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By S. Roy

Soft laminated iron ore (SLO) having a higher hematite content and Martite goethite iron ore (MGO) having a higher goethite content were subjected to detailed characterization and beneficiation. The present research was designed to investigate if these abundant, low-grade ores can be enriched adequately using standard industry techniques. No significant enrichment of the ores using jigging operation on the coarse (-3,200 +595 mm) size fraction could be achieved. Good liberation was only attained in the 150 to 300 mm particle size range in both cases. Desliming enriches the ground ores significantly. The effect of the feed size on the separation efficiencies of the ground ores were studied using flowing-film concentration on a Wilfley table. Better enrichment is obtained in the case of 150-mm sized feed by tabling. The grade of SLO is improved from 56.14% to 66.51% Fe, while the Fe content of MGO is enriched from 55.16% to 65.83%. Substantial rejection of alumina and silica is also achieved. Due to the friable nature of MGO and the higher goethite content in it, the loss of Fe in the form of ultrafines is greater in this case compared to that of SLO.

Jan 1, 2009

By Raja V. Ramani

The importance of adequate mine ventilation for good health and safety conditions has been recognized since miners first ventured underground. All over the world, governmental actions on mine health and safety are directly connected with mine atmospheric environments, their assessment and control. These governmental actions have been, and continue to be, motivated by the repeated experience that potential threats from inadequate control can evolve, either suddenly or in the long-term, into unpleasant reality, with catastrophic health and safety consequences. These governmental actions are also an indication of the remarkable professional progress being made in the field of mine ventilation. Surely, no developed country allows underground mines to operate without strong measures for the control of ventilation under legislation specific to the mining industry. In the United States, the federal government's responsibility for mine safety has evolved over the years through a series of legislative actions beginning in 1865 and continuing through 1910, 1941, 1947 and 1952. The passage of the Federal Metal and Nonmetallic Mine Safety Act of 1966 (the 1966 Metal Act), the Federal Coal Mine Health and Safety Act of 1969 (the 1969 Coal Act) and the Federal Mine Safety and Health Amendments Act of 1977 (the 1977 Mine Act) are the most important milestones in this long legislative history. The 1977 Mine Act adopted many of the stronger features of the Occupational Health and Safety Act of 1970, perhaps the most significant piece of legislation on workers' occupational health and safety in US history. It is worthwhile to ask, "How far has the United States come in mine ventilation since the enactment of the 1969 Coal Mine Health and Safety Act?" This Act and its associated regulations defined in great specificity many standards for healthful and safe operation of a mine and, in some cases, what constitutes good ventilation practice. Since 1969, the frequency and severity of disaster-type events in US coal mines has decreased markedly. A primary reason for this achievement is the strength of the Coal Mine Health and Safety Act's regulatory features in such areas as methane concentration control, dust control, intrinsic safety and explosion-proof enclosures, minimum air quantity and quality standards and air distribution and escapeway provisions. These requirements greatly influenced mine ventilation planning, engineering and practice, leading to increasingly safe working conditions.

Jan 1, 1993

By F. Sanchez, A. Mejias, C. Frias, G. Diaz

"Crude zinc oxides are the major source of secondary zinc and are produced from fuming processes like Waelz kilns. The impurities of crude zinc oxides make difficult their processing in primary zinc refineries due to mainly high chloride tenor. Washing with sodium carbonate is a costly operation and chloride removal efficiency is not good enough, so further purification steps are required. The crude zinc oxides are easily treated using ZINCEX™ technology based on leaching, solvent extraction, and electrowinning. The ZINCEX™ process is commercially available and is designed to be a perfect barrier for metallic impurities and halogens, allowing selective zinc extraction in mixed chloride and sulfate leaching solutions. Other valuable components as lead and silver can be efficiently recovered from the leaching residue using PLINT technology in chloride media. Silver is recovered as silver cement and lead is precipitated as pure lead oxide or carbonate, which can be smelted at low temperature.IntroductionZinc is a fully recyclable metal and at present approximately 70% of the zinc produced worldwide comes from primary zinc while 30% originates from secondary materials. Nowadays, the zinc recycling rate is continuously increasing mainly through galvanized steel scrap processing, and crude zinc oxides are the major source of secondary zinc [1]. Secondary zinc oxides are obtained from fuming processes like W aelz Kiln, Rotary Hearth Furnace or Primus Furnace. Waelz is the dominant technology accounting for 80% of total crude zinc oxides production worldwide. In the Waelz process, steel dust is mixed with solid fuel reductant (coke breeze) and pelletized. It is then fed to the kiln and heated to a reaction temperature of l ,200°C. In such conditions, zinc, lead, and other non-ferrous metals are vaporized into the flue gas together with chlorides and alkaline metals. Mixed oxides are drawn from the kiln with the process gases and separated to produce typical crude zinc oxides [2]."

Jan 1, 2011

By Mohamed Gamal, Bill Zietlow

"In oil fields that have been depleted with conventional surface oil wells but still contain significant reserves, an extraction alternative that has been constructed recently consists of a drilling gallery below the oil-bearing formation at the bottom of a 1,200-ft deep shaft where upward sloping wells are being drilled to allow oil collection by gravity. The gallery is 92-ft diameter with a flat ceiling supported by rock bolts and shotcrete structurally connected to the shaft liner, which doubles as a large tension support element. A special excavation sequence was implemented for the gallery to maximize arching in the stress above the large diameter gallery. The gallery was located in competent sandstone, constructed with sequential excavation methods, and designed with a 3D finite element model. Special consideration was given to optimizing the gallery location to take advantage of the geology for construction and support while giving good positioning to the well drilling equipment. BACKGROUND Brierley Associates was contracted to provide both design and construction management services for an approximately 1,165-ft deep, 18-ft excavated diameter vertical shaft that opens to a 92-ft diameter flat roof gallery. The geotechnical data for the site was based on information available from literature and from data obtained during core drilling and from in-situ testing in a 1250-ft deep borehole. Wire line coring was conducted using a HQ, 10-ft long core barrel with a mud-rotary drilling method through sedimentary bedrock. The geometry of the shaft and the bottom gallery is shown in Figure 1(a). GEOLOGIC SETTING AND STRUCTURAL GEOLOGY The stratigraphy at the site includes a series of interbedded marine limestone, shale, claystone, siltstone, sandstone, and chert units. Limestone and shale are the predominant lithologies in the upper approximately 675 ft, while the lower portion contains five distinct sandstone units and more abundant shale, claystone, siltstone, and coal than the upper zone. A cherty sandstone at a depth of 1,130 below ground surface (bgs) was encountered. At a depth of about 1,000 ft to 1,116 ft bgs, a non-marine sandstone unit was encountered. This sandstone is the hydrocarbon bearing layer. Joints and fractures observed in the limestone had dips ranging from 0 to 90 deg. from horizontal with joint and fracture surfaces that ranged from planar to irregular and smooth to rough. Several, near vertical shear planes with slickensides were observed with surfaces that were generally smooth and planar. RQD values for the limestone ranged from 0 to 100 percent but in general were good to excellent."

Jan 1, 2016

By H. H. Gardner

Introduction The Greenhill mine of West Canadian Collieries, Limited, is on the Alberta side of the Crowsnest pass, twelve miles from the Alberta British Columbia boundary-line. Here, five coal seams of Lower Cretaceous age are found in the Kootenay formation. They outcrop on the north and south slopes of the valley, with strike approximately N.30°W., paralleling the main range of the Rocky mountains, and dip about 40 deg. westward. Of the five seams, only two, designated No. 1 and No. 2, have been worked to date. On the West Canadian Collieries property, No. 1 seam ranges in thickness from thirty feet to nil. Generally, it has a hard, strong conglomerate roof. No. 2 seam is separated from No. 1 by forty-five feet of shales and sandstones. It has a thickness of eight to thirty feet.

Jan 1, 1947

By I. J. Demer, M. L. Holzworth, J. C. Kremer, P. A. Beck

For alloys which are in practice heat treated to obtain increased strength, such as steels, duralumin, copper-beryllium, and others, the treatment usually involves heating to a relatively high temperature. At such temperatures the grain size of the product is largely determined by grain growth. Even in metals and alloys annealed merely to relieve work hardening, recrystal-lization is generally followed by a certain amount of grain growth. Thus, effective grain size control, which is often of great practical importance in manufacturing processes, depends on the grain growth behavior of the material used. Despite its importance, grain growth has been the subject of few investigations of a fundamental nature. The term "grain growth" has been used to designate a group of related, but distinctly different, phenomena. The two most important and best known of this group are illustrated by the following example. Curve a in Fig I shows the increase of the average grain size of a copper-beryllium alloy, containing 2 pct Be and 0.15 pct Co, with increasing annealing temperature. The time of annealing was 2 hr. The grain size was quite uniform in all specimens. The results of a similar experiment with an alloy containing 2 pct Be and 0.31 pct Co are shown by curve b It is seen that for any annealing temperature below T, the grain size was smaller than. in the previous case. Grain growth became slower with the higher Co content. This "inhibiting" effect of the higher Co addition was associated with the appearance in the microstructure of fine, light blue particles of the CoBe phase. Up to temperature T, the structure of the inhibited alloy (curve b) was just as uniform as the structures represented by curve a. However, after annealing at T or at higher temperatures, the inhibited alloy showed some extremely large grains (much larger than the grain sizes developed by the uninhibited alloy with low Co content) mixed with the small grains according to curve b. The presence of these mixed or "duplex" structures is indicated in Fig I by the vertical lines branching off curve b. The type of grain growth occurring in uninhibited Cu-Be alloys (curve a) has been most frequently and best investigated in brass. This type has been designated as "normal grain growth,'' while the grain growth phenomena occurring in inhibited materials were, at times, referred to as "abnormal grain growth." However, since the latter term has been applied occasionally to the phenomenon of critical recrystallization, which also results in large grains although by an entirely different mechanism, in the present paper a different nomenclature has been adopted in order to avoid confusion. Typical of the grain growth in uninhibited metals and alloys is the continuous

Jan 1, 1949

By S. I. Anufrieva, N. A. Permyakova, E. G. Likhnikeevich

"Russia’s rare metal reserves are composed of compositionally and structurally complex ores and are characterized by an increased content of natural radionuclides due to their geochemical similarity with rare metals. For instance, concentrates of Zashikhinsky daeposit are characterized by an increased content of uranium (0,06%) and thorium (0,59%); Beloziminsky deposit holds pyrochlore-apatite-magnetite-carbonate ores characterized by increased radioactivity (130 mkR/h) and containing 0,0016-0,0025% of uranium; Etykinsky deposit is characterized by columbite-pyrochlore-microlith mineralization with an average ore grade of 0,013% of uranium and 0,0020% of thorium; eudialyte concentrate of Lovozero deposit (Alluaiv area) belongs to Class II of mineral reserves. Industrial development of these mineral reserves involves the need to comply with environmental standards, public health requirements applicable to finished core and by-products, to take into account the amount and class of the generated radioactive waste, the possibility of disposal or recycling of the radioactive production waste. Concentration processes of radioactive rare metal feeds most often lead to a concentration of natural radionuclides and their accumulation in concentrates. Comprehensive hydrometallurgical processes are currently under development for such concentrates, aimed at producing salable products compliant with the radiation safety standards. The choice of the hydrometallurgical processing method for radioactive rare metal concentrates is based on the mineralogical component of the concentrate, textural and structural features, the distribution of valuable components and impurities, and the content of radionuclides. A systemic approach to the selection of processing methods, in particular integrating several methods, is an effective solution. Methods may not only be combined, but also inextricably linked with each other. Hydrometallurgical processing methods include leaching by acidic and alkaline agents; sulfatization for selectively decomposing the minerals and moving the bulk of U and Th into solution; fluorine extraction process. Methods of precipitation and co-precipitation, extraction (by liquid and solid extractants), sorption, and ion exchange are used to decontaminate the solutions by removing thorium, mezathorium, uranium, and their radioactive decay products. Agents used in hydrometallurgical processing of radioactive rare metal ores include sulfuric, nitric, hydrochloric, hydrofluoric acid, alkali (NaOH, KOH), sorbents (for example, AB-17) for sorption of uranium and extractants (mono- and bidentate organophosphorus compounds, diamides, etc.) for the extraction separation of rare, rare-earth, and radioactive elements."

Jan 1, 2018

By J. S. Bowles

THE martensite transformation in lithium, dis- covered by Barrett,' has been studied extensively by X-ray techniques by Barrett and Trautz,² and Barrett and Clifton.V he present paper reports the results of an investigation into the metallographic characteristics of lithium martensite. Such an investigation has not been carried out before. The spontaneous transformation in lithium consists of a change from a body-centered cubic to a close-packed hexagonal structure with the hexagonal layers in imperfect stacking sequence." As far as is known at present, this transformation can be regarded as being crystallographically equivalent to the body-centered cubic to close-packed hexagonal transformation that occurs in zirconium,5 although stacking errors have not been reported in zirconium. From a study of the orientation relationships in zirconium, Burgers5 as proposed that the martensite transformation, b.c.c. to c.p.h., occurs by a heterogeneous shear on the system (112) [111]. The crystal-lographic principle underlying this proposal is that the configuration of atoms in the (112) plane of a b.c.c. structure is exactly the same as that in the (1010) plane of a close-packed hexagonal structure based on the same atomic radius. The pattern in 2v2 both these planes is a rectangle d X 2v2d where v3 d is the atomic diameter. Thus a close-packed hexagonal structure can be built up from a body-centered cubic structure by displacing the (112) planes relative to each other.* This mechanism leads to orientations that can be described by the relations: (110)b.c.e. // (0001)c,p.h.; [111]b.c.c. // [1120]c.p.h Observations confirm these relations. In zirconium, Burgers' measurements indicated an angle of 0" to 2" between the close-packed directions, while Barrett's measurements on lithium indicated an angle of 3". According to the Burgers' mechanism, the martensite habit plane for this transformation would be expected to be the (112)b.c.c. plane, for this plane would not be distorted by the transformation. One of the purposes of this investigation was to find out whether the observed lithium habit plane agrees with this prediction of the Burgers' mechanism. Experimental Procedure Materials: The lithium was from the same purified ingot used by Barrett and Trautz.² The Bridgman technique was used to produce single crystals. To maintain a temperature gradient in the melt, during the production of these crystals, it was necessary to use a steel mould with a wall thickness of only 0.015 in. Metallographic Techniques: Lithium specimens could be given an excellent metallographic polish by swabbing them gently with cold methyl or ethyl alcohol.? The best results were obtained with methyl alcohol saturated with the reaction product, lithium alcoholate. With higher alcohols the reaction became progressively slower and the attack became an etch pit attack rather than a polish attack. Butyl and amyl alcohols were used for macroetching. After polishing, it was necessary to remove all traces of alcohol from the specimens; otherwise, on subsequent quenching in liquid nitrogen, the alcohol froze to a glassy film. The alcohol was removed with dry benzene. The benzene in turn had to be removed before quenching, but since it does not react with lithium it could be allowed to evaporate. The specimens could then be quickly quenched before they began to tarnish. This operation could be carried out in air on all but excessively humid days when it was advisable to use an atmosphere of dry nitrogen or argon. For examinations at room temperature, the specimens could be transferred directly from the benzene bath into a bath of mineral oil. In mineral oil the specimens oxidized slowly by the diffusion of oxygen through the oil but the structure remained visible for about an hour. Lithium Martensite: Specimens prepared in the manner described above transformed spontaneously to martensite with an audible click when quenched into liquid nitrogen; i.e., M, was above the boiling point of nitrogen (77°K). The disparity between this result and the M, temperature of 71°K, found by Barrett and Trautz, is probably to be attributed to the large grain size and freedom from mechanical deformation of the specimens used in the present work. The relief effects produced by the transformation did not disappear when specimens were quenched from liquid nitrogen into mineral oil at room temperature. This permitted the microstructures to be studied at room temperature where, of course, the martensitic phase was no longer present. Typical micrographs of lithium "martensite" made at room temperature are reproduced in figs. 1, 2, and 3. As anticipated by Barrett and Trautz, the microstruc-

Jan 1, 1952

By W. M. Fox, D. P. Detwiler

IN the course of research on semiconducting inter-metallic compounds, it became necessary to obtain gallium metal of greater purity that that available commercially. Several methods were considered for further purification, including acid leaching,' fractional crystallization,' and zone-refining.3-5 The method of fractional crystallization was discarded as being equivalent to zone-refining in purification but inefficient in material and time. Both acid leaching and zone-refining were tried, and the method finally adopted is a combination of the two. The acid leaching technique has been reported' to produce gallium in which no impurities are detectable spectroscopically. Although this method is very effective in removing oxides and surface contaminants, semiconducting material made of gallium subjected only to leaching indicated little reduction in the concentration of metallic impurities. Zone-refining, however, appears very effective in removing trace metallic impurities, but comparatively ineffective in removing the surface oxide film. Consequently, the method evolved consists of acid leaching to thoroughly clean the surface, followed by zone-refining to remove metallic impurities. The low melting point and relatively high thermal conductivity of gallium introduce some difficulty in maintaining frozen and molten zones in zone-refining. To accomplish this, it is found necessary to reduce the effective ambient temperature by circulating ice water in coils about the regions that are to be kept frozen, while heat is supplied to the molten regions by resistance coils. The power supplied to the heating coils is regulated by a constant-voltage transformer and a variable autotransformer. Both heating and cooling coils are mounted on a transite base. The gallium ingot is held in a closed pyrex tube sliding inside the heating and cooling coils, the reciprocating method of Tanenbaum et al. being employed to move the molten zones through the ingot at a rate of 2 in. per hr. This apparatus is shown in Fig. 1. The results of a spectroscopic analysis f a zone-refined ingot, as well as of the material as-received and after acid leaching, are shown in Table I. The ingot was 32 cm in length, and received 37 molten-zone passes, the molten zone being about 4 cm long. The only impurity found was lead, the following elements being reported also as checked but not found in the pure material: Al, Sb, As, Ba, Be, Bi, B, Cd, Ca, Cr, Co, Cb, Cu, Ge, Au, Fe, Mg, Mn, Mo, Ni, Pt, Si, Ag, Na, Sr, Sn, Te, Ti, W, V, Zn, and Zr. There thus appears no indication of pickup of Al, Mg, or Si from the pyrex boat as reported by Zimmerman' in his fractional crystallization. Thus it appears that definite removal of lead from gallium occurs during the zone-refining process. It also may be concluded that a more sensitive analytical procedure than spectroscopy is required to evaluate quantitatively the purity of zone-refined metals. One such procedure which is proposed for use in the near future is the measurement of very low temperature resistivity. Although this will not identify the impurities present, it offers a very sensitive check of total impurity. Acknowledgment This work was supported by the Air Research and Development Command, United States Air Force.

Jan 1, 1956

By María Rocha, Benjamín Cebrián, Roberto Laredo

"Ring blasting designs have to achieve different goals in order to become efficient whether is done in up hole or downhole fashion. Ore recovery/dilution control, fragmentation and drift integrity all have to be taken into account when selecting parameters such as burden, spacing, linear explosive density and stemming. Blast energy simulation allows identifying contours of rock breakage and fragmentation, thuschoosing a combination of spacing at the end of holes and appropriate burden. Also, simulations are keyto concentrate energy levels on the mid part of the ring while making sure there is not too high of energy concentration around the drift, which integrity is needed for a safe ore mucking."

Jan 1, 2017

By G. D. Hood

The U.S. Bureau of Mines investigated rapid froth flotation through the use of more efficient bubble-particle collisions that improved the overall flotation kinetics. An in-line static mixer efficiently mixed the air bubbles, water, and ore, rapidly attaching the hydrophobic mineral to the bubble surface. As the mixture entered the flotation chamber, the hydrophobic mineral was already attached to the bubbles and was quickly floated away from the remaining ore pulp. A rougher concentrate containing 4.5 pct copper was obtained from a western porphyry copper ore containing 0.67 pct copper. Over 99 pct copper was recovered from the ore at a rate 7 times faster than conventional flotation.

Jan 1, 1991

By A. Robles-Vega

In recent years, tellurium has been extensively used in the manufacture of semiconductor materials. For this type of application, high-purity tellurium is required. Selenium, lead and silicon are usually the main impurities in tellurium. During the electrolytic refining of copper, tellurium gold and silver are collected in the anode slimes. A pyrometallurgical treatment is used to recover gold and silver from the decopperized anode slimes whereas tellurium is oxidized and skimmed off from the refining furnace as a Na2CO3-based slag. In the slag, tellurium is present as sodium tellurite (Na2TeO3), which is further water-leached from the slag. The first step in the conventional process for tellurium recovery consists of the precipitation of the tellurium contained in the leaching solution as tellurium dioxide (TeO2). The solid TeO2 is then dissolved under acidic conditions for its further reduction with sulfur dioxide gas (SO2). In this paper, an alternative route for tellurium production is presented in which a sodium tellurate [Na2TeO4] intermediate is obtained by oxidation of the sodium tellurite in an alkaline solution following the water leaching step. Sodium tellurate is then dissolved in acid media and high-purity tellurium is obtained by reduction with SO2 gas. Experimental tests under laboratory conditions indicate that the novel process yields higher precipitation selectivity for tellurium than the conventional process. A comparison of its efficiency concerning impurities co-precipitation with respect to the conventional process is discussed.

Jan 1, 2009

By Mountiney B

The development and operation of three large open cut brown coal mines in the Latrobe Valley, Victoria, Australia, requires a wide range of drilling techniques for coal resource evaluation and stratigraphic defi- nition, material property identification, open cut dewatering, and instal- lation of groundwater monitoring bores. This paper describes in detail the range of drilling techniques, equip- ment used and associated problems with drilling, in a deep sedimentary basin containing several major brown coal seams, multiple aquifer sys- tems of varying pressures and thin layers of hard materials including pyrite, siderite and basalt. Methods of rotary drilling include wireline core drilling, conventional core drilling, conventional flush drilling, diamond core drilling, reverse circulation air lift drilling and bucket auger drilling. Cable tool drilling is also used for strata definition and aquifer sampling.

Jan 1, 1989

By J Ding, H J Peng, S B. Zhu, L Hou, J R. Zhang, S Y. Wu

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Numerous Fe-Cu-Au-rare earth element (REE) deposits have been identified within the Palaeoproterozoic Dongchuan Group of the Kangdian region of SW China. Geochronologic and geochemical data of the dolerite dykes and other volcanic rocks reveal extensional activity occurred about 1.7 Ga called ‘Kunyang Rifting’. The Kangdian region underwent variable degrees of extension, meaning that breakup in the central part of this region occurred earlier than in the north. Research on microphysiography, isotopic geochemistry and inclusions of the Yinachang typical Fe-Cu-Au-REE deposits suggest that the dominant mineralisation fluid is high-temperature, high-salinity magma fluid, containing alkalic components, volatile phase and Cu-Au. Metasomatism and mixing between this magmatic fluid and carbonaceous wall rock and meteoric water caused the precipitation of Fe, REEs and Cu-Au. A chalcopyrite Re-Os age from the Yinachang deposit obtained during this study is some 50–100 million years younger than the timing of emplacement of the deeply sourced Haizi and Dongchuan dolerites. The Yinachang deposit is a typical iron oxide-copper-gold (IOCG)-type deposit, and the presence of this and other deposits in the Kangdian region indicates that the region hosts an intraplate extension-related IOCG system within the western edge of the Yangtze Block, China.CITATION:Hou, L, Ding, J, Zhang, J R, Zhu, S B, Wu, S Y and Peng, H J, 2015. Proterozoic iron oxide-copper-gold mineralisation in the Kangdian Region, south-west Yangtze block, China – a case study on the Yinachang Fe-Cu-Au-rare earth element deposit , in Proceedings PACRIM 2015 Congress, pp 255–264 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By Robert Glass Cleland

FROM the time of its organization down to 1917, a period of more than eighty years, Phelps, Dodge & Co. was seldom involved in what could be called a major labor difficulty. Behind this remarkable record lay both a philosophy and its practical application. The philosophy was an attitude toward society called the Golden Rule. That philosophy had been a living principle in the lives of the founders of the company, Anson Phelps, Daniel James, and William E. Dodge. Their successors, William E. Dodge, Jr., and Daniel Willis James, accepted the same philosophy. Dr. James Douglas governed his life by it. All of these men and their families had given tangible expression to that conviction in benefactions of great magnitude and variety-churches, hospitals, educational institutions, libraries, missionary undertakings, and other organizations for human betterment, such as the Young Men's and Young Women's Christian Associations, and the development of model communities about their mills and factories. According to the best standards of their generation, they had sought to improve the condition of labor,

Jan 1, 1952

By J. van der Merwe, D. Tharandt

The corrosion behaviour of 304L stainless steel laser-cladded with various amounts of ruthenium (Ru) was evaluated in solutions of sulphuric acid and sulphuric acid plus sodium chloride at 25°C and 45°C by open-circuit potential and cyclic potentiodynamic polarization tests. In general, the addition of Ru to the stainless steel increased its corrosion resistance in 1 M H2SO4, as well as in 1 M H2SO4 plus 1 wt% NaCl. This was observed for a number of parameters such as corrosion rate, corrosion potential, open-circuit potential, and current density. However, increasing the amount of Ru added beyond a certain level did not result in further improvement in corrosion protection. For each environment there is an optimal Ru concentration for the best corrosion protection. For example, in 1 M H2SO4 at 25°C, 2.44 wt% Ru shows the least active surface in terms of corrosion. Further research into ruthenium coatings on stainless steels is recommended.

Jan 1, 2015

By R. J. Brison, W. C. Bleimeister

The International Salt Company has long been interested in finding an efficient process for the removal of impurities from rock salt, and particularly from the rock salt produced at the Detroit mine. Methods which have been used previously at the Detroit mine included both hand sorting and differential crushing in a Bradford breaker with rejection of the oversize. Neither of these methods was adequately effective. The development of a new process for removal of impurities from rock salt has been described in the preceding article." Basically, the process consists of exposure of crude rock salt to radiant heating which selectively heats the impure particles. Subsequently the heated particles are removed by adhesion to a heat sensitive-coating on a conveyor belt. This method was found to be effective in improving both the quality and appearance of rock salt by the rejection of the dark, impure particles.

Jan 8, 1960

By C. H. Bucknam

Classical acid-base accounting using modified Sobek titration methods has resulted in interpretation of results for materials with neutralization potential (NP) less than 20 tons of CaCO3/1000 tons of material (2% CaCO3) as "uncertain" due to lack of sensitivity within that content range. Standardization of a "fizzless" acid neutralization potential (ANP) method was undertaken in the American Society for Testing and Materials (ASTM) International using two ranges of sulfuric acid additions based on reaction pH and carbonate carbon estimates rather than subjective fizz testing as well as hydrogen peroxide additions to correct for mineral acidity. The method is identified as the acid neutralization potential acidity (ANPA) titration method. During interlaboratory testing a positive bias was discovered within the "uncertain" range which was further investigated and resolved by increasing the test sample weight from one to five grams for samples needing improved accuracy in materials with ANP <2% CaCO3. Test results from the interlaboratory testing of the low range method is presented and compared with the results from the original ANPA method in the paper.

Feb 27, 2013

By E. Dernedde

Cell rooms of aluminium smelters have large openings in the sidewalls and in the roof. These openings provide a high ventilation rate, which removes heat and contaminants emitted by the reduction cells and thereby ensures acceptable working conditions inside the cell room. However the large openings make the airflows through the smelter building sensitive to the wind. In this study equations for the airflow through the openings of a smelter building exposed to crosswinds were developed and verified against plant measurements. The equations were then used to estimate the airflows through a two-storeyed smelter building containing VS Soderberg cells. Wind protection by wind-covers over the sidewall openings and by upwind buildings made the airflows through the building less sensitive to the wind. Physical and mathematical modelling showed that working conditions inside the wind-protected cell room would be acceptable for crosswinds at speeds up to 16 km/h. These predictions were confirmed by measurements taken in a VS Soderberg smelter.

Jan 1, 2007

By Chas. F. Jackson

The annual reports of the supervising engineers of the nine sections comprising the Mining Division are assembled in tie following pages and constitute the annual report of the division. In planning activities, the aim is to adapt them to changes in conditions, in the needs of the mining industries, and in the public interest; those current activities that contribute most to problem of present concern are emphasized, investigations of less immediate importance being recessed, if necessary.

Jan 1, 1940