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By M. A. Halim, V. I. Lakshmanan

Recycling is one of the key elements for sustainable process development for the recovery of value-added products and reducing environmental impact. Process Research ORTECH Inc. has developed several innovative and sustainable technologies, which minimizes the use of water, and chemicals for the recovery of gold, vanadium and gallium from secondary sources by maximizing the recycling of reagents, and reuse of water from process effluents.

Jan 1, 2015

By A. Wahib Khair

"This article first describes the impact of respirable dust on the health of miners in underground coal mines in the United States of America. Second, it identifies the major sources of dust generation, namely cutting tools in the road headings. Two surveys associated with cutting tools were made to determine the useful life of these cutting tools, and to determine the effect of cutting tool wear on productivity of the continuous miners. Third, this article presents the results of a series of experiments carried out in the Rock Mechanics Laboratories at West Virginia University in order to study: 3.1 the effect of cutting tool rate of wear on respirable dust generation, 3.1.1 the effects of rock materials on tool wear and respirable dust generation, 3.1.2 the effect of cutting tool geometric parameters on respirable dust generation, and 3.1.3 the effect of tip materials used in the cutting tool on respirable dust generation. Recommendations in regard to cutting tool design are also presented in this paper.Silica and coal dust are the two major elements affecting the health of underground miners. According to Lemen [1] approximately 1,500 men died due to breathing in silica dust in 1936 while tunneling through a mountain of mostly silica, near the town of Gauley Bridge, West Virginia. Coal dust resulting in lung diseases in one of the major health hazards in underground coal mines. The impact of black lung on miners, coal workers' pneumoconioisis (CWP), has ranged from 16,000 to 23,000 each year since 1982 [1].The trend for conventional mining to continuous machine cutting of coal, using more productive machinery, is inexorable. Intolerable level of dust generated at the face is an indication of inefficient coal/rock cutting by these machines. The federal goverment of the United States paid about 11.7 billion dollars in workmen's compensation to more than 470,000 miners with CWP [2]. Bieniawski and Zipf [3] reported that annual benefit payments were about 2 billion dollars. The enactment of the Health and Safety Act in 1969 in the United States triggered the initial investigation into coal cutting mechanisms and cutting tool designs.The surveys concerning the utilization of cutting bits and performance of continuous miners in underground coal mines were made in order to have first hand information about bit consumption and coal produ¬ction.Three types of used bits, commonly utilized cutting tools on continuous miners, were collected from different coal mines. The used bits were grouped into symmetrically and asymmetrically worn bits. Distribution analysis for weight loss and conical height loss was done. Details of the results are presented elsewhere [4], here the results are summarized briefly. The analysis shows that approximately 50% of the collected bits have worn asymmetrically, which shows that many bits do not rotate properly during cutting. Analysis of the distribution of bit wear showed that the degree of bit wear varied from one type to another and with mining conditions. On average, the weight loss of the used bits was 4% to 7% with a maximum of 31%. Correspondingly, the loss of the conical height was observed to vary between 11% and 23% with a maximum of 71%. Figure 1 shows typical data associated with some of the used bits."

Jan 1, 1998

By A. Dadgar

The adsorption kinetics of AuBr4 on Dowex ® -21K ion-exchange resin were studied and found to be independent of the initial gold, bromine, and base metals concentrations. A commercially-available undivided hypochlorite generating cell was used to generate bromine from simulated mixed halide (Br-/CI-) solutions. Electrolyses were performed with solutions containing very low Br' ion concentrations. The current efficiencies were 80-90%, and Br- ion utilization was maximized. A detailed economic assessment was made considering the capital and the operating costs for a 1000 mtpd gold ore processing plant. The toxicity and discharge levels of bromide, bromine, and cyanide were compared from a detailed analysis of the published literature data. Comparing bromine vapor with hydrogen cyanide gas for a given length of exposure, the lethal concentration of bromine is about 3 times less than hydrogen cyanide. The toxicity of sodium bromide is similar to that of sodium chloride. Acute poisoning to bromides and chlorides is rare because of their low toxicities. The allowed discharge levels of Br-, Br2, and CN- in fresh water are 250, 0.1, and 0.005 mg dm-3, respectively.

Jan 1, 1992

By K D. Wilkes

The WEMCO Heavy Media Drum Separator was first introduced by WEMCO in California in the 1940`s, initially from their base in San Francisco and later when the company moved to Sacramento. The WEMCO Company became a part of EIMCO Process Equipment in 1985, and in 2002 EIMCO became a part of the GL&V Group when Dorr-Oliver EIMCO was created. Throughout this period of time the WEMCO Drum has been installed on a variety of different applications and is now operating at the heart of many of the world?s largest Minerals and Coal Processing Plants, as well as being used by many smaller producers and metal re-cycling operations. This paper looks at the practical aspects of using WEMCO Drums in a representative range of processing applications.

Jan 1, 2006

By G. V. Theja, V. B. Maji

Large infrastructure projects like tunnel excavations, underground constructions face innumerable risks. For successful completion of these projects, it is essential that we foresee and understand risks that could occur during different phases of the project. One of the risks affecting underground excavation projects is the inaccurate performance prediction of TBMs. As this could severely affect the project, resulting in lower advance rates and could also result in changing the excavation machine or method, due to difficulties in excavation, thereby increasing the overall cost of tunnelling. This makes performance prediction of the TBMs as one of the crucial aspects in tunnelling, as a precise estimation of its performance is required for planning and estimation of time and cost of the tunnelling projects. This performance prediction of TBM is a challenging geotechnical problem that is intricate and complex in nature, this is possibly due to the fact that TBM performance prediction involves understanding the rock fragmentation process in wide range from micro-scale (i.e. the interaction of surface of rock material and cutter tip) to macro-scale (including the interaction of rock mass and TBM). Thus in order for the performance prediction model to be efficient, parameters of both TBM specifications and ground conditions have to be considered. Various models have been proposed by researchers since the early phases of TBM application, these studies resulted in the development and improvement of numerous penetration prediction models. Most of these models consider the geotechnical parameters that are input to the model to be consistent along the TBM drive and neglect the uncertainties in parameters that occur. And so to improve the predictive capability of these models and to incorporate the above uncertainties, the penetration rate is modeled as a stochastic variable depending on the geotechnical and TBM parameters, its statistical distribution is determined and is used to characterize the penetration rate instead.

Jan 1, 2015

By Voyle R. McFarland, Robert A. Burmeister, David A. Stevenson

The distribution of lead between phases in the Ag-Sb-Te system was studied using microautoradio -graphy. Two compositions were investigated, both containing an intermediate phase Known as silver antimony telluride as the major phase, and one containing AgzTe and the other SbzTes as the minor phase. For both compositions, two thermal treatments were used: nonequilibrium solidification from the melt and long equilibration anneals of the as-solidified structure. For each composition, lead was segregated in the minor phase of the as-solidified structure, but was distributed in the matrix after anneal. The electrical resistivity and carrier type were insensitive to the distribution of lead in the two-phase structure. ThERE has been considerable interest in the Ag-Sb-Te system because of its thermoelectric properties. The major interest has been in compositions on the vertical section between AgzTe and SbzTes, particularly the 50 mole pct SbzTes composition AgSbTez (compositions are conveniently expressed as mole percent SbzTes along the AgzTe-SbzTes section). One of the major problems in the proper evaluation and utilization of this material is the inability to control the electrical properties through impurity additions: all alloys prepared to date have been p-type, even with the addition of large amounts of impurities. It has been shown Wit all the compositions previously studied contain an intermediate phase of the NaCl st'ructure as a major phase (denoted by b) and a second phase, either AgzTe or SbzTe3, as a minor phase.'-3 One explanation for the unusual electrical behavior of this material is that the impurity additions have a higher solubility in the second phase than in the matrix; the impurity would segregate to the second phase, leaving the bulk matrix essentially free of impurity.4 In order to investigate this mechanism with a specific impurity element, the distribution of lead between the two phases was determined using autoradiography. Lead 210 was chosen because of the suitability of its 0.029 mev 0 particle for autoradiography and also because of the interest in lead as an impurity in this system.5'6 EXPERIMENTAL PROCEDURE Two compositions were taken from the vertical section between AgzTe and SbzTes, 50 mole pet SbzTes (Viz. AgSbTez) and 75 mole pct SbzTes, in which AgzTe and SbzTes appear, respectively, as the minor phase. Lead containing radioactive lead (pb210) was added to the above compositions to provide a concentration of 0.1 wt pct Pb. The material was placed in a graphite crucible in a quartz tube which was then evacuated and sealed. The samples were melted and solidified by cooling at a rate of 8°C per min and then removed and prepared for microa~toradiography. After autoradiographic examination of these samples, they were again encapsulated and annealed in an isothermal bath at 300°C for a number of days and prepared for examination. An alternate method of preparation employed a zone-melting furnace; the molten zone traversed the sample at a rate of 1.2 cm per hr and the solid was maintained at a temperature of 500°C both before and after solidification. This treatment had the same effect as solidification at a slow rate followed by an anneal for several hours at 500°C. In order to obtain the best resolution, thin sections of the alloy were prepared by hand lapping to a thickness of approximately 20 p. Other samples were prepared for examination by lapping a flat surface on the bulk sample. The resolution, although somewhat better in the former procedure, was adequate in both instances and the majority of the samples were treated in the latter fashion. A piece of autoradiographic film (Kodak Experimental SP 764 Autoradiographic Permeable Base Safety Stripping Film) was stripped from its backing, care being taken to avoid fogging due to static-electrical discharge. A small amount of water was placed on the sample, the film applied emulsion side down on the surface of the sample, and the sample and the film dipped into water in order to assure smooth contact. After drying, the film was exposed for 2 to 5 days, the period of time selected to give the best resolution. The film was developed on the specimen and fixed and washed in place. Two major factors must be considered in establishing the reliability of an autoradiograph: the in-

Jan 1, 1964

By Daniel Martin

THE dendritic pattern of steels shown by deep etching is used exten-sively as a guide in the inspection and control of the great majority of steels used in ordnance construction and for many applications in indus-try. The value of macroexamination lies in the fact that it enables a qualified observer to make deductions concerning the general quality of relatively large pieces of metal. Not the least of these general character-istics is the nature and extent of the dendritic segregation in the steel, either in the cast condition or after mechanical or thermal treatments. PREVIOUS WORK Detailed methods for macroetching were outlined by Yatsevitch1 and have been standardized by the American Society for Testing Materials. A comprehensive study of the occurrence, origin, and the chemical and crystalline nature of the dendritic structure was given by Keshian.2 The marked persistence of dendritic segregation in nickel steels is fully recognized and has been discussed by Sauveur and Reed' and by others. Very little, however, has been written on the effect of the various elements on the macrostructure of steels, and the purpose of this report is to submit evidence concerning the influence of chromium, nickel and molybdenum on the macrostructure of some 4 by 4-in. ingots cast and treated under closely controlled conditions.

Jan 1, 1939

By Beech-Jones J. M

At Port Latta in Tasmania, Savage River Mines operates vertical shaft furnaces for the firing of pelletised magnetite concentrates. At times the temperature profile of the furnace has changed markedly, necessitating the- burning of greater quantities of fuel to maintain good pellet quality. A study of the oxidati=of magnetite concentrates was under- taken because this exothermic process supplies much of the heat required to indurate the pellets. Using the thermal analyses methods, different magnetite concentrates from Australian and overseas were heated in air under identical conditions, to compare rates of oxygen uptake and of heat release. In addition, a compari- son was made of the oxidation behaviour of different particle size fractions of a selected concentrate. Particle size analyses, x-ray diffraction and dilatometer tests were used to aid inter pretation of the thermal analysis traces. The investigation emphasized the importance of particle size and ferrous iron content in determining' oxidation rates from the commencement of heating.

Jan 1, 1974

By M. O. Lai

"Metal matrix composite (MMC) with composition of Al-4.Swt.%Cu reinforced by IOwt.%TiB2 or ISwt.%SiC particulate has been successfully fabricated using powder metallurgy technique. Disk, compression and beam specimens were prepared with (a) layered structure containing ductile Al-4.Swt.%Cu with brittle Al-4.Swt.%Cu/TiB2 or Al-4.Swt.%Cu/SiC layers, and (b) homogenous constituent with composition of Al-4.Swt.%Cu/lOwt.%TiB2' The specimens for the fracture toughness measurement were built through three ductile-brittle-ductile alternating layers. For the beam specimens, the layers were built through brittle-ductile-brittle sequence. The brittle layer consisted of Al-4.S%Cu with fixed amount of reinforcement. Fracture toughness testing revealed an increase for layered composites although the total amount of the reinforcement was the same for all disk specimens. The increase in fracture toughness is due to the existence of ductile layers which manifests a strong influence on delaying the occurrence of fracture. It acts as a barrier to resist the propagation of crack and hence increases the fracture toughness of the layered MMC specimens, Delamination in the beam specimens was observed to be due to shear stresses. Fracture surfaces of both disk, compress and beam specimens were characterized using the SEM. IntroductionMechanical and thermal properties can be achieved by the incorporation of refractory secondary phases to constrain the plastic flow of the matrix in a metal matrix composite (MMC). The size of the reinforcement particulate incorporated must be in the range larger than the dislocation cell size and strongly bonded to the matrix (I). Particulate reinforced metal matrix composites hence provide high modulus, improved wear resistance and strength (2-4). Because of the incorporation of refractory phases which are generally brittle, the major limitation in the mechanical properties of MMCs is their limited ductility in comparison to their base metals. Cracks normally initiate from the reinforcement and voids (4, 5). Due to the lack of ductility, cracks propagate rapidly with increase in load. As a result, the interactions between reinforcement particles and propagating cracks have recently been of great research interest (6). In addition, volume fraction of reinforcement and aging condition of the matrix significantly affect the mechanical behaviour of MMCs. In the case of AI-3.5%Cu reinforced with varying volume fractions of SiC particulate, it has been found that the probability of particle fracture increased with increasing volume fraction of reinforcement (7)."

Jan 1, 1996

By B. M. Larsen, T. E. Brower, J. W. Bain

A mass of circumstantial evidence is presented to indicate that the main source of alloy losses in open-hearth tapping is oxidation by air, with the steel apparently reacting with an amount of oxygen equivalent to about 30 times its own volume of air. The effect is erratic from heat to heat, depending largely on turbulence and distance of free fall of the stream of liquid metal. THIS paper reports another phase in a general study of oxidation in the open-hearth, various aspects of which have already been discussed in previous papers.1,2,3 It is based on experiments conducted on commercial, basic open-hearth furnaces at various times when opportunity offered, beginning about 1938, in an attempt to determine the mechanism and measure the amount of air oxidation during the flow of the tapping stream through the air into a ladle. This effect is closely connected, not only with alloy losses and control of chemical analysis, but possibly with various questions regarding inclusion content and steel quality and with a true picture of the deoxidation of steel in general. Thus it is believed that discussion of a large part of the results to date may be of assistance to others who are studying problems related to deoxidation or to steel cleanliness and quality. The literature reveals that strangely little attention has been devoted specifically to the effect of pouring steel through open air. Bardenheuer and Henke4 in 1939, in a paper devoted largely to overall losses of manganese in the basic open-hearth, reported that for a number of heats tapped into a tilted ladle held just beneath the runner so that the maximum distance of drop of the stream through the air was held to less than about 30 in., there was in most cases almost no loss of manganese from furnace to ladle. Hultgren,5 in 1945, showed that in high-carbon basic electric steel deoxidized in the furnace and containing no large inclusions as it left the furnace, large silicate inclusions, often rich in manganese oxide, were present in samples dipped from the pool in the ladle; also that the rise in content of large inclusions (above 0.01 mm dim) was greater when the metal stream was made to spray or flow in a turbulent manner. Our interest in this phase of oxidation in the open-hearth was first aroused by a study of alloy efficiencies on ladle additions. The frequency curves of manganese efficiency (net recovery of metal added in ladle) given in fig. 1 are of interest in this connection. Lowest, and also most variable (47 to 95 pct), recovery was in low-carbon heats having no coal additions to the ladle, progressing upward to a maximum average and least variable (82 to 97 pct) recovery in high-carbon heats killed with aluminum and silicon. Both coal additions and higher carbon contents in the tap stream, as well as additions of silicon and aluminum, help to lower the amount of manganese loss. But the most interesting point is the amount of manganese oxidized in many heats tapped at 0.50 to 1.06 pct carbon. It has been shown in a previous paper3 that the amount of oxygen in the tap stream in such heats is very small, usually below 0.01 pct, too small to oxidize any appreciable amount of manganese. Also, the fact that manganese should be oxidized at all in a metal solution containing such more stable oxide-forming elements as aluminum and silicon is an indication of some rather intense oxidizing effect such as could be caused by reaction with the air during ladle filling. Oxygen Balances from Tap Stream to Teeming Stream: Data in the form of alloy efficiencies, such as those shown in fig. 1, are not a proper measure of such a general oxidation effect. Having available

Jan 1, 1951

By Ramona Prillhofer

Salt slag is a waste product produced by the recycling of aluminum. In most European countries (e.g. Austria, Germany) the landfill disposal of this waste is forbidden because the slag contains soluble salts and these represent a potential source of pollution to the surface and groundwater. Additionally, consisting metal and some compounds in the salt slag can react with water and resulting from this, noxious gases are generated. The recovery of useful materials from these wastes is accordingly both environmentally necessary and economically feasible. This study describes a complete recycling-process for the salt slag, which includes a leaching-cristallization-process to obtain the oxidic residue, a pyrometallurgical-step to clear the oxidic residue and finally an extensive characterization of the achieved products. Due to the increasing price of raw materials, the utilization of the oxidic residue into commercial products has been investigated and application possibilities will be discussed.

Jan 1, 2009

By E. Turner

This is the 3rd Paper in a series by this author, the first two being published at the two previous International Conferences. Since the Aachen Conference, Rio Tinto has carried out an extensive benchmarking exercise to see how we are positioned with respect to other leading companies (in our sector and other sectors of major economic importance). We need to be sure that Rio Tinto is at the forefront of best practises in Sustainable Development (SD) and is using the most effective tools and methods. This paper will present key findings from this work. Rio Tinto Minerals, working as representatives of IMA-Europe was a leading contributor to the European Commission DG Enterprise Voluntary Reporting Scheme for SD Indicators in the Non-Energy Extractive Industry. In Rio Tinto Minerals we have been using these SDIs in the management of our business and the paper will report on how they contribute to the management of our business and the paper will report on how they contribute to business value in: deepening customer relationships, eco-efficiency of operations, land use planning and permitting for new and expanding facilities, community relations, policy engagement with government authorities and strengthening the bond between the company and employees. We continue to support the Voluntary SDI Reporting Scheme, considering it to be important in the expanding EU and as a model for other regions globally. For example we have ore suppliers in developing countries and we use these SDIs in assisting them to better their performance, for we have an obligation to use our influence for continuous improvement. The paper will describe this work. Over the last 12 months our company has created a new Industrial Minerals unit called Rio Tinto Minerals which brings together all the borates, talc and salt operations, R&D, marketing, sales and customer care worldwide. The paper will present also the new Sustainability Policy of Rio Tinto Minerals.

Jan 1, 2007

By Y. Wang

Arsenic-bearing acidic effluent from hydrometallurgical processes contains many harmful metal ions and must be appropriately treated before discharge. In the present study, arsenic, copper, zinc, aluminum, and magnesium were co-precipitated by means of the Fenton reaction. The precipitates obtained under different conditions were investigated to determine their stability. The results indicate that pH value and hydrogen peroxide (H2O2) dosage have significant effects on the removal of various elements. Arsenic, copper, zinc, and aluminum (but not magnesium) can be removed at pH 5–6 and anH2O2/As mole ratio of 2 at ambient temperature. The precipitates were mainly amorphous and granular with particle size in the micrometre range. The arsenic concentration in leachate from the toxicity characteristic leaching test was 3.6 mg/L, which proves that the precipitates are effective in fixing arsenic.

Aug 3, 2023

By P Crittenden

Thiess Pty LtdÆs Australian Mining business unit used 7.6 PJ of energy in the 2007/2008 financial year. This represented more than 85 per cent of Thiess Pty LtdÆs total energy use and therefore meant that the Australian Mining business unit is required to conduct energy efficiency assessments and report publicly on the outcomes by December 2008 under the Federal GovernmentÆs Energy Efficiency Opportunities (EEO) Act. Thiess Pty Ltd has a policy commitment to sustainable development throughout its operations. This includes minimisation of its carbon footprint and the Australian Mining business unit has a strong focus on efficiency in all of its operations. It approached the energy efficiency assessment as an opportunity to further improve and build on its energy efficiency and greenhouse gas reduction focus in the business. As a mine contractor, Thiess faced a number of challenges in designing an assessment process that would be both effective and efficient to deliver. For example, unlike most other companies involved in the Energy Efficiency Opportunities program, the energy use associated with the Australian Mining business unit is not fixed to any single geographic location in Australia. Mining vehicles are moved from site to site according to the specific requirements of mine owners and the timing associated with the commencement and completion of contracts. Thiess departed from a traditional æsite by siteÆ based assessment and designed a ærepresentative assessmentÆ approach that involved detailed investigation of data across all sites and a focused assessment on a single site.Data and analysis was an essential part of the assessment and indicators at company, mine and site level were essential in identifying opportunities and tracking progress. Forty-six potential energy saving opportunities were identified and four of these are currently being implemented. The projects being implemented are: payload management, automating mobile lighting equipment, plant idle time management, and turbo idle downtime. The potential savings from the four major projects that have been identified are approximately 150 800 GJ/annum, equivalent to 10 600 tonnes of CO2-e/annum with a simple payback period of less than two years. Beyond the fuel savings however, there are a number of other benefits from the assessment, including operational efficiency, reduced maintenance costs and even a potential reduction in the number of vehicles required to complete the work. The EEO assessment has significantly increased the importance and urgency of energy efficiency and facilitated the sharing of good practice across all Thiess operations. Not only have four projects been adopted for immediate implementation but a further pipeline of projects is available for future possible implementation. This case study describes: how Thiess conducted its assessment including the use of energy data and indicators, the opportunities identified that are currently being implemented, and the lessons learnt and how other organisations can use these to improve their approach to energy efficiency assessments. This case study is a more comprehensive version of a case study developed for the Commonwealth Department of Resources, Energy and Tourism. The assessment results reported in this case study are drawn from the Thiess Energy Efficiency Opportunities Report 2008.

Jan 1, 2009

Using a series-model of an automotive short range radar sensor (SRR) and a recently completed experimental radar system, field tests have been performed in a surface mine. It was examined, to what extent low-cost electronically scanning radar sensors can provide useful data for assistance systems on large scale mining machines. Simple sensors are useful for anti-collision safety zones or hopper car automation. The more complex and sophisticated experimental radar system using digital beam-forming can clearly detect and map the contours of trenches and slopes. The overall promising results refer to many more potential applications for electronically scanning radar in surface and underground mining as a reliable alternative to mechanical laser scanners.

Jan 1, 2007

By A. W. F. Smith, P. B. Prangnell, D. N. Crowther, P. J. Apps

It is well known that the refinement of grain size in metals leads to a significant improvement in important mechanical properties. As part of a European collaborative project, processing schedules have been investigated aimed at producing a homogeneous ultra-fine ferrite and spheroidised carbide aggregate microstructure structure in high carbon (CMn) steels (0.6-1.2wt%C), via conventional 'warm' rolling and innovative Equal Channel Angular Extrusion (ECAE). Suitable deformation schedules were determined from dilatometry and thermo-mechanical Gleeble simulations. Evidence of an ultra-fine ferrite and carbide aggregate microstructure following 'warm' rolling is given. A significant improvement in tensile strength, particularly proof stress (0.2%) was also noted in comparison to material deformed at higher temperatures. Concurrent Equal Channel Angular Extrusion (ECAE) experiments investigated microstructural evolution with incremental strain. Extensive analysis was carried out using various techniques, including high resolution Electron Back Scattered Diffraction (EBSD). Evidence of ferrite grain refinement was noted in a eutectoid composition steel. A sub-micron ferrite structure was observed following high strains (E-3.33) and the mechanical properties exhibit a marked increase in tensile strength.

Jan 1, 2004

By B. A. Filas

Stabilizing fine coal refuse ponds for reclamation at Monterey Coal Company's No. 1 Mine has been difficult. Entrained water in the stored refuse causes liquefaction as reclamation caps are placed, resulting in additional material requirements than originally projected to stabilize the pond surface. Laboratory results indicate that in-place refuse densities may be substantially improved at No. I Mine by converting from a single-point to a managed slurry distribution system. Increased densities result in improved storage efficiency, less entrained moisture and a more stable refuse mass, thereby providing an improved working surface for reclamation and improved post-closure cover stability.

Jan 1, 1993

By A. V. Kurkov

The secondary action reagents (SAR) are organic diphilic compounds capable of altering ac-id-base and donor-acceptor properties of the main collector and consequently the energy of collector interaction with the mineral?s surface, its hardness and fixation forms ratio through associates formation via the hydrogen bonds. When the basic flotation conditions are being established, convergence of the electronic structure of the collector and the mineral being extracted due to minerals surface preconditioning with modifiers and the most efficient collector choice. At the next stage of the selective flotation condition establishment SAR is selected for a more precise adjustment of the energy of the collector fixation on the mineral. Such an approach makes it possible to solve efficiently various issues of flotation separation of non-sulfide minerals. In particular neutral organic substances containing groupings C==O, S==O, P==O (ethers of carboxylic and phosphonic acids, amides of carboxylic, phosphonic and sulfonic acids) were proposed as SAR. In order to enhance the flotation process selectivity in the conditions of water recycling including the selectivity of carboxylic collectors especially in the environment of high hardness water flotation, it was proposed to use SAR with long hydrocarbonic radical and groups with enhanced electronic density within the molecule: N-methylolamides of alkylphosphoric acids and ethers of methylphosphonic acid. Introduction of small amounts of these compounds alongside with the main fatty-acid collector enhance the performance of fatty-acid flotation of fluorite, beryl, columbite etc., lowers the collector consumption, and completely compensates the depressive effect of recycled water. Di-2-ethylhexyl ether of methylphosphonic acid?CH3P(O)(OC8H17-i)2 (hexarane) was more thoroughly researched as such an agent within fatty-acid flotation process. Following aspects of the flotation system were studied: interaction of oleic acid and sodium oleate with hexarane in the liquid phase (infrared spectroscopy); heat emission under the interaction of hexarane-oleic acid ? sodium oleate ? calcium salts (isoperiboric diathermic colorimeter); colloid-disperse state of the collector influenced by hexarane (nephelometric analysis); dynamics of the mineral surface hydration due to the agents (method of indicator negative adsorption); hexarane effect upon the interaction of fat-ty-acid collector with calcium salts (complexometric method with Trilon-B); floatability of pure minerals (quartz, microcline, beryl, columbite) in Hallimond tube; hexarane effect upon oleic acid (sodium oleate) adsorption (nephelometric method for identification of the residual content of oleic acid and its forms within the solution). Upon the research it can be definitely concluded that the adjusting effect of such compounds as hexarane within the non-sulfide minerals flotation process is mainly determined by their interaction with the main collector both within the pulp and at the mineral surface with associates formation due to the hydrogen bond. The consequence is calcium oleates destruction with the release of the most active collector under flotation in hard water environment which determines the efficiency of hexarane joint application with fatty-acid collector under recycled water supply. Therefore the introduction of the class of secondary action reagents is supported by their operation mechanisms and flotation process function and determines a new approach to the development of efficient conditions of selective flotation separation of non-sulfide minerals.

Jan 1, 2014

By Thomas W. McClain

This paper describes the importance of considering ground control measures when importing U.S. continuous mining technology in foreign countries. Important ground control factors are discussed. Each year the USA exports a significant amount of continuous miner equipment (i.e. continuous miners, roof bolters, coal haulers, shuttle cars, continuous haulages, scoops and feeder-breakers). International customers see the opportunity to significantly improve their productivity and increase their longwall gateroad development rates by implementing the room-and-pillar (place changing) mining systems used throughout the USA. However, a number of issues are often overlooked or not thoroughly evaluated when selecting the equipment, often resulting in lower than expected productivity. Ground control is one of the critical factors that must be addressed. Since 1993, the author has assisted numerous international customers and manufacturers with implementing or improving the performance of continuous miner and room-and-pillar systems in Australia, India, Mexico, South Africa, and the United Kingdom. An essential first step is to conduct a thorough ground control study, and then integrate its findings into mine layout, equipment selection and section operating plans. Based on actual case histories, the author will present a number of examples and "Do's and Don'ts." Another key to success is the involvement of manufacturers and suppliers with customers when implementing new systems and technology. The importance of allowing for cultural evolution by both management and workers for acceptance and successful implementation of any new system is also discussed. Over the past ten years, the global coal industry has gone through some very dramatic changes. Countries that previously experienced a freight advantage, such as Australia shipping coal to Japan and Korea versus the United States, are finding they are now in a world coal market similar to other commodities and products. Today, coal prices arc stated F.O.B. at the consumer, and the origin is often irrelevant. Also, previously state-run coal industries have been privatized, such as the United Kingdom, and others such as Poland and India are currently going through the same transition from state-run to the private sector. In all cases, the key to continued viability, or survival, depends largely on reducing costs in order to compete for a market share. Two ways exist to reduce costs. First, almost everyone tries to reduce expenditures. Depending on the circumstances at a given mine or in a specific country, this helps to some point. However, most find that secondly, production must be increased to achieve the necessary cost reductions to compete in today's global coal market. As a result, over the past ten years, foreign companies and countries have looked to the USA for new mining methods and systems to significantly increase productivity. Thus, a major portion of American equipment manufacturers and suppliers sales have been exports, which has played a major role in helping to "keep-the-doors-open" for a number of companies through the lean 1990's, when American coal companies were postponing capital expenditures and expansions. As foreign companies and countries have looked to the USA for ways to improve productivity, they have become particularly interested in continuous miner equipment systems and most often "room-and-pillar," "bord-and-pillar" or "place changing" mining systems for four reasons. First, in countries such as the United Kingdom and Germany, who have been longwall mining for generations, there remain numerous remnant small pockets of reserves in existing mines that are either too small or too difficult to longwall mine, and are conducive to the flexibility of continuous miner systems. Second, for countries such as Australia, who have experienced the constant problem of developing longwall gateroads in a timely manner to avoid longwall move delays, new or alternate methods are required. Third, companies and countries using roadheader machines on coal production are recognizing the increased productivity potential of continuous miner equipment. Fourth, countries such as South Africa and India, where a substantial amount of the production comes from conventional mining methods, "drill-and-blast", companies are recognizing the opportunity to improve by implementing continuous miner technology. Colliers & Associates, Inc. has found that over the past eight years too often foreign companies or countries purchase American continuous miner equipment without first conducting a thorough geologic, geotechnical and ground control study for the reserves to be mined. The problems are compounded by not developing mine plans, and submitting them to the regulatory authorities for approval prior to purchasing and even implementing the equipment.

Jan 1, 2001

By Charles K. Presley

This paper deals with drilling large diameter shafts for the mining and construction industry with diameters in excess of 3 feet to more than 20 feet in diameter. It discusses appropriate applications of the rotary drill method, linings for large diameter shafts, circulation systems,, and the limitations of the method. Each specific rotary drill method is determined by the geology of the area, the depth to be drilled and the formation fluids encountered. Shaft lining or casing must be improved to result in lighter weight, higher strength and lower cost. All phases of rotary drilling equipment must be improved to drill shafts in excess of 10 feet in diameter. As these goals are reached, more shafts of large diameter will be drilled by the rotary method for the mining and construction industry.

Jan 1, 1967