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By James T. Wood

STRATIGRAPHY structure and closure of the Paloma field are discussed, with some details regarding the present state of development. The Paloma anticline, a large dome modified by faults, is the largest single closed dome in the southern San Joaquin Valley without surface outcrop or topographic expression. It owes its discovery to geophysics. Of nine wells drilled to the Stevens sand, seven are productive. The ultimate productive area may approximate 3000 acres when the limits of the field are determined.

Jan 1, 1942

By M. S. Azun

M.S. Azun I have many objections to the content of the author's paper. Before discussing it, however, I would like to repeat the property of semivariogram function. Second order stationary properties of regionalized variables (ReV's) such as semivariogram function ?(h) are perfectly known in geostatistics. Also, the kriging equations in the language of mathematical statistics using second order stationary properties are well understood. However, the way to use the sample (estimated) semivariogram function in any one of the kriging procedures is vague. The sample semivariogram function is given as follows: [1 N-hy*(h) = 2(N h) i21 {Xi-Xi+h}Z, h=0, 1, N-1] where N is the total number of samples, Xi is the sample value at the i - th location, X i+h is the sample value at the i +h - th location, and h is the distance among the samples. An estimation variance of sample semivariogram function of first lag is smaller than that of higher order lag. The theoretical semivariogram function reaches the variance of samples asymptotically. But this is not easily observable because of the larger variation involved in the estimate of semivariogram function. In general, an estimation procedure is done for h = 0, 1, 2,…., up to the greatest integer less than N/2, even though sample semivariogram function can be computable through N-1. After estimating semivariogram function, the critical question of how to model sample semivariogram function arises. As seen in the above equation, sample semivariogram function is discrete and can be smoothed by the model being selected. Therefore, modeling of sample semivariogram function is the most important step in geostatistics. It not only smoothes a discrete function but also affects the results of the kriging procedure. When the only aim is to model the semivariogram function, which is the basic point of the author's paper, one can employ any fitting techniques, such as curve fitting, or any ar¬bitrary functions, which are called submodels in the paper. The term "arbitrary function" is used rather than "submodel" because there is no basic understanding of developing them. The author suggests that the sum of those submodels can also be used for the modeling of sample semivariogram function. The combination of any arbitrary functions brings many problems instead of giving an insight of the domain structure considered. The author used two arbitrary functions and the nugget effect in response to sample semivariogram function (Fig. 10). For the same example, he stated that the parameters involved in the mixed arbitrary function model can be accepted when the discrepancy between sample semivariogram function and the model is small visually. For verifying the fitting behavior of any selected model, one should not be contented with the visual satisfactory. Some statistical measure such as goodness of fit has to be used. The author's practice is no more than an exercise in curve fitting without any fundamental understanding or conceptualization of the underlying physical mechanism. Furthermore, the selection of any model is not an easy task if the purpose is the search for the "best" response to the observed second order properties of ReV's. I suggest that the Markovian model (Azun, 1983), on the basis of a theoretical understanding of underlying mechanism, which gives more information about the occurrence of regionalized variables, is used to respond all properties of ReV's. There are a lot of problems for modeling of onedimensional sample semivariogram function. Thus, it is not appropriate to go to higher order dimensional sample semivariogram function modeling. In the meantime, I would recommend that one can connect the values of standardized sample semivariogram function rather than simple values of semivariogram function in the two-dimensional estimation. The standardized values can be computed in dividing the semivariogram function value by the number of sample pairs involved in each lag regardless of the directions. In conclusion, geostatistics is an interdisciplinary area in mining that uses the principles of mathematical statistics. Thus, it should not violate any probabilistic and statistical rules. When Matheron was developing the theory of geostatistical study in the early years of geostatistics, many mining people had a reservation accepting the geostatistical tools. However, this does not mean that we, the geostatisticians, might try to convince those people using some "strange" tools or rules as some authors implied (Baafi and Kim, 1984). Instead, we have to develop and explain the geostatistical tools staying only in the framework of statistical concepts and properties. ? References Azun, M.S., 1983, "Stochastic Process Modeling of Spatially Distributed Geostatistical Data," Columbia University, Ph.D. Thesis. Baafi, E.Y., and Kim, Y.C., 1984, "Discussion - Comparison of Different Ore Reserve Estimation Methods Using Conditional Simulation," Mining Engineering, Vol. 36, No. 3, p. 280. Reply by J.M. Rendu The interactive method proposed by Rendu allows practitioners to develop semivariogram models that take into account not only the numerical information obtained by sampling, but also highly significant additional information that often cannot be quantified. The geology of the deposit - including hypotheses concerning its genesis, sampling methods, assaying methods, and mathematical methods used to calculate the semivariograms - all have an influence on the numerical results obtained and on how these results should be interpreted. If all the information concerning the spatial distribution of values in a mineral deposit was contained in the sample values, it could be argued that statistical techniques alone would produce optimum models. However, this is rarely, if ever, the case. Methods that allow the user to take into account his experience and his geologic understanding of the deposit should not be rejected for the sake of theoretical statistical purity. ?

Jan 1, 1986

By David Burgess, Hershiel H. Hayden

Experiments at the Somerset mine, Colo., under an agreement between US. Steel Corp. and the US. Bureau of Mines are described. A test was made of the tube bundle method of mine air sampling which was developed for European longwall mines; some 300,000 running feet of tubing provided continuous monitoring at 38 locations. Carbon monoxide concentrations were obtained with standard deviations of less than 1 ppm and oxygen concentrations with standard deviations of less than 0.2%. A base level of CO index (ppm CO evolved per percent 0, removed) was determined to be zero to 20 through most of the passageways of the mine. However, in one working section where the coal was initially hot (about 180°F within a pillar) the CO index was demonstrably higher, 120 trending upward to about 60 when smoke appeared and the section was sealed. The data are discussed in terms of laboratory experiments on CO evolution from coals.

Jan 1, 1977

By M. Desjardins

The Hoyle Pond underground mine, located in the Porcupine Gold Camp, east of the city of Timmins, Ontario, Canada, is the cornerstone of Goldcorp Canada Ltd?s Porcupine Gold Mines. Cut and fill, shrinkage, longhole and panel mining methods are employed to excavate the narrow gold bearing structures. In order to meet increased flow requirements of 256 m3/s at the mine, a new Fresh Air Raise (FAR) and new surface fans were commissioned in early 2005. The newly acquired fans were capable of supplying the desired volume of air within a range of 1.5 and 2.0 kPa. Upon commissioning of the surface fans the total pressure was found to be exceedingly high; far beyond the design capabilities of the new installation. Consequently only one surface fan could be operated at any given time providing about half the required volume of air. Extensive work was immediately started aimed at reducing the system resistance in order to permit operation of the two fans in parallel and achieve the required mine flows. Larger booster fans were installed in parallel at the 900 m level, a 3 m raise bore linking the 450 and 900 m levels was developed to twin the existing fresh air circuit, and the FAR from surface to the 450 m level was twinned with the original FAR. This strategy, completed in 2012, resulted in a drastic reduction in system resistance and pressures, allowing the two surface fresh air fans to be safely operated in parallel and meeting the flow requirements. This paper describes details of the engineering design work and commissioning of the modified ventilation system, successfully ensuring the long term viability of the project.

Aug 1, 2013

By Rodrigo Toro, Ivan Yutronic N

"The Copper Concentrator Plant of Compañía Minera Doña Inés de Collahuasi (CMDIC) is composed of three grinding lines, the third one being the largest. Due to the capacity feature of the third line, specially its SAG mill, it is a priority that the advanced process control team of the Company deploys a supervisory control strategy that allows this unit to operate in an optimal way, in order to achieve the maximum productivity at minimum cost. It is in this kind of tasks where advanced control applications play a key role in obtaining the best economic profit of the process.The advanced process control team, formed by people from Informatics, Automation and Operations of CMDIC have assumed the challenge of generating the transition from a manual SAG Mill 1011 operation (40 x 22 feet, the largest copper SAG mill of the world), to a fully automatic SAG Mill using a multivariable control strategy instead of a rule based on expert control system (widely used in industrial mining process control applications).Therefore, CMDIC decided to work together with Honeywell APC Team implementing an advanced automatic control strategy for the SAG Mill 1011, using for this purpose a technology called Model Based Predictive Control (MPC), based on a variety of control methods that uses dynamical models of the process, obtained from input/output data, in order to print the process knowledge into a group of mathematical relationships that links the constraints (controlled variables) with available commands (manipulated variables) and measured disturbances.The main objective of the advanced control strategy is to ensure process government, tending to throughput stability and optimization, by the execution of coordinated control actions, proactively avoiding measured disturbances effects and the SAG mill overloading.The most important benefits of using a multivariable control strategy are: the automated operation of SAG mill 1011 (that was manually operated before the implementation of this application), a safer, more coordinated and more stable process operation, achieving through this an increase of throughput and a decrease of specific energy consumption, controlling the amount of oversize material production, power consumption, mill loading, noise and torque. In addition to the operational results, this challenge has consolidated a control team, with the participation of engineers and operators, diminishing the typical implementation time and achieving a greater use of the application in a short time."

Jan 1, 2010

By E. H. Myrhaug, K. Aasly, T. Malvik

Quartz is one of the main raw materials for the carbothermic production of ferrosilicon and silicon metal. The ideal process is written: SiO2 + 2C = Si + 2CO The real process is much more complicated, depending on the quality of the raw materials. Several research projects have been carried out on quartz for the (Fe)Si process during the last 50-60 years. One of the important properties that have been discussed in this review is the volume expansion that takes place between 850 °C to 1000 ºC and explosive disintegration for some quartz types. No final and definite conclusions have been made but several reasons have been mentioned: The influence of the phase transformation to tridymite, which takes place within the same temperature interval, has been discussed in several papers. Alkali impurities have been mentioned as a critical factor for this transformation to take place. Other researchers have mentioned mica impurities as a critical factor for the behavior of the quartz at these temperatures. Studies of fluid inclusions in quartz was reported in some papers focusing on the volume expansion of these during heating as a source of explosive disintegration, especially along planes of healed micro fractures that often contain vast numbers of such inclusions. Several methods for investigations of the important properties of quartz have been presented and these provide a good basis for the further research on quartz raw materials.

Jan 1, 2007

Discussion of the paper of J. V. EMMONS, presented at the Pittsburgh meeting, October, 1914. and printed in Bulletin No. 93, September, 1914, pp. 2233 to 2248. ALBERT SAUVEUR, Cambridge, Mass.-Mr. Emmons is to be congratulated for having placed before us in so forcible and satisfactory a manner a question of much importance-that of the surface decarbonization of steel. Of course, both manufacturers and consumers have known for many years that during the heat treatment of high-carbon steel, surface deca.rbonization is always likely to occur to a greater or less degree, but the subject does not seem to have been investigated with the method and thoroughness it deserves. I am in substantial agreement with Mr. Emmons's conclusions, and I have but little to add to what he has so well said. His statement that carbon dioxide is just as effective an oxidizing agent as pure oxygen is likely to cause surprise and some will wonder whether his investigation has been carried far enough to warrant so unexpected a conclusion. The reaction C + 0 = CO, expressing the oxidation of carbon by pure oxygen, is decidedly exothermic, whereas the reaction C + C02 = 2C0, expressing the oxidation of carbon by carbon dioxide, is endothermic. Decarburization by pure oxygen, therefore, should take place much more readily than by carbon dioxide. One cannot help regretting that the author does not mention' the best way of preventing in a practical manner surface decarbonization while treating tool steel and other high-carbon steels.

Jan 4, 1915

Water represents 80?85% of the volume of mineral pulp processed in flotation circuits. Imperatives for a more detailed focus on circuit water quality and its control have come from increasing requirements to use relatively impure primary water supplies (e.g. high salinity, treated sewage) and high proportions of recycle from tailings dams, thickener overflows, dewatered and filter products. An integrated methodology for examining process water quality and its effect on minerals separation has been developed coupled with minerals surface chemistry across the complete processing circuit. Unrecognised factors, including varying proportions of water streams (daily or hourly), colloidal precipitation, highly variable pH and Eh, reaction and dissolution of minerals, minerals surface layer coatings, residual reagents and their reaction products, and microbiological activity have been studied in eight mineral processing circuits. The methodology combines: solution survey and modelling; microbiological surveys; minerals surface analysis and modelling; and process response. It has been possible to match the predicted (model) pulp chemistry with that measured from surveys of the solution and mineral surfaces. Treatment methods have included: monitored and balanced stream combinations; organic species removal; flocculation and aggregation; induced precipitation; dissolved air flotation; ageing (oxidation, UV exposure); and chemical surface conditioning of minerals. Some specific achievements from the methodology applied in plant and laboratory testing, with examples from case studies, will be described.

Jan 1, 2001

A system to continuously measure the concentration of radon in mine ventilating air has been developed and tested in a uranium mine. In use, the air/radon mixture to be monitored is pumped through filters into a scintillation cell where nuclear decay of the radon produces flashes of light. These are electronically counted, giving a quantitative measure of the radon present. Air is continuously drawn from the mine atmosphere into the radon sensor box. This air sample passes through two filters into the detector cell as shown in the schematic diagram. A portion of the radon in the detector cell will experience nuclear decay, producing polomium 218 and an alpha particle. The alpha particles from the fraction that decays strike a zinc-sulfide coating on the inside wall of the cell and produce flashes of light. These enter a photo-multiplier tube which records each flash as an electrical pulse. An amplifier increases the voltage of each pulse, allowing electronic screening to remove noise and other undesirable pulses. The remaining pulses are counted by a conventional data acquisition system.

Jan 1, 1978

By Charles M. Wilk, Lori Tiefenthaler

"Information presented in this paper can be used to support deep soil mixing, subsurface grouting and slurry wall technology as sustainable construction technologies. Ordinary Portland Cement (OPC) is the default cementitious material used by Deep Foundation Institute (DFI) Members for geotechnical work. Owners, engineers and contractors can contribute to the sustainability of a geotechnical project by increasing the use blended hydraulic cements and industrial byproducts to replace some of the OPC in mix designs. Sustainability is defined as the quality of not being harmful to the environment or depleting natural resources. Production of cementitious materials consumes natural raw materials and energy while also generating air emissions and waste. Life Cycle Assessments can be used to compare the relative environmental impacts of one cementitious material to another. Blended hydraulic cements (BHCs) are interground (or blended) mixtures of Supplementary Cementitious Materials (SCMs) with OPC. Commonly used SCMs include fly ash, ground granulated blast furnace slag (GGBFS) and limestone. Examples of industrial byproducts commonly used in geotechnical work include coal combustion residuals (CCR) (aka fly ash), and ground granulated blast furnace slag (GGBFS). Much of life cycle impact of these SCMs and industrial byproducts have already been borne by the industries that generated them. There is increasing awareness to LCA and sustainability of different materials used on projects. This is evident in the application of the Leadership in Energy and Environmental Design (LEED) program. The savings in environmental impact with the use of SCMs and industrial byproducts can make proposed use of these materials in a geotechnical project more attractive in terms of sustainability. This paper presents (a) information that compares published life cycle assessment data of OPC, BHCs, and slag cement (SC) to illustrate the potential benefits to sustainability and (b) general strategies for positioning a geotechnical application, use, project design or cementitious material mix as a more sustainable alternative"

Jan 1, 2017

By Greenwood J. N

This is the fourth paper in the series on Australian w,ar materials and the work was undertaken as part of the programme for producing hard carbides. It had been intended to determine the influence of tantalum and columbium' carbides in mixtures with tungsten carbide. Owing to other, urgent developments, it has not been possible to proceed with that programme.1. THE PROCESSING OF A TANTALITE ORE(a) The OreThe minerals in which tantalum and columbium most commonly occur are tantalite and columbite. These two minerals are the end members of an isomorphous series of tantalates and columbates of iron and manganese, but in nature the series grade into each other.Some of the best deposits of tantalum and columbium ores in the world occur in the north-west of Australia. Until recently tantalite low in columbium was the only mine~al in demand but discoveries of extended uses for columbium, e.g., addition of ferro-columbium to high chromium I steels inhibits intergranular corrosion (weld decay), have created a demand for columbite low in tantalum as weB. Both of these types of' ore occur in the Pilbara district in Western Australia and most of the ore mined is exported to America after a preliminary grinding and concentration by gravity.A sample from the Bynoe Harbour locality, west of Darwin, was used in this investigation. It consisted of coarse lumps of tantalite with quartz in minor amounts. Cassiterite w.as also present. A recent investigation!l) gave the analysis as:

Jan 1, 1943

The reactivity of clay minerals and variety of these reactions are greater than any other known colloidal material. While it is acknowledged that clay minerals can cause problems in mineral flotation, the literature contains conflicting evidence, particularly with respect to the effect of clays on froth stability. It is well known that achieving and maintaining optimum froth stability is an influential factor in determining froth flotation performance. However, the presence of clay minerals in the ore is a major challenge to obtaining a stable froth. In fact, clay minerals could reduce froth flotation performance by both decreasing and increasing froth stability. The mechanism by which clay minerals affect froth stability is not fully understood and needs to be investigated further. In order to improve flotation performance, reliable knowledge of the effect of clay minerals on froth stability is essential which is discussed in this paper. Keywords: froth flotation, froth stability, clay, clay minerals

Sep 1, 2012

By L. L. Oden

The purpose of this research was to develop a method to remove copper and tin from the magnetic fraction of incinerated municipal refuse, as recovered by the Bureau of Mines pilot plant in College Park, Md. Copper, present in the scrap in a metallic form bonded to ferrous objects, was amenable to leaching in cupric ammonium carbonate solution. Copper levels in small 5-to 10-lb lots of treated scrap were reduced from the initial level, 0.5 to 0.6 pct, to 0.1 to 0.2 pct. Larger lots of scrap (100 lb) were treated less effectively because of poor contact of solution and scrap. Oxidation in the air or in aerated aqueous solution was applied to liberate tin from the dilute solid solution present on the surface of incinerated tinplate. Shredding of air-oxidized scrap or caustic leaching of scrap oxidized in solution reduced tin levels from the initial 0.25-pct level to about 0.1 pct.

Jan 1, 1973

By Nan Lee, Stephen H. Chung, Peter Lienberger

INCO Limited's Thompson Open Pit has researched extensively into improved blasting techniques towards increased productivity as well as optimum pit wall protection. Blasting with excessive amounts of explosives near the pit wall can induce severe back-break, new cracks and opening-up of existing joints in the wall. These ill effects can reduce the wall slope stability and restrict mining activities.

Jan 1, 1992

By M. Cai

"It is well known that Peak Particle Velocity (PPV) plays a critical role in triggering rockburst damage in burst-prone underground mines. To estimate the PPV distribution around excavations, advanced numerical modeling can be used. In wave propagation numerical modeling, velocity field is often assumed to be uniform around an excavation. However, it is observed that wave velocities near mine openings are not constant, but rather non-uniform. Wave velocity in a rock mass depends on many factors such as rock quality and confinement. In particular, confinement has a large influence on wave velocity. The confinement around an excavation is low at the wall boundary and increases gradually and reaches a constant value far away from the excavation boundary. Hence, stress redistribution due to excavation will have a profound influence on wave propagation in underground mines. A better understanding of the influence of excavation effect on wave propagation helps to interpret the field observation of rockburst damage and improve mine safety. For this purpose, a non-uniform velocity model need to be constructed and the influence excavation effect should be taken into account in numerical wave propagation modeling.In the present study, a non-linear velocity model is developed firstly by considering the influence of confinement on wave velocity. This model links wave velocity to confinement explicitly. A coupled numerical method is then developed and used to study the seismic wave pattern around excavations in underground mines. Two codes, FLAC and SPECFEM2D, are coupled in the analysis. The motivation of developing the FLAC/SPECFEM2D coupled approach is to take merit of each code, such as the stress analysis capability in FLAC and the powerful wave propagation analysis capability in SPECFEM2D. The coupling process is realized through three steps: (1) static stress redistribution around an excavation is analyzed in FLAC; (2) data for coupling analysis, such as non-uniform velocity field (based on the new developed velocity model), mesh, absorbing boundaries, etc., are generated by FISH functions in FLAC and passed to SPECFEM2D; and (3) wave propagation modeling is performed in the SPECFEM2D considering a fault-slip seismic source. Because stress redistribution around the excavation is considered, non-uniform velocity field for the SPECFEM2D model can be obtained and this is a notable feature of this study. Very large difference in the S-wave response in these two modeling approaches with uniform and non-uniform velocity fields can be seen from the modeling results.Using the FLAC/SPECFEM2D coupled modeling approach, accurate velocity models can be constructed and this in turn will help to produce accurate PPV distribution around the excavations. Accurate PPV contours can be used to identify high rockburst risk zones for improved dynamic ground support strategy."

Jan 1, 2015

By Chas. Kohl

ABOUT 1929 an engineer was engaged to organize a Safety Department, lay out an educational program, and achieve a reduction in accident frequency. Due to the large number of employees, about 12,000, and the distances between the various properties, it was a big undertaking. Most of the workmen are from the Sierra and for generations have been agricultural people, with little conception of modern tools and machinery, and to a large degree are illiterate. However, gratifying results have been obtained, as evidenced by the accident frequency curve during the sixteen-year period. Safety offices have been established in each of the six major properties, staffed by men who devote their entire efforts to inspections of working conditions and equipment, instructions as to safe methods, and investigations of accidents. The Corporation is a member of the Inter-American Safety Council, receiving their publications and literature, which serve to keep us up to date and informed on modern methods. Dissemination of this material is accomplished chiefly through word-of-mouth and bulletin boards. When it is found that the accident rate is increasing in a certain occupation, as for instance underground haulage or mine hoisting, the operators so engaged are assembled and given renewed instructions on the safety code pertaining to their work. Inter-camp competitions in accident avoidance are being conducted, with annual awards for that unit having the lowest severity rate for the year.

Jan 1, 1945

By Emma Arakelova

An increase in concentration of a Zn-containing volatile complex for synthesis of ZnO films was investigated when processing their target by ultraviolet radiation emitted by mercury lamp. The experiments were carried out using a flow-type quartz reactor. ZnO tableted target was preliminarily irradiated during 2 to 7 hours. H2O2 (98%) vapor at 25Pa passed through the reactor with ZnO target at 373K. As substrate material, five subsequent quartz cylinders were used at 423K. The experiment lasts 4 hours. H2O2 decomposition on ZnO surface was accompanied by formation of a Zn-containing volatile complex which passed in gas phase and decomposed on the substrates with isolation of final ZnO. The concentration of the Zn-containing volatile complex (N) in gas phase increases with UV pre-irradiation time (t) (without irradiation N = 1.05 1011 particles/cm3; after t=2 hours, N = 5.19 1011 particles/cm3, after t=4 hours, N = 9.95 1011 particles/cm3; after t=7 hours, N = 1.86 1012 particles/cm3.

Jan 1, 2006

By K. C. Corin, M. S. Manono, R. M. Manenzhe, J. G. Wiese

"Environmental concerns necessitate the recycling of process water within mining operations. Given that recycled water is chemically different from fresh water, and collectors are added such that they adsorb at the liquid-particle interface, changes in the aqueous phase are expected to affect collector adsorption. A Finnish nickel-copper ore was floated in synthetic plant waters of varying ionic strengths and plant waters obtained at Boliden Kevitsa Mine, with aerophine and sodium isopropyl xanthate as collectors. Of the tested waters, the copper thickener overflow was the least conducive to xanthate adsorption and valuable mineral recovery. The nickel thickener overflow, standard process water, and raw water were the most conducive to xanthate adsorption. For the raw water and nickel thickener overflow, increased adsorption correlated with increased valuable mineral recovery. Further, recycling xanthate retained in water affected the selectivity of the collector and hence the concentrate grades.INTRODUCTIONFlotation is a separation process that exploits the differences in the surface properties of the particles being separated. The efficiency of separation is dependent on the degree of hydrophobicity achieved by the particles meant to be floated, which are, in most cases, valuable minerals. The hydrophobicity is in turn dependent on the adsorption of the chosen collector onto the surfaces of the floated particles (Fuerstenau, 1984; Taggart and Hassialis, 1946). Empirical findings suggest that species dissolved in solution strongly influence collector adsorption and overall flotation response (Fuerstenau and Chander, 1986). Due to environmental concerns, it is becoming more pertinent for mining plants to recycle process water and hence limit the usage of potable water. There is an interest to ensure minimal discharge of plant water into the environment, as this water is typically polluted with process reagents that may render it toxic (Levay et al., 2001)."

Jan 1, 2018

By H. L. Talbot, A. J. Hall, R. S. Young

A method for the chemical differentiation of oxidized cobalt from sulphide cobalt in complex mine and concentrator products is of considerable interest to a number of mining companies throughout the world. At Rhokana Corporation, in Northern Rhodesia, for instance, cobalt is found chiefly in the sulphide form, as carrollite, but a cobalt oxide mineral also occurs irregularly underground, and relatively small quantities in the mill feed from time to time are difficult to detect visually at the concentrator. The oxide cobalt is not amenable to the sulphide flotation process used at Rhokana and nearly all of it passes into the tailing. The occasional period when high tailing losses occur with no appreciable change in the cobalt content of the mill feed has naturally been disturbing to the concentrator staff, who had no means of determining whether an influx of cobalt oxide ore or laxity on the part of the mill flotation operators as responsible for these results. A procedure for determining oxidized copper minerals, based on their solubility in dilute sulphuric acid saturated with SO2, has been used for many years in the copper industry. In the presence of cuprite the procedure fails, but otherwise it gives results quite satisfactory for control pur- poses. Empirical methods for determining oxidized forms of zinc and lead have been proposed, but they are generally unsatisfactory except in isolated cases of a very simple ore. No published procedure for determining oxidized forms of cobalt or siinilar elements has come to the authors'notice. Experimental Procedure There are obviously two alternatives in attacking a problem of this nature. One is to employ a solvent for oxide cobalt that will not dissolve cobalt sulphide. The other is to find a substance capable of oxidizing the cobalt sulphide to sulphate, which of course is water-soluble and can then be leached from the water-insoluble oxide cobalt. A representative sample of Rhokana cobalt oxide ore was secured, ground to minus 200-mesh, and carefully rolled to furnish a standard sample for this work. The analysis of this material gave the following percentages: Co, 0.55; Cu, 1.64; Fe, 2.98; S, 0.08; SiO2, 41.42; Al2o3, 11.20; CaO, 13.82; MgO, 3.80. As a source of cobalt sulphide a similar large sample of carrollite was prepared, analyzing Co, 23.36 per cent; Cu, 27.32; and S, 31.13. This sample of course was not pure carrollite, but was the best obtainable in quantities sufficient for a standard intended for considerable work. It was a pure sulphide sample, microscopic examination showing only carrollite, a little bornite, and gangue, with no visible sign of oxidized ore present. A wide variety of reagents as used in an effort to selectively dissolve oxide cobalt or to oxidize sulphide cobalt to

Jan 1, 1949

By Victor C. Bryan

"One of the more challenging issues facing operators of U.S. mines and quarries is blasting in an environmentally acceptable way. It is quite important that industry management understand and apply guidance, discipline, and control in the exercise of blasting operations. This presentation is a discussion of problems related to that environment away from the blasthole that may or may not be adversely affected by blasting and the steps management may consider in resolving resultant problems. In any case, one of the main concerns that will continuously be brought up is thatmanagement procedures inherent to good blasting is a uxporate responsibility of the mine or quarry business entity; and can not be delegated to the explosive manufacturer or supplier. This management attitude, based on education, training, and the comprehension that the process of production begins with drilling and blasting and consumes a significant amount of overall production costs."

Jan 1, 1995