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By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By T. A. Rickard

Freeman, the English historian, said that he had learned from Macaulay "never to be afraid of using the same word or name over and over again if by that means anything could be added to clearness or force. Macaulay never goes on, like some writers, talking about `the former' and `the latter', `he', `she', `it', and `they', through !clause after clause, while his reader has to look back to see which of several persons it is that is so darkly referred to". He might have learned also from Macaulay that a preposition makes a' feeble ending for a serious statement. How often do you hear `the former' and `the latter' in conversation? Good conversation is a guide not to be dis¬dained. When you must use `the latter', do not confuse it with `the last'. Cheap labor, cheap fuel, and cheap transport are essential, the latter [last] being particularly important in base-metal mining. The apparatus may be used to determine such gases as hydrogen sulphide, chlorine, oxides of nitrogen and some others, as well as sulphur dioxide. In the case of the latter two, etc. The two last mentioned are "sulphur dioxide" and "some others". He should have stated which two, and he should have avoided that wretched phrase "in the case of ". Pinning may be partly prevented by use of chalk, oil, or turpentine. The latter [last] is best. I "Partly prevented" is a poor phrase. `Prevented! is a word that does not lend itself readily to modification. He means `checked' or `corrected'.

Jan 1, 1931

By J. L. Llanca

The New Level Mine project (NLMP), the planned underground expansion of the El Teniente mine in Rancagua, Chile, is expected to reach a daily extraction rate of 137 to 180 ktpd upon achieving full capacity. Production is planned to start in the year 2017 and the current plan is to meet that target through two development phases, from the year 2012 to 2014 and from the year 2015 to 2017. To achieve the 2012 to 2014 underground development schedule, the ventilation requirements have been estimated in the range of 189 m3/s (400 kcfm), and cannot be made available without significant modifications to the current system of El Teniente. As a result, a certain number of alternatives were explored to find a solution to this shortfall, for example, adding raises to generate parallel airways and installing fans to reinforce the current ventilation system. From the alternatives studied, the installation of a second main fan (system) in parallel to an existing one was identified as the best solution, and selected for implementation, however the location was not ideal and there were concerns as to the operation of both fans once the second fan was installed. This paper presents the study used to estimate the operational points of both the current and the new fan, and to justify the parallel installation of the additional main fan. An additional computational fluid dynamics study was undertaken to validate the operational point, given the particular geometry of the fan?s location and placement, to guarantee a stable operation of the fans. Finally, the protocols arising out of this work for starting the fans, and operating them in parallel to avoid generating a stall condition and damaging the investment are discussed.

Aug 1, 2013

By M. Vallée, J. -P. Charette, D. P. Gold

"The Oka Carbonatite and Alkaline Complex is a Lower Cretaceous intrusive body of the Monteregian petrographic province. Carbonate rocks of various types, and associated alkaline rocks of the ijolite and okaite suites, are distributed in a double ring-dyke structure 4 Yi miles long by 1 1/2 miles across. Alnoite and alrioite breccia pipes intrude all rocks of the Complex and indicate, from inclusions, that a cover of Palaeozoic rocks existed at the time of emplacement.The results of radiometric, magnetic and gravity surveys of the Complex are compiled and discussed both with respect to the regional pattern and, locally, the bed-rock geology. The Complex is characterized by high-intensity anomalies.Exploration activities started during 1953, and mining operations began in 1961 on the property of St. Lawrence Columbium and Metals Corporation, at one time the world's largest producer of niobium concentrates. Because of the boudinaged and fractured nature of many of the rocks and the variability in grade of the ore minerals, the role of the mining geologist is both demanding and exacting. Rock types are varied and their mutual relation-ships ambiguous, the minerals are rare and complex, and close geological control of the ore is needed in the mine and in the mill. Closely spaced diamond drill holes are needed for mining control, and the ore-waste contact is defined mainly by assay results.In the exploration for 'carbonatites' in Eastern Canada, aeromagnetic surveys are judged to be the best exploration tool, followed in decreasing order by the search for circular structures on aerial photographs, regional gravity surveys and radiometric surveys."

Jan 1, 1967

By J. E. Schiller

The Bureau of Mines is investigating methods to treat waste water that contains cyanide. This report describes a new method that removes heavy metals and all forms of cyanide. In the first step, hydrogen peroxide and sodium thiosulfate are added at pH 7 to 9 in a 1:2 molar ratio to convert free and weakly complexed cyanide to nontoxic thiocyanate. Then steryldimethylbenzylammonium chloride is added to precipitate ferro-cyanide, and finally, ferric sulfate is added as a sweep floc and sequestrant for heavy metals. After the suspended solids settle, the water is polished by filtering. The water initially contained 1 to 5 mg/L Fe, 1 to 5 mg/L Cu, and 10 to 30 mg/L total cyanide; the level of each of these constituents was reduced to less than 0.02 mg/L.

Jan 1, 1983

By N McKay, J Vann, W Ware, P Hodkiewicz, C Morley

"Geometallurgy is now recognised within the mining industry as an approach that can both maximise value and reduce the risks associated with resource development. The process of spatial ore variability testing for metallurgical response and the use of quick, inexpensive metallurgical proxies has been well developed in the past decade in industry and the literature, and via various collaborative research programs and laboratories. Technology continues to advance with new techniques such as hand-held analytical tools and automated hyperspectral core scanning, allowing for even faster, less expensive in situ geometallurgical testing.In the current mining industry downturn, a critical frontier of geometallurgy is in its application in short-term geological modelling (ore control) and mine planning, and the associated decision-making. This is the end game at which the hard-won knowledge of orebody variability can be exploited to add near-term value. In order for spatial block models to be fit-for-purpose for such tactical uses, they must be populated with key geometallurgical information and then have workflows that use this richer model as a basis of material allocation to destinations so that the true value of the resource is realised.We envision geometallurgy (geomet) programs designed to add and sustain value at two levels:‘Strategic geomet’ has a long-term strategic focus that actively uses all relevant data that helps predict processing performance such as bench-scale metallurgical tests, mineralogy, geochemistry, ore texture etc (‘the geometallurgical database’) to model spatial ore variability and metallurgical response throughout the life-of-mine (LOM). This will enable better resource definition, more optimal mine planning and scheduling, improved process design and sustaining capital strategy over the LOM. The value-realisation is gained by basing all these strategic decisions on spatial models that better reflect the actual value of blocks (or aggregates of blocks) in the model.‘Tactical geomet’ has a short- to medium-term tactical focus that, again, actively uses the geometallurgical database, but also includes new data derived during ore control activities (such as drilling and sampling) to inform allocation-to-destination decisions via the ore control process. This will enable improved efficiency (ie less error) in allocation of mining blocks as direct feed, stockpile or waste. Importantly, this efficiency will be measured in terms of value and not grade, which is an incomplete – and typically biased – proxy for value. The key benefit is that ore control will then be planned and executed on the basis of realised value.We therefore propose a twofold systematic and holistic, value-based geometallurgical process. This process needs to be planned and implemented in an integrated manner, noting that strategic and tactical geometallurgy can be worked on by the same professionals, sharing data, methodologies and potentially models. What differs between the two levels is the required granularity, the business context and (critically) the decision-making time horizons.CITATION:McKay, N, Vann, J, Ware, W, Morley, C, Hodkiewicz, P, 2016. Strategic and Tactical Geometallurgy – a Systematic Process to Add and Sustain Resource Value, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 29–36 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By William A. Hockings

Methods for the measurement of liberation of finely ground iron ores are described. The general method consists of separating a sample of the ground ore into a number of size fractions, followed by measuring the liberation of each fraction. The size separation has been done using electro-formed screens of 20-, 10-and 5-micrometer apertures, and also by air elutriation. Liberation (i.e., the distribution of compositions of individual particles) has been measured by optical microscopy. A computer pro-gram was used to adjust the raw count data so that it agrees with the chemical analyses of the size fractions. Various ways of presenting the results are given, and Some applications of the results to flotation processing are discussed.

Jan 1, 1981

By Brian Patrick, Norman Bell, Mark Schoenfield, Thomas Weber, Dietrich Gross

"The reduction of carbon dioxide emissions and the resultant greenhouse gas affect is hampered by the fact that all fossil fuels contain copious quantities of carbon. Process tweaking can keep the amount of carbon dioxide to a minimum but cannot significantly reduce the amount of carbon dioxide generated. The very nature of utilizing fuels requires that they be burned to release the heat required for the various processes. Reduction of metal oxides to manufacture or modify pure metals, generation of power, transportation and many other forms of fuel usage result in much of the generation of man made carbon dioxide. Oxyfuel is a unique contributor to carbon dioxide emissions. While creating higher concentrations of carbon dioxide the total volume of carbon dioxide generated is reduced. This paper will examine the unique characteristics and potential of oxyfuel that make the generation of lower volumes of carbon dioxide possible.Nearly ten years ago a commercial application of oxy-fuel was installed at Jupiter Aluminum Company in Hammond, Indiana. This process was funded and developed by Dietrich Gross CEO. This aluminum remelt facility now runs completely on oxy-fuel and has continuously for over ten years. This has reduced the melt rates to as low as 750 BTU per pound in continuous melting periods."

Jan 1, 2009

By Carmel Bofinger, Maureen E. Hassall, David Cliff, Eric Stemn

Incident investigation is of utmost importance in most high-risk industries and is often used to improve organisational safety. This study was undertaken to examine the content of past incident investigation reports to determine the effectiveness of the incident investigations. The study uses a semi-quantitative method to assess the effectiveness of incident investigations in the Ghanaian mining industry by evaluating the quality of past investigation reports. The assessment tool consists of five elements with several indicators and rating scales for assessing the quality of an investigation report as a measure of the effectiveness of the investigation. The method was applied to 304 investigation reports of three Ghanaian large-scale gold mines, and the results correlated with incidence rates of the mines to determine if any relationship existed. The results showed that the mines differ significantly in the quality of their investigation reports, suggesting differences in the effectiveness of their investigations. In addition, the incidence rates of the mines negatively correlated with some elements of the assessment tool. In general, the method was found useful and revealed areas where improvement is needed.

By H. V. R. von Rhaden

Systematic quantitative X-ray diffraction analyses performed on diamond-drill cores originating from the Aandenk formation at the Loraine Gold Mine, located in the Welkom goldfield, Orange Free State, South Africa, have revealed the presence of a number of phyllosilicate mineral assemblages which have not hitherto been reported from this region. Rectorite, a regularly interstratified 1:1 mica-montmorillonite "swelling clay", is found to occur together with paragonite, muscovite, pyrophyllite, kaolinite, and chlorite in highly-altered friable rocks. The presence of rectorite in mill feeds may have potentially serious implications with respect to gold recovery. Quantitative X-ray diffraction analysis for phyllosilicates can be used as an aid to correlation, and also to guide the widths of stopes in underground mining. Rectorite has a unique mode of origin, which is discussed.

Jan 1, 1991

By Frank A. Peters

The Bayer process treating Jamaican bauxite was evaluated from an economic standpoint, using standard estimating methods and published data, to present a reference point for cost estimates for nonbauxite alumina processes. The estimated operating cost for a plant producing 1,000 tons of alumina a day is $47.96 per ton of alumina when charging $8 per ton for bauxite and $2.30 per hour for direct labor. The estimated fixed capital cost is $46 million.

Jan 1, 1966

By J. F. Vynne

ABSTRACT This paper examines several of the systems and processes that have been developed over the past few years and are now being utilized by major mining companies on draglines in North America, Australia and South Africa. These technologies include production monitors and reporting systems, GPS navigation systems, structural integrity monitoring systems, structural analysis studies to increase the dragline rated suspended loads (RSLs) and inspection and response strategies. The use of these technologies provides significant increases in dragline production and reduces maintenance costs, downtime and the chance of a catastrophic failure.

Jan 1, 2010

By M Hawkins

The Clem Jones Tunnel (formally known as the North-South Bypass Tunnel), a A$2.88 billion road tunnel project in Brisbane, Queensland, was successfully completed almost seven months ahead of schedule. The project included two parallel 4.7 km long road tunnels, 740 m of intermediate roadway access ramps and two auxiliary ventilation tunnels. The tunnels incorporate intelligent tunnel systems, best practice fire and life safety standards and typical civil tunnel elements.Over the duration of the project the Parsons Brinckerhoff (PB) and AECOM (formally Maunsell) design joint venture (MPB) were Lead Designers to the Leighton Contractors and Baulderstone Bilfinger Berger Joint Venture (LBBJV). Construction of the toll road commenced in September 2006 and was completed in March 2010, with the tunnel opening then. Contributing to the success of this project was the continued support the lead designers gave throughout the construction period.This paper will focus on some of the structural elements that contributed to the success of the project – in particular the cable tunnel structure, a small precast, culvert shaped element under the pavement of the mainline tunnel, and the fit-out of the Gibbon Street shaft which were designed to be constructed in a combination of precast and in situ concrete.The cable tunnel was incorporated early in the design phase and runs the length of much of the tunnel. This paper will outline the challenges faced by the designers with implementing this system which provided significant construction advantages, among which were being able to install a separate ventilation duct during construction and to start fitting out the mechanical and electrical conduits and drainage system while tunnelling was still underway.The Gibbon Street shaft had a length and width of 20 m by 40 m and an overall depth of 38 m. A 20 m high structure of precast and in situ concrete was constructed in the base to accommodate mechanical and electrical equipment and provide a take-off access for the southern ventilation tunnel. The construction purpose for this structure was to provide a junction between the tunnel boring machine (TBM) and the roadheader-style tunnels, a staging platform for commencing the roadheader tunnelling, and a platform where the TBMs could be dismantled and removed.The design was assessed and reviewed many times throughout the construction process to address the needs of each of these stages. Innovative use of precast concrete was used to minimise construction time.Additionally, the designers provided support to the construction team from the time of design completion through to the tunnel opening. This meant that the changes to the design and adjustment of construction loadings could also be assessed. The fi nal outcome resulted in an efficient construction sequence and a project that has provided an excellent outcome for the client, stakeholders and community.

Mar 8, 2011

By A. D. Hammond

Vanadium is a transition metal, ductile, silver-gray metal. It is harder than most metals and steels and it has a good resistance to corrosion, it is stable against alkalis, sulfuric and hydrochloric acids. Vanadium is oxidized in air about 660 °C, although an oxide layer forms even at room temperature. The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2-5. In aqueous solution the colors are lilac V2+, green V3+, blue VO2+ and, at high pH, yellow VO42-. Considered to be as abundant as zinc, metallic vanadium is not found in nature, but it is known to exist in about 65 different minerals. Economically significant examples include patronite (VS4), vanadinite (Pb5(VO4)3Cl), associated to the uranium mineral carnotite (K2(UO2)2(VO4)2?3H2O) and in a vanadium mica called, roscoelite K(V3+,Al,Mg)[(Si,Al)4O10](OH)2. Other important vanadium ore oxides are montroseite (V,Fe)O(OH) and corvusite (Na,Ca,K)V8O2.4H2O. Much of the world's vanadium mine production comes from magnetite-hosted deposit and to a lesser extent, in sedimentary-hosted sandstone. Vanadium is also present in bauxite and in fossil fuel deposits such as crude oil, coal, oil shale and tar sands. In crude oil, concentrations up to 1,200 ppm have been reported. A significant vanadium production comes from the processing of petroleum residues, fly ash and recycling spent catalysts. In 2011, metallurgical applications accounted for 93% of the use of vanadium. Here, an alloy called ferrovanadium is utilized to strengthen steel to be used as rebar in the construction industry, in the manufacturing of axles, crankshafts, gears and chassis in the automotive and transportation industries and in the manufacturing of high-speed tools. In the aerospace industry, vanadium is utilized as a titanium alloy in the manufacturing of airframes and jet engines. The reason for the wide use of vanadium as alloy is its high strength-to-weight ratio, the highest of any engineered material on earth. The major non-metallurgical use of vanadium is in the production of catalysts for the chemical industry. The most commercially important compound is vanadium pentoxide (V2O5), which is used as catalyst in the production of sulfuric acid.

Feb 23, 2014

By Joseph A. DeCarlo

The annual survey of the oven-coke industry by the Bureau of Mines, United States Department of the Interior, described in this report shows that 79 plants were operating in 22 States December 31, 1956. On that date 15,923 serviceable ovens existed, with a maximum total annual coke capacity of 79,965,100 net tons, and 631 new ovens were under construction. Their annual coke capacity was 3,307,300 net tons. The number of serviceable ovens in existence relates only to those capable of producing coke and does not include (1) any ovens that were blanked off or retired permanently in batteries that were operating December 31, 1956, and (2) ovens that had been demolished and were being rebuilt on that date. For this reason, the number of ovens at furnace plants reported by the Bureau of Mines at the end of each calendar year differs from the number reported for the same group by the American Iron & Steel Institute, as the institute includes ovens being rebuilt.

Jan 1, 1958

By Silas Li, Michael Harris-Gifford, Jason Choi, William H. Hansmire

Twin-bore tunnels with a single track in each tunnel are currently the most common subway tunnel configuration. However, a large diameter single-bore tunnel with two tracks separated by a center wall could replace twin-bore tunnels and introduce potential benefits but require necessary modifications to the subway system. In particular, a nominal 40-foot-diameter single-bore tunnel can be considered in lieu of nominal 20-foot-diameter twin-bore tunnels. This paper discusses the benefits and modifications introduced by replacing twin-bore tunnels with a single-bore tunnel, with respect to various elements of the subway related to the tunnel, stations, track, and tunnel systems.

Dec 1, 2022

By M Haest, O Dominguez, D Mittrup

Technological innovations and emerging analytical capabilities are transforming the way drill samples are analysed, with real-time mineralogical analysis made possible. In addition, new business/technical requirements are challenging long standing processes to incorporate more sources of information during planning in order to improve compliance to plan during mining and processing. Unfortunately, the new sources of information that are added do not always have adequate protocols in place to ensure quality data is collected.Spectral data covering the visible – near – short wave – midwave – longwave range are routinely collected by the Geoscience and Exploration department at BHP Billiton Iron Ore for accurate mineralogical identification. These data are used for geological interpretations (logging and modelling) and prediction of physical variables (metallurgical and geotechnical properties).This paper introduces how sampling and quality assurance / quality control concepts have been applied in the spectral data process. The described routine for sampling, data collection/management and reconciliation has been developed to track system precision and accurately and consistently ensure the data is of high quality before it is used across the mining chain.CITATION:Mittrup, D, Dominguez, O and Haest, M, 2017. A new approach to implement quality assurance and quality control to technological innovations – quality of spectral data capture and processes in the minerals industry, in Proceedings Eighth World Conference on Sampling and Blending , pp 265–270 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By Louay Owaidat, Daniel Jabbour, Allan Frappier, Jose Gomez, Mark Stanley, Tino Maestas

The U.S. Army Corps of Engineers (USACE) is implementing a levee strengthening program along the Sacramento River East Levee (SREL) designed to correct 11 miles of deficient levees as identified by recent hydraulic and geotechnical investigations. The first project, the subject of this paper, completed in 2020 resulted in approximately 3.0 miles of improvements to the California Central Valley Flood Protection system. The project area lies along the east bank of the Sacramento River in Sacramento. The program consists of constructing cutoff walls through existing levee embankments to remediate levee through seepage and under-seepage. Key challenges included designing and constructing measures to remediate a 100-year-old legacy levee system, the presence of both industrial and residential properties immediately adjacent to the landside of the levee creating severe space and access limitations, and performing this work during the 2020 statewide mandate to shelter-in-place due to the COVID-19 pandemic. The project team of contractors, USACE, state and local agencies, and engineering firms partnered to bring this project to successful completion within budget and on schedule expending more than 60,000 man-hours with no lost time accidents. With the issuance of future planned contracts, the program will significantly reduce flood risk to the City of Sacramento.

Sep 8, 2021

By Sara Swiokla Korsikas, Toren Olson, Amado Guzman, Yuri O. Zepeda P

Ore agglomeration has been used as part of the heap leaching process for the last 40 years. However, industrial experience shows that the lack of a universal agglomeration standard has limited the benefits of this, otherwise, valuable unit process. The more complex the ore, in terms of the nature and relative abundance of fines (<74 μm), the more important that the agglomeration product satisfies some minimal requirements. This paper presents an agglomeration scale that identifies the quality standards for agglomerates and documents the resulting mechanical, physical, and hydraulic (hydrodynamic) behavior associated with each level on the agglomeration scale. The hydrodynamic properties of an agglomeration product are critical for the proper design of a leaching operation and, as shown in this paper, can be used to select the optimal pretreatment method for a given ore sample. Agglomeration as a unit process not only allows better conditioning of the hydrodynamic behavior of the ore but also creates an opportunity for optimized delivery of reagents to kick-start the leaching process which may ultimately improve the economic performance of leaching. Industrial case data is used to demonstrate the shortfalls associated with low-quality agglomeration and the benefits of improved agglomeration which range from enhanced porous structure (better percolation and drainage characteristics) to better metallurgical response (faster kinetics and higher metal recovery). Proper agglomeration has been used to render otherwise untreatable ores into valuable leaching resources.

Feb 9, 2024

By Thomas O. Llewellyn

This U.S. Bureau of Mines (USBM) report presents a concise review on sources, processes, supply, and historical use patterns of domestic cadmium. It also covers a preliminary estimated cadmium material flow for the year 1989. This preliminary study contains information on cadmium and cadmium-bearing products in the United States. The data in this report were obtained from both published and/or unpublished sources of information. However, in order to estimate the fate of cadmium in each operation or application stage, some assumptions, judgments, and correlations were made by the USBM in an attempt to determine the material flows losses.

Jan 1, 1994