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By Michael S. Moats, Scott C. Campin, J. Brent Hiskey

"Electrochemical techniques are a valuable means of analyzing the passivation of commercial copper anodes. Electrochemical impedance spectroscopy (EIS) provides information concerning transport and reaction phenomena occurring at an electrode surface. Commercial. copper anodes of varying compositions have been examined using EIS. Experiments were conducted in a flat cell with an electrolyte of 40 gil Cu2 + and 160 gil H2S04 maintained at 65 DC. Impedance spectra were obtained at the potentials characteristic of the open circuit voltage and passive region for each anode. The spectra of the passivating films exhibited a flattened resistive/capacitive loop at middle to high frequencies and an inductive loop at low frequencies. An equivalent· circuit utilizing an inductor-resistor series in parallel with the double layer capacitance and charge transfer resistance was adequate in modeling the impedance data. The influence of anodes impurities on the components of the equivalent circuit is discussed and correlated with a hi-layer passivation model.IntroductionPassivation of copper anodes during industrial electrorefining has received considerable attention in the past few decades. Great strides have been made in understanding the roles of anode impurities [1-25], electrolysis parameters [20,26], and electrolyte chemistries [20,26]. Even so, passivation still occurs even in the most modem of refineries. The exact cause of passivation is not fully understood. It is known that the anode surface becomes covered by a passivating film. This film has been proposed to be CuS04'&5H20, Cu20, or mixed oxides. The localized concentrations of Ft, Cu+, and Cu2+ ions determines which phase is more favorable. The presence of these ions is controlled by the reaction kinetics and diffusion of species through the slimes layer.Reaction kinetics between Cu, Cu +, and Cu2+ are based on the dissolution mechanism of copper. There exists four different models to describe the dissolution of pure copper. The classical model of Mattsson and Bockris [27] involves two single electron transfers with the cuprous-cupric reaction being the rate detennining step. More recently, Wong, Collier, and MacFarlane [28] used ac impedance to elucidate a more complex mechanism involving the affect of pH and anions. Their findings indicate that the formation of cuprous ions in solution, Cu(I)so~ is favored over Cu(1I) ions adsorbed to the electrode surface in the presence of sulfate and as pH increases from pH 1 to pH 5."

Jan 1, 1997

By K A Plumb

New structural studies in the Walker Fault Zone of eastern Arnhem Land are integrated with basin-wide reconnaissance observations, made to refine models for the structural evolution of the McArthur Basin and provide new insights into the nature of metal logenetical ly important pre-inversion phases of the basin's evolution. At least five principal events may be identified during the Proterozoic: The Tawallah Group and equivalents were deposited throughout the McArthur Basin during an extensional event. Rifting of an incipient Batten Trough occurred at this time, in a terrain characterised by orthogonal, linked extensional faults. Uplift and erosion of the Tawallah Group accompanied continuing extension and was penecontemporaneous with continuing deposition of the overlying Parsons Range Group, within a precursor to the Walker Trough. Dt (of the Walker Fault Zone) relates to a new rifting event, penecontemporaneous with deposition of the McArthur Group and its equivalents in the Walker and Batten Troughs. This rifting accompanied dextral strike-slip faulting along northerly-trending bounding faults, as a result of northwesterly-directed oblique extension, leading to pull-apart basins. D2 inversion of the Batten and Walker Fault Zones pre-dates deposition of the Roper Group. In the proposed model WNW-ESE directed shortening (D2.), accompanied by folding and thrusting, and by local development of cleavage in the Walker Fault Zone, is seen to be followed by northerly-trending sinistral faulting (D2b), about a SE to ESE-directed compression. D3 is basin-wide and post-dates the Roper Group. It is characterised by conjugate faulting and folding about ENE to NE-directed compression. The latest Proterozoic event to be identified (D4) comprises widespread north-trending strike-slip dextral faulting of Roper Group, coupled with N-S directed thrusting across the Urapunga Fault Zone and Murphy Inlier This is accompanied by late dextral reactivation of NNW to NNE-trending faults in the Walker and Batten Fault Zones.

Jan 1, 1994

By E. A. Holbrook

IN my thirty years of educational work in the mineral industries and other engineering fields, this past year has been the most unusual and difficult one. Contact with educators from other schools leads to the conclusion that the same situation is countrywide. The first of our difficulties came from the shortsighted policy of the Selective Service in taking out of the colleges, continuously, all engineering students as soon as they had reached their eighteenth birthday. England, Canada, and Russia, too, even in the midst of their critical war situations, had the good sense to keep their young engineering brains in college, for they realized the vital necessity of a steady flow of engineering graduates into the war industries and into the postwar peace industries. As a result of the policy of our Government, our engineering schools were left with only a handful of students who had been rejected for military service. Our colleges, faced with the prospect of several years without students and without income, hastened to give leave of absence to many of their competent teachers who quickly were taken into industry and in many instances are now being retained there at higher salaries than colleges are accustomed or able to pay their teaching personnel. We are finding it most difficult to induce these men to return to their former engineering teaching work. In my judgment, it will take us three or four years to restore our engineering departments to their former level in quality of instruction.

Jan 1, 1946

By Jianjun Tang, Wenjuan Bai

This paper presents a new method of formulation design for multi-component composite explosives. Based on the thermochemistry of the detonation process, the mathematic model of formulation design is established by optimization mathematics. Using the heat of detonation as target functions and taking the constraint conditions such as oxygen balance and costs etc into consideration, this model can provide an optimal solution quickly by means of personal computer. Using this method, the calculation and the simulation tests for a series of constituent sets and various constraint conditions can be conducted easily. In this way, the optimal formulation for the explosive can be determined, on the basis of the maximum heat of detonation and the lower cost.

Jan 1, 1997

By W. E. Lindquist

Roasting of refractory gold ores has the primary goal of oxidizing sulfides and organics to improve gold recoveries prior to leaching. Commercial installations currently utilize bubbling and circulating fluidized beds. The principle of flash roasting is aimed at a more cost effective method of whole ore roasting for large throughput applications. Results of pilot plant testing and scale up to commercial design will be discussed in further detail in this paper.

Jan 1, 1993

By Humberto Napoli BELLEI

O Sol é a principal fonte de energia sustentável com enorme potencial na geração de energia elétrica. O Brasil como outros países do mundo estão começando a construção de fazendas solares. Atualmente as especificações das estruturas para construção das estruturas dos painéis utilizados nessas fazendas tem sido de aços pós galvanizados justificado pela questão de tempo de garantia, principalmente, devido a presença de furos e bordas que ficariam protegidos contra a corrosão pela grande quantidade de revestimento utilizado. Nesse trabalho serão apresentados resultados de um aço pré-galvanizado que se mostrou seguro e confiável na proteção contra a corrosão dos furos e bordas dos painéis. O estudo teve como base as informações obtidas após o aço ter sido testado no ensaio em câmara de névoa salina e de dados já conhecidos em ensaios de campo.

Oct 30, 2017

By Eric E. Cather

In 1984 and 1986, at the request of the U.S. Forest Service, the U.S. Bureau of Mines conducted a mineral appraisal of the 315,000-acre Lemhi Range study area. This area is located in Lemhi and Custer Counties, about 25 mi south of Salmon, Idaho, and is in the Northern Rocky Mountain physiographic province, Topography is generally rugged with elevations ranging from 5,600 ft to about 11,350 ft above sea level. Since the 1880's, approximately 500 mining claims have been located within the study area; about 400 were current at the time of this investigation. Also, part or all of 12 patented mining claims are in the study area. During Bureau field work, forty-four mineralized sites were examined. The sites had been explored by 80 adits, 14 shafts, and about 140 pits and trenches. At least five properties in the study area have had significant production; the adjacent Mohawk, Grace Phelan, and Snowbird claims had a combined total of 136,000 oz of silver and 67,000 lb of lead; production at the Brown Bull was about 14,800 oz of silver and 115,000 lb of lead; the Portland mine yielded an unrecorded amount of silver. The Hilltop mine, located a few hundred feet outside the study area, produced 125,000 oz of silver, 2.7 million lb of lead, 87,000 lb of zinc, and 62,000 lb of copper from mineralized zones that might extend into the study area. More than 10,000 lb of copper were produced at the Blue Jay mine from workings located about 1,000 ft outside the study area. The Bureau of Mines investigation did not reveal the presence of identified resources in the study area. However, several areas contain mineralized sites and are known occurrences. Some of these warrant additional work to further delineate the mineralization and possibly determine identified resources.

Jan 1, 1988

By Evan Boone, Peter Bellairs

A technical services visit was conducted to determine the initial parameters to successfully presplit several benches for an input crusher installation at the Wolffdene quarry. The paper details the preliminary design utilising both detonating cord only and specialised presplit product charges and compares these to the final designs utilised based on site experience. The role of accurate drilling, explosive loading and geology in obtaining successful cost effective presplits is highlighted.

Jan 1, 1998

By Thomas C. Atchison

The experimental work described in this report is part of a continuing study by the Federal Bureau of Mines of the fundamental physical processes involved in breaking rock with explosives. Six explosives were tested for their strain-producing abilities in a dolomitic marble. The explosives selected for testing had a tenfold variation in detonation pressure and a fivefold variation in characteristic impedance (product of loading density and rate of detonation). Strain pulses produced by the detonation of small charges of the explosives were recorded at distances of 5 to 130 feet. Peak strain, ?, was found to decrease with distance, R, in accordance with an exponential propagation law previously determined for other rock types, namely ? = (K/R)e ?aR The absorption constant, a, did not vary significantly with the explosive and was of the same order of magnitude as that for other rock types. The different explosives produced a fivefold variation in the value of the intercept constant, K.

Jan 1, 1961

By Toshia Suzuki, Keiji Kakudate, Yoshihiro Adachi

"A macro model for the steel usage pattern in Japan is proposed. The steels are classified into four types; converter steel for machinery and for construction and electric furnace (EF) steel for machinery and for construction. The steels are assumed to be discharged from the society in accordance with lifetime distributions of each usage. The amount of EF steel and the accumulation in society are calculated using a population balance model. The comparison with the calculated results and statistics ensures the validity of the model. Since the amount of EF steel for construction will increase and be oversupplied, EF steel will have to be used for machinery. The required and available amounts to supply EF steel for machinery are considered from the point of allowable· copper concentration for machinery use. Copper contaminates steel used for machinery during recycling process and contamination ratio is evaluated with the model. Copper concentration in EF steel is predicted for various scenarios.IntroductionThe amount of CO2 emission from Japanese steel industry is 48.0 million C-ton in 1990 and it occupies 15.1% of the total amount in Japan. In order to reduce the C02 emission and to save the natural resources, it is strongly required to promote the recycling of steel. However, the impurity contaminates steel in recycling process and lowers its quality. The copper concentration in EF steel is analyzed by Toi et al. using a macro model with the assumption that steel is discharged in proportion to the accumulation amount [1]. However the discharged amount of products is dependent on their age for service and usage pattern and not on the accumulation amount. In addition, the degree of copper contamination is different depending on the usage of steel. Therefore a precise model that contains the age for service within the society as a parameter and distinguishes the usage· of steel is necessary in order to clarify the problems in the recycling of steel."

Jan 1, 2000

By William Gleason

With its 2011 acquisition of rival equipment company Bucyrus International, Caterpillar added underground mining and large shovels to its line of products and further solidified its standing as the leading mining equipment manufacturer in the world with solutions for every aspect of mining. When Caterpillar spent $8.8 billion to acquire Bucyrus, the global mining business was flourishing, as mining companies around the world worked to keep up with demands for nearly every commodity. Flash forward to 2013, and the global mining landscape looks very different. Lower demand for raw material from China and India and falling commodity prices have forced most mining companies to pull back on their production. The reductions from the mining industry have hit equipment makers like Caterpillar and Komatsu hard. In October, Caterpillar reported that its quarterly earnings had fallen 44 percent. The changing conditions have also changed the narrative from Caterpillar and other equipment makers to customers from offering solutions to move the most tons per hour, to now offering solutions for the lowest cost per ton. In September, Caterpillar hosted some of its mining customers and the trade press at its Tinaja Hills Demonstration and Learning Center near Tucson, AZ to talk about its range of products, from its MineStar System designed to help increase efficiency through better equipment management and planning, all the way up to the massive Cat 7495 and 7495HF electric rope shovel lines acquired through the Bucyrus takeover

Dec 1, 2013

By R. H. Grau, S. B. Robertson, F. Garcia, A. C. Smith, T. P. Mucho

Researchers working for the National Institute for Occupational Safety and Health (NIOSH) at the Pittsburgh Research Center are developing ways to protect the health of miners. Part of that effort is improving the air quality in metal/nonmetal mines by developing proper ventilation techniques. The air quality of large opening nonmetal mines can be greatly improved by using engineering controls of contaminant prevention and proper ventilation techniques. Contaminant prevention includes methods to reduce contaminants from entering the mine air. Ventilation can be improved with appropriate fan selection and fan operation used in conjunction with air coursing using manmade and insitu rock stoppings.

By H. H. Heady

A naphtha obtained by destructive, recycle hydrogenation of crude shale oil, produced by gas-combustion retorting of Colorado oil shale, was found by the Bureau of Mines to contain 49.1 percent paraffins, 20.3 percent cycloparaffins, 7.8 percent olefins, and 22.8 percent aromatics. The naphtha contained only minor amounts of sulfur, nitrogen, and oxygen compounds. Compounds containing less than 5 carbon-atoms per molecule were removed by distillation before analysis. The paraffins where predominantly straight-chain compounds; n-Hexane was present in the largest quantity, and the other straight-chain paraffins decreased in amount as the molecular weight increased. The cycloparaffins, which contained both cyclopentanes and cyclohexanes, were evenly distributed throughout the boiling range. Although the naphtha had been produced by hydrogenation, it contained a small quantity of olefins. Straight-chain olefins with a terminal double bond comprised about two-thirds of these compounds. Among olefins with an internal double bond, those having trans configuration were present in three times the quantity of those in the cis form. In the aromatics all but one of the alkylbenzenes having nine or less carbon-atoms per molecule were identified; toluene was present in the greatest quantity. Only a few of the higher molecular-weight homologs were identified. The composition of the naphtha was computed from analyses of 105 narrow¬boiling distillation fractions. Volume, density, refractive indices, bromine number, and an ultraviolet spectrum were determined on each fraction. From these data the hydrocarbon-group composition of each fraction was estimated. A silica gel adsorption analysis was used to check the values of nearly one-third of the fraction calculated from physical-property data. Mass and infrared spectra were obtained on some fractions for identifying individual compounds or types of compounds, such as terminal olefins.

Jan 1, 1960

By Michael R. King

The application and use of steel fibre reinforced concrete in precast tunnel lining design is a growing trend due to its advantages in performance over plain concrete, and ease of manufacture compared to traditionally reinforced concrete. However, the design process and performance characteristics of the material are poorly served by current codes and standards. This paper provides some basic design guidance for segmental linings, and compares the material properties for the different material options. A typical example is considered to compare the possible results of lining arrangement and thicknesses for a plain, reinforced, and fibre reinforced design solution.

Jan 1, 2005

By R. J. Durrheim

The seismicity of the Witwatersrand Basin and Bushveld Complex has been analysed, revealing significant differences in source and damage mechanisms. A comparison of mining taking place at similar depths and extraction ratios indicates that the seismic energy release rate is considerably lower in the Bushveld Complex. Technologies introduced in the past decade to manage the risk of rockbursting are reviewed and assessed. These include geophysical methods to detect hazardous structures ahead of mining, new mining layouts and support systems, and the mechanization of in-stope processes. Despite important differences in geology, in situ stress, mining layouts and methods, there are many opportunities for the reciprocal transfer of knowledge, experience and technology between the gold and platinum mining sectors to improve the management of the rockburst risk.

Jan 1, 2005

By J. W. Parkinson

With most of the coal currently mined in the eastern U.S. already requiring cleaning to meet electric utility coal specifications, the question remains how medium- and high-sulfur coal producers will provide the even better quality coal expected to be demanded if pending acid rain legislation is enacted. One emerging approach is to crush the coal to liberate additional ash and sulfur so that better quality coal can be produced at equal yields. This paper discusses how to measure liberation. the premiums the utility market is willing to pay for lower sulfur coal, and a staged middlings crushing scheme that promises the benefits of total raw coal crushing but at lower costs. For some coals, cautious application of liberation concepts may be the only way to produce a product that can be quality and cost competitive in the future utility coal market.

Jan 1, 1988

At their last meeting, the Directors of the Institute passed the following resolution regarding Robert W. Hunt, who was president of the Institute in 1883 and 1906. This resolution was engrossed and presented to Captain Hunt at a dinner given to him in Chicago, December 9, on the occasion of his eightieth birthday. Resolution At that time it was announced that $5000 had been guaranteed as the nucleous of a fund, the income of which will be used for prizes to be awarded each year, under the supervision of the American Institute of Mining Engineers, for the best papers on iron and steel subjects. The Board of Directors of the American Institute of Mining Engineers extend to their distinguished colleague, Robert W. Hunt, a hearty greeting upon his eightieth birthday anniversary. They congratulate him upon his notable achievements as a pioneer in ,the manufacture of iron and steel, and his long and admirable service both as a practical director and as a wise critic and counselor in that art. They remember with gratitude his successful administration, for two separate periods, of the Presidency of the Institute, and they recall with pride the honor conferred upon it through the award to him of the John Fritz Gold Medal. Not least is their satisfaction in the retrospect of forty-four years of his membership in the Institute, with its unbroken record of loyal friendship acid delightful companionship; and they pray, that this record may be continued for happy years to come. In witness whereof, they have ordered this minute to be entered upon the records of the Board, and a copy duly attested to be sent to Captain Hunt.

Jan 1, 1919

By Jiang Su, Alan Bloodworth

"Composite sprayed concrete lining (SCL), consisting of two layers of permanent sprayed concrete separated by a layer of spray-applied waterproofing membrane, represents the latest development in SCL tunneling, but presents several challenges to designers. This paper aims to address the following issues: (1) how to simulate composite action, (2) behavior of a composite SCL tunnel, and (3) how to utilize composite action to achieve lining thickness efficiency. It firstly sets out the background to the composite SCL concept, and then presents a strategy for numerical investigation. The main part of the paper is the presentation and discussion of the simulation results, focusing on the lining deformation, load sharing and the safety margin of both linings. Interface stresses are also examined. It is found that significant secondary lining thickness reduction may be achieved by utilizing composite action. Challenges for the design of composite SCL tunnels are briefly discussed at the end. INTRODUCTION Sprayed concrete lined (SCL) tunnelling has seen rapid development over the last twenty years in the UK (Su 2013). One of these developments has been the replacement of traditional sheet membrane and cast in situ secondary lining with innovative spray applied waterproofing membrane and sprayed secondary lining system, which has been adopted in recent major projects, such as Crossrail (Pickett 2013), and brings many benefits to the construction (Dimmock et al. 2013). The combination of sprayed primary lining, spray applied waterproofing membrane and sprayed secondary lining is perceived to provide a structurally efficient lining system that outperforms the traditional lining system, which consists of sacrificial primary lining, sheet waterproofing membrane and cast in situ secondary lining. The claimed benefits in structural performance arises from the composite action between the sprayed primary and secondary linings via the spray applied waterproofing membrane, which produces a much stiffer cross-section and therefore a more efficient use of materials. Early investigations on the design of composite SCL tunnels were carried out without (1) definite and reliable long-term interface parameters, (2) a verified numerical modelling technique, or (3) consideration of different stress histories between primary and secondary linings (Thomas and Pickett 2011, Marcher et al. 2011). This paper reports the findings from a numerical parametric study on a typical composite SCL tunnel with varied secondary lining thickness. The results show that the true benefit of composite lining arises from the optimisation of the lining thickness (stiffness) ratio between the primary and secondary linings to achieve secondary lining safety and thickness efficiency at the same time."

Jan 1, 2016

By Dorricott M. G

This paper reviews the present status of mining engineering education in Australia, outlines the main objectives of current programs, and looks at some of the difficulties that need to be overcome to maintain and improve current standards.A case is made for greater co-ordination and co-operation between the institutions themselves, and between industry and the professional bodies to ensure the highest standards are achieved in the most efficient way.

Jan 1, 1992

By John E. Roberts

People are not a novelty. But the phenomenal numbers thereof, who have approached, settled, and been born in California in the past twenty-five years, are such a problem as to be a novelty in the broadest sense of the word. California, with less than 7,000,000 people in 1940, and over 19,000,000 in 1966. In 5 1/2 years, (1960-65) the southerly 14 counties of California, which together comprise one-half the land area of our state, had an increase in population greater than Colorado, or Arkansas, or Oregon, or any one of 19 other states.

Jan 1, 1967