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By W. C. Peters, M. W. Pullen, C. A. Bays

During the past three and a half years considerable improvement in the techniques of solution extraction of salt has been made by the use of wells which are cross-connected by hydraulic fracture at the base of the salt. Fracture is initiated by the application of hydraulic pressure. Underreaming and perforating techniques are used to control initiation. The fracture is then extended by continuous pumping until a pressure communication is obtained. Pressure communication is followed by washing-through to obtain a low-pressure connection. Well construction using non-shrinking cements that will bond with the salt and with associated strata is essential to the process. The connecting procedure described permits solution to attack the salt deposit from its base upward, thereby permitting greater recovery, fewer well repairs, better saturation of brine, and overall economy of development and operation. The fracture method of cross-connection requires special pumping of the fluid and is limited by present experience to initial well spacings up to about 1200 feet. The method has been used in bedded salts and is applicable for wells in salt domes. Since spring of 1956, new developnents in salt extraction wells have followed procedures substantially different from those in prior use. Although multiple well systems, connected either by the natural consequence of the solution process or by undercutting under protective pads, have been used previously, the past three and a half years have brought about new designs and new operation procedures based on cross-connection of the wells using hydraulic fracture. To date these techniques have been applied largely in the bedded salt deposits of Michigan, Ontario, Ohio, West Virginia, and New York. To the writers' knowledge they have not been used in salt dome wells. The methods have not yet been in use for a sufficient period to permit any statistical comparison with the older methods. It is evident from experience to date that the methods result in higher recoveries, lower capital and operating costs, better saturation of produced brine, reduced well maintenance and repair, and in considerably fewer production units to insure

Jan 1, 1961

By N Cusworth

The development of a resource project inevitably requires the investigation of a vast range of issues across most engineering disciplines û mining, metallurgical, chemical, civil, electrical, mechanical and environmental û as well as the geosciences. It is also a characteristic feature of the resource industry that no two orebodies û and hence no two development projects û are the same. So these technical issues have to be addressed to a greater or lesser extent in evaluating any resource projectÆs development potential. Not surprisingly then, technical issues tend to predominate when assessing the development potential of a project in the process typically referred to as ædoing a feasibility studyÆ. But the principal purpose of a æfeasibility studyÆ is to determine whether a development opportunity makes good business sense, not just whether it is technically possible. Resolution of technical issues is often seen as the primary focus of a feasibility study, whereas in reality, these technical issues are the basis upon which an asset delivery and business plan is built. This is not to say that technical issues are unimportant û they are a prerequisite to the demonstration of a projectÆs viability. The feasibility study process must therefore demonstrate that not only have the technical issues been satisfactorily addressed, but also that the broader commercial, economic and social issues have been considered in the development of a comprehensive business plan, which includes an assessment of the risk-reward profile of the proposed development. This paper will present a framework for the conduct of æfeasibility studiesÆ and provide guidance to minimum standards and best practice.

Jan 1, 2007

By Frederick M. Becket

AFTER all the chronology that has been given, what is the present status of chromium steels? For the purpose of this discussion the different types of chromium steels can be divided into three classifications-those containing relatively low , percentages of chromium, say 5 per cent or less; the medium-chromium steels containing up to about 18 or 19 per cent chromium; and the steels containing still higher percentages of chromium, and some of the special alloys. Chromium has some unique effects in steel, so it is well to make a few generalizations. The affinity of chromium for carbon is great and the metal is unique in the manger in which it supplements and enhances the effects of carbon. Chromium retards -considerably the thermal transformations on cooling and exerts an opposing influence both on the absorption and precipitation of the carbides in steel. These statements make it easy to understand the fact that chromium .steels are capable of producing a hardened product at a much slower rate of cooling than is, true of plain carbon steel, and that chromium carbide or -the mixed carbides of iron and chromium do not contribute to brittleness to as great a degree as does iron carbide.

Jan 1, 1929

By John Tribe

"This paper gives the organizational history of Luscar Ltd. and its various coal producing operations. Each 0/ the operations is then described individually. They include the Bienfait Mine, the Boundary Dam Mine, the Diplomat Mine, the Luscar Mine and the Coal Valley Mine. The company's plans/or expansion are also discussed. IntroductionLuscar Ltd. is an Edmonton-based energy company formed in 1967 through an amalgamation of two pioneer coal companies-Mountain Park Collieries and Luscar Coals Ltd. In 1912, Mountain Park Collieries initiated the development of an underground mine in the Coal Branch area of Alberta. This mine necessitated the establishment of a townsite and the provision of rail access. The second operation, Luscar Coals Ltd., was established in 1921 at Luscar, Alberta. This was also an underground operation and required the development of a rail spur and townsite. The product from both mines was used to fuel railway steam locomotives until the 1950's. The market demand for coal decreased as the use of the diesel locomotive increased, so that these operations were finally closed in 1954. Through the amalgamation of the two companies in 1967, however, Luscar Ltd. was formed to become an active participant in the revival of coal operations. Western Canadian Luscar Ltd. is involved in the exploration, development, production and marketing of coal, coal products, oil and gas. Luscar Ltd. is currently participating in five producing mines (Fig. I). The Diplomat Mine, approximately 125 miles southeast of Edmonton, was in production when it was acquired in 1949 by Luscar Coals Ltd. In 1966, the Bienfait Mine and char plant were added. The Luscar Mine, which is a 50/50 joint venture of Luscar Ltd. and the Consolidation Coal Company of Canada, and is operated by Cardinal River Coals Limited, started production in 1969 on the original Luscar Coals Ltd. mine site. The Boundary Dam Mine was opened in 1974. Both the Bienfait and Boundary Dam operations are located in the lignite coal fields of southeastern Saskatchewan. The most recent addition to the group is the Coal Valley Mine, 40 miles southwest of Edson, Alberta. It commenced commercial production in July, 1978 under the operation of Luscar Stereo (1977) Limited."

Jan 1, 1980

By M. S. Riyazulla

The Hutti greenstone belt comprising predominantly of low-potassium tholeitic basalt has undergone regional metamorphism of a transition zone between greenchist to amphibolite facies. The important mineral constituents of the volcanic suite are amphibole and plagioclase which appear to be the product of regional metamorphism. These minerals have been recognized as the main indicators of metamorphic temperature and pressure. With a view to understand the P-T conditions of metamorphism of the belt, electron microprobe studies were carried out on amphibole and plagioclase and the chemical data was used to decipher the metamorphic conditions. The results obtained indicated a metamorphic temperature of about 6000 c and pressure of 5 kbs. for the Hutti greenstone belt.

Jan 1, 1996

By White A. H, Gillies A. D S

In recent years the Australian gold industry has gone through a major expansion phase. The need for finance has led to adoption of different approaches such as the well known gold loan, forward selling, equity participation by suppliers and equipment leasing. During early periods of the expansion, significant new equity was raised chiefly for high risk exploration ventures. The major form of new equity finance was ordinary shares, often in 'No Liability' companies. The increasing capital requirement of the huge new development projects of the 1980s also spurred the use of debt finance. This trend was accelerated as high inflation and the taxation advantages of debt finance made borrowing attractive. This paper reviews major financing techniques used by the Australian gold industry with particular emphasis on the innovative financing techniques initiated recently. An analysis has been undertaken of the effects on the industry of issues such gold loans, forward selling, equity participation by suppliers, fly-in fly-out operations, contractor mining and equipment leasing. In order to achieve a better understanding of the innovative financing techniques, a survey of already published financial data from well known Australian gold mines was carried out. Data was collected from various published financial reports of gold mining companies. In addition, a questionnaire survey was sent to gold mining companies to assist the collection of further information. The results of this study show that there are a significant number of gold mines variously using gold loans, forward sales, contractor mining and fly-in and fly-out arrangements to finance their projects. Only four operations have vendor suppliers investing capital funds in their projects. Based on the findings of this study, conclusions and recommendations are drawn that these approaches are likely to be with Australian gold industry for some time in the future and will continue to be intensively applied to finance gold projects.

Jan 1, 1994

By O. P. Hood

The spontaneous combustion of coal lies at the bottom of the subject of storage. It is useless to store coal that is to be lost by fire from spontaneous combustion. Every engineer is familiar with the phenomena of the self-heating of coal, yet, for all that, spontaneous combustion is relatively rare. If we counted the times a portion of cod was stored where it would be undisturbed for a few weeks, the number of such storage operations in any one year would mount into the millions. Of these, a relatively small number show the phenomena of spontaneous combustion and time risk per ton is very small. It is extremely rare that in the smaller operations involving; only a few tons there is any heating. There is no spontaneous combustion of anthracite, and very rarely does the domestic consumer of bituminous coal find troublesome heating. The main interest in the subject lies in the large piles needed as reserves for public-service utilities, and the industries. Everyone desires to have directions for storage that are perfectly simple and yet will insure against loss. Unfortunately, the problem is too complicated for a simple solution. Many of the factors involved are difficult to determine, as we have no practical means of quantitative measurement. The factors involve chemistry, physics, and engineering, and the man who is

Jan 1, 1939

By J. Kulczycka

The concept of sustainable development is be-coming present in the policies of increasing number of industries and governments. The complexity affects not only production aspects, but has also special relevance for environmental decision making. Not only producers are re-evaluating the services they expect from the environment and concomitantly increasing their willingness to sacrifice other consumption in favour of enhanced environmental services, but the character of environmental issues is becoming more complex as well. Incomplete information, uncertainty, system wide change, trans-frontier impacts, current causes that have far reaching future effects, irreversibility, and possibilities of catastrophic change all complicate the environmental decision making process. Non-ferrous metals production, due to a relatively low level of metals content in ore, results in generating huge amounts of tailings, exceeding usually 90% of the mine output. They must be stored in special facilities, which have the significant impact on the environment both during tailing management facilities (TMF) operation and after their closure. One of the most essential impacts of operating and closed TMFs is their eolic activity, displaying in worsening air quality, aero-sanitary conditions in the neigh-boring villages and contamination of soils close to the facility by heavy metals.

Jan 1, 2005

By Jury C. G

A decade of expansion and high production targets have led to changes in the number and structure of the Mount Isa Mines Limited work- force. Falls in labour turnover and absenteeism are correlated with two demographic variables, improved selection and placement procedures and home purchase facilities. Some results of recent population surveys are presented and discussed in terms of future housing needs and potential employment problems encountered by school leavers.

Jan 1, 1974

By Aaron Nickoli, Brad Clark, Thomas Horan E. I. T.

The Canal Road Dip Slide is an active landslide located on South Pender Island, British Columbia. The effects of the fall 2021 atmospheric river prompted the British Columbia Ministry of Transportation and Infrastructure to initiate an emergency response project to realign Canal Road out of the active landslide zone for safe traffic passage. The work was tendered in a bidding process and included blasting and rock excavation work at the project site. Tetra Tech Canada Inc. was retained by the contractor to be their Blast and Vibration Specialist. The close proximities of an active landslide, a Canadian National Park, and other segments of construction posed stringent constraints to blasting. The governing constraints to blast design included a Peak Particle Velocity (PPV) limit of 3 mm/s (0.12 in/s) along the adjacent landslide centerline and a slide movement constraint. Sixteen blasts were executed throughout the scope of work to remove 2595 m3 (3394 yd3) of meta-sedimentary rock. Blast designs adhered to the constraints by utilizing up to quadruple decking in 50+ blast holes which lead to complex timing schemes. Several blasts were over 4 seconds in duration, with one at nearly 8 seconds. The landslide area was monitored with Shape Accel Arrays (SAA) throughout the scope of work that tracked geohazard slide movement during construction. The SAA data is presented, and the effect of blasting is discussed. Site specific parameters for PPV estimation were calculated and are presented. Collaboration and communication between the stakeholders allowed the project team to successfully overcome the technical challenges posed by the Canal Road Dip Slide.

Jan 26, 2026

By Thomas J. Ferree

"There has been a major evolution of mineral processing technology in the past decade. The evolution has been driven by recognition of broad environmental changes which have impacted various areas of the world. Numerous government regulations have required many mining and mineral processing organizations to introduce changes to reduce the undesirable effects on the environment; many mining companies have voluntarily introduced new technologies and practices which surpass the limits imposed by the regulations. Surprisingly, some of the 'new' technologies are modifications of concepts developed decades earlier. Gravity separation technology is in this category.Mineral Deposits Limited, an Australian company, has been a world leader in the development of mining concepts, reclamation practices and equipment technology that is environmentally suited to today's requirements. This paper relates to equipment used for gravity concentration and electrostatic separation systems, including Reichert cones, spirals, and electrostatic separators. The basic devices and technologies were developed more than forty-five years ago, but use of the systems was quite limited until environmental and conservation practices were recognized and introduced. Spiral concentrators, for example, were patented in the mid-l940s by I.B. Humphreys in Denver , Colorado. The two types of spirals marketed (the Model 24A for minerals and the Model 24C for coal) remained essentially unchanged until expiration of the patents. During this early period most spirals were used in iron-ore wash plants on the Mesabi Range to recover fine iron which previously had been discarded. About the same time sand mining plants in Florida incorporated spirals to recover titanium minerals and zircon from lowgrade beach sands. The Labrador Trough opened new opportunities for spirals when hard-rock iron-ore deposits were developed; approximately 10 000 Model 24A Humphreys spirals were installed between 1958 and 1966. About 5000 spirals of this model are still operating in the same capacity, in spite of the fact that extensive improvements have since been made in gravity separation technology."

Jan 1, 1993

By Nixon C. A

The exploration of Mount Isa Mines' new copper source will require the development of a five kilometre 4.7 x 5.5 metre blind decline commencing 1000m below the surface and extending to 1600m below the surface. With virgin rock temperatures approaching 60¦C, the ventilation strategy represents a complete departure from any previously used at this mine, in that refrigeration becomes essential. The use of direct water to air cooling techniques has become commonplace in mines throughout the world and their application is being adopted at Mount Isa Mines. A heat load simulation routine has been implemented to allow for the design of refrigeration requirements, as well as to aid in the selection of diesel or electric equipment. This enabled planners to determine the size of a surface based refrigeration plant. Future refrigeration demand for expansion into the ore production stage has also been investigated.

Jan 1, 1988

By A. E. Bellis

There is a wide difference of opinion among rifle experts in the matter of barrel steel, and the relative importance to the life of the barrel of the steel's composition, heat treatment, structure, and physical properties. In order to promote discussion, which it is hoped may' lead to the discovery of the source of some of the traditional beliefs on the subject, the results of some tests are presented here, with data on heat treating, physical tests, and erosion. The detailed metallographic study of this steel is given in another paper.l The conclusions from these tests should be capable of wider application than their direct bearing on the barrel-steel problem. The Government specifications for barrel steel for model 1903 rifle (Springfield) call for carbon 0.50 to 0.60 per cent., manganese 1.00 to 1.29 per cent., silicon under 0.25 per cent., sulfur under 0.06 per cent., phosphorus under 0.08 per cent. The minimum physical requirements are: Tensile strength, 110,000 lb. per sq. in. (7733 kg. per sq. cm.); yield point, 75,000 lb. per sq. in (5472 kg. per sq. cm.); elongation, 20 per cent.; reduction of area, 45 per cent. Material fulfilling these requirements gives practically no failures when proof-fired, with charge of 70,000 lb. per sq. in. pressure, which is 40 per cent. in excess of the service charge. The turning and drilling operations show up any seams or laps such as accidentally occur even in the best heats of open-hearth steel, so that faulty stock is practically all eliminated before proof-firing. These physical requirements are met either by rolling billets at a proper temperature down to the form of tapered barrel blanks or by heat treating bars that have been upset to cnlarge the breech section. The transformation temperature of this steel, on heating, is around 1350" F. (732' C.), varying somewhat with the composition and the rate of heating. The actual treatment of the barrel blanks, as carried out by different manufacturers, gives four kinds of barrels, which will be called A, B, C, and D, for convenience. A barrels result from heat treating upset blanks by quenching at

Jan 1, 1920

By Donald K. Weaver

THERE have been eight different oil zones identified and produced at Santa Fe Springs, of which three or four are in turn divided into two or three parts. These zones are, from top to bottom, the Foix, difference of opinion over this nomenclature, with reference to the different zones referred to as Clark, it has no particular bearing on the water problems. Each of these oil zones has had waters of varying salinity associated with it, either within or at the bottom of the 'zone. Table 1 is a tabulation of the zones, their maximum thicknesses, salinity and heads of various waters. Surface waters are fresh, and of high head, giving artesian flow in some instances.

Jan 1, 1930

By Oscar Lee, B. W. Gandrud, F. D. DeVaney

"IntroductionFlue dust which results from the smelting of ores containing appreciable quantities of fines is one of the troublesome products of iron blast-furnace practice. Gases issuing from the furnaces at a high velocity carry small particles of coke, ore and flux into dust-collecting chambers. These particles constitute the flue dust. Lasses of iron ore through the production of flue dust vary between wide limits in the different furnaces, and depend on a number of factors, such as size and design of furnace, amount of fines in the ore, the operating conditions and the blast pressure.Blast-furnace operators of the Birmingham district keenly realize this waste. The ores are comparatively low grade and require more fuel than is ordinarily used elsewhere. Hence the flue dust is low in iron content and high in coke. As a result it is not in suitable condition for direct sintering. In many other iron and steel centers direct sintering is a common practice. In the Birmingham district efforts have been made to prevent this loss by recharging the dust into the furnace, but, as might be expected, a material fine enough to be blown out once will very likely be carried over again.In general, the flue-dust losses in this district will average 250 pounds per ton of pig iron produced, but at times the losses at different furnaces are substantially higher or lower than this figure. On the basis of the present rate of pig-iron production, the annual loss of flue dust exceeds 300,000 tons. The iron content of the dust probably averages 25 per cent, therefore about 75,000 tons of iron is wasted yearly, or about 3 per cent of the iron mined is lost in flue dust."

Jul 1, 1926

By James J. Meadows, Jason D. Pampena, Emanuele G. Cauda, Lauren G. Chubb

Exposure to respirable crystalline silica (RCS) can cause serious and irreparable negative health effects, including silicosis and lung cancer. Workers in coal mines have the potential of being exposed to RCS found in dust generated by various mining processes. The silica content of respirable dust in one single mine can vary substantially over both time and location. The current monitoring approach for RCS relies on the use of traditional air sampling followed by laboratory analysis. Results generated using this approach are generally not available for several days to several weeks after sampling, and this delay prevents timely and effective intervention if needed. An alternate analytical method is needed to reduce the time required to quantify the RCS exposure of mine workers. The National Institute for Occupational Safety and Health (NIOSH) has developed a new method using commercially available portable infrared spectrometers for measuring RCS at the end of the sampling shift. This paper will describe the application of the new field-based RCS analytical process for coal mines, including the use of the new method with the existing Coal Mine Dust Personal Sampler Unit. In a case study conducted by NIOSH with a coal mine operator in West Virginia, field-based RCS analysis was completed at a mine site to evaluate the new technique. The RCS analysis results obtained by the field-based method in this case study showed sufficiently strong correlation with results obtained by the MSHA standard laboratory analysis method to allow the mine operator to use the field-based method for evaluating process improvements.

By E. Haccuria

Due to the growing share of electrical cars, the use of lithium ion batteries significantly increased. Recycling of these batteries is essential to safely dispose hazardous materials as well as to recover valuables (Cu, Ni, Co, etc.). In order to optimise the recycling process, accurate information is required on the slag phase equilibria for battery smelting. The slag is a multi-component system containing alumina from the battery cases, silica and lime from fluxes, and manganese and lithium from the electrode materials. The present study accurately determined the phase equilibria in the "MnO"-Al2O3-SiO2 sub-ternary system at metal alloy saturation. Particular attention was given to the accuracy and reliability of the final results by highlighting the different reaction pathways, mass transfer- and reaction mechanisms taking place in the system during experiments. This attention enabled improved experimental methodology and measurements. Based on the present study, further measurements will be undertaken in the quaternary "MnO"-Al2O3-CaO-SiO2 system at low "MnO" concentrations, which closely represents the future recycling industrial slags.

Jan 1, 2014

By Greg Beckstrom

Minnesota is a major mining state. This statement is not a dream or stretch goal but is a fact. As reported in a recent edition of Mining Engineering magazine, Minnesota ranks as the third largest state in terms revenues generated from nonfuels mineral production. The vibrancy of the mining sector in Minnesota can be attributed to several factors. The northeastern corner of the state is home to Minnesota?s iron range, one of North America?s largest deposits of iron ore. Iron ore from Minnesota is a strategic resource that has been [ ] instrumental to the nation?s development ? 90 percent of the iron used to build ships and planes during World War II came from Minnesota. Taconite pellets now produced from openpit mines on the iron range are shipped to steel mills worldwide. The growing appetite for steel in China and India has reignited once moribund mining operations throughout the iron range.

Jan 1, 2012

By B. A. Eaton, K. E. Brown, C. R. Knowles, D. E. Andrews, I. H. Silberberg

This paper presents the resitlts of an investigation of two-phase, gm-liquid flow in horizontal pipelines. Experimental data were taken in three field-size, horizontal pipelines, two of which were constructed for this purpose. The data were obtained using water, distillate and crude oil separately as the liquid phase, and natural gas as the second phase. Experimental pressure-length traverse, liquid holdup and flow-pattern data were collected for each set of flow rates. These data were used to develop three correlations that are presented herein. The liquid-holdup values correlated with various flow parameters without regard to the existing flow pattern. The same was true for the energy-loss factors. A new flow-pattern map is presented that appears to be quite reliable, but not required for the pressure-loss calculations. The liquid-holdup correlation and the energy-loss factor correlation are used in conjunction with a two-phase flow power balance, developed during this study, to predict the pressure losses that occur during gas-liquid flow in horizontal pipelines. A recommended calculational procedure is given, as well as a statistical analysis of the results. This procedure lends itself to computer application, since several small pressure decrements are needed to calculate a pressure-length traverse. The correlations are shown graphically, but may be curve fitted with existing curve-fitring computer programs. INTRODUCTION Due to the frequent occurrence of gas-liquid flow in pipelines and the desire to accurately calculate the pressure losses that occur in these lines, two-phase flow is of considerable interest to the petroleum, chemical and nuclear industries. In the petroleum industry, gas-liquid mixtures have been transported over relatively long distances in a common line due to the advent of centralized gathering and separation systems. Long two-phase flowlines are usually accompanied by large pressure drops which influence the design of the system. Gas-lift installations are designed on the basis of known tubing pressures at the wellheads. The horizontal flowline connecting the wellhead and the separator system must be correctly sized in order to minimize the horizontal flowline pressure losses and the wellhead tubing pressure. Practically all oilwell production design involves horizontal two-phase flow in pipeknes. All of the flow processes of oil and gas production must be studied simultaneously to insure good well design. Since the beginning of offshore oilfield development, long horizontal flowlines have been constructed. Because pressure losses greatly influence the performance of producing wells, a method is desired that can be used to predict such pressure losses and select optimum flowline size. Several types of gas-liquid flow exist, and many of these are discussed by Gouse The study of pressure gradients, fluid distributions and flow patterns that occur in horizontaI multiphase flow is made difficult by the great number of variables involved. The various flow regimes give rise to changing velocities of the fluid particles in all directions. These instabilities of the interface between the gas and liquid prohibit the determination of actual vector velocities of fluid particles in each phase. Also, it is practically impossible to arrive at correct sets of boundary conditions. Therefore, most investigators have concluded that a solution to the problem by the classical fluid dynamics approach, whereby the Navier-Stokes equationsM are formulated and solved, is far too complex. Other methods must be utilized to develop general correlations that will predict the behavior of gas-liquid horizontal flow systems. Multiphase flow studies have sought to develop a technique with which the pressure drop can be calculated. Pressure losses in two-phase, gas-liquid flow are quite different from those encountered in single-phase flow; in most cases an interface exists and the gas slips past the liquid. The interface may be smooth or have varying degrees of roughness, depending on the flow pattern. Therefore, a transfer of energy from the gaseous phase to the liquid phase may take place while energy is lost from the system through the wetting phase at the pipe wall. Such an energy transfer may be either in the form of heat exchange or of acceleration. Since each phase must flow through a smaller area than if it flowed alone, amazingly high pressure losses occur when compared to single-phase flow. Most investigators of horizontal two-phase flow phenomena have chosen to separate their experimental data into several groups of observed flow patterns or regimes.

By J. Lindström, J. Hamuyuni, M. Lundström, J. Aromaa

"The rising demand for metals today, coupled with the scarcity of primary sources for raw materials threatens both technological advancements and industrial manufacturing. In order to meet the demand, metals and other resources trapped in waste streams, have to be harnessed. This philosophy supports circular economy, where metals and other resources are kept in a closed loop. The pickling acid recovery system of most stainless steel production is one such example where the dissolved metals such as iron, nickel and chromium are currently not completely recovered due to the limitations of the current technologies. The aim of this study was to assess the available metals recovery methods from extremely concentrated acids. The main aim is to simultaneously recover metals and keep sulphuric acid reusable in acid circulation process. From the available literature, the most promising methods were chosen for laboratory experiments. Based on experimental work, the results and observations of electrodeposition, solvent extraction, and freeze crystallization are provided. KEYWORDS Pickling acid, metal recovery, solvent extraction, cathodic polarization, Freeze crystallization. INTRODUCTION Pickling in stainless steel production is an essential surface treatment process (Regel-Rosocka, M. (2010); Agrawal and Sahu, 2009). It is applied for removing surface films such as oxides and chromium-depleted layers to improve the corrosion resistance and surface finish of steel (Regel-Rosocka, 2010). Whilst the process greatly improves the surface finish of the stainless steel, it generates large amount of used acid, containing dissolved metals including chromium, iron, and nickel (Agrawal and Sahu, 2009). Recovery of acid is common practice for most steel producing industries (Nyman and Koivunen, 1986). In this work, acid regeneration process is investigated so as to simultaneously reusing sulfuric acid and recovering the dissolved metals. Recovery of valuable metals even in very small amounts would also bring additional revenue to the steel production industry. At a time when metal production has also been challenged by lack of natural resources for raw materials, secondary sources for metals such as the acid pickling process therefore, have greater potential as supplements. From earlier studies, electrodeposition (Giovanardi and Orlando, 2011; Kuznetsov et al., 200; Rögener et al., 2012; Surviliene et al., 2006), solvent extraction (Alguacil and López 1996; Haghshenas et al., 2009; Kesieme et al., 2013) and freeze crystallization (Beyer et al.,2003; Hasan et al.,2017; Van der Ham et al., 1999) are some of the most established potential methods. Earlier studies have also shown that simultaneous recovery of acid and metals would require combination of different methods. This is primarily due to the nature of very stable metal containing complex compounds formed during pickling. These complexes must be broken down to free the metals for further recovery processes."

Jan 1, 2018