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By T. Scheldt, M. Lu, A. Myrvang

Abstract: In this paper both continuous and discontinuous modelling are utilised in order to analyze the stability of the Gjøvik Olympic Mountain Hall. The large span cavern (62 m) was built for the 1994 Winter Olympic Games at Lillehammer, and is a unique case study because of the large amount of available input data, through a comprehensive pre-investigation, stress and deformation monitoring program before, during and after the excavation. Phase2, a two-dimensional non-linear finite element program, and the Discontinuous Deformation Analysis (DDA) are used as representative tools for continuous and discontinuous modelling, respectively. The analysis results are compared and discussed taking the reliability of the models, time-consumption and costs into consideration. Some guidelines for the total modelling process, from field measurements to final results, are also presented. Zusammenfassung: In diesem Artikel werden sowohl kontinuierlich als auch diskontinuierlich Modellierung verwendet, um die Stabilität, der in den Berg gebauten Olympiahalle in Gjøvik zu analysieren. Die Olympiahalle wurde 1994 zu den Olympische Spielen in Lillehammer errichtet. Ihr Dach erstreckt sich über eine Breite von zweiundsechzig Meter. Für den Bau wurden umfangreiche Daten durch Voruntersuchungen, und Überwachung von Gebirgsspannungen und Deformationen bevor, während und nach Exkavation eingesammelt. Auf Grund dieser großen Datenmenge stellt die Olympiahalle ein herausragendes Beispiel für den Bau ähnlicher Projekte dar. Für die kontinuierlichen Modellierungen wurde „Phase2“, ein zwei-dimensionales, nicht lineares „endlich Element“ Rechnerprogramm angewandt. Die diskontinuierlichen Modellierungen erstellte man mit Hilfe von der „Diskontinuierliche Deformations Analyse“ (DDA). Die Analysenergebnisse sind mit Rücksicht auf die Zuverlässigkeit der Modelle, Zeitverbrauch und Kosten verglichen und diskutiert worden. Im Artikel werden Richtlinien für den Modellierungsprozess von Dateneinsammlung bis Schlussfolgerung gegeben. Résumé: Dans cet article la modélisation continue et discontinue sont utilisés pour analyser la stabilité de Gjøvik Olympic Mountain Hall. Cette caverne de grande portée (62 m) a été construite pour les Jeux Olympiques d’Hiver de 1994 à Lillehammer, et est une étude de cas unique grâce à la grande quantité de données disponibles, de par un programme de pré-investigation compréhensive, monitorage des contraintes et déformations avant, pendant et après l'excavation. Phase2, un code d’éléments finis non linéaire à deux dimensions, et l’Analyse en Déformations Discontinues (DDA) sont utilisés comme outils représentatifs de la modélisation continue et discontinue, respectivement. Les résultats d'analyses sont comparés et sont discutés, prenant en compte la fiabilité des modèles, la consommation en temps de calcul et les coûts. Quelques indications pour le procédé total de modélisation, des mesures sur place aux résultats finaux, sont aussi présentées.

Jan 1, 2003

By R. Padilla, M. C. Ruiz

Arsenic, antimony and bismuth are commonly found in copper concentrates usually as the minerals enargite, stibnite and bismuthinite, respectively. Concentrates having high levels of arsenic and antimony must be pretreated before smelting. Roasting is the preferred method for removing these toxic impurities from concentrates; However, the removal of As, Sb and Bi in oxidizing roasting by volatilization may not be complete due to the slow reaction rates at 500- 700 °C. Oxidizing/volatilization data were obtained from pure mineral mixtures and from arsenic rich copper concentrate. The reaction mechanism for the volatilization of arsenic and antimony were discussed. Near 100% As and over 95% Sb volatilized in the oxidation of a mixture of pure minerals at 700 °C, 1% oxygen, while over 95% As, and 35% Sb volatilized at 600 °C in 1% oxygen atmosphere when using a copper concentrate containing 3.51% As, 0.14% Sb, and 0.01% Bi. Bismuth did not volatilize.

Jan 1, 2015

By Horace Knerr

The term. "high-yield-strength," used in the title of Dr. Gillett's paper (p. 40) is obviously relative. His discussion is limited to improved steels intended to compete with the low-cost, low-carbon, hot-rolled, sheet and plate steels of commerce made and used on a tonnage basis, without heat-treatment. In his list of about three dozen steels, only three have a yield strength of 70,000 lb. per sq. in., or over. Double such values are not uncommon in aircraft steels. Dr. Jeffries (p. 21) refers to "light-weight metals," obviously meaning strong alloys of low specific gravity; namely, aluminum alloys of the duralumin type and certain magnesium alloys. In a structural material, "lightness" is determined by two factors, strength and specific gravity. They must always be considered jointly. The basis of comparison is a strength-weight ratio, obtained by dividing the desired strength value, such as tensile strength, yield strength, or endurance limit, by weight per unit of volume, such as specific gravity or pounds per cubic inch1. For example, aluminum is a heavy metal, structurally, unless alloyed and heat-treated to give it high strength. When the strength of a structural metal is raised by heat-treatment or by cold-work, its specific gravity is not appreciably changed, but it is made lighter in direct proportion to the increase in strength because less of it will be required to carry the load. The lightness of the finished structure of adequate strength is the real point of interest. This structure must not only carry designed load, but "stand the gaff" of service, which includes the effects of accidental overload, fatigue, corrosion, loosening of joints, and so forth. Neither Dr. Gillett nor Dr. Jeffries mentions the true "lightest material of construction," which is alloy steel, tubular in form (Fig. 1), assembled by welding and heat-treated to a yield strength in excess of 150,000 lb. per sq. inch.

Jan 1, 1936

By Rodney G. Orr, Phil Robertshaw, Roland Loewer, Klau Lehnert-Thiel

This paper documents the 1988 discovery and subsequent evaluation (to 1991) of diamond bearing kimberlites in the Fort à la Corne area, Saskatchewan, by Uranerz Exploration and Mining Limited. Cameco Corporation began participating as a joint venture partner (50%) in mid-1989. The first indications that kimberlite-type intrusions might exist in the area carne from Geological Survey of Canada aeromagnetic maps. Because of the overburden thickness (over 100 m), magnetometer surveys continue to be the main exploration tool in defining pipe locations and sizes. Magnetometer surveys in varying levels of detail have outlined one main cluster and two sub-clusters, the main group being some 10 km by 50 km in size. In excess of 70 individual targets have been interpreted from the magnetics as probably representing kimberlites. The size range of the individual magnetically-defined bodies is between 1 ha and 74 ha. Proof that the magnetic anomalies were kimberlite intrusions carne in 1989 when each of seven test holes, all drilled on different targets, intersected the potential diamond host rock. The majority of the targets tested were diamond-bearing, with the indicator mineral chemistries suggesting that both peridotitic and ecIogitic diamond parageneses could be expected. To date, 18 individual kimberlite bodies have been drill-tested. A total of 39 bulk samples, amounting to 186 t (representing 360 t of theoretical sample recoveries) were processed in 1990 and 1991. One hundred and sixty diamonds were recovered, averaging 0.04 carats in weight, the largest being 0.6 carats. Most of the bulk sample grades are less than 2 carats/loo t; only three bulk samples have higher grades, the best being approximately 10.5 carats/l00 1. The diamonds are predominantly gem-quality stones.

Jan 1, 1992

By John F. Gamble

Amphiboles are hydrated mineral silicates five of which occur in asbestiform habits as asbestos grunerite (amosite) asbestos, riebeckite (crocidolite) asbestos, anthophyllite asbestos, tremolite asbestos and actinolite asbestos] and non-asbestiform habits (grunerite, riebeckite, anthophyllite, tremolite and actinolite). The asbestiform varieties are characterized by long, thin fibers while non-asbestiform varieties such as cleavage fragments form short fibers with larger widths. The U.S. regulatory method for counting asbestos fibers (aspect ratio [>]3:1, length [>]5 µm) does not distinguish between asbestos and cleavage fragments. The method biases toward increased counts of non-asbestiform cleavage fragments compared to long, thin asbestos fibers. One consequence of this regulatory approach is that workers can be erroneously classified as exposed to concentrations of asbestos (asbestiform amphiboles) above the U.S. 0.1 f/mL exposure standard when in fact they are not exposed to asbestos at all but non-asbestiform amphibole cleavage fragments. Another consequence is that the known carcinogenic effects of asbestos may be falsely attributed to non-asbestiform amphibole cleavage fragments of the same mineral. The purpose of this review is to assess whether amphibole cleavage fragments pose the same risk of lung cancer and mesothelioma characteristic of amphibole asbestos fibers. We identified three groups of workers exposed to non-asbestiform amphiboles: two groups exposed to grunerite (Homestake gold miners and taconite miners) and one group exposed to industrial talc containing non-asbestiform tremolite and anthophyllite in St. Lawrence County, NY. In addition to assessing strength of association and exposure?response trends in the non-asbestiform amphibole cohorts, comparisons were also made with cohorts exposed to the asbestiform counterpart (positive control) and cohorts exposed to the mineral (e.g. talc) that does not contain amphiboles (negative controls). The cohorts exposed to non-asbestiform amphiboles had no excesses of lung cancer or mesothelioma. Similar results were observed in the negative control groups, in stark contrast to the excess risks of asbestos-related disease found in the asbestos cohorts. The only possible exception is the twofold increased risk of lung cancer where exposure was to industrial talc containing cleavage fragments of tremolite and anthophyllite. However, this risk is not considered attributable to the talc or amphibole cleavage fragments for several reasons. A similar increased risk of lung cancer was found in Vermont talc workers, studied in the same time period. Their exposure was to relatively pure talc. There was no relationship between lung cancer mortality and exposure measured as mg/m3 years and years worked. A case?control study reported that all the lung cancer cases were smokers (or former smokers) and attributed the excess to smoking. There were two mesothelioma cases among the NY State talc workers exposed to cleavage fragments of tremolite and anthophyllite, but talc is not a plausible cause because of too short latency and potential for previous asbestos exposure. The positive controls of tremolite asbestos and anthophyllite asbestos exposed workers showed excess risks of both lung cancer and mesothelioma and positive exposure? response trends. St. Lawrence, NY talc does not produce mesotheliomas in animals while amphibole asbestos does. In sum, the weight of evidence fully supports a conclusion that non-asbestiform amphiboles do not increase the risk of lung cancer or mesothelioma. ©2008 Published by Elsevier Inc. Keywords: Amphiboles; Cleavage fragments; Lung cancer; Mesothelioma; Asbestos; Non-asbestiform amphiboles; Grunerite; Talc

Jan 1, 2007

By C. G. Anderson

With demand and prices for copper and gold at near record high levels, coupled with a lack of readily treated orebodies, the emergence of environmentally sound hydrometallurgical treatment of enargite concentrates has become a priority. This paper will outline the application the industrially proven technologies of low pressure and temperature NSC (Nitrogen Species Catalyzed) pressure leaching and ASL (Alkaline Sulfide Leaching) for the recovery of copper and gold from enargite. Copper can be recovered as cathode metal or as a clean concentrate suitable for smelting. Gold is recovered by smelting, conventional cyanidation or alkaline sulfide hydrometallurgy. Coupled with this is the effective precipitation and stabilization of arsenic as scorodite and ferrihydrite.

Jan 1, 2007

Due to the relatively remote location of the St. Anthony Mine, the high cost of transportation and milling, plus the low grade nature of the deposit, the United Nuclear Corporation began investigating methods of mechanical upgrading approximately eighteen moths ago. This investigation culminated in the installation of Model 17 and Model 18 ore sorting machines. The machines are marketed in the United States and Canada by Ore Sorters of Canada (Ltd.). The installation of this advanced technology will enable United Nuclear Corporation to fully realize the residual potential of St. Anthony.

Jan 1, 1979

By G. R. St. Pierre, S. W. Gilby

The equilibrium vapors established over Fe-Cr-Ni alloys containing up to 50 pct Cr at 1600°C were determined by collecting the effusate from thoria Knud-sen cells. From these data, the activities of iron and nickel in the ternary alloys have been calculated. In a separate set of measurements, a mass spectrometer was used to determine the activities of the three components in a series of Fe-Cr-Ni alloys. In binary Ni-Cr melts, the activity coefficient of chromium referred to pure solid chromium as standard state is less than one at low chromium contents but is greater than one for melts containing more than 30 at. pct Cr. For Ni-Cr melts containing less than 10 at. pct Cr, In ?Cr = 0.15-0.92 N2. Ternary activity diagrams for Fe-Cr-Ni alloys are presented. In iron-rich alloys, the interactions between the three components are negligible; however, in nickel-rich alloys, the three principal interactions have significant positive values. THE activities of components in binary Fe-Ni alloys have been measured both in the solid solution1-3 and liquid solution4-6 temperature ranges. The determination for Fe-Ni melts have been made by three different methods: transpiration,4 Knudsen-cell effusion with analysis of an accumulated condensate,' and Knudsen-cell effusion with direct measurements of relative component intensities by mass spectrometric methods.6 The results obtained by the three different methods in three different laboratories are in excellent agreement and considerable confidence is placed in the activity coefficients for Fe-Ni melts. At 1600°C, the activity coefficients in dilute solution are ?°Ni = 0.66 and ?oFe = 0.40 for the pure liquid components as standard states. Measurements made on solid solution Fe-Cr alloys7-10 indicate that the component activities are slightly greater than ideal. The measured activities in iron-rich Fe-Cr liquid alloy11-16 indicate almost ideal behavior for this system. The recommended activity coefficient of chromium in dilute solution in liquid iron at 1600o C, ?oCr, is 1.18 when referred to pure solid chromium as standard state and 1.04 when referred to pure undercooled liquid chromium as standard state." The conversion factor of 1.14 is based on a melting point of 1857°C and an enthalpy of melting of 4047 cal per g at. for chromium.21,37 The activity coefficient of iron in dilute solution in liquid chromium has not been measured. Activity measurements on solid Ni-Cr alloys have been made by several investigators.17-20 During the review of this manuscript, Fruehan12 published the results of a study on liquid Ni-Cr alloys at 1600°C. He used galvanic cells22 with ZrO2(CaO) as the electrolyte and Cr/Cr2O3 for the reference electrode. His results indicate that ?oCr in nickel at 1600°C is about 1.01 when referred to pure solid chromium and about 0.89 when referred to pure undercooled liquid chromium as standard state. The activity coefficient of nickel in liquid chromium is unknown. The compositions of vapors freely evaporating from some molten Fe-Cr-Ni alloys have been measured by Lyubimov, Granovskaya, and Berenstein.23 Their results, combined with known vapor pressures, indicate strong positive deviation for chromium in iron-rich alloys and strong negative deviation for chromium in nickel-rich alloys. EXPERIMENTAL PROCEDURES This research was undertaken to determine the activities of components in ternary Fe-Cr-Ni melts containing up to 50 at. pct Cr. At the initiation of the research, we decided to use a Knudsen-cell method wherein a portion of the effusing vapor is condensed on a cold plate.' The composition of the equilibrium vapor for each alloy composition is determined in this method by holding the system under constant conditions for a period of time sufficient to collect enough condensate on the cold plate for chemical analysis. The activities of components in ternary alloys can be calculated from such vapor composition determinations by Eq. [1].24

Jan 1, 1970

By C. G. Fink, G. L. Putnam

The dissolution of gold by cyanide solutions was studied by determining the time required for the solvents to dissolve gold leaf. Minute traces, even 0.5 ppm, of sulphide ion retard the dissolution of gold, and this behavior cannot be accounted for by the presently accepted hypotheses involving oxygen-depletion or thiocyanate formation. On the other hand, traces of the salts of lead, bismuth, mercury, and thallium considerably accelerate the dissolution. The beneficial effect of lead is dependent upon the pH and cyanide ion concentration of the solution. ALTHOUGH cyanide solvents are used very ex-x*. tensively for the recovery of gold from ores and concentrates, the normal rate of solution of the precious metal as determined by Barsky, Swainson, and Hedley,1 and others2 is less than about 3 mg per sq cm of exposed gold surface per hour, corresponding to a corrosion depth of approximately 1.5 microns (0.00006 in.) per hr. Although the slow rate may be increased to some extent in certain cases, as, for example, when the the gold is partially imbedded in iron pyrites,3 the leaching operation is generally the most time-consuming step of the cyanide process. Frequently it is necessary for the leaching solvents to remain in contact with the ores for 50 to 200 hr in order to dissolve all of the gold particles.' Not only does the slow solution rate cause some increase in the capital costs, but the cyanide consumption also may be increased because of vaporization of hydrocyanic acid and secondary reactions with minerals such as malachite (CuCO3 • Cu(OH)2), and pyrrhotite, which often are associated with gold. It is not surprising that numerous attempts have been made to accelerate the dissolution of gold in cyanide solutions. Experimental Gold Leaf Test: The gold leaf test was apparently originated by M. Faraday, who, by means of it, discovered that dilute cyanide solutions would dissolve gold readily in the presence of oxygen. The usefulness and reliability of the test have been discussed elsewhere.5,6 Essentially, the method consists of determining the time required for 5-ml portions of cyanide solvents to dissolve squares of 23 carat gold leaf, 0.5 cm on edge, when shaken in 10-ml test tubes with the solvents. The weight of gold leaf per test was 0.051 mg as determined by the direct weighing of a leaf 8.6x8.6 cm (weight = 15 mg) and measuring the area of the test sample (0.25 sq cm). Gold leaf is of remarkably uniform thickness.6 Since gold leaf, like native gold, contains small amounts of copper and silver, the results are comparable with those one might expect in cyaniding gold ores. As six or more tests can be made simul- taneously, the relative efficiencies of the solvents can be evaluated readily. All dilute solutions of lead, bismuth, thallium and mercury salts were prepared by the ordinary dilution method used by chemists. Our C.P. sodium cyanide and buffering reagents had no detectable amounts of either sulphide ion or heavy metals. Soluble Sulphides in the Cyanide Process: The action of soluble sulphides is of interest in the study of the dissolution of gold in cyanide solutions. That gold ores which contain compounds of arsenic and antimony often are not amenable to direct cyanide treatment is well known, and it said that arsenic and antimony are "cyanicides."7 It is commonly believed that part of the sulphur content of such ores is soluble in alkaline solutions to give sulphide ion, which reacts with the free cyanide content of the leaching solutions to form inert thio-cyanates or reacts with the dissolved oxygen to form sulphites or sulphates.8 A purpose of this paper is to demonstrate that sulphide ion may behave in a manner that cannot be explained by either the oxygen-depletion or thiocyanate formation theories and to prove directly that concentrations of sulphide ion which cannot be detected even by colorimetric methods may retard the dissolution of gold.

Jan 1, 1951

By C. G. Fink, G. L. Putnam

The dissolution of gold by cyanide solutions was studied by determining the time required for the solvents to dissolve gold leaf. Minute traces, even 0.5 ppm, of sulphide ion retard the dissolution of gold, and this behavior cannot be accounted for by the presently accepted hypotheses involving oxygen-depletion or thiocyanate formation. On the other hand, traces of the salts of lead, bismuth, mercury, and thallium considerably accelerate the dissolution. The beneficial effect of lead is dependent upon the pH and cyanide ion concentration of the solution. ALTHOUGH cyanide solvents are used very ex-x*. tensively for the recovery of gold from ores and concentrates, the normal rate of solution of the precious metal as determined by Barsky, Swainson, and Hedley,1 and others2 is less than about 3 mg per sq cm of exposed gold surface per hour, corresponding to a corrosion depth of approximately 1.5 microns (0.00006 in.) per hr. Although the slow rate may be increased to some extent in certain cases, as, for example, when the the gold is partially imbedded in iron pyrites,3 the leaching operation is generally the most time-consuming step of the cyanide process. Frequently it is necessary for the leaching solvents to remain in contact with the ores for 50 to 200 hr in order to dissolve all of the gold particles.' Not only does the slow solution rate cause some increase in the capital costs, but the cyanide consumption also may be increased because of vaporization of hydrocyanic acid and secondary reactions with minerals such as malachite (CuCO3 • Cu(OH)2), and pyrrhotite, which often are associated with gold. It is not surprising that numerous attempts have been made to accelerate the dissolution of gold in cyanide solutions. Experimental Gold Leaf Test: The gold leaf test was apparently originated by M. Faraday, who, by means of it, discovered that dilute cyanide solutions would dissolve gold readily in the presence of oxygen. The usefulness and reliability of the test have been discussed elsewhere.5,6 Essentially, the method consists of determining the time required for 5-ml portions of cyanide solvents to dissolve squares of 23 carat gold leaf, 0.5 cm on edge, when shaken in 10-ml test tubes with the solvents. The weight of gold leaf per test was 0.051 mg as determined by the direct weighing of a leaf 8.6x8.6 cm (weight = 15 mg) and measuring the area of the test sample (0.25 sq cm). Gold leaf is of remarkably uniform thickness.6 Since gold leaf, like native gold, contains small amounts of copper and silver, the results are comparable with those one might expect in cyaniding gold ores. As six or more tests can be made simul- taneously, the relative efficiencies of the solvents can be evaluated readily. All dilute solutions of lead, bismuth, thallium and mercury salts were prepared by the ordinary dilution method used by chemists. Our C.P. sodium cyanide and buffering reagents had no detectable amounts of either sulphide ion or heavy metals. Soluble Sulphides in the Cyanide Process: The action of soluble sulphides is of interest in the study of the dissolution of gold in cyanide solutions. That gold ores which contain compounds of arsenic and antimony often are not amenable to direct cyanide treatment is well known, and it said that arsenic and antimony are "cyanicides."7 It is commonly believed that part of the sulphur content of such ores is soluble in alkaline solutions to give sulphide ion, which reacts with the free cyanide content of the leaching solutions to form inert thio-cyanates or reacts with the dissolved oxygen to form sulphites or sulphates.8 A purpose of this paper is to demonstrate that sulphide ion may behave in a manner that cannot be explained by either the oxygen-depletion or thiocyanate formation theories and to prove directly that concentrations of sulphide ion which cannot be detected even by colorimetric methods may retard the dissolution of gold.

Jan 1, 1951

By W. J. Errington

The Isasmelt process was developed at Mount Isa Mines Limited in Queensland, Australia in collaboration with CSIRO, the Australian Government research organisation. Originally developed for primary lead smelting, culminating in the construction of a 60,000 tonnes per annum lead smelter at Mount Isa, this technology now also provides a major part of the current 200,000 tonnes per annum copper smelting capacity at Mount Isa. A programme is now in place to expand copper production to 250,000 tonnes per annum. The technology has also been applied to secondary lead smelting at Britannia Refined Metals, a MIM subsidiary company, where a 30,000 tonnes per annum lead plant based on battery scrap feed has been operating since 1991. Mount Isa Mines Limited decided to license the technology in1988, and copper smelting plants utilising Isasmelt technology are now operated by Cyprus Miami Mining Corporation in the USA and by Sterlite Industries in India. In addition, the technology was adopted by AGIP for smelting copper/nickel concentrates in Australia. Union Miniere are currently constructing an Isasmelt furnace to smelt and convert copper-containing materials at their plant at Hoboken in Belgium. This paper discusses these developments and also some likely future developments which include the application of the technology for continuous copper and nickel converting and applications in the treatment of zinc-containing residues.

Jan 1, 1997

By Kotaro Ogura

"Ethylene has been produced in aqueous solution from CO2 by the electrochemical reduction driven by a natural energy. This process is useful for storing a large amount of the natural energy. In the closed system, the conversion efficiency of CO2 is almost 100%, and the maximum selectivity for the formation of ethylene is more than 70%. On the other hand, the current efficiency for the competitive reduction of water is less than 10%. The electrolysis is practicable under such special conditions as three-phase interface consisting of gas, solution and metal, concentrated solution of potassium halide, low pH and copper or copper halide-confined metal electrode. These requirements are thoroughly examined, and the grounds to reply upon are revealed. A series of chemical apparatuses including an electrolytic cell in a large scale are designed for the ethylene production, which allow us continuously to supply raw CO2 and to extract the product.IntroductionIn connection with the depletion of the petroleum reserve, much attention has been paid to the utilization of natural energies such as sunlight, wind force and waves. However, these energies are always changeable, and some means of storing them are necessary for the common use. In general, natural energies are transformed to the electric energy at the time of utilization, but the electricity is not very storable. This is one of the reasons why the application of natural energy is not so expanded. On the other hand, the storing of natural energy by plants is very skilful. In the photosynthesis, solar energy is transformed to chemical energy by fixing carbon dioxide."

Jan 1, 2009

Energy Savings and Technology Comparison Using Small Grinding Media Considering the complexity of minerals, the need for finer grinding is increasing along with the energy cost. However, energy is increasing exponentially when grinding finer with conventional grinding balls. The use of small grinding media represents the best potential to improve energy efficiency. Today, it is possible to use grinding media as small as 1 mm. How do they perform in industrial grinding mills? The use of small grinding media (5 - 12 mm), called Millpebs, in regrind mills proved that finer grinding can be achieved at lower energy consumption. In ball mills, energy savings vary from 10 per cent to 40 per cent compared to 25 mm media. A regrind ball mill with a mix of small grinding media can be as energy efficient as an Isa Mill charged with 2.5 and 3.5 mm beads. In vertical stirred mills, energy savings vary from 30 per cent to 60 per cent. To carry out the same final grind, a vertical stirred mill with Millpebs will consume at least 60 per cent less energy than a ball mill using 25 mm grinding media. More potential savings were identified. To achieve those improvements, some operating conditions must be met: 1) feed size should be less than 250 ¦m; 2) the pulp must be fluid enough; 3) finally, the slurry linear velocity should not be excessive. This paper talks about all those industrial results improvement and operating conditions.

Sep 13, 2010

By Charles F. Seemann

It is with considerable trepidation that I set out to defend "litigation" to Design Professionals (DPs), as a better method of resolving disputes than arbitration, in the light of my personal feeling that an increasing amount of America's productive process is being squandered in litigation. Newer methods of dispute resolution, particularly arbitration, are fashionable, and opponents of these schemes risk being viewed as cynical or self-serving. My quandary is heightened since for some smaller disputes, arbitration seems clearly the better choice. I must concede, for example, that when the cost of dispute resolution--i.e., the cost of the process (such as arbitrators fees, attorneys fees, etc.), plus the cost impact of the non-productivity of involved employees--approximates the amount of the dispute, controlling that cost may be as important as a correct resolution. This principle is particularly true for small disputes arising during the progress of a project; it is probably more cost-effective for all parties to resolve their disputes quickly than permitting the dispute to drag out.

Jan 1, 1988

By J Ta’ala, M Handyside

Mechanical sampling from conveyors has historically been a staple in the iron ore industry when information related to chemistry, sizing and moisture is required. In order to comply with ISO 3082:2009, samples can be taken either on a mass or time basis provided no bias is introduced by periodical variation in quality or quantity. With the introduction of mechanical sample carousels, you also have the opportunity to collect samples on a mass or time basis. In order to optimise automatic sample stations in a changing production environment, BHP Billiton Iron Ore (BHPBIO) has developed a simulation model that enables the various combinations of mass–mass, mass–time, time–time and time–mass to be investigated.The sample station model can utilise actual (variable) feed rates to achieve high resolution and enables the simulation of sample size variation. Cutter speeds and other settings can then be adjusted to better optimise the performance of the sample station with regards to optimal sample size as well as ensuring the sample station is in compliance with ISO 3082. The model can also assist process engineers in adjusting settings to better optimise the sample station and reduce unwanted events such as blockages. The model can be easily modified to conform to various sample station designs. This paper demonstrates the use of the model and the benefits that can be achieved.CITATION:Handyside, M and Ta’ala, J, 2014. Simulating time versus mass basis?sampling, in Proceedings Sampling 2014 , pp 155–164 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 29, 2014

By Dorricott M. G

This paper reviews the present status of mining engineering education in Australia, outlines the main objectives of current programs, and looks at some of the difficulties that need to be overcome to maintain and improve current standards.A case is made for greater co-ordination and co-operation between the institutions themselves, and between industry and the professional bodies to ensure the highest standards are achieved in the most efficient way.

Jan 1, 1992

By Zhihe Dou

SHS reaction system has advantages of heat flux density, energy concentration and reaction speed, with sufficient conditions in thermodynamic and kinetic reaction. This paper invented a new technology of SHS metallurgy of preparing melting point alloys and refractory compounds using its own chemical energy. SHS-leaching process for preparing nano boron powder or ultrafine boride powder and SHS-casting process for preparing titanium-based alloy and immiscible alloy were studied. The results indicate that highly active boron powder of greater than purity of 93%, particle size less than 100nm and purity greater than 98.5%, particle size less than 400nm REB6 can be prepared. With SHS-Casting process, the oxygen content of less than 0.59% ferrotitanium, oxygen content of less than 0.5% titanium alloy and ?40-80*100mm large size of CuCr, Cu-Fe alloy ingots were prepared. This technology has greatly enhanced the thermal reduction method added values of preparing metallurgical products and its competitiveness.

Jan 1, 2014

By E. T. Turkdogan, L. J. Martonik, R. J. Fruehan

Electrochemical measuretnents of the solid oxide electrolyte galvanic cells CY-Cr2O3 I ZrO2 (CaO) 1 O (in Fe alloy) CY-Cr2O3 I Tho2 (Y2O3)I O en Fe alloy) have been made at 1600°C (2912°F) in order to test the Performance of such cells at liquid steel temperatures. The oxygen pvobe (cell) consists of a disk of ZrO2 (CaO) or Tho2 (Y2O3) electrolyte fused at one end of a silica tube filled with a mixture of Cr-Cr2O3 which is the reference electrode. Upon immersion in liquid steel, the electromotive force readings achieve a steady value within a few seconds, and remain steady for 30 win or more. The perforwzance of the probes has been tested using Fe-O, Fe-Si-O, Fe-Cr-O, Fe-V-O, and Fe-Al-O alloys; the oxygen contents of liquid steel derived from the measured electromotive forces are in satisfactory agreement with those determined by arulysis. Use of the probe in the deoxi-datiorz of steel, in laboratory experiments, is discussed. The results indicate that there is insignificant electronic conductivity in ZrO2(CuO) at oxygen activities down to those corresponding to 10 ppm in steel. At lower oxygen activities, probes tipped with ThOn (Y2O3) disks perform satisfactorily at oxygen activities down to 1 ppm O or less. THE key to the control of deoxidation of steel is a sensing device to measure rapidly the concentration of oxygen in liquid steel in the furnace, ladle or tun-dish at any desired stage of deoxidation. The analysis of the cast steel by the neutron-activation or vacuum-fusion method gives total oxygen as oxide and silicate inclusions. This analysis is important for guidance to steel cleanliness; however, such a postmortem is of little value in the control of deoxidation of liquid steel. At the General Meeting of the American Iron and Steel Institute in New York, 1968, Turkdogan and Fruehan' presented a paper on the preliminary results of the work done in this laboratory on rapid determination of oxygen in steel by an oxygen probe. Details of the work done in this laboratory leading to the development of a galvanic cell for the determination of oxygen in liquid steel, and the results of the tests made are given in this paper. It was through Wagner's contributions, since the early Thirties, to the physical chemistry of semiconductors in general that it ultimately became possible to construct galvanic cells for application at high temperatures. In 1957, Kiukkola and wagner2 successfully demonstrated the use of several solid electrolytes in measuring the free energies of several chemical reactions, in particular, the use of lime-stabilized zir-conia in high-temperature oxidation reactions. Starting 7 years later, a number of papers appeared in the technical literature3-' demonstrating possible applicability of galvanic cells for the determination of oxygen in liquid steel. In the earliest work, Japanese investigators3j4 experimented with various types of reference electrodes, e.g., graphite-saturated liquid iron at 1 atm CO or Ni-NiO mixtures; the results obtained, though promising, were not of sufficient accuracy. Except for the work of Baker and West,6 all other investigators5,7,8 showed that ZrO2(CaO) electrolyte could be used for this purpose. The main part of the galvanic cell used by Fischer and ~ckermann' and by schwerdtfeger7 (the latter work was done in this laboratory), consisted of a ZrO2(CaO) tube, -1 cm ID, closed at one end, with a platinum contact wire fixed mechanically inside the closed end. The tube was flushed with a gas of known oxygen partial pressure, e.g., air, CO-CO2 or H2-CO2 mixtures; gas along with the platinum lead wire served as the reference electrode. The oxygen contents derived from measured electromotive forces agreed reasonably well with the oxygen contents determined by vacuum-fusion analysis. It is evident from recent investigations that the electromotive force technique using a solid oxide electrolyte is fundamentally well suited for the determination of oxygen in liquid steel. However, it is equally clear that the cell arrangement of the type as commonly used is in need of considerable improvement, as it exhibits several shortcomings for industrial and even laboratory use. 1) Because of its size, the zirconia tube, though stabilized, has a poor resistance to thermal shock. 2) Fine pores and microcracks, which are invariably present in zirconia tubes, are detrimental to the satisfactory operation of the cell, particularly when gas reference electrodes are used. 3) Air or carbon dioxide reference electrodes give rise to high electromotive force readings; as a result, the determination of oxygen in steel becomes less accurate. For higher accuracy, the oxygen partial pressure of the reference electrode should be in the range similar to that of oxygen in steel. 4) Even in laboratory experiments, difficulties are experienced when flushing the tube with gases and maintaining the proper gas flow rate. Fischer and Ackermann,' who used air as the reference electrode, reported that when the flow rate was too low, furnace gases would leak into the electrolyte tube, therefore lowering the oxygen potential and measured electromotive force. The required flow rate in order to avoid leakage depended on the tightness of the electrolyte tube which varied with different tubes, thus making it difficult to predict in advance the required flow rate. However, if the flow rate is too high the inside wall of the electrolyte tube would be cooler than the wall

Jan 1, 1970

The mineralogy and textures of a portion oC ore from the 25 level northern orebody, North mine, Broken Hill are described. This ore, in places, contains up to 70 per cent cubanite (CuFe2S3 ) which has crystallized directly with other sulphides and associated gangue minerals.Several breakdown reactions involving the cubanite are also considered.

Jan 1, 1969

By Oluwatosin A. Aladejebi, Apsara S. Jayasekara, Raymond J. Longbottom, Mark Reid, Marc in het Panhuis, Brian J. Monaghan

The coke analogue is a new research tool that has been developed to quantify and characterize the effect minerals in coke have on coke reactivity. The analogue material is made from a number of different carbon or carbon containing materials and minerals to in part replicate real industrial coke’s reactivity behavior. Elucidation of the effects of minerals on coke reactivity has proved difficult due to the complex and heterogeneous nature of industrial coke and the potential non-additive effects of minerals on coke reactivity. The coke analogue addresses this complexity and heterogeneity through control of its mineralogy, mineral size and mineral dispersion through the analogue, porosity and carbon structures. Initial studies using the analogue were focused on coke dissolution kinetics in liquid iron but recent work has focused in characterization of its porosity, carbon structure and rate of reaction.

Jan 1, 2014