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By M. F. Dibble

The Fosfago phosphate rock concentrator is located in the state of Goias, Brazil, 300 km south of Brasilia. The ore is from an enriched carbonatite, which was discovered in 1971 during exploration for pyrochlore niobium ore. The flowsheet was developed in Brazil by personnel from Agrico Chemical Company and Consolidated South America. Engineering was provided by Codemin, a subsidiary of Consolidated, Engineering and construction management was pro- vided by both Agrico and Consolidated personnel who formed the Fosfago team. The concentrator was designed for 500,000 tpy of 37-38% P2Oj dried product. The facilities consist of open pit mining, crushing, stockpiling, and concentration. The product is pipelined seven km to a filtering, flash drying, and railroad loadout station. The plant was successfully started in May 1979.

Jan 1, 1980

The Cadia Mine is located 25kms South West of Orange in the central west of New South Wales (NSW), Australia (Figure 1). Orange is a major regional centre with a population of 35,000 people. Cadia has a history of mining and exploration dating back to 1851 and shortly after the first Australian gold rush at Ophir, north of Orange. Newcrest Mining commenced an exploration program at Cadia Hill in 1992. This identified a substantial zone of copper and gold mineralization. Subsequent resource definition drilling defined an orebody with a mineable reserve of 200 million tonnes of ore with an average gold grade of 0.74g/t and 0.17\ copper. A full feasibility study commenced in 1994, approvals to proceed with development were granted in September 1996 and the processing plant was commissioned in July 1998. The project came in on budget at A$440 million and on time, 24 months from design to construction. The estimated operating cost at the time of commissioning was A$8.85/t of mill feed.

Jan 1, 1999

By FREDERICK C. BROWN

THE practice of fine-grinding is now being so successfully - carried on in some fields, notably in West Australia, and its advisability has been so frequently pointed out' that the matter in this paper is not put forward as being new ; its chief object being to call attention to the importance of fine-grinding in the treatment of comparatively low-grade ores. I have been engaged during the last five years in the cyanide-treatment of ores in the Ohinemuri district (North Island), New Zealand, and I consider that, in the near future, extremely fine-grinding (almost sliming) will become a very important feature of the milling-methods in this field, since it seems absolutely necessary to reduce the most of ores to a very fine state of division if a high extraction is to be obtained; and, in most cases, the extra percentage of saving will leave a good margin above the increased cost of treatment due both to the fine-grinding and to the interest on the capital spent for the grinding-machinery. The average ore of the Ohinemuri field is composed of a quartz-gangue with some calcite, carrying the gold-value in the form of an alloy of gold and silver in about equal proportions, and the silver-value in the form of mixed sulphides of silver, usually associated with a considerable amount of iron pyrites. In the upper levels, the ores are decomposed and carry large quantities of black manganese oxide and some iron oxide, but, as. depth is reached, the decomposed ore gives place to sulphides and, in some mines, rhodonite, manganese silicate, is present in fairly large quantities. The average value of the

Jan 1, 1906

By Stephen R. Iverson, Jeffrey C. Johnson, Donovan J. Benton, Michael J. Raffaldi, Lewis A. Martin

"The NIOSH ground control safety research program at Spokane, Washington, is exploring applications of photogrammetry to rock mass and support monitoring. This paper describes two ways photogrammetric techniques are being used. First, photogrammetric data of laboratory testing is being used to correlate energy input and support deformation. This information can be used to infer remaining support toughness after ground deformation events. This technique is also demonstrated in a field application. Second, field photogrammetric data is compared to crackmeter data from a deep underground mine. Accuracies were found to average 8 mm, but have produced results within 0.2 mm of true displacement, as measured by crackmeters. Application of these techniques consists of monitoring overall fault activity by monitoring multiple points around the crackmeter. A case study is provided in which a crackmeter is clearly shown to have provided insufficient information regarding overall fault ground deformation. Photogrammetry is proving to be a useful ground monitoring tool due to its unobtrusiveness and ease of use.INTRODUCTIONNIOSH Mine Safety ResearchPhotogrammetry systems have been implemented by the National Institute for Occupational Safety and Health (NIOSH) as part of its ground control research to improve mine safety. Conventional monitoring of ground movement has typically focused on movement of a few discrete points that are marked or anchored to instruments. Loss of a designated point or anchor, or the ability to identify a stable point in an unstable area, have often frustrated monitoring efforts. NIOSH researchers are using photogrammetry to conduct full-field measurements of rock surfaces underground. Periodic measurements of the entire surface of a ramp allow patterns of displacement to be observed. Full-field measurements provide much more insight into ground behavior than point measurements.BackgroundPrevious work by Benton, et al. (2014) discussed laboratory calibration and verification testing of two photogrammetry systems being used by NIOSH researchers. Both systems utilize stereoscopic image pairing techniques for photogrammetric reconstruction. This paper discusses how a laboratory system was used to conduct volumetric analyses of testing of shotcrete panels with varying types of reinforcement. The laboratory system was found to be accurate to within 2 mm. Additionally, a field photogrammetry system was found to produce linear measurements within 1 mm of known lengths in laboratory conditions. This system is currently being used at a deep underground mine to observe ground support conditions and deformations that have occurred. This paper discusses comparison of preliminary volumetric measurements of rib deformation to laboratory tests, as well as comparison of the field system against a crackmeter installed across a fault surface where it intersects the ramp."

Jan 1, 2015

By George S. Rice

The extremely valuable papers and discussions on coal-cluat explosions by Bache,' Eavenson, Shurick, Mannakee,* and Raymond are of unusual interest to me, since it has been my duty to carry on investigations on this and allied subjects for the Technologic Branch of the United States Geological Survey during the past year, and to make a series of coal-dust tests in the explosion-gallery at Pittsburg during a short periocl when its use could be diverted from the pressing work of testing explosives. In several of the discussions mentioned, it has been assumecl that the Technologic Branch of the Survey mas not paying attention to certain phases of the general problem, or to the specific question of temperature and humidity of mine-air in its effect upon the explosibility of coal-dust. This assumption is not correct, since from the time of the establishment of the " Mine-Accident Division," with its subdivisions of explosives, rescue-work, and mine-investigation, the mining engineer.; of the last-named section have made the subject one of chief consideration. Their general duties, including mine-sampling for governmeilt purposes, emergency-calls for rescue-work, and esplosion investigations, have prevented undivided attention, but all of them have been supplied with instruments for such determinations, and special report-forms have been in use and a great many observations made in mining-districts to which the mining engineers have gone. With the idea of obtaining a uniform system of reporting these data, and in the hope that the work may be of service to mining engineers in the field, the collecting blanks in use are shown in Forrns 1 and 2.

Jan 1, 1911

By C. C. Harris

An analytical solution of the integro-differential equation of batch grinding is proposed as a first appoximation to the xYt surface. The size distribution equation (xY plane) is a three parameter equation previously suggested. Possible refinements are outlined. Comminution kinetics research is presently following several related courses. Some are equivalent, in that they represent different ways of viewing the same facet of the problem, though the entire endeavor cannot be described as being completely integrated. The purpose of this note is to propose and discuss a framework into which the various approaches might be fitted. This must clearly be founded upon an analysis of the xYt surface.' (See also Fig. 1 of Reference 26.) The investigations referred to above comprise mainly researches into the following: (1) The kinetics of the creation of the finer sizes during relatively small grinding times. This is the Fahrenwald-Arbiter-Bhrany 2-3 approach which leads to equations equivalent to a special case of the charles4 relationship. It emerges that initial production of fines follow essentially zero order* kinetics. (2) Disappearance kinetics of the coarser fractions. This appears to be a first order relationship.5-6 (3) Prediction of the xYt surface via the selection and breakage functions utilizing computer-programmed or approximate solutions of the integro-differential equation of batch grinding.5,8-17 A recent discussion by Mika et al.5 references the relevant literature up to about 1966. In addition to these main-stream researches there is some work on the minor topic of extremely long grinding time considered as a limiting case.18-19 The field is supported by investigations into the size distribution of fragments produced by breakage processes, some of this work being most valuably statistical-mechanical in nature.20-25 Better fitting equations, however, are obtained by statistical and curve-fitting methods.26 This

Jan 1, 1969

By G. Springer

The identification of lost mineral values in mill tailings frequently requires the inspection of hundreds of thousands to millions of particles. The search of these particles can be made automatic by using an electron microprobe. A standard instrument (Cambridge Mark V) was modified by the addition of stepping motors to advance the specimen stage in a controlled manner. The X-ray Signal is monitored continuously by a computer interfaced to the instrument with an analog-to-digital converter. 400,000 particles of a tailings sample can be scanned in about 3 hours. Particles as small as 2 um and containing as little as 3% of a particular element can be detected.

Jan 1, 1982

By D. Farrish, W. A. Grell

"IntroductionMost base metal mines sell their concentrate to a custom smelter. The two parties concerned therefore draw up a contract which would detail the conditions under which concentrate sales will take place. The contract will identify treatment and marketing charges (including escalations), deductions for metal losses in the smelter, pricing formula, timing of payments, penalties for deleterious elements, etc.An understanding of the smelter contract is important to the mineral processor, for it will determine how he operates the plant to maximize economic return.Description of Contract ClausesUsing copper concentrate as an example, the smelter contract generally contains the following three basic charges:I. Metal Deductions- as the smelting process does not recover all the metal contained;2. A Smelting Charge- expressed per ton of material to cover costs on the bulk material such as receiving, unloading, thawing in winter, sampling, roasting to drive off sulphur, smelting through the matte and blister stages to recover mostof the copper and precious metals;3. A Refining Charge- expressed per pound of copper.The following is a review in some detail of a number of clauses which could be considered typical of a treatment and marketing type of copper concentrate sales contract. Most normal considerations in an agreement could be covered by the following types of clauses.Terminology- covers definitions, units of measurement to be used (e.g. short tons, troy ounces, etc.), currency (Canadian dollars). The term ""unit"" may be defined - l OJo of a ton of concentrate, e.g. one unit of copper means 20 pounds of copper per short ton of concentrate."

Jan 1, 1989

By Kenneth Trelewicz

This report describes the total effort that went into developing environmental test criteria for general mine instrumentation. The project was a two-phase effort. Phase I consisted of research and mine visits to develop an environmental profile for mine instrumentation. The profile was translated into general requirements and then into test requirements. A review of existing government and commercial specifications was performed to determine if they matched mine instrumentation test requirements. Finally, a set of environmental test procedures was developed for the testing of mine instrumentation. Phase II consisted of selecting and purchasing sample mine instrumentation and subjecting them to the previously developed tests. The purpose was twofold: (1) to evaluate the criteria developed for use as an instrumentation test document and (2) to determine the effects of the various criteria on a representative sample of both proven and newly developed instrumentation. The test criteria were then modified, based on the results of the testing, and are listed therein.

Jan 1, 1981

By B. Q. Li, H. C. de Groh, X. Lu

"A fully 3-D, transient finite element model is developed to represent the magnetic damping effects on complex fluid flow, heat transfer and electromagnetic field distributions in a metallic melt. The model development is based on our in-house finite element code for the fluid flow, heat transfer and electromagnetic field calculations. The numerical model is tested against numerical and experimental results for water as reported in literature. Various numerical simulations are carried out for the melt convection and temperature distribution with and without the presence of a transverse magnetic field. Numerical results show that magnetic damping can be effectively applied to stabilize melt flow, reduce turbulence and flow levels in the melt and over a certain threshold value a higher magnetic field resulted in a greater reduction in velocity. Also, for the study of melt flow instability, a long enough running time is needed to ensure the final fluid flow recirculation pattern. Moreover, numerical results suggest that there seems to exist a threshold value of applied magnetic field, above which magnetic damping becomes possible and below which the convection in the melt is actually enhanced.1. INTRODUCTIONThe imposition of a DC magnetic field on a moving, electrically conducting fluid, such as molten metal or semiconductor melt, produces an opposing Lorentz force that results in a reduction of flow velocity in the liquid. This effect has been explored in both the semiconductor and metals industries to control natural convection and/or surface tension induced Marangoni convection as well as thermally induced flow instability during solidification processing of these melts [1-6]. A mathematical model can be of great use in developing both fundamental understanding of the fluid-magnetic field interactions in these magnetically-assisted processing systems and basic guidelines for process design, control and optimization.This paper presents a 3-D mathematical model for magnetically damped fluid flow and heat transfer in a melt cavity, which is useful for interpreting results for unidirectional solidification processes at slow solidification rate, and some preliminary results concerning the magnetic damping effects on the flow instability in the melt. The model development is based on the finite element solution of the Navier-Stokes equations, energy equations and equations for induced electric field. The model is tested against reported results and is then applied to study the fluid flow and thermal distribution in the metallic melt with and without an external magnetic field."

Jan 1, 1999

By D. W. Fuerstenau, S. Raghavan

This paper presents a brief summary of some of the thermodynamic aspects of flotation processes. Thermodynamic considerations that control interfacial and wetting behavior in mineral/water/air systems are discussed. Particular attention is given to the thermodynamics of collector adsorption.

Jan 1, 1976

By J. W. Lyman

The U.S. Department of the Interior, Bureau of Mines, investigated methods to recover valuable rare-earth materials from NdFeB magnet scrap. Although several processing techniques were evaluated" the best separation of rare earths from the NdFeB magnet ,scrap was obtained by sulfuric acid dissolution followed by precipitation of recyclable rare-earth salts. Both sodium and ammonium intermediate double-salt precipitates' that can be converted to a variety of useful neodymium products were investigated. The sodium system showed a neodymium recovery of 98 pct, while the ammonium system yielded 70 pct during double-salt precipitation. The iron-rich effluent following the rare-earth recovery was treated to produce sodium and ammonium iron jarosites that can be disposed of or converted to hematite. By following this new procedure, many materials handling and economic disadvantages found with fluoride or oxalate direct precipitation were avoided.

Jan 1, 1992

By M. N. Brodie, John Chapman

INTRODUCTION - DEFINITION & HISTORICAL PERSPECTIVE While this symposium is concerned with comminution which, by definition, relates to all stages of size reduction of an ore body to a form suitable for mineral separation, the electrical drive aspect of the grinding section will receive most attention in contrast to the crushing, screening and materials handling elements of the process. The reason for this is that today's large mills, thirty feet diameter and upwards, present mechanical and electrical problems which require a degree of sophistication in their solution not previously required. The ability to satisfy these demands, so far as electrical technology is concerned, largely results from the development of semi-conductor devices. These can now handle typical electrical distribution power levels within remarkably s m all volumes and with high efficiency when compared with the motor-generator sets, mercury arc rectifiers, rotating amplifiers, magnetic amplifiers and vacuum tubes which were commonly used to provide speed and torque controls as recently as the early nineteen-sixties. The hardware available to the electrical engineer has changed dramatically whereby even the simplest control system formerly using hard-wired relays is now superseded by the program m able logic controller with its computer-like memory containing the sequence of operation, in other words, the software. Reverting now to the mineral process itself, it is assumed that the ore body has been mined using explosives and is delivered to the concentrating plant in its 'run of mine' form. The problem becomes one of reducing the material to a size which will permit an acceptable recovery of the mineral with the most economical use of energy. The size of 'run of mine' material will range from about minus five feet for high tonnage open pit operations to minus two feet for the smaller underground mine. The final reduction in size may range from minus ten mesh to minus two hundred mesh (exceptionally as fine as minus six hundred mesh) depending upon the concentration method and dissemination of the mineral values within the ore. There is no single circuit that satisfies all applications, but the pattern of metallurgical equipment use shown in Table 1 appears discernable from current practice, in general terms.

Jan 1, 1982

By S. S. Solomons, V. H. Tillmann, L. Smaniotto

INTRODUCTION The Zinc Corporation, Limited and New Broken Hill Consolidated Limited (ZC/NBHC) mines are situated at Broken Hill, New South Wales, Australia (refer Fig. 1). Both companies are wholly owned subsidiaries of Australian Mining and Smelting Limited (AM&S). Annual production from both mines is 2.3 million tonnes of lead, silver and zinc ore mined by a variety of underground methods. From 1911 to 1968, conventional overhand cut and fill stoping (both open and square set timber) was used almost exclusively, though some trials with shrinkage and sublevel stoping were undertaken. The trial stopes used short holes in conparison with today's sublevel open stopes. Mechanised cut and fill methods with regular rockbolt support were introduced in the early 1960's and undercut and fill stoping replaced square set timber stoping for pillar extraction in the late 1960's. Since 1968, increasing emphasis has been placed on longhole open stoping (LHOS) although some areas of the orebodies are comrnrnitted to the abovemehtioned methods since existing stope development makes it impracticable to change. In 1979, approximately half the total production was mined by LHDS and it is expected that the LHOS proportion will increase in the future. A vertical crater retreat method of longhole mining has also been successfully introduced to replace the undercut and fill stoping of some pillars and it is expected that this stoping method will be used in some future primary ore extraction. This paper reviews the progress of LHOS technology at ZC/NBHC with emphasis on the stope planning and design process and the importance of rock mechanics applications. The objective has been to maximise the primary extraction of the orebody giving due consideration to stability and safety. This has led to the design of a novel sloped wall longhole stoping method which should eliminate the formation of pillars by mining the orebody in a "continuous" manner incorporating a sloped sand interface between the blocks of ore being mined and the previously mined sandfilled stope. The expected results include the complete extract of the orebody without the formation of pillars and with minimal dilution of ore with sandfill. The evolution of the method can be best illustrated by following the mining progress of the relatively new Southern 'B1 Lode orebody at the NBHC mine. GEOLOGY Southern '8' Lode is the southern extension of the 'Bt Lode orebody, which is currently being mined further to the north in ZC/NBHC (refer Fig. 2). The ore block being developed and stoped extends for a vertical height of 90 metres from No. 17 level down to approximately ten metres above No. 19 level. The ore minerals are sphalerite and galena with the zinc:lead ratio averaging approximately 3:l with a minor amount of silver associated with the galena. There is a sharp contact between the ore and the country rock on the footwall and keel, while the hanging wall gradates into medium and low grade material. The gangue is primarily quartz together with garnet, biotite, feldspar, gahnite, sericite and minor apatite. In various horizons within the orebody, grey feldspar, quartz and garnet pegmatites occur as stratiform layers. The ore and country rock are competent with some inconpetent boundaries.

Jan 1, 1981

By Meimei Zhang

In the overall open pit mine planning process, mining phase design is a strategic driver in guiding and constructing the block extraction sequence and determining the annual net cash flow distribution. Mining phase design should obey some practical constraints, such as ?minimum mining width? and ?flat mining phase bottom?, to allow space for haul road development and truck and shovel access on each bench. However, these practical mining phase design requirements are not taken into account in all first-cut mining phase design methods and post-processing is always required to convert an impractical design to a practical one, resulting in a potentially significant loss of Net Present Value (NPV) relative to the first-cut impractical designs. In this paper, we present a method using a meta-heuristic algorithm ? Simulated Annealing ? to enforce those practical constraints in determining a mineable phase design whilst ensuring minimum NPV loss.

Oct 1, 2009

By Leizhang Gao, Zhengfeng Qu, Pingsheng Lai, Chenguang Bai, Meilong Hu

FFC process could be used to prepare titanium foams. The mixed oxides CaO-TiO2 with mole ratio 1:2 were sintered into CaTiO3-TiO2 mixture. CaTiO3-TiO2 was then used as cathode and electrolyzed in molten CaCl2 to prepare porous titanium. The porous titanium with the porosity of about 72.15% was first fabricated. The internal pores are in the presence of circular cavities and the pore size is in the range of 50–100 lm. Compared with the powder metallurgy technique using the space-holder this method promises to be lower cost and less processing. It is potential to fabricate titanium foams using FFC process.

Mar 1, 2018

By H. G. Doll

The S.P. log is shown to be a measurement of the potential drop along the drill hole, caused by ohmic effect in the mud. The notion of static S.P. is brought forward, and its relation to the S.P. log is discussed. Other factors influencing the shape and amplitude of the log are considered; attention is given to conditions encountered in practice. Numerous figures are given illustrating graphically the results; these figures are of particular interest for comparison with field examples. The S.P. log, although indicating permeability, is not an absolute measurement of permeability, nor of porosity, of the formations traversed by a drill hole. It is affected by several parameters, such as resistivity of formations and mud, thickness of formations, and others, which should be appraised carefully. Simple rules have been established for a better distinction of the boundaries of permeabl: sections, particularly in difficult cases, such as those encountered in highly resistive formations. A systematic application of the established principles will assist in obtaining more information from the S.P. log than was possible thus far; for instance, under favorable conditions, presence of oil may be detected, or amount of shale in sands may be estimated. Introduction The S.P. log, or spontaneous potential log, has been known and widely used during the last 15 years for the location of permeable beds traversed by drill holes.1,2 In electrical logging practice, the S.P. log is shown on the left hand side track of the record (as may be seen in later examples) where it can be easily correlated and interpreted with the resistivity curves located to the right. Usually, the S.P. log consists of a base line, more or less straight, having excursions or "peaks" to the left. The base line frequently has been found to correspond to impervious beds, while the peaks are usually found opposite permeable strata. Measurements which will indicate positively the presence of permeability in the formations, and which will give accurately the boundaries of the permeable zones, are of great importance in oil-field practice. Thus far, the S.P. log is the best approach to such determinations; unfortunately, its interpretation is not always evident. With respect to the base line of the S.P. log, it may be noticed that this line is not always at a definite location on the chart. Sometimes it may shift abruptly, while other times a gradual drift is apparent. As far as the peaks are concerned, their shape is not uniform; some are rounded while others are sharp. Also, from other data, it may be found that occasionally the peaks extend appreciably beyond the boundaries of permeable zones into zones which are not everywhere permeable. A comparison with permeability measurements made on cores has often confirmed that there was no definite correspondence between the magnitudes of the peaks and the permeability values. In the same geological horizon, it generally will be found that most of the thick and permeable for-

Jan 1, 1949

By J. A. Herbst

During the last decade it has been established that conventional flotation control strategies based on classical control theory result in significant increases in grade, recovery, and operating-cost savings. In the current report a description of an advanced model-based control philosophy is presented. The derivation and verification of a simplified flotation model is described. The implementation of a Kalman filter for estimation of unmeasured variables for input to controllers is discussed. Several control strategies using the model-based approach are described, emphasizing the nonlinear nature of the flotation plant. Expected trends in the implementation of such model-based flotation control strategies in the future are discussed.

Jan 1, 1986

By Ernest Stütz

(New York Meeting, October, 1913.) THE problem of increasing blast-furnace efficiency through diminution of flue-dust production while operating with burdens consisting largely of fine ores has of recent years attracted the attention of metallurgists, whether directly or indirectly interested in the economies of iron smelting, and the various methods evolved from theory or practice have been. submitted to wide discussion. After the very thorough and, at that time, exhaustive view of the whole subject, which was afforded to the industry by the meeting of this Institute in February, 1912, the subject was again taken up at the meeting of the Verein deutscher Eisenhüttenleute at Düsseldorf in December, 1912. While American and German conditions are not entirely identical, it may be of interest to give here the words of the gentleman summing up the discussion at the Düsseldorf meeting : ?The chief advantage offered by the use of briquettes lies in the fact that disturbances in the furnace, caused mostly by the presence of fine ores in the burden, are avoided, and that blast pressure can be considerably reduced. The resulting economies cannot be overrated, as, with lower blast consumption per ton of product, the installation will be able to take care of increased production. In consequence of lower pressure and speed of blast, heat is more efficiently utilized,, flue gas temperature is lowered, and coke particles are less liable to be carried along with the flue dust, of which considerably less is produced. Finally, by increased regularity of operation and higher temperature in the lower parts of the furnace, the quality of the product is improved. The question of briquetting iron ores has grown to be one of the most important in the iron industry, and it is not any more a question of what is the cost 'of briquetting a ton of ore, but what, in. using ore briquettes, is the cost, of: production of a ton of iron."

Jan 7, 1913

By Jiling Wang, Xuefeng Liu, Haojian Duan, Lifeng Zhang, Ying Ren, Wen Yang

"In order to study the influence of MgO-C refractory on steel cleanliness and inclusions during steelmaking process, and to understand the reaction mechanism deeply, laboratory deoxidation and equilibrium experiments were respectively performed in MgO crucibles at 1873K. In the former experiment, after Al addition, steel samples were taken at different holding time. In the latter experiment, different slag components and different contents of carbon and aluminum in steel were considered respectively. The inclusion characteristics of each experiment were analyzed. The results showed that with the increasing of holding time after deoxidation by Al, MgO existed in the small inclusions firstly, and then in the large ones such as the clusters. The MgO content in the inclusions increased with the increasing of holding time, indicating that the MgO in crucible could be individually reduced by the aluminum in the molten steel. The reaction could occur within nine minutes.IntroductionNon-metallic inclusions would have positive or negative effect on steel quality depend on the quantity, size and composition of inclusions. Large inclusions are always detrimental. From the point of view of inclusion property, plastic inclusions are required by steel cord, while hard inclusions are preferred by pipeline steel. One of the most important ways to increase the steel quality is reducing the inclusion size and controlling the inclusion composition in steel. Nowadays, MgO based refractory is used as ladle glaze material with more and more frequency, which results in different inclusion characteristics in molten steel, for example, the inevitable generation of MgO contained inclusions during ladle treatment of steel. In other words, the inclusions in this type ladle will influence on the steel cleanliness and the product property. Thus, keeping an eye on the inclusion formation behavior in the steel with MgO-C ladle glaze is important for the steel industry. There have been a few studies in this regard. Li et al[l] studied the reactions between MgO-C refractory, molten slag and metal using a high temperature X-ray radiographic apparatus. They found that the local corrosion was regarded as due to the cyclic dissolution of MgO and graphite in the refractory into slag and metal phase. The gas bubbles formed according to the reaction of (FeO)+C(s)=Fe(l)+CO(g) greatly influenced the corrosion. On an industrial scale, Du[2] found that ladle glaze is a major source of inclusions in the ladle. An experimental study has been performed by Lehmann in order to estimate the importance of the reaction between a MgO-based tundish refractory and an Al-killed steel[3]."

Jan 1, 2014