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By A. Kaufmann, B. Cullity, G. Bitsianes

T0 determine the bulk of the phase diagram, techniques for melting, thermal analysis, heat treatment, metallography, and X-ray diffraction that have already been described were used.' It proved difficult to get definitive results for most of the alloy system because of the large number of compounds, their high melting points, and their extreme brittle-ness which made metallography difficult. The final phase diagram, essentially as shown in Fig. 1, was issued with considerable trepidation.' The phase relationships at the two ends of the system were defined with satisfactory accuracy. In the central region between U,Si, and USi, there was great uncertainty concerning the melting points and even the composition of the compounds. At the uranium end of the system, it is quite clear that a eutectic exists at about 985 °C and approximately 8 or 9 atomic pct Si. The a-to-8 transformation is not appreciably altered by silicon, but the 8-to-y transformation is raised to about 795°C. There is appreciable solid solubility in y-uranium, as demonstrated by the micrographs of Fig. 2. The occurrence of the E phase was not suspected at first, since the alloys as melted and furnace cooled gave no X-ray diffraction or thermal arrest indication of it. However, suitable metallography revealed a rim around each of the compound particles as shown in Fig. 3. Heat treatment above 600°C revealed that the rim was another phase which formed by peritectoid reaction between uranium and U,Si,. This reaction proceeds slowly and it is difficult to get it to go to completion. Consequently, there is some uncertainty concerning the exact composition of P and the exact peritectoid temperature. On the basis of various metallurgical studies, it was decided that the most probable composition for t was about 23 atomic pct Si. Metallographic examination shows the closest approach to a single phase at this composition. Likewise, density and hardness measurements of heat-treated alloys shown in Figs. 9 and 10 show a change in slope at 23 pct Si. This is revealed most clearly by plotting the difference in hardness or density between chill-cast and heat- treated alloys as shown in Fig. 4. Zachariasen2 was able to index the diffraction lines of P and to determine the arrangement of the atoms in the unit cell. He concluded that the composition must be US. However, it is felt that the metallurgical studies are reliable and that Zachariasen's X-ray work does not furnish positive proof that the P phase exists exactly at the stoichiometric composition U3Si. There are many instances in alloy systems where a phase does not occur at the composition dictated by the molecular structure. It is possible that the chemical analyses used in the present work were subject to some systematic error. This seems unlikely, however, since recent work in several laboratories seems to show excess compound at 25 atomic pct Si.

Jan 1, 1958

By Laurance L. Oden, Jack C. White, Alan D. Hartman

The U.S. Bureau of Mines, under a Memorandum of Agreement with the American Society of Mechanical Engineers (ASME), established design criteria for a facility to field residues from municipal waste combustion. This facility, which is available to potential users on a cost-sharing basis, is also applicable to a variety of inorganic waste materials from smelting or melting operations. The design consists of a mechanical feed handling system, electric arc melting furnace, fume-off gas handling system, and thermal oxidizer for final off gas treatment. Screw conveyors and a bucket elevator deliver up to 2,000 Ib/h of minus I-in material to a three-phase electric arc melting furnace. This unique 800-kVe A furnace has a water-cooled shell and roof to minimize interaction of the melt with the refractory lining. The volume of the hearth below the slag taphole is approximately 1.2 st of steel. The furnace is sealed, allowing atmosphere control within the furnace and fume duct by nitrogen or inert gas injection. A jet-pulsed baghouse removes particulate from the off gas and serves as an acid gas scrubber. The clean off gas is heated to 1,800' F for 1 s in a propane-fired thermal oxidizer before being vented to the atmosphere.

Jan 1, 1993

By AIME AIME

THE growth of the spirit of progress and mutual aid which motivated the founders of the Institute sixty years ago in Wilkes-Barre was vigorously demonstrated at the sixtieth anniversary meeting held there on May 22. Committees headed by Cadwallader Evans, "resident director" of the Institute, and Paul Sterling, chairman of the local section, had arranged for a full-day tour of the northern anthracite field, so that the hundred and fifty members and guests who had come for the celebration of the anniversary might see the changes and progress made in that field in recent years. More than forty automobiles were in line in the cavalcade which left the Westmoreland Club at nine- thirty. Operations visited were fully described in the May issue of MINING AND METALLURGY, so it is enough to say that after a seventy-five mile drive through the beautiful Susquehanna Valley and over the rolling green hills of northern Pennsylvania a stop was made for lunch at Forest City. Carey, Baxter and Kennedy, contractors at the stripping operations there, had provided, in the shelter of tents, a well-prepared luncheon and other refreshments. The return trip was made by way of Scranton, arriving at Wilkes-Barre at five- thirty.

Jan 1, 1931

By Bengt L. Stillborg

INTRODUCTION This paper summarizes the result of a two and a half year research program. The objective of the research was to develop a fundamental understanding of the Rib-in-Roc method. Through the development of a new model technology, namely three-dimensional physical models which powerfully exploit the results of dimensional analysis Stillborg, Stephansson and Swan (1), it has been possible to establish the contribution to both permanent and immediate stabilization of a large underground opening pre-reinforced by the Rib-in-Roc method. Using the results from these physical models and earlier work by Stillborg and Stephansson (2) and Åkesson (3), a conceptual synthesis is given in this paper so demonstrating the Rib-in-Roc method to be a practical working system of pre-reinforcement. DESCRIPTION OF THE RIB-IN-ROC METHOD To give the reader an idea of how this method of pre-reinforcement is performed, a short description will be given, Figure 1. Before any full-scale excavation takes place an entry is made in the host rock and rib raises are driven around the proposed opening. These raises are made at a spacing that is dependent upon rock quality; an opening in poor rock needs more ribs per length of opening. As the ribs are driven they are used as a site from which very competent rock bolting can be done. As a rib is excavated it is filled with reinforced concrete. Finally after having in this way reinforced the zone around the proposed opening, (a reinforced arch is formed) the displacements are automatically controlled as the opening is being excavated. Using this method openings with a span of 50-60 meters (160-200 ft) and a height of 60-80 meters (200-260 ft) are likely to be realised.

Jan 1, 1979

By H. Conrad, K. Jung

"The effect of an external electric field E=5(+) kV/cm applied during the solution heat treatment at 500°-550°C of three commercial Al-Mg-Si alloys (AA6061, AA6022 and AA61l1) on the asquenched resistivity Pw and hardness H.,NULL, w was investigated. It was found that the field gave a significant increase in Pw and in Hv,w, for AA6022 and AA6111, but had no clear effect on AA6061. Thermodynamic analysis gave that the effect of the field on AA6022 and AA6111 was to reduce both the enthalpy ?H, and entropy ?H, of solution. Considering the chemical composition of the three alloys it appears that the influence of the field may depend on the amount of Cu plus excess Si present in the alloy.IntroductionKlypin and Soloviev [1, 2] were the first to report that the application of an external electric field during solution heat treatment (SHT) of Al alloys gave an increase in the as-quenched resistivity and hardness. They attributed these effects of the field to an increase in solubility of the alloying constituents during the SHT. More recently Liu and coworkers [3, 4] also reported an increase in the as-quenched resistivity of Al-Li alloys with application of an electric field during SHT. Further, the present authors [5] found that the application of an electric field during the SHT of the commercial Al-Mg-Si alloys AA6022 and AA61i1 increased their as-quenched resistivity and hardness. Their thermodynamic analysis of the results indicated that the field decreased both the enthalpy ?H, and entropy ?S, of solution."

Jan 1, 2004

By Wan-sub Kim, Joon-Tae Lee, Seongkyu See, Yong-Kyu Park

Softening heat treatment of CHQ alloy steel (Cr-Mo Steel) is a bottleneck process that requires 90% or more of the entire manufacturing process. In order to reduce the property deviation between edge and center and remove the low-temperature structure problems, CHQ products is heat treated by customers. This technology comes from the idea to solve the problem by applying the concept of “In-line isothermal transformation through initial quenching + heat source addition. Consider the stability of field operations, durability from high ambient temperature and fall of scale, Instantaneous heating and cooling control was required for the conversion of slow cooling and rapid cooling products. An electric heating system was applied to the underside of Stelmor air-cooling nozzle. Using the Scan Pyrometer, the feedback control was performed and fine temperature control was performed through the thermocouple by zone. Through the this technology, it is possible to develop and expand products that can be shortened or omitted by the heat treatment process of customers.

Oct 1, 2019

By Robert L. Dean

THE pioneer mining company in Idaho to use airplanes extensively is the Yellow Pine project at Stibnite now owned by the Bradley interests. From 1901 to 1903 the gold boom at Thunder Mountain, in central Idaho overflowed to adjacent areas, prospectors discovering cinnabar and stibnite near the present site of Stibnite in Valley County. The workings were practically abandoned by 1911 through lack of capital and high costs of transportation on pack train roads over several mountain passes open only five months each year. During the World War there was some prospecting and production, and in 1921 twelve of the original companies were merged. Small-scale mining up to 1927 proved that an expenditure of several million dollars would be necessary to operate profitably. These properties were purchased by the Bradley interests during the period of 1927 to 1930. In 1927, there was no mining equipment except hand tools, no telephones, and only one building. Two mountain

Jan 1, 1935

By W. G. Davenport

This chapter extends our mathematical description of flash smelting to -nitrogen in the flash furnace blast. As in chapters 4 and 5, the discussion is limited to auto thermal smelting (no hydrocarbon combustion). Hydrocarbon combustion is introduced in Chapter 9. Outokumpu flash furnace blast is a mixture of air and industrial oxygen. Most of its N2 originates in the air portion of the blast. A small portion originates as an impurity in the industrial oxygen. The nitrogen entering a flash furnace must always be heated from its input temperature, 298 K in this chapter, to its off gas temperature, -1500 K. Energy must be supplied for this purpose. With auto thermal smelting, the energy is-provided by oxidizing extra Fe-and S.

Jan 1, 2001

By B. M. Davis

The problem of assessing uncertainty in grade estimates has been a topic of research and debate since kriging was first introduced. Use of the kriging variance was originally touted as all that was necessary in order to produce confidence limits for grade estimates. Since then the prudence of using the kriging variance for confidence interval estimation has been questioned, and techniques such as the jackknife and conditional simulation have been proposed to develop "true" interval estimates. This paper compares the differences between interval estimates produced by the three methods and makes conclusions about the performance of confidence intervals produced by the different methods.

Jan 1, 1997

By G. Akdogan, P. Mutimutema, M. Tadie

The South African gold mining industry has a legacy of abundant tailings dams, which have attracted the attention of investors because of their potential as a cheaper secondary gold resource. In this we investigate study gold recovery from a refractory calcine tailings dam. Bulk mineralogy of the tailings silicates and iron oxides to be the most abundant phases. Scanning Electron Microscopy (SEM) showed gold to exist in submicrometre and micrometre sizes, as free gold, and associated with arsenic, sulphur, and silicates e.g. quartz and talc. Gold recovery by direct cyanidation was low at 17.3%. Mechanical (ultra fine grinding P80 -16μm) and chemical (alkaline, NaOH) pre-treatment and microwave roasting and microwave-assisted cyanide leaching were investigated to increase gold recoveries. Ultrafine grinding was the most effective, producing recoveries of 66.5%. NaOH pre-leaching of ultrafine milled material increased recovery to 71.5%. Alkaline pre-leaching overall increased recoveries for non-pretreated material, making this process the most preferred because it is less costly than ultrafine grinding. Microwave roasting and microwave-assisted leaching did not achieve higher recoveries than alkaline pre-treatment or fine grinding. The investigation highlights and confirms that chemical treatment with NaOH is a powerful tool for gold extraction from refractory tailings.

Oct 1, 2022

By Sidney Katell

The reaction of coal, oil, or natural gas with air and oxygen and/or steam yields a gas containing varying amounts of impurities. Depending on the raw material and the end use of the product, these impurities include solids, such as dust or slag, and gases, such as hydrogen sulfide, carbon dioxide, and nitrogen. Considerable effort has been expended in developing and operating purification systems, and the literature is replete with equipment data and operating results. The research problems, the design, and the operation of the various systems have been the subjects of patent applications, journal articles, and textbooks.

Jan 1, 1959

Shoveling ore cost so much at Tyrone during the year 1917 that it was deemed advisable to conduct tests to see where the fault lay. These tests were in the nature of time studies and extended over a period of very nearly a year. No data were available on this work to supply a starting point, so it was necessary to begin in a very elementary way, to find out the capacity of the average Mexican laborer. To' obtain a basis for comparison, it was necessary to determine the capacity of various types and sizes of shovels, so as to know whether the 21-1b. (9.5-kg.) load was the best load underground as well as on surface. A list of essential factors influencing shoveling was also made out during the course of a short series of preliminary time studies, and the motions involved in shoveling were analyzed and subdivided for convenience in studying. The necessary forms and record sheets were also decided upon at this time. A second short series of tests was then conducted on the surface, so as to be able to estimate the negative effects of underground work on the shovelers, and to minimize, as far as possible, the need for studying obviously poor types and sizes of shovels under the difficult conditions to be encountered in the mine. The test work underground consumed by far the greater proportion of the time and was divided into three series: Shoveling directly into a chute; shoveling into a wheelbarrow and tramming to a chute; and shoveling into a car and tramming to a chute. In each series the following points were determined for various lengths of time worked: Number of shovelfuls handled per minute, effect of distance thrown on shoveling speed, amount of rest required, amount of time consumed in tramming and dumping, proportion of working day occupied in shoveling, total tonnage handled during various working periods, effect of distance on tonnage handled during the day.

Jan 2, 1919

By Thomas Höfler, Michael Auinger, Bernhard Linder

Gas-fired pusher furnaces are commonly used to heat steel slabs before hot rolling. Temperatures well above 1000 °C combined with an oxidizing atmosphere containing H2O, CO2 and O2 result in rapid oxidation of most steel grades. The resulting oxide scale and the chemistry of the metal-scale-interface are major determining factors for the occurrence of hot rolling defects. To better understand these phenomena, lab-scale trials were performed with two different steel grades in an electric tube furnace in the temperature range 1000-1250 °C, using an atmosphere of about 20 % H2O, 7 % CO2 and 3 % O2. Humidification of the gas was achieved by evaporation, using a custom thermostat with standard laboratory glassware. The resulting samples were prepared metallographically, using cold mounting under vacuum with taper section angles, and analyzed using light microscopy and SEM/EDS. The scale structure of the Si alloyed steel was highly dependent on the oxidation temperature due to the formation of eutectic liquid phases of FeO, Fe2SiO4 and FeAl2O4. Below the eutectic temperature, the scale of the Si steel appeared to be made up of three distinct areas: The external scale consisting solely of Fe oxides, the internal scale containing Fe2SiO4 and FeAl2O4, and an internal oxidation zone with SiO2 and Al2O3 in a mostly plain Fe matrix. Comparisons of the experimental results with simulations of the internal oxidation showed good qualitative agreement.

Oct 1, 2019

By James V. Errico

On October 1, 1993 the regulations for assessing and cleaning up contaminated soil and groundwater in the Commonwealth of Massachusetts were revised. These new regulations, known as the Massachusetts Contingency Plan (MCP) 310 CMR 40.0000, were developed to keep routine releases out of the regulatory system and rely on private parties to handle most releases without Department of Environmental Protection (DEP) oversight. An integral part of the new MCP is the Licensed Site Professional (LSP). An LSP is required to handle activities and render opinions once a site enters the MCP. These regulations must be adhered to where ever a release has occurred, including construction sites. A brief overview of the new MCP is given below; see attached MCP Flowchart for graphical summary. Entering the MCP Process A release of oil or hazardous material (OHM) to the soil or groundwater above applicable reportable quantities (RQ's) or reportable concentrations (RC's) will require notification to the DEP and compliance with applicable provisions of the MCP. RQ's and RC's are listed in the MCP (310 CMR 40.1600) for most compounds that are typically encountered. For each compound there are two RC's for soil (S-1 and S-2) and two for groundwater (GW-1 and GW-2). The S-1 and GW-1 RC's apply to sites that are environmentally more sensitive, as a result they are lower than the S-2 and GW-2 RC's.

Jan 1, 1994

By Cyril Smith

A COMPLETE discussion of the literature on the subject of the influence of copper on iron and steel will be published elsewhere.1 The present paper is concerned especially with the precipitation-hardening of copper steels, and brief mention will be made here only of the work of Kin-near,2,3 Nehl4 and Buchholtz and Koster,5 who alone have studied this phase of the subject. Kinnear found that normalized low-carbon steel castings containing about 1.0 per cent copper on drawing at temperatures in the neighbor-hood of 530° C. (1000° F.) increased in tensile strength and yield point, with little decrease in ductility. The maximum effect was obtained with about 0.9 to 1.0 per cent copper, and when the copper exceeded 3 per. cent no improvement occurred on reheating. Kinnear did not study the effect of time of reheating-an all important factor where precipitation is concerned. Nehl,6 who apparently was unaware of Kinnear's work, recognized the change as due to precipitation and studied the interdependence of time and temperature of reheating, the temperature of the initial solution heat treatment, and the speed of cooling necessary to retain the bulk of the copper in supersaturated solu-tion and to give an increase in hardness and tensile strength on reheating. Nehl found that if the final rolling or forging temperatures exceeded 700° C. (1300° F.) it was not necessary even to normalize the steel, but full precipitation occurred on merely reheating the forged or rolled shapes at 500° C. (930° F.).

Jan 1, 1933

By Lara de Assis Moreira, Vinicius Thiago Lecco Rampinelli

The energy efficiency of reheating furnaces is a continuous challenge, as these equipment consume a representative portion of the total fuel of an integrated steel plant. Therefore, any investigation and implementation which brings improvement in this figure become an important issue for the mill competitiveness. In the case of production delays due to external factors (the condition addressed in this work), whether predicted or unforeseen, the slabs remain inside the furnace with high temperatures in order to avoid production delay during the production restart, elevating the specific consumption and scale formation. This work increased the energy efficiency of the two ArcelorMittal Tubarão’s walking beam reheating furnaces, by reducing the consumption of mixed gas during production delays (either scheduled or not) lasting less than 3 hours. The objectives were achieved through improvements, among them, tuning of Level 2 automation system parameters, automatization of procedures and operational training. The work resulted in a 34.4% fuel gas consumption reduction during the delays.

Oct 1, 2019

Open cut low grade gold mines form the basis of the current upsurge in the mining industry in Australia. The effect on profitability in the short term and viability in the long term requires accurate estimation of grade and tonnages. The application of the Ditch Witch Trenching Machine as a grade control tool has occurred rapidly and the machine is now a working tool in many mines throughout Western Australia.

Jan 1, 1987

By W. I. Nissen

This Bureau of Mines report presents the design for a commercial-sized flue gas desulfurization (FGD) demonstration plant that uses the citrate process. The goal of the Bureau's citrate process is to minimize the undesirable environmental impacts of industrial plants emitting SO2-bearing gas. The FGD plant is located at the George F. Weaton powerplant, Monaca, Pa. Construction was completed in April 1979 and will be followed by preliminary testing and a 1-year testing and evaluation program. Design capacity of the FGD plant is 156,000 scfm of 0.2-volume-percent-SO2 flue gas yielding about 16 tons of sulfur per day. The plant is intended to (1) clean fly ash, SO2, and Cl- from the gas while cooling the gas in a venturi scrubber, (2) absorb SO2 from the gas using 1,200 gpm of a countercurrent-flowing citric acid-sodium citrate-sodium thiosulfate solution, (3) react the absorbed SO2 in two 13,000-gal stirred closed vessels with added H2S, thus precipitating elemental sulfur and regenerating the citrate solution for recycle, and (4) recover the sulfur from the slurry by air flotation, followed by melting in a heat exchanger and separation from the occluded citrate solution in a sulfur decanter at 35 psi and 135° C.

Jan 1, 1979

By Henry Stoch

It?s a green, green world ? Public concern about the impact of human activities on the environment and the roles that businesses play in that impact is rising. What?s happened in the last few months? ? Recent news: ? British Columbia announces carbon tax in 2008 budget ? Federal Court ruling stalls oil sands approvals due to a lack of consideration of GHG implications ? US Energy Independence and Security Act could limit government procurement of oil sands-derived fuels ? Western Climate Initiative (WCI) suggests a ?first seller? approach for regulating generators outside WCI jurisdictions ? Implications ? A cost for carbon has arrived ? The lack of a GHG strategy can have a material impact on your business ? Regulations in other jurisdictions could affect your organization

May 1, 2008

By Sheng-Hui X

This paper introduces a new coal-based rotary kiln process of DRI production - the CRIMM process, which is developed by Changsha Research Institute of Mining and Metallurgy in the past years. Its main features are the use of composite pellets (in rotary kiln). The process consists of preparation of pellets from iron concentrate and coating of coal on their surfaces. The new process is able to overcome a series of defects of the conventional coal-based rotary kiln processes. A continuous test was conducted using an experiment rotary kiln (-0.6;, x 3 m). TFe of the magnetic iron concentrate used in the test is 67.25 per cent. TFe of the product DRI is 88.54 per cent, MFe is 84.11 per cent, S and P are less than 0.02 per cent. The metallisation ratio of pellet is 95 per cent. The pellet power ratio is less than 0.3 per cent. The utilisation coefficient of rotary kiln is 1.3 t/m'-d. The overall recovery of iron concentrates is 99.7 per cent. Two small industrial plants using the CRIMM process are being set up in China. Their coal consumption can be decreased to 520 kg standard coal per ton DRI respectively.

Jan 1, 1999