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By S. W. White

Plasma arc technology is increasingly being used to process a number of waste materials. In present research, plasma technology is being investigated to treat waste magnesium baghouse dust, which is a waste material from the Magnetherm process. This dust contains mostly MgO, but also contains NazO, CaO, and KzO. Plasma energy is to be used along with a reducing agent to produce pure gaseous magnesium while keeping the other materials in a slag. The magnesium will then be collected by rapid quenching. A non-transferred arc plasma torch is ideal for this reaction because of its high enthalpy and improved energy efficiency over conventional methods. Another advantage of plasma is that it allows for the pre-heating or pre-reacting of fine particles before contact with the melt. Thermodynamic calculations using the Gibb energy minimization method were used to determine the most stable compositions of the materials at various temperatures. Energy balances have also been calculated. These results conclude that we can recover approximately 98% of the magnesium with a proper quenching technique. The calculated results are compared with the experimental data, and good agreement between them was observed.

Jan 1, 1999

By A. D. Hammond

Vanadium is a transition metal, ductile, silver-gray metal. It is harder than most metals and steels and it has a good resistance to corrosion, it is stable against alkalis, sulfuric and hydrochloric acids. Vanadium is oxidized in air about 660 °C, although an oxide layer forms even at room temperature. The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2-5. In aqueous solution the colors are lilac V2+, green V3+, blue VO2+ and, at high pH, yellow VO42-. Considered to be as abundant as zinc, metallic vanadium is not found in nature, but it is known to exist in about 65 different minerals. Economically significant examples include patronite (VS4), vanadinite (Pb5(VO4)3Cl), associated to the uranium mineral carnotite (K2(UO2)2(VO4)2?3H2O) and in a vanadium mica called, roscoelite K(V3+,Al,Mg)[(Si,Al)4O10](OH)2. Other important vanadium ore oxides are montroseite (V,Fe)O(OH) and corvusite (Na,Ca,K)V8O2.4H2O. Much of the world's vanadium mine production comes from magnetite-hosted deposit and to a lesser extent, in sedimentary-hosted sandstone. Vanadium is also present in bauxite and in fossil fuel deposits such as crude oil, coal, oil shale and tar sands. In crude oil, concentrations up to 1,200 ppm have been reported. A significant vanadium production comes from the processing of petroleum residues, fly ash and recycling spent catalysts. In 2011, metallurgical applications accounted for 93% of the use of vanadium. Here, an alloy called ferrovanadium is utilized to strengthen steel to be used as rebar in the construction industry, in the manufacturing of axles, crankshafts, gears and chassis in the automotive and transportation industries and in the manufacturing of high-speed tools. In the aerospace industry, vanadium is utilized as a titanium alloy in the manufacturing of airframes and jet engines. The reason for the wide use of vanadium as alloy is its high strength-to-weight ratio, the highest of any engineered material on earth. The major non-metallurgical use of vanadium is in the production of catalysts for the chemical industry. The most commercially important compound is vanadium pentoxide (V2O5), which is used as catalyst in the production of sulfuric acid.

Feb 23, 2014

By P. C. M. Knops, K. Rijnsburger, R. M. Santos

To overcome the challenges of mineral CO2 sequestration, this work utilizes a unique proprietary Gravity Pressure Vessel (GPV) reactor technology, and focuses on reaction products of high economic value. The GPV provides intense process conditions through hydrostatic pressurization and heat exchange integration that harvests exothermic reaction energy. Here, laboratory-scale tests of the envisioned process was performed in tubular and continuously stirred tank reactor (CSTR) autoclave reactors. The mineral used was Olivine (~Mg1.6Fe2+0.4(SiO4) + ppm Ni/Cr), although asbestos, steel slags and oil shale residues are also under investigation. The effect of several process parameters on reaction extent and product properties was tested: CO2 pressure, temperature, residence time, additives (buffers, lixiviants, chelators, oxidizers), solids loading, and mixing rate. The products (carbonates, amorphous silica and Chromite) were physically separated (based on size, density and magnetic properties), characterized (for chemistry, mineralogy and morphology) and tested in intended applications (e.g. as pozzolanic carbon-negative building material). Economically, it is found that product value is the main driver for mineral carbonation, rather than, or in addition to, the sequestered CO2. The approach of using a GPV and focusing on valuable reaction products could thus make CO2 mineralization a feasible and sustainable hydrometallurgical process.

Jan 1, 2015

By R. A. Allwes

In-plane bending and torsion tests were conducted on full-scale masonry walls to evaluate three post-reinforcement designs. The designs were developed to minimize longwall mine subsidence damage to existing residential masonry foundations. The bending tests show that vertical and horizontal post tensioned tendons significantly increase the resistance of a masonry wall' to in-plane bending. The torsion tests reveal that post tensioned tendons increase a masonry wall's limit of deformation but do not increase its torsional stiffness. The torsion tests also show that the masonry units minimally contribute to the torsional stiffness of a masonry wall.

Jan 1, 1995

By Ann G. Kim

The Bureau of Mines estimated the methane content of a coal, which depends primarily upon rank and pressure, from the adsorption equation V kpn, where k and n are constants related to rank. By incorporating corrections for moisture, ash, and temperature, and estimating pressure and temperature as a function of depth, the methane content of coal in place can be estimated from the following equation: [ ] Values calculated with this equation generally are in reasonable agreement with direct determinations. By assuming a standard moisture and ash content, and using the hydrostatic head to estimate pressure, a graph of rank and depth versus gas content was constructed. Although estimated values were consistently high for several high-volatile bituminous coals from an area where the pressure is known to be less than hydrostatic, the estimated methane content for most coals shows reasonable agreement with values determined by the direct method.

Jan 1, 1977

By K Jupp, T J. Howard

Cliffs Natural Resources Pty Ltd (CNR) operates iron ore mines in the Koolyanobbing region of Western Australia, about 50 km north of the town of Southern Cross. Ore is trucked from three geographically isolated sources to the crusher at Koolyanobbing, where it is blended before and during crushing. Lump and fines products are produced and railed to Esperance for ship loading and export to Asian customers. CNR is examining alternative processing paths, from mining to ship loading, with the aim of improving efficiency and reducing costs. Modifications to the system must be consistent with potential future expansions and maintain the low inter-shipment grade variability on which CNR prides itself and has built a strong relationship with its customers. In searching for the optimum process design, many options from mine face to ship loading must be evaluated and compared. Pilot plant studies are infeasible, while complex mineralogical interactions, competing goals and numerous possible system configurations limit the applicability of theoretical analysis. It was therefore concluded that simulation modeling would provide the confidence to take the next step into production trials. This paper describes techniques applied at CNR to simulate grade variability resulting from potential process design changes. The simulation models are easily run Excel-based modules, with each module representing a different part of the process. The modules use extensive Visual Basic macros driven by Excel's user-friendly interfaces. Presentation of the results is enhanced by Excel's excellent graphical capabilities. The simulation software stores and graphically presents time-stamped data from a run, enabling detailed analysis of different process configurations. Final success of a simulation run is measured by inter-shipment variability (standard deviation and process capability) and in-process ore tonnages. Meaningful results from the simulations require the initial input data contain the same correlations present in the real production environment, between the mineral components, production linkages and across time. The data also have to allow simulation of potential changes to mining method and introduction of new pits into the blend. Mining data from the real operations under study are therefore used, with average grades and variability adjusted to match potential future development proposals. It is also necessary to filter out medium and long-term variations from the production data as this variability is best controlled through the conventional medium to long-term mine planning process, not by the process design being studied. The filtering was carried out using a Fourier transform technique, which is described.

Jan 1, 2009

By Jorge A. S. Tenorio, Girley F. Rodrigues, Joner O. Alves, Denise C. R. Espinosa

"Rock wools are mineral fibers composed of amorphous silicates, due to their thermo-acoustic characteristics this material has a broad consumer market in the construction, automotive, and electric-electronics industries. This work studied the recovery of wastes from ornamental rocks (granite and marble) as partial raw materials in the production of rock wools. Residues from granite and marble cuttings are industrial wastes with considerable production and limited applications. These wastes should be appropriately managed because when discharged in rivers or lakes can cause siltation, and also they can cause serious human health problems, such as silicosis. Samples of produced materials with thickness smaller than 500µm were characterized by chemical analyses, XRD, and DTA. Results showed that the rock wools produced using granite or marble wastes have important properties, especially the melting point. This process decreases the extraction of mineral resources and provides a profitable destination for the ornamental rock wastes.IntroductionThe ornamental rocks industry is a sector with large production of wastes. During the granite and marble extraction processes and specifically during the rocks cutting (see Figure 1), approximately 35 tons of powdered rock per month can be produced. These residues should be appropriately managed, because when discharged in rivers, lakes or watersheds, they can cause siltation. Also, these wastes can cause serious human health problems, such as silicosis [1].Currently, the granite and marble wastes are mainly used in civil construction to produce materials in the form of mortar, bricks and tiles. However, due the current produced volumes and the average growth of world production estimated at 6% per year, new applications for these wastes are necessary [2]."

Jan 1, 2011

By D. J. Chaiko

Aqueous biphasic extraction (ABE) processes offer the potential for low-cost, highly selective separations. This countercurrent extraction technique involves selective partitioning of either dissolved solutes or ultrafine particulates between two immiscible aqueous phases. The extraction systems that we have studied are generated by combining an aqueous salt solution with an aqueous polymer solution. We have examined a wide range of applications for ABE, including the treatment of solid and liquid nuclear wastes, decontamination of soils, and processing of mineral ores. We have also conducted fundamental studies of solution microstructure using small angle neutron scattering (SANS): In this chapter we review the physicochemical fundamentals of aqueous biphase formation and discuss the development and scaleup of ABE processes for environmental remediation.

Jan 1, 1996

By Tyler Luxner

Stillwater Mining Co. (SMC) is the largest primary producer of platinum and palladium in North America. SMC operates two underground mines in south central Montana, along the 45-km (28-mile) platinum/palladium J-M Reef in the Stillwater Complex. The Stillwater Mine exploits 9.6 km (6 miles) of deposit strike length and East Boulder Mine exploits 4 km (2.5 miles) of deposit length. The two mines are 20.4 km (12.7 miles) apart with SMC controlling a considerable length along the entire J-M Reef trace. Production at the Stillwater Mine began in 1986 and in 1988 the first tunnel boring machine (TBM) was commissioned, becoming an integral part of mine development at SMC. TBMs have been used for developing production footwall laterals (FWL) to access new mining blocks at the Stillwater Mine, as well as boring twin crosscut ac-cess tunnels at the East Boulder. Two TBM development expansion projects are currently in progress: the Graham Creek project at the East Boulder Mine, which will extend footwall lateral development 2,591 m (8,500 ft) to the west, and the Blitz project, where a TBM will be commissioned to extend east out of the Stillwater Mine to 3,658 m (12,000 ft) beyond the current production mining front. General strike and dip of the Reef is west to east and to the north, respectively.

Jan 1, 2012

By Edward Keller

(New York meeting, February, 1912.) IN a paper, entitled A Uniform Method for the Assay of Copper Material for Gold and Silver,1 A. R. Ledoux invited the assayers of this country to contribute to a symposium, in which the results of their assays of given samples of copper-matte and metallic copper would be made comparable. This symposium 2 appeared about one year thereafter; and through it and its discussion, first became generally known the fact that the ,gold-yield by the all-fire method of assaying is usually higher than by the so-called combination (wet and dry) method, in which nitric acid is employed as a solvent for the copper. In the publication alluded to, the supposed cause of gold-losses in the latter method was declared to be the solvent action of copper nitrate, or of the reduction-products of the nitric acid, upon the gold. Up to a very recent date, gold has been held to be insoluble in pure nitric acid. (The solvent action of any chlorine present in the nitric acid must here properly be disregarded as belonging in the realm of carelessness. Among later allusions to this topic, W. R. Tan Liew 3 ascribes the solution of the gold in the combination-assay entirely to the action of nitrous acid at the high reaction-temperature of copper and nitric acid ; F. B. Flinn 4 a believes the low result in gold to be due exclusively to mechanical losses-finely-divided gold penetrating through the filter-paper-but presents no experimental data confirmative of this belief; and 0. Pufahl 5 attributes the solubility of the gold in some coppers to the presence of selenium-a view which appears to be shared by many as- 1 Trans., xxiv., 575 (1894). 2 Trans., xxv., 250 (1895). 3 Engineering and Mining Journal, vol. lxix., No. 16, p. 469 (Apr. 21, 1900). 4 Engineering and Mining Journal, vol. lxxxvii., No.11, p. 569 (Mar. 13, 1909). 5 Lunge, Chemische Technische Untersuchungs Methoden, vol. ii., p. 229 (1900).

Jul 1, 1912

Reliably detect fires by sensing sub-micrometer-sized particles released into the air by smoldering or burning materials. Approach An extremely sensitive, ionization-type fire detector has been built that continuously draws air samples through its ionizing field and collects the ionized smoke particles downstream, thereby generating a proportional electrical output signal. (An offshoot instrument measures the size distribution and number of sub-micrometer particles in air.) How It Works Mine air to be monitored is drawn through the instrument assembly by a small pump. A pre-filter and cyclone remove dust particles and other particles larger than 0.6 micrometer diameter. The air and remaining aerosol-sized particles flow through a gastight tube which contains the detector. See diagram. Smoke and other sub-micrometer-size particles moving Into the detector, pass through an Ionizing field, and are struck by alpha particles released from radioactive source located on the axis of the tube, The alpha particles move radially outward until they strike smoke particles or molecules of air or water. When struck, a smoke particle or molecule loses an electron and becomes positively ionized.

Jan 1, 1979

By Tony Szwilski

Using Unity 3D as a collaborative multi-user virtual on-line environment, an interactive virtual underground mine platform (IVUMP) is being developed to provide on-line access to mine safety preparedness training with a focus on mine emergency response exercises (MEREs). Communication and information flow among MERE participants and their actions can be monitored, recorded and evaluated. A mine ventilation simulation utility VFIRE is being incorporated to enhance the realism and interactive nature of the ?in-world? exercises as well as extend its functionality to include training in real-time ventilation and fire control.

Aug 1, 2013

By Jerome J. Hoeppner, Walter W. Fowkes

The Federal Bureau of Mines has determined the distribution of forms of sulfur for several lignites and gasification chars and noted the changes induced by the gasification process . A method was adopted for quantitatively determining sulfide sulfur that was found to be present in the chars , although absent in the lignites . Changes in the behavior and distribution of sulfur forms were further investigated concerning the ashing of lignites and chars under standard conditions , as well as at various temperatures , and the determination of volatile matter applied to both chars and lignites . The authors concluded that the first and greatest change in the form of sulfur present in natural lignite , upon heat treatment , resulted from the reduction of pyritic and sulfate sulfur to sulfide . Organically - bound sulfur originally present is less reactive , but largely disappears on strong ignition . An appreciable part of the sulfur content of natural lignite is fixed in the char as sulfide and in the ash as water - soluble sulfate and will affect the summation of constituents , to a greater or lesser degree , in reporting the ultimate analysis of a lignite or char .

Jul 1, 1960

By Mauritz Kotze, Jason Furtney, Ewan Sellers, Sandy Etchells, Tom Szendrei

The development of a simple model for gas flow and burden movement has driven the need to improve our understanding of burden breakage mechanisms for single hole blasts and the interaction between multiple holes in solid and jointed rock masses. Conventional analytical understandings of the burden breakout using the elastic-tensile fracture model were studied and found to provide a breakout angle that is independent of burden in contradiction to experimental data. By considering rock fracture in terms of Mohr-Coulomb plasticity using analytical expressions from the field of cavity expansion analysis an improved relationship between breakout angle and burden is derived until the point of critical breakout at which the angle of breakout suddenly changes from between 90 degree and 100 degrees to zero. This suggests that the critical burden occurs at about 0.6 times the radial fracture zone calculated from the analytical solutions.

Jan 1, 2013

By Donald P. Tuchman, Robert P. Vinson, Jon C. Volkwein

Research by the National Institute for Occupational Safety and Health (NIOSH) has pursued quartz analysis for the specialized ?lter assemblies of a new worker-wearable personal dust monitor (PDM). The PDM is a real-time instrument utilizing a tapered element oscillating microbalance (TEOM®). Standard ?berglass TEOM ?lters cannot accommodate the desired P-7 infrared analytical method used by the Mine Safety and Health Administration (MSHA). Novel ?lter materials were tested with the objective of demonstrating this type of analysis. Low temperature ashing and spectrometric examination were employed, revealing that nylon ?ber candidate ?lters left minimal residual ash and produced no signi?cant spectral interference. Avoiding titanium dioxide in all ?lter materials proved to be a key requirement. Fine quartz particulates were collected on prototype ?lters in a Marple chamber, either open-faced or through PDMs during test runs. The ?lters were then subjected to MSHA P-7 analysis and the spectrometrically based analytical results for quartz mass were compared to reference measurements. Also, PDM instrumental mass readings were compared to ?lter gravimetric measurements. Results suggest that the P-7 method is adaptable to variations in ?lter materials and that quartz dust analysis by the P-7 method when utilizing the new ashable PDM ?lters can have accuracy and precision within 10% and 4%, respectively. This is within the declared 13% accuracy and 7–10% precision of the P-7 method itself. Instrument mass readings had modest positive bias but met NIOSH accuracy criteria. Continued work with specialized PDM ?lters is merited, as they are a new type of TEOM sample amenable to ashing analysis of particulates.

By ManhKha Trinh, Neal Pyke

Dofasco was the first company to adopt oxygen steelmaking in North America in 1954, two years after the first LD vessel installed and operated successfully in Linz, Austria. Since then, Dofasco has investigated and implemented several strategies to maximize hot metal usage and minimize overall cost. Some key strategies -low hot metal silicon, combined blowing conversion, vacuum degassing tank upgrade and BOF slag carryover control - are discussed. Post combustion, scrap preheat, carbon injection trials along with current operating philosophies are described.

Jan 1, 2004

Despite the current economic downturn that is now decimating iron ore production, Minnesota?s mining operators remain optimistic about the long-term prospects for the industry. Reflecting this optimism, the development of several new mining projects continues in the state. The future of mining in Minnesota was the featured topic at the combined 82nd Annual Minnesota Section of SME Meeting and 70th Annual University of Minnesota Mining Symposium. More than 500 mining industry professionals, including engineers, executives, mining managers and equipment suppliers from the around the world, attended the meeting, which was held April 14 and 15, 2009, in Duluth, MN. The combined meeting featured a keynote session with three distinguished speakers plus a panel discussion by representatives from several of Minnesota?s taconite producers. The keynote speakers were Curtis Clark, president and chief operating officer, Behr Dolbear, who gave a presentation on the ?State of the Mining Industry.? Phil Newman, chief operating officer, CRU Strategies, spoke about challenges facing the mining industry and James A. Skurla, acting director, Bureau of Business and Economic Research, Labovitz School of Business and Economics, University of Minnesota Duluth, discussed the importance of mining to northeastern Minnesota?s economy. The taconite producers panel discussion included Jonathan Holmes, vice president and operations manager, ArcelorMittal; Ed Latendresse, vice president and general manger, Hibbing Taconite; John Tuomi, vice president operations services, United Taconite and Mike Mliner, vice president and general manager, Northshore Mining. The mangers provided updates on their respective operation The meeting included concurrent technical papers sessions on mining, processing, environmental and nonferrous mining. The sessions included technical papers that provided information on the status of a number of new mining projects in the state. The conference also offered a SME short course titled ?The basics of iron mining.? A tradeshow that featured about 100 companies and organizations offering products and services to Minnesota?s mining industry ran in conjunction to the conference. It was estimated that more than 900 people, including conference registrants and special invited guests of the vendors, attended the tradeshow opening reception. This was the largest trade show in many years. The Minnesota Section of SME also held its annual business meeting during the conference.

Jan 1, 2009

By Waddah Akili

The demand on pile installation in the offshore of the Arabian Gulf has, over the last two decades, experienced unprecedented boom, triggered by the construction of platforms, to help facilitate the production and transport of oil and gas. Available borehole data show that ground conditions for pile installation in the offshore is highly variable, resulting in misassessment of insitu conditions, leading to a huge discrepancy between ultimate pile capacities, based on design, and actual capacities after installation. The paper makes use of pile installation records derived from several platforms in the offshore of the state of Qatar, the Gulf Region. More specifically, the paper evaluates “as–installed” ultimate capacities and safety factors, recommends remedial installation procedures, and proposes a means for determining pile acceptability for piles meeting refusal short of design penetration. The paper offers what is believed to be relevant recommendations to guide the design and installation of future offshore structures; enabling the geotechnical community in the Region to solve their current offshore pile installation problems and gain an added margin of confidence regarding the ultimate capacity of installed piles.

The writers of these notes, having conducted some tests on the steam consumption of air compressors under varying conditions, believe that the detailed results of such tests will be of interest to the members of the Institute, and may lead to the contribution of further and more valuable information, of benefit both to manufacturers and users of this class of machinery-to the manufacturer in that he frequently has the opportunity of giving a very thorough test to the machine in the shop, and-tothe user or purchaser by making clear to him what may be reasonably demanded of a high-class machine. It must be remembered that, though of the highest importance, a low steam consumption is but one of the many features of a high-classmachine; for the present, however, it has been considered advisable to confine the paper chiefly to the first-mentioned aspect, with such information concerning the air ends as is obtained along with the steam consumption tests. Unfortunately, too few of these tests are conducted, and but few results are published, therefore the writers feel that no apology is needed in bringing their results before the members.Some nine months ago the Brilliant Extended G. M. Co. was supplied with a compressor by Messrs. Thompson and Co., of Castlemaine, and with the object of testing its actual performance.

Jan 1, 1907

By Wenxian Zhu, Xuema Li, Patrick R. Taylor

"Experiments were performed in a non-transferred arc, thermal plasma flow reactor to investigate the synthesis of ultra fine boron nitride (BN) powder from the reaction system of boron oxide (Bz03), methane (CH4), ammonia (NH3) and hydrogen (H2). Argon (Ar) and nitrogen (N2) were used as plasma gases. The thermodynamics and kinetics of the synthesis reactions were examined and a chemical reaction mechanism was proposed. The powders produced under certain operating conditions had high purity and good conversions. All the products were extremely fine powders (< 30nm) and were uniform in size distribution. The powder products were analyzed by chemical and physical characterization. The effects of the reaction variables on the conversions from B203 to BN and the purity of the products were investigated.IntroductionIn the past few decades, boron nitride (BN) has attracted a great deal of interest because of its excellent thermal, chemical and electrical properties (1-4) It has a high thermal stability and thermal conductivity. Chemically, it is very stable and is not wetted by most molten metals and slag. It is also an excellent low loss insulator. Since hexagonal boron nitride (h-BN) is light in weight, strong and easily fabricated, it has applications in a variety of specialized high temperature areas, such as a high temperature lubricant, crucibles for molten metals, thermocouple protection tubes, break rings for horizontal continuous casting of steel, and friction reducing coatings. In cubic form, boron nitride is one of the hardest materials known, second only to diamond, and it is an excellent material for tools in which the use of carbon based materials is limited by oxidation or reaction with metals."

Jan 1, 1998