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By Rafael Padilla

In the production of copper from chalcopyrite (CuFeS2) concentrates by the smelting and converting technology, the ambient pollution with gaseous S02 and toxic metals such as arsenic compounds is still a serious problem, especial1y in the converting step due to the batch nature of the conventional Peirce Smith process. Non-SO2 emitting alternatives are leaching processes. However, few of them have had a limited industrial application and they are not very effective in discarding safely the toxic impurities. A combination of pyro-hydrometal1urgical methods: the sulfidation of chalcopyrite and subsequent leaching of the sulfidized material is a non-polluting alternative to treat not only clean chalcopyrite concentrates but also complex chalcopyrite-enargite concentrates. In this article, this alternative is discussed concerning the thermodynamics and kinetics of the sulfidation of chalcopyrite with gaseous sulfur. The kinetics of the leaching of the sulfidized concentrate in an H2SO4-NaCI-O2 system is also discussed.

Jan 1, 2003

By Michel Massé

Eleonore Project- Agenda ? Purpose and Technical Overview ? SmartEXEC Control Capabilities ? SmartEXEC System Archetecture ? SmartEXEC System Advantage Eleonore Project- Purpose and Technical Overview ? Control air quality while maintaining target production levels at minimum energy operating cost ? Improve safety, work place conditions and operation flexibility ? Reduce energy consumption and green house gases footprint

Aug 1, 2013

By Milton C. Head, Aulton E. Roland, William E. Hawes

INTRODUCTION Uranium mining in the Grants Mineral Belt has undergone changes from methods pioneered during the 1950's and has now become fairly standardized throughout the district. The orebodies vary in size and shape and have been most successfully mined by using modified room and pillar methods with pillar recovery. This paper will expand on methods and equipment that are being used and modifications of these that will increase productivity and efficiency. GEOLOGICAL BACKGROUND The petrology of the Grants Mineral Belt consists of alternating layers of sandstone and shales (mudstone), with occasional thin layers of coal. The sandstones are aquifers which are generally artesian to some extent. The shales are bentonitic and decompose into extremely sloppy mud when exposed to water. Figure 1 shows a typical geologic section. Most of the uranium produced in the Grants Mineral Belt comes from the Westwater Canyon member of the Morrison Formation and occurs as scattered ore bodies throughout the formation. This formation consists of layers of bentonitic shale and sandstone of varying degrees' of cementing and grain size. It is also a very significant artesian aquifer. The unconfined compressive strength of the various formations is not high, as shown in Table I. It is important to note that these represent average values and a great range may exist within a single formation, especially In the Westwater which is the ore formation. [ ]

Jan 1, 1982

By M. Tangstad

Keywords: Pyrometallurgy, ROMA, Norway, furnace, fines The ROMA project is a competence project on optimizing the usage of raw materials and energy in the ferromanganese, silicon, and aluminium industries. One of the items investigated in this project is the effect of fines on the furnace, and the usage of agglomerates versus lumpy ore. From lab-scale experiments it is shown, that for the charge to agglomerate in the furnace, the charge has to be exposed to a temperature higher than about 1200°C, independent of fines content. The fines less than 1 mm also showed higher agglomeration properties, compared to 2?4 mm, which showed no agglomeration property at all. The properties of agglomerates are very dependent on the pre-treatment of the agglomerate. Sinter and pellets, which have been heated to high temperatures, show a better strength, but also a lower CO reactivity. Sinter also shows a lower melting temperature compared to the ore.

Jan 1, 2011

By I Mason, G Turner, J Hargreaves

One of the key objectives in production from any mine is the minimisation of ore loss and dilution. This can only be achieved when the distribution of ore within the mine is known. The distribution of ore is usually evaluated from a combination of drill hole information and underground mapping data. Three-dimensional models of the ore distribution are then constructed by interpolating grades, contact locations and confirming these estimates through mapping. While the interpolation procedure can incorporate an understanding of the local geological conditions, it is an approximation and thus susceptible to some degree of ore loss or dilution. Naturally, such problems increase in areas of sparse geologic information or greater geologic complexity. Borehole radar offers an approach to decrease the interpolative aspects of modelling by providing a continuous image of some ore contacts. Borehole radar works by building a two-dimensional image of an ore contact from radio waves bounced off the contact from closely spaced positions along a borehole. This image can be imported into Datamine (or a similar design package) and incorporated into geological models of a given ore block. The results of a trial survey from the Mariners nickel mine at Kambalda are presented to illustrate the improved level of detail and accuracy that can be achieved through the incorporation of borehole radar into orebody delineation practice. Once implemented on a large-scale this technique has the potential to greatly increase the cost-effectiveness of long hole stoping at Kambalda, through increased ore recovery and reduced dilution.

Jan 1, 2000

By Sadegh Firoozi

Experiments measuring the kinetics of oxidation and making visual observations of the oxidation of approximately 6 g static lead baths containing arsenic, antimony and tin were conducted in the temperature range from 500 to 600 oC. A range of repeatable behaviours were observed, notably: the formation of a coherent, solid oxide layers on pure lead and lead-tin alloys; the formation of liquid oxide droplets during the initial oxidation of lead-arsenic and lead-antimony alloys and the eventual formation of a complete oxide layer covering the entire free surface of these alloys. Thermogravimetric measurements revealed that the rate of oxygen uptake was strongly influenced by the form of oxides being generated at the melt/gas interface. Compared to the rates of oxidation of pure lead, arsenic increased the rate of oxygen uptake throughout the temperature range via the formation of liquid oxidation products. The presence of antimony resulted in a moderate increase in the rate of oxygen uptake as compared to arsenic. Tin was effective in lowering the rate of oxidation even in the presence of arsenic because the oxidation product was always a coherent layer that acted as a physical barrier to oxygen transport to the underlying alloy.

Jan 1, 2006

By K. Y. Haramy

A scale-invariant theory of the strength and deformability of rock masses in static equilibrium and at incipient failure is proposed. The theory provides a rationale for designing structures in rock. This paper presents results of experiments conducted by the U.S. Bureau of Mines and theoretical methods to determine and interpret in situ strength of rock masses using the borehole shear tester.

Jan 1, 1995

By Alejandro Gutiérrez, David Ahues, Paola Merino, Felipe González

A Discrete Elements Method (DEM) study of load movement within a SAG mill 12,192 × 7620 (40′ × 25′) in normal operating conditions is performed. The purpose is to determine how the geometry of the lifters affects the kinetics of the load inside the mill. Specifically, the changes produced by the incorporation of inclined lifters and spiral or helicoidal pulp lifters to the kinetics are evaluated. Four study cases are identified: first, the base case corresponds to a conventional geometry; the second case corresponds to inclined lifters incorporation; third case corresponds to a mill with helicoidal discharge; and the fourth case corresponds to a mill with inclined lifters and helicoidal pulp lifters. To save computational resources, the water that enters the mill has been modeled by varying the coefficient of restitution. The results of a series of experiments are presented to determine how this coefficient varies when having impacts on surfaces with different liquid levels. A comparative analysis is made of the following variables: mean transport speed and material flow, for normal operating conditions. Taking as reference the mill with straight lifters and radial pulp lifters (case 1), the case with the inclined lifters and radial pulp lifters increases the material discharge flow less to 76 mm of size by 5.1%, and this value increases even more when the helicoidal pulp lifters are incorporated reaching a 58.6%. The most significant change is seen in the flow through the grates and the pulp lifters discharge, which can increase substantially improving the operation.

By Charles W. Daugherty, Robert Nyren

The replacement of Boston’s elevated Highway I-93 running north to south through the heart of the city with 8-lane tunneled roadways, coupled with the underground extension of Highway I-90 eastward to Logan Airport, has earned the Central Artery/Tunnel (CA/T) Project the position of the largest infrastructure project in the U.S. today. The gigantic interchange featuring numerous ramps where these two main branches of the Artery intersect required the construction of three huge jacked tunnel boxes that were pushed beneath eight active Amtrak and commuter rail tracks that had to remain undisturbed in spite of poor geology and a minimum of cover between the track beds and the tunnel crowns. Ground freezing was chosen as the method of stabilizing the soil over the tunnels, and it was extended in one area to stabilize the ground at the intersection between the tunnels and an abutting deep cut-and-cover excavation. Because many standard geotechnical instruments consist basically of open standpipes filled with water, it was a major challenge to keep them de-iced and in a condition to provide data on vertical and lateral ground movements. The efforts to do so are herein described.

Jan 1, 2003

By L. Westerstrom

Supply and Demand After a dismal first half, the industry saw a marked improvement in its markets during the final six months of 1983. Domestic consumption was 17.6% higher in the second half of the year, primarily due to a surge in electric power requirements. The sharp increase in demand for electric power during the third and fourth quarters afforded utilities the opportunity to lower stocks that had accumulated to record levels during 1982. Consumer stocks were reduced from 179 Mt (197 million st) at the end of June to 153 Mt (169 million st) by the end of the year. That is the largest inventory drawdown on record during a six-month period without a major coal strike. Despite the huge depletion in inventories, coal production in the second half of 1983 rose 1.3% above output in the second half of 1982. However, because of the disappointing first half, production in 1983 totaled only 712 Mt (785 million st), 6.4% less than the 760 Mt (838 million st) produced in 1982. Demand The extent to which the economic recovery affected coal markets in 1983 varied: • total domestic coal consumption increased 4.2%; • electric utility coal consumption increased 5.3%; • exports declined by about one-fourth; • coal consumption at coke plants declined 9.5%; and • coal consumption in the other industrial sectors increased 2.9%. Domestic coal consumption totaled 667 Mt (737 million st) it 1983, 27 Mt (30 million st) more than 1982. Electric utility consumption increased from 539 M1 (594 million st) in 1982 to 567 M1 (625 million st) in 1983. Coal consumption at coke plants declined from 37 Mt (41 million st) to 34 M1 (37 million st). Residential and commercial use increased 181 kt (200,000 st) - from 7.4 to 7.6 Mt (8.2 to 8.4 million st). Electric Utilities: Electric power generation increased 3.1% in 1983. Demand for electric power increased in all major consumer categories. Residential and commercial use rose 2.7% and 3.3%, respectively. The most striking increase, however, and indicative of the economy's strong upturn, was the increase in industrial electric power use. Industrial power requirements, which declined 9.8% in 1982, rose 4.1% in 1983. The electric utility sector continued to expand its use of coal last year while lowering its requirements of oil and natural gas. In 1983, electric generation from coal increased 5.7%, while genera-

Jan 5, 1984

By Thomas M. Barczak

A critical safety component for all underground mining is intrinsic and standing support systems. Specifically, tabular hardrock mining exploits a wide variety of deposits that require various methodologies to safely mine the ore material. Several new support systems have been developed in recent years for hard rock applications which have been modified or applied in a variety of ground control applications. These include prestressing devices, improved cribs, and free standing supports. Various standing support and prop-type systems have been designed for hard rock applications with seismic loading conditions to accept prestressing. The prestressing, using water-filled cells, creates an active load upon installation and is considered essential to maintain support during and after the blasting of the mine faces. Heavy seismic activity is also present in these mines and the prestressing units can provide some energy absorption capability to help preserve the integrity of the support. This paper presents an overview of these innovations in support technology.

May 1, 2007

By N. A. Gokcen, S. Fujishiro

The dissociation pressure of Cr3C2 has been measured in the range of 1908" to 2237°K by means of graphite Knudsen effusion cells. It has been found that Cr3C2 vaporizes according to the following reaction: 1/3 Cr3C2 (s or 1) = 2/3 C (graph.) + Cr (g). The equilibrizcm pressure, P, of Cr (g) is found to be log Ps=- - (21,194/T) + 6.525 over solid Cr3C2 and estimated as log P, = - (19,535/T) + 5.76 over liquid Cr3C2. CARBIDES of chromium are of great importance in alloy steels and cemented carbides. The published data on their therm odynamic properties at high temperatures, however, are meager. The heat capacity and change in entropy of Cr3C2 were determined calorimetrically by Kelley and Moore1 in the range of approximately 50" to 300°K, and by Oriani and Murphy2 from 297" to 1188°K. The standard entropy of Cr3C2at 298.15°K, obtained by Kelley.7 was later confirmed by DeSorbo.4 Equilibrium in the reaction was investigated by Boericke.5 A recent tabular summary

Jan 1, 1962

By Homero Delboni Junior, Thiago Nunan, Flávia Vargas

Ball mill liners perform two main functions in grinding process: protect the mill shell from the aggressive milling environment and delivery input power to the charge. When it comes to liners optimization the challenge are to prolong the service life and improve grinding performance. Some liners characteristics such as A / B ratio, lifters number, lifter height, and attack angle are extremely relevant to grinding process. By analyzing process data, and through DEM simulations application, these parameters were improved on W-mill liner, located at Vazante concentration plant. The new profile promoted a reduction of power variability between the final and the initial life cicle intervals and, therefore, better stability to circuit operation. In addition, the new liner service life reached 21,603 hours, 25% higher compared to the previous one in use. This optimized profile therefore proved to be able to improve its functions by achieving superior process performance combined with longer service life.

Oct 3, 2019

By W A. Ducker, R-H Yoon, M Mao

Froth flotation relies on an attractive force between a particle and a bubble to selectively extract particles from a mixture. The range and magnitude of this attractive force is an area of ongoing investigation. We describe measurements of the effect of dissolved gases on the long-range attractive surface forces between a silica plate and a glass sphere in aqueous octadecyltrimethylammonium chloride (C18TACl) solutions. The measurements follow on the work of Sakamoto et al (2002) who have concluded that long-range interactions occur in air-equilibrated surfactant solutions but not in degassed solutions. In the present work, we have measured attractive forces that have a much larger in magnitude than the expected van der Waals force in solutions that were degassed by the same procedure used by Sakamoto et al (2002). We find that the forces are most attractive at 5 + 10-6 M C18TACl, which is close to the charge compensation point (ccp) of the glass sphere. At this concentration, the attractive force decays exponentially with distance and the decay length is 34 in air-saturated solution, and 38 nm in degassed solutions. In both air-equilibrated and degassed solution, the force is quite sensitive to the concentration of surfactant. The force is also sensitive to the pH. We note that our degassing procedure increases the pH of the solution from about 5.7 to 6.6 (presumably by removal of dissolved CO2). We find that the forces measured in degassed solution can be reproduced by using a solution that was equilibrated in air, then the pH was increased by addition of NaOH. Therefore, we conclude that the main effect of degassing in our experiments is to raise the pH. We show that the range and magnitude of the attractive force decreases in the presence of salt (NaCl). This suggests an electrostatic mechanism for the attraction. Possible mechanisms for the attractive force are examined, including the mechanisms that rely on a patchy coverage of surfactant on the silica surface.

Jan 1, 2005

By A. George Stern

[In the examination of bentonitic clay suspensions used for oil-well drilling fluids3/ (and for other purposes, such as a core binder for foundry sand) it is important to have comparative tests for evaluating them. A satisfactory clay for these and other purposes should have the property of forming what is commonly called a "gel," but the measurement of this property has been a real problem. To date the solution has not been satisfactory, and some of the difficulties are considered in, this, paper, which describes a simple form of instrument (identified as an eykometer) for measuring the yield point under hydrostatic conditions of non-Newtonian clay suspensions, including those muds that are thixotropic. An oil-well drilling mud serves several functions, many of which depend on the "gel" characteristics of the mud. Among the more important functions are: (a) To plaster the sides of the hole to prevent caving of the walls; (b) to prevent the loss of the circulating fluid out of the hole by seepage; (c) to carry sand and cuttings out of the hole to the surface as they are formed by the rotary drill; and (d) when circulation of the fluid stops for shut-down or other unavoidable cause, to hold the cuttings in suspension by the setting up of the gel, thereby avoiding the difficulties that result when these cuttings are allowed to fall through the fluid and pack at the bottom of the hole.]

Jan 1, 1940

By Mingchun Lu, Zhijia Liu, Xueqi Zhang, Jianliang Zhang

"In order to solve the problem of shortage of scrap, especially high quality scrap, a new substitute for scrap or DRI has been developed. The decarbonization mechanism of granular pig iron has been analyzed and the technical process and decarbonized granular pig iron have been evaluated in this paper. The research result shows that this new process is superior to direct reduction process in product quality, construction investment, operation flexibility, production efficiency etc. Decarbonized granular pig iron (DGPI) not only can be used as conventional scrap but also can be charged into EAF as high purity .burden equivalent to heavy scrap:IntroductionIn the past years, with the universal application of continuos casting technique in China, the amount of scrap generated inside steelworks has been reducing continually. On the other hand, the EAF steel proportion is increasing and this gives to the obvious change in structure of steel product. At present, the requirement on both scrap quantity and scrap quality is being paid more and more attention. Because China is a country which is devoid of scrap and poor in resource (nature gas and high grade iron ore) for developing direct reduction iron (DRI) so that sponge iron can not be produced cosmically in China and has to be mainly imported. Instead of part of scrap, some cold pig iron in cold state has been charged into EAF in China. However the high carbon content in pig iron has limited its proportion in EAF metal burden. Because the price of pig iron is lower than that of imported DRI in China, the technique of granular pig iron decarboniztion is hopeful to become effective way to produce substitute for scrap or DRI."

Jan 1, 2000

By George Owusu

A study has been carried out on the use of solvent extraction, instead of the traditional zinc dust cementation process, to remove copper from concentrated zinc sulphate leach solutions. In a series of experiments using plant solution containing 1.9 g/L Cu, 2 g/L Fe, 173 g/L Zn, 7.9 g/L H,SO,, 0.25 g/L Cd, 15 mg/L Co etc. and LIX 622 in SX-1, up to about 97-98 % of copper present in the zinc sulphate leach solution was extracted with negligible co-extractions of zinc, iron, cadmium, cobalt, etc. pH modification was not required for this reagent. The copper loaded organic was almost completely stripped using 150 g/L sulphuric acid. Investigations into the effect of any possible organiclextractant contamination on zinc electrowinning showed (if any) little effect on current efficiency if the organic contamination is less than 45 ppm; current efficiencies of 95-97 % were obtained. At organic contaminations higher than 45 ppm, the current efficiency dropped to about 92- 94 %. Visually, the organic-contaminated cathode sheets had rough surface morphology, becoming more intense with increasing organic concentration, compared to the non-contaminated cathode sheets.

Jan 1, 1998

By J. P. H. Steele, T. Vincent, C. Debrunner, M. Whitehorn

For a variety of reasons, the need for automation of underground mining equipment is growing dramatically, e.g., improved safety and health, availability of labor, deeper mines, and desire for more focused excavation. While there has been tremendous progress made in this direction, much needs to be done to reach the holy grail of an autonomous mining machine. This paper reviews a number of technological developments and presents research and development needs for future development. A report on our current project for the Western Mining Resource Center at CSM is included.

Jan 1, 2000

By Marcus Digre

The autogenous grinding method has been progressively employed in mineral dressing plants during the last 15 years. The term has been used with somewhat different meanings (1), (2), (3). In this paper the author will use it in the most restricted way, for processes where run-of-mine ore (rock) in one step is reduced to a grind product by the action of the ore itself without any other grinding media present. The pebble grinding process where the major part of the ore enters the mill as finely crushed product which is ground further with selected coarse ore pieces acting as grinding media, is not considered autogenous grinding. Processes where a minor amount extraneous media as steel-balls is added to supplement an autogenous mill charge will be called semiautogenous. Other terms need also to be defined. "Mill charge" will be used about the active part of the mill content which performs the grinding, that is the steel balls in ball grinding and the coarse ore pieces in pebble and autogenous grinding. The interstitial nearly finished material is not included in the term "mill charge", and for the wet grinding operations is called the "mill pulp' The term "pebble" will be used for any rounded ore or rock piece in the mill charge whether it is an autogenous or a pebble grinding operation.

Jan 1, 1970

By Rudolf E. Greuer

It is undisputed that an interaction between mine fires and mine ventilation systems exists. The ventilation carries the poisonous and sometimes explosive combustion products, which constitute the greatest danger of mine fires, through the mine and it provides the oxygen on which the intensity of the fire depends. The fire, on the other hand, can produce considerable ventilation disturbances which make it difficult to predict the path along which the combustion products travel. The opinions, how serious a threat such fire generated ventilation disturbances are, vary. Where shallow deposits are mined and brisk ventilation currents are used, it is frequently felt that these disturbances are of no serious concern. Where mine workings extend over larger elevation differences and where such disturbances have been encountered and been the cause of some larger disasters, their assessment is an integral part of all fire emergency plans. The author felt that the potential of digital computers for the design of ventilation emergency plans, contrary to their acceptance for conventional ventilation planning for more than two decades, is not yet fully utilized. He designed a program for the simulation of ventilation systems under emergency conditions in particular fires. This was part of work completed for a contract with the U.S. Bureau of Mines ( Open File Report OFR 115(1)-78)

Jan 1, 1980