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By Nikhil Dhawan, Sanjay Pindar

The limited lifespan, ever-growing demand, and significant lithium and cobalt content are responsible factors for the immediate recycling of discarded lithium-ion batteries. Discharged batteries were dismantled, segregated, and size reduced to recover cathode and anode material. The active cathode material comprises LiCoO2 (65.8%) and LiMn2O4 (34.2%) and was carbothermal reduced with recovered graphite in a microwave furnace followed by water leaching and magnetic separation. A Box Behnken statistical experimental design is used for process optimization. Both cobalt and manganese report to magnetic fraction, whereas graphite and lithium carbonate report to non-magnetic fraction and solution crystal respectively. The final product comprises of cobalt 73% and manganese of 14% with process yield of 36% and saturation magnetization of 76 emu/g.

May 16, 2020

By S. Kauchali

"Underground coal gasification (UCG) is recognized as an efficient mining technique capable of chemically converting the coal from deep coal seams into synthesis gas. Depending on the main constituents of the synthesis gas, chemicals, electricity, or heat can be produced at the surface. This paper provides a high-level graphical method to assist practitioners in developing preliminary gasification processes and experimental programmes prior to detailed designs or field trials. The graphical method identifies theoretical limits of operation for sensible gasification within a thermally balanced region, based primarily on the basic coal chemistry. The analyses of the theoretical outputs are compared to actual field trials from sites in the USA and Australia, with very favourable results. A South African coal is studied to determine the possible synthesis gas outputs achievable using various UCG techniques: controlled retractable injection point (CRIP) and linked vertical wells (LVW). For CRIP techniques, an important result suggests that pyrolysis, and subsequent char production, are important intermediate phenomena allowing for increased thermal efficiencies of UCG. The conclusion is that South African coals need to be studied for pyrolysis-char behaviour as part of any future UCG programme. The results also suggest that UCG with CRIP would be a preferred technology choice for Bosjesspruit coal where pyrolysis dynamics are important. Lastly, the use of CO2 as oxidant in the gasification process is shown to produce syngas with significant higher heating value. Introduction and literature surveyCoal is a commonly utilized fossil fuel, providing over 40% of global electricity demand and about 90% of South Africa’s primary energy needs. However, less than 20% of the known world resources are suitable for possible extraction using conventional surface and underground mining techniques (Andrianopolous,, Korre, and Durucan, 2015). Underground coal gasification (UCG) has the potential to recover the energy stored in coal in an environmentally responsible manner by exploiting seams that are deemed unmineable by traditional methods. The UCG process, if successfully developed, can increase coal reserves substantially. For example, in the Limpopo region of South Africa alone, the estimated potential for UCG gas, based on existing geological records, is over 400 trillion cubic feet (TCF) natural gas equivalent – this is about a hundred times more gas than the existing 4-TCF Pande-Temane natural gas field reserve in Mozambique (de Pontes, Mocumbi, and Sangweni, 2014)."

Oct 1, 2018

By D. C. Lynch

While silica ores are generally considered to have little value, those with exceptionally low B and P content have, potentially, significant worth if processed for use in photovoltaics. The sales value of a cubic meter of ?run of the mill? silica sand is $42 per cubic meter (retail and delivered). If the silica sand can be used to produce solar silicon, its value after processing is $34,000 per cubic meter. Factors that impact the suitability of silica for direct processing in production of photovoltaics are examined.

Jan 1, 2010

By O. V. Bush

Most governments recognize that energy efficiency represents a partial solution to reducing global capital shortages and environmental crises that threaten to seriously impede economic growth. Much of the United States and many foreign countries are embracing the concept of Integrated Resource Planning (IRP) which incorporates Supply Side Management (SSM) and Demand Side Management (DSM). Since SSM comes at twice to three times the cost of DSM, it makes economic sense to employ the energy conservation techniques of DSM. This paper will explain these concepts and some of the incentives being put forward by governments and utilities to promote DSM.

Jan 1, 1995

By Thomas P. Battle

Modern-day direct reduction of iron first developed as a small-scale, low capital and operating cost alternative to the blast furnace. Since commercialization of continuous DR technology in the late 1960s, the market for the products of direct reduction has grown to more than 74 million tonnes in 2012. The initial advantages of DR plants over BF facilities have grown over the years, for several reasons, including the increased size of DR modules, lower energy and emissions (particularly CO2), along with the flexibility to use a number of different reductants. The development of DR technology over the past forty years will be emphasized in this presentation, including recent developments that allow for even more direct sustainability comparisons with the iron blast furnace – and even combine the two technologies for improved synergies. Also briefly discussed will be the possibilities of using direct reduction for non-ferrous ores.

Jan 1, 2014

By Herty, C. H.

The effect of temperature on the physical properties of structural materials has been the subject of many investigations during the past decade. The literature on the effect of elevated temperatures. is voluminous, and during the last four years a great deal of experimental work has been carried out on the effect of low temperatures on the impact properties of steel. For many engineering purposes it is important to know the shock resistance of steels at low atmospheric temperatures, and with the ever-developing field of refrigeration and separation of materials at low temperatures, the normal limits of atmospheric temperature have been exceeded in practice. Iron and its alloys in the unnotched condition have a high impact strength at low temperatures, but in practice variations in type of notches result either from design or accidentally through scratches and surface or internal defects. A study of notched bar impact tests is, therefore, highly important to the engineer. A survey of the literature on low temperature impact testing indicates that chemical composition, heat treatment and method of testing have been the variables which have been considered in most previous work. In only a few instances has any mention of the steel- making method been mentioned and in these the comparison was between steel-making processes and not between steel-making methods on the same process. In view of the wide variations in impact properties at room temperature, in quench and strain ageing and in grain growth of steels of identical chemical composition, (by this is meant the usual five element analysis reported), it was felt

Jan 1, 1957

By Toby Mayo, Tassos Grammatikopoulos, Massoud Aghamirian, MARK FEDIKOW

The Zoro pegmatite project in east-central Manitoba occurs 20 km east of the historic mining town of Snow Lake. A composite sample (Master Comp) was prepared fromthree pegmatite zones within Zoro Dyke “D1” including the North, Central, and South Zones for mineralogical analysis and heavy liquid separation (HLS). The mineralogical examination was conducted on a subsample crushed to ca. P80 of 600 μm to determine the overall mineral assemblage, liberation of spodumene, and assess the potential recovery of spodumene by flotation. XRD and QEMSCAN results show that the sample consists of spodumene (10.5%), quartz (29.3%), plagioclase (29.0%), K-feldspars (21.3%), micas (5.1%), tourmaline (2.9%), and Fe-Mn-phosphates (0.1%). Spodumene is well liberated (88%), but also forms complex particles (7%), and middlings with quartz (4%). Liberation of spodumene increases from 81 in the + 600 μm to 95%in the − 106 μm size fraction. Liberation of quartz, feldspars, and micas account for 89%, 94%, and 83%, respectively. Electron probe micro-analyses and LA-ICP-MS showed that the average Li concentration is 3.7% in spodumene, 2196 ppm in micas, 1001 ppm in tourmaline, and 115 ppm in K-feldspars. Thus, spodumene accounts for 96%, micas 2%, Fe-Mn phosphates 1%, and both K-feldspars and tourmaline for < 1% of the total Li in the sample. The mineralogical data indicate the potential to recover spodumene by flotation with minimal Li losses due to other than spodumene carriers. Heavy liquid separation was conducted on the Master Comp which was crushed to − 6.4 mm, while the − 600 μmfractionwas removed fromthis test. The coarse fraction − 6.4mm/+ 600 μmwas subjected to HLS tests with eight heavy liquid-specific gravity cut-points (2.65 to 3.10 g/cm3). HLS indicates that it is possible to produce a high-grade lithium concentrate (close to 6% Li2O) after the rejection of iron silicates with magnetic separation.

Sep 16, 2020

By G. E. Agar, W. B. Kipkie, R. A. Tenbergen

"This paper describes the successful pilot plant testing of a flowsheet, developed at INCO Ltd.'s J.Roy Gordon Research Laboratory (JRGRL), for improved separation of the constituent minerals in a bulk copper nickel concentrate.The flowsheet utilized the fact that xanthate concentration on the mineral surfaces is the most important variable affecting the high lime separation and that reduction of the xanthate concentration could be effected by an oxidative conditioning stage.When the adsorbed xanthate was reduced to a suitably low level, chalcopyrite and pyrrhotite could be floated to leave a high grade nickel concentrate as the residue. Sodium cyanide was added to the froth product to depress pyrrhotite and any remaining pentlandite. The temporary depression of chalcopyrite by the sodium cyanide was overcome by introducing a conditioning step following cyanide addition. The advantages of the flowsheet; improved copper-nickel separation, operation without heating of the pulp, production of both high grade nickel concentrate ( 29. 5% Ni, . 26% Cu) and copper concentrate ( <O. 5% Ni, 30% Cu) were all realized."

Jan 1, 1984

By L. F. Zeiler

In the past, health concerns in coal mines have primarily centered on those elements which have been essentially inherent to the mining environment. These would include respirable coal mine dust, respirable crystalline silica, excessive noise levels, and diesel exhaust particulates. Commercially-available chemical products are prevalent on mine property. These potentially toxic materials are chemical formulations that can degrease, clean, and lubricate metal parts, separate coal from rock in float/sink operations, and aid in roof consolidation, among other uses. As the general public has become more aware of the hazards of chemical exposures, miners have likewise become more concerned about working with an ever-expanding variety of chemical products on the job. Often, product or chemical specific hazard communication training is inadequate or ineffective, and miners do not know exactly what the ingredients are in the products they handle, or the health hazards involved with their use or misuse. Currently, the Mine Safety and Health Administration (MSHA), by law, enforces 1972 Threshold Limit Values (TLV). MSHA is making preparations to adopt new personal exposure limits for enforcement. The values given throughout the article are 1994 TLV&apos;s and are not enforcement standards, but are used for discussion purposes. They reflect the current scientific thinking regarding personal exposure to these chemical agents. An overview of these products is presented, and the potential health hazards associated with their use are discussed. Controls needed to prevent overexposures, such as proper handling procedures and personal protective equipment, are covered. Methods used to collect and identify contaminants are presented.

Jan 1, 1995

By Ali Kahriman, Abdulkadir Karadogan, Alper Celtikci, Ahmet Varol, Ertugrul Kaya, Turgay Ozat

This paper presents analysis of environmental effects induced by cautious blasting during the construction of the Istanbul Subway 4 Levent - Ayazaga Darulsafaka Metro Tunnel Project carried out by the contractor, located at Northern Istanbul in Turkey. Within the scope of the study, for the prediction of the peak particle velocity and to determine the slope of the attenuation curves together with the maximum charge per delay for the S6-7-8 shafts of this tunnel route, ground vibration components were measured carefully by using five vibration monitors during the construction of the tunnels which required blasting. The particle velocities and frequency values of all blast events are evaluated according to the United States Bureau of Mines (USBM) and German DIN 4150 Norms in order to predict, and compare the influence grades to the neighboring buildings, and structures. Also, data pairs of scaled distance and peak particle velocity obtained from 107 records belong to 51 shots were analyzed statistically. Empirical relationships with correlation at the 95 % confidence interval were established for these tunnel excavations and suggested for the test sites in order to estimate particle velocity of the ground vibrations. As a result of the studies, some practical charts are created in order to minimize the psychological effects of the shots, and simplify the authorities of shots’ job. And last but not least, make sure that the shots will be done in a controlled way.

Jan 1, 2011

By J. B. Hiskey

Thiourea is a reagent capable of complexing gold and silver. With the proper oxidant, thiourea can effectively dissolve metallic gold and silver. A thiourea leaching system possesses potential advantages over conventional cyanidation including acidic solutions instead of alkaline, cationic complexes in contrast to metal-cyanide anionic complexes, and faster leaching rates with acidic solution of thiourea. Generally, the rate of metal dissolution in thiourea solutions is fastest when ferric ion is employed as an oxidant. Acidic thiourea solutions for certain applications could offer a nontoxic and noncorrosive option for processing gold and silver. This paper provides information regarding the fundamental chemistry of the acidic thiourea system, and reviews the dissolution of both silver and gold in acidic solutions of thiourea. The recovery of gold and silver from acidic thiourea solution is discussed.

Jan 1, 1981

By Lorne Roberts

"This paper describes: how Falconbridge&apos;s fire protection system meets the needs of the Lockerby Mine; why the system was chosen over other alternatives; how it is unique, but can be applied to any underground situation; details of the system; how it was installed; the role of a fire protection company; and general considerations when choosing afire-suppresant system.IntroductionIn May 1981, after about three years of searching for the best fire protection system for the re-opened Lockerby nickel mine at Whitefish, near Sudbury, Ontario, Falconbridge Nickel Mines Ltd. installed an AFFF type of fire suppression system. It was designed and supplied by the Fire Protection Systems Division of Levitt -Safety Ltd.The system protects against loss of life, equipment and/or production, and it complies with legislation should fire occur in a fuel storage area and/or scooptram garage and service bay at any or all of the three levels near Shaft No.2.About 18 months after Levitt-Safety began working with Falconbridge, the system was designed and installed at a cost considerably less than that which would be incurred if fire damage caused the loss of two days of production.The fire protection system, which overcomes a limited water supply, is a self-contained balanced pressure proportioning system. It senses the flow and automatically determines the correct concentration of foam to water. It is triggered by a release mechanism which operates a bank of nitrogen cylinders, which in turn pressurize a pressure vessel to expel the foam concentrate and water from the tanks. This solution is piped to sprinkler heads in the specific area."

Jan 1, 1982

By R. L. Keiski, H. Miettunen

"The serpentinite massifs of Hitura are located in the municipality of Nivala in Central Finland. The most important sulfide minerals in the ore are pentlandite, pyrrhotite and chalcopyrite. The ore body consists of amphibolite rocks in contact with serpentinite against mica gneiss. The mean Ni grade of the ore is about 0.7%, and the highest Ni grades have been encountered in close contact. In general, the inner parts of the ore are strongly serpentinized ultramafite and some sulfides have been converted to mackinawite and valleriite. The degree of alteration varies considerably within the ore body and, correspondingly, the grain size of the sulfides varies as well. In this study, flotation tests were done with samples from different zones of the ore body. The flotation test results on the bench scale and plant scale are discussed in terms of the mineralogical features of the ore. Ores in the North Hitura zone differ from those in the South Hitura zone.IntroductionThe Hitura nickel mine, like the entire Nivala area, is part of the Bothnian Svecokarelian schist zone, where numerous Ni-Cu boulders have been discovered since the early 1930s. The Nivala area has therefore been the subject of exploration activities by the Geological Survey of Finland (GSF) and mining companies. The first period of exploration started in 1936, and the Makola nickel deposit, located 3 km south of the Hitura mine, was discovered by GSF in 1937. About 415,000 tonnes of ore were mined at Makola between 1941 and 1954. In 1937, during the exploration and development stage of the Makola mine, boulder tracing and a geophysical survey revealed a significant ultramafic body with some lowgrade Ni-Cu occurrences in the South Hitura zone.In 1961, GSF continued the exploration program in the area and discovered the North Hitura ultramafic complex and its allied Ni-Cu occurrences. In 1964, Outokumpu Oy bought the property and, after underground exploration, comprehensive mineralogical studies, process research and a feasibility study, production started in 1970 (Isohanni et al., 1985)."

Jan 1, 2015

By Oliver C. Ralston

[The NOJ&apos;l..metals Division deals wi tt mi:leral n t inte .ded to be used a ra\o,f materials for extraction of metals. ~ _ ereas, a. materinl containing a chromite, if used&apos; for production of c~1r()rrti1..1r.&apos;l ::tetE&apos; .. l or fcrrochromiu"1, 1,oJould be a chromi te ore, if used as 8. rcfrn.cto~J or for prod .1.ction of chromium chemicals, it is a chromi te-beari [. ~?oCl... Li;{eHise, a r:1a&neti te used for production of iron is a metallifero"&apos;..ls ~in8re..i; if used 8.S a water-filtration granule in .:l magne.tically cleaned filter bed, it &apos;ould be a nonmetallic in-dustrial mineral.]

Jan 1, 1940

By J. S. Roper

"IntroductionSNOW LAKE is situated in northern Manitoba at latitude 54° 55 and longitude 100°, 400 miles northwesterly of Winnipeg, 80 miles northeast of The Pas, 80 miles east of Flin Flon. A 38-mile road from Wekusko, on the Hudson's Bay railway, serves the community.The mine is located in and close to the southern edge of the Precambrian Shield in typical low-relief muskeg and lake country.The Howe Sound Exploration Company, Limited optioned the property from Nor Acme Gold Mines, Limited, after preliminary diamond drilling had outlined two orebodies of low-grade arsenical gold ore.Following the examination and study of geological data and of 50,000 feet of diamond-drill core, and metallurgical tests made during 1942 to 1945, a decision was made to develop the mine and build a 2 ,000-ton mill concurrently. This development has been described by G. C. Lipsey in a paper entitled The Development of a Mining Operation from Diamond-Drill Data which was published in the August. 1952, issue of Mining Engineering.Geological Features of the OrebodiesThe orebodies at Snow Lake occur in volcanic rocks of acid to basic composition and, to a lesser extent, in intrusive hornblendite. The hornblendite is a massive, uniform, .coarse-textured rock except in the immediate vicinity of the ore zone, where it becomes sheared and carbonatized. The acid volcanics have been converted to quartz-garnet-biotite gneiss, and the basic volcanics to amphibolite gneiss. Orebodies have been formed by the replacement of all three rock types."

Jan 1, 1955

After more than 20 years dependence on bituminous coal as a primary fuel for generating electricity, the Pennsylvania Power and Light Company initiated a one-year study on the economics of building an electric generating station using anthracite as a fuel. The study will be completed in December 1976. If the feasibility study so indicates, PP&L will consider installing four 400,000 kilowatt generating units for scheduled commercial operation in 1985. Each unit would consume up to one million tons of anthracite annually. Anthracite generally is more difficult and expensive to extract than bituminous coal, but it has a significantly lower sulfur content than the bituminous coal currently being used by PP&L, thereby eliminating the costs of installing sulfur emission controls at generating stations. Moreover, significant reductions in transportation costs may be realized because the utility&apos;s operating territory is situated in the center of the anthracite region in northeastern Pennsylvania. These advantages may indicate that the use of anthracite is more economical than bituminous coal to PP&L. ASBESTOS -Asbestos production in the U.S. dropped again in 1975 until it was just two-thirds of that in 1973. This was in spite of the very strong demand caused by the Quebec strike. The 7-month strike of the asbestos miners in Thetford Mines, Quebec cut off 55 percent of the normal supply of U.S. consumers. Apparent domestic consumption was less than 75 percent of that in 1974. The wage settlement will probably result in a 20 percent increase in asbestos prices.

Jan 1, 1975

By H. M. Lewis

The current status of the international zinc market is summarized, and a supply /demand outlook is presented for the next five years. A number of technical problems facing the industry are outlined. Introduction ZINC has sometimes been called the unknown metal. Considering that on a world basis it ranks third among non-ferrous metals in production and consumption, zinc retains a certain modesty. It has no distinctive colour like copper, lacks the low density of aluminum or magnesium and is not always easy to identify as a product. The &apos;spangle&apos; of galvanized steel is probably zinc&apos;s most distinguishing feature. The purpose of this article is to develop an over-all review of zinc. Starting with the current position of the metal, the major factors that will shape its future will be described so that an assessment of the outlook for zinc can be made.

Jan 1, 1978

By Douglas Glenn Stalheim

Hot strip structural steel coil used in construction, engineering, transport, structural applications and other applications are widely used in yield strengths from 300 – 700 MPa. However, structural design engineers are now not only requiring various strength levels but also other mechanical properties, primarily good formability, toughness and weldability. To produce a balanced approach to a cost effective structural steel, hot strip coil requires an understanding of utilization of an optimized alloy composition designed for the layout/equipment capabilities of a given hot strip mill to produce the desired metallurgy for optimum mechanical property performance. The term “cost effective” does not just focus on alloy design, but also ease of overall processing from steelmaking, casting, rolling and cooling, stable mechanical properties with a statistically normal distribution, no downgrades/rejections and a product that the end user recognizes as being superior to others. The desired metallurgy is simply understanding what will be the optimum microstructure and cross sectional grain size/distribution needed to meet the mechanical property requirements. This paper is a follow up paper that previously described optimum base alloy designs along with steelmaking/casting processing considerations and will focus on proper reheating, rolling and cooling metallurgy/processing strategies to produce quality cost effective hot strip structural steel coil.

Aug 17, 2017

By H. A. Kee

In the mining industry, as in other business, one of the more satisfactory results of sincere but cheerful effort lies in the proper completion of undertakings and problems, which, to be successful, must continually hold the interest of all concerned in the work. In most undertakings, genuine interest and satisfaction is largely dependent on the proper appraisal of opportunities presented, and the opportunity to associate ourselves with sinking operations at McIntyre central shaft, from the surface to a depth of 4,133 feet, was genuinely appreciated. This opportunity was made possible by the previous persistent and successful leadership of Mr. J. P. Bickell, President, with the assistance of his associates, and of the general manager, Mr. R.J. Ennis, in the development of the McIntyre Porcupine mine, and I beg to state that any success in this sinking operation was very largely due to the congenial co-operation and splendid workmanship of Captain Martin C. Horne, his shift bosses, leaders, and all those who worked with us . Our slogan throughout was " Safety First for Pleasant and Efficient Workmanship," and this general policy made it possible to sink and timber 2.,123 feet during the first year without a serious accident.

Jan 1, 1928

By L. E. C. Pignatari

Mine reconciliation is seen, for many, as a test of the quality of model estimates, while in fact it should be seen as a powerful tool for detecting and correcting problems in each step of mining operations, from resource estimation to metal production. Adequate reconciliation practices allow a more efficient control of the mining processes; however, its results can be illusory unless all parties involved have been in compliance with the principles of sampling correctness. This paper presents a new, segmented reconciliation matrix, which is based on the Theory of Sampling (TOS), developed to monitor gold operations and reserve estimation.

Jan 1, 2011