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By L. M. Burman

The phase-boundary pressure required to maintain a natural hydrocarbon fluid in a single phase must be considered in planning the recovery of reservoir liquids by miscible-phase processes. The change in the phase-boundary pressure at reservoir temperature that results when a light component or a mixture of light components is added to a reservoir fluid is an especially important consideration. The cricondenbar pressure (maximum phase-boundary pressure) and the critical pressure are unique correlated pressures that have been utilized to calculate the change in phase-boundary pressure that may result when the composition of a reservoir liquid is altered by an additive. In this study one reservoir oil and three gas-condensate fluids are used as examples. Correlations pertaining to the critical and cricondenbar states in chapters 4 and 5 of Bureau of Mines Monograph 10 (3)5 were used to demonstrate how butane and lighter components added to these reservoir fluids affect their phase-boundary pressures.

Jan 1, 1962

By Frank M. Kimmerle

Spent Potlining (SPL) contains recoverable chemical elements (C, F, Na and Al) which are lost in stabilization or immobilization processes primarily aimed at eliminating cyanides and reducing leach rates of soluble fluorides prior to landfiling. They can be recovered in a variety of mineral forms for recycling in the aluminum industry and elsewhere. Alcan has developed a cost-effective hydrometallurgical route, combining a number of proven unit processes to destroy cyanides, recycle the chemical values and provide a zero-discharge process. Pilot plant studies of this Low Caustic Leach and Liming (LCL&L) Process prove that the fluoride scan be converted to acid grade fluorspar, while the sodium and aluminum are recovered as a sodium aluminate and caustic feed to the Bayer Plant operations. The remaining brick and carbon fraction constitutes a high ash solid fuel which meets TCLP leach criteria and whose reduced sodium content enhances its value as a chemical reducing agent.

Jan 1, 1994

Low Zinc Prices Close Alcoa Mine Alcoa Mining Co., announced that it will suspend operations at its Hutson mine, near Salem, Ky., because of low zinc prices, January 15. The Aluminum Co. of America subsidiary announced that the low market has made zinc mining un- profitable. About 70 men were employed at the mine, with a production of about 5000 tons of zinc annually. Alcoa said the shutdown would not affect other company operations, with most of the men at Hutson absorbed in the mining firm's fluorspar operations in the same area.

Jan 2, 1953

By Leopoldo Gutierrez, Esau Arinaitwe, Marek Pawlik

"The effect of various polymers, including: anionic carboxymethyl cellulose (CMC), polystyrene sulfonate (PSS), humic acids (HA) and non-ionic hydroxypropyl cellulose, on the wettability of Athabasca bitumen was evaluated through dynamic contact angle measurements using the captive bubble technique. The tests were carried out as a function of pH at a constant ionic strength (0.01 mol/L sodium chloride). The evolution of the three-phase contact angle between the solution, bitumen and an air bubble was followed as a function of time over a period of ~6 minutes. The contact angle data were modelled using a first-order kinetic equation. The results were analyzed in terms of the initial contact angle, the evolution rate constant, and the steady-state contact angle value. In the case of anionic polymers, a pronounced decrease in the initial contact angle value was observed at pH 3. Under acidic conditions, there was no significant effect of CMC observed on the steady-state contact angle value but PSS and HA significantly decreased the steady-state contact angle value. At pH 8.5. the anionic polymers did not affect the wettability of the bitumen surface but they significantly decreased the contact angle evolution rate. These results suggested that CMC is not capable of permanently lowering the hydrophobicity of bitumen, and the polymer only slowed down the evolution of the contact angle to the steady-state value. The results also showed that polystyrene sulfonate and humic acids were capable of making bitumen hydrophilic but only under acidic conditions. Only hydroxypropyl cellulose (HPC) produced a large decrease in the steady-state contact angle under alkaline conditions (pH 8.5). The kinetics of contact angle evolution in the presence of HPC was also drastically lowered. The results were discussed in terms of the chemical composition of the polymers and their different affinities towards the bitumen surface."

Jan 1, 2014

By Robert H. Bedford

The Rogan-Mallery tin property is in the foothills on the south slope of the Tehachapi Mountains, Kern County, Calif. It was first visited by the senior author in August 1942, and exploration by means of trenching and diamond drilling began in May 1944 and was concluded in August of the same year. Cassiterite, associated with iron-rich gossan, occurs in a limestone roof pendant at places near or at its contact with the underlying granitic rocks. The cassiterite grain sizes range from 20 mesh to 150 mesh. Surface and diamond-drill samples showed tin ranging from traces up to 122.6 pounds per ton. Exploration by the Bureau of Mines included 2,100 cubic yards of trenching and the drilling of 11 diamond drill holes totaling 1,000 feet. Dana Hogan, president of the Rogan Petroleum Co. of Los Angeles, Calif.) brought these projects to the attention of the Bureau of Mines in July 1942, and the following month a Bureau engineer made a preliminary examination in company with Hillard Mallery, of 408 Ruby Street, Redondo Beach, Calif., the man who discovered them.

Jan 1, 1949

By John Ellenberger

The National Institute for Occupational Safety and Health (NIOSH) has collected pillar and span data at 34 stone mines in 10 states to develop pillar and roof span design guidelines for underground stone mines. Pillar, floor and roof conditions each contribute significantly to the overall mine stability. The roof may be stable for a century, or it may appear to be stable but fail with little warning. Clearly, an assessment of the mine roof is critical to the safety of these operations. However, up until now, the assessment of the mine roof came primarily from exposures in roof falls or portal areas. This provides only limited information, and a more proactive approach is needed to assess changing mine conditions. A separate effort was undertaken to examine the roof structure with the use of a borescope. Numerous physical and geologic roof structures were observed with a stratascope/borehole video camera. The objective of this work was to develop a technique of assigning numerical values to features seen within the mine roof and apply those values to formulate a roof stability evaluation. Such features as changes in color, grain size, and general lithologies are readily observed. Minor structures in the rock, fossils and fractures are also readily identified. Each feature may have a variable and site-specific impact on roof quality. A number of mines were visited and a series of holes were borescoped in each mine. The features identified in the roof were classified and potential for roof damage related to each feature was assessed. A process is presented that relates the structures and their locations to provide a numerical value, or roof quality index that can be used to assess roof stability.

Jan 1, 2009

By A. Bastrzyk

Text The mining and refining of minerals generates large amounts of solid waste. The waste from cleaning operations constitutes up to 90% of the total production. Although some of them can be used in mining, civil enegineering, construction, agriculture, most of them must be disposed in dumps and slurry ponds, causing major economic and enviromental problems (Alonso, 2002; Alon-so, 1999). The refuse from minerals cleaning may have considerable valuable particles content, which can be used in industry. Thus, the recovery of these particles from minerals waste by using a cleaning method effective at fine particle size, may overcome these consequences. Surfactants are used in numerous applications including emulsification and solid surface modification. In the oil agglomeration of minerals, the ionic surfactants (both anionic and cationic) are used for the hydrophobization of mineral surface and the oil-water emulsion preparation. When the cationic surfactant is injected into the oil-water mixture, surfactant molecules adsorb at the oil-water interface, changing droplets? properties. The addition of anionic surfactant to the mineral suspension was found to modify the solid-liquid interface. In this paper, the condition and mechanism of selective separation of magnesite from quartz are presented. A satisfactory was achieved with the amount of anionic collector (sodium oleate) equal to 15.2 mg/gsolid and with the amount of cationic collector 27.9 mg/gsolid for cetyltrimethylammonium bromide (CTAB) and 16.9 mg/gsolid for dodecyloammonium hydrochloride (DDAHCl) at pH 8. At these conditions, the amount of agglomerated carbonates was about 12% for CTAB and 5% for DDAHCl.

Jan 1, 2014

By Francis Foley

INTRODUCTION DURING the summer of 1919, the late Dr. Henry M. Howe, then Chairman of the Division of Engineering of the National Research Council, organized a committee to obtain a better insight into the behavior of carbon steels under the influence of various treatments by a proper control of the time and temperature factors. During part of 1919 and 1920, work in connection with this investigation was carried on at Dr: Howe's laboratory at Bedford Hills, N. Y. During 1921 there was an enforced hiatus in the work, occasioned by the illness which resulted in Dr. Howe's death in 1922. At that time one of the present authors compiled the results of the work which had been done and this was published in 1923.1 Following the publication of this work, it seemed desirable to carry on in the same manner an investigation of steel of C 0.75 per cent., which steel had not been as fully treated as had the other steels of C 0.34 and 0.52 per cent., used in the published work. Furthermore, certain unusual results have been obtained in the treatment of C 0.52 per cent. steel by quenching and drawing, and repetition of this part of the work seemed advisable. This has been done during the past year at the School of Mines and Metallurgy of the University of Missouri at Rolla, Mo., by a cooperative undertaking of the School and the Bureau of Mines, working in conjunction with the Committee on Heat Treatment of Carbon Steels of the National Research Council. The present paper is a report of the results obtained in this work.

Jan 2, 1926

By J Simpson, M Johnston

Recently Mount Isa Mines undertook a study to review the lead-zinc orebodies to extent of resource and reserves and determine the new life-of-mine schedule, as the Mount Isa and Hilton orebodies had not be reviewed for many years. Also, the recovered value of the Mount Isa, Hilton and George Fisher orebodies had been increased by major performance improvements in the lead-zinc concentrator. The Mount Isa Lead-Zinc concentrator processes fine-grained lead-zinc ore from the Mount Isa, Hilton and George Fisher orebodies. These orebodies have varying levels of pyrite and large variation in the grain size and texture of the galena, sphalerite and pyrite. This variation has a large effect on the recovery of the lead and zinc in the concentrator. Some ores achieve 90 per cent recovery at target grades, yet other ores are unable to achieve æsaleableÆ concentrate grade, with no metal being recovered to concentrate and therefore effectively losing the contained metal to the final tailings. Models were created to predict the metallurgical performance of these orebodies, to better reflect the variation that occurs. These improved metallurgical models and economic data allowed the determination of the Net Smelter Return (NSR) for each block in the geological block model. This NSR is the return to MIM of the metals contained in concentrate. The NSR was used as the cut-off grade criteria when determining the value of the ore. This formed the basis of the lead-zinc life-of-mine schedule and the optimisation of the lead-zinc business.

Jan 1, 2003

By W. W. Adams

[S,1.1.8'"' of explordves -permissible explosivos,21 other high explosives, and black blasting povrder -in the Uni ted States during the caJ.endar yenr 1937 reached a ~ombined total that slightly exceeded the quantity sold in 1936. A larger output was re orted. for permisAiblA and other hig! explosives but asmal-ler for black po~~er. Production of the three classes of explosives totaled 404, 744,294 pounds, more than 3 pel'CGnt over 1336. The total qrumti ty produced included 49,579,441 pounds of perminsibles, 2~8,924,253 pounds of other high ex-plosives, 36,403,950 pounds of black powder in pellet form, and 29,836,65q pounds of bla~k powder in granular form.]

Jan 1, 1938

By P. R. Taylor

A reaction is evaluated by which heated and pressurized water is used to precipitate metal oxides from loaded Kelex 100 complexes. Pure copper oxide (CuO) and pure nickel (Nio) in powder form, and ranging in average size from 12 to 25 micrometers, were found to precipitate from copper and nickel loaded Kelex 100/kerosene complexes, by water heated and pressurized to between 374 and 400 °c and 2170 psig (148 atm) and 3500 psig (238 atm). The precipitation is suggested to result from hydrolysis of the metal, following exchange for the hydrogen in the phenolic hydroxyl of the Kelex 100 structure, enhanced by the conditions provided by heated and pressurized water. The reaction is believed to have the characteristics of homogeneous nucleation and heterogeneous growth. The effects of temperature, pressure, initial metal concentration and seed addition on the kinetics of the process were studied. In addition, characterization studies were performed on the reaction products. A detailed discussion of the experimental results is presented.

Jan 1, 1992

By L. Y. Wang

In order to produce the iron and steel products with high quality and decrease the output of steel tailings, the quality of molten iron is a critical factor for iron and steel companies, especially the content of sulfidic in molten iron. Hot metal pre-treatment, an important and effective method to desulphur, is widely used in steel production. Millions of tons of slag from desulphurization and slag skimming are produced each year in China, and many more times this amount is stored in slag dams because of the lack of effective means to deal with it. In order to achieve the goal of sustain-able development, recycling these slag becomes necessary. The main objective of this paper is to study the composition characteristics of slag that from desulphurization and slag skimming. The sample was obtained from Anshan Iron and Steel Group Corporation, processed by hot metal pre-treatment. In this study, the chemical components and the mineral compositions of sample were tested. The results of chemical components and iron chemistry phase analysis showed that the iron and sulphide content in this sample were high, and the iron products existed mainly in the form of magnetite, metallic iron, ferrosilite. X-ray diffraction (XRD) and scanning electron microscope (SEM) results indicated that the sample included metallic iron, ferrate, wustite, metasilicate, aluminate, aluminosilicate, white lime and soon. Grading magnetic separation test work showed that magnetic separation was an effective method to recovery iron products and decrease the sulphide content in concentrate, and the tailing could be used as the raw material or padding in cement production.

Jan 1, 2014

By G. A. Bole, F. W. Davis

The purpose of this paper is not to report, to the Institute, the results so far obtained in the survey, by the Bureau of Mines, of the metallurgical requirements for open-hearth refractories, but to present an outline that we hope will serve as a basis for discussion. The systematic survey that the Bureau proposes to make has not been outlined, although considerable preliminary work has been done in the way of interviewing open-hearth superintendents in several of the larger steel plants from the Chicago district eastward. At the several conferences so many of the opinions were diametrically oppoeite, when considering the same point, that it was thought that such an opportunity as the Institute offers in the way of a clearing house for moot metallurgical topics should not be overlooked. For this reason, the paper has been prepared as a basis for a discussion which, it is believed, will be of value in outlining the program of the Bureau. D. A. LYoN, Assistant Director. The importance of securing suitable refractories for metallurgical operations is daily becoming more universally recognized; particularly in the manufacture of open-hearth steel, where the life and earning power of the furnace depends largely on the judgment and care exercised in the selection of the correct quality of refractory for each of the parts. Any innovation that would make available to the steel manufacturers refractories with longer life or better suited to their needs than those now employed, and at a cost that would permit of their use, would be of enormous value to the industry at large. It is quite probable that revolutionary changes would not be necessary. Material now used in some parts of the furnace might, by more suitable preparation, be made of much greater service; in other parts, possibly entirely different material would be necessary in order to effect much improvement. Inasmuch as different parts of the furnace structure perform different functions and are subjected to different service conditions, a refractory suitable for one part will be entirely unsuited for another. For this reason, to make a comprehensive study of the refractory requirements of the processes, we should consider the furnace as built up of a number

Jan 1, 1924

By J. Juilland

Over 10 percent of the United States of America or 41 percent of the Federal lands is managed by the Bureau of Land Management (BLM) as Public Lands. The mission is to manage the use of these lands and their resources. The way in which BLM carries out its mission is being refocused under the concepts of biodiversity and ecosystem-based management for the benefit of various human needs including environmental, social and economic values. The Bureau is developing methods to integrate the renewable and non-renewable resources programs into the concepts of biodiversity and ecosystem-based management. Exploration, development and extraction of energy or mineral resources on Public Lands are affected. The statements that following the next few pages are my personal views as a scientist (economic geologist -mining technologist) who is and has been involved for the last twenty years in the multiple-use management of Public Lands. They are not necessarily the position of the Bureau of Land Management, although much of the information on which I base my views comes from my experience with the BLM. The Bureau of Land Management (BLM) manages over 10 percent of the United States (270 million acres or 108 million hectares) which is 41 percent of the Federal Lands. Lands managed by BLM are known as Public Lands as opposed to the National Forest Lands which are Federal Land Policy and Management Act (FLPMA) of 1976 which in Sec. 102 states ??that it is the policy of the United States (7) ?that management be on the basis of multiple use and sustained yield??, the mission of the BLM is rapidly refocused under the concepts of biodiversity, ecosystems, and ecosystems-based management for the benefit of the environment, human needs and socio-economic values.

Jan 1, 1994

By Kimio Itagaki

"As a contribution to understand the smelting of copper or nickel matte by blowing oxygen or oxygen-enriched air, the phase equilibrium and the distribution of minor elements between the iron-silicate based slag and the Cu2S-FeS or Ni3S2-FeS matte at 1573K were investigated in a magnesia crucible under controlled partial pressures of SO2 at 0.1, 0.5 and 1.atm. At a given matte grade, the solubility of copper in the slag was found to be independent of p5O2 while that of nickel was dependent on pSO2 and these behaviors were analysed thermodynainically based on a concept of oxidic and sulfidic dissolution of the components in the slag. When the matte grade was specified, the distribution ratios of X, defined as (wt pct X in slag)/(wt pct X in matte}, for As, Sb and Bi increased with increasing p5O2 while that for Ag was constant against p5O2.IntroductionA combination of intensive reactors with the use of oxygen or oxygen-.enriched air as the blowing gas has provided a number of improved copper and nickel smelting processes such as INCO-Flash, Outokumpu-Flash, Mitsubishi-Continuous and IBRC (top blown rotary converter) processes. Phase equilibrium and thermodynamic studies for the slag and the copper matte or the nickel matte under high partial pressure of SO2 are of practical importance for evaluating the behaviours of the related components in the oxygen-smelting.A series of experimental studies have been already conducted in a limited range of conditions for Pso2 around 0.1 atm, which corresponds to the smelting with air-Stowing [1-5]. However, there remain very few data on the phase equilibrium in the matteslag systems under higher partial pressures of SO2. Tavera and Davenport studied the phase equilibrium between the copper matte and fayalite slag phases under the partial pressure of SO2 controlled at 0.1 - 1 atrn but without controlling the partial pressures of sulfur and oxygen [6]. A potential diagram for the Cu-Fe-S-O-SiO2 system at 1523 - 1573K suggests that the partial pressure of S2 equilibrated with the matte and the fayalite slag with saturated SiO2 under the high SO2 pressure is considerably high at 10-4 - 10-2 atrn [7]. This condition must require controlling of p52 as well as Pso2, in the equilibrium experiments, otherwise, the equilibrium condition may be hardly attained due to the continuous flushing of sulfur from the system."

Jan 1, 2000

St. Peter sandstone is very different from the minerals and rocks that have been studied extensively in mining. On the one hand, it is brittle as characterized by an unusually high friction angle and steeply curved failure envelopes. On the other hand, it is friable, possessing extremely low, and in most cases zero cohesion. The scarcity of the ground control techniques for this particular mining environment has created many difficulties for the mine operators. In order to resolve these problems, the geotechnical properties of the St. Peter sandstones were investigated through a comprehensive research program, which included uniaxial test, triaxial test, porosity test, thin section, X-ray diffraction (XRD), and scanning electron microscope (SEM). The specimens used for the uniaxial and triaxial tests were specially prepared because of the highly friable nature of the St. Peter sandstone. Thin section, XRD and SEM were utilized to examine the effect of the microstructure of the St. Peter sandstones on its strength characteristics.

Feb 27, 2013

By Carl Verholek

Remote control systems for industrial applications have advanced since the early 20 years, increasing its capabilities by utilizing new electronic technology. This electronic “tool” has benefited many mining operations, making them a safer place to work and at the same time more productive. Almost any operation that presently uses a man at the controls of the machine or using a wired tether control, is a candidate for improvement by the addition of a remote control. Remote control systems add safety, reliability and productivity at a cost that is usually recovered in mere months after installation.

May 25, 1998

By Welby G. Courtney

The Bureau of Mines conducted a field test program in the Pittsburgh coal seam to investigate the effect of water sprays in the suppression of respirable dust being formed while cutting with a continuous-mining machine. Emphasis was given to the location of spray nozzles on the top and bottom of the cutting boom. Results showed that (1) sumping caused about 60 percent of the dust escaping the face area, and shearing and loading caused the other 40 percent; (2) during sumping, top and bottom sprays were equally effective in dust suppression and reduced dust ~13 percent; (3) during shearing and loading, bottom sprays reduced dust 61 percent and were about 50 percent more effective than top sprays; (4) the combination of top and bottom sprays was slightly more effective than the separate systems, but water consumption increased 60 percent; and (5) inclusion of throat sprays decreased dust reduction by removing some of the water from top and bottom sprays where it was more effective.

Jan 1, 1978

The N3500 orebody is the northern continuation of the 3500 orebody at Xstrata Copper's Enterprise Mine and occurs at a depth of 1.3 to 1.8 km. At the nearby S3500 orebody, extreme deformation was observed in access drives where there was a high number of bedding planes per metre combined with either graphite or talc infill. The observed failure mechanism was largely controlled by the geometry of the inclined bedding submitted to high horizontal stresses. Due to the anisotropic strength and deformation behaviour of the shale rock mass, traditional isotropic methods of geomechanical property estimation based upon GSI are not appropriate. A numerical modelling approach, based upon the distinct element codes UDEC (2D) and 3DEC (3D), has been developed to accurately simulate the failure mechanisms and deformation observed in the initial infrastructure surrounding the N3500 orebody.

Nov 25, 2010

By Paul Merica

ALTHOUGH nickel was discovered and isolated as early as 1750 and its valuable properties recognized, many years passed before it was used commercially for wire, sheet, rods, etc., in the pure form. This was due partly to its high cost at that time and partly to the fact that it was not possible to refine and cast nickel into ingots sufficiently malleable to be amenable to the usual forging, rolling, or drawing processes. So remarkable was this fact, and so different from the experience at that time with metals such as copper and iron, that it has left its impress on the no-menclature within the nickel industry. To this day, furnace-cast nickel produced in such a manner as to be suitable for rolling and forging is called malleable nickel to distinguish it from the ordinary pig and shot nickel of commerce. In 1878, the firm of Jos. Wharton, of Philadelphia (which later became The American Nickel Works, a constituent of The International Nickel Co.) exhibited at the Paris Exhibition specimens of rolled pure nickel strip and of drawn nickel wire. About this time, there was considerable activity in the study of the refining of nickel and several methods were described, some of which were patented, for the production of furnace-cast malleable nickel including the use of manganese (Boed-dicker,1 Selve and Lotter2), the use of potassium permanganate (Bernsdorfer Metallwarenfabrik3) and the use of phosphorus (Garnier4). By far the most efficient method was discovered by Th. Fleitmann in 1879;5 it consisted in adding to the molten nickel, just before pouring the castings, from 0.05 to 0.125 per cent. of metallic magnesium. This soon became the recognized final malleableizing treatment for furnace-cast nickel.

Jan 1, 1925