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By R Ashworth, S J. Hall

During trials which began in May 2005, traditional steel dump bodies for transporting iron ore on 220-tonne haul trucks at a Labrador iron ore mine were compared to a novel rubber suspended dump body. Loads were measured and compared over some 93 700 loads, representing more than 20 Mt transported. Maintenance costs and downtime were also measured over the course of the trial, which lasted nearly one year. This paper outlines the parameters and results of the trials. Parameters measured included payload and production improvements, carry-back reduction, downtime due to body maintenance, and wear on the floor of the suspended dump body. These parameters were then compared to those for conventional steel dump bodies in use at the mine, and conclusions were drawn. The resulting comparisons were significantly positive in favour of the new suspended dump bodies, confirming that each truck could haul an additional 41 000 tonnes per year, that downtime hours could be considerably reduced, and that body availability and service life can be extended through use of the suspended dump body. There was also a high level of operator acceptance of the suspended dump bodies due to less loading shock and a smoother ride.

Jan 1, 2007

By Peng Qian, Xiao Li, Guoyan Fu, Peiwei Han, Yongliang Wang, Shufeng Ye

"Arsenic removal from high arsenic gold concentrate is conducive to increase the mineral value and realize the mineral comprehensive utilization. This study investigated the alkaline pressure oxidation leaching (APOL) of an arsenical gold concentrate in lower temperature to separate the arsenic into filtrate. The effects of temperature, NaOH concentration, solid-liquid ratio, reaction pressure and stirring speed on the leaching efficiency were investigated, and the characteristics of the gold concentrate and leaching residues were evaluated using XRD and SEM analysis methods. The obtained results showed that by using lower temperature (<60?) it is possible to avoid the production of elemental sulfur during the leaching process, which is benefit for the oxidation of arsenopyrite; When the reaction was carried out under appropriate conditions, more than 98% of the arsenic will be extracted into the filtrate as the form of arsenate or thioarsenate. INTRODUCTION In recent years, there has been considerable interest in the recovery of gold from refractory arsenical gold ore. The arsenic in this kind of ore usually exists as the form of arsenopyrite, and the gold surrounded by arsenopyrite exists as the form of fine particles, which will give many difficulties to metallurgical work. When the content of arsenic in the gold ore is more than 0.5%, it will seriously penalize the smelting efficiency (Ruiz et al., 2014). So pretreatment of the refractory gold ore is necessary to obtain the largest economic value and environmental benefits (Balaz et al., 2000). The oxidation pretreatment processes mainly include roasting oxidation, pressure oxidation, chemical treatment and biological treatment (Ann et al., 1992; Kou and Chen, 2012; Tongamp et al., 2010; Fernandez et al., 1995; Lin and Zheng, 1996). Among them, the roasting oxidation and pressure oxidation are the more ordinary processes in industry. The roasting oxidation process is the mature and adaptable technology, but the production of waste gas containing sulfur and arsenic will pollute the environment. The pressure oxidation method possesses certain metallurgical and environmental advantages, and can efficiently decompose the mineral. According to the different solution media, the pretreatment can be divided into alkaline and acidic pressure leaching pretreatments (Papangelakis and Demopoulos, 1990; Hiskey and Sanchez, 1995). The acidic pressure oxidation method has been used in most smelting plants for high arsenic gold ore pretreatment, while the alkaline pressure oxidation is still not widely applied. Compared with the acidic pressure oxidation, the alkaline pressure oxidation can be realized under lower temperatures."

Jan 1, 2018

By R. Nilsson

In the present work, an assessment of the sulphide capacities of a number of binary and ternary slag systems have been carried out in the light of a sulphide capacity model. The model is based on the expression: {CS- exp (-A G °/R T) ? ao2 / fs2-} where AGO is the standard Gibbs energy change for the above reaction, ao2 is the activity of oxygen ions and f, is the activity coefficient of the sulphide ion in the slag. In the present model, the ratio (ao2/fs2) is optimized for the experimental data available in literature. The systems assessed are the binaries MnO-SiO2, CaO-SiO2, Al2O3-CaO, as well as the ternaries CaO-Al2O3-SiO2 and CaO-MnO-SiO2. In the case of all these systems, the experimental data available in literature were complemented by measurements carried out at the Division of Theoretical Metallurgy. The sulphide capacities of some FeO- containing binary, ternary and quaternary slags are also examined. The potentiality of the model to estimate the sulphide capacities of complex slag systems from binary and ternary data is demonstrated.

Jan 1, 1996

By Liming Yuan, John C. Edwards, Gene F. Friel, Robert A. Franks

Diesel fuel fire experiments were conducted in NIOSH’s Pittsburgh Research Laboratory’s (PRL) Safety Research Coal Mine (SRCM) to determine the critical air velocity for preventing smoke rollback. Such information is necessary for the preplanning and implementation of ventilation changes during mine fire fighting and rescue operations. The fire intensity varied from 50 kW to 300 kW depending upon the fuel tray area. Airflow in the 2 m high and 2.9 m wide coal mine entry was regulated during the course of each experiment; measured upwind from the fire as an average over the entry cross-section with an ultrasonic airflow sensor; and recorded dynamically with a mine monitoring system. The extent of smoke reversal was monitored with light obscuration monitors, ionization smoke sensors, and visual observations. Experimental results for the critical air velocity for smoke reversal as a function of fire intensity compared very well with model predictions based upon a computational fluid dynamics (CFD) fire dynamics simulator.

Jan 1, 2005

By Manasi Wijerathna, D. S. Liyanapathirana

"Deep cement mixing is a popular soft ground improving technology that improves the bearing capacity and settlement characteristics of natural soil. When Deep Cement Mixed (DCM) columns are installed attached to each other in a wall configuration, the walls are capable of resisting bending moments and shear forces in the direction transverse to the columns. Therefore, installing DCM walls beneath the embankment slope perpendicular to the alignment of the embankment is a proper solution to prevent excessive lateral deformations of the embankment. Previous research studies have shown that failure patterns of DCM column walls are different to failure patterns of individual DCM column rows, under lateral loads. This study investigates the failure patterns of embankments where DCM column walls are located beneath the slopes, with respect to DCM wall strength, DCM column wall width and the spacing between DCM walls. 2D and 3D numerical models developed using the ABAQUS/standard finite element programme, were used in this investigation. Results show that the DCM wall strength and width of the DCM wall have a significant influence on the failure mode and the critical failure surface of the embankment. 3D simulation results demonstrate that the failure due to soil extrusion between columns was less pronounced in embankments improved with DCM walls, due to the interaction between the DCM walls and the surrounding natural soil.INTRODUCTIONEmbankments constructed over soft ground are highly susceptible to global slope failure and excessive displacements due to combined effects of vertical and lateral loads beneath the embankment slope (Zheng et al., 2009, Han and Gabr, 2002). The overall stability of the embankment can be significantly improved by improving the soil beneath the slope of the embankment using Deep Cement Mixed (DCM) column rows or overlapped DCM column walls (Jamsawang et al., 2015, Larsson and Broms, 2000, Topolniki, 2004, Broms, 1999). According to the literature, the improved ground experience different failure modes other than shear failure, such as separation of columns, overturning, shear failure along the columns or dowel action (Broms, 1999). Some of the failure modes reported by Broms (1999) are shown in Fig. 1. The ultimate failure mode depends on the geometry and the strength of the improved ground (Jamsawang et al., 2015, Kitazume and Maruyama, 2006, Kitazume and Maruyama, 2007)."

Jan 1, 1900

By W. A. Binsacca

The concentrator treats sulfide ore containing lead, copper, zinc, gold and silver, at the rate of 850 tons per 24 hr., and produces lead, copper, zinc and iron concentrates by selective flotation methods. The ore occurs below the oxidized zone along a main fracture, the wall rock of which is either greywacke or calcareous shale. The predominating sulfide minerals are galena, sphalerite, pyrite and chalcopyrite; the others are quartz and calcite. In minor amounts, arsenopyrite, pyrrhotite and hematite occur, and such secondary minerals as smithsonite, chalcocite, covellite, bornite, cerussite and anglesite are detected in the ore, the last two named occurring principally as surface alterations of the galena. The ore is hauled from the mine bins in 10-ton cars which pass over the track scales before entering the car dumper ahead of the crusher plant.&apos; A conveyor belt delivers the crushed ore to the sulfide bin, which has a capacity of 2800 tons. The primary grinding unit consists of two 6 by 12-ft. Marcy rod mills operating in parallel and in open circuit, each taking 425 tons per day. One rod mill discharges into an 8 by 25-ft. Dorr classifier with a 12-ft. bowl and the other into a 6 by 25-ft. Dorr duplex classifier. These classifiers are arranged so that each unit rakes the sands into a 6 by 14-ft. Traylor ball mill, which discharges to the bowl classifier only. The duplex classifier therefore operates in open circuit and the bowl classifier in closed circuit, the overflow of both classifiers furnishing the feed for the flotation section. Other groupings have been tried, but this has been found the most satisfactory. The Marcy mills are driven by 150-hp. slip-ring induction motors with speed reducers to give 17 r.p.m. The Traylor mill operates at a speed of 24 r.p.m. and is driven by a 200-hp. slip-ring induction motor, direct connected to pinion and gear. The bowl classifier operates at a speed of 22 r.p.m., with the bowl rake making 4.5 r.p.m. and the duplex classifier at 31 r.p.m. High-carbon steel rods of Mexican manufacture, 12 ft. long by 3-in. diameter, are used in the Marcy mills, with a resulting consumption of 1.52 Ib. per ton ore. The Traylor mill is fed 3-in. cast-iron balls cast in

Jan 1, 1935

By J Jeffrey, G W. Wilson, L Gilbert, C

Prior to the commencement of mining, the acid rock drainage (ARD) potential of the waste rock to be produced by an open cut mining operation is assessed by a variety of techniques carried out on drill-hole samples. These include, among others, acid base accounting (ABA), net acid generation (NAG) testing, and kinetic testing. Based on the results obtained, a strategy for the identification, separation and selective placement of waste rock having different potentials to form ARD is developed. During the course of mining, the waste rock classification scheme will be re-assessed periodically to confirm that it is appropriate. This re-evaluation may result in a change in classification scheme, and waste rock dump samples may be obtained for ARD assay purposes to confirm the appropriateness of the revised scheme. The paper describes the evolution over time of the scheme used to classify waste rock at a major open pit gold operation in New South Wales, Australia, including the development of a hydrological model. To confirm the appropriateness of the revised scheme, ARD assay testing was carried out on drill-hole samples collected from dumps having different ARD potential designations, including Non-Acid Forming (NAF), Potentially Acid Forming (PAF), and Low Grade Ore stockpiles. The results of the ARD assay testing and water quality monitoring confirmed the appropriateness of the ARD potential designations and the revised classification scheme, which has been adopted.

Jan 1, 2003

By David N. Hedges

This paper discusses the actual recovery and installation of a longwall in a bituminous coal mine in Western Pennsylvania. The coal bed mined is in the Lower Freeport seam which averages 42 inches (1.07m) in height locally. Drainage from the mine is approximately 3.5 million gallons of water per day (13.25 million liters per day). This water deteriorates the mines predominately fire clay bottom making it extremely difficult to move equipment. Support removal is accomplished by pulling the 6 ton (5443 kg) shields out under their own hydraulic power and transporting them by track over four miles (6437m) co the next longwall panel. This paper also discusses the changes that will be made to aid in the succeeding longwall recoveries and installations.

Jan 1, 1984

By Emily Wortman-Wunder

As the 2012 president of the Society for Mining, Metallurgy, and Exploration, Inc., I am pleased to present the 2012 issue of the Transactions of the Society for Mining, Metallurgy, and Exploration, Vol. 332. A significant portion of the contribution that we make as a professional society is the publication of professional and technical papers that accelerate the advancement of scientific knowledge and enable the transfer of technology. Communication within the mining community is the key to a successful society. This technology exchange continues a tradition that dates back to the 1871 meeting of 22 mining engineers in Wilkes-Barre, PA, that resulted in the founding of AIME; those individuals envisioned that these transaction volumes “would form a most valuable and greatly needed addition to our professional literature.” This volume fulfills that pledge. The 2012 Transactions is the third Transactions to take advantage of new publication technologies. It is available solely as an online subscription. The new format better suits the way this material is used and, ultimately, better enables the transfer and dissemination of knowledge. The 2012 Transactions contains some of the most interesting research from the past year, including a paper on the uranium boom in Namibia, work on improving the safety of coal pillar extraction, ways to improve the optimization and efficiency of various mine activities and the newest research from the U.S. National Institute for Occupational Safety and Health (NIOSH). The 2012 Transactions consists of a total of 67 technical papers (550 pages, including index), including all 18 papers published in 2012 in the Technical Papers Section of Mining Engineering magazine (Vol. 64) and all 31 papers published in 2012 in Minerals & Metallurgical Processing (Vol. 29). Additionally, this volume contains 18 papers that are being published for the first time in this issue. The papers presented in this volume were written by some of the most distinguished professionals in the industry worldwide. All 67 technical papers were peer-reviewed. The process of review and publication requires much hard work by authors, reviewers and our publications staff. As the 2012 president of SME and on behalf of all our members, I would like to extend our gratitude to all whose volunteer efforts contributed to the publication of this volume.

Jan 1, 2012

By S. Iverson

Fall of ground accidents continue to be a source of injury in underground metal mines. MSHA accident statistics indicate that most rock fall accidents occur at a new face where drilling and blasting methods are used. Removing loose rock by scaling is imperative to removing the potential for rock fall injury. Detection of potentially loose rock could improve the scaling process and result in fewer rock falls. Infrared thermal imaging cameras were investigated as far back as 1966 as a tool for loose rock detection. Early on it was clear that sensitivity (e.g. detectable temperature increment) is a key factor in this application. Both pixel resolution and temperature resolution have greatly improved with modern instruments. This paper describes an evaluation of modern infrared thermal imaging camera technology to detect loose rock conditions at six underground metal mines in the western U.S. It was found that thermal images provide a high resolution visual discrimination between loose rock and intact rock. However, detecting loose rock was difficult in cases where the rock and ventilation air were at the same temperature. Loose rock was detected when rock was both warmer and cooler than the ventilation air temperature. Warm rock with cool ventilation air provided the best conditions for detection.

Feb 23, 2014

By Burman B. C

This paper describes studies into two particular aspects of the Lochiel deposit which formed part of feasibility level geot2chnical and hydrogeological investigations for proposed open cut mine development. The two aspects were depressurisation of thick beds of silt located through the profile and the determination of characteristics and origins of soil structure and their effect on pit stability. The studies were very detailed and multi disciplinary and highlight the integration of geology, geotechnics, hydrogeology and mining that is required for mine development studies. It is considered that as more marginal deposits are developed throughout the world the demands for efficient economic mining together with in- creasing scales of operation will require simi- lar types of studies. As such the studies pre- sented herein are likely to be a forerunner to a,emerging trend for development of open pit mines in difficult ground and water conditions.

Jan 1, 1986

By Elia Elias, Alan Crosky, Paul Hagan, Damon Vandermaat, Serkan Saydam, Peter H. Craig

"The University of New South Wales (UNSW Australia) had been involved in the study of premature failure of rock bolts in Australian coal mines from the initial identification of the problem in 1999 (Crosky et al 2002). Rock bolt steel changes over the last decade appear to have not reduced the incidence of failures. A broadened UNSW research project funded by the Australian Research Council (ARC) and Industry has targeted finding the environmental causes through extensive field and laboratory experiments. This paper describes the field studies conducted in underground coal mines, in particular attempts to measure the contribution to corrosion from groundwater, mineralogy and microbial activity. Various underground survey techniques were used to determine the extent of broken bolts, with the presence of both stress corrosion cracking (SCC) and localized deep pitting making no single technique suitable on their own. Groundwater found dripping from bolts across various coalfields in Australia were found to be not aggressive and known groundwater corrosivity classification systems did not correlate to where broken bolts were found. In-hole coupon bolts placed in roof strata containing claystone bands confirmed the clay as being a major contributor to corrosion. Microbes capable of contributing to steel corrosion were found to be present in groundwater, and culturing of the microbes taken from in-situ coupon bolts proved that the bacteria was present on the bolt surface. An ‘in-hole bolt corrosion coupon’ development by the project may have multiple benefits of 1) helping quantify newly developed corrosivity classification systems, 2) providing an in-situ ground support corrosion monitoring tool, and 3) for testing possible corrosion protection solutions.introductionThe problem of premature rock bolt failure in Australian coal mines was published in 2002 and 2004 by UNSW Australia from Australian Coal Association Research Program (ACARP) funded projects. The majority of the broken bolts examined had steel Charpy impact toughness values of 4 – 7 Joules, and the failure mechanism was most often stress corrosion cracking (SCC). Steel fracture mechanics predicts that an increase in impact toughness will increase the length of the crack before sudden brittle failure. In the final report of 2004, anecdotal evidence from one coal mine indicated that the problem may be eliminated in some environments by a change to steel grades with higher Charpy impact values of ~16. (Crosky et al, 2002 and 2004)"

Jan 1, 2015

By Hans von Michaelis

"INTRODUCTIONThe renaissance in gold and silver recovery technology has continued to unfold and it is appropriate to review some of the useful new technologies as well as try to identify some of the industry's future needs and frontiers.The remarkable strengthening in the US dollar has resulted in a relatively low gold price in US Dollars of around $310/oz at the time of writing and silver at $6.25/oz. This general softening in the dollar prices and the recent confusion as to environmental compatibility of cyanidation tailings and effluents, has led to a slowdown in announcements of new operations. Another reason for the slackening off in the USA is that in the past few years a large part of the capital has come from oi I and gas companies that now seem to be losing interest in mineral ventures, and foreign investors for whom the dollar is becoming out of reach. In the author's opinion this represents an unprecedented window of opportunity.Elsewhere in the world where local currencies have weakened, the price of gold is at or close to its all time high.For example, in South African Rands, the gold price was R571.00/oz when the rand was US$1.47 and the gold price reached US$800. Now at US $309/oz and with the Rand at US$0.51 = Rl .00, the local gold price is R600. The price of si Iver in Mexican pesos is not much less than it was when silver reached US$50/oz. Gold, and silver prices in local currencies outside North America are still buovant and at levels where additional investment in new projects is more encouraging.Even in Canada where the dollar is worth about US$0. 75, this provides a smaller but significant cushion compared with US operations. Considering the present strength of the US dollar and even the Canadian dollar relative to many other gold producing countries, there should be significant investment opportunities at today's prices. Mining companies have started to descend on Brazil, for example, where in a matter of just a few years annual gold production has increased from 10 to 70 tons. In South Africa, a Canadian company backed by Swiss financing has been able to take over a Witwatersrand gold mining operation and is installing a huge new tailin9s retreatment plant to process about 1 million tons per month of tailings."

Jan 1, 1985

By Peter N. Holtham, Geoffrey J. Lyman, The University of Queensland, Matthew S. Brennan, Vijay Subramanian, Rui X. Rong

"The cyclone would have a claim to be the commonest, least understood and most abused piece of mineral processing equipment available for study by researchers. It has certainly generated its fair share of publications – 1,000 in the last 60 years would be a fair estimate. However this remarkable degree of interest and scale of investigation is not reflected in our understanding of how they work; cyclones are still installed inappropriately and run poorly, which suggests that there are still things to learn about this deceptively simple process.In mineral processing there are two broad classes of cyclone: the hydrocyclone, used in classification, thickening and dewatering, and the dense medium cyclone, used for concentration by density. Although rarely studied together, the laws of physics presumably apply equally to both and so it seems that there would be interesting things to learn by considering them as a single class of device. The good news is that in recent years there have been spectacular advances in the computational and measurement tools available to study these devices, including computational fluid dynamics (CFD), tomography, and laser doppler anemometry (LDA), and some good progress has been made in an understanding of the fundamental principles involved.The JKMRC has made many experimental studies of hydrocyclones and DM cyclones, leading to useful empirical models. However some recent CFD and tomographic work, in association with work of other institutions, has thrown important light on the workings of these processes. Progress has also been made in novel designs of cyclone to achieve improved separating efficiency, based on an attack on the subprocesses believed to contribute to inefficient operation. This paper describes the work to date.Modelling of the dense medium and classifying cyclone was conducted using the Fluent computational fluid dynamics code. Three phase simulations of the dense medium application (air/water/medium) showed appropriate medium segregation effects but over-predicted the level of segregation compared to segregation measured by gamma-ray tomography. This is believed to be because the basic Algebraic Slip mixture model in Fluent does not model any back-mixing of the dispersed phase due to turbulence."

Jan 1, 2003

By Sam Palombo, James José Varela

"Washing can be defined as the process used to eliminate or reduce the dirt (presence of fines or slimes) of one material. It is also the basic and oldest process applied to ore preparation for further concentration. This process, in combination with commnution and screening, form the so called washing plant and in many cases produce end products. This work describes the factors that influence the performance of the washing process and main washing technologies used in the mineral processing industry.The Hydro-Clean represents, since 1998, a state of the art technology in this area and is comprised of one of the most innovative solutions developed at HAVER & BOECKER. HAVER & BOECKER design and manufacture technology for mining and related industries. Today the Hydro-Clean is manufactured and sold throughout the Haver Screening Group (HSG) which is comprised of HAVER & BOECKER Maschinenfabrik Münster, HAVER & BOECKER Latinoamericana – Brazil and W.S. Tyler Canada.The Hydro-Clean is a washing technology based on utilization of high pressure water jets. To follow we will discuss how the Hydro-Clean’s different modes of operation result in several advantages related with mine waste reduction, recovery of saleable product, lower capital costs, superior washing results, less stress for the material, a wider range of application and less maintenance cost. Aside from these positive factors, its lower operation costs related to the consumption of energy and water are presented. It is important to note that the quantities, tonnages, data and management concepts presented in the paper are accurate for the time of writing and are subject to change and modification as operations progress."

Jan 1, 2009

By SONGHE WANG, YI XUE, PENG HOU, CAIHUI ZHU, XUANYE JIAO, Feng Gao

The abstract discusses the challenges of coalbed methane development in China due to low coal seam permeability. It highlights protective layer mining as a method to reduce in-situ stress and enhance permeability for improved gas drainage and disaster prevention. The study involves experimental and numerical simulations to analyze gas migration and permeability changes during stress release. It includes a stress-strain-seepage coupled test on coal, development of a mathematical model for coal seepage under mining unloading, and a numerical model based on the Wulan coal mine to explore in-situ stress release, permeability evolution, and gas drainage in an unloaded coal seam. The aim is to demonstrate the effectiveness of combining protective layer mining and gas drainage technology for gas outburst risk elimination.

Mar 14, 2022

By John Durkin

A system based on seismic techniques has been developed to detect and locate men trapped underground following a mine disaster. Both theoretical and field studies have been used to generate models to predict the performance of the system. For a strong source, it is almost certain that the miner&apos;s signal will be detected if the geophone array can be positioned over a likely area of entrapment. After signal processing, it is highly likely that the location of the miner can be determined within an accuracy of 100 ft (30.5 m). The system is presently operational in a state of readiness in the event of a mine disaster.

Jan 1, 1980

By Raymond Brandon, Marshall Pease

A pattern for providing a large utility, The Detroit Edison Co., with an adequate fuel supply is outlined. From the standpoint of both fuel procurement and utilization, consideration has been given competition relationships, fuel properties as well as operating conditions that must be met to provide dependable service and reliable plant operation.

Jan 2, 1951

By V. E. Cogho

Optimum Coal Mine comprises numerous defunct, active, and future mining sections. The mine is primarily a large opencast coal mine; however, underground mining activities will be increasing steadily over the next five years. Opencast and underground mining activities have a significant impact on surface and groundwater resources. To ensure that the mine will be able to continue with its mining operations in the catchment, the extent of this impact requires that substantial intervention and mitigation measures need to be implemented to ensure the environmental integrity and economic use of the catchment&apos;s water resources. In developing a sustainable long-term mine water management strategy, numerous scenarios had to be analysed. The various scenarios are a combination of water and land management activities. The main components of the mine&apos;s integrated water management strategy include: ? Management of water recharge by continual and appropriate rehabilitation of disturbed land ? Beneficial re-use of impacted mine water for coal plant process water and mining operations ? Reclamation and desalination of remaining excess impacted mine water to potable standard. From the mine&apos;s long-term water balance, it is evident that the continued implementation of numerous water management actions is required to mitigate the water resources impact in a sustainable manner. In addition, the installation of a water reclamation plant at Optimum Coal Mine (15Ml/day) is a key step for the mine to achieve a zero impact target.

Jan 1, 2012

The purpose of this study was to investigate the immobilization as a host for metallic pollutants (Cr, Cu, Pb, and Zn) by ettringite phase. Ettringite phase is produced through hydration reaction of calcium aluminate with gypsum. From the XRD patterns, it is known that the distance between spaces in 010 planes in ettringite crystal increase with an increase of ionic radius of heavy metal except Pb; no big difference is shown. For this reason, the d-value of 010 planes in ettringite crystal increased with the substitution of Cr, Cu and Zn having a big Al ironic radius. But in case of Pb, because the substitution occurred at calcium site, it does not influence to increase d-value of 010 planes.

Jan 1, 2006