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By M. I. Kalashnikova, Y. M. Shneerson, E. E. Zhmarin, Y. V. Degtiarev, E. M. Vigdorchik

Separation of a magnetic fraction from nickel concentrate following matte flotation, and its treatment in a separate circuit enable reduces precious metals losses. The magnetic fraction is treated in two stages of oxidative leaching: atmospheric and pressure leaching. A study of the atmospheric stage, using mathematical modelling, is described in this paper. The mathematical model and experimental data were used to carry out industrial process calculations. The model enabled extrapolation of the results of batch laboratory test to industrial-scale continuous processing and the selection of optimal process conditions and large-scale equipment. In December 2004, commercial oxidative leaching tests were performed on the magnetic fraction at the Severonickel Plant (Monchegorsk, Russia). A comparative analysis of the mathematical modelling results and the actual process parameters is presented.

Jan 1, 2005

By R. H. Matjie, J. R. Bunt, A. C. Collins, J. C. van Dyk, C. A. Strydom

South African discard coal fines and K₂CO₃ blends were heated in a laboratory-scale rotary kiln to produce ashes for H₂SO₄ leaching tests. The optimized H₂SO₄ leaching conditions of 6.12 mol.dm³ (M) H₂SO₄, solid to liquid ratios 1:5 and 1:10, and 80°C for 8 hours were used. K₂CO₃ was added to increase the dissolution efficiency of K. The objective was to determine if the Al present in metakaolinite (Al₂O₃.2SiO₂), the Al, K, and Ti in the alumino-silicate glasses, and the Ti in rutile (TiO₂) in the ashes could be selectively dissolved in H₂SO₄. XRF results show that the ashes formed at 700°C dissolved more efficiently (87% Al, 89% K and 23% Ti) compared to the ashes formed at 1050°C. This can be attributed to the presence of Al₂O₃.2SiO₂, K₂CO₃ melt, K₂CO₃ remnants, KAl(SO₄)₂, and K-aluminosilicate glass in these ashes. XRD results indicate that the ashes prepared at 1050°C contained anorthite (CaAl₂Si₂O₈), microcline (KAlSi₃O₈), pseudomullite (Al₂O₃.SiO₂), and silicon spinel (2Al₂O₃.3SiO₂), which are either insoluble or only sparingly soluble in H₂SO₄. These minerals resulted in the lower dissolution efficiencies of Al and K. Based on the high dissolution efficiencies of Al and K for the ashes produced at 700°C, coal fines blended with K₂CO₃ could possibly be utilized as feedstocks for the production of aluminium(III), potassium(I), and titanium(IV) and a sulphate-containing leach liquor. Furthermore, the environmental issues and costs associated with the handling and disposal of large volumes of coal fines will also be resolved.

Aug 2, 2022

By Raja V. Ramani

The potential usefulnuss of reclaimed surface-mined land has received much attention in recent times. This attention is partially due to the establishment of federal environmental reclamation standards but concern for achieving better land uses has also been shown by interested members of the mining industry. In an effort to develop a procedure for evaluating postmining land use potentials, specific mines in various regions of the U. S. were studied to determine the extent of current mined-land planning and to discover characteristics that are regional in nature. As part of this investigation, a 430-acre surface mine in Clear-field County, Pennsylvania has been studied. Established site planning principles have been applied to the case study site including formation of a data base, development of alternate land use plans, and evaluation of the economic, environmental, and social impacts of the land use alternatives. Key factors affecting site realization have been identified along with positive suggestions for applying land use planning processes to mined-land planning.

Jan 1, 1983

By G. Kugler, M. Tercelj

"The 1.2690 high alloyed tool steel is usually applied for cold working and is alloyed with carbide-forming elements Cr, V, W and Mo. It exhibits very poor hot deformability. Since there is no enough available data in literature for elucidation of this problem, hot workability and development of microstructure during hot deformation was studied. Hot compression tests were carried out in temperature range 850-1150 °C and strain rates range 0.001-6 s-1. SEM and OM were used for observation of microstructure. Results revealed very complex precipitation of carbides that depends on deformation temperature as well as on strain rate. It was found that especially at lower temperatures of hot working range the precipitation of carbides strongly depends on strain rate. Three different hot deformation behaviors’ were observed depending on temperature and strain rate range.IntroductionThe hot workability of highly alloyed high speed steels is usually described as relatively poor in comparison to other steels due to their tendency of cracking during hot working especially when inappropriate hot working conditions are applied. Alloying elements such as Cr, W, Mo and V in ledeburitic tool steels form carbides that improve hardenability, strength, hardness, wear resistance, etc., but they decrease hot workability and narrow hot working temperature range in comparison to conventional steels. The size, distribution, type and fraction of carbides, as well as the thermomechanical history of material and hot working parameters have major influence on the hot workability. The microstructure of ledeburitic tool steels during hot deformation can be characterized as a two-phase system consisting of an austenite matrix and a combination of ledeburitic carbides [1-4]. In the soft-annealed condition the total volume fraction of carbides is in the range 19-30% and in the quenched condition in the range 9-25%, depending on the chemical composition. During heating before deformation a large quantity of carbides dissolve, but non-dissolved carbides can have an extremely diverse influence on the hot workability due to variations in their composition, size, distribution, hardness and shape, and their different behavior during the deformation phase [5-7]."

Jan 1, 2011

By K. Gonçalves

One of Vale?s sponsored research project is aimed at the implementation of a practical scale-up procedure for flotation. In this context, detailed flotation kinetics characterization is of critical importance. This work presents the results of a campaign aimed at characterizing flotation kinetic parameters with respect to particle composition. MLA analysis was carried out for 40 narrow-sized iron ore particles with known flotation time from a controlled flotation kinetic test. The iron ore sample studied (59% hematite and 41% quartz) comes from a mine in the southeast of Brazil and the type of reagents applied are the same as used in the plant. For the reagent conditions tested, the overall rougher concentrate (sink) yielded 79.1%, pure quartz and hematite recoveries to the froth were 56.0% and 4.8%, respectively. The results from the kinetic tests show that the flotation rate of the particles doesn?t vary much (~0.03s-1) with composition and that the fraction of floatable particles in each grade controls the separation action. The results show that the rate of flotation is controlled by transport and that the selectivity is controlled by the fraction of floatable particle of each phase.

Sep 1, 2012

By R. E. Boni, G. Derge

Application of surface tension measurements has been made to molten silicates in order to determine the effect of sulphur upon the surface tensions of synthetic blast furnace slags. In melts with the same molar ratios of AI2O3 + SiO2 to the basic oxides BaO, CaO, and MgO, the surface tensions increase in the order of oxides listed. Sulphur lowers the surface tensions of the basic BaO, basic CaO, acid BaO, acid CaO, and acid MgO slags in that order; and the concentration of excess sulphur at the slag surface increases in this same order of slags. The rate and amount of desulphurization of iron by these slags is favored by a low excess surface sulphur in the slag. IN a previous paper,1 the authors discussed the applications of surface tension measurements of molten silicates to problems of metallurgical interest. Of major importance is the aid that such studies lend to forming a working concept of slag structure. Since the ability of a slag to desulphurize metal depends strongly upon its composition,2"4 fundamental information about the structural differences between various slags which contain sulphur should aid the development of better desulphurizing media. For that reason, the present investigation concerns the effect of sulphur upon the surface tensions of synthetic blast furnace slags. Experimental Procedure , The maximum bubble-pressure method was used to measure the surface tensions of synthetic blast furnace slags in the temperature range 1300° to 1600°C. The method is based upon the equation which was developed by Schrödinger5 from a consideration of the forces of hydrostatic pressure and surface tension of a liquid which oppose bubble formation when a gas is forced through a tube immersed in the liquid. where y is the surface tension between argon and slag in dynes per centimeter; g is the gravitational constant, centimeters per second2; H is the manometer reading in centimeters; s2 is the density of manometer fluid in grams per cubic centimeter; S1 is the density of the medium in grams per cubic

Jan 1, 1957

By K. S. Raja, B. McNall, B. Pesic

"High-level radioactive wastes are stored in large underground storage tanks made of low-carbon steel. The wastes consist of concentrated solutions of sodium nitrate (NaNO3) and sodium hydroxide (NaOH), and the radionuclides 137Cs, 99Tc, and 90Sr. The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV), which in turn modifies the kinetics of corrosion of the storage tank. To understand the influence of technetate ions on the corrosion of steel, electrochemical polarization studies of A 537 steel samples were carried out in 1 M NaNO3 + 0 .05 M S r(NO3)2 + 0.1 M NaOH with and without addition of HReO4 at different temperatures (24 – 85 °C). The concentration of HReO4 was varied from 0.014 – 0.04 M.INTRODUCTIONAqueous processing of spent nuclear materials generates a large amount of high-level radioactive wastes. The wastes are primarily salt solutions of sodium hydroxide and sodium nitrate which also contain fission products such as 137Cs, 99Tc, and 90Sr. Among the high level radioactive fission products, Tc-99 is of great importance because of its high concentration, long half-life (2.1 x 105 years), high solubility in geologic waters as technetate, and rapid diffusivity through the geologic systems. The solubility of technetate ions varies depending on the oxidizing conditions prevailing in the storage containers. High level radioactive wastes are stored in single shell or double shell tanks made of low carbon steels such as ASTM type A15, A516-70 and A537. Most of the available literature on corrosion of steel in simulated radio active waste environments pertains to nitrate induced stress corrosion cracking (Subramanian & Mickalonis, 2005). The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV). Corrosion of steel and formation of Fe(II) and Fe(III) will affect adsorption and reduction of Tc species. The radioactive species can irreversibly be sorbed on the steel surface by oxidation of Fe(II) to more stable Fe(III) and fixed as less soluble Tc(IV)/Fe(III). The solubility of Tc species is also affected by other factors such as dissolved oxygen, local pH, temperature etc. How the corrosion behavior of steel will be affected in the presence of Tc species is not clearly understood.Cartledge (Cartledge, 1960) demonstrated that passivation of iron can be achieved in the presence of oxygen along with suitable inhibitor ions/molecules of the general formula XO4 n-, such as pertechnetate (TcO4 -). The pertechnetate ion is univalent. Since it is derived from a strong acid, no buffering action can be expected from this ion. The redox potential of the reaction (1) is 0.738 VSHE (Pourbaix, 1974)."

Jan 1, 2012

By Dewa Putu Agus Sudarmaja, Widi Astuti, Januarti Jaya Eka Putri, Yayat Iman Supriyatna, Himawan Tri Bayu Murti Petrus, I Wayan Warmada, Siti Nurul Aisyiyah Jenie, Ferian Anggara, Anisa Maulidia, Vincent Sutresno Hadi Sujoto, Sutijan

With the rapid development of renewable energy technology, such as electricity reserves, to store energy for electric or electric vehicles, environmentally friendly energy sources are expected to continue to be fulfilled according to mobility and stationary energy needs. Lithium is the most attractive candidate for energy storage development. The presence of lithium in Indonesia in the Sidoarjo mud content is interesting to be used as an alternative source of raw materials. During the research, sulfuric acid acted as a solvent, and hydrogen peroxide acted as an oxidation agent. Lithium recovery will be studied using a leaching process at various temperatures (30, 45, and 60 °C) and sulfuric acid concentrations (0.5, 1, 2, 3, 4, and 6 mol/L). The increasing temperature, sulfuric acid concentration, and hydrogen peroxide concentration will directly affect the lithium recovery. An increase in sulfuric acid concentration will be directly proportional to the recovery of lithium in the solution. Optimum conditions were obtained at varying 6 mol/L sulfuric acid concentrations and 60 °C temperature variations. The shrinking core model (SCM) studied leaching kinetics, and ash layer diffusion acted as a rate-controlling process. The activation energy of the leaching process was obtained at 38.90 kJ/mol.

Jul 25, 2023

By P. A. Korpi

The angular spiral lining system reduces energy consumption and grinding media consumption in grate discharge ball mills. This paper discusses the effect of this lining system on mill product size distribution. Performance comparisons of a grinding circuit outfitted with angular spiral liners in the ball mills are made with respect to standard double-wave liner installations. The angular spiral lining system was developed by Waagner-Biro of Austria. The installation of this lining system at Magma Copper Company, San Manuel, Arizona, is the first of its kind in a grate discharge ball mill used for wet grinding.

Jan 1, 1979

By Thomas A. Printz

The wide use of carbon steel in construction and engineering projects makes this engineering material accountable for approximately 85% of the total annual steel production worldwide. Despite the lack of corrosion resistance of carbon steel, it is incorporated into the permanent work for marine applications, power plants, transportation projects, chemical processing, mining, petroleum production and refining, pipelines, mining and construction equipment. Corrosion is an electro-chemical process that occurs in the presence of water and air. When an electric current is introduced to water or soil, the rate of carbon steel corrosion increases rapidly. Gaseous atmospheric constituents that are capable of electrolytic activity can also increase the rate of corrosion. Corrosion tends to be more rapid in environments in which the steel is exposed to water, and then air, rather than being constantly submerged. The exposure to seawater increases steel pitting because the electrical conductivity is improved in salt water.

Jan 1, 2013

By A Purwodihardjo

Evaluation of the construction method used for the pedestrian underpass construction at Ipswich Road, Brisbane, Australia is presented in this paper. The pedestrian underpass was constructed through the existing railway embankment between Harrogate and O’Keefe Streets on the eastern side of Ipswich Road. This underpass construction is part of the CLEM7 tunnel project (formerly known as the North-South Bypass Tunnel) which is the longest toll road in Australia at a total length of 6.8 km. The jacked box construction technique was initially identified as a preferred option during the tender and concept design phases. However at the final design stage, the cut and cover technique was selected as this method can reduce the construction time and cost significantly. The design and construction teams effectively managed the challenges, complexities and risks associated with undertaking cut and cover tunnel through the existing heavily utilised rail embankment. The on-site construction time for the underpass using the cut and cover technique was reduced to less than 42 hours.

Mar 8, 2011

Since 2001, the Hybrid Stress Blast Model (HSBM) project members have developed a software suite to model the complete blasting process from non-ideal detonation to muck pile formation. To preserve the physics and improve solution time, the breakage engine uses a combination of analytical models and 2D axisym-metric finite differences to model near-field crushing, coupled to 3D discrete lattice fracturing and distinct element numerical methods to model throw and muck pile development. The model has been validated by comparison with laboratory and field tests in kimberlite. Multiple blasthole simulations are used to demonstrate how changes to blasting parameters can influence downstream efficiencies. Case studies of wall control blasting show that the presplit design must balance the two opposing effects of increased damage with increased charge and decreasing attenuation of the seismic waves with decreasing charge. Modelling of decoupled explosives needs further development. Reducing the charge towards the back of the trim blast results in a much more significant decrease in back damage than altering the timing. The model demonstrates how separation along the weaker planes in a jointed rock can coarsen the fragmentation, leading to inefficient beneficiation, and extends the damage to a distance of at least twice the burden behind from the blasthole, severely compromising the wall stability.

Jan 1, 2012

By J. Desrosiers

"Minnova Inc. has five operating divisions thoughout Canada. One of them is Lac Dufault which was established in 1964.Lac Dufault is located 15 km north of Rouyn-Noranda, in what is known as Noranda volcanic centre, in northwestern Quebec. For more than 25 years, Lac Dufault has produced copper, zinc, gold and silver from four different mines: Norbec, Millenbach, Corbet and now Ansil.Ansil, officially in production since July 1989, is one of the deepest mines presently in production in Quebec. This high-grade copper, gold, zinc and silver orebody is being mined at a rate of 1200 tonnes per day with a total workforce of 200 employees.Of particular interest are the high mechanization level of the underground mine, technical innovations also underground, and computer applications throughout the division.IntroductionMinnova Inc. was formerly known as Corporation Falconbridge Copper until 50% of its shares were bought by Kerr Addison Mines Ltd . in 1986 and it became a member of Noranda Group of Companies.Minnova stands for mining innovation. It means Minnovaaims to use state-of-the-art technologies in mining and exploration to achieve maximum efficiency and cost effectiveness. It also means that they aim to use both proven and innovative management principles to the optimum benefit of their employees and shareholders. Minnova has operations across Canada. Presently four mining divisions produce copper, zinc, gold, silver and lead. Two are situated in Quebec: Lac Dufault (established in 1964) and Lac Shortt (established in 1985); one in Ontario; Winston Lake (established in 1988); and one in British Columbia; Samatosum (established in 1989).Minnova has an annual exploration budget of $15 million divided 60/40 between base metals and precious metals. Most of Minnova's exploration efforts are concentrated around their existing mines. Exploration is carried out from six regional offices located at Rouyn-Noranda and Chapais in Quebec; Thunder Bay in Ontario, Vancouver in British Columbia, Reno, Nevada in the United State and Panama City Panama. Each of the Canadian offices maintains close liaison with nearby operations.Lac Dufault Division is located in the Noranda mining camp, approximately 15 km north of the city of Rouyn-Noranda, in northwestern Quebec (Fig . 1)."

Jan 1, 1991

By Rodney R. Koch

The phys ica l properties of gold should faci li tate its detection. However, the average concentration of gold in the ea rth's cru st precl udes the ability of geophys ical methods to detect the metal directly. In order to effectively pursue geophys ical detection and location of gold mineralization there must also be geological input - i.e. a model. This will lead to the selection of the appropriate geophy ical techn ique(s) in the fo llow-up programs. Interpretation of the fie ld survey data is of con iderable importance in expl oration geophys ics. Analytical techniques such as cont inuation, fi ltering, and spectral analys is, are now routinely empl oyed in the analys is of survey data to aid the interpretation process. The uccessful application of geophysical methods and the use processing techniques is demonstrated by two recent Saskatchewan discoveries. The first, the Star Lake 21 Zone, with reserves of 230,000 tons grading bener than 17.14 git Au associated with a disseminated sulphide quartz-bearing shear zone yielded geophysical anomalies that were distinctive, obvious, and would have lead directly to its discovery. The econd , the Laurel Lake Prospect, with ore grade intersections of 28.0I git Au and 52 .46 git Ag· over 5.49 m, resulted in numerous geophysical anomalies. However, none of these anomalies demonstrated association with the mineralization until processed results indicated that structural features crosscuning regional trends were important cont rol mechanisms for the mineral ization.

Jan 1, 1986

By L. E. Mordberg, E. N. Nesterova

Geochemical studies of the bauxite deposits show that the primary composition is gibbsitic. Some trace elements were relatively mobile during bauxite formation with the content of Th, U and Zr increasing and that of Rb, Ni and Co decreasing. Y and Pb were relatively immobile during lateritisation; their contents and ratios were inherited from different types of underlying rocks. The supply of Ni and Co took place at the diagenetic or epigenetic stages; their ultimate source was the crystalline basement in the region. The studies support the view that the bauxite was likely to have originated as a result of in-situ lateritisation and not through sedimentary transport and redeposition

Jun 18, 1905

By D. K. Chibwe, P. Taskinen

"Typical operation of industrial Peirce-Smith converters (PSCs) used in copper smelting results in several common phenomena such as excessive splashing, slopping, tuyere blockage, and low converter campaign life due to high tuyere line refractory erosion. These phenomena give rise to an inefficient operation from both a process and an energy perspective.This investigation presents numerical and physical models of flow patterns, mixing, solid-liquid mass transfer, and slag-matte phase distribution in a slice model of an industrial PSC. For physical simulations, a 0.2-scale cold model was developed. Water, kerosene, air, and sintered benzoic acid compacts were used to simulate matte, slag, injected gas, and solid additions into the PSC. The two- and three-dimensional numerical simulations of the three-phase system were carried out using volume of fluid (VOF) and realizable k- e (RKE) turbulence models to account for the multiphase and turbulence nature of the flow respectively. These models were implemented using the commercial computational fluid dynamics numerical code FLUENT.Both numerical and physical simulations were able to predict, in agreement, the mixing and dispersion characteristics of the system in relation to various blowing conditions employed in the investigation. Measurement of mass transfer characteristics conclusively indicated that fluid flow in the PSC is stratified. Both blowing configuration and volume of slag in the converters were found to have significant effects on mixing propagation, wave formation, and splashing.The splashing and wave motion in these converters are known to cause losses of metal/matte and potential production time due to the requirement for intermittent cleaning of the converter mouth, resulting in reduced process throughput. To prevent these losses and hence to increase process efficiency, we propose a combined blowing configuration using top lance and lateral nozzles. The numerical simulations were conducted on combined, as well as lateral, blowing conditions. In comparison, the recent results of the combined blowing concept were found to be encouraging."

Jan 1, 2014

By L. T. Matthews, C. E. Loo

During sintering, porous ore particles are easily assimilated by liquid melt. Two simple models of the process are considered: the dissolution of a solid by a liquid and the penetration of a liquid into a porous solid. Laboratory sintering studies covering a range of experimental conditions were undertaken to characterise the assimilation of large particles of ore and flux by melts formed from different mixes of fines. For ores, the process appeared to be complicated by the detachment of fines from the ore surface prior to melt formation, according to the mass of adhering fines and surface roughness of the particle. This delayed the onset of assimilation and sometimes reduced it, although melt penetration was fast and effective. Studies using different temperature profiles suggested that the assimilation of haematite was controlled by the transport of Fe2O3 away from the surface of ore particles. The assimilation of limestone depended more on thermal conditions than on the three magnesia-bearing minerals considered. Changing the composition of the initial melt significantly altered the extent of assimilation of ores and limestone, but again had a less marked effect on the magnesia-bearing fluxes.

Jan 8, 1992

By Tasuma Suzuki

Electrokinetic/permeable reactive barrier system is a promising in situ soil and ground water remediation technique to reduce toxic NO3- into less toxic NH4+. Using granular zero-valent iron (Fe0) as a reductant, the first objective of this study was to investigate the influence of the solid-liquid ratio and aqueouspHon NO3- reduction. The results obtained from a series of batch experiments showed that NO3- reduction was enhanced by either increasing solid-liquid ratio or decreasing aqueous pH. Based on insights obtained from batch experiments, the second objective of this study was set to design the remediation conditions of the electrokinetic/Fe0permeable reactive barrier system to maximize the NO3- reduction efficiency. Experimental results showed that the effectiveness of the system strongly depended on the Fe0 percentage in the reactive barrier, the pH in the anode reservoir, and the applied voltage, which were consistent with the results obtained from batch experiments. Under optimized treatment conditions, nearly 100 % NO3-was reduced into NH4+ in the permeable reactive barrier and collected in the cathode reservoir. Insights obtained from this study provided fundamental information on roles each of remediation design parameters plays, and will be useful to optimize the remediation conditions. Keywords: electrokinetic remediation, permeable reactive barrier, zero-valent iron, nitrate

Sep 1, 2012

By L. E. Mylting

Modern ash handling systems exist in considerable numbers and a great deal of design and operating experience has been accumulated, It is the endeavor of this paper to point to a number of frequently recurring problems, A general appreciation of these problems will be helpful in both design and operation of systems. The light fly ash and the heavy bottom ash present different problems, and each will therefore be treated separately. Fly ash is collected in the ducting from the furnace to the stack and beneath the mechanical and electrostatic dust collectors. The greatest amount of dust is collected beneath the mechanicals and electrostatics. Hoppers are generally provided as integral parts of the collector. Suitable valves and piping are connected to these hoppers for removal of the dust. The size and shape of these hoppers are important factors in determining frequency of handling and the capacity of the system.

Jan 1, 1958

By B BussiFre, J Molson, M Aubertin, G W. Wils

Waste rock piles containing reactive sulfide minerals can serve as long-term sources of acid mine drainage (AMD). Within these piles, many physical, geochemical and biological processes can contribute to the production of AMD. The flow of water, for example, depends on internal pile structure, which depends on the dumping methods used to construct the pile. In this paper, the internal structure and grain size distribution of typical waste rock piles are first reviewed with respect to their effect on internal water flow. A numerical model is then applied to simulate unsaturated flow within a waste pile assuming two primary waste materials, different atmospheric conditions and several geometric configurations. The simulations suggest that water movement can be controlled by introducing fine-grained material layers within the coarser host material. However, these layers should not be horizontal because they can lead to localised high-saturation regions as well as preferential flow favouring the production of AMD. A shallow slope towards the pile boundary may be introduced to force drainage to the outside while maintaining low saturation within the interior, thus reducing the production of AMD.

Jan 1, 2003