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By R. F. Hammen

Heavy metal contamination of water is a problem of immense national and international proportions. However, effective cleanup is complicated both by the toxicity and the low concentrations of metals in wastewater streams. Using high performance chelation chromatography, the solid phase extraction and purification of extremely dilute metals from water was highly effective. The process is based on selective displacement of metals from a chromatographic column containing a chelating resin. The resin is characterized by extremely efficient adsorption kinetics which allow rapid and complete removal of the metals.

Jan 1, 1993

By John M. Gordon

DURING and after 1949, various groups of British mining engineers came to the Dominion Coal Company, Limited, at Sydney, N .S., to see at first hand the Dosco MINER ( 1). These visits culminated in 1952 with the ordering of four Dosco Miners by the (British) National Coal Board on an experimental basis through their Experimental Expenditure Funds. Others are now on order. The first machine was delivered in February, 1953, and, after slight alterations to suit the different power supply, the machine was made ready to work. Due mainly to the size of the machine, new rules and regulations governing its operation had to be put into effect and it was not until April, 1954, that the machine was put underground. It started to produce in June of that year. The three others were delivered early in 1955. The authors were sent to England by the Dominion Coal Company to install and demonstrate these machines and to work with the Coal Board engineers to- further interest in the machines in the British coal fields .

Jan 1, 1956

By Olgac Kangal, Ali Guney, Gulay Bulut, Guven Onal, Ayhan A. Sirkeci

This paper presents the results of pilot scale column flotation applications in the two different copper concentrators in Turkey. The Kure Copper Plant is located in the Black Sea Region of Turkey. In Kure, a very fine grinding requirement for an adequate level of liberation makes a successful flotation difficult and consequently the final concentrate can hardly assay above 16% Cu Column flotation tests were conducted at the plant site using two different column types The experiments proved that the grade of the concentrate could be increased from about 14% Cu to 25-26% Cu. Murgul Cakmakkaya Copper Concentrator is the largest copper concentrator in Turkey. Although concentrate production capacity is around 170,000 tons annually with 22-23% Cu content, this figure tends to be much lower than that. In Murgul a Turbo Column of Multotec Company of South Africa was employed. As a result of systematic column flotation tests, the grade of the concentrate was increased from 20.3% Cu to 28.7% Cu.

Jan 1, 2003

By T Perera, B Fan, S Thang, T Hsia

Minerals are valuable resources and critical elements for a broad range of biological and technological applications, including technological developments to improve energy efficiency and the global movement to promote a low-carbon economy. However, in order to extract these critical metals, large amounts of waste and toxic chemicals are generated, as well as the use of high energy and large amounts of water consumption. Froth flotation is one of the most commonly used processes to separate and collect high-value minerals, but it still has some limitations, including low flotation efficiency performances using existing collectors and other reagents. Therefore, there is an urgent need to design and develop new metal-specific collectors to more efficiently separate and recover valuable minerals and to allow bulk water recovery from flocculated tailings. In this research, we propose to use our newly designed and synthesised novel collectors derived from a type of vitamin E (α-tocopherol), a relatively inexpensive and non-toxic natural molecule. As a potential collector-building block, α-tocopherol has a long hydrophobic carbon chain that facilitates the attachment to air bubbles during the froth flotation process. In addition, the phenol group of this molecule can be easily modified to incorporate various functional groups for targeting different types of minerals. Furthermore, α-tocopherol can be converted into a monomer for polymerisation by the reversible addition-fragmentation chain-transfer (RAFT) process, which can provide us with polymer based-collectors with high precision control of molecular weight and architecture. So far, small-scale qualitative experiments on α-tocopherol-based collectors have been performed with good results, which indicates the feasibility of these compounds as novel collectors for improved froth flotation processes.

Aug 24, 2022

By Giancarlo Alfonso Lovón Canchumani

A indústria da mineração do ferro brasileira ocupa posição relevante no cenário mundial, exportando para os principais mercados consumidores os produtos beneficiados. Esta indústria de beneficiamento tem consumo elevado de recursos e de energia, o que consequentemente gera grandes quantidades de emissões gasosas, líquidas e sólidas, contaminantes do meio ambiente. Nesse contexto o presente artigo tem por objetivo avaliar o ciclo de vida da produção de pelotas de minério de ferro, através da identificação dos impactos ambientais gerados nas etapas de lavra, beneficiamento, transporte e pelotização, com o intuito de dar subsídios a medidas mitigadoras. Foi realizado um estudo de caso em uma empresa de produção de pelotas de minério de ferro e utilizando a metodologia de Avaliação do Ciclo de Vida, baseado na norma ISO 14040. De acordo com os resultados obtidos os impactos ambientais mais importantes em relação ao ciclo de vida da produção de pelota, são referentes à categoria de depleção dos recursos minerais com 64,4% do total ponderado e a emissão de particulados no processo de lavra, que monta a 28,6% do mesmo total. Enquanto a fase com maior contribuição para o impacto total para a produção da pelota é a de beneficiamento.

Aug 16, 2017

By Pier Francesco Paglini, Gian Luca Menchini, Pier Francesco Boschi

"PROJECTThe “Caltanissetta” Tunnel is part of the ANAS S.p.A (National Autonomous Roads Corporation) $ 1.3 Billion Highway 640 Caltanissetta-Agrigento (Sicily, Italy) Rehabilitation Project, consisting in upgrading of 62 km (40 miles) of highway. The Italian multinational construction company Cooperativa Muratori & Cementisti di Ravenna, is the General Contractor for the design and build contract. The highway S.S. 640 starts from Porto Empedocle, to the intersection with the Motorway A 19 Catania-Palermo.The entire project, double carriageway designed for speed 70-120 km/h and maximum longitudinal slope of 4.2%, is divided into two sections. First Section: just finished and opened to traffic. Second Section: mainly involving the province of Caltanissetta, length about 28 km (18 miles), works started in 2013. This second section includes the most challenging work of all the project, the “Caltanissetta” tunnel consisting of two separate tubes, each with 3.9 km length and inside diameter of 13.50 m, in order to host 2 traffic lines and an emergency line. HORIZONTAL AND VERTICAL ALIGNMENT - GEOLOGY AND HYDROGEOLOGYThe plan alignment of “Caltanissetta” tunnel is formed by two tubes which are located at a minimum mutual distance of 22 m to a maximum of 63 m, with n. 9 pedestrian and n. 4 road cross passages; ventilation shafts are not provided. Overburden over portals area is about 5 m till a maximum of 120 m. Tunnel sections have variable longitudinal slope from 2.6% to 0.5%, transversal slope of about 3.5%. Right tube length is 3,992 m, left tube length is 3,877 m."

Jan 1, 2016

By Peter Ay, Bodo Müller, Jens Markowski, Manfred Kanthak, Florian Logsch

"Presently the global commodity situation for non ferrous-, precious- and rare metals is characterized by a strong increase in consumption and a simultaneous shortage of materials derived from primary sources. So the use of secondary raw materials gains is important due to economic and ecological reasons. Non Ferrous-, precious- and rare earth metals were detected in household waste (Municipal solid waste, MSW) for years. In MSW-treatments plants NF-metals are actually mostly separated from dried fractions. The separation of these metals is carried out with the aim of removing particles which disrupt further processing. A selective enrichment of individual non-ferrous metals has not been carried out previously. The separated fractions contain mixtures of Al, Cu, Zn, Pb, Sn, alloys, precious metals (e. g. Au, Ag, Pt) and rare metals (Ga, In, Nd etc.) along with considerable amounts of contaminations. The R&D project "NE-Rec" selectively processes the coarsely separated non-ferrous-metal-conglomerates increasing the concentration of targeted metals. Metals and metal mixtures are concentrated by sorting steps and the impurities are discharged from the process. Still contaminated precious metals are then subjected to a wet-chemical treatment. So metals can be specifically brought into solution or can be precipitated to separate unwanted components (inerts, polymers, foreign metals). Further the relevant metals will be concentrated by thermal-metallurgical processes. The technology, developed in the R&D project, enables identification, separation and processing of non-ferrous metals, precious metals and REM in household waste and transfers them into further processable individual fractions."

Jan 1, 2014

By J. J. C. Heynike

The relationship between population growth and steel consumption since the beginning of the twentieth century is indicated, reference being made to the increasing capacity of production units and the resultant increased pollution in the same area. The need for the control of fugitive emissions with its associated high cost is pointed out. There is a direct relationship between energy and pollution, and examples are given of several improvements that have been made to achieve better energy usage and reduced pollution. Several practical examples of air-pollution control systems are described as applicable to the main metallurgical steel processes of today. In conclusion, reference is made to the fact that, with the improvements attained in reducing pollution, the public will not tolerate a decline in the standards already attained. Environmental control and better energy utilization will continue to be important aspects of steel-plant design and operation.

Jan 1, 1978

By R. Cook

Knowledge based applications are becoming important to Associated Manganese for efficiently dispatching ore of appropriate grades to customers on time. The G2 expert system shell has been used to develop blending and scheduling applications using a combination of object-oriented rule based, procedural, and heuristic approaches. The blending application, for example uses a heuristic approach for creating blends from thousands of small stacks of manganese ore of various grades and sizes, to meet customer specifications while fully exploiting the available inventory. Data capture and data warehousing have become important issues, and the Internet shows strong potential for distribution of pre-processed information.

Jan 1, 1997

By H. E. Wilde

"Zinc has been used for many years as a galvanic coating for the protection of steel. Electrochemical measurements show that zinc actually overprotects steel. The corrosion rate of DQSK (drawing quality semi-killed) steel in air saturated salt water was determined as a Junction of applied cathodic potential. The resulting data indicate that at a critical cathodic over potential of - O. 725 Vsce an acceptably low corrosion rate of less than 1 mpy occurs. Using the developed criterion, alloys of Zn/X and AL/X were produced and evaluated in galvanic contact with steel in a standard laboratory test. The results indicate that Zn /Mn, Zn /Co, AI/Mg/Si and AI/Mg/Ge alloys offer excellent galvanic protection along with (a) no hydrogen evolution, and (b) improved dissolution life over Zn coatings.IntroductionZinc coated (galvanized) steel has been successfully used in applications where bare (or painted non-galvanized) steel would suffer corrosive attack. In general, galvanic coupling to zinc, as either an anode or a coating, is an effective means for combatting steel corrosion. Because of this, the use of galvanized steel has increased markedly, stimulated primarily by automobile manufacurers seeking to extend the corrosion warranties on automobiles(1).Although effective, zinc coatings are not without a number of drawbacks which warrant efforts to improve them. For example, because of the widely differing electrode potentials between zinc and steel ( - 1.05 Vsce and - 0.60 Vscc, respectively, in air saturated NaCl solutions), the zinc corrodes at a rapid rate to protect the steel. This is reflected in the limited lifetimes of galvanized unpainted siding. The basic electrochemistry controlling the situation is shown in Figure 1, for a system controlled by oxygen reduction. The zinc corrodes sacrificially to protect the steel, while cathodically polarizing the steel to a potential near that of zinc's open circuit anode potential."

Jan 1, 1990

By Lee W. Saperstein

In surface mining for coal, common practice for the disposal of preparation plant refuse is to bury it. As with surface refuse piles, these buried wastes can ignite and can also lead to ground and surface water pollution. Steps to ameliorate these problems have been devised over the years. C and K Coal Company, of Clarion, Pa., the largest Pennsylvania surface mining company, has incorporated all of these steps and added of few, of their own in their latest disposal practice. In addition to layering and compacting, C and K practices selective placement and dilution to minimize longterm problems.

Jan 1, 1977

By Zhi-biao Yin

Copper smelter flue dusts often cannot be directly recycled to the smelting process and accumulate as hazardous wastes requiring environmentally acceptable disposal. Because of the limited amount of flue dust, a separate copper extraction process must be simple and require-a small plant investment. A flue dust process has been developed, consisting of the following steps: (1) roasting a pelletized mixture of hydrated lime and flue dust to fix arsenic and sulfur as insoluble calcium salts, (2) heap leaching the roasted pellets with a buffered ammonia/ammonium salt solution to extract copper as an ammine complex in a lined cell that is the final repository of the leached pellets, and (3) boiling ammonia from the lixiviant to precipitate copper. Condensed ammonia and the filtered solution are returned to leaching. Heap leaching in the final repository cell lowers the capital investment significantly compared with competing extraction processes. Chemistry with respect to arsenic, sulfur and copper is discussed.

Jan 1, 1992

By Susan M. White

Increased coal production, wider use of indiscriminate mining techniques, improved cleaning methods, and greater emphasis on clean fuels is increasing the rate at which wastes accumulate Over the next several years, Colorado Plateau underground coal production is predicted to increase. Currently, mine refuse is deposited in canyons or lowland areas near mines. This study presents information on the nature of coal refuse and disposal practices on the Colorado Plateau. Samples were collected and analyzed to provide information to help formulate alternative methods for reclaiming refuse piles. The analyses were based on determining the capability of unmodified refuse to provide a suitable medium for plant growth. Local topsoils which would be used in reclamation were used as standards. Potential environmental hazards were assessed also. A general cost analysis was done for both surface and underground disposal and the advantages and disadvantages of each were assessed. Several problems were identified which, if solved, would increase the effectiveness of state regulatory programs.

Jan 1, 1982

By Roland Hoet

Mine operators, conveyor system designers, consultants, and manufacturers have had opportunities over the past decade to utilize various actively controlled technologies to drive complex underground conveyor systems. These technologies included several electrical drive solutions, mechanical drive solutions, and hydromechanical (fluid coupling) drive solutions. All of these technologies have their inherent advantages and disadvantages, and only after several years of operation can mine operators fairly evaluate the overall benefits (short term performance and cost vs. longer term operational and maintenance costs) of any particular drive. Far too often in today's world, decisions for new equipment are made with inadequate regard to issues concerning serviceability and maintainability. Many of the newer electrical technologies (primarily AC variable speed drives) which have been used in recent years were selected based on the perceived desirable benefit from variable speed operation. This technology, however, which differs sign8cantly between various manufacturers, is in a constant state of evolution which puts into question the manufacturers' ability for long-term product support. In addition, various forms of this technology have also generated some undesirable operational issues, including reduced motor life, harmonics for the power system, and mine communications problems. This technology is also extremely current-limited, which results in problems handling overload conditions, a frequent occurrence often resulting from a decline in the coal recovery rate (conveying more rock than coal). The fluid coupling, however, is based on a technology which has been used successfully in underground conveyor applications for decades. Although the base hydrodynamic technology is well proven and has inherently beneficial characteristics on conveyor applications, Voith has continuously improved on this technology to meet the increasing demands of today's challenging conveyor haulage systems. Recognizing a need in the market for a reliable, actively controlled drive system, Voith Turbo began development in 1996 of a new, actively controlled coupling which was targeted specifically for the higher powered, complex underground conveyors. Voith introduced the new TPKL Fill Controlled coupling product to the market in 1997, and the first two applications for this new technology were on multiple drive mpper booster applications on longwall panel conveyors. Since the successful startup of these two conveyor systems in 1998, Voith has supplied over 200 TPKL couplings to the mining industry worldwide, with over 150 in US coal mining applications alone. This paper will provide an overview of the TPKL's capabilities, performance, and reliability based on the TPKL's impressive installation base and operational history.

Jan 1, 2004

By R. J. Bridwell

Acid mine drainage (AMD) occurs in high sulfur coal and heavy metal mining environments. We show remediation methods using 3D numerical ground water flow models and chemical kinetics of pyrite oxidation for acid leaching of pyrite during air and ground water flow. A recently developed numerical model couples air and water flow with kinetics of iron-reactive bacteria, oxygen transport, specific chemical reaction rates, and pyrite oxidation to calculate migration control of pollution. A model is presented which considers diminution of acid mine drainage in pyrite rich ore bodies by raising the potentiometric surface through a vadose zone to reduce acid mine drainage. A ground water model is presented of an initially saturated mountain, containing an adit, with a sloping ground water table. Ground water recharge consists of snowfall and normal precipitation. Simulations indicate that the historically open adit creates a desaturated mountain above the adit. Significant air saturation ranging from 10-90% oxygen can occur to depths of the adit (-270 m). Remediation consists of plugging the adit, which fill s adit and mountain with water from recharge. Plugging the adit required <10 years for resaturation and rise of the water table in the mountain.

Jan 1, 1994

By J. E. Wey

Extraction of cobalt from cobalt sulfide and cobaltite flotation concentrate from the Blackbird Mine, Idaho, was investigated using an adapted strain of Thiobacillus ferrooxidans. Cobalt extractions as high as 100% were realized in the inoculated experiments, whereas only 4% extraction was obtained in the sterile run. The influence of pulp density on the rate and extent of cobalt extraction was also determined. It was found that the extraction of cobalt followed predominantly the indirect mode of bacterial activity. In this process, ferric iron oxidizes cobaltite to cobalt sulfate and ferric arsenate while being reduced to its ferrous state; the bacteria continuously re-oxidize ferrous to ferric iron. Electrochemical measurements using cyclic voltammetry suggested that cobaltite oxidation involved a number of intermediate reactions.

Jan 1, 1993

By Nar S. Dalal, Xianglin Shi, Val Vallyathan

"INTRODOCTIONIn an earlier communication 1 from our laboratory it was reported that mechanical crushing of coal and quartz under normal air atmosphere generates of free radicals on the particle surfaces, and that these radicals decay with time, hence pointing to a higher toxicity of fresh dusts in relationship to pneumoconiosis and silicosis. More recently Fubini et al.2 have also reported the detection by electron spin resonance (ESR) of the formation of SiO. and Si-type of radicals from quartz particles crushed under atmospheric conditions. In agreement with earlier ESR studies on single crystals of quartz crushed under high vacuum ( -10-10 torr>3 and subsequent exposure to air,3 and to other gases,4 these radicals were identified2 as being formed by the homolytic cleavage of the Si-0-Si bonds and the reactions of the Si• and SiO- radical with atmosphere. Fubini et al.2 also suggested that these radicals might be involved in the mechanism of the fibrotic action by silica, either by transforming the particle surface into a selective oxidating agent or as an initiator of a sequence of reactions leading to fibrosis. Earlier Gabor and Anca5 bad reported that lipid ·peroxidation caused by free radicals on the silica surface might be involved in the red blood cell membrane damage. Thus far, however, no parallel cytotoxicity, fibrogenicity, and free radica1 studies on a given quartz dust sample have been reported, except for some earlier work from our laboratory.1·6·7 We now present more recent results obtained from parallel cytotoxicity, fibrogenicity, and free radica1 measurements on a freshly made quartz dust. The dust's free radica1 content was measured using ESR spectroscopy while its cytotoxicity potential was estimated via hemolysis. Hemolysis was employed as the toxicity test because it is a widely used method for estimating the potential of a dust for disrupting the cell membrane. 8 The fibrotic potential was followed by measuring the dust-induced lipid peroxidation, using linoleic acid as a model lipid. As discussed below, the results obtained suggest new clues to the mechanism of the quartzrelated cytotoxicity and fibrogenicity. MATERIALS AND METHODSReagentsCrystalline quartz particles with a size range of 0.2-2.5 mm were obtained from the Generic Respirable Dust Technology Center, Pennsylvania State University, University Park, Pennsylvania. These particles were crushed in air to obtain quartz dust samples with particle sizes smaller than 20 microns. We chose to work with a dust with mixed particle sizes, rather than a specific range, as an effort to simulate the mining atmosphere. An agate mortar-pestle arrangement was used for the crushing and grinding because of the close similarity of the structure of agate to that of quartz. Diethylenetriaminepentaacetic acid (DETAPAC) were purchased from Sigma. All other chemica1s were purchased from Fisher or Aldrich.Hemolysls ExperimentsHemolytic activity of silica was measured, following an established procedure,9 as the amount of hemoglobin released from a 2 % suspension of sheep erythrocytes after incubation with 10 mg of silica dust for one hour at 37 °C. The hemoglobin release was estimated via the absorbance at 540 nm using a Gioford spectrophotometer. The procedure was calibrated by substituting the silica dust by a phosphate buffer solution as a negative control (background) and O.S % Triton-X-100 as a positive control (100% hemolysis). The percentage of hemolysis was calculated as follows:"

Jan 1, 1990

By Russell E. Griffen

With the development of larger mine-haulage trucks in recent years, the visual field of the driver has diminished correspondingly. Specifically, the operator&apos;s lack of direct vision in the right front area and directly to the rear constitutes a serious hazard to personnel in nearby small utility vehicles. Recently developed electronic technology has made it possible to supplement the use of mirrors and fresnel lenses to warn the operator of specific collision dangers in the truck&apos;s blind areas. This Bureau of Mines report describes the results of a coordinated contract and in-house research program to develop and test in-mine prototype electronic systems to detect the presence of smaller vehicles within the blind areas of large mine-haulage trucks. Each system utilized transmitters installed on the smaller vehicles and receivers installed on the haulage trucks. Transmitting techniques tested included both low-and high-frequency radio waves. On-vehicle testing established the engineering feasibility of each approach. Further private sector product development to improve reliability and reduce system costs is recommended. Mining companies should consider the advantages of each type of system.

Jan 1, 1988

By DING TANG, JINGHE CHEN, Shuiping Zhong, CHEN KUANG

The Zijinshan gold-copper mine, in spite of the low-grade nature of the ore, has become one of the largest production-scale and most profitable non-ferrous metal mines in China. The successful application of hydrometallurgy as well as proper engineering design are the key factors for large-scale development of the Zijinshan gold-copper mine. In this contribution, the practical experience acquired in the development of the Zijinshan gold and copper mines is summarized. This covers most aspects of the production process including mining, beneficiation, ore stacking, heap (bio)leaching, carbon-in-leach, solvent extraction, electrowinning, wastewater and tailing treatments. The authors believe that this practical experience will not only help to promote the development of hydrometallurgy, but can also serve as a model for other gold and/or copper plants around the world.

Jun 3, 2020

By P Cameron

MetPlant conferences have focused on ensuring mining projects are well designed then optimised to operate safely and effectively at the top end of world’s best practice to ensure shareholders are not just happy but delighted. This assumes the MetPlant was built right the first time. However, reality is, too often Plant Metallurgists (PlantMets) find after commissioning they are faced with the expensive task of correcting errors or modifying shortcomings to achieve product quality at name-plate capacity, i.e. get it right the second time. Why do companies spend good money to engineer an excellent feasibility study then allow “wise men” remote from the project team to impose cuts in budget and schedule, often under the guise of value engineering? Since mining is full of uncertainties, such actions can increase the risks of failure with the result that some MetPlants do not work well. Can PlantMets influence the remote wise men who often are also imposing the rules for lending and the required returns to appreciate the uncertainties of mining and their associated risks then let the project team get it right the first time? PlantMets can negotiate with the wise men from the outset of the project and bring them into an outer layer of the team where they can understand the risks then share responsibility and accountability to achieve the common goal of building a MetPlant which works well the first time and deliver the forecast profits. Since shareholders are not in the business to make losses they appoint a Board of Directors to deliver the best outcomes for the shareholders. Thus the Board should seek effective advice on the risk reward implications from the PlantMet before making their decisions.CITATION:Cameron, P, 2015. Do all metplants work well? PlantMets can ensure they do, in Proceedings MetPlant 2015, pp 2–9 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 7, 2015