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By E. Ghali, N. Sorour, G. Houlachi

"The binary Fe53Mo47 and ternary Fe54Mo30P16 coatings have been electrodeposited from citrate-based electrolyte on mild steel (MS) substrates. The electrodeposition has been conducted for 6 hours at 20 mA cm-2 and 30°C. The electrochemical tests were carried out in chlorate solutions containing 300 g L-1 NaCl and 4 g L-1 K2Cr2O7 at pH 6.4 and 80°C. A number of surface characterization techniques such as SEM-EDS, XRD and EMP were used to study the microstructure of the alloys. The electrocatalytic activity of these coatings was investigated using steady-state polarization and galvanostatic technique. This study revealed that the Fe-Mo-P coating could be considered as a promising cathode material for the hydrogen evolution reaction (HER). The results showed an important decrease of hydrogen overpotential for Fe-Mo-P alloy as compared to that of Fe-Mo and especially MS which is a traditional cathode in chlorate industry. The HER overpotential for Fe54Mo30P16 at current density of 250 mA cm-2 was decreased by 30% in comparison to that of MS (1029 mV), and by 16.5% to that of Fe53Mo47 coating (857 mV).INTRODUCTIONSodium chlorate is used for manufacturing of several daily consumption products. This chemical is mainly employed for the production of chlorine dioxide (ClO2) that is a bleaching agent used in the pulp and paper industry. The ClO2 is also consumed for generation of perchlorates, chlorites and other chlorates, as an herbicide and in uranium processing (Cornell, 2002). Sodium chlorate is produced industrially via following overall formula in un-divided electrochemical cell (Nylén & Cornell, 2009):"

Jan 1, 2016

By L. Thompsen

High-pressure grinding rolls (HPGR) offer capacity increases, savings in operating costs and metallurgical advantages. The first installation of the Polycom HPGR in a copper ore treatment plant occurred in July 1995 at Cyprus Sierrita’s mining complex near Green Valley, AZ (Fig. 1). Until that time, the benefits this technology offers for copper and gold ore were only demonstrated on testwork. In other industries, such as diamonds, HPGR have proven to be reliable in industrial-scale plants and have set a new standard for this kind of ore treatment plant. HPGR are also successfully used for the comminution of coal, blast furnace slag and in cement and pelletizing plants. The installation at the Cyprus Sierrita Mine should prove the economical benefits in commerical-scale copper mining, confirming the results of comprehensive testwork(Fig. 2).

Jan 1, 1996

By K. Lillkung

The use of secondary sources has become a very attractive option in the production of platinum group metals as the demand for these metals has increased. One of the promising sources are the spent catalysts, which provide an attractive source as they have relatively high metal content compared with the ores where the metal is originally extracted from. The concentration of platinum group metals in catalytic converters is in the range of 0.1-1 mg/g as the concentration in ores is usually less than 10 ppm. Aqueous chloride solutions are claimed to be a cost effective way in which platinum group metals can be brought into solution and concentrated. In this work the effect of different parameters on the dissolution rates of Pt, Pd and Rh were investigated. The parameters investigated were the Cl- concentration, the temperature and applied potential. Chloride concentrations used were 62.5, 90, 125 and 250 g/l. Temperatures were 25, 40, 60, 80 and 94°C. Potentials were 950, 1050, 1150 and 1250 mV vs. SCE for Pt and Rh and 380, 410, 440 and 470 mV vs. SCE for Pd. Dissolution rates were calculated from the current densities determined by potentiostatic measurements. Thin wire electrodes were used in the measurements. As expected, higher temperature, higher potential and higher chloride content generally increasedthe dissolution rate. However, the effect was nonlinear and slightly different for different metals. The results show that strongly oxidizing conditions are needed in order to achieve reasonable dissolution rates. With the highest chloride content and at potential of 1250 mV vs. SCE and 94°C the dissolution rate of Pt was nearly 1 mm/h, whereas in similar conditions Rh achieved a rate of only nearly 100 µm/h. Similarly, with the highest chloride content and at potential of 470 mV vs. SCE at 94 °C the dissolution rate of Pd was nearly 1 mm/h. Keywords: Pt, Pd, Rh, redox potential

Sep 1, 2012

By D. L. Sawyer

Aqueous C12-02 leaching procedures developed by the Bureau of Mines to produce zinc chloride from zinc sulfide bulk concentrates were effective in extracting 99 pct of the zinc and 97 pet of the silver contained in samples of massive seafloor sulfides from the southern Juan de Fuca Ridge. Zinc sulfide (sphalerite and wurtzite) mineralization comprised 55 and 88 pct of two specimens provided by the U.S. Geological Survey for this study. Minor occurrences of galena, chalcopyrite, and other minerals in the sulfides permitted the recovery of pregnant liquors that were low in metal values other than zinc, which were successfully purified by a two-step cementation procedure using zinc dust.

Jan 1, 1983

By K. B. Le Bron, T. van Aard

The empirical pillar strength formulae have been widely, and in most cases successfully, applied to design underground pillars for mines in the Bushveld Igneous Complex (BIC). This paper presents the case for combining the empirical method with numerical modelling when it comes to crush pillar stability analyses. The benefits include an understanding of potential failure mechanisms, which may then be accounted for in the designs. In addition, the impact of weak layers, such as shear zones, the impact of the dip of the orebody, differences in layouts, such as holing widths and the presence of advanced strike gulleys (ASGs) immediately adjacent to the crush pillars, and stress regime (k-ratio) may be studied using numerical modelling, as it is not accounted for in the empirical method.

Mar 5, 2025

By C. R. Austin

THE investigation described in this paper deals with the development of high-temperature alloys of the Konel series over a considerable period of time at the Research Laboratories of the Westinghouse Electric and Manufacturing Co. The word "Konel" has been coined to designate a class of alloys which are essentially nickel-cobalt-iron with other elements added, usually in small quantities. Most of these alloys contain titanium, usually about 2.5 percent. The main consideration related to strength at high temperatures but the thermionic characteristics of the alloys was also of considerable importance. It is, however, with the mechanical properties at elevated temperatures that we are herein concerned. Much attention has also been devoted to their age-hardening characteristics. There is little need to stress the utilitarian aspect of this subject, as it has been discussed frequently. Alloys exhibiting superior properties at normal or elevated temperatures rapidly find many suitable applications. There may be some question, however, as to what constitutes a "superior alloy, " or an alloy that may have good service possibilities at high temperatures. The problem is complex and various means have been employed to predict the useful life that may be expected of a material. In recent years the "creep limit" has been used as the best means of evaluation. Such tests necessarily are prolonged and hence collection of data is very slow. In a general survey of many alloys therefore the creep test is not desirable and recourse must be had to much shorter time tests in order more rapidly to select alloys which appear to show promise. For this reason the present survey has been made using the high-temperature tensile test and a bend' test developed by Howard Scott.1 In the tensile test the conditions have been standardized for all tests, so that values obtained are at least comparable, one alloy with another, although the absolute values recorded merely indicate the mechanical properties at the given temperature under a definite rate of loading.

Jan 1, 1931

By S Gillies, H W. Wu

A study has been undertaken into mine ventilation systems currently in use within Australian modern coal longwall (LW) extraction mines. It reviews systems and discusses evolving changes being adopted to address the more complex challenges. There is a strong move to longer panels, wider faces, greater extraction heights, increased production rates, more efficient ventilation and decreased personnel. Each of these changes is motivated by improvement in productivity and generally leads to cost reduction. In addition, mine workings are moving deeper, which results in increased ventilation control issues such as higher total and respirable dust levels, greater seam gas contents in parallel with lower in situ permeabilities, spontaneous combustion and heat management issues. A comprehensive database of Australian LW ventilation practice is analysed. Currently there are a variety of LW panel ventilation circuits used in Australian underground coal mines due to various combinations of seam characteristics, gas emission rates, spontaneous combustion, geological features and surface constraints. The main issues usually addressed in the designing and planning of ventilation circuits for LW panels are airway velocity, gas concentrations, LW cutting methods (eg Bi-di, Uni-di or half web), ventilation of control devices, pressure differentials and leakage paths and understanding gas concentrations across the length and width of the goaf. If the ventilation circuit can manage the applied contaminant load (gases, heat and dust) at an acceptable cost and circuit duty, then supplementary controls, such as gas drainage, refrigeration and dust sprays and scrubbers, may not be required. CITATION:Gillies, S and Wu, H W, 2013. Review of Australian longwall panel ventilation practices, in Proceedings The Australian Mine Ventilation Conference , pp 87-94 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By C. M. Clapperton, K. E. Darke, A. J. Boyce, C. M. Rice, S. D. Redwood

"Abstract - The Kori Kollo gold deposit is hosted by a c.15 Ma sericitized dacite stock in the La Joya district on the Bolivian Altiplano. The mineralization is of the Bolivian polymetallic vein (BPV) type, with a significant amount of the gold reserves contained in the oxide cap. Field and microscopic studies, K-Ar dating, ??34S values of pyrite, alunite and jarosite, and ??18O values of alunite and jarosite demonstrate that some of this gold is supergene. Two types of supergene gold are present: minute gold grains, 1 to 10 microns across, of high fineness and associated with jarosite and iron oxy-hydroxides; and ‘invisible’ gold, which is probably sorbed onto minerals such as jarosite and iron oxy-hydroxides.Pyrite ??34S values fall in the limited range -3.5 ± 0.6‰, consistent with a magmatic origin. Sulfate ??34S values are homogeneous and overlap closely with those of pyrite (-1.2 ± 2.1‰), which supports petrographic evidence that sulfates replaced pyrite. By contrast, sulfate ??18O values are inhomogeneous with a large range (alunite +2 to 26‰, jarosite -5 to +18‰). These data are interpreted as reflecting kinetically controlled reactions involving various proportions of atmospheric oxygen and local meteoric water. This is typical of supergene alteration and is due to the seasonally dry climate of the Altiplano.The oxide-zone mineralogy is dominated by sulfates and iron oxy-hydroxide minerals with some phosphates and halides, which indicates that the groundwaters were acidic, oxidizing and relatively saline. Under these conditions the most likely complexes responsible for gold mobilization are halides.Geological data and K-Ar ages indicate that oxidation of the BPV deposits began at least around 11 Ma and possibly up to 15 Ma ago, and that supergene alteration lasted until around 4 Ma. During this period, erosion was minimal. Although supergene processes have been active on the Bolivian Altiplano since the Middle Miocene, in contrast to Northern Chile, enrichment of gold has not occurred."

Jan 1, 1997

By S. Seetharaman

The present paper presents. the concept of micro-models and illustrates the application of the same in the simulations metallurgical processes. Development of micromodels requires access to accurate thermodynamic, thermophysicaland kinetic information for the relevant systems with suitable models to extrapolate the data as functions of temperature and composition. Experimental measurements and modelling of the thermodynamic properties, sulphide capacities and viscosities of oxide melts carried out in the department are presented. The incorporation of these models in process models, with special reference to ladle refining of steel is illustrated. Typical example of micro-modelling of solid-gas reactions is also presented.

Jan 1, 1999

By G Pizarro, O Miranda, D Rosales

In panel/block caving mines, large amounts of information are collected at the operations. This information includes grades and extracted tonnage, fragmentation, lithology, design of stopes and main infrastructure, geotechnical information, overbreak progress, seismicity, numerical modelling and many other mine variables. To improve the reliability of the production plan it is required to integrate the mine data into one platform. In this paper, the logic of a new technological platform is presented for analysis, modelling and design in panel/block caving mines. The platform includes an acquisition system for mine data and geotechnical information, a back-analysis module for calibrating statistical models and a module of visualisation of the results. The application and benefits of the platform is illustrated for mining induced seismic risk for panel/block caving mining operation. The platform can be used in the mine design and planning processes and is useful for reducing uncertainty in the mining business of panel/block caving operations.CITATION:Miranda, O, Rosales, D, Pizarro, G and Vallejos, J, 2016. Development of an integrated platform for the analysis, modelling and design in panel caving mines, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 237–240 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By Peter Metcalfe

"Wireless communication in the mineral processing environment is not as simple as it is in the home or office environment. The correct design of a wireless network in the mineral processing environment can offer a more flexible and lower cost installation than the transitional fiber networks. However with the flexibility of a wireless solution, also comes some limitations. By reviewing the plant requirements along with weighting the wireless benefits and limitations it is possible to design a network that combines the robustness of a wired solution with the mobility of a wireless solution. This paper addresses some wireless design considerations and it looks at some real life examples in the following areas: •,Meshed wireless network for high levels of redundancy •,Wireless instruments (such as HART, Modbus and others) •,Portable devices for mobile operators •,Network monitoring for plant personnel (it’s no longer just for IT people) INTRODUCTION Typical networks used in the mineral processing environment consist of a fiber network infrastructure with industrial switches used to connect the network devices. These fiber networks can be redundant or put into a ring topologies to offer a higher level of availability. Fiber networks have the benefits of: •,Immunity to noise from power and grounding issues •,Ability to span long distances (2km for multimode fiber and 20km for single mode fiber) •,Maintainable “off-the-shelf” technology Fiber networks however have some drawbacks, such as: •,Relativity high initial installation cost for cable trays, poles, trenches and pulling and termination of cable. •,Fixed geographic topology, adding future fiber drops may be challenging and expensive. •,Mobile users are not considered. Integrating a wireless network with a fiber network can offer the best of two worlds, a reliable high speed backbone for mission critical activities and a wireless network for remote applications and mobile users."

Jan 1, 2014

By Paulo C. Fernández A, Sergio Matamala V, Claudio C. Gajardo, Christian A. Rees P

In fragmentation processes in open-pit mining, it has been observed that there are many opportunities for improvement if greater control of ore displacement in blasting is achieved, reducing the percentage of mixing between ore and waste material (dilution) through the integration of new technologies that allow its quantification and optimization of extraction polygons. This work investigates the relevance of the initiation sequence and direction of displacement in blasting in relation to ore dilution and the potential benefits of process optimization. A three-dimensional modeling tool was used to evaluate movement control optimizing the extraction zone based on the maximization of ore recovery. The study was made by iterating different scenarios, by varying only the initiation sequence and inter-hole delays. To validate the displacement simulation, a total of 10 blasts were carried out for calibration, obtaining a level of agreement between the simulation surface and the actual topographic survey of 80% or higher. The analysis included horizontal and vertical displacement, quantification of swell and dilution within extraction polygons for different scenarios, and informed decision-making based on ore control. The results clearly indicate that by modifying the blast initiation sequence, greater control over dilution in ore/waste transition areas is achieved, thus optimizing the recovery of the planned material and maximizing the ore grade. The use of this type of simulation tools allows for the generation of extraction strategies based on the value of the polygon, unnecessary displacements in the free face, optimal loading fronts, etc., maximizing the recovery of ore and stockpile material, complying with the planned tonnage and ore grade for each extraction polygon, delivering added value to the chain and emphasizing the importance of adding new technologies to the mining industry that allow for the optimization of processes to maximize profits.

Jan 26, 2026

By W. G. Davenport

A flash furnace can be run many different ways. It can, for example, be operated with: (a) highly 02"enriched, ambient temperature blast and no fossil fuel (b) considerable fossil fuel and hot, slightly Or enriched blast. It can also produce different grades of matte. With all these possibilities, the flash furnace operator can benefit from any technique that will indicate the 'best' way to operate his furnace. One such technique is Excel's 'Solver'optimizationroutine#. This chapter shows how our matrices and Excers optimization.abllity can be used to optimize a flash furnace operation. The chapter sets three optimization goals: (a) minimum industrial oxygen + oil cost, $ per tonne of concentrate (b) maximum smelting rate, tonnes of concentrate per hour (c) maximum profit, $ per hour.

Jan 1, 2001

By Milton C. Graves, Marcos Zentilli

"Gold has been reported from most geological environments in Nova Scotia; however, virtually all production (circa 2,000, 000 troy ounces; circa 60 tonnes) has come from that part of the province to the south of the Glooscap Fault which is underlain by Lower Paleozoic rocks of the Meguma Group. Over fifty concordant sets of quartz-carbonate-arsenopyrite veins have seen production. The host rocks are greenschist-grade equivalents of Cambro-Ordovician flyschoid quartz wackes and shales folded and metamorphosed during the Devonian Acadian Orogeny. The veins were emplaced under conditions of greenschist-grade regional metamorphism and under the same conditions of tectonic stress that later resulted in the regional folds and penetrative, axial-plane slaty cleavage. Rapid filling of hydraulic fractures caused by excess metamorphic pore fluid pressure under Acadian tectonic stress conditions can account for the geometry and paragenesis of these veins.The ultimate source for gold deposits in most greenschist-grade domains remains in doubt, but these domains seem to have had ample gold within them available for mobilization. The work done, to date, on the gold geology of Nova Scotia suggests that regional greenschist metamorphism was an effective mobilizer and a potential concentrator of Au, As, W, Fe and S from these vast reservoirs.In rocks of pre-Acadian age north of the Glooscap Fault, gold occurs as an important accessory in volcanogenic massive sulphide ore, as a minor constituent in other types of basemetal concentrations and in one small concordant group of quartz veins.The post-Acadian metallogenetic domain, which overlies and overprints the two older domains, contains small amounts of gold in many mineralizing environments. Veins, with stibnite and gold, cross-cut crystalline rocks. Disseminated gold is present in basal conglomerates of post-tectonic molasse. Gold has been a by-product of Mississippi Valley-type Pb-Zn-Ba-Sr deposits in Lower Carboniferous sedimentary rocks and has been reported with Pb-Zn-Ba-F in veins which cross-cut Lower Carboniferous and older rocks. Small post-glacial placers have also seen minor production."

Jan 1, 1982

By Hongshuang Di, Tianyu Zhang, Huiqiang Huang

A CMnSiAl transformation induced plasticity (TRIP) steel was used to study the effect of retained austenite on room-temperature mechanical properties. The steel plates with retained austenite were obtained by hot rolling, cold rolling and subsequent continuous annealing. The starting and finishing temperature of hot rolling are between Ac1 and Ac3. Reduction ratio of cold rolling is 75%. The continuous annealing is carried out at different intercritical temperatures. The relationship between work hardening exponent and retained austenite was discussed. The results show that, the Ac1 and Ac3 were much high because of the alloy elements, and the temperature range between them was wide. Due to the high hot rolling temperature, the grains was hereditarily refined as a result of dynamic recrystallization. Annealing at intercritical temperature of 930 ºC, retained austenite with relatively high stability reached a maximum volume fraction of 25%, a maximum total elongation of 30.2% and a best ultimate tensile strength × total elongation of 20.1 GPa·%. Instantaneous work hardening exponent reflects strengthening mechanisms at different strain stages. The TRIP effect of retained austenite is the main mechanism during deformation. With retained austenite of sufficient amount and high stability, continuous work hardening was observed in the tensile specimen of 930 ºC.

Oct 1, 2019

The effect of change in slag composition upon metal losses to the slag and the relationship between slag composition and slag matte separation was investigated at 1400°C. The synthetic slags containing CaO, MgO, SiO2,, A1,0, and FeO were similar to those employed in the electric furnace smelting of sulphide Cu-Ni concentrates containing PGM (Precious Group Metals) from the Merensky Reef of South Africa. The matte with a grade of 9.3% Cu and 16.0% Ni was a typical electric furnace product. The results indicated that the Cu and Ni solubility in the slag increases with the increase of the basicity ratio and CaO and MgO contents of the slag. At constant CaO/MgO ratios the rise in basicity decreases the metal losses. When FeO and SiO2 contents of the slag are kept constant, the substitution of MgO with CaO decreases the metal losses. The relationship between slag composition and matte-slag separation was found to depend primarily on the basicity ratio and the FeO content of the slag. The net effect comes from a strong interaction of the two in such a way that increasing basicity and decreasing FeO contents deteriorate the clean separation of the two phases.

Jan 1, 1994

By Mark Jolly, Nasim Soleimanian

"During the last 20 years CFD (Computational Fluid Dynamics) has been used as a tool to aid furnace designers and manufacturers to improve energy efficiency and effectiveness of glass furnaces. However as the models are maturing the effect of feeding equipment used to push the raw material into the furnace has not been included in the process models. This paper investigates the effects of batch pattern in the melt space caused by charging equipment on the energy efficiency of the furnace focusing on the melting zone. A simple batch patterns sensitivity study has been performed using purpose built software (Glass Furnace Model-GFM). It is concluded that in order to further reduce the energy consumption of the furnace it is necessary to model the batch charging process in more detail to find more opportunities for improvement.Introduction Glass manufacturing is a conservative industry which applies to all the four major segments (float glass, container glass, fiberglass, and specialty glasses). Risks due to the high capital investment, very long service life of the furnaces, and the demand for high performance and quality from the outset translates into evolutionary progress rather than revolutionary. The main problem facing glass manufacturers are the financial cost of manufacture, its impact on the environment, and mounting pressure imposed by the authorities for greener manufacturing and reduction in emissions.The main energy intensive activities involved in continuous glass manufacturing are: the need for high temperature to create and maintain the viscous flow, homogenisation of glass melt (melt residence time), and maintaining the two to achieve continuous output of glass at the right quality. The high temperature and long duration of homogenisation has resulted in the design oflarge furnaces, which have high energy consumption, low specific performance, and high C02 emissions. As an example in the container glass sector the most efficient furnace has a specific primary energy consumption of 3.8 GJ /tonne of glass at a level of 50% cullet in the batch. Even very small improvements in efficiency by optimising operation would have a high impact [1-14]. Given the conservative nature of the industry and the costs involved in experimental data gathering, CFD modeling of the process has been used extensively during last two decades to not only improve our understanding of the process but also as a tool in predicting possible optimisation windows, e.g. Glass Furnace Model ( GFM), a commercially available piece of software that has been developed to optimise furnace operation."

Jan 1, 2013

By M. Stachowiak, M. Nowicki, K. Walas, A. Skoczylas, P. Stefaniak

In this paper the authors present a walking robot dedicated to the inspection of a belt conveyor’s transportation system in an underground mine. The developed robot can independently diagnose all of the key rotating elements of the belt conveyor (pulleys, bearings, drums, gears, engines) based on vibration and acoustic signals as well as typical RGB (red, green, blue) and thermal images. The article presents key diagnostic procedures applied to real industrial data obtained during robot testing.The work was developed as part of the ‘THING–subTerranean Haptic INvestiGator’ project. The authors presented the main assumptions of the research methodology developed for the needs of technical diagnostics of conveyor elements typical of inspection work performed by mining staff. Based on industrial data, the use of algorithms for elements such as rollers, drive stations, and the conveyor belt were shown. The main assumption of the research is to develop a robot adapted to the conditions of a deep mine, capable of carrying out an autonomous inspection of mining infrastructure. The conducted tests and the developed fault detection algorithms were aimed at preparing the robot for underground tests in the operating conditions of the mine.

Sep 1, 2021

By S. S. Clarke

ABOUT two years ago some of my friends were discussing the amount of drill-steel breakage that was permissible or not excessive, per month, per rock ton, per ton of steel or any unit of measure or output that would give a comparison between different kinds of drill steel. No one seemed to know what life to expect of steel, or what percentage of breakage might be termed excessive. In fact there were no operating data available to guide one in selecting the best steel for our mines, nor could any ideas or information be secured from the steel manufacturers. One was merely told that so and so used their steel and it was very satisfactory; or else one was given a highly technical lecture on their specific heat-treatment. Any estimates on expected breakage were just guesses, ranging from a fraction of a per cent to as high as ten per cent per month.

Jan 1, 1933

By H. B. Muller

Single stage autogenous grinding of run-of-mine ore was selected by Broken Hill South Ltd., parent Company of Cobar Mines Pty. Ltd. for the concentrator to treat 60,000 tons per four weekly period of copper and complex copper-lead-zinc sulphide ores from the C.S.A. Mine at Cobar, Australia. Ore is mined by mechanised horizontal cut-and-fill stoping and is prepared for grinding by crushing under- ground in a 60 in. x 48 in. jaw-crusher set at 5 in. closed side setting. The ore is reduced to 80% minus 76 microns in two parallel sections each of one 22 ft. dim. x 7 ft. long autogenous grinding mill, powered by a 1,250 H.P. motor, operating in closed circuit with a single stage 20 in. dim. cyclone. Broken Hill South's original concept of the concentrator required the maximum use of reliable instrumentation, centralised control, and the minimum of manning. To achieve this objective the control room, housing the process recorders, alarms, closed circuit television monitors and all the control equipment, overlooks the grinding and flotation sections, and the whole plant is serviced by a public address system. The grinding units and associated equipment are located in the open and are serviced with the aid of a mobile crane and a mobile hydraulically-operated liner lifting device.

Jan 1, 1970