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By C. Y. Tang, Z. H. Chen, T. C. Lee

"In sheet metal forming process, the forming limit and strain distribution are governed by plastic instability and fracture following strain localization. It has been proved that the temperature gradient caused by plastic deformation as well as friction is one of the crucial factors to induce the strain localization in high-speed metal forming processes. In this paper, a numerical simulation of the sheet metal extrusion process has been conducted by using thermal-mechanical coupling finite element method. An improved mixed finite element method has been used to solve the large deformation elasto-plastic problem. In thermal phase, the transient heat transfer finite element method together with the Crank-Nicholson algorithm has been employed to determine the temperature field. Both the numerical results and the experimental observations reveal that the temperature gradient plays an important role in inducing the strain localization, which eventually leads to fracture failure in the sheet metal extrusion process.IntroductionSheet metal extrusion is such a process where the extrusion punch penetrates into one surface of the sheet metal material to let it extrude and flow towards the outlet of the die. This process can be used to produce protruding parts on a strip material. In engineering applications, the quality of the product is affected by many factors such as stress state, loading speed, material properties and lubrication condition. The research on failure mechanisms and improvement of formability in sheet metal forming processes by exploitation of differential thermal conditions has been of great interest recently [1-3]. It has been proved that the temperature gradient caused by plastic deformation, heat transfer, and friction between sheet and tools is one of crucial factors to affect 'the formability in high speed sheet metal forming processes [4]. In our previous study of sheet metal extrusion, it has been observed that plastic deformation is highly localized and some specimens are subjected to fracture failure in the form of crack propagation [5]. To understand this failure phenomenon, the effects of temperature gradients must not be ignored."

Jan 1, 2001

By Rafael Errazuriz

About eighty miles north of the city of Antofagasta, Chile, located just below the Tropic of Capricorn, there spreads a wide desert area where copper oxide outcrops can be seen with the naked eye. Numerous old mining works and dump heaps with the green of atacamite and chrisocolla shining in the blazing sun, attest to the work done by miners in the beginning of this century. The dry desert air preserves the footstep marks, paths and trails of old cartwheels from years back. The mining area known as Michilla and Panizos Blancos, is located on the high plateau at 3000 ft above sea level. Around 1920 a Bleichert ropeway was built, which carried ores from the best known mine to a wharf at the Michilla bay. High grade silicious ores were shipped to the Gatico Smelter further north or to smelters in the United States or Japan.

Jan 8, 1973

By Harpal Parmar

This paper evaluates dynamic methods of pile capacity prediction by comparing their results to static load test results. Dynamic and static pile load test data were assembled from four southeastern states of the U.S. End-of-drive and restrike capacities were evaluated using the Pile Driving Analyzer (PDA) and by wave equation (WEAP) analyses. These were compared to static (Davisson criterion) loads. The best comparison was obtained for restrike PDA results; restrike wave equation analyses values also compared well. The end-of-drive results for both methods-showed relatively poor comparisons. The PDA was recognized as an important tool to measure energy transferred to the pile; this transferred energy was recognized as an uncertainty when conducting wave equation analyses. A statistical analysis showed restrike capacity results to be associated with higher precision and accuracy as compared to end-of-drive methods. The authors believe that restrike dynamic testing is essential to establish long term static soil strength and that it will lead to accurate and cost-effective design of piles.

Jan 1, 1996

By T. P. Meloy

Media mills operate by having energy transferred to the media which in turn grinds the feed material in a packed bed. Regardless of the mill type, the media energy density per unit surface area is constant. Since for optimum grinding conditions, both peak pressures and particle number of the bed depth are constant, the frequency of energy input is inversely proportional to feed size. As the particle size decreases the voles energy density increases linearly necessitating cooling in stirred mills. Grinding finer particles therefore, requires moving from rotary to vibratory mills, and the finest, the stirred mills.

Jan 1, 1987

By EDWARD B. DURHAH

The illustration Fig. 12, of the paper of Edward B. Durham, "Electrolytic Refining at the U. S. Mint, San Francisco, Cal.," printed in Bulletin No. 58, October, 1911, p. 830, contained an error. The corrected diagram is printed below.

Nov 1, 1911

By Marcel Magnusson, Guozhu Ye, Pekka Vaananen, Yang Tian

The most used technology for recycling of spent alkaline batteries consists of crushing, magnetic separation and processing of the nonmagnetic fraction, black mass, using a rotary kiln. In the process only zinc is recovered and all manganese in the black mass is lost. According to the EU regulation for recycling of batteries, more than 50% of batteries should be recovered. To meet the demand, Swerea MEFOS has together with a major battery recycler IsoLogistics in Finland and Sweden developed technologies for efficient recovery of zinc and manganese aiming for >50% recovery. This paper will focus on a treatment process using a DC furnace to produce a ZnO- and a MnO-product. The process has been demonstrated in pilot scale, 1 ton/h. The major outcomes will be highlighted. Another approach by using thermal vacuum technology for distillation of zinc metal has also been demonstrated in laboratory scale which is also reported in this paper.

Mar 1, 2018

The most complete mining show ever held in the United States and the largest exposition of its kind to be held anywhere in the world in 1988. That's how the American Mining Congress is billing its "MINExpo International '88," to be held April 24-28 at Chicago's McCormick Place, the largest exposition facility in the country. MINExpo International '88 will combine for the first time two previously separate AMC-sponsored shows - the International Coal Show and the International Mining Show. Starting with the 1988 show, MINExpo International will be held every four years. The next show, in 1992, will be held in Las Vegas. The MINExpo in Chicago will feature more than 500 mining equipment and services exhibits covering 3 hm2 (320,000 sq ft) of exhibit space. Exhibitors will display products ranging from small safety devices to large earth-moving equipment. MINExpo is one of the few trade shows selected by the US Department of Commerce for its Foreign Buyer Program. Commerce is working with US embassies around the world to publicize MINExpo and to form delegations of visitors from many countries. Overseas visitors to the show will be assisted at an on-site International Business Center. It will provide currency exchange, translation, and other services to foreign buyers. Registrants at MINExpo will also be able to attend their choice of 27 morning-only program sessions. At these sessions, international mining experts from industry, government, and academe will analyze technical, strategic, and policy matters and discuss the outlook for the industry. "Toward the 21st Century" is the theme of this year's program. The technical workshops and managerial seminars are designed to assist mining executives, engineers, and geologists as well as mine superintendents, managers, and foremen in handling their responsibilities. Based on previous attendance at AMC international mining shows, the association says that more than 25,000 persons are expected to attend the Chicago show. It is expected that approximately 15% of the attendees will be from foreign countries. The Soviet Union will be among those exhibiting at MINExpo. The Russians have leased more than 2.8 dame (3000 sq ft) of space to display their mining machinery and equipment. It is the first time that the Russians have joined in an exhibition of mining equipment in the US. The two largest manufacturers of mining equipment in the Soviet Union, Setmash and Avtoexport, will put on display in Chicago a variety of Russian-made equipment. It will range from 100 t (110 st) heavy-duty dump trucks and diesel engines to drilling, hoisting, and conveying equipment. In addition to some 400 US exhibitors of mining equipment and services at MINExpo, nearly 100 companies will be present from other major mining nations such as Australia, Canada, Great Britain, Japan, the Netherlands, and West Germany. And, for the first time, a Chinese manufacturer will take part in the AMC show, participating with its US marketing partner.

Jan 3, 1988

By J. E. Taylor

A detailed planning and design project has been undertaken at Callide Coalfields, as the first step towards implementing a fully integrated mine graphics system. The system, when fully installed, will support applications ranging from business graphics through to terrain modelling and computer-aided design. The conceptual design which will accomplish this is presented. The problems of retrospectively applying graphics standards to existing applications are discussed, and a practical solution outlined.

Jan 1, 1986

By W. E. Coxe

In 1857 the Philadelphia and Reading Railroad Company, whose main line extended from Philadelphia to Pottsville, Pennsylvania, with branches into the coal regions of Schuylliill County, made a contract with the Fairmount Rolling Mill, at Philadelphia, for the rerolling of some four thousand tons of iron rails. The essential features of the agreement were that the old rails should be piled with puddled iron and rolled into flats for the rail pile, which latter was • to be of a section seven inches square, and after being heated, and reduced, by rolling, to a bloom of a section about fire inches by six inches, was to be reheated, before being finished into the rail of the T pattern, four inches high, weighing sixty-four pounds per yard. Great care was exercised in the execution of this contract, and the rails being distributed over all parts of the road, gave general satisfaction by their excellent wear. Five years afterward, the principal proprietor and manager of the Fairmount Rolling Mill was elected President of the Reading Railroad, and very many of the rails made under his supervision were still in use in the tracks of the company, of which he had just assumed the management. His first efforts were, therefore, directed to the procuring of more rails of the same quality wherewith to replace those worn out. Here he encountered some trouble, makers refusing to bid because of the details in the specification, the required reheating being the objectionable feature, for which it was generally intimated they would not be sufficiently remunerated for the increased labor, extra coal consumed, and the changes necessary from the established methods of working. Most of the new rails were, therefore, bought, and the old rails rerolled without regard to any particulars as to the manner of piling, heating, etc., each manufacturer furnishing what he deemed the best article possible for the money. As a consequence, rails of all imaginable grades were placed in the tracks, some giving out in six

By W. E. C. Coxe

IN 1857 the Philadelphia and Reading Railroad Company, whose main line extended from Philadelphia to Pottsville, Pennsylvania, with branches into the coal regions of Schuylkill County, made a contract with the Fairmount Rolling Mill, at Philadelphia, for the rerolling of some four thousand tons of iron rails. The essential features of the agreement were that the old rails should be piled with puddled iron and rolled into flats for the rail pile, which latter was to be of a section seven inches square, and after being heated, and reduced, by rolling, to a bloom of a section about five inches by six inches, was to be reheated, before being finished into the rail of the T pattern, four inches high, weighing sixty-four pounds per yard. Great care was exercised in the execution of this contract, and the rails being distributed over all parts of the road, gave general satis¬faction by their excellent wear. Five years afterward, the principal proprietor and manager of the Fairmount Rolling Mill was elected President of the Reading Railroad, and very many of the rails made under his supervision were still in use in the tracks of the company, of which he had just assumed the management. His first efforts were, therefore, directed to the procuring of more rails of the same quality wherewith to replace those worn out. Here he encountered some trouble, makers refusing to bid because of the details in the specification, the required reheating being the objectionable feature, for which it was generally intimated they would not be sufficiently remunerated for the increased labor, extra coal consumed, and the changes necessary from the established methods of working. Most of the new rails were, therefore, bought, and the old rails rerolled without regard to any particulars as to the manner of piling, heating, etc., each manufacturer furnishing what he deemed the best article possible for the money. As a consequence, rails of all imaginable grades were placed in the tracks, some giving out in six

Jan 1, 1877

By Norman C. Stines

Russia's mineral potential is a secret that has been effectively kept by the Iron Curtain. There is no conclusive data and because of its extreme importance to the Free World, the subject is greatly discussed. Opinions range from those presented by Paul Tyler in his article "Russia's Mineral Potential," June issue of MINING ENGINEERING to those of Norman C. Stines, presented herewith. Mr. Stines is a consulting mining engineer of Los Gatos, Calif. He was in Russia, China, and Manchuria from 1909 to 1918 as a mining executive. From 1917 to 1919 he served as assistant military attache Intelligence Branch U. S. Army in Petrograd, Russia.

Jan 11, 1951

By Alexandre de Freitas Gomes de Mendonça

São crescentes as exigências por confiabilidade nos processos siderúrgicos. Nesse contexto, a Usiminas tem direcionado esforços em suas aciarias na busca da melhoria contínua dos processos garantindo a maior estabilidade operacional. O lingotamento contínuo é responsável pela solidificação controlada do aço líquido. A solidificação inicia-se no molde pela formação de uma pele que sustenta o núcleo líquido ao longo da máquina. O rompimento dessa pele representa um dos maiores problemas no processo de lingotamento contínuo por vazar o aço líquido no interior do veio e atingir as partes eletromecânicas da máquina. Essa ocorrência oferece risco de dano às pessoas, promove a interrupção do lingotamento no veio, sucateamento de produtos e indisponibilidade momentânea do equipamento. Visando reduzir a frequência de rompimentos, a Usiminas repotencializou o sistema de exaustão de vapor, adequou o sistema de detecção de rompimento de pele e criou uma equipe multidisciplinar para análise de cada evento. Essas ações reduziram significativamente a frequência dos rompimentos de pele na Aciaria 2 da Usina de Ipatinga, a ponto de registrar 539 dias sem esse evento.

Aug 17, 2017

By R. S. Olson

An analysis of the wash thickener-two stage filtration circuit was undertaken to quantitatively describe the circuit performance. On the basis of information developed in this study, the factors of major importance in reducing soluble loss are: filter wash, wash zone size, filter capacity, filter feed pulp dilution, blow back, filter cloth, water to repulp, water to primary wash, water to feed pulp and thickener underflow. The wash thickener-two stage filtration circuit has been used in many hydrometallurgical plants to separate solute from leach solids. As many as 20 to 30 plant operating variables determine the performance of the wash circuit and hence the soluble loss. The complex relationships of these variables, with each other and with soluble loss, make the evaluation of their effect on mill performance difficult. An analysis of this type of circuit was undertaken to quantitatively describe the circuit performance. THE CIRCUIT The diagram in Fig. 1 represents the operation of the wash thickener-two stage filter circuit. This circuit provides for counter current, cross current or for a combination of countercurrent-cross current operation. The feed pulp stream, J, is intended to include any solution or water, other than primary and secondary filtrate, which enters the wash thickener. Except for filter washing, the operations in the circuit are simple mixing operations which can be described by material balance. The concentration of solute in the filtrate and cake solution after application of wash liquor cannot be described by simple material balance. The displacement washing equation, derived by Rhodes1 and extended by Choundhury and Dahlstrom,2 appears to best describe this case of miscible displacement in porous media. In a useful form, it is

Jan 1, 1963

By Phillip A. Armstrong, Charles A. Lewinsohn, John H. Gordon

"This paper describes the opportunity offered by employing systems based on mixed conductive ceramics, in particular, ceramics conductive to oxygen ions and electrons, in reducing CO2 emissions from metallurgical production. Membranes based on these mixed conducting properties enable commercial viability of several attractive metallurgical processes. One of these processes utilizes modular, ceramic-membrane structures for the generation of pure oxygen, in tonnage quantity. The membrane-based systems offer significant capital savings and operating efficiencies in various metallurgical processes. The current status of this technology is summarized below.IntroductionCryogenic oxygen supply technology is currently the state-of-the-art for applications that require large quantities of oxygen (hundreds to thousands of tons per day). Cryogenic technology, however, requires substantial energy inputs and, hence, adds significant costs and emissions to processes. Furthermore, cryogenic oxygen supply technology is mature and there is relatively little potential for substantial capital cost reduction or efficiency improvement in coming decades. Non-cryogenic technologies offer a means to reduce the environmental footprint and cost of the oxygen supply facility in various applications.Ion Transport membranesCommercially available non-cryogenic air separation technologies, such as adsorption-based and polymeric membrane-based methods, do not afford the economies of scale that the cryogenic distillation enjoys. Therefore, industrial gas industry researchers began searching for alternatives to the relatively inactive and unselective polymeric membrane materials available. In the late 1980’s, Air Products began developing a new class of highly selective membrane materials with exceptionally high activity for oxygen transport. The materials constitute a class of oxide ceramics, and conduct both oxygen (as oxygen ions) and electrons in the same membrane, separating oxygen from air electrochemically. Numerous detailed process economics studies have shown that, based on these ion-transport membranes (ITM’s), the cost of oxygen can be reduced by approximately one-third relative to that obtained from state-of-the-art cryogenic oxygen supply technology, through a combination of capital cost savings and efficiency improvements. [1,2,3]"

Jan 1, 2008

One of the most important parameters in mine ventilation planning is the friction factor (K). Accurate values of friction factors are critical especially when carrying out mine ventilation simulations. No computer simulation of a mine ventilation network is meaningful if the airway resistances are not accurately estimated (when planning a new mine) or measured (for an existing mine). However, in the first case not many reliable values of friction factors exist in the international literature. This paper presents the results of a research project carried out in the province of Quebec where ventilation friction factors were measured in all underground metal mines. These friction factors are statistically analyzed and tabulated. A friction factor database was created that also includes the friction factors measured in the past by other people. This database can help the mine engineer to accurately estimate ventilation friction factors according to the specific conditions. This database offers several values of friction factors typical for hard rock mine conditions typical of modern underground metal mines.

Jan 1, 2009

By C. M. Schwartz, J. R. Bridge, D. A. Vaughan

THERMAL expansion coefficients of a uranium were originally reported' on the basis of X-ray diffraction measurement of lattice constants at 25°, 300°, and 650°C. These data have been reproduced by Katz and Rabinowitch.' CuK radiation had been used in this work, with consequent crowding of the patterns. Considerable overlap of the back-reflection lines was observed as the temperature was raised. Subsequent reexamination of the data led to the conclusion that errors had resulted from failure to obtain unequivocal indexing of the high angle reflections at elevated temperatures. The measurements have been repeated, using FeK radiation, which provided sufficient dispersion to assure proper indexing of the reflections, at each temperature level. The unit cell dimensions were re-determined at ten temperatures, from 25" to 650°C. Schuch and Laquer easured the macroscopic contraction from room temperature down to —253°C, and reported a negative value from —210" to —253°C; they suggested the possibility of the occurrence of a phase change. In the present work, the lattice constants of uranium have been measured down to —253°C, to test this hypothesis. Filings were prepared from a single piece of pure uranium bar stock. They were carefully cleaned with a magnet and pickled in nitric acid to remove traces of iron from the file. They were then annealed at 600°C in a sealed evacuated silica tube. The annealed filings were pickled in strong nitric acid to remove any oxide layer, washed in water and alcohol, quickly dried, and sealed in evacuated thin-walled silica capillary tubes. If properly sealed, the sample could be heated to the a-ß transforination temperature without significant buildup of the diffraction pattern of oxide. The high temperature X-ray diffraction camera was modified from the design of Hume-Rothery and Reynolds.' The thermocouple used to record the specimen temperature was calibrated from lattice-constant measurements of a standard silver specimen, using the Hume-Rothery and Reynolds values for silver over the temperature range from 25" to 700°C. Temperatures were reproducible to 210°C. Temperatures to —210°C were attained by passing precooled gas over the sample. The gas from the cooling train was directed over the sample capillary tube and thermocouple by means of a chimney of 1-mil polystyrene. The 36-gage Cu-constantan thermocouple had been calibrated by

Jan 1, 1957

By J. R. Tickner

"Gold is conventionally analyzed using fire-assay or other destructive chemical methods that impose significant sample preparation, OH&S, and skilled labour requirements. Developed over the past 15 years by the CSIRO, PhotonAssay provides a new approach. A high intensity, high-energy x-ray source is used to activate atoms of gold and other elements in bulk mineral samples. The resulting activity is counted to automatically, accurately and rapidly determine metal grade. Samples weighing 0.5–1.0 kg can be measured in a few minutes with minimal preparation. As the method is matrix-agnostic, traditionally hard-to-assay materials such as highly refractory ores, carbon pulps and copper concentrates require no special treatment. We present the status of commercial PhotonAssay systems being developed by Chrysos Corporation. The first unit with a throughput of up to 80 samples per hour is to be deployed in an Australian assay laboratory in late 2017; smaller systems suitable for providing real-time assay directly at the mine-site will be progressively rolled out from mid-2018. Performance results from extensive testing using both mine-sourced and standard reference materials are presented, demonstrating the sensitivity and accuracy of the method. Implications for replacing conventional gold assay in exploration, mining and processing operations are discussed.INTRODUCTION Accurate methods for assaying ore grade are essential throughout the exploration, mining and mineral processing value chain. The discovery and evaluation of new ore deposits, reserve and resource definition, mine operations planning, ore processing, metal accounting and product quality evaluation all rely on accurate measurement of the valuable metal content of bulk materials. The analysis of gold presents particular challenges, stemming from the very low concentrations at which commercial operations run (often part-per-million (ppm), or equivalently one gram-per-tonne levels or below), and the highly heterogeneous nature of many gold deposits. These challenges mean that any analytical method must have high sensitivity and be capable of measuring large-mass samples. The most widely used quantitative analytical method for gold is fire-assay (Hoffman, Clark and Yeager 1998). An initial ore sample typically weighing several kilograms is dried, crushed and pulverized to allow a small sub-sample (10–50 g is common) to be representatively drawn. The sub-sample is mixed with flux, litharge (lead oxide), a reducing compound and other reagents. The mixture is fired at a temperature of 1000–1200°C until molten. After cooling, the slag is removed and the lead button containing any gold present in the sample is remelted in a porous cupel. The lead is absorbed into the cupel, leaving a gold prill which is either weighed directly, or dissolved in acid and analysed via atomic absorption spectroscopy (AAS) or inductively coupled plasma spectroscopy (ICP or ICP/MS)."

Jan 1, 2017

By Alexander E. Sobolev

The kinetics of oxidative dissolution of lead sulfide in solutions of nitric acid and sodium hypochlorite was studied using the rotating disk method and the factor experiment design. The dependences of the PbS dissolution rate on concentration of oxidant (HNO3 or NaOCl), temperature, disk rotation frequency, and duration of interaction were determined. The adequate kinetic models allowing calculating the specific dissolution rate at any combination of values of the influencing factors were obtained. As a result of the complex analysis of kinetic parameters, the modes of the each process proceeding were established, their macromechanisms were determined, and the limiting stages of the oxidative dissolution processes were revealed. The dissolution kinetics of lead sulfide in solutions of nitric acid was found to have several regimes. At HNO3 concentrations below 0.5 mol/L, the process proceeds in a mixed mode close to a diffusion-controlled. It is caused by low oxidative activity of HNO3 and considerable diffusional diffuculties at this acid concentration range. At the nitric acid concentrations more than 0.5 mol/L and less than 6.0 mol/L, the process was found to be kinetically controlled. The limiting stage of the interaction is the surface chemical reaction. The observed relatively high order of the dissolution rate with respect to the concentration of HNO3 was explained by the autocatalytic action of the acid reduction products. At nitric acid concentrations exceeding 6 mol/L, the process proceeds in a mixed mode close to a diffusion-controlled, and the dissolution rate sharply decreased that was explained by a decrease in the solubility of reaction products. When lead sulfide is dissolved in sodium hypochlorite solutions, at first time the amount of PbS transferred into solution remains close to zero. Gradually, as time goes, this amount begins to increase sharply. The dissolution rate rises and reaches the maximum value, further remaining constant. At the steady-state regime, the dissolution rate is independent of the duration of interaction and disk rotation frequency. The process was found to be kinetically controlled. The limiting stage is likely to be chemical reaction on the surface of solid lead sulfide. The obtained kinetic characteristics enlarge the database on hydrochemical oxidation kinetics of sulfides and can be used for the elaboration of the recommendations for the effective comprehensive exploitation of lead-bearing ores and concentrates. Keywords: lead sulfide, nitric acid, sodium hypochlorite, hydrochemical oxidation, dissolution kinetics

Sep 1, 2012

By John N. Ludden, Maurice Rive, Hillar Pintson

"Quelques soixante-dix-sept plutons présents dans la Sous-Province de Pontiac et dans la partie centrale de la Sous-Province de I’Abitibi ont fait I ’objet d’une reconnaissance systématique. Ils ont été regroupes en huit suites plutoniques majeures et trois suites mineures à partir de critères géologiques et petro logiques. Parmi les suites majeures, quatre représentent I' activité intrusive la plus ancienne dans la région. L’une d' entre e/les est représentée par deux complexes anorthosito-gabbroi' ques lites et les trois autres comprennent les orthogneiss dioritiques a leucotonalitiques et les intrusions dons la composition varie de diurétique et granodioritique à leucotonalitique. Leur mise en place peut être pretectonique a syn ou tarditectonique; certains plutons sont synvolcaniques. Quelques data/ions U! Pb effectuées à propos de ces roches donnent des âges s' étalant entre 2 718 et 2 694 MA. Les données géochimiques indiquent la présence des deux lignées magmatiques, tholemique et calcoalcaline bien qu’il n'y ait aucune évidence de relations entre elles dans I' espace et dans le temps. Ces suites magmatiques différentes peuvent provenir soit d’une croute tholemique impliquée dans un processus de subduction soit directement du manteau.Les trois autres suites majeures comprenant des monzodiorites, des granodiorites et des monzonites ainsi que les deux suites mineures comprenant des syenites correspondent à un évènement intrusif plus jeunesse déroulant entre2 694 et2 680 MA. Ces roches sont syn, tarti a post tectoniques et sont enrichies en alcalins, Ba, Sr et terres rares legeres par rapport aux quatre suites précédentes. Leurs caractères chimiques prop res suggèrent qu' e/les proviennent d' une source différente par rapport à celle precedemment citee.La derniere suite plutonique majeure correspond a un monzogranite leucocrate, riche en pegmatite, également syn a tard tectonique, dont I' age n' est pas connu avec précision. ll représente le seul granite ""vrai"" de la région et dérive d’une anatexie soit des meta sédiments soit des granodiorites-tonalites plus anciennes. La troisième suite plutonique mineure correspond a quatre stocks de granodiorite porphyrique qui n’ont pas été étudiés en détail.ABSTRACTSevenly-sevenplutons have been identified in the east-centra/part of the Abitibi Subprovince and adjacent Pontiac Subprovince. These have been subdivided, on the basis of geological and petrological criteria, into eight major and three minor plutonic suite. Four of the major suite, which represent the oldest intrusive activity in the area, range in composition from dioritic-leucotonalitic orthogneisses to diorite-granodiorite/leucotonalite and include two layered anorthosite- gabbro complexes. Their time of emplacement ranges from pretectonic to syn-late-tectonic and some plutons are synvolcanic. U-Pb zircon ages for these rocks range from 2 718 to 2 694 Ma. Geochemical data indicate the presence of both calc-alkaline and tholeiitic magma series for these rocks although there is no evidence time and space relationships between the two. The different magma series also suggest the derivation of these rocks from two sources, either from subduced tholeiitic crust or directly from the mantle. Three major monzodiorite-granodiorite, monzonite, and two minor syenite suites comprise a younger inlrusive event ranging from 2 694 to 2 680 Ma in age. These rocks are syn-, late- to post-tectonica and, compared to the above four plutonic suites, are enriched in alkalis, Ba, Sr and light Rare Earth Elements.Their distinctive geochemistry suggests that these rocks were derived from a different source region than for the older plutonic suites. The remaining major plutonic suite consists of leucocratic, pegmatite-rich, monzogranite-granodiorite. These rocks are also syn- to late-tectonic but their ages are not known with precision. They are the only ""true"" granites in the area and were derived by the partial melting of either older"

Jan 1, 1990

By Shulan Wang, Xuan Liu, Li Li

"Electrochemistry of Fe(III) in 69CaCl2-12CaF2-19KF and 81CaCl2-19KF (mole percentage, %) was investigated at 827 oC on molybdenum electrode by cyclic voltammetry, chronoamperometry and galvanostatic electrolysis using Fe2O3 as the Fe(III) source. The reduction of Fe(III) to Fe was conducted in one step and controlled by diffusion process. Fe(III) shown greater reduction rate and diffusion coefficient in molten 81CaCl2-19KF than in 69CaCl2- 12CaF2-19KF. Galvanostic electrolysis of Fe was performed in both molten salts with a cylindrical cathode rotating at 200 r/min and dendritic iron deposit was obtained.Keywords: iron; electrolysis; electrochemistry; molten saltIntroductionThe production of iron and steel causes huge emissions of CO2. Iron electrowinning in molten salts with dissolved Fe2O3 using an inert oxygen evolving anode is an alternative process to reduce or eliminate the formation of CO2. Research on novel process of producing metal has been reported recently [1-2] by using CaCl2 as the main electrolyte and dissolving CaO in CaCl2 due to the high solubility of CaO in the melt. This process has been used in preparing many active metals and alloys [3-14]. In the present work, the electrochemical behavior of iron in CaCl2-KF was studied and transport property of iron ion in the melt was discussed.ExperimentalCaCl2,CaF2 and KF (in analytical purity) were dried in air for 48 h. Mixed salts used in experiments were placed in a graphite crucible (??58 mm inner diameter). The graphite crucible together with the salts was heated at 473 K for 12 h in a furnace with flowing Ar (99.99%) before further heating. Temperature inside the furnace was measured by an S type thermocouple. Electrochemical measurements, such as cyclic voltammetry and chronocoulometry, were performed in a three electrode cell by EG&G PAR273A potentiostat/galvanostatand. Galvanostatic electrodepositon of iron was conducted in a two electrode cell. Molybdenum (??2 mm) and iron (??5 mm) were used as the working electrode (WE) and the reference electrode, respectively. A graphite crucible and a magnetite rod (??25 mm ) consisted of 100% magnetite and sintered at 950 oC in argon atmosphere for 2 h with electrical conductivity of 366 O-1m-1 at room temperature were used as the counter electrodes in the galvanostatic electrolysis experiment. Carbon (??10 mm) was used as the counter electrode in electrochemical measurement. The deposits were washed in distilled water bubbled with argon and dried in air before being characterized by X-ray diffraction (PW3040/60 diffractometer) and scanning electron microscope (SEM, SSX-550)."

Jan 1, 2014