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By S. Chander

The effect of sample storage in argon and in air on kinetics of oxidation of pyrite from a coal source was studied using accelerated weathering test in laboratory columns. Prior to the weathering tests the samples were crushed, ground, and stored for various time periods in argon and air. The results showed a dramatic difference in the rate of oxidation of the aged samples. The differences were interpreted based on the hypothesis that the aging of pyrite led to the formation of surface coatings which changed with time. The significance of these results in pyrite/reagent interactions in flotation and in evaluating the acid mine drainage potential of pyritic waste materials is discussed.

Jan 1, 1993

By H. C. Harrell

The Tennessee Valley Authority began employing geophysical well logging for foundation investigations in October 1973. Since that time more than 3,000 holes have been evaluated for engineering purposes. The Tennessee Valley Authority has not actively used geo-physical well logging for exploration of construction materials, but we feel that much of the information derived from geophysical logs for foundation exploration is applicable to the construction materials industry. This paper will then discuss geophysical logging as applied to foundation engineering and, by implication, the feasibility of use in construction materials exploration. The use of geophysical logging and percussion drilling instead of coring has greatly expanded TVA's data acquisition capabilities and has also resulted in substantial savings in time and money. Economical boreholes are obtained through the use of large percussion track drills (Figure 1). This equipment is capable of drilling through the overburden, setting steel casing on the top of rock, and drilling the rock beneath the casing. Holes as deep as 400 feet (121.9 m) have been drilled by this method.

Jan 1, 1977

By John M. Devine

Hydrogen sulphide associated with natural gas was noted as early as at Point Albino, Canada. The presence of this impurity was recognized also in other of the earlier oil and gas fields, although the occurrence was by no means common. However, in recent years, with the development of the producing zones of test Texas and the Texas Panhandle, the Production of "sour" crude has increased greatly and hydrogen sulphide has proved a generally troublesome factor--frequently a major problem--in the drilling and operation of many wells in those areas. The problems arising from the drilling and producing of oil or gas wells in hydrogen-sulphide areas, fall under two general divisions: safety problems and corrosion problems. Mention is made of a third division which is closely related to the other two, that of treating--or the development of processes for the removal of hydrogen iron the standpoint of safety and health hazards, hydrogen sulphide in the petroleum industry has been discussed in a number of publications. Likewise, the problem of hydrogen-sulphide corrosion of production equipment has been given considerable attention in the literature.

Jan 1, 1931

By C. Roos

Tradicionalmente en la industria minera, el flujo principal del proceso funcional para la evaluación de recursos y reservas procede de geólogos que elaboran el modelo geológico, de allí a los geólogos que hacen la estimación de los recursos (los modeladores) quienes estiman los grados, y a los ingenieros de mina que desarrollan el diseño de la mina y su calendario. La interfaz entre estas tres disciplinas no está siempre exenta de baches. Las presunciones hechas durante una etapa del proceso no siempre son comunicadas a los demás, a pesar que la mayoría de las empresas mineras tienen procedimientos y protocolos establecidos para promover la comunicación a lo largo de las distintas disciplinas. Estos procedimientos no siempre logran su propósito debido a una variedad de razones que incluyen restricciones de tiempo, no tener disponible a las personas apropiadas, o a una falta de entendimiento de lo que las otras disciplinas requieren, y el proceso de traspaso puede degenerar en el envío de archivos a la siguiente disciplina en el flujo de proceso. Este artículo se ocupa de la interfaz entre la estimación del recurso y las disciplinas de la ingeniería de minas y el esquema de algunas de las presunciones comunes hechas al generar un modelo del recurso y los riesgos que los ingenieros podrían correr al elevar los grados de corte, optimizar calendarios o realizar predicciones. Los casos de estudio presentados se centran en depósitos de oro a cielo abierto, pero los conceptos deben ser aplicables a toda la industria. Aquí también proveemos un resumen de preguntas clave y recomendaciones.

Jan 1, 2014

By Reza Kamali, Mohsen Bashiri, Hadi Fanisalek

"Nomenclature: A: area (m2), C: heat capacity (WIK), cp: specific heat (J/Kg K), d: internal tube diameter (in), F: correction factor for multi-pass and crossflow heat exchanger, h: convective heat transfer coefficient (W/m2K), k: thermal conductivity (W/mK), L: length (m), m: mass flow rate (Kg/s), W: flow rate, N: number, Q: heat rate (W), R: thermal resistance, T: temperature (°C), U: overall heat transfer coefficient (W/m2K), ;1,,P: pressure drop (Pa), ;1,,T: temperature difference (°C), p: density (lb/ft3), N: number of tube passes, U,: velocity in tubes, iJh: head loss in feet of flowing fluid, Up: velocity in the pipe leading to and from the heat exchanger (ft/sec), µ: viscosity ( cp ), Llpf frictional pressure loss (psi/l 00 equivalent ft of pipe) Subscripts: b: baffle, c: cold, cf counter flow, ex: exchanger, f: fouling, h: hot, i: inlet-inner, ib: inlet baffle, lm: logarithmic mean, m: mean, o: outlet-outer, s: shell, t: tube, w: wall AbstractThe main bottleneck for primary aluminum production industry is dealing with a huge amount of input energy. The fact is that part of provided energy to aluminum production smelters will be lost as waste heat and it never used for aluminum production. One part of waste heat is escaping from the potroom exhaust gases, which was studied for possible recovery in a desalination plant to produce distilled water and the paper was presented in 2011 TMS Annual Meeting. However, it was shown that waste heat recovery plant to produce distilled water is highly profitable but the main fact is that the exhaust gases from potroom are highly corrosive, abrasive and dusty. The main challenge for desalination plant construction, which is using aluminum smelter exhaust gases as the main heat source, is the highly corrosive environment that makes the situation difficult and complicated for equipments design and plant construction. In this paper, we are trying to study a detailed investigation regarding the heat exchangers fouling, corrosion in heat exchangers including heat exchangers' material, how often we need to shut down the plant for maintenance or cleaning, and plant thermal efficiency with considering fouling."

Jan 1, 2012

By J. Hanna

Four Ca-bentonitic clays from Alabama were evaluated for use in Diammonium Phosphate (DAP) or Urea Ammonium Nitrate (UAN) fertilizer suspensions. The viscosity and gel strength of suspensions prepared with different proportions of a Western bentonite clay and sodium exchanged Alabama clays, were measured as a function of clay content and dispersant concentration. The results obtained suggested that three of the Alabama Ca-bentonites would replace about 40% of the more expensive Western bentonite in UAN and DAP fertilizer suspensions. The performance of the Na-modified clays, prepared according to the TVA soda ash method, was as good or even better than those observed for the Mg-, Na/Mg-or K-modified clays. The TVA clay modification procedure appears to be reliable and cost effective.

Jan 1, 1989

By V. Ramachandran

In view of the increasing environmental regulations that have been promulgated in the last 30 years, non-ferrous smelters and refineries have learnt to handle effectively the process waste streams that need to be bled from the system for impurities' control The cations of concern are copper, lead, zinc, cadmium, mercury, thallium, nickel, silver, sodium and potassium. Anionic species of arsenic and selenium also need to be addressed, Sulfates and chlorides-not a major concern at present-have come under scrutiny in the recent past. The current paper reviews several treatment options with reference to a) types of waste streams processed b )process chemistry c)discharge options and recovery of treated water and d) sludge disposal The long term goal of any smelter and/lor refinery should be to achieve zero liquid discharge from the plant. Methods to obtain zero discharge are discussed.

Jan 1, 2003

By Foster Fraas

The objective of this research was separation of one highly conductive mineral from a second conductive mineral , a procedure which is impractical in commercial electrostatic separators using metal rolls . Such separators permit separation of nonconductive from conductive minerals . A new technique involved use of carrier electrode rolls specially prepared by anodizing and / or oxidizing at high temperatures to form suitable oxide surfaces . Specific oxides included aluminum , copper , and nickel . The significant result provided by the new surfaces was the extension of the separation range to higher conductivities , an extension in relative mineral conductivity from 10-14 mhos . The results are in accordance with the blocking- layer theory .

Jan 1, 1964

By R. C. Moe

Pelletizing studies were conducted to find ways of improving the metallurgical properties of acid and fluxed pellets. In acid pellets, melting temperature was controlled by the formation of low melting temperature fayalite during reduction. Formation of a permeable metallic shell during reduction allows diffusion of reducing gas to the pellet core, decreasing fayalite formation. With fluxed pellets, slag chemistry had the main influence on metallurgical properties. Mineralogical, chemical and structural transformations that occur during reduction were studied at various intervals for a number of Mesabi Range pellet types. Six pellet types were selected for further investigation based on significant differences in softening/melting characteristics. Retention of porosity in the metallic shell was found to be the overriding factor in determining softening/melting behavior.

Jan 1, 1990

The mining industry has recognised for some time the importance of supporting programs which serve to educate the Australian public about the socio-economic benefits of mineral resource development. More recently, industry leaders have realised that the future development of the industry will depend on attracting sufficient young people to commit to a career in the industry. Apart from lending support to the traditional education institutions in Australia, the industry now has the opportunity to participate in the development of education programs in museums. Whilst historic, mining-related theme parks such as Sovereign Hill and Coal Creek in Victoria serve very effectively the objective of relating past mining activities to the socio-economic development of Australia, there still exists the need to provide a facility which, under the same roof, excites interest in geology, mining, mineral processing and the role of minerals and energy in modern society. The redeveloped Geological and Mining Museum (the "Mining Museum"), which is located in The Rocks area of Sydney, meets this objective. With the central themes of formation and transformation this new Museum, which aims to be the best of its type in the world, will use modern museum exhibit techniques and the resources of the Minerals and Energy Information Centre to educate the community including teachers and school children. In the best tradition of museums, outstanding mineral and other collections will complement a comprehensive range of interactive, high technology exhibits which will include a number of exploratory "hands on" facilities. Australian companies are joining with Government to fund this exciting new museum. There is still a need for industry professionals to realise that a modern "mining" museum is no longer just a repository for objects of mining heritage but is also an important centre which serves as an important educational and public relations interface. The Education Section of the new "Mining Museum", which is linked closely with the new Minerals and Energy Information Centre, will be working closely with appropriate mining-related Tertiary institutions to develop specific career programs aimed at secondary students who wish to pursue a career in the mineral resource industries.

Jan 1, 1989

By Sravya Kosaraju, Christian Ekberg, Stefan Allard

Li-ion batteries are now used in electric vehicles (EVs), plug-in hybrid vehicles (PHEVs) and, hybrid electric vehicles (HEVs). Nanostructured Li(NiyMnzCo1-y-z)O2 is one of the more popular cathode chemistries for automotive Li-ion battery, due to its enhanced properties such as large surface area, short diffusion length, enhanced ionic and electronic conductivity, improved mechanical strength and structural integrity [Pan et al, 2013]. Recycling of Li-ion batteries helps to mitigate environmental effects of virgin metal extractions along with improper disposal of end of life batteries. To fulfill these objectives of the recycling, recovery of pure streams of the involved metals should be considered. In this study, the batteries were first discharged and dismantled in an inert atmosphere (Ar). The electrodes were then heat treated in a box furnace. This was done in order to break the chains of the adhesive (PVDF) and consequently separate the metallic substrates Cu and Al from the electrochemically active compound. This heat-treatment also helped to simplify the dissolution of the metal constituents in the electrochemically active compound from the cathode in the acid leaching process. Solvent extraction was chosen to achieve separation and recovery of metals with higher purity from these leachates. In the scope of the present work, a complete process from the point of dismantling to separation of constituent metals using solvent extraction was studied.

Jan 1, 2014

By Ananda Moreira Vaz Ourique de Avila

High and intermediate temperature fuel cells (FC) are power generators characterized by high efficiency and their use in cogeneration systems. The single fuel cells are connected in series by the use of interconnects to form a fuel cell stack. Ferritic stainless steels have been used in the making of high and intermediate temperature operation solid oxide fuel cells interconnects. However, at high temperatures, on the order of 700-8500C, these steels can present significant oxidation and degradation processes, promoting increased electrical resistivity and corrosion losses that result in contamination of the electrodes and reducing the performance and the useful life of the FC. Intensive R&D activities have been made to minimize these problems and the use of composite coatings on metallic substrate has been considered. This paper evaluates the use of coatings of copper and nickel, with particles of La2O3, Y2O3, CeO2, LaCrO3 and doped chromites applied on ferritic stainless steels AISI 430, AISI 441 and Crofer22APU produced by electrodeposition. The produced samples were evaluated by microscopy techniques, gravimetric analysis and by electrothermal characterization. The most significant results were obtained with chromites coatings (LaCrO3 pure, mono- and multiple-doped) showing the combination of the best features of metal coatings, substrates and ceramic particles with semiconductor properties.

Aug 7, 2018

By K. Sarveswara Rao

The present paper firstly describes some recent trends from literature on energy management via process intensification to arrive at sustainable technologies for aqueous processing of minerals, metals and materials. Secondly, the energy saving measures practiced in leaching, solid-solution separation, solution purification, metal and material winning and environmental aspects have been discussed. The emerging importance of interdisciplinary nature of hydrometallurgy for practical applications is also highlighted. With the above background, the present paper describes an overview of energy conservation and autoclave processes with a special reference to hydrometallurgical research activities of our Laboratory.

Jan 1, 2008

By Douglas J. Lootens

Geologic mapping was undertaken in the Sierrita Mountains as part of a Doctoral program at the University of Arizona, Tucson. During the study, approximately 35 square miles was mapped in detail, with particular attention given to specific areas of great or significant structural complexity and their relation to mineralization in the vicinity. A combination, of field studies and photogeologic interpretation was used in order to define regional and local structural controls for disseminated copper-molybdenum mineralization in and adjacent to the study area. Gratitude is expressed to the faculty of the University of Arizona, Department of Geology for their assistance in this work and to Bear Creek Mining Company for making numerous reports and drill cores available for study.

Jan 1, 1965

By Fernando Romero Lage

The purpose of this paper is to analyze detailed crushing and screening configurations and the interrelationship as they relate to mass flow balance, operating efficiency, plant availability and final production. The entropy of ore bodies limits the standardization of crushing and screening plants, however, consideration for a continuous and sensible assessment of the mass flow balance of the circuit will yield the best achievable results. Since energy costs have continuously risen in the last few years, it is imperative that these circuits offer low power requirements and low operating expenses. The paper will detail how the efficient implementation of continuous mass flow balance in the application of crushing and screening plants will generate quality improvement and process improvement, which will translate into bigger production and energy savings.

May 1, 2010

By M. Rufli

Until not so long ago most ring geared mills were operated with fix speed motors only. By using the latest generation of medium voltage frequency converters, new possibilities have arisen to improve the grinding process. Beside all the direct and indirect advantages, several dedicated functions have now been implemented for ring geared grinding mills in the minerals industry. The sophisticated operational functions ensure a smooth, safe and reliable operation with minimum stress for the mechanical equipment and therefore utmost availability of the mill. Several papers have already been presented concerning the benefits of using this state of the art technology for mill drives. Now this paper is focusing on the experiences gained with this kind of sophisticated ring geared mill drive system rather than only show and explains the operational benefit of the different functions. Several measurements of different operating conditions, starting, frozen charge remover, controlled roll back, backlash, etc., made on an installed and commissioned 2 x 5 MW dual pinion ring geared mill drive system will be shown and discussed. The accuracy of the load sharing between the two 5 MW motors during starting, normal operation and stopping will be demonstrated using real measurements from an operating system. Finally the inherent features of these drive systems are briefly discussed.

Jan 1, 2011

By M. A. Barakat

"Adsorption of heavy metal ions specifically, Cu(II), Zn(II), Mn(II), and Cr(VI) from aqueous solution on synthetic 4A Zeolite was evaluated. The 4A zeolite was synthesized previously by dehydroxylation of low grade Kalabsha Kaolin at 800 °C, and reacted hydrothermally with 2-4 M NaOH solution at 100 °C for 2h. The adsorption capacity of the metal ions were found to be strongly dependent on pH and initial metal ion concentration. At the optimium conditions the adsorption capacity decreased in the order Cu(II) > Zn(II) > Mn(II) > Cr(VI) ions. Almost complete adsorption was achieved for both of Cu(II) and Zn(II) ions at pH > 6, while the adsorption capacity for both Mn(II) and Cr(VI) was 96, and 55.3 % at pH 11 and pH 3, respectively. The results also showed that the grain size of the 4A zeolite has a little effect on the adsorption capacity. The experimental data was compared with two adsorption isotherms, Langmuir and Freundlich isotheroms. The results showed a good agreement of the Langmuir plots with the experimental data.1. IntroductionSeveral industrial wastewater streams may contain heavy metals such as Cr, Cu, Pb, Zn, Co, Ni, Mn, etc. including the waste liquids generated by metal finishing or the mineral processing industries. Heavy metals are considered hazardous pollutants due to their toxicity, even at low concentration, and nonbiodegradability. Increasing level of heavy metals in natural water bodies poses a serious threat to all living species including humans. It is, therefore, essential to reduce the heavy metal concentration in effluents/wastewater before it is discharged into the water bodies [1]."

Jan 1, 2008

By A. J. Forney

Recent experiments used catalysts of plate assemblies in synthesizing high-Btu gas and gasoline indirectly from coal. A gas with a heating value of 925 to 943 Bt-: per cubic foot has been prod u la the hot-gas-recycle pilot plant from synthesis gas (3H2+100) with lathe turnings used as catalyst in the first reactor, and assemblies of parallel sprayed plats of nickel in the second. Solid plates made of Raney nickel, and steel and aluminum plates sprayed with Raney nickel or nickel oxide were tested. Those catalysts had very low resistance to gas flow; 90 percent lower than nickel granules used in previous experiments. In a single stage of synthesis thee nickel plates were only partially successful. Although the heating values of the product gas ranged from 856 to 941 Btu per cubic foot, the carbon monoxide content of he gas was above 0.1 percent. Both steel and wrought turnings were tested in single-stage synthesis, but the conversion of hydrogen and carbon monoxide was too low to attain the desired heating value of 900 Btu per cubic foot in the product gas. Assemblies of plates thermally sprayed with fusel iron were tried in an experiment to make gasoline. A gasoline yield of 52 percent (of the hydro¬carbons produced) was obtained using a 1H2-10O feed These sprayed assemblies were in service for 1,500 hours, the longest that this type of catalyst has been used. When a second reactor containing Raney nickel catalyst was added in series with the first reactor, complete utilization of the feed gas was obtained because in addition to the liquid product, a high-Btu gas with a heating value of 800 Btu per cubic foot was made.

Jan 1, 1965

By Alastair Grogan, Ron Elliott, Dale MacLean

Blasting for armour stone presents many unique challenges. Often, blasters get themselves into trouble when they assume that they can simply modify a production blast design to produce the required fragmentation size. They bid on the project using typical production blasting costs, and then find that they cannot produce the required fragmentation size and quantity with an acceptable waste factor. This paper outlines industry best practice guidelines for the production of riprap or armour stone. The paper examines the importance of initial geological mapping to determine the average in-situ block size, and the advantages to be gained from working with the geology to maximize production of the required block sizes. The paper also outlines the importance of proper explosives selection as well as blast designs that are unique to the production of riprap. The paper reviews challenges and experiences realized from multiple projects in differing rock types.

By G. S. Rice

The recommendations of the Bureau of Mines on rock dusting practices are embodied, except in a few details, in the Recommended American Practice for Rock-Dusting Coal Mines to Prevent Coal-Dust Explosions, approved by the American Engineering Standards Committee. December 30, 1925. It is specified that the dust to be used is of a elm that all will pass through a sieve having 20 meshes per linear inch and that 50 per cent or more will pass through a sieve having 200 meshes per linear inch. Thus the coarsest size of dust and the minimum proportion of fine dust are specified, but the specification does not indicate whether a larger proportion of fine dust would be desirable. There have been advocates of the use of that size of rock dust of which the particles would all approach 200-mesh in fineness. Explosion tests were made in the Experimental mine in the earlier period of testing which indicated that the finer rock dust is somewhat more effective under test conditions, but not sufficiently so to Justify the cost of finer grinding of the dust; also there are some disadvantages of finer dust described hereafter.

Jan 1, 1930