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Prof. Dr. H. Seger and Mr. E. Cramer, Chemisches Laboratorium fur Thonindustrie, Berlin, Prussia (communication to the President)* : We have learned, with much interest, from the pamphlet sent to us, of the work of Messrs. Hofman and Demond, particularly as we observe from their experiments that these gentlemen recognize the usefulness of the Seger cones, and that this method of determining temperatures in the furnaces of the ceramic industry and in the tests of refractory clays is valued, not only in all parts of Germany, but also in other countries. Permit us to say, with reference to the crucibles employed in tests for refractoriness, that we have used of late, besides the magnesia crucibles, also those made of Zettlitz kaolin, with the addition of alumina, previously calcined, with regard to which we beg to refer to our article in the Thonindustrie-Zeitung of December 9, 1893.

Jan 1, 1895

By L. Szecowka, M. Poskart, Siwka M. . J.

Oxides of nitrogen, created during combustion, are the most hazardous components of atmospheric pollution. However, it is possible to limit the negative influence of hazardous components on the natural environment. An experimental appartatus was built to determine the influence of the following "primary methods" on the reduction in concentration of NOx: air staging, reburning and flue gas recirculation. The influence of the simultaneous usage of the primary methods on reduction in NOx emissions was also examined. A significant increase in the efficiency of NOx reduction was achieved in two cases.

Jan 1, 2004

By W. H. Schiffbauer

NIOSH has developed an active proximity warning system called HASARD (Hazardous Area Signaling and Ranging Device) for warning workers as they approach known dangerous areas around heavy mining equipment and other dangerous work zones. HASARD is composed of a transmitter and a receiver. The transmitter generates a 60-kHz magnetic field using one or more wire loop antennas. Each antenna is adjusted to establish a magnetic field pattern for each hazardous area. The receiver, worn by the worker, is a magnetic field strength meter. The received signal is compared against preset levels which are calibrated to identify levels of danger. The receiver outputs can include visual, audible, and vibratory indicators and it can also be made to disable machine functions. HASARD was field tested on a Joy 12 continuous miner, a Komatsu 210 M Haulpak, and on a highwall launch vehicle. Slight modifications were made for each application. HASARD provided warnings as designed and proved to be rugged enough to withstand the harshest of production environments.

By D. W. Hutchinson

One of the most important problems facing the coal industry today is the disposal of refuse from the coal preparation plants in a safe, economical, and efficient manner while complying with all legal requirements. The most commonly used refuse disposal method has been landfill/impoundment. In this method, the coarser refuse fractions are disposed of by layering and compaction into a landfill. The fine coal slurry refuse fraction is impounded in a dam constructed of a portion or all of the coarser refuse fractions. The failure of an impoundment at Buffalo Creek, Saunders, West Virginia and the sliding failure of a coarse refuse pile at Aberfan, Wales, England, resulted in an evaluation of refuse disposal methods by various regulatory agencies as well as coal producers. The result of this evaluation was the promulgation of Federal regulations dealing with the preparation, operation, and final abandonment of coal refuse disposal areas. As a consequence of these regulations the use of the landfill/impoundment method of disposal became in some cases economically unfeasible or technically impossible. At the time of the promulgation of the new Federal regulations, United States Steel Corporation was in the process of designing the Cumberland preparation plant. As a result of the new regulations

Jan 1, 1977

By Alexander L. Field

The rate of elimination of carbon largely controls the time required to make a heat of steel by the basic open-hearth process and to an important degree determines the cost of refining. Practical experience has led to the generally accepted belief that the use of slags relatively high in iron oxide, such as are required to bring about rapid refining, leads to a certain sacrifice of quality in the product. As a consequence, a compromise must be made between the exceedingly slow rate of carbon drop which would correspond to the ideal case and the rapid rate which would best satisfy the condition of minimum cost. An increase in rate of refining necessarily implies an increase in the concentration of iron oxide dissolved in the metal. However, even for the infinitely slow rate that corresponds to slag-metal equilibrium, the metal would contain a certain definite concentration of dissolved iron oxide. It is a matter of great practical importance, therefore, to determine the quantitative relation between the minimum or equilibrium concentration of iron oxide in the metal and the higher concentrations which must actually obtain in practice. The present paper is devoted to the development of certain equations, derived from the established laws of physical chemistry, which will enable this relation between rate of refining and the degree of oxidation of the metal bath to be computed from operating data. So attempt is made to exhaust the possibilities of this general method of treatment. In considering rate of refining, attention is mainly confined to rate of carbon elimination. However, the equations are of a more general nature and their application may readily be extended. The results of the preliminary calculations given herein indicate that increased rate of refining may have a decided effect in increasing the concentration of iron oxide dissolved in the metal. The uncertainty which attaches to the calculated value for this relationship arises in part from probable errors in experimental data on which the calculations are based, and in part from the lack of complete or favorably disposed information on basic open-hearth practice. When the relation between rate of refining and degree of oxidation of the metal has been more accurately established than has been done in the present paper, it will then become possible to consider what comprises

By S. Aktas

The present work describes an investigation of a hydrometallurgical process for the recovery of mercury from spent silver oxide button cells. The cell paste was leached in nitric acid to solubilize silver, mercury and zinc. The optimum leaching conditions, in which mercury is entirely converted to Hg2+ ions and, therefore, does not coprecipitate with silver chloride during treatment with potassium chloride solution, were 1.0 M HNO3, 45° C, 1 hour and 200 rpm. After the silver was removed from the solution, mercury was cemented out with zinc powder with an efficiency greater than 99%. In the cementation experiments, the amount of zinc powder, shaking rate, temperature and solution pH were investigated in detail. The mercury recovery (%) increased as the amounts of zinc powder and the temperature were increased. Zinc hydroxide was precipitated from the waste solution by the addition of sodium hydroxide. The Zn(OH)2 precipitate was then converted to zinc oxide. The proposed process is proven to be simple, straightforward and environmentally friendly.

Nov 1, 2011

By S. Aktas

The present work describes an investigation of a hydrometallurgical process for the recovery of mercury from spent silver oxide button cells. The cell paste was leached in nitric acid to solubilize silver, mercury and zinc. The optimum leaching conditions, in which mercury is entirely converted to Hg2+ ions and, therefore, does not co-precipitate with silver chloride during treatment with potassium chloride solution, were 1.0 M HNO3, 45° C, 1 hour and 200 rpm. After the silver was removed from the solution, mercury was cemented out with zinc powder with an efficiency greater than 99%. In the cementation experiments, the amount of zinc powder, shaking rate, temperature and solution pH were investigated in detail. The mercury recovery (%) increased as the amounts of zinc powder and the temperature were increased. Zinc hydroxide was precipitated from the waste solution by the addition of sodium hydroxide. The Zn(OH)2 precipitate was then converted to zinc oxide. The proposed process is proven to be simple, straightforward and environmentally friendly.

Jan 1, 2011

By Rhulani F. Maluleke, Francis W. Petersen, John H. Marsh, Johann de T. Steyl, Allan Nesbitt

"Pressure leaching of chalcopyrite and nickeliferrous pyrrotite at temperatures between 105 and 200 ºC has been proposed as a potentially viable route for the extraction of mineral elements from sulphide concentrates. In general, these concentrates contain iron, and the economic success of the processes is partially dependent on the choice of the environmentally acceptable iron-removal technique. One of the most widely used methods for the removal of iron from sulphate liquors is precipitation as hematite, goethite, or jarosite. The nature of the iron precipitate formed dictates downstream dewatering and residue treatment and disposal options. However, a better understanding of iron precipitation under the defined process conditions would consequently be of benefit in process design and optimisation.This study investigated the precipitation of iron in the autoclave at temperatures between 105 and 200 ºC. The effects of temperature, acid concentration, iron concentration, and the presence of other metal cations on the nature and composition of the precipitates were determined."

Jan 1, 2003

By AIME AIME

T HE Institute of Metals Division and the Iron and Steel Division will meet jointly at the Stevens Hotel, Chicago, during the week of the American Metals Congress, Sept. 22-26. The Iron and Steel Di- vision of the American Society of Mechanical Engineers, the American Society for Steel Treating and the American Welding Society meet at the same time. but the sessions have been arranged to conflict as little as possible. A rich program of papers and plant visits has been arranged for the members and guests of the two Institute Divisions. The annual dinner and a pro- gram of entertainment are being arranged by the Woman's Auxiliary of the Chicago Section. Members are urged to register immediately up011 arrival and to make dinner and plant visit reservations at the same time.

Jan 1, 1930

By Thi Hien Tran, Huy Hoan Nguyen, Thi Thu Hien-Dinh, Hong Son Nguyen, Duy Anh Dao

"Lithium discovered in La Vi deposit, Quang Ngai province in the Central of Vietnam was estimated with a reserve of approximately 1.5 million tones of lithium ore, which was characterized by mainly lepidolite with muscovite, albite, and quartz. This study investigated reasonable flowsheet and optimal conditions of enrichment technology for lepidolite from the mined ore by flotation process, and producing Li2CO3 and LiCl from lepidolite concentrate by hydrometallurgical process. The significant conditions for froth flotation of lithium ore including particle size, pH of ore slurry, pulp density, chemical spending (collectors, activators, depressants, and frothers), stirring and flotation time were investigated. The identified reasonable flowsheet and optimal conditions for froth flotation the La Vi lithium ore processed lepidolite concentrate containing up to 4 wt.% Li2O with a recovery of 87.61 wt.%. The processes of sulfation roasting lepidolite concentrate using FeSO4.7H2O, then leaching in H2SO4 solution, and removing impurities were carried out to prepare a pure lithium-bearing solution for producing Li2CO3 and LiCl. The products containing 99.05 wt.% of Li2CO3 and 99.02 wt.% of LiCl were obtained with recoveries of 82.97 wt.% and 85.77 wt.%, respectively. The obtained results indicated that lithium ore in La Vi deposit can be processed to produce commercial lithium products and lead the study to develop technology for a new industry of lithium processing in Vietnam.INTRODUCTION Lithium is the lightest metal, which has many superior properties in both metal and compound (such as Li2CO3, LiCl...) states since its discovery in 1817 by Swedish chemist Johan August Arfwedson. Lithium is a favourable material for many high technology fields such as aerospace industry and chemical industry. Some industrial fields which present the main consumptions of lithium include ceramic, glass, aluminum alloy, lubricants, rechargeable Li-ion batteries, synthetic rubber, and pharmaceuticals. The worldwide production of lithium in 2014 was 31,700 tones, continually increased in 2015 of 5% presented 32,500 tones (USGS, 2016). The demand for lithium tends to increase because of the raising in consumption of lithium batteries. Lithium is mined from salar brines, mainly in Chile and Bolivia, but also from granites and pegmatites, which contain minerals with high lithium content such as spodumene - LiAlSi2O6 (Heinrich et al., 1978; Linnen et al., 2012); petalite - LiAlSi4O10 (Sitando & Crouse, 2012); zinnwaldite - KLiFe2+Al(AlSi3O10)(F,OH)2 (Paukov et al., 2010; Kondás J. & Jandová J., 2006); lepidolite - K(Li,Al)3(Si,Al)4O10(F,OH)2 (Luong et al., 2013); and amblygonite - LiAlPO4F (Garrett, 2004)."

Jan 1, 2018

By R. J. Mirville

Flocculation is an important step in the treatment of coal preparation waste waters. The effects of polymer charge and molecular weight and solution pH and ionic strength on the adsorption and flocculation characteristics of a series of polymeric flocculants on some typical waste water constituents have been studied experimentally. The results indicate that the nature and extent of flocculation are strongly system-dependent. For the case of coal, both adsorption and flocculation behavior can be correlated with the polymer conformation in solution. For the mineral constituents, on the other hand, adsorption and flocculation depend also on the surface properties of the solid.

Jan 1, 1979

By M Alston

Many organisations struggle to yield meaningful outcomes from incident investigations. This paper will demonstrate that we can discover systemic issues by rethinking the ‘Why’ and ‘How’ of investigations, fostering genuine risk reduction. Key points: 1. Shift from ‘prevent recurrence’ to ‘learn and reduce risk’: conventional investigations focus narrowly on recurrence prevention, resulting in narrowly focused investigations with limited ability to identify and reduce organisational risk. Redirecting our objective to learning and improvement opens avenues for broader risk mitigation. 2. Understanding daily work for risk insights: recognise that work is not always completed in full compliance with procedures. Workers will adapt how they complete tasks influenced by the conditions and management systems that exist every day. Understanding the conditions and systems affecting everyday work is vital for uncovering systemic risks. 3. Unearth systemic issues through in-depth exploration: many investigations address surface concerns such as lack of training, incorrect procedures, equipment not being maintained, and missing overarching organisational risks. Systemic, organisation-wide risks are not identified. To discover these systemic issues and create shared learnings, investigators must question management systems, including resourcing, planning and risk management. 4. Design actions for safe failure: common actions like discipline and training fall short and do not reduce risk. Resilience emerges from well-designed controls. Incorporate planning, better resources, interlocks, and guarding to bridge the gap between task execution and risk. 5. Investigation Reports as a Business Case: Investigation reports should not simply state historical information regarding an incident. They are to facilitate decision-making and be presented as a business case to drive change. Organisations can move beyond localised risk and ineffective administrative actions by changing investigation objectives and methods. They can facilitate learning, understand daily work intricacies, identify systemic issues, and enhance the capacity for safety, driving lasting risk reduction.

Apr 16, 2024

By Gaifeng Xue, Lei Zhang, Aimin Duan, J. Y. Hwang, Lina Wang

"The removal of chemical oxygen demand (COD) from coking wastewater was experimentally investigated using a three-dimensional electrode reactor. The experimental results showed that the refractory organics in coking wastewater can be effectively removed by this process, and COD removal efficiency was affected by the operating parameters, such as electrolytic retention time, particle electrode dosage, initial pH, current density, aeration amount and electrical conductivity. The experimental results show that the three-dimensional electrode could have a COD removal efficiency of more than 60% and a running cost of no more than 6 YUAN (RMB)/t. This indicates the great potential of a three-dimensional electrode reactor in engineering applications as an advanced treatment methods for coking wastewater.IntroductionCoking wastewater is generated from coal coking, coal gas purification, and by-product recovery processes of coking; it is composed of phenolic compounds, heterocyclic compounds, polycyclic aromatic hydrocarbons, ammonia, cyanide, polycyclic nitrogen-containing aromatics, acyclic compounds, etc. Most of these constituents are refractory, poorly biodegradabile, toxic and carcinogenic [1-3]. Currently, coking wastewater is usually treated by different forms of A/O biological nitrogen removal processes as the primary treatment means, but the aforementioned processes are not efficient enough to meet the requirements of the National Discharge Standard in China (GB13456-1992). According to the continuous requirement on improving environmental protection for the coking industry (revised 2008), increasing wastewater utilization ratios and reducing the discharge of effluent in the coke industry have to be implemented for cleaner production and sustainable development. Therefore, advanced technologies need to be developed to treat coking wastewater and reutilize the product as industrial cooling water, which would be one of the best choices to achieve zero discharge of wastewater and reduce water consumption per ton of steel produced. In this study, a three-dimensional fluidized bed electrode reactor was adopted for the advanced treatment of coking wastewater, and the effects of operating conditions, including particle dosage, initial pH, current density, supporting electrolyte, as well as aeration amount on the COD removal rate, were investigated. Its running costs were also estimated."

Jan 1, 2012

By A. Kotze, D. Messina, E. Nagels, Y. Cryns, S. Arnout

The FlashPhos process aims to recover white phosphorus (P4) from sewage sludge by drying, flash combustion/gasification, and carbothermic refining steps. This study evaluates the material behaviour of sewage sludge ash melting and reduction in a refining furnace for the novel FlashPhos process. Thermodynamic modelling in FactSage 8.2 is combined with experiments from a tube furnace to determine the possible phosphorus recovery and minor element behaviour. For the two studied sludges, a yield of 40% and 75% white phosphorus is achieved after 1 hour at 1600°C, corresponding with a 60% and 25% loss to the metal phase. This is slightly above the calculated equilibrium yield of 28%–73%, which depends mainly on the Fe/P ratio of the sludge. Temperature is found to have a significant influence on the final phosphorus yield when leading to incomplete melting of the ash. A clean slag is produced in the process free of heavy metals making it suitable to be used as a cement-like binder material. The main heavy metals that co-evaporate with the phosphorus are Zn, Pb, As, Sb, and Sn. Additional processing steps will be required to remove these to produce a pure P4 product. The metal alloy consists of mostly Fe and P with smaller amounts of other components such as Mo, Cr, Cu, Mn, Sn, Sb, and V. The final slag consists of CaO, SiO2, MgO, and Al2O3 with virtually complete removal of P and heavy metals.

Oct 2, 2025

By A. W. Fahrenwald

The gyratory mill shown in Figures I and II is a ball mill in every sense of the term, in that the grinding media are balls. The media container, called the shell, is of the form of a shallow cylindrical tank whose position is with axis vertical The mechanism of the mill is designed to swing the shell in a circular path of small radius and, at the same time, to hold the shell in a position of constant orientation, i.e., the motion of the shell is such that every point on the shell surface -- bottom, wall and cover--travels in a perfect (horizontal) circle. The gyratory mill is definitely not a centrifugal ball mill. The balls do not, individually Qr in mass, travel in a circular path. Each ball, under heavy pressure from all directions, develops a sphere, or zone, of activity. Particles entering this sphere are crushed by impact. The gyratory ball mill, unlike the conventional tumbling mill, does not have, and is cursed by, a "critical speed". The speed of gyration, and in turn the power drawn by the mill--and ball potency--is limited only by the mechanical en- durance of the machine parts.

Jan 1, 1959

By D. D. Blue

To insure domestic production of aluminium for, essential civilian and defense uses, the Government, under authority of the Defense Production Act of 1950, programed and promoted an aluminum-expansion program that will more than double the primary production capacity that existed in 1949. In view of this vastly increased production, the raw materials, with respect to both quantity and sources, are reviewed. The raw-material consumption pattern, the requirements during an expansion period when excess quantities of materials for starting up new facilities are consumed, and the probable requirements for production of 1.7 million tons per year of primary aluminum are discussed. The raw materials that presented the most difficult supply problems were bauxite, electrical power, and fluoride salts, and the supply pattern for these materials probably will undergo changes. A major part of the electrical energy for the increased capacity was to come from thermal generation, Jamaica-was to become a major source of bauxite, and synthetic fluoride salts were replacing natural cryolite in increasing quantities. Other raw-material requirements discussed are: Soda ash; lime, and limestone; starch; filter cloth; fuel; alumina; the carbonaceous materials, green and calcined petroleum coke, high-and low-temperature pitch and coke or anthracite; cryolite; aluminum fluoride; the materials going into production of synthetic fluorides, acid-grade fluorspar, and sulfuric acid; and labor. INTRODUCTION The raw materials for the aluminum industry that have received the most publicity are bauxite, the ore that supplies elemental aluminum, and electrical energy, the means by which aluminum oxide is reduced to metal. A number of other important materials are, however, required in large quantities in the production of primary aluminum metal.

Jan 1, 1954

By V. A. Mironenko

The combined study of ground water regime and rock deformations has resulted in the theoretical substantiation of the common principles for analysis of the hydrodynamic and geomechanical processes Within the scope of unique scientific direction -hydrogeomechanics (Mironenko and Shestakov, 1974). The hydrogeomechanical models are widely used now for the analysis and forecasting the extremely important processes connected with the safe and efficient mining operations, as well as with the protection of geological medium. Among these processes are: -deformations of the open-pit slopes and spoil dumps; -consolidation of rocks due to the ground-water pressure drop; -water-end-rock material inrush into mine workings caused by deformations of the undermined rock mass; -geodynamical processes due to the changes in ground water regime; -artificial hydrofracturing in rocks; -transformations of clay linings under the tailing ponds and other technical water basins.

Jan 1, 1990

By T. Wettainen

Malmberget town is located in northern Sweden, approximately 70 km north of the Arctic Circle. Parts of the town overlie more than 20 iron orebodies, consisting mainly of magnetite with smaller quantities of haematite. The mine is operated by the mining company LKAB. Mining started in the 17th century, but not until the railway to the coastal city of Luleå was completed in 1888 did large-scale production commence. Around 1920, mining proceeded underground and today sublevel caving is the only mining method used. Sublevel caving causes subsidence of the ground surface, and buildings and residential areas have been relocated due to the mining activities for more than 50 years. The number of seismic events accompanied by strong ground vibrations is now increasing. In 2008 the mine received a permit from the Environmental Court of Sweden to increase production to 20 Mt of crude ore per year. A prerequisite for the permit was that the mine conducts a number of investigations regarding the environmental impact on the residents of Malmberget. One of these investigations concerned how seismicity will change as production increases and what measures could be taken to reduce inconvenience to the town residents. Today the mine possesses an extensive seismic monitoring system with more than 180 underground and surface geophones. For this study, eleven seismically active volumes in Malmberget mine were identified, and for each of them, a yearly future maximum magnitude interval was estimated based on the current production plan. Relationships between historical seismic events and measured ground vibrations in the town of Malmberget were established, and future ground vibrations caused by expected seismic events were estimated using a probabilistic approach. The outcome was the number of intervals of expected ground vibration per year and per monitoring point. Possible measures to reduce inconvenience for the town residents include blast restrictions, sequencing, and possibly preconditioning. The ultimate long-term solution is an almost complete relocation of Malmberget town. This process has recently been formalized and LKAB is taking an active part in realizing this goal.

Jan 1, 2014

By John B. Umhau

[This !m-i~!.al survey giver, statistice.1 data res;?~dirf ~:rimay ard ?eco~- dqr or scmn tin used in thL: United St,ztas by industries an? incluclcz d;ta on stop&apos;ics, ~urchares, ard plnrt losr.c.5. It is :i ml:anwe of consq~tion in terms of fir.is1icd -prcd.~cts nz6.e iry initid ti11 Sabric:,.torc,, that is, aon- cerns that purchzse virc,in zni s~col~d&apos;l~y i.i.5 ti:; 01&apos; tin c;cra.. rav materi,als ar,d co:lrrert them into !ror?ucts such F!: ti:i plz.te, ~lloyr;, and. c?hemic?ls; comy~nias ;~urchn.&apos;.ii~; alloys, ch:rr.ic,~l::, or tin vl?.tc fcr furthcr a:mflzc- ture ?rc: ~-.f>t i~ci~~dcd. Tilit r~lqe:;tionrr::ire submit tod to consunern ar,nt:incd no dofinition of rnr.oncl.:ryr me$.-i; but, ovrirq to ti~i-: a~counti~ procedure used s.l~o~c-:t 1&apos; thu scrnn hac i~-.rtergol:e ch?rri?~ of ovinerzhip or titlo, thc rc!coverod t! n !its b~en i-c<;,r(it.!rj L.S r,e~3r;d:q met.1. Tbv tin content ~f ]

Jan 1, 1938

By Morland R, Peck R

The Joint Committee of The Australasian Institute of Mining and Metallurgy (AusIMM) and the Australian Mining Industry Council (AMIC) have published a Code for the Reporting of Identified Mineral Resources and Ore Reserves. The Code is the result of an initiative begun in 1971 to achieve industry self regulation of Resources and Ore Reserves reporting which resulted first in guidelines for reporting standards but which have now been incorporated in ASX Listing Rules as a Code with significant sanctions ensuring compliance. This paper describes the background to the Code, its key provisions, and comments on practical aspects of working with the Code and compliance issues.

Jan 1, 1990