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By G. L. Dyer, R. D. Alorro, R. E. Browner

A potential new rare earth extraction process has been suggested (Lazo, et al., 2017) (Lazo, et al., 2018) based on converting the rare earth elements to solid phase rare earth oxalates in an oxalic acid leach. Oxalic acid consumption is a significant issue in the process, therefore to improve the viability of this proposed new extraction method, a process to recover oxalate from the leach solution and recycle oxalic acid is required. A review of the literature and confirmation through thermodynamic analysis of the potential options identified precipitation of calcium or ferrous oxalate as the best potential options. The use of metallic iron to both provide ferrous ions as a precipitant and reduce ferric ions in solution would provide the most economical option, however slow kinetics and unreacted iron created significant issues with this process. The direct use of ferrous ions, while faster and more efficient, produced a precipitate with relatively poor solid/liquid handling characteristics and would require an intermediate stage utilising calcium in regenerating the oxalate. Utilising calcium chloride and oxide created very similar precipitates with better physical properties than the ferrous oxalate and that a reasonable proportion of the oxalate could be recovered before neutralisation of the solution induced precipitation of other phases such as iron oxy-hydroxides and calcium phosphate. The produced calcium oxalate was easily converted to oxalic acid and gypsum via immersion in sulphuric acid. It was also found that there is a significant loss of oxalic acid due to factors other than rare earth oxalate precipitation during leaching. This leads to a maximum oxalate recovery in the range of 50 %.

Jan 1, 2020

By P. D. White, J. T. Moss, J. S. McNiel

Results of experimental work on the in situ combustion process were first published in this country in 1953' when Kuhn and Koch described results of a three-well test in Jefferson County, Okla. Shortly there-after Grant and Szasz2 described field studies in Nowata County, Okla., in which several modifications of the basic combustion process were investigated by injection of various oxidizing gas mixtures other than air. In the past five years speculation concerning this method of oil recovery has continued, with a number of interesting papers on various aspects of in situ combustion appearing in the literature3,4,5,6,7. However, only one of these' provided actual engineering information on pattern-type field experiments. The primary objectives of the Oklahoma three-well test were to check operation of specially designed electrical ignition equipment and evaluate problems associated with initiation of combustion in a natural oil sand reservoir. Immediately following successful completion of this test in the Pontotoc sand, plans were activated for a second field experiment to be conducted in the same sand a short distance away. The objective of this second field test1 as to establish a relationship between field observations and information derived from laboratory experimentation and computations. Secondary objectives of the test were to develop operating tech- niques and define operating problems, and to obtain information that would assist in the economic and engineering appraisals of the process. Careful planning was required since this test was designed with the hope of providing basic information on the characteristics and operation of a combustion drive. It was necessary to include test facilities which would not only permit precise control and measurement of the process variables but would also provide sufficient flexibility of control to insure that variables in the combustion process could be studied during the course of the test under a wide range of conditions. In order to accomplish these objectives elaborate instrumentation and several control wells were included in the design of the test installation. This type installation was felt to be well suited for an experimental study, but was in no respect intended as a counterpart of a commercial-scale operation. PRELIMINARY LABORATORY WORK An important objective of the field experiment, as stated previously, has been to obtain reliable data on operating variables which might be compared with similar data obtained in laboratory combustion tests. The value of successful correlations between quantities that can be measured in the laboratory and those obtained in a full-scale commercial venture has been well established for other industrial processes. The difficulty of following a process underground should make such correlations even more essential here. Also. approaching the field test phase of development of in situ combustion, it was considered desirable to precede design of test equipment with laboratory combustion studies under a variety of conditions to establish likely ranges of variables. These included temperature, air injection rate, frontal advance rate and produced gas composition.

By R. Renzoni, S. Belboom, F. Tourneur, A. Léonard

"Construction is a field which is concerned by environment. Tools as environmental product declarations are increasingly often used to compare several products and to take account of the environmental sphere in the choice. Environmental declarations of Belgian bluestone and sandstone products were realized in accordance with the ISO standards and following the standard NF P 01-010. The main goals of these studies were to obtain Belgian environmental product declarations to strengthen existing databases and to provide defences against Asian competition. Indeed, competition with China for bluestone products and with India for sandstone pavement is very important due the fact of the very competitive prices for foreign products. The impacts on climate change, resources and acidification of the sole transport were taken into account for foreign products"

Jan 1, 2011

By Satoshi Itoh

Phase equilibria and activities of the components in the liquid lead-antimony-oxygen temary system, which is of fundamental importance for discussing the recovery of lead and antimony from a used lead-battery, have been investigated at 1173 and 1223 K. The two liquid phases of metal and oxide were observed at the temperatures studied, and the tie lines indicating isoactivities were determined. The activities of PbO, Sb015 and Sb203 in the PbO-SbOu and PbO-Sb203 pseudo-binary systems were then obtained by applying the Gibbs-Duhem equation to the phase relation of metal-oxide equilibrium. Both in the pseudo-binary systems the activities exhibit negative deviations from Raoult's law. The vapor pressures of lead, antimony and lead oxide, antimony oxide were calculated by using the activities of the components in the lead-antimony-oxygen ternary system. As a result, an oxidation of antimony concentrated in an anode slime followed by evaporation as antimony oxide Sb406 was found to be considerably effective for the recovery of lead and antimony from a used lead-battery.

Jan 1, 2003

By Joseph F. Shirley

A froth flotation plant to recover by-product molybdenite must be designed specifically for the selected separation process and the type of ore being treated. However, some general rules concerning by-product molybdenite plant design can be suggested that would be valid for most processes. The term by-product molybdenite in this paper is limited to the recovery of molybdenite from copper porphyry ores, which essentially amounts to selectively separating molybdenite from copper and iron sulfide concentrates. In addition, most of the discussions would apply only to the almost universally used approach of floating the molybdenite and depressing the copper and iron sulfide minerals.

Jan 1, 1979

By Y. J. Wang

In the mathematical analysis of electrical networks, the electrical devices are often modeled using idealized network elements such as current sources, voltage sources, and resistors. An analogous approach is outlined here for the modeling of mine ventilation networks, which can be considered nonlinear resistive networks. The modeling technique proposed uses five basic (non-reducible) elements: the H element, the Q element, the D element, the R element, and the N element. These elements are characterized by their (a) pressure gain or loss, (b) air quantity, and (c) pressure-versus-quantity relationship, each of which may be known or unknown. In addition to the definition of the basic elements, the necessary conditions for which there exists a unique solution are discussed. This is performed using theoretical developments derived from electrical circuit theory and illustrated in example networks. The proposed procedures are useful in the solution and characterization of mine ventilation networks.

Jan 1, 1996

By J Loeb, R Ramanathan, H Ingham, P Cameron

Most mining operations, including iron ore, maintain a focus on continuous improvement and asset optimisation in their operations. As all the unit operations in the Mine-to-Mill value chain are interdependent, available technologies that address efficiencies across the value chain are once again in the spotlight as companies are driven to improve productivity and maximise mine site profits to increase return on capital invested. Core to continuous improvement is the need to understand the baseline and impact of changes to the process. In this paper, we discuss some of the critical attributes in the Mine-to-Mill process, including their influence on productivity and cost, the need for direct measurement and areas where they should be applied. Many initiatives can be considered to improve Mine-to-Mill processes. Mining operations are planned and executed based on designs and models to achieve the operation's objectives. However, there are many variables in the different parts of the value chain, such as blasting, material handling, crushing and screening. Therefore, measurement of the key attributes establishes the baseline for Mine-to-Mill (or Pit to Plant) performance, which is necessary to understand the impact of any proposed improvements to the process design and execution and monitor the outcomes on an ongoing basis sustain the improvements that have been implemented. This paper focuses on two types of measurement – blast movement and particle size of materials through the Mine-to-Mill process. Several innovative technologies and control loops are readily available to measure these attributes and assist operations to improve productivity and mine site profits. The size of the tangible benefits, which can flow from measuring and optimising fragmentation and blast movement, provide a remarkable return on the investment. Realising these benefits needs a focus outside conventional operation silos as a successful Mine-to-Mill project requires a multidiscipline approach across all the silos in the value chain. Required technologies are available; adding the necessary ingredients of communication and co-operation by all concerned across the silos will ensure the benefits are realised.

Nov 8, 2021

By R. I. Kraydenko, A. N. Dyachenko

"The possibility of SiO2 5N production by staged purification of ammonium hexafluosilicate (NH4)2SiF6 is discussed. High-purity silicon dioxide can be obtained with fluoridation of quartz concentrate by solid NH4F at 100 °C, with further sublimation of the product at 320 °C, its dissolution, ammonia hydrolysis, filtration and drying of SiO2•nH2O. This is accompanied by regeneration of the processing reagent - NH4F.INTRODUCTIONProduction of high-purity silica-5N (SiO2 content over 99.999%) is an important and urgent task of the modern chemical industry. This material is used in the manufacture of optical glass, optical fibers for internet cables, silicon for solar power and electronics.Quartz concentrate is raw material for the production of silicon dioxide. The existing technologies of synthetic silicon dioxide were introduced in the mid-twentieth century. These methods are energy-consuming, multi-step and do not meet stringent environmental requirements. In fact, as some conventional technologies became obsolete; it became necessary to develop new methods for the production of synthetic silica. We believe that the fluoride technology of processing of quartz materials by ammonium fluoride is the most promising direction.In industry, silicon dioxide marked ""Silica White"" is obtained by liquid-phase method. The method consists of the precipitation of amorphous silica from sodium silicate solutions with acids. The resulting product is filtered, washed and dried. Depending on the deposition conditions and nature of the coagulant the ""Silica White"" is acidic, neutral or alkaline. The dry product is subjected to grinding. The degree of dispersion and porosity of the particles of Silica White depends on the nature of decomposition agent (a substance that decomposes the silicate) and coagulant, conditions of sedimentation, filtration and drying. During the drying process the silica particles are sintered into aggregates of a few millimeters."

Jan 1, 2012

By Charles Roeder, Amy Leland, Dawn E. Lehman

Concrete filled steel tubes (CFSTs) are composite members that are commonly used in many countries today. CFST components are used in the United States, but they are more common in Asia, in part because the connections used in Asia are quite labor intensive and there are not standard connections in the U.S. In addition, US design specifications are prepared by separate groups for structural steel and reinforced concrete structures and so composite systems that use CFST components are not overseen by a single group and as such there are several, conflicting design standards. In the US, steel tubes used for CFST are more slender (i.e., the diameter-to-thickness, D/t, ratio is larger) than some other countries, and labor practices (structural steel labor is different than reinforcing steel labor) also cause potential conflicts in construction. As a result, CFST has had some use in tall building construction in the US, but very limited use in bridge construction. A research program at the University of Washington has been in progress to address many of these issues with an eye towards universal design expressions, simpler, standardized connections and promotion of accelerated bridge construction (ABC). The research has resulted in recent changes to the American Association of State Highway Officials (AASHTO) bridge design specification as well as state departments of transportation (DOTs), which supports the increased use of CFST in bridge pile and drilled-shaft foundations. An experimental research study which investigate the flexural strength, shear strength and connections was conducted. These connections provide good performance under both seismic and gravity loads and address the concerns of US construction. These connections, their design rules and requirements, and their impact on composite behavior and system performance are discussed. These results permit rapid and economical construction of CFST bridge piers, piles and drilled shaft foundations. They encourage the use of more slender and economical tubes, while achieving the benefits of composite construction. INTRODUCTION Concrete filled steel tubes (CFSTs) are widely used for bridge and building construction in Asia, but the use of CFST in bridge construction is limited in the US. The historical use of structural steel and reinforced concrete in US bridge construction have resulted in more developed design expression for those construction methods, which has limited the use of CFST. Bridge construction in the US is inherently different than in Asia because of differences in codes, labor costs and construction practices. As a consequence, design and construction practices that are economical and practical in other countries may not be practical for US bridge construction.

Jan 1, 2019

By S. G. Hardcastle, K. C. Butler, M. G. Grenier

The most common method of determining airflow employed by mine ventilation engineers is the product of i) the average air velocity as measured by a vane anemometer and stopwatch through a continuous traversing technique, with ii) the cross-sectional area of the roadway. This method requires the vane anemometer to accumulate the total flow over the duration of the traverse. Historically, this has been facilitated by a mechanical analog instrument that has either a counter or set of dials that display the flow. Common instruments of this type are Airflow Development's AM5000, Davis's, or Taylor's Biram type anemometer. The AM5000 is widely used in the Canadian mining industry but is no longer available. Therefore, regulatory authorities have seen fit to evaluate presently available commercial instruments to replace the AM5000. This paper describes an instrument evaluation contracted by the Atomic Energy Control Board of Canada which regulates the uranium industry. Over the last two decades there have been numerous advances in the development of electronic air velocity meters. Currently available units have the following features: a) battery operation; b) are compact and can be hand-held; c) employ LCD's, and microelectronic circuitry; and d) provide a time integration for the duration of a traverse. These features make such instruments a possible replacement to the analog units and stopwatch determinations. This paper details five of the new generation of vane anemometers plus a vortex air meter, and it explores their limitations in comparison to analog units. Specific consideration is given to linear response, the effects of yaw, traversing speeds and ergonomics relating to both handling and use. The paper concludes with some features that are attractive and should be considered when purchasing a new anemometer.

Jan 1, 1991

By Shin-ya Kitamura

Kinetic modeling is very important to understand steelmaking reactions. The coupled reaction model proposed by Prof. D.G.C Robertson is the best suited program, and therefore, the author has applied it to the various steelmaking reactions, a few examples of which are discussed. Hot metal dephosphorization occurs under non-equilibrium conditions as it takes place between the slag, which has a high oxygen potential, and the hot metal, which has a low oxygen potential. A process simulation model based on the coupled reaction model was constructed. This model considers the solid and liquid slag, liquid metal phases, and the reaction between the solid and liquid slag, besides the reaction between the liquid slag and liquid metal. Using this model, the ruling factor to increase the reaction efficiency of dephosphorization has been verified. In the secondary refining process, the values of inclusion composition calculated by the thermodynamic model, under the assumption of equilibrium with the metal composition, were found to be different from those observed in practice. A kinetic model, incorporating the reactions between slag, metal, inclusion, and refractory has been postulated, and the composition change of inclusion during treatment has been analyzed.

Jan 1, 2014

By A. V. Myaskov, V. S. Valavin, K. D’Elia, I. O. Krylov, Vu Van Toan, T. I. Yushina

"The purpose of this research is the development of a technology for processing the concentration tailings of limonite ores at Kamysh-Burun Mining and Processing Complex into an iron- containing product for ROMELT process. In the concentration and metallurgical processing of iron ores, substantial amounts of waste are generated (tailings, slimes, slags, metallurgical dust, etc.) that can be converted into a commercial product if is properly processed. This article presents the results of experimental studies of the feasibility of processing iron- containing tailings of Kamysh-Burun deposit (slimes from Verkhne-Churbash storage facility (VCh sample) and dumped waste of Kamysh-Burun (KB sample)) to obtaining valuable components for further uses. Applying Mossbauer spectroscopy has been shown that the iron minerals in the studied samples are technogenic varieties of iron hydroxides. The most suitable technology is the magnetic roasting process, since iron hydroxides are easily transformed into a magnetic, easily recoverable form. Have been shown the advantages of a two-stage magnetic separation, in a strong field and with polygradient separators. Concentrating this material through magnetic methods makes it possible to increase the iron content to 20-21 %. Magnetic concentration of the deeper layers materials results in iron- containing concentrates with a total iron content of up to 58% whit a phosphorus content of about 2%. Reducing the phosphorus content is possible by blending upper and lower layers of the material at a ratio of 1:1. Thus, it is possible to process the material accumulated in the slime storage facility using the ROMELT process combined with preliminary three-stage magnetic concentration and disposal of tailings with the permissible iron content of less than 5%. Wastes from smelting will be slags suitable for use in construction industry. The Kamysh-Burun material preparation for ROMELT process should be performed applying gravity-washing with separation of the -0.4 mm fraction and additional blending for dephosphorizing the concentrate. The smelting will produce pig iron and slag."

Jan 1, 2018

By T. Gibson

It is generally accepted that South African coal mines have gone through the mechanization of most of its underground mines, and while there certainly were a lot of productivity improvements, the lack of visibility on these machines operating underground still leave vast areas for improvement. The average actual cutting time still remains very low, in the 30 per cent area, which leaves significant improvement possible. Currently all analysis is carried out using hand-written reports. Unfortunately this is subjective and often inaccurate because of human interpretation. In addition in order to avoid costly component failure, a monitoring system is required to warn of eminent failures and condition monitoring. The challenge faced was to supply and install a system that was ‘Open’ and could be retrofitted to existing machines in operation because of the current standard of communication links to the underground sections. In addition it was intended to use, existing ‘off the shelf’ software and hardware and adapting this for the harsh underground mining conditions wherever possible in order to reduce costs. As development occurred, as with all technology, doors opened to other opportunities such as, remote access data logging and Internet based reporting. We focused on the Voest Alpine Bergtechnik (VA) range of continuous miners, as need arose to achieve the desired cost improvements because of the strategy of service contracts the subsidiary company, Voest Alpine Mining & Tunnelling (VAMT) offer the mining industry in South Africa. This paper describes a data logging system that has been installed on various continuous miners that provides data in real time, on line, and that could be expanded to any electrically supplied underground mobile or stationary mining machine.

Sep 1, 2001

By Stefan Stein, Jorge Davo, Adrian Villanueva, Abhay Kulkarni, Shane Hoff

Pellet sizing plays a key role in the productivity of the entire pelletization and subsequent induration processes, whereas uneven pellet sizing can increase the circulating load of the balling circuit inducing operational instability leading to production loses. The present work focuses in comparing the agglomeration kinetics, expressed as the number of pellets produced in a determined target size range, of different organic binder-bentonite binder systems. The batch experimental results show that the binder system has a great influence in the resulting pellet sizing, which could lead to advantages in terms of balling circuit efficiency and eventually operational de-bottlenecking.

Oct 1, 2019

By Gerard C. Gambs

The electric utility industry is the largest customer of the U.S. coal industry, consuming nearly 50% of present coal production. By 1980, the electric utilities are expected to burn over 500 million tpy of coal or 75% of total coal production. When coal is burned in electric utility plants, ash is produced in one of several forms. These include fly ash, bottom ash and bottom slag. At the present time, approximately 20 million tons of these ashes are produced and must be disposed of by the utilities at a cost of 50[c] to $2 per ton. In 15 years, more than double this quantity will be produced. Only a small quantity of this ash is put to any practical use. Much remains to be done about expanding uses for fly ash and bottom slag.

Jan 1, 1967

By Ernest G. Enck

"The Rockets' Red Glare" of the Fourth of July is produced by strontium compounds. However, strontium has a number of less spectacular uses; i.e. in, or in connection with, the manufacture of ceramics, caustic soda, glass, railway and truck signal flares, beet sugar and steel. The principal ore of strontium for use both as the mineral and for production of compounds is celestite (SrSO4). This mineral varies in color from white to pink or blue depending on presence of impurities. It has a hardness of about 3.5 and specific gravity of 3.9. It is brittle and has perfect basal and prismatic cleavages. The high grade ore is obtained from England, hence it has become the standard for all other producing areas. (See analyses, Table 1.) The most objectionable impurity in English celestite is iron, coming mostly from adhering clay. On the other hand, Mexican celestite, while no higher in strontium sulfate content, is extremely low in iron (less than 0.2 pct), hence it is more desirable for certain uses. Most of the celestite in Spain and in the United States is high in calcium and barium, and commonly high in iron, and requires some form of beneficiation in order to be equal to English ore. The natural carbonate (SrCO3), or strontianite, is less important than celestite as a source of strontium, because it is less abundant and is not so widespread in its occurrence. Furthermore, it generally occurs with calcite (CaCO3) and lead sulfide (PbS), and for most uses these impurities are detrimental. This mineral is generally white or yellowish, forming needle-like crystals. It has a hardness of about 3.7 and a specific gravity of 3.68-3.8. The mineral is brittle and has an imperfect cleavage. A typical analysis of German strontianite is shown in Table 1. [ ] Distribution of Deposits UNITED STATES Occurrences of strontium minerals are known in Arkansas, Arizona, California, Illinois, Ohio, Pennsylvania, Tennessee, Texas, and Washington. Celestite occurs in the Vulture Mountains, Maricopa County, Arizona in beds three to ten feet thick associated with sandstone, gypsum, and barite. Because of the low strontium content, approximately 86 pct SrSO4, it has no commercial value. A large deposit of celestite occurs in San Bernardino County, California, in the Cady Mountains near Argus Station, about eight miles west of Ludlow. The celestite here is interbedded with shaly and clayey tuff in a zone about 300 ft thick. Massive, finely crystalline ore has been recovered with an analysis

Jan 1, 1960

By P M. Cepuritis

In hard rock mining, large-scale bulk mining methods such as block or panel caving (BC/PC) and sublevel caving (SLC) typically generate significant surface deformations such as subsidence. Surface deformations need to be considered in the project evaluation and planning stages of cave mines, for example, planning and location of critical underground mine planning infrastructure such as portals, haulage and vent shafts, access roads, or potential damage to existing infrastructure, changes to surface water management, waste dump, stockpile and tailings dam stability, and environmental impacts. Assessing the impact and risks associated with subsidence is a key component in robust mine planning and operations management.

Nov 29, 2022

By M. S. Prasad

This paper presents the process methods of beneficiating various copper-cobalt and copper-zinc ores mined by Gecamines in Zaire. Geology and mineralization of both sedimentary and vein type deposits are described with special emphasis on the production of oxide, dolomitic and sulfide concentrates. Description of different types of concentrators and their treatment methods are discussed for the production of sulfide, oxide and dolomitic concentrates. Production of concentrates, their consumption and stocks are briefly reviewed. Modernization of the concentrators with substantial investments on grinding, classification, flotation methods and tailings treatments are also discussed to improve the metallurgical efficiency of the concentrators with a view to improve the production of concentrates both qualitatively and quantitatively.

Jan 1, 1990

By R. HAYDEN, H. B. HALLOWELL, H. O. Hofman

THE object of refining copper in the reverberatory furnace is to obtain a metal which will have the highest attainable degree of malleability, ductility and electric conductivity, and present at the same time a level surface when it solidifies in the mold after casting. These desirable physical properties are governed by the character of the impurities and the forms in which they are present, by the amount of cuprous oxide retained by the copper, by the quantity of gas held in solid solution, by the casting-temperature, and by the thickness of the casting. The effects of impurities, of cuprous oxide and of gases upon the mechanical properties of copper have been studied by Hampe in his classical paper "Contributions to the Metallurgy of Copper." The most recent research into the effect of metals upon the electrical conductivity of copper is that of Addicks.2 The influence of cuprous oxide upon the electrical conductivity has been investigated by Walker' and Addicks.4 The absorption of gases has received' attention by Hampe,5 Stahl 6 and Heyn.7 The effects of casting-temperature have been noted by Stahl.8

Mar 1, 1907

"RésuméDans la première partie de cet article on discute Ie mode d'écail age aetueJJement en usage dans des mines souterraines. Par la suite, on presente la problematique d'écaillage à l’aide de barres conventionnelles et on discute les plus recénts développements des outils d'ecaillage portatifs et mécanisés ainsi que les techniques de détection des roches branlantes. Plus tard, on analyse la tâche d'écaillage avec des barres conventionnelles. Dans les chapitres qui suivent on présente un concept d'un outil d'écaillage portatif et mécanisé développe à l'Université Laval, ainsi que les résultats des essais de cet outil, effectués dans quelques mines au Québec. On constate que Ie nouvel outil d'écaillage démontre un potentieJ intéressant tant au niveau de l'effort requis pour effectuer la tâche d'écaillage que de la sécurité des mineurs.On conclut que l’application de cet outil fera un pas important sur Ia voie d'amélioration des conditions de travail dans les exploitations souterraines, tout en assuarnt une qualité accrue de l'écaillage.AbstractThe first part of this paper discusses the type of scaling operations presently in use in underground mines and derma; a scaling factor which is expressed as the:: area necessary to scale to extract one ton of ore. Subsequently, the problems associated with conventional scaling methods are discussed as well as recent developments in mechanized hand-held scaling devices and methods of loose detection. The elements of the scaling process are further analyzed. In subsequent sections of this paper, the conception and design of a mechanized scaling device, developed at Universite Laval is described. The results of field tests conducted in Quebec hard rock mines are presented. The experimental findings show that the mechanized hand-held scaling device shows great potential in improving the productivity and safety of underground mining operations."

Jan 1, 1995