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By Yoshihiko Maeda

"Although Japanese mining industry once had been a polluter of toxic heavy metals and gasses, it has been struggling for improvement of environment at mining and smelting facilities under the strict Japanese regulations. Through these efforts, the industry has developed various environmental technologies to be applied in other industries and society.Recycling of metal scraps, for example, has been conducted at smelting facilities. Treatment of hazardous waste, cleanup of contaminated soil and management of landfill are other examples of application of mining and smelting technologies and facilities. In accordance with the worldwide environmental concerns, the industry has become one of the leading industries to promote ""Sustainable Development"", and it is expected further contribution in reducing various environmental burdens to earth by utilizing its mining and smelting technologies and facilities. Some of the examples of these applications are presented in this paper.IntroductionDowa Mining Co., Ltd., established in 1984, is known as one of the ~op Japanese producer of nonferrous metals. Base on its special expertise in the mining and smelting of complex ores, it has expanded its business areas to downstream activities ranging from highly purified metals and alloys, electronics materials, chemicals and related various businesses. Dowa Mining now is becoming more active in the field of waste treatment and recycling.Dowa Mining had operated some mines until 1980th, located at the western part and northern part of Honshuu Island in Japan; the former is pyrite mine while the later is ""Black Ore"" mine,· a complex sulfide ore composed of high grade of copper,· silver, lead and zinc. However, due to the strong yen began in1985; Dowa Mining closed its mining operation in 1994, and has sifted to mining operations in Mexico."

Jan 1, 2000

By J. C. Scully

In June, 1965, Sanderson and scully5 reported at the Conference on Environment Sensitive Mechanical Properties of Materials at the Research Institute for Advanced Studies at Baltimore that thin foils of titanium could be prepared by chemical polishing in a mixture of 44 pct HF and 73 pct HNO3 in the volumetric ratio 2:3. The technique is simpler than that since reported by Rice and Orava. As-received annealed titanium (containing 0.8 pct Fe and 30 ppm H) in the form of sheet 0.05 cm thick is placed in the solution and moved up and down. The reaction is violent but suitable foils are obtained very easily and consistently. A typical micrograph is shown in Fig. 3. The small precipitates were not identified. Yamane and ueda6 observed many spotlike features which they referred to as small dislocation loops. While their spots may be due to the reaction of the warm foil with the air as suggested by Rice and Orava, the precipitates in Fig. 3 are also found when foils of titanium are prepared by electro-polishing at low temperatures and subsequently examined in the electron microscope without any inter- mediate warming. Furthermore, they are not a surface effect. It is necessary to add that alloys of titanium cannot be so easily thinned by the chemical polishing solution described above since it contaminates the a, phase with hydrogen and produces y hydride. These matters are described at length in a paper7 and their relevance to stress corrosion is considered elsewhere.'-* Author's Reply The authors are grateful to Dr. Scully for bringing to our attention his hitherto unpublished technique for thinning unalloyed titanium, and deeply regret the unintended apparent duplication. The chemical thinning solution (7 parts HNO3 and 3 parts HF, by volume) reported by us is the same as that with which, for some period in the past, we had experienced success in the preparation of foils from single and polycrystalline niobium. Its subsequent effective application to titanium was a logical step, which, clearly independently of Scully, was conceived by Mr. Rice, to whom full credit is due. A few comments are warranted concerning some of the details of the preceding Discussion. It is evident to the discerning reader that the two thinning techniques under consideration are chemically almost identical, and in that sense are equally "simple". The chemical aspect is, of course, the one of primary importance in both communications. Thereafter, the relative simplicity is dictated by the mechanics of the actual thinning operation selected by the individual investigator. Our standard dimpling, or dishing, procedure was chosen with a view toward providing, for the electron transparent areas of the sample, the maximum protection from extraneous deformation during handling. That the long, straight dislocations visible in Scully's electron micrograph of a seemingly recovered structure closely resemble handling dislocations would tend to indicate the merit of our adopted technique. Features similar to those which Scully has attributed to precipitates, without any apparent diffraction contrast confirmation, were not observed in any of our clean foils taken from annealed or deformed specimens. This was admittedly somewhat surprising since the 3700 ppm (nominal) Fe in the A-70 commercial-grade titanium examined should have given rise to TiFe precipitates. Presumably these existed but were un-resolvable. Curiously, Scully's "precipitate1' density is fairly high although the iron content quoted was less than one-fourth of that in our material. One is forced to conclude from the evidence that prior thermal and mechanical treatments are responsible for the two different types of structure observed.

Jan 1, 1968

By Peter N. Loncar

Most miners dream of finding a gold mine sometime during their mining careers, but not very often do such dreams come true. On the tenth day of September, 1962, our dream of finding gold came true when the results of the third drill hole were received. This was undoubtedly one of the most exciting days of our lives. Little did we realize then that this was the beginning of a major discovery destined to became one of the largest gold mines in the country. Discovering and mining gold is not entirely new, however, to Eureka. County a old Lynn Mining District in northeastern Nevada. Since 1900 there has been sporadic activity, mostly consisting of small lode mines and placers. These have produced totally about $300,000; and existence of our orebody would probably have remained unknown had it not been for the United States Geological Survey. The USGS extensively mapped the Roberts Mountain Thrust and published a paper indicating that mineral occurred along this fault and in some places was gold bearing. Utilizing this information, our Newmont Exploration geologists located an area in which: drills were brought in to test their theories. By keeping flexible in our thinning and working, we were able to bring a raw prospect to a producing mine with ore reserves of eleven million tons in a short three-year period.

Jan 1, 1965

By Y. J. Wang

This paper describes a graphical technique by which the operating points for a two-fan ventilation system can be represented as the intersection of the modified fan curves. In constructing the diagram, the air quantities associated with the fans are considered to be independent variables and employed as the axes of a rectangular coordinate system. The diagram may include, in addition to the modified fan curves, contour lines for resistances, pressures, and air powers. Procedures for drawing the diagram are discussed and illustrated with an example of the ventilation system.

Jan 1, 1985

By Matthew A. Perras

With growing populations, infrastructure projects are utilizing underground space to expand transportation networks, water supply and sewer disposal systems and hydropower facilities. These new projects require large diameter tunnels to meet the growing demands. As the tunnel diameter increases, not all rock mass properties are scalable and precedent experience becomes less reliable. One such non-scaleable property is lamination thickness. Numerical modelling was conducted to determine the influence of lamination thicknesses on a 16 m diameter tunnel. Five different areas of excavation response were found to exist for laminations ranging between 0.16 to 16 metres in thickness. For this tunnel diameter, critical lamination thicknesses of 6 metre and 1 metre were found to exist. Above 6 metres the excavation response was similar to isotropic models. Below 6 metres the stresses and yield are channeled by the lamination boundaries, increasing plastic deformation. Below 1m multiple lamination units become unstable and the displacements increase significantly and the shape and extent of the yield zone size changes dramatically. The yield zone is controlled by bed deflections and bed parallel shear. As the lamination thickness decreases tensile failure first begins in the haunch area and progressively extends above the crown until a self-limiting plastic yield zone shape is reach at lamination thicknesses below 0.4 metres. Conclusions drawn from observations at the Niagara Tunnel Project are those of the authors.

May 1, 2009

By S Liu, N M. Rana, A Take, N Ghahramani, D Clohan, S McDougall, S G. Evans, H J. Chen

Tailings dam breaches have caused significant life loss, social, economic and environmental damage in recent years. The term "tailings-flow" refers to various forms of tailings outflow movement resulting from the breach of a tailings dam. These flows, comprising a mixture of tailings, water and dam materials, can take different forms, ranging from a debris flood to a flowslide, and can travel long distances and impact large areas. The inundation extents depend on the failure mechanism, tailings dam height, total released volume, sediment concentration (associated with the rheological behaviour of the flow) and downstream conditions (including topography, land cover and presence of a water body). Numerical runout modelling of tailings dam breaches is important for predicting the dynamics and extent of tailings-flows, which are crucial steps in tailings dam consequence analysis and risk management. This paper presents a comparison of numerical simulations of the 1994 Merriespruit tailings dam breach using three numerical models: DAN3D, FLO-2D and MADflow3D. Using compiled site condition information and data from the literature and public domain, model performance was evaluated primarily based on comparisons between the observed and simulated inundation extents. The main purpose of this preliminary model benchmarking exercise was to help us evaluate the capabilities and limitations of each model, and to identify opportunities for future model improvements as part of a broader research initiative known as CanBreach. This exercise also highlights the inherent complexity of tailings-flows and the importance of using judgement to interpret model input and results.

Jul 1, 2021

By F Rashidinejad

Iran has had an active mining sector for some 7000 years. Exceptional in terms of its mineral diversity, Iran produces 62 minerals, and is ranked among the world’s 15 most mineral-rich countries. Many people around the world know Iran as one of the major petroleum exporters. Oil and natural gas dominate Iran’s economy, and oil exports provide the principal source of income, contributing more than 80 per cent of foreign exchange earnings. Transformation of Iran from an oil exporter to an independent country to oil has been on the table for many years, even before the Islamic Revolution of 1979. Development of the Iran’s mineral industry is one of the major replacements for petroleum exports. In the last decade, Iran invested billion dollars in the mining and mineral industry sectors and to increase the added value, tried to export processed minerals instead of the raw materials. In accordance with the ‘20-year Perspective 2025’ that targeted by the Supreme Leader, Iran will be a country with the first rank in economy, science and technology in its region. The objectives over this perspective include briefly increasing annual production to 55 Mt of crude steel, 800 000 tonne of copper cathode, 1.5 Mt of aluminium, 200 Mt mineral products, 300 000 tonne of zinc and 5 000 kg of gold. These goals are achievable in normal circumstances, but concurrency of the 20-year Perspective 2025 with commencement of the UN Security Council sanctions against Iran, frustrated objectives of the perspective, at least the ones related to the mining and mineral industry sectors. This paper tries to elaborate the development programs and following challenges for the mining activities of Iran by 2025.

Nov 22, 2011

By G H. Reavely, The University of Western Ontario Department of Geology

The lower Middle Devonian Sylvania Sandstone occurs in the sub-surface in the western part of Mal-den township, Essex county, Ontario. The formation is composed of well rounded, frosted quartz grains with a silica content varying from 42 to 93 per cent and the grains are cemented by carbonate, constituting up to 57 per cent of the rock. This sand-stone is not a homogeneous bed but is divided by strata rich in carbon-ate cement. The thickness of the Sylvania in Malden township varies up to a known maximum thickness of 88 feet. The lower contact with the chert-bearing Bois Blanc formation is sharp but the upper contact with the Amherstburg formation (Detroit River group) exists as a transition by a gradual downward increase in quartz grains. The Sylvania would seem to outcrop in the lake bottom near the mouth of the Detroit River dipping to the north along a broad anticline the axis of which follows the Detroit River. Just south of Amherstburg, a local east-west trending

Jan 1, 1961

WMC Limited, owner/operator of Olympic Dam, the worldÆs largest underground uranium mine and the fourth largest underground copper mine has now completed an expansion that has been classed as a benchmark in the mining industry. To achieve a production increase from 3.4 to 9.25 Mtpa from an underground mining operation in two years was a major challenge, it was essential to review the overall materials handling system from æthe face to the stockpileÆ. The challenge was two-fold:How to deliver 30 000 tonne of ore per day to the processing plant, from a single underground mine? To provide the processing plant with a consistent metallurgical feed. This paper traces the transformation from the old to the new materials handling system at Olympic Dam.

Jan 1, 2000

By Raymond O. Dannenberg

The Bureau of Mines conducted laboratory and full-scale tests to develop a process for improving the flotation characteristics of lime-treated waste water produced by the Kennecott Copper Corp., Magna, UT. Unknown substances in the waste water reduced the flotation efficiency of the metal sulfides. An estimated annual loss of 795,000 lb Cu, 232,000 lb Mo, 5,625 tr oz Ag, and 617 tr oz Au would result from recycling the total flow from the lime treatment plant to the flotation mill in an effort to conserve water and reduce associated expense. The tests indicated that aeration or treatment with activated carbon significantly improved the water quality. The improvements in molybdenum recovery averaged 8 pct for carbon, 11 pet for activated carbon, and 16 pct for combined aeration and activated carbon. The combination of the two processes produced water quality as good as or better than normal feed water.

Jan 1, 2011

By Shilai Yuan, Huimin Lu, Liyuan Zhao, Zhijiang Gao

"A purification process was developed to removal impurity element boron from metallurgical grade silicon by electromagnetic induction slag melting. Vacuum melting furnace was used to purify boron in both Al2O3-MgO-CaO-SiO2 slag system and Al2O3-CaO-SiO2 slag system. The relationship between different slag chemistry and the removal of boron in silicon were studied using Back Propagation (BP) Neural Network model. The best slag chemistry for the removal of boron was predicted by Genetic Algorithm (GA) contributed by the use of Matlab. The results show that the mass fraction of Boron in silicon is reduced from 11.7496×10-6 to 2.3259×10-6 after slag melting in 28.96%Al2O3-3.43%MgO-36.24%CaO-31.37%SiO2 slag system. The relative error obtained with GA-BP Neural Network model was below 0.35%.IntroductionSolar energy, due to its low green house gas emissions, has been paid great attention. Accordingly, the demand for solar grade silicon (SoG-Si) has been growing rapidly. The quest for developing a low-cost method of producing SoG-Si has been moving forward in the last decade. Refining of metallurgical-grade silicon (MG-Si) attracts research interest due to its low material and energy costs, and more environmentally friendly technology in comparison to the traditional Simens process. As such, impurity elements in MG-Si must be removed to low levels for the photovoltaics (PV) cell to operate at optimum efficiency. Most impurities in metallurgical-grade silicon (MG-Si), especially metal elements, can be separated by directional solidification and the zone refining plasma-arc method [1, 2]. The main focus in refining MG-Si to SoG-Si is on the impurities which are the most difficult to remove. Boron has relatively high segregation coefficients (KB=0.8, concentration of Boron in solid silicon divided by its concentration in liquid silicon) [3] and higher vapor tension (the saturated vapor pressure of boron and silicon are 6.78×10-7 Pa and 0.4 Pa, respectively). The vacuum melting and directional solidification methods hence have no effects on boron removal.Slag refining involves melting MG-Si in the presence of a flux to produce a slag phase that can take up the impurity elements. The mechanism of slag refining is considered to include two main steps: the oxidation of boron and the absorption of boron oxide by slag materials. The oxidation of boron, described by the oxygen potential (PO2), resulting from the equilibrium Si and SiO2. The absorption of boron oxide, described as the slag basicity, is interpreted as expected to facilitate their extraction to alkali and alkali-earth oxides in the slag phase. Thus, effective removal may be obtained for a certain slag composition. Researchers [4-5] examined the effect of boron removal in CaO-SiO2 based ternary systems and showed that the addition of excess CaO can decrease the activity of SiO2. Researchers [6-8] studied the boron behaviors in CaO-SiO2-Al2O3, CaO-SiO2-Na2O, Al2O3-BaO-SiO2, CaO-SiO2-Li2O and Al2O3-CaO-MgO-SiO2 slag systems by adding boron in the silicon to a degree. Li2O, Na2O, MgO and BaO are thought to be associated with B2O3."

Jan 1, 2014

By I. Lowthian Bell

THERE has been probably no improvement introduced into the manufacture of iron which created more surprise in the minds of practical smelters and of scientific men than Neilson's discovery of the hot blast. In 1829, Messrs. Dunlop & Co. consumed at the Clyde Works, near Glasgow, nearly 79 tons of coal to make a ton of pig iron, of which about 20 cwts. was employed under the boilers of the blowing engines, leaving nearly 7 tons for the consumption of the furnace itself. In the year 1833, by heating the air to 612' F. (322' C.), they redoccd the 79 tons to 3 tons by the mere burning of 8 cwts. of coal in the apparatus for raising the blast to this temperature. The statenlent just given is strictly true in a commercial sense, but when we come to consider the question as one of physical science, it is necessary to eliminate some of the conditions which conduced to so extraordinary a result. Anterior to Neilson's time the fuel employed in smelting iron was coke, and it was supposed at that period, erroneously, however, that coal in its raw state, when burned with cold air, was totsally unfit for the purpose in question. This mineral, as it was obtained from the Lanarkshire coal-field, contained about 35 per cent. of volatile matter, but the process of charring it was performed in so unskilful a manner that instead of receiving 88 cwts. of coke from 135 cwts. of coal, 60 cwts. only was the product of the operation. Again, the reduced colisumption of carbon in the furnace itself was accompanied by a corresponding diminution of blast, and this was followed by an economy of half a ton in engine coal. After making a proper allowance, however, for all these collateral circumstances, we are within the mark when we admit that in actual coke, which is really the form the fuel has to assume before it is burnt in the blast-furnace, not less than 30 cwts. was saved by heating the blast to 615° F. (322° C.). This unexpected economy, be it remembered, was obtained by the combustion of the 8 cwts. of coal, somewhat wastefully applied in the hot-air apparatus. Numerous have been the opirlions advanced by different authorities in the scientific world to account for the apparent anomaly, bat none,

By D Baas, J Le, R Braun, R Chandramohan, K Hollis, G Lane

The Phu Kham Copper-Gold Operation (Phu Kham) is located in northern Laos, approximately 140 kilometres from the capital, Vientiane. The operation is a producing asset for Australian-based copper and gold producer, PanAust Limited (PanAust) and is operated by Lao-registered company, Phu Bia Mining Limited (Phu Bia Mining). PanAust holds a 90 % interest in Phu Bia Mining. The Government of Laos owns the remaining 10 %.The Phu Kham Operation has recently undergone a series of process improvements to treat the anticipated competent ores scheduled for 2017 and 2018. The operation’s comminution circuit, which comprises a semi-autogenous (SAG) mill and two ball mills, each with 13 megawatts (MW) of installed power, was expected to be SAG mill limited when treating competent basement rock. Ausenco Services Pty Ltd (Ausenco), was engaged to help optimise and enhance the productivity of the Phu Kham comminution circuit over an eight-month period. The work involved participating in and overseeing the redesign of the SAG mill liner systems and developing operational strategies for maximising throughput through to the end of mine life. Ausenco’s comminution optimisation tool, Ausgrind, was used to benchmark and analyse plant data with empirical models, predict circuit performance for varying ore characteristics and evaluate liner wear and predict the life for varying operating parameters. Variances between the actual and the predicted values were assessed in detail to identify missed opportunities, and guiding operating parameters were redefined to maximise throughput and productivity. In combination with the redesigned liner system, optimised process controls for varying ore competencies, and improved operational practices and troubleshooting strategies, increased Phu Kham overall production, exceeding the milling capacity when treating competent ores. CITATION:Chandramohan, R, Braun, R, Lane, G, Hollis, K, Le, J and Baas, D, 2018. SAG mill optimisation and increasing throughput at the Phu Kham Copper-Gold Operation – a success story, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 113–128 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By S. D. Strauss

Mr. Strauss takes apart the double threat of monopoly and failing resources in this article. Originally presented before the American Electroplaters Society, the basic contents o f his message are a warning that traditional trust-busting and mineral shortage concepts have been outdated by the broadened scope of competition. But to the miner, stoic before the cyclical predictions of feast and famine, traditional markets aren't getting any easier.

Jan 8, 1961

By S. S. Peng, V. Z. Sun

One of the major concerns of ground control in a coal mine is the prevention of roof, pillar and floor failures of the mine entry. To better design and evaluate the stability of a mine entry within a certain level of confidence, a reliability approach is introduced. The advantage of using the reliability approach, rather than the conventional safety-factor (SF) method, is that it not only takes variability of both rock/coal properties and stress into consideration but also assesses the stability of each component and the mine entry as a whole. Therefore, it is anticipated that by using this approach the current ground-control technology in a coal mine will convey a better sense of confidence. The results of a case study show that there is a significant difference in mine entry stability between the current design method and the reliability approach.

Jan 1, 1999

By David Schlain

"INTRODUCTION Electrolytic manganese is produced by electrolysis of a solution of manganese sulfate and ammonium sulfate in a diaphragm-type cell, metallic manganoese being deposited on the cathodes and sulfuric acid produced at the anodes. The spent electrolyte is used to leach fresh ore that has previously been subjected to a reducing roast; the resulting leach liquor is purified and returned to the cell.The leach liquor produced at the Bureau of Mines pilot plant 3/ at Boulder City, Nev., contains 135 to 140 grams of ammonium sulfate and 32 to 36 grams of manganese (as sulfate) per liter, and has a pH of about 2.5. After neutralization to a pH of 6.4 to 6.6 with ammonia and thickening, 0.10 to 0.15 gram of hydrogen sulfide per liter is added to the liquor to precipitate the heavy metals, and after 15 to 30 minutes the precipitate is filtered off. Residual sulfides and colloidal material are removed by ferric hydroxide formed by adding a small amount of ferrous sulfate to the solution at a pH of 6.5 to 7.0 and passing air through it. The solution is then filtered and clarified as a precoat filter. Finally, 0.1 gram of sulfur dioxide per liter is added, and the solution is electrolyzed in an anode-in-diaphragm cell. The spent electrolyte coming from the cell contains approximately 10 grams manganese, 135 grams ammonium sulfate, and 45 grams sulfuric acid per liter."

Oct 1, 1946

By John A. Mavrogenes

The Texaco gasification system developed at the Monte Bello pilot plant efficiently bums petroleum-coke thereby producing syn-gas and electricity. This system produces more electricity than conventional burners, yet the only by-products are pharmaceutical grade sulfur and V -rich slag. Vanadium is known to exist in multiple valence states in compounds which possess a wide range of melting points and physical properties. Consequently, it becomes important to carefully regulate oxygen fugacity throughout the system in order to control vanadium valence state. Vanadium phase equilibria is presently poorly understood, in large part because of the multiple oxidation states of vanadium (-I, 0, +2, +3, +4, and +5) and the difficulty of unequivocally identifying the valence state(s) in many compounds. The operation of these gasifiers at approximately 1400°C is well above the melting point of V20S but considerably below the melting temperature of V02 and V 203. If J02 can be regulated to keep the burner within the V 205 field, slag material would more likely remain molten and more easily flow out of the bottom of the burner. In pure V oxides. the oxidation state is readily determined by microprobe analysis. where V20S (V+5) is 56% V, V02 (V+4) is 61.4% V, and V203 (V+3) is 68% V. However, V valence in multi-element phases (especially phases containing other elements of variable valence) cannot be resolved by microprobe analysis alone. Petroleum-coke gasification slags collected from within the gasifier under different oxidation conditions were studied by electron microprobe analysis (EMPA). X-ray diffraction (XRD). X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. Raman spectrometry in conjunction with microprobe analysis was found to resolve the valence of vanadium in the phases of these slags. Raman spectra collected from homogeneous single phase V-oxide standards in vacuum at low temperatures (-150°C) yielded peaks characteristic to each valence state. Gasifier slag samples are, however, much more complicated. Oxidized samples contain: fine grained (Ca. Mg, Fe. V) oxide matrix of variable composition, (Fe. V, Ni) spinel. (Fe, AI, V, Ni, Mg) spinel, V205laths, AI-Si glass blebs and Ni sulfides. Reduced samples contain: crystalline Ca-siIicate matrix, subhedral to euhedral (V, Fe, Mg, AI) spinel, subhedral V02, Fe and Fe-Ni sulfides, Fe-Ni alloys, and complex Ca-oxide matrix. The different spinel assemblages, the characteristic V-oxides and the distinctly different character of the matrices makes the oxidized and reduced slags readily discernible.

Jan 1, 1995

By Martin Hertzberg

In this Bureau of Mines report, the optical detection of fires and explosions is considered fundamentally. The measured spectral radiances from methane-air ignitions are compared with the background irradiances from stray and ambient sources, and with the spectral sensitivites of various sensors. The comparison naturally suggests the optimum spectral ranges and signal processing logic that can uniquely characterize the ignition event. Both ultraviolet (UV) and infrared (IR) are considered. Several alternate sensing methods are proposed and discussed. The development and testing of an IR system designed for use in ignition suppression devices in mines is described.

Jan 1, 1975

By Walter F. Morton

La mina y la planta concentradora de Chilete de la Northern Peru Mining & Smelting Co., están situadas en Cajamarca, norte del Perú, donde en 1948 se encontraron cubicadas cantidades de minerales de plomo- zinc, que fueron añadidas a las reservas de la mina. Posteriormente se construyó una planta de flotación que permitió mejorar la filtración de los concentrados y a su vez aprovechar al máximo los minerales de la mena como la ganga, así como su concentración de valores económicos en los mismos.

Jun 20, 1954

By S. Yuan

Oxygen ion conducting yttria-stabilized zirconia (YSZ) tube was used to remove oxygen from molten Cu at 1373K. Outer surface of the tube was in contact with the melt and the inner surface containing a thin layer of porous Ni-ZrO2 cermet electrode was in contact with a reducing gas. The migration of oxygen species (O2-) from the Cu melt through the YSZ tube is accompanied by an equal and opposite flux of electrons maintaining electroneutrality. Without applying an external EMF, the fluxes are maximized by short circuiting the melt with the cermet electrode. For efficient oxygen removal, the YSZ tube must be thin, contact resistances should be negligible, and the electrodes must be porous and cover the entire electrolyte surface for charge transfer. This refining process is environmentally sound, can use reducing gases such as H2, CH4 and CO without running the risk of increasing H or C content of the melt.

Jan 1, 1993