonated near the surface of the water. A survey of the area revealed a breeding farm for sea bass approximately 250 metres (273 yards) from the intended blast area. It was initially thought that the water pressures produced for the detonation of the explosives may cause harm to the fish. Much work has been carried out over the past few decades on the effect of open water blasting and its effects on aquatic wildlife; this includes water pressure modelling techniques which can be used as predictive tools.

Jan 1, 2010

By F. Calizaya, S. Bhattacharyya

"INTRODUCTION Mechanized underground mines often suffer from noise overexposure. Noise levels are usually above the Permissible Exposure Limit (PEL) where underground fans are used. Sound levels in active workings can reach 121 dB(A), especially when fans are not equipped with silencers. Use of silencers seldom ensure PEL for various reasons. Overexposure of noise induces permanent hearing loss among mine workers. Recent field studies by a NIOSH-funded research project at six coal and non-coal mines revalidated the findings. The University of Utah has undertaken laboratory studies to reduce fan noise at the source. A new silencer prototype with varying noise dampening material has been designed and tested. The silencer and an associated extension which can be repacked with different dampening materials were used in various configurations. Attempts were made to simulate field conditions where installations are quick and not perfect. The test results are presented here. NOISE IN UNDERGROUND MINES Noise induced hearing loss (NIHL) is a chronic problem in the mining industry. In spite of regulations being in place and elaborate hearing protection programs under way, hearing loss is prevalent among the mine workers (Bise, 2001). All production and support machinery in mining generate loud noise often beyond the approved exposure level. Researchers in the U.S. have identified auxiliary fans as one of the major sources of noise that can create noise exposure levels up to 121 dB(A), which is one of the highest in the mining operation (Bauer, 2006). Studies have demonstrated substantial reduction of noise level by using silencers. Adequate fan selection and proper utilization of silencers in auxiliary fans have great potential of abating the problem. In hard rock mines, auxiliary fans are used in blower configuration to ventilate development headings and large production stopes, and also to ventilate underground shops, crushers, conveyor transfer points, etc. Typical duct diameters in hard rock mines vary from 0.91 m to 1.21 m. Silencers are often omitted for cost reduction. In coal mines auxiliary fans are used in exhaust configuration with rigid ducts 0.61- 0.76 m in diameter (Hagood, 1982 and Moreby, 2009) to ventilate working faces in gate-roads and main entry developments. Sometimes, stone dusters are added at the discharge end to dust the roof, ribs and floor. AUXILIARY FANS AND SILENCERS Auxiliary fans are relatively smaller in size than the main fans and often have high rotational speeds (1800 -3000 rpm). Fans are selected based on pressure-quantity requirements and space restrictions only. Noise emissions are rarely considered during the selection stage. Installation of fans, ducts and other accessories is mainly based on best practices, which often do not include noise control. As a result, the operation of an auxiliary or local ventilation system normally produces excessive noise."

Jan 1, 2018

By Margaret R. Egan

A study of the combustion emission products of rigid ventilation ducting was completed by the U.S. Bureau of Mines. The ducting was composed of fiberglass-reinforced polyester resin. Four properties of the ducting were evaluated: (1) propensity to ignite, (2) smoke characteristics, (3) gas emissions, and (4) heat release. Particle sizes, obscuration, optical densities, and production constants for gas and smoke were also calculated. These results provide comprehensive data about the emission products, detectability, and relative hazards of fiberglass-reinforced plastic ducting and other mine combustibles under realistic fire conditions.

Jan 1, 1990

By A. Lee Barrett

AN accelerated trend toward mechanical mining was noted in 1940, calling for improvements in and better performance of transportation, hoisting, and ventilating equipment. One of the most interesting experi¬ments in transportation is the track shuttle-car operation first put into use by the Princeton Mining Co. in Indiana and later at the Montour 4 mine of the Pittsburgh Coal Co. This system is based on the use of 10-ton drop-bottom mine cars operating on track and han¬dled by an ordinary gathering loco¬motive. These mine cars are loaded and taken in trips of two to a central dumping station which serves four or less loading machines. The dumping station consists of two standard chain-and-flight room conveyors, approximately 50 ft. long placed side by side approximately 4 ft. below the track from which the drop-bottom cars are dumped. These conveyors are operated at low speed and discharge into two similar elevating conveyors which operate at a higher speed and convey the coal to a trip of standard mine cars. A dumping station is usually located so that approximately 500,000 tons of coal may be handled through it before a move is required. This plan appears to have considerable possibilities for the mine equipped with small mine cars and standard locomotives since the advantages of large mine cars can be secured at a fraction of the cost required to install such cars throughout the mine. It appears logical that the future will see a much wider use of this modification in transportation.

Jan 1, 1941

By G. Lindkvist

Roasting of concentrates with high impurity levels is normally done in multiple- hearth furnaces where the concentrates are heated with oilfired burners in order to remove As, Sb and Bi before the final sulfide oxidation. Although it is a countercurrent heat exchange process it uses a lot of oil. In order to develop an energy saving, and from a working environmental point of view a less harmful process than the multiplehearth process, pilot-plant tests have been done in a two-stage fluidized bed for partial roasting. The test materials have been As-rich concentrates with 8-25 % As some 5b and Bi. The Cu-content was 0-28 %. The tests have been successful with <0.3 % As,in the calcine and with an elimination of 5b between 80 and 90 %. In order to achieve the proper conditions for good impurity removal, 1.e. right temperature,residence time and sulphur potential, the tests were performed in a special designed roaster. The roaster consists of two beds with the facilities for recirculation of calcine, preheating of the blast, and possibility to use oxygen enrichment. The construction makes it easy to control the reactions that generate the heat in the bed and reduce the amount of dust that passes through the cyclones. As two roasting steps are used, the possibility to obtain optimal conditions for impurity removal is improved and the calcine can either be smelted to a normal matte, or after being dead-roasted in the second stage, be leached in the normal way for gold extraction. The calcine was smelted with slag. The matte and the slag obtained had low quantities of impurities in the matte and a favourable distribution of impurities to the slag.

Jan 1, 1983

By TENNEY C. DeSOLLAR

TRADITION tells us that the earliest use of Alabama iron was to make shoes for the horses of General Andrew Jackson and his men during the first part of the nineteenth century. The first recorded incident in the making of iron was the request of U. S. Indian Agent Benjamin Hawkins "that a crew of blacksmiths be sent to the Creek Nation in the lower Mississippi territory." These frontiersmen made up the first body of pioneer iron makers in the territory. The first known blast furnace was built by Joseph Heslip in 1818 at Russellville, named after Major William Russell, who was General Jackson&apos;s chief of scouts. The Tannehill furnace was built in 1830 in what is now Tuscaloosa County and its ruins, as shown above, can be seen today.

Jan 1, 1937

By M. Melih Demirkan, Jared Deible, Michael Rosenmeier, Mazen Elias Adib, Juan J. Gutierrez, Raghav Ramanathan

Dewatering and groundwater control is required frequently for construction projects and needs to be accounted for and dealt with care during design and construction to complete the project successfully. Dewatering can cause changes in porewater pressure, which changes the effective vertical stress in a soil mass. Dewatering can also cause changes in groundwater chemistry which in turn can cause changes in porewater pressure and also dissolution of soluble minerals in the soil and rock. The Guideline developed in this study addresses the engineering issues, approaches to lessen the potential risks associated with construction dewatering, and presents dewatering practices to support dewatering applications regulated by the Municipality of Abu Dhabi City (ADM) in the United Arab Emirates (UAE). The subsurface condition within the city presents significant geotechnical problems due to presence of shallow subsurface cavities and soluble minerals in the soil and rock. Therefore it is critical to develop standards for dewatering practices to provide information for local dewatering engineers and contractors with special emphasis to control and to eliminate the subsidence/collapse problems related to dewatering projects within the Abu Dhabi city. The ADM is also responsible for approval of permit applications for projects that involve dewatering. In order to minimize the risk related to subsidence/collapse problems due to dewatering, construction companies and dewatering contractors need to be informed about possible mitigative measures that can be employed to reduce risks. The guidelines were developed as part of this study based on detailed analysis of the local subsurface conditions. A set of rules and regulations are developed for geotechnical and hydrogeological investigations, dewatering design and monitoring criteria depending on the hazard zones, proximity of excavation to critical structures, excavation depth. The Guidelines include examples of permit application packages for three types of dewatering projects; one involving shallow dewatering, one involving intermediate depth dewatering, and one involving deep dewatering. These Guidelines are considered as living document and will be updated as required, as additional information is collected and additional local experience is gained.

Jan 1, 2016

By AIME AIME

DESTRUCTION of the plants, machines, utilities, tools, materials, and other essentials for peacetime living penalizes not only the owners of the materials destroyed, but the world as a whole. Specifically, the fundamental fallacy of any proposal for the in- discriminate destruction of the German industrial system is that it fails to differentiate between the wartime and the peacetime economy of the Reich. We are for one simple, clear objective-an effective industrial means to keep Germany from starting another war. This objective should not be con- fused, especially before the war is even won, with the appropriate punishment of Germany or with the international arrangements for the long future to be made around the peace table by the representatives of the Allied Nations after victory is achieved. This paper, therefore, does not deal with broad, complex postwar questions of diplomacy and international policy. "Unconditional surrender" implies disarmament of the German armies, the surrender of all arms, munitions, air- planes, and other ordnance material in stock piles or in process. It also should include the elimination of all German war production facilities, such as ordnance plants, munitions plants, and submarine works, and the control of raw materials required by war industries.

Jan 1, 1944

By S. J. Aresco

The Bureau of Mines has been active in promoting the purchase of coal for Government use under specifications that define the requirements in terms of heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analyses. To these, when required, are added the ash-softening temperature, the free-swelling index, and the Hardgrove grind-ability index. Under most of these specification contracts the bidders guarantee the quality of the coal, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled in accordance with instructions4 issued by the Bureau of Mines; the samples are analyzed in the Bureau laboratory to determine whether the coal is of the quality guaranteed by the contractor; if it is not, a price adjustment is made. Analyses of the delivered coal and tipple samples (samples collected at mine tipples as coal is being loaded into railroad cars or trucks) provide valuable data for use in evaluating future bids. In addition, the continuous sampling of coal as delivered is a check on the practical results obtained in burning the coal.

Jan 1, 1965

By O. Schnake, M. Isakson, C. A. Landolt

The paper presents the conceptual basis for the development of an Activity Based Costing system (ABC) for the analysis and estimation of process costs in mining and metallurgy. In particular, it discusses three major thrusts towards attaining increased efficiency in extraction and processing systems: (a) understanding the link between process and expenses, (b) identifying the chemical and physical factors that govern process costs and ( c) using process and cost models of the production systems. The authors have developed computer techniques to analyze data from conventional accounting and apply them to the development of process based ABC systems. The cost causing activities are linked to management units patterned after the organizational structure of the production system. All costs are associated with specific process functions such as charge preparation, smelting, refining, etc. The level of detail is determined by the quality of data available in conventional accounting systems. The system permits data analysis of historical cases and the projection of costs for new production schemes. Results can be presented in various levels of aggregation, following organizational and/or functional structures. The outputs of the system are tabular and graphical, typically following Pareto analysis concepts.

Jan 1, 2007

By Miao Tian

Large quantities of copper complex resources are produced globally and urgent to be cleanly processed. This article presents a thermodynamic analysis of mixed smelting process including low-grade polymetallic copper sulfide concentrates, high copper content sulfide concentrates, metallurgical by-products (copper removal slag from lead metallurgy), and copper powder from electronic waste. A top blown smelting reactor to simulate mixed smelting process is developed using a metallurgical process simulator, METSIM. Reactor parameters, heat loss and phase distributions are estimated from actual plant data. The proper proportion between complicated primary and secondary copper resources is determined by analyzing the influence of the feed rates of various resources, oxygen, silica flux and revert on the smelting performance. Autogenous smelting process is built by optimized matching materials of copper complex resources, in terms of the reactor temperature, copper content in matte and slag, and the percentage of magnetite in slag.