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By T. M. Ruff

A prototype mucking machine designed to operate in narrow-vein stopes was developed by Foster-Miller, Inc., Waltham, MA, under contract with the U.S. Bureau of Mines. The machine, called a compact loader-trammer, or minimucker, was designed to replace slusher muckers in narrow-vein underground mines. The minimucker is a six-wheel-drive, skid-steered, load-haul-dump (LHD) machine that loads muck at the front with a novel slide-bucket system and ejects it out the rear so that the machine does not have to be turned around. To correct deficiencies of the tether-remote-control system, a computer-based, radio-remote-control system was retrofitted to the minimucker. Initial tests indicated a need to assist the operator in guiding the machine in narrow stopes. An automatic guidance system that used ultrasonic ranging sensors and a wall-following algorithm was installed. Additional tests in a simulated test stope showed that these changes improved the operation of the minimucker. The design and functions of the minimucker and its computer-based, remote-control system are reviewed, and an ultrasonic-sensor-based guidance system is described.

Jan 1, 2010

The topic of the relationships between energy and particle size has had two very active periods -the first in the early thirties, when the relative merits of Rittinger's and Kick's proposals were vigorously debated; the second in the early fifties, when Bond's Third Theory was published. This second stage has produced several contributions that have provided a clearer picture of energy /size correlations in comminution. Derivations of a general relationship have been made from single-fracture experiments and from the rate of comminution, and both methods arrive at an equation of the type E = AK-11? The constant A in the equation may be regarded as a grindability parameter. In some respects, an understanding of the phenomena associated with comminution is still lacking, and research in this field should therefore be expanded. T HE SEARCH for a relationship between the energy consumed in comminution and the size of the broken product has been long and varied, and many

Jan 1, 1964

Increasingly specialized blasting needs require that the explosive energy available in a borehole be reliably known for representative blasting conditions. The underwater test, when properly performed, can yield such information and thus provide a reliable rating of explosives in terms of energy release. This paper reiterates the stringent experimental conditions to be satisfied, and data analysis and interpretation techniques to be followed to achieve this. This is supported by detailed experimental studies involving select parameters in both detonator and booster sensitive explosive compositions. The paper also illustrates the inadvisability of equating blasting performance with the commonly calculated energy values.

Jan 1, 2000

By P. L. Yorio, D. R. Willmer

"The current paper presents the results of a study designed to explore the types of practices that are fundamentally important to developing and maintaining comprehensive risk-based health and safety management systems (HSMS) in mining organizations. Eighteen practicing health and safety (H&S) executives, managers, and professionals from a variety of mining commodities were asked to assess the fundamental importance of 20 distinct elements and 133 different practices assembled from a review of several HSMS consensus standards. The research approach assumes that developing and maintaining a robust HSMS requires unwavering attention to activities designed to either: 1) directly contribute to a risk management system’s plan-do-check-act cycle; or 2) build an organization’s internal infrastructure without which the cycle cannot be sustained. The results of this study suggest that the following areas require consistent focus and attention: Leadership Development; Accountability; Knowledge, Skills, and Abilities Development; System Coordination; Culture Enhancement; Behavior Optimization; and Risk Management Studies. Each element and its corresponding top-ranked and top-rated practices are discussed.INTRODUCTION Since the time of the Industrial Revolution, occupational health and safety (H&S) management has been a topic of practitioner thought and academic inquiry (1). In the U.S., decades of regulation and research have resulted in a surplus of prescriptive information (techniques, tools, approaches, standards, programs, practices, policies, etc.). With an abundance of such information, a simple H&S solution to address a problem in the U.S. mining industry may seem straightforward. Counter to this assertion, however, some evidence suggests that the abundance of information may create complexity and cause confusion in the minds of organizational leaders and H&S managers, ultimately discouraging the voluntary pursuit of a sound approach (2). In line with this perspective, in 2006 the U.S. National Mining Association (NMA) formed an independent commission to examine H&S management issues within the mining industry. The findings of the commission called for the mining industry to adopt a risk-based management paradigm. In the presentation of its findings, the commission stated that “…every mine should employ a sound risk-analysis process, should conduct a risk analysis, and should develop a management plan to address significant hazards identified by the analysis” (3). Grounded in the well-known plan-do-check-act cycle, the recommended risk management system allows for mines to ground strategic management choices in their mine-specific hazards and risk profiles"

Jan 1, 2015

By HONGWEI YANG, Lili Zhang

The oxidation behavior of copper smelting slag under non-isothermal conditions was studied by thermal analysis. The results indicate that the copper slag is mainly composed of fayalite ( Fe2SiO4) and magnetite ( Fe3O4). The oxidation behavior can be divided into two reaction stages with the increase in temperature; the first stage is the oxidation of fayalite to magnetite, and the second stage is the oxidation of magnetite to hematite. The two reaction stages cannot be strictly separated; that is, the reaction of fayalite is not complete, and magnetite has begun to transform into hematite. Based on the TG (thermogravimetric) curves, the ABS (Achar–Brindley–Sharp–Wendworth) differential and the Coats–Redfern integral methods were employed to investigate the oxidation kinetics of copper slag during the continuous heating process. The oxidation of fayalite into magnetite and amorphous silica phases occurs mainly in the temperature range of 673 to 1083 K. The activation energies calculated by the two methods are 193.69 and 195.52 kJ mol− 1, respectively. The reaction is consistent with Avrami–Erofeev equation, and the mechanism of oxidation is random nucleation and growth. The oxidation of magnetite to hematite occurs at 1083–1303 K. The activation energies are 308.79 and 328.77 kJ mol− 1, respectively. The mechanism conforms to the Jander equation and is controlled by the two-dimensional diffusion.

May 16, 2022

By A. M. Garbers-Craig, T. Coetsee, T. M. Nemavhola

Accretions often form in furnaces when slag and charge materials attach to the refractory wall and build up over time. Accretion formation is usually unwanted because it reduces the working volume of the reactor and hinders material flow through the reactor. However, in some instances a thin, stable accretion layer may be desirable to protect the underlying refractory material. In order to prevent and/or manage accretion formation, it is important to understand the underlying principles of this phenomenon in the particular reactor. Excessive accretion formation hampered production at the Exxaro FerroAlloys ferrosilicon melting and atomization plant. This plant uses induction furnaces in which a 15% silicon-iron alloy is produced by batch smelting a mixture of ferrosilicon of 75%Si grade and low-carbon steel. The molten ferrosilicon alloy is then gas-atomized to a powdered product for use as a dense medium in mineral processing plants. The objective of this study was to investigate the effect of different impurity levels in the ferrosilicon feed material on the extent of accretion formation as well as the effect on the accretion properties, which influence the ease of accretion removal upon furnace shut-down. Refractory and accretion samples were collected after a furnace shut-down and characterized using X-ray diffraction and scanning electron microscopy–energy dispersive spectroscopy. It was concluded that the trace elements in the FeSi-75 feed material (Al, Ca, Mn) were mostly responsible for accretion formation, but that rust on the low-carbon steel and oxidation of the steel contributed to accretion attachment to the lining. The total contaminant content, calcium to aluminium ratio in the FeSi-75 feed material, and thereby the liquid to solids ratio in the accretion at temperature determine the strength of attachment as well as growth of the accretion.

Feb 2, 2021

By S. C. Termes

This paper discusses recent Federal Bureau of Mines research on the selective flocculation of various minerals with insoluble crosslinked starch xanthate (ISX). ISX is insoluble, has a shelf life of over a year when kept cold, and has a higher molecular weight due to cross linking than the soluble noncrosslinked starch xanthate used in previous flocculation studies on nonsulfide minerals. ISX readily flocculates a number of sulfide mineral fines but not silicious gangue. Floc formation, floc size, and settling rate are strongly dependent on pH, with the pH dependence differing for each mineral. Bornite has been selectively flocculated from bornite-quartz mixtures, and the bornite-containing flocs were separated from the unflocculated quartz using decantation and washing procedures.

Jan 1, 1982

By M. J. Ferrante

Relative enthalpies of V20S from 298.15 to 1,101.0 K were measured at the Bureau of Mines to provide data needed for the advancement of min-eral technology. Enthalpies were measured with a copper-block calorimeter. A sharp melting point was found at 951 K, with [~~ = 15.690 kcal/ mol ] for the standard enthalpy of melting. Tabulated values are given at selected temperature increments between 298.15 and 1,500 K for the standard relative enthalpy [(HO -H~98),] heat capacity (CpO), entropy (SO), and Gibbs energy function [-(Go -H298)/T]. Standard relative enthal-pies are also given in equation form and combined with data from the literature to derive values of standard enthalpies of formation and Gibbs energies of formation.

Jan 1, 1986

"Standing 92 stories high and just over 1,362 ft tall, Chicago’s Trump International Hotel and Tower is perfectly positioned at the center of one of the world’s most impressive skylines.The Tower serves as a link between its famous predecessors, Willis Tower (formerly, the Sears Tower) to the south and the John Hancock Building to the north. Originally planned to be the world’s tallest building, the project was scaled back when the developers started questioning the need for super-tall buildings after the September 11, 2001 terrorist attacks. In its River North neighborhood, Trump Tower dominates the skyline as a symbol of Chicago’s last great building boom, standing triumphantly over other high-profile projects that have been postponed due to current economic realities.It is often said that the three most important factors in real estate are location, location and location. This maxim was not forgotten by The Trump Organization when the site was selected for the International Hotel and Tower. Located two blocks west of Michigan Avenue and Chicago’s famed Magnificent Mile, the site is bound by the historic Wrigley Building to the east, Wabash Avenue to the north and west, and the Chicago River to the south. The building’s position along a bend in the Chicago River allows visitors and residents unobstructed views to the mouth of the Chicago River and Lake Michigan. Site ChallengesUnderneath the site there are approximately 10 to 20 ft of sand and urban fill underlain by soft Chicago blue clay. At 75 ft in depth, the soft clay transitions into Chicago hardpan, a very hard till that was consolidated by the glaciers over 10,000 years ago. Below the hardpan, the till turns granular with cobbles, boulders and water under pressure. Bedrock is about 100 ft below existing grade and has a weathered surface with fractures and clay seams. Unweathered limestone bedrock is sound and hard with unconfined compressive strengths of 10,000 to 20,000 psi."

Jan 1, 2009

By G. Mucsi

This paper deals with the laboratory investigation of cathode ray tube (CRT) glass based glass foam, a relatively new product so called ?Geofil bubbles?. The main process engineering material properties of raw materials, such as particle size distribution, moisture content, density and specific surface area are shown. Then the preparation of raw cathode ray tube glass waste is presented including the following steps: crushing in impact crusher, grinding in laboratory scale ball mill, mixing, pelleting and sintering. We found that it was possible to produce foam glass (with proper mechanical stability and particle density) from the investigated waste CRT glass. The material characteristics of the final product strongly depend on the sintering conditions. Optimum conditions were determined particle size fraction was found to be 4-6 mm, temperature 800 0C, residence time 7.5 min. Keywords: waste CRT glass, grinding, pelleting, sintering, glass foam

Sep 1, 2012

By K Knorr, S Birch

The mineralogy of new certified-reference-materials (CRM) for X-ray fluorescence from Western Australia (ASCRM 030 to 035) was analysed by X-ray diffraction using the BRUKER energy dispersive one-dimensional detector LYNXEYE-XE. The samples were studied using standard-less quantitative phase analysis, based on the Rietveld method. This method delivers the relative amount of crystalline phases. All materials were found to be high-grade iron ore predominantly consisting of hematite and goethite and very low amounts of magnetite. In addition, the gangue mineralogy was characterised. It consists of low-per cent amounts of carbonate (siderite/calcite), quartz, kaolinite, chlorite and gibbsite.Furthermore, all samples were analysed with the external standard method. This is an elegant way to probe for amorphous content without adding an internal standard. All six samples were found to contain up to 16 per cent amorphous or nano-crystalline material.CITATION:Knorr, K and Birch, S, 2013. Mineralogy of new Australian x-ray fluorescence standards, in Proceedings Iron Ore 2013 , pp 269-274 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By R. W. Huber

The successful development of a titanium prototype of the 81-mm. mortar base plate for the Army Ordnance Corps is outlined in this report. Information is presented dealing with forming, forging, and machining, welding and assembly techniques, and design changes relative to this prototype. INTRODUCTION The work of the Federal Bureau of Mines in making ductile titanium available2/ has resulted in the establishment of a new industry. Owing to its strategic importance and the combination of low density and high strength, titanium has received considerable attention as a structural metal. Titanium's favorable strength-to-weight ratio is of particular importance to the Army Ordnance for equipment that is transported by airplane or by foot soldiers.

Jan 1, 1956

By S. P. Kinney

The efficient operation of a blast furnace is primarily dependent upon efficient contact between the descending stream of solid materials and the ascending stream of gas. The United States Bureau of dines is conducting a program of research dealing with the interior of the present-day furnace. The work is being carried oat by.(1) observations on commercial furnaces end (2) experiments in the laboratory. Through the courtesy of the officials of the Illinois Steel Co. it was possible to make a detailed investigation of the interior of the shaft of Number.4 furnace at the company's South Works, South Chicago, Ill. The experimental work is to be reported in a U. S. Bureau of Mines bulletin which will include the results of several thousand observations on the interior of the shaft of this furnace. Such of the data as are presented later in this paper constitute only a brief summary.

Jan 1, 1929

By Hoberg H, Schneider FU

The stability of suspensions can frequently be controlled only by the use of supplementary polymeric agents. Such methods date back to the time of the ancient Egyptians, who used natural rubber as a deflocculant for carbon black in the manufacture of ink (Anon, EncyclopediaBritannica, 1968). Since the development of synthetic polymers in the 1950s they have been deployed in all manner of applications. Indeed the mining and paper industries as well as industrial or communal waste water treatment plants are largely dependent on flocculants which make a major contribution to the relief of the environment. As some of the polymers used are carried out from the process via purified water, problems can emanate from the application itself as long as no reliable data is available as to the exact whereabouts of the polymers and their impact on the biosphere. In order not to invade other systems, they would have to be biologically degradable which has not, until now, been confirmed (Blockhaus, Sequaris and Schwuger, 1991; Schumann, 1991). It has, however, previously been demonstrated (Hoberg et al, 1990) that when process water circulates in mineral processing operations, residual amounts of polymeric flocculants can have extremely adverse effects on the selectivity of flotation processes. The adsorption behaviour is consequently one of the most important considerations in the development of new polymers, the aim being to minimise the amount of non-absorbent matter. The objective of the investigations carried out on ampholitic synthetic polymers of high molecular weight to be reported on here was to permit the connection between settling index and adsorptivity to be characterised in greater detail. As the level of knowledge concerning flocculation and polymer adsorption in real systems is still limited in spite of numerous practical and theoretical studies in this field, the experiment was designed to be relatively broadly-based. As well as investigating various raw materials, an attempt was made to compile results on the influence exerted by different surface charges.

Jan 1, 1993

By R Knight

"In project evaluation there are two matters of keen interest to non-executive directors: the process by which an investment recommendation is reached, as well as the investment itself, as presented. It is sometimes mistakenly believed that Boards of directors are interested only in the result. That is not so. The process by which project evaluations are derived and socialised with the Board is as important as the result, sometimes more so.Setting aside the gloomy predictions of the doomsayers and looking through short-term volatility in supply and demand, the overall availability of mineral resources more often than not exceeds demand. There are in reality more development projects in prospect at any one time than are needed to meet the market. Only the fittest will prosper, although some others may survive.Optimism springs eternal in the mining industry and every project promoter, executive or entrepreneur has a convincing project development case. Some will create value for shareholders, but the historical evidence suggests that many will fail to meet the expectations set in their evaluation.Boards of directors make the final decision to invest, or not, in a new mine. Knowledge is power, and on that basis the balance of power favours management. Management has the facts (or in some cases, what passes for fact) and the passion to invest. The non-executives have the power of approval – yes or no – but before making a decision directors must demonstrate due diligence, the essential precursor to project approval.Management has a vital part to play in facilitating that due diligence process and in encouraging the independent thought processes of the Board. A closed approach by management fosters a negative, risk-averse attitude on the part of the Board. One that encourages an understanding of the rigour of the project evaluation process and the robustness of the result will allow directors to understand better the implications of their decision.CITATION:Knight, R, 2016. Project evaluation – a non-executive director’s perspective, in Proceedings Project Evaluation 2016, pp 11–19 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 8, 2016

By A. Haxhiaj, E. Haxhiaj

"The paper has as a studying object the issue of effective management of gasses’ heating and dusts in reductive melting process in lead (Pb) metallurgy. It also analyses the issue related to the usage and recycling of dusts and gasses in all pyro-metallurgical processes of technical lead production. The paper contains the analysis of technological process of separation of humidity, gasses, and dusts of valuable remainders in “Trepça” plant. Paper has the results of theoreticalexperimental studying, analytical and graphical of gasses thermal balance depending on height and composition of load, and the coke quantity on load for reductive melt in “Water-Jacket” furnaces. With thermal balance, having into consideration all parameters of heat in entry and exit depending on aforementioned factors we aimed to optimize the parameters of the process, keeping the attention to the minimization of energy consumption, and the overall influence on environment.1. IntroductionThe upper part of the furnace which is the study point of this paper lies from the reactions zone of Water-Jacket furnace and it also includes the furnace neck. In this zone has been elaborated the zonal material balance referenced third in the row. The separation of humidity, dusts, gases and lead with gases depends on many parameters like temperature, load composition, and height of load inserted in the furnace, and also the height of preheating zone in Water-jacket furnace. Lead oxidizes in reaction zone of the furnace and exhales with gases like dusts and small particles after which falls in worthy storage of Trepça plant and has negative effects in environment, and economic stability of reductive melting process of Water-jacket furnace. Thermal balance of gases in this zone depends on many factors; height and load composition, coke quantity in a load. The calculation has been done as the standard methodology of thermal calculation is done; moreover, by using a computer for mathematical models which enables very accurate results. We must emphasize that acquired and used heat in reaction zone and melted materials is calculated in others studies, so their influence in preheating zone is assumed."

Jan 1, 2010

By O. C. Garst

"The lightness and relatively high strength per unit weight of certain magnesium alloys have interested designing engineers for many years. Ever since the noted investigator Bunsen3/ first produced the element by electrolysis of the fused chloride in 1852, utilization of this light metal has been considered. Magnesium is widely distributed over the earth's surface in high-grade as well as low-grade deposits; it occupies eighth place in the list of elements arranged in order of their decreasing abundance, as there is 2.24 percent magnesium in the earth's lithosphere. Even though the element is distributed widely in the form of relatively insoluble: minerals and also as soluble salts in sea water and spring water, as well as being an indispensable constituent of plants and animals, the technology of magnesium was slow development. This slowness of development was first caused by confusion or the part of the early investigators who thought that magnesia, magnesite, magnetite, and the pyrolusite-type manganese ores were compounds of the same metal. At one time the metal that we now know as manganese was called magnesium, and magnesium was called either magnium or talcium. In addition to this coon, the chemical activity of the metal, especially at high temperatures, created problems that are still difficult to solve.With the advance of science in all branches, .methods for -he production of magnesium were developed. The methods first used for producing the element were: (1) reduction of magnesium salts with alkali metals,4/ (2) electrolysis of aqueous solutions of magnesium salts, and (3) electrolysis of fused magnesiun salts.The first attempts to produce magnesium by the carbothermal reduction of magnesia were failures as sufficient thermodynamic knowledge concerning the reversibility of the reaction between magnesia and carbon was not at hand. As the igneous electrolytic Method for making the element was more easily controlled than the others and. yielded more metal per unit of energy, considerable work was expended on the improvement of this process. The work in this field paralled that on the electroreduction of aluminum and the alkali metals. For several years the entire magnesium industry was dependent on this igneous electrolysis process for its supply of the metal, but as demand for the metal increased and more scientific knowledge was available, other processes were developed. Today magnesium is produced by the electrolysis of molton magnesium chloride electrolytes, the carbothermal reduction of magnesia, in arc furnaces followed by shock cooling of the furnace gases by a coin inert atmosphere, and the silicothermal reduction of calcined dolomite in stainless steel retorts."

Mar 1, 1946

By Jun Ohbayashi, Yoshiyuki Yagiura, Hiroaki Miyatake, Masuo Kondoh, Naotoshi Shinkawa

"Reducing the improvement ratio of ground improvement is an extremely efficient way to reduce the construction cost and construction period of mitigation measures for soft ground. The Arch Action Low Improvement Ratio Cement Column (ALiCC Method) is one method for this, and it is being increasingly applied to sites. This method enables us to rationally evaluate the embankment loads that are acting on cement improved soil columns and unimproved ground, by considering the arch action generated in the embankments and from there thusly allocate improved soil columns in spans of a greater distance than those needed for conventional methods. As a result, it serves to reduce construction costs and the construction period, while also minimizing the settling of the embankment and differential settlement, by placing numerous improved soil columns in the ground immediately beneath the embankment at equidistant intervals. In this report, we give a basic overview of the ALiCC Method, report typical construction results from real life cases that have been carried out, and make comparisons with other construction methods in order to report on the effectiveness of this design method.OVERVIEW OF ARCH ACTION LOW IMPROVEMENT RATIO CEMENT COLUMN (ALiCC) METHODIn the area of mitigation measures for soft ground, a significant role is played by ground improvements using improved materials such as cement. For this reason, a reduction in construction costs and construction period required for ground improvements has become of greater importance. The Public Works Research Institute carried out joint research with Kiso-Jiban Consultants Co. Ltd., Kitac Co. Ltd., and Fudo Tetra Co. Ltd. over a period from 1998 through 2002, and, from that, developed the ""Arch Action Low Improvement Ratio Cement Column Method"" (hereinafter referred to as the ""ALiCC Method"") that enables ground improvement with a lower improvement ratio (the improved area ratio is approx. 10% to 30%) than is required for conventional methods, while also ensuring stabilization and minimizing the settling of embankments.In the area of mitigation methods for soft ground by deep mixing, the dominant method until now has been that (50% or more of improvement ratio) shown in Fig. 1. This method comprehensively improves the area under the face of the slopes of both sides of the embankment. This is based on the calculated stability against rotational slip, which states, ""the most effective way to ensure the stabilization of the embankment environment is to carry out improvements of the area under the face of the slope."" Therefore, for the area under the face of the slope, ground improvement by deep mixing was done, and for the soft ground in the area under the middle part of the embankment, accelerated consolidation methods (hereinafter referred to as ""conventional method"") such as sand draining method and paper draining method were used. Mitigation measures that combine these improvement methods have also been mainstream for a long period of time and are used to prevent side deformation around the embankment. However, there have been some problems that have occurred, such as a situation where consolidation settling occurs in the center area under the embankment where no improvement had been carried out. This phenomenon leads to a situation in which the improved soil columns in the area under the face the of slope are pushed to the outside, which results in side deformation occurring around the area of the embankment, and additionally the occurrence of a step due to a situation of differential settlement between the improved ground and the consolidation advancing part, which results in cracks in the embankment."

Jan 1, 2015

By D. Kalumba, S. Jjuuko

"Thin Spray-on Liners resist relative small deformations (< 1 mm) between rock blocks or fragments in terms of a combination of shear, adhesive and tensile-bond strengths. Shear-bond strength addresses the ability of a thin liner to resist stresses that act parallel to the rock-liner interface. Therefore quantification of shear-bond strength is essential in the formulation of design standards and requirements for Thin Spray-on Liners. In this paper Thin Spray-on Liner support mechanisms are reviewed. In addition previous methods of Thin Spray-on Liner shear-bond testing are discussed. The paper also explains the research being carried out at the University of Cape Town to investigate the effect of different parameters on the shear-bond strength.INTRODUCTIONRock surface support is widely used to combat rockfalls and resulting injuries and fatalities in the vicinity of active faces (Potvin, 2002), where workers spend most of their time (Adams & Baker, 2002; Potvin, 2002; Lacerda, 2004). The conventional (traditional) surface support systems in underground rock support include passive methods such as mesh and lacing and active methods such as shotcrete. However, rockfall sources between 1990 and 2000 in Nevada gold mines showed a steady increase in rockfall injury associated with mesh support as shown in Figure 1 (Lacerda, 2004). The conventional methods also negatively impact the mining operations with regards to costs, logistics and mining cycle times due to large material volumes (Tannant, 2001; Ozturk & Tannant, 2010; Ferreira, 2012). Therefore, these systems need to be substituted, with enhanced methods, in order to realize the business target of the mining industry of providing the planned return on investment made without harm and within budget."

Jan 1, 2015

By M. Zaki El-Sabban

Tables of chemical thermodynamic properties for the ideal gas state from 0° to 1,000° K are reported for eight alkanethiols, three cycloalkanethiols and arylthiols, six thiaalkanes, two dithiaalkanes, three thiacycloalkanes, and three thiophenes. They are based on current physical and thermochemical constants and definitions, reliable vibrational assignments, and the latest insights into molecular structure and energetics.

Jan 1, 1970