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By C. Baldwin Sawyer

During the last half century, much time has been devoted to investigations of the effect of nitrogen on the physical properties of steel, but in all discussions of results there is considerable doubt as to the accuracy and interpretation of analyses. No conclusions concerning the effects of nitrogen on the physical properties of steel can be more reliable than the methods used for determining the quantities of nitrogen present. The work described in this paper endeavors to establish some additional conditions required by the customary distillation method for reliable and nccurate determinations. Results by a combustion method of analysis for total nitrogen content are presented; these indicate that all of the nitrogen in steel, exclusive of that contained in blowholes, may be determined by the distillation method. Based on these more sound and more reliable analyses, results havc been obtained that bear on the following divisions of the general subject, nitrogen in steel: Nitrification of steel by melting in nitrogen, nitrification of steel by heating in ammonia, decomposition of nitrified steel by heating, and thermal analysis of nitrified steel. Consideration of Two Methods of Analysis and Some Results The details of the distillation and combustion methods are chemical in character and of little interest to most readers. They are therefore described in an appendix. The distillation method is essentially that described by Hurum and Fay1 and was generally used throughout this work. It is capable of the greatest accuracy and all results given are significant to the last, figure. Where analyses do not check, the samples

Jan 1, 1923

By R. G. Robins

Metal separations based on the selective precipitation of phosphates have a potential application in many hydrometallurgical processes. This paper reviews the literature on the solubility of a number of both divalent and trivalent metal phosphates and presents the result of some additional experimental measurements. The systems examined have been modelled to obtain free energy of formation data for the various species. Computer generated solubility diagrams which are described can be useful in predicting a variety of metal separations.

Jan 1, 1991

By Levi de Oliveira Bueno

Constant stress testing was used for characterization of creep behavior of a 1Cr0.5Mo steel plate in the ex-service condition. The tests were performed on creep machines equipped with Andrade-Chalmers type profiles, high sensitivity SLVC transducer extensometry, high stability temperature controllers, and facilities for monitoring the creep curves with an automatic data logging system. Ten creep machines of this type were used in this research, in an experimental work that lasted for one year. Three temperature levels were selected: 538, 565 and 593°C, with stress in the range from 52 to 224 MPa producing rupture times varying from 5 to about 3950h. The creep curves were all followed with great scrutiny using data logger scanning rates which enabled storing thousands of readings in each case. The experimental analysis involved measurements of minimum creep rate, rupture time and final elongation at rupture. The data were analyzed according to the classical phenomenological / physical relations (Norton, Arrhenius, Zenner-Hollomon, Monkman-Grant) and also considering five traditional parameterization methodologies (Larson-Miller, Orr-Sherby-Dorn, Goldhoff-Sherby, Manson- Haferd and Manson-Succop). Comparisons are presented among the possibilities of data extrapolation from five different methodologies. Comparison is also made with creep results obtained on a similar plate of the same material in the virgin condition.

Aug 16, 2017

By K. K. Kelley

"In an earlier consideration of the vapor pressure of iron 3/ it was found necessary to estimate the specific heat of gaseous iron to write satisfactory free-energy-of-vaporization equations for the several forms of iron. That the specific heat of gaseous iron will exceed greatly the classical value of Cp = 4.967 calories per gram-mole per degree is evident from even a cursory Lamination of its spectrum. The two lowest energy states are separated by only 416 cm-1, which is small enough so that the second state is effective, theoretically, at below room temperature. Such phenomena are by no means uncommon, but, while they have been recognized with substances that ordinarily are encountered as gases, classical gaseous specific--heat values still are used, often without question, for the vapors of metals and other elements that are solids under ordinary conditions. The following calculations for iron and copper gases are presented to illustrate the sort of deviations from classical values that are encountered with metal gases.The methods employed in calculating from spectroscopic data of thermodynamic quantities such as specific heat, entropy, and free energy have been described, in detail by Giauque 4/ and others. These will be briefly reviewed here. It is customary to separate the translational energy of a molecule from the rotational, vibrational, and electronic energies. In the case of monatomic gases, only translational and electronic Energies are involved. The classical expression for the specific heat of a mona¬tomic gas, Cp = 4.967, deals only with energy stored in the molecule as translational energy and consequently is valid only in temperature ranges in which no appreciable number of molecules undergoes a change in electronic state."

May 1, 1937

By Toru Yamasaki

"Bimodal lithostratigrafic assemblages are of significance in volcanogenic massive sulfide (VMS)-hosted lithology. The largest deposits are either bimodal-siliciclastic or maficsiliciclastic, and the presence of a significant siliciclastic component in the host stratigraphic succession favors large VMS deposits (e.g., Franklin et al., 2005; Barrie and Hannington, 1999). In the case of modern sub-seafloor VMS deposits in arc-related settings, the majority of deposits have been discovered in association with calderas or cauldrons (Halbach et al., 1993; Ishibashi and Urabe, 1995; Iizasa et al., 1999). These features are formed by the explosive eruption of silicic volcanoes, so that silicic host rocks and/or pumiceous volcanic clasts are generally observed around the ore deposits (e.g., Binns and Scott, 1993; Fiske et al., 2001). Caldera-like and graben-like morphological features therefore attract attention in geophysical surveys. However, silicic lithologies (dacite and rhyolite) normally contain only small amount of metallic elements (e.g., a few ppm to a few dozen ppm of Cu), whereas mafic rocks, such as basalts and basaltic andesites, contain significant amounts of metals (e.g., a few hundred ppm of Cu). Thus, the origin of metallic elements in VMS deposits associate with the silicic host rock remains unclear.The Iheya North Knoll is a volcanic complex in the middle of the Okinawa Trough. It is located in a young and actively spreading back-arc basin that extends for 1200 km behind the Ryukyu arc-trench system (Lee et al., 1980; Letouzey and Kimura, 1986). Several active hydrothermal fields have been recognized in the Iheya North Knoll. Mineralization at the Iheya North Knoll is characterized by relatively juvenile features consisting of VMS deposits with associated hydrothermal alterations to various degrees. Massive sphaleriterich sulfides at this site, recovered for the first time from beneath an active seafloor hydrothermal system, strongly resemble the black ore of the Kuroko deposits of the Miocene age in Japan (Takai et al., 2011). From February 11 to March 17, 2016, the SIP CK16-01 (Exp. 908) D/V Chikyu cruise was conducted at Iheya North Knoll and the rifting center of the Iheya Minor Ridge area, middle Okinawa Trough. The Iheya Minor Ridge area is also an active hydrothermal field, located ~30 km southeast of the Iheya North Knoll. In this area, basaltic rocks are widely distributed, and drilling has confirmed that the basaltic materials continue to ~120 m below the seafloor (Kumagai et al., in prep)."

Jan 1, 2017

By Zvi Rivlin

Classical nucleation theory states that in first order phase transformations, such as liquid to solid transition, nucleation of the product phase starts with the formation of small, unstable clusters (embryos). When the thermodynamic barrier to nucleation is overcome, the embryos grow and attain a critical size, beyond which they are stable, i.e. they become nuclei. If nucle- ation does not occur, the parent, liquid phase remains in metastable equilibrium. At temperature lowers, undercooling increase and atomic mobility decreases. The viscosity change in the undercooled liquid may result in the formation of glassy state. As demonstrated in previous papers [I-21, in solidification involving surface nucleation of the product phase, as the case is in rapid quenching by melt-spinning, both nucleation temperature and nucleation time depend upon the number of atoms available at the isothermal surface in contact with the substrate. As a result of the thinness of the melt-spun ribbons, the embryo clusters that form at the freezing temperature may not be supplied by the amount of atoms necessary for their growth to critical nuclei sizes. In such extreme conditions, the liquid does not crystallize, it forms a metallic glass. A numerical simulation method is proposed for the reactions involved in embryo cluster formation and growth, at the atomic level. The simulation enables the caIcuIation of either the nucleation or the glass transition temperatures. Calculations made for the well-known glass forming CuZr and FeB systems afford prediction of the geometrical and thermodynamically conditions necessary for the formation of either crystalline or amorphous ribbons in melt-spun ribbons.

Jan 1, 1994

By Max J. Spendlove

The secondary copper industry is comprised of numerous enterprises which collectively employ many of the recovery and refining processes now used in primary plants as well as many other processes that are unique to the industry. Effective methods are used for identifying and segregating all types of scrap according to widely accepted standard classifications. Segregated scrap and waste materials usually require some preliminary processing to remove both valuable and deleterious associated constituents. Smelting, melting, alloying, and pyrorefining are common methods used for producing secondary metal, but operating techniques usually differ from primary metal operations because of the difference in physical and chemical properties of the respective raw materials. Some copper scrap is converted to copper chemicals rather than to refined metals or alloys. Recovery efficiencies of all processes are reasonably high, and the quality of products meets rigid specifications.

Jan 1, 1961

By R Ayothiraman

Tunnel excavation may induce adverse effects on nearby existing structures/foundations in urban areas. Accurate prediction of tunnelling effects on pile foundations of nearby structures in the urban environment poses a major challenge during design. Several studies have been undertaken to understand the mechanisms of the soil-tunnel-pile interaction, which focused only on influence of tunnelling on nearby existing building and foundations. However, effect of pile loading on existing tunnels did not receive enough research attention so far. So it is essential to measure the response of existing tunnel-lining due to loading on newly constructed pile to assess to the safety against the additional forces/moment caused by pile loading and to evaluate the critical distance for the proposed construction of any structures from the tunnel location. This paper presents result of three-dimensional (3D) finite element analysis carried out in ABAQUS to investigate the effects of pile loading on existing tunnels embedded in cohesive soil. It is found that the effects on tunnel lining depend on horizontal separation distance between pile and tunnel as well as location/elevation of pile tip with respect to tunnel location.

Mar 8, 2011

By J. A. Hansuld

"THIS SESSION marks something of a milestone in that it is, as far as I know, the first session at a CIM Annual Meeting devoted entirely to exploration geochemistry. This is an indication of the general acceptance and widespread recognition by industry of geochemistry in mineral exploration. As a first, I hope it proves sufficiently successful and interesting that geochemical exploration sessions will become a routine part of future CIM annual meetings. The greater use and acceptance of geochemistry has resulted in many investigations and advances, especially in areas such as the Canadian Shield. For a first session on geochemistry, the meeting in Quebec suggested an ideal opportunity to assess these advances and report on the current application of geochemistry in the Shield. The theme of the session is ""Geochemical Exploration in the Canadian Shield - The State of the Art."" A series of six papers will be presented dealing with the various dispersion media - rocks, heavy minerals, ""soils"", lake sediments, waters and vegetation. As a background to the individual presentations, I would like to take a few minutes to briefly trace the history of the use of geochemistry in the Canadian Shield."

Jan 1, 1971

By C Simpson, J M. F Clout, G Plummer

Detrital iron deposits (‘DID’) in the Hamersley Province of Western Australia have been successfully mined and processed as small quantities of saleable standalone or blended lump and fine ore products over many decades. Despite their past, present, and potential future exploitation, they have received far less geological attention than the economically more significant higher grade bedded iron deposits (BID) or channel iron deposits (CID). DID are composed of Pliocene to Quaternary unconsolidated colluvial/alluvial hematite gravels with minor sand, silt, and ferruginous clay, as well as minor iron rich hematite clast conglomerates. DID mineralisation at Solomon has been subdivided into six distinct stratigraphic units, DID-5 (lowermost) to DID-0 (uppermost) based on differences in clast and matrix textures and mineralogy, degree of consolidation/lithification, particle size distribution and replacement textures. The most significant accumulations of DID-1 to DID-5 are in tributary valleys that have been cut through the Joffre Member of the Brockman Iron Formation on either side of the main Kings-Queens valley which contains the CID. DID-5 and DID-4 are ferruginous conglomerate, referred to as canga, with four subtypes recognised. DID-4 is composed of BID hematite clasts cemented by hematite or goethite. DID-5 is characterised by partial to complete replacement of BID hematite clasts and matrix by the yellow ochreous and brown to black vitreous forms of goethite. DID-3 to DID-0 are unconsolidated hematite detritals composed of largely (>80 weight per cent) fine to coarse gravel, minor sand and little silt or clay. The gravel clasts are largely composed of hematite and hydrohematite that replace BID, micro-nanoplaty hematite-martite-ochreous goethite (m-nplH-M-oG) BID, reworked canga, hematite pisoids, siliceous hematite BID (micro-nanoplaty hematite-martite-quartz, m-nplH-M-quartz), chert (~10–20 per cent) and minor (<5 per cent) Banded Iron Formation (BIF). Hematite abundance decreases from DID-3 to DID-0 whilst siliceous hematite BID is highest in abundance in DID-0 and lowest in DID-3. A key finding of the study is that >90 per cent of mineralised detrital clasts are derived from hypogene altered BID micro-nanoplaty hematite-martite with subsequent later supergene ochreous goethite mineralisation hosted by the Joffre Member. The DID genesis model entails interpreted Palaeoproterozoic siliceous hematite hypogene microplaty BID mineralisation of the Joffre Member undergoing Cenozoic supergene leaching of quartz and replacement by ochreous goethite to form low phosphorous BID micro-nanoplaty hematite-martite-ochreous goethite clasts. BID martitenanoplaty hematite-martite-ochreous goethite clasts and detritus eroded from hill slopes were deposited in the valleys as an initial single DID-5-DID-4 unit over a weathered pre-CID basal conglomerate. DID-5 and DID-4 underwent goethite cementation of the matrix followed by replacement by hydrohematite, hematite, and maghemite. DID-3 formed during subsequent periods of erosion of largely DID-4 hematite clasts and pisoids. Groundwater flow-through hematite canga resulted in partial to complete hydration replacement of DID-4 hematite clasts and matrix by ochreous and vitreous goethite to form DID-5. Deposition of DID-2 to DID-0 was via reworking and deposition of DID-5 to DID-4 canga and DID-3 as clasts and pisoids/ooids, as well as siliceous hematite and BIF sourced from the Joffre Member in the hill slopes.

Nov 8, 2021

By Dany Pelletier, Yeves Breau, Ahmed Bouajila, Claude Gagnon

"In flotation circuits, direct measurement of the volumetric flow rate delivered by electromagnetic flowmeters is often difficult to obtain particularly due to piping and flow constraints. However, on-line material balance calculation could offer a reliable alternative to flow rate sensing. This paper describes an on-line material balance software package as applied to a copper flotation circuit for mass flow rate estimation mainly based on the output of an x-ray fluorescence onstream analyser. Rule-based procedures for the management of the main calculation modules are designed and integrated to a Comdale expert system. Attempts to diagnose the flotation process from mass flow rate data are also discussed.INTRODUCTIONThe need for improved process diagnosis, control and optimisation has become more evident for the mineral processing industry in the last decade. Therefore, new process variables need to be inferred or measured particularly in highly multivariable processes such as flotation. This process is subject to a wide variety of disturbances mainly generated by frequent and sometimes abrupt changes in physical and chemical characteristics of the ore and due to some irregularities in manual process operating procedures.A flotation circuit scheme is always a complex network counting more than two dozens of slurry streams. Information about those streams (%solids, metal content analysis, and flow rates) are important for process diagnosis, performance evaluation control and optimization (1,3).On-line sensing instruments such as x-ray fluorescence (XRF) on-stream analysers (OSA), gamma density gauges and electromagnetic flowmeters have been developed for the measurement of those variables. Unlike the other variables, stream flow rates could be determined by different ways:"

Jan 1, 2000

By J. W. Leonard, B. A. Donahue

A method is described for incorporating coal petrography into mining and preparation plant quality control based on conventional analyses. Complete analyses are made of each of the uniform and relatively distinct petrographic bands in a coal face. With this information it is possible to develop petrographic standardization curves. These curves permit diverse coal characteristics to be rapidly monitored by application of a few standard coal tests. Single seam quality control is discussed in this paper. Inquiries continue to be made about coal petrography, and specifically, about whether coal petrography should be applied more extensively in the coal industry. Coal petrography is the study of the distinct physical, optical, and chemical increments which make up the organic rock mixture which we know as coal. Petrography can be applied by any coal company or at any coal mine where conventional coal analytical facilities are available and where additional resources can be allocated for an increased number of determinations. This first paper of a two part series includes (1) a proposed conventional approach to single seam petrography based on the development of petrographic standardization graphs and (2) some informative and supplemental interrelationships involving coal characteristics developed as a result of this research. In the second part of this series, to be published at a later date, those petrographic characteristics of bands taken from many different coal seams located over wide geographic areas which can be closely related to each other will be considered. These findings will be examined looking toward the development of a comprehensive, conventional approach to coal petrography which can be used as a common basis for multi-rank petrographic standardization graphs. Implicit to the understanding of coal petrography is the well established fact1,2 that the individual analyses of distinct petrographic bands often differ widely from the average analysis which is used to characterize a whole coal seam. In fact, a distinct and minor banded increment of coal in a high volatile seam may actually be a medium or low volatile coal with an analysis similar to the average analyses of seams located in distant coal fields. During the mining of coal, much degradation is caused which tends to randomly scatter coal bands. The degraded, scattered, and physically separated constituents of distinct petrographic bands are processed side by side in the coal preparation plant as distinct petrographic fractions with particles grouped according to a narrow size range (which derives in part from common hardness), specific gravity, and-or surface chemistry. Tile data obtained from numerous analyses made on each of the bands of any given coal seam, although diverse, can be readily interrelated. Indeed, these interrelationships can be developed into a series of nomographs or petrographic standardization graphs to serve as a basis for developing a conventional petrographic* program. Thus, by analyzing one property (for example, ash) of a selected petrographic fraction collected or separated from the flow of coal in a preparation plant, it should be possible to estimate the other physical, chemical, and thermal properties of this fraction by referring to the petrographic standardization graphs. It follows that any or all petrographic fractions in the total coal flow originating from a single coal seam can be rapidly monitored for many properties on the basis of a single analysis run on each fraction. In recent years coal petrographic research has concentrated heavily on that phase of this work which involves microscopic reflectance measurements made at many minute and selected points on a coal briquette surface.3,4 Thus, the percentage of the total number of reflectance measurements that fall into each of a consecutive series of arbitrarily chosen reflectance classes are used to characterize coal. This procedure is analagous to using the face of a coal briquette to represent the reflectance characteristics present at the face of a coal seam. Moreover, by analyzing petrographic fractions of known and uniform optical properties it is possible to closely relate reflectance to other coal characteristics. For example, reflectance has long been known to be related to such

Jan 1, 1968

Copper nickel separation is performed by mineral processing techniques both pre and post smelting in Copper Cliff at Vale Canada?s Operations. The separation at Clarabelle Mill takes advantage of the ore mineralogy to affect a separation on the rougher concentrate where chalcopyrite and pentlandite exhibit high liberation and high recoveries thus their separation is simple although incomplete. The copper concentrate comprises only 50% of the copper in ore with the remaining copper being separated post smelting in the Matte Separation plant where the slow cooled Bessemer Matte is again treated by mineral processing operations using flotation to separate the chalcocite and heazlewoodite and magnetic separators to remove a metallic nickel alloy. This paper discusses the mineralogy, separation processes and work currently underway to improve the separation of copper from nickel in these plants.

Sep 1, 2012

By A. Wieniewski

The observed progress in technology of non-ferrous ores enrichment and condition of machines and equipment in the ores concentrators on the one hand have brought a possibility and on the other resulted in necessity for introduction of modernization actions. Positive results of investigations into influence of chemical modification of selected products of enrichment process on copper ores enrichment results gave possibility for implementation of chemical-flotation technologies of ores enrichment. The substantial development in flotation machines structure has contributed to modernization of flotation process resulting in increase of enrichment efficiency. The paper presents the idea and results of chemical modification of difficult in enrichment semi-products in the technology of copper ores enrichment and the results obtained after application of the modernised technology. The structure of large-volume flotation machines used in various stages of flotation and current situation in modernization of flotation process in copper ores concentrators are also described. The paper presents industrial-scale results of flotation after application of modified flotation reagents of collector group. Introduction of modifiers into the widely used xanthates resulted in increase of copper recovery in concentrate.

Jan 1, 2014

By J. N. Maycock, P. W. M. Jacobs

Previous measurements of the thermoelectric power of ionic crystals are reviewed briefly. It is concluded that, while extensive measurerements are available on systems in which the electrode M has a cation in cornon with the sall MX, there is as yet little modern work on systems in which the metal electrode M&apos; does not haue a calion in common with the salt. We haue now measured the thermoelectric power of- single cryslals of KC1 and of KC1 + SrCl2 between plati.nu?n electrodes over a much wider range of temperature than before. individual ionic heats of transport, which, while probably not very accurate, are of a reasonable order of magnitude, are obtained from this data on the basis of an assumption that charge carriers do not cross the electrode/salt interface. RELATIVELY little work has been done on thermal diffusion in ionic crystals. Reinhold and coworkers1-I measured the thermoelectric power and Soret effect in silver and cuprous salts and their mixed crystals. One electrode was kept at constant temperature and electromotive force was measured as a function of the temperature gradient. This is not a satisfactory technique if the results are to be compared with theory; rather should the electromotive force be measured for small temperature differences as a function of the mean temperature of the two electrodes. They used electrodes having the same cation as the salt. Patrick and Lawsons measured the thermoelectric power of AgBr and of AgBr containing 0.25 mole pct CdBr2 using silver electrodes and temperature gradients of 10°C in the temperature range 100° to 400°C. The results were analyzed using the Teltow9 values of the ratio of the mobility of the two types of charge carrier (cation vacancies and interstitials) found from conductance measurements and the wagnerlo estimate of the heterogeneous contribution to the thermopower, Ohet They obtained values of qi = 0.017 ev and q$ = -0.385 ev for the heats of transport of interstitial Ag ions and cation vacancies, respectively. Their data has been reanalyzed by Haga using the corrections to the Wagner formula for ehet given by Howard andLidiard; Haga found ev. Christy et a1.14 have measured the thermopower of AgBr containing 0.01 to 1.0 mole pct CdBr,. They analyzed their results in terms of the theory of Howard and Lidiard and found that excellent agreement with the theory was obtained if q5 + : + hF was set equal to 0.70 ev at 175°C and equal to 0.58 ev at 250°C. Since Teltow&apos;s value for hF, the enthalpy of formation of a Frenkel defect pair, is 1.27 ev, this means that qt + q: increases in magnitude from -0.57 ev at 175°C to -0.69 ev at 250°C. This result is in poor agreement with Patrick and Lawson&apos;s value of -0.37 ev for pure AgBr (for which the corrections to the Wagner estimate for ehet are very small). christy1&apos; has also reported thermopower measurements for pure silver halides and for the systems he finds that qr + qt for AgBr increases in magnitude from about -0.55 ev at 150°C to about -1.1 ev at 400°C. The temperature dependence of the sum of the heats of transport in AgCl is very similar in magnitude. The sum qi + q cannot be decomposed into the individual interstitial and vacancy heats of transport without a knowledge of the entropy contribution from the change in the lattice vibrational frequencies around the interstitial and vacancy. Despite this it seems an inescapable conclusion from Christy&apos;s analysis that and -6 = Q Ag are quite strongly temperature-de pendent and that -q: is much greater in magnitude than the corresponding activation energy for vacancy migration, +0.37 ev. It remains a mystery as to why the data for pure AgBr are fitted so well by the assumption of temperature-independent heats of transport if association of impurity ions and vacancies is neglected.l The values for q$ and q: so obtained are also much more in line with those expected from a simple kinetic interpretation of the heats of transport due to wirtz.17 Christy and Hsueh have also measured the thermopower of CuCl between copper electrodes; 0 for pure CuCl is comparable with that for the silver halides but, owing to the limited solubility of divalent cation impurities it was not found possible to deduce values for the heats of transport. In contrast to these extensive measurements on cells of the type M MX 1 M, there have been relatively few attempts to measure the thermoelectric power of cells of the form M&apos; 1 MX I M&apos;. (We specifically exclude from discussion cells of this type in which the metal electrodes M&apos; are in contact with gas containing a controlled partial pressure of either M or X,, since in these cells the electrochemical reactions are analogous to those of the first type.) The thermoelectric power of Pb12, PbC12, TlC1, TlBr, TlI, NaNO3, and KNO 3 between platinum electrodes was measured by Thie1e.l3 In discussing these measurements Holtan20 asserts that the thermopotential initially fluctuated wildly and even changed sign before approaching a steady value. A high degree of irreproducibility is also evident in the work of Nikitinskaya and Murin21 who first studied the thermopower of NaCl and KC1 between platinum electrodes. Much better reproduci-bility was achieved in our earlier measurements on KC1;22 these were, however, confined to a relatively narrow temperature range and one of the objects of the work reported in this paper was to extend the temperature range of the measurements of the thermoelectric power 8 of KC1. The only other published

Jan 1, 1967

By Greg Wyartt

"At an Australian iron ore open-cut mine, 129 separate blast patterns (consisting of 38.5 million tonnes /42.4 million US tons, equaling 28% of annual blasted tonnes) were initiated using electronic detonators. 87 patterns were designed as per site methodology using ‘vectorial’ initiation timing sequences (blast direction and relief specified only), while the remaining 42 patterns were designed with interactive initiation timing sequences - hole by hole sequencing based on the measured site specific primary shock wave (P-wave) velocity and distance between blast-holes. The intention of this project was primarily to reduce material size presented to the crushing circuit, and also to determine if productivity benefits could be obtained by the use of interactive timing."

Jan 1, 2017

By J. H. Wilhelm

Continuous thickeners can be sized either from previous experience, continuous pilot-scale test results, or from batch settling tests. Although it is a relatively simple process to size full-scale thickeners when previous experience or pilot-scale operating data are available, batch testing is often the only realistic method for sizing thickeners due to time restrictions, budget limitations and availability of sample material. Many authors have, therefore, suggested means of running batch tests and analyzing the resulting data. Fundamental thickening theory had its beginning with the work o£ Coe and Clevenger(1). In order to determine the size of the thickener settling area, they proposed that a series of batch settling tests be run at various initial concentrations. The solids handling capacity at each concentration can then be determined and the lowest capacity (maximum area requirements) used to size the thickener. Kynch(2) developed a mathematical analysis in which the relationship between solids concentration and settling rate can be obtained from a single batch settling curve. Talmage and Fitch(3), Yoshioka(4)(5) and Dick(6), have enlarged upon these works to give a basis for methods of sizing thickeners.

Jan 1, 1979

By Geoffrey Hughes

The Narragansett Bay Commission (NBC) is a regional sewer authority that serves ten communities in the Providence, Rhode Island metropolitan area. From 1992 to 1999, the NBC developed a comprehensive facilities plan to abate Combined Sewer Overflow (CSO) pollution in the Upper Narragansett Bay. The plan underwent many major evolutions during this period, most notably the addition of a stakeholder?s process by which NBC demonstrated a site-specific plan to control the pollutants and meet water quality standards. The favored solution consisted of deep tunnel storage with treatment at existing wastewater facilities that had been recently upgraded. In 1999, a final plan was accepted which included two tunnels, five CSO interceptors, twelve sewer separation projects, a wetland facility, and a wastewater treatment facility upgrade. The program is to be constructed over 20 years in three sequential phases (Figure 1). Phase I of the program includes a 4,963 m (16,284 ft) long, 7.9 m (26 ft) diameter, 70.1 m (230 ft) deep storage tunnel; seven drop shafts with connecting adits; ancillary facilities; and a pump station. Construction of Phase I began in 2001 and is expected to be operational by October 2008. This paper focuses on design and construction of the Fields Point Tunnel Pump Station (FPTPS)located at the south end of the main spine tunnel. A189 Ml/day (50 MGD) pump station is required to lift CSO flows from the tunnel to the Fields Point Wastewater Treatment Facility (FPWWTF). The pumps are to be housed in a 35.6 m × 18.6 m ×20.7 m (117 ft × 61 ft × 68 ft), 91.4 m (300 ft) deep cavern excavated in a complex meta-sedimentary rock of the Rhode Island Formation, and connected to the surface by 9.7 m (32 ft) and 3.4 m (11 ft) diameter shafts. Factors which influenced selection of the size, configuration and location of facilities included the preferred arrangement of pumps, critical aspects of site geology, and estimated cost. Technical and value engineering reviews also affected the final design. Following Notice to Proceed (NTP), concerns were raised by the contractor regarding constructability and design. Additional geotechnical investigation and independent engineering review were employed to validate the design assumptions. The cavern was successfully excavated and sup-ported in rock, completed on schedule and within budget in 2005. In 1992 the NBC retained Louis Berger Group (LBG) as Program Manager (PM) for the CSO Abatement Program. LBG thereafter formed a design team including: Jacobs Engineering Group(JEG) as the designer for underground structures and near surface collection facilities; Black and Veatch(B&V) to design the pumping system and associated facilities; Haley and Aldrich (H&A) to oversee the geotechnical program; and Malcolm Pirnie to design the system-wide instrumentation and control system. Construction management, resident engineering, and inspection services were provided by the joint venture Gilbane/Jacobs Associates (G/J).

Jan 1, 2008

By Patrick R. Taylor

Iron phosphate glasses are promising host matrices for vitrifying actinide rich nuclear wastes materials because of their high solubility of actinide oxides, high chemical durability, and relatively low melting temperatures. An iron phosphate waste form was developed at the University of Missouri-Rolla. The structure and property of the waste form were well characterized by materials techniques. However, to scale the process and advance it to commercial viability, it is necessary to understand the processing parameters, such as the partitioning of waste elements and the viscosity as a function of temperature. Viscosity of 40 Fe203 - 60 P205 mole % iron phosphate melts (prepared with phosphorous pentoxide and ferric oxide) at 1000-1200 C was measured by the rotating-spindle method. It was discovered that this fluid has non-Newtonian behavior. Experiments were performed to study flow properties following the Standard Test methods for Rheological Properties of Non-Newtonian Materials by Rotational (Brookfield) Viscometer (ASTM D 2196-86). Samples prepared using ammonium phosphate and ferric oxide showed Newtonian behavior and the temperature dependence of the viscosity was studied over the range of 1000 to 1200 degrees C. The difference in flow behavior between the two fluids was analyzed in terms of preparation conditions and variation in the final composition and phases. The partitioning behavior of waste elements in the iron phosphate glass was studied by melting in a high temperature furnace and JCP analysis. The experimental results show that the solubility of Ce and Sr in phosphate glasses is significantly higher than the solubility associated with borosilicate glasses. This strengthens the conclusion that iron phosphate may be a viable alternative to borosilicate glass for immobilization of high heavy-metal-content wastes and actinide rich wastes.

Jan 1, 2002

By D. D. Harbuck

To decrease reliance on foreign sources for the strategic and critical metals gallium and germanium, the U.S. Bureau of Mines identified and developed processing technology for two domestic sources of these metals: a Tennessee zinc residue and a Utah ore. Sulfuric acid (H2S04) solutions were used to solubilize gallium and germanium in both sources. Statistically designed experiments showed that the most important parameter for high metal extraction from zinc residue was the H2S04 concentration. At a concentration of 2.9M H2S04, 95 pct of the gallium was extracted, and at a concentration of 0.6M H2S04, 73 pct of the germanium was extracted. Controlled H2S04 concentration was also the key for high metal extractions (97 pct Ga, 87 pct Ge) from the Utah ore. Such control was achieved using a two-stage countercurrent leach circuit. Testing showed that the insoluble germanium in both the residue and ore was tied up with silica. Several methods for overcoming this problem are given. To recover gallium and germanium from the leach solutions, the solvent extractants octylphenyl acid phosphate (OPAP) (for gallium) and LIX 63-OPAP (for germanium) were identified. These extractants were tested in separate, continuous, solvent-extraction circuits yielding a gallium recovery of 94 pct and a germanium recovery of more than 90 pct.

Jan 1, 2010