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By P. Zhang, S. Al-Thyabat

"Phosphate rock contains traces of rare earth elements (REEs) and can be a secondary source of these critical materials as large tonnages of phosphate rock are mined annually. Attention has mostly focused on the extraction of REEs from phosphogypsum, which contains more than 70 percent of the REEs reporting to phosphate concentrate, with only limited work conducted on REE extraction from sand tailings and slime even though they account for 16 percent and 15 percent, respectively, of REEs mined with phosphate matrix.In this work, phosphate flotation tailings were upgraded by gravity separation and froth flotation. Gravity separation was conducted using a laboratory shaking table, while flotation was conducted in a Denver D-12 flotation cell. The concentrated tailings were then leached by nitric acid followed by REE extraction with solvent and ion-exchange resin.The sand tailings were assayed as having 2.6 percent phosphate (P2O5 ) and 198.1 µg/g REEs. It was found that the shaking table could produce tailing concentrate assayed as having 8.6 percent P2O5 and 616 µg/g REEs but with only 20 percent REE recovery, while the froth flotation produced froth concentrate assayed as having 8.1 percent P2O5 and 368.2 µg/g REEs with 63.5 percent REE recovery. Leaching the flotation concentrate with 5.2 M (25 percent) nitric acid followed by extraction with solvent and ion-exchange resin yielded precipitates with REE contents of 0.926 and 0.314 percent, respectively, compared with 0.716 and 0.213 percent when table concentrate was used.IntroductionRare earth elements (REEs) consist of a group of 17 elements: the 15 lanthanides along with yttrium (Y) and scandium (Sc). They are rare not because of their scarcity in the Earth’s crust but because they are rarely found in economic and mineable deposits. REEs are called “seeds of technology” because of their importance to some critical technological industries such as renewable energy, hybrid cars, electronics and batteries. On average, an electric car or a hybrid car contains about 10 kg of REEs (Grasso, 2012; Radhika et al., 2011).REEs are usually categorized into light (LREE) and heavy (HREE). LREEs consist of lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pr), samarium (Sm), europium (Eu), gadolinium (Gd) and scandium (Sc), while HREEs consist of terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu) and yttrium (Y). About 200 minerals contain traces of REEs, but only three are considered economically significant: bastnasite, with the formula La,Ce(CO3)F; monazite, with the formula(Ce,La,Nd,Th)PO4; and xenotime, with the formulaYPO4 (Jordens, Cheng and Waters, 2013)."

Jan 1, 2016

California Academy of Sciences, Golden Gate Park, San Francisco, Calif C E Grunsky, President A price list of the publications of the Academy will be sent upon request The voluminous literature issued by the Academy deals principally with subjects in the fields of botany, zoology and biology. The Proceedings are issued as volumes, but separates of each paper contained in the proceedings may be obtained at prices indicated in the list of publications A few of the papers which may be of interest to geologists, follow, and indicate the scope and character of the papers of the Society

Jan 1, 1933

By R. V. Higgins

A numerical method is presented to calculate the isopressure (isobar) lines and streamlines for an oilfield from the pressure distribution. A knowledge of these lines is useful in the study of the flow of fluids in underground reservoirs, especially for those containing gaseous and/or liquid hydrocarbons. This work was done primarily to enable determination of the shape factors needed in the calculation of petroleum reservoir performance. However, it has application for the flow of water in aquifers, or electricity or heat in odd-shaped geometry. Techniques previously developed were used to calculate the pressure distribution. From this pressure distribution, the isopressure lines were calculated accurately by the method presented in this paper. Then by successively projecting orthogonal lines from one isopressure line to another, the streamlines are determined. From the coordinates of the isopressures and the streamlines, the shape factors can then be determined by a published method. Computer methods are presented to calculate the streamlines and isopressures for any well-spacing pattern existing within a field with multiple wells. The method reproduces the flow net for several well configurations having extensive geometrical variations. Such information provides the petroleum engineer with data from which he can compute oil recoveries for different patterns and thereby maximize the recovery of hydrocarbons from the reservoir.

Jan 1, 1972

By V. G. Papangelakis, G. A. Moldoveanu

"Rare earths adsorbed on clay minerals are easily recovered via ion exchange during leaching with inorganic monovalent salt solutions. The leaching efficiency of various salts at 0.5M and 25°C was investigated as a function of cation type and salt system (sulphates vs. chlorides). (NH4)2SO4 was identified as the lixiviant of choice and a procedure was established to investigate the influence of lixiviant concentration, temperature, pH and agitation on desorption kinetics and REE extraction levels. It was determined that the kinetics were fast and the optimum leaching conditions (for >80% total REE extraction) required pH below 5 and moderate temperatures (<50°C). INTRODUCTIONRare earth elements (REE) are at the core of numerous advanced applications due to their various uses in high strength permanent magnets, lasers, automotive catalytic converters, fiber optics/superconductors, and electronic devices (as phosphors in TVs and display screens for computers and cell phones). Because of the ongoing development of new technologies, there is an increased demand for REE in the international market, with emphasis on identifying new resources to insure an adequate supply for present and future use. World production of rare earths is dominated by China, the United States and Australia; however, in terms of resources, China dominates the world potential with reserves estimated to be over 90% of the total (Chen, 2011).The main commercially significant REE sources, as reviewed by O’Driscoll (1991) are bastnasite (carbonate) and monazite (phosphate) minerals, containing up to 70% wt. rare earth oxides (REO). In spite of being high grade, these ores are associated with elevated recovery costs due to difficulty in mining, separation and beneficiation. Moreover, aggressive conditions are required to solubilize the REE from the mineral, such as leaching with hot, concentrated acids or baking in 70% NaOH (Gupta & Krishnamurti, 2005)."

Jan 1, 2012

By Larry DeGraff

With the increase of new mine development in the past several years, many coal mines have decided to self- perform the design and construction for their slope development projects. The development process of determining the proper configuration is challenging, and a major economical consideration. Greenbrier Smokeless Minerals engineering staff and consultants, along with DSI/American Commercial, developed a support configuration that was best suited for their slope. The developmental process took into consideration the length of slope, depth of slope at the high-wall transition, economics of a single or multiple entries, waterproofing, stresses on the steel supports and lagging during the backfilling operation. This paper describes the developmental concept of using a single entry, side by side configuration, using steel ?Banjo String? supports with steel plank lagging, to develop a long term permanent installation in a cut and cover application.

Jan 1, 2009

By Mark S. Stagg, Virgil J. Stachura, John W. Kopp, David E. Siskind

The Bureau of Mines studied airblast from surface mining to assess its damage and annoyance potential, and to determine safe levels and appropriate measurement techniques. Research results obtained from direct measurements of airblast-produced structure responses, damage, and analysis of instrument characteristics were combined with studies of sonic booms and human response to transient overpressures. Safe levels of airblast were found to be 134 dBL (0.1 Hz), 133 dBL (2 Hz), 129 dBL (6 Hz), and 105 dB C-slow. These four air- blast levels and measurement methods are equivalent in terms of structure response, and any one could be used as a safe-level criterion. Of the four methods, only the 0.1-Hz high-pass linear method accurately measures the total airblast energy present; however, the other three were found to adequately quantify the structure response and also represent techniques that are readily available to industry. Where a single airblast measuring system must be used, the 2-Hz linear peak response is the best overall compromise. The human response and annoyance problem from airblast is probably caused primarily by wall rattling and the resulting secondary noises. Although these will not entirely be precluded by the recommended levels, they are low enough to pre- clude damage to residential structures and any possible human injury over the long term.

Jan 1, 1965

By Henry R. Colen

When we were asked to prepare a paper on gold to be part of the Economics of Precious Metals session, our immediate thought was that we should address the question of supply. Are the existing mines of the world capable of filling the demand for gold? We recognized that gold does not conform to the normal pressures of supply and demand. Major new sources of production and increased sales might have a very short term effect and depress the price but this does not last very long. Those forces that affect gold prices are very different from the ones economists normally deal with. Factors such as mass psychology, political tensions and fear are certainly more important to the gold price than supply and demand in today&apos;s world.

Jan 1, 1981

By R. G. Travis

1. Reserve estimates have been made for eight coal beds in Monongalia County, W. Va., but only the Pittsburgh, Sewickley, and Upper Freeport beds are important at this time. The Pittsburgh, Sewickley, Waynesburg, and Upper Freeport beds contain the largest recoverable reserves. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 short tons per acre-foot of coal in place, are estimated at 3,526 million tons as of January 1, 1954. Of this total, 3,294 mil-lion tons is in beds 28 inches and more thick. Areas in each bed except the Pittsburgh were omitted from the estimate because available data relative to the bed characteristics are too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1956

By F. W. Schroeder

AT the annual meeting of the Institute 2 years ago, a paper,1 " Requirements of Refractories for Open Hearths," was presented by F. W. Davis and G. A. Bole of the U. S. Bureau of Mines. In a brief foreword, D. A. Lyon stated that the paper was not to report the results obtained but rather to present an outline to serve as a basis for discussion. The essential parts of an open-hearth furnace were described and the conditions under which they operate. Some constructive discussion followed the reading of the paper. One of the first fellowship investigations undertaken by the Bureau of Mines in 1924 under the cooperative agreement with Carnegie Institute of Technology, through the Metallurgical Advisory Board, was to determine service conditions of open-hearth refractories. The present paper gives the results of this work which was done in the Pittsburgh district and was in charge of the authors. Material contributions in the form of data were contributed by E. N. Bauer, J. W. Campbell, G. H. Pfeiffer and A. Grodner, Carnegie Institute of Technology research fellows. The study covered 18 mos.

Jan 7, 1926

By R. B. Russell

The expansion coefficients of hexagonal (a) zirconium have been calculated from the lattice expansionparameters of both coefficientsofhexagonallow and high hafnium alloys in the range 0° to 600°C. It is found parametersofboththat the coefficients are straight-line functions of the temperature and that the effect of hafnium is to depress the mean coefficients by about 1 pct at room thattemperature and 9 pct at 600°C. The cubic (ß) form was stabilized so that its coefficient could be determined from 400&apos; to 900°C. COEFFICIENTS of thermal expansion for hexagonal-close-packed (a) zirconium were determined up to 600°C (1112°F), without any interference from the effects of preferred orientation, by measurement of the lattice parameters obtained from a symmetrical back-reflection focusing X-ray camera. This paper combines the results for a 1.2 atomic pct hafnium alloy from an earlier report&apos; with those for hafnium-free zirconium. The problem confronting the investigator is essentially that of getting sharp, high-angle diffraction lines which represent the material at a known constanl. temperature and chemical composition. In order to do this, it was necessary to use the proper X-ray emission wave length (Co K was chosen) and to have a fine-grained metal whose atomic spacings would be free from effects of cold work (the specimen was annealed) and to prevent a changing composition owing to gas absorption during the heating of the metal to temperature (the sample was heated in a vacuum). A summary of the effect of temperature on properties is listed in Table I which gives data for ordinary zirconium, as well as new values for the low hafnium metal. The coefficients of the linear thermal expansion that have been reported are given in Table 11. The discrepancies shown may be explained perhaps by the effect of preferred orientation, and McGeary and Lustman2 have done this successfully for sheet metal. The differences in texture cannot explain all the differences in expansion coefficient shown in Table II. liesults by the author agree most closely with those of Kroll.3 Chemical analysis of the high hafnium metal pre- viously reported1 showed that it was 98.22 atomic pct (97.40 wt pct) pure. The low hafnium metal was dehydrogenated Westinghouse crystal bar, designated SMZ-137A. Its analysis was as given in Table 111 (chemical analyses 5377, 5431, and 5432).

Jan 1, 1955

By Manoj Khandelwal, Bright Akuinor Tsidi, Newton Amegbey, Daniel Mireku-Gyimah

This study emphasizes the importance of understanding the factors that influence the throwing of flyrock in mining operations, a significant hazard to both workers and nearby structures. Moreover, it highlights how blasting engineers, when estimating flyrock occurrences and their travel distance, typically rely on input parameters such as powder factor (PF), hole length (HL), subdrill (SD), spacing (S), hole diameter (D), burden (B) and stemming length (ST), while overlooking crucial factors like velocity of detonation (VOD) and charge per bank cubic meter (CPBCM). Through analysis using support vector machine (SVM) modeling in MATLAB, the study underscores the impact of including or excluding VOD and CPBCM on flyrock throw distance.

Jul 1, 2024

By Steve Colbum

LTl’s MapStar LPS (laser positioning system) utilize both tripod mounted and hand held reflectorless distance meters. These are eye safe, easy-to-use, and specifically designed to endure the harsh environment characteristic to the mining, quarry and explosives industries. Survey data collected by the systems is digitally stored in a ruggedized data collector and then processed with a specialized, interactive software program, which can be run on any standard PC. Win Prof, the Windows-based analytical software package is used to reduce the data for generating bench face profiles, surfaces, volumes, estimating true burdens and mining ratio calculations. In addition, the software has many other built-in routines to calculate powder factors, toe shear, to map structural contacts and to predict the flyrock potential based on the Burden to Energy ratios. An extensive, built-in library of explosive’s data facilitates these calculations. It will also conform automatically to user-specified minimum and/or maximum burden in relation to the explosive energy, hole diameter and bench geometry - for both vertical and inclined holes. Numerical data can be represented in 2D or 3D to emphasize the hole-burden-face relationships.In this workshop, the MapStar LPS instruments and Win Prof analytical software will be thoroughly demonstrated. Demonstrations include equipment configuration, typical field setups and several effective survey procedures, including processing of some sample data.

Jan 1, 2000

Twenty field-scale tests were conducted in a 28 MW pulverized coal power plant in Healy, Alaska, to examine mill power consumption in relation to coal grind size. The intent in this field-scale study was to verify if grind size truly impacted power consumption by a detectable amount. The regression model developed from the data indicates that grind size does impact mill power consumption, with finer grinds consuming significantly more power than coarser grinds. However, other factors such as coal hardness (i.e., the lower the Hardgrove Grindability Index, or the harder the coal, the higher the power consumption) and mill throughput (i.e., the higher the throughput, the higher the power consumption) had to be included before the impact of grind size could be isolated. It was also observed that combining amperage and flow rate into a single parameter, i.e., specific amperage, hurt modeling. Cost analysis based on the regression model indicate a power savings of $19,972 per year if the coal were ground to 50% passing 76 mm rather than the industry standard of 70% passing 76 mm. The study also demonstrated that size reduction constituted a significant portion of the power consumption.

Jan 1, 2008

By Thiago Viana de Oliveira Turra

Foi estudado o comportamento do resultado de dureza com o acréscimo de tempo de patamar de tratamento térmico para alívio de tensões, em juntas soldadas com processos MAG e TIG. Utilizou-se o metal base ASTM A743 CA6NM, um aço inoxidável martensítico usado na fabricação de rotores para geração de energia hidroelétrica, e o consumível de soldagem AWS A5.9 ER410NiMo. No processo MAG, foi usado o gás mistura de 96% Ar + 4% CO2, e no processo TIG o gás 100% Ar. Para cada processo, foi soldado um corpo de prova, que foi cortado em sete fatias ao longo do comprimento. Observou-se redução na dureza do estado “como soldado” para o primeiro ciclo de oito horas de patamar. Nos demais ciclos a variação encontrada não tem significância dentro da dispersão da amostragem.

Oct 30, 2017

By M Zoorabadi, Y Zhang, D Bringemeier, S Nicoll, N Kerr

Lihir operations of Newcrest Mining Limited (NML) are on Lihir Island (PNG) which is located approximately 900 km north-north-east of the national capital Port Moresby. The mine is located within the Luise Caldera of the Luise Volcano which is located on the east coast of the island. The caldera is an extinct volcanic crater that is geothermally active. Volcanic activity on Lihir Island is limited to remnant hydrothermal venting in the Luise Caldera in the form of hot springs and fumaroles. Steam and gas (including H2S) naturally discharge within the pit area and along the Kapit beach and near shore region. The hydrothermal reservoir temperatures can reach 100°C at the water table and exceed 200°C at depth. Newcrest maintains a Geo-hazard Management Plan to identify and manage the various geotechnical and geothermal hazards on-site. The major geothermal hazard to mining at Lihir is the occurrence of geothermal outbursts, which have occurred in the past with varying intensities and caused two ‘near misses’, production delays and material losses.

Nov 29, 2022

By Zhe Wang, Tichang Sun, Yongqiang Zhao, Zhengyao Li

Coal-based reduction followed by magnetic separation is a promising technology for processing refractory iron ores. Analysis of the size distribution of metallic iron particles is an effective approach for exploring the mechanisms of coal-based reduction. As metallic iron particles exhibit very complex shapes compared with nature ores, approaches for measuring and characterising metallic iron particles still remain unclear. In this study, the size of metallic iron particles was measured and characterised using manual point-counting by optical microscopy technics and image analysis. The effects of CaF2 as an additive on behaviour of the particle size distribution (i.e. mean size and cumulative frequency distribution) were also determined. Results indicate that CaF2 had a significant effect on the growth of metallic iron particles. When the CaF2 dosage increased from 0 to 8%, the mean size according to the area method increased from 9.03 to 16.28 μm, while the promotion effect gradually weakened and generated many fine metallic iron particles when the CaF2 dosage exceeded 8%. An increase in CaF2 dosage also led to cumulative distribution curves gradually shifting to the right mainly because F− can break the crystal structure of each phase during the carbothermic reduction of titanomagnetite and reduce the stability of the lattice structure, thus reducing the melting point and accelerating the growth of metallic iron grains. Compared to different measuring methods, the area method is a more suitable approach for measuring and characterising the size of metallic iron particles.

Sep 18, 2020

By D. C. Buffum, L. D. Jaffee

THAT the path of brittle fracture in temper brit-tle steel differs from the path in unembrittled steel has been known for some years1 More recently it has been recognized that alloy steels, at least, display two forms of temper brittleness1 which may be called upper-nose and lower-nose. No experimental evidence has been published, however, to show that the two forms can be distinguished by simple inspection of brittle fractures. Fig. 1 is a photograph of the fractured surface of a V-notch Charpy specimen of SAE 3140 steel in which temper brittleness developed during heat treatment in the lower-nose temperature range.&apos; The steel was austenitized 1 hr at 900°, tempered 1 hr at 675", and embrittled 48 hr at 500°C, with water-quenching after each treatment. The temperature of transition from ductile to brittle fracture in the Charpy test was + 2°C (criterion of transition: 100 pet fibrous). The hardness was Re 25; the austenite grain size ASTM 8. This specimen was broken at 150°C in the standard Charpy test and absorbed 6.6 ft-lb; its fracture was rated 0 pet fibrous. Fig. 1 shows that the fracture appeared rough to the naked eye. At the side of the specimen away from the notch (the side which was in compression during the test), the surface as a whole deviated sharply from a plane. At higher magnification, X60, the surface gave

Jan 1, 1959

By A. D. David

The object of this paper is to reduce to the simplest possiblc discussion the recent developments in refinery technology without resorting to detailed technical descriptions of the various items. During the year 1929, the most noteworthy tendencies have been towards the installation of more flexible plants, more unified operations, more balanced performance and greater fuel economy. In no other year in the history of petroleum refining has the industry witnessed to as great a degree the crystallization of so rnany developments in almost every phase of the art. Economic pressure has been the controlling factor, supplemented however by a market demand for more volatile anti-knock gasoline and higher quality of lubricating oils, resulting from the extended use of high-compression motors. Catalytic Hydrogenation Possibly the outstanding achievement during the year has been the beginning of construction of plants by the Standard Oil Co. of New Jersey for the catalytic hydrogenation of the so-called heavier and inferior petroleum oils to produce therefrom not only high yields of anti-knock gasoline, but also lubricating oils equal in quality to the best grades obtainable. It is reported that the plants will operate at a pressure of 4000 lb. or higher and temperatures in excess of 900" F. will be used. The hydrogen required for the conversion will be produced from refinery gases. This type of processing will doubtless be an important factor in balancing future operations; in other words, it can be used to eliminate present waste products and permit production of high-grade products from low-grade crude. Improvements in Lubricating Oils Another important development during the past year has been the extended use of vacuum stills, making possible the production of lubricating oils from what was formerly classed as "fuel-oil crude," or crude from

Jan 1, 1930

By Paul S. Korinko, Simona E. Hunyadi Murph

To address a radiological contamination event, a materials and process project was initiated. During the course of this project, processes and materials were developed that successfully captured zinc vapors physically and chemically, respectively. However, the physical traps were placed in an undesirable area and it was determined that the chemically captured zinc reactions was reversible. Consequently, advanced nanomaterials are being developed to capture zinc vapors. The current state of the art of the science and engineering of these materials and their efficacy for zinc capture and retention is discussed in this paper.

Jan 1, 2015

By J. R. Allsup

Air pollutants in exhaust gas produced from LP-gas (propane) were studied using both laboratory engines and vehicles. The objective of the study was to evaluate engine parameters relating to the advantageous use of propane as a low-pollution fuel. Some comparisons are made between gasoline, natural gas, and propane. Results show that engines can operate over a wider range of A/F with minimum carbon monoxide and hydrocarbon emission when using propane than when using gasoline. Mixture enrichment using propane is unnecessary during cold starts, thereby eliminating the emission penalty during warmup. Carbon monoxide and hydrocarbon emission using propane are unaffected by ambient temperature. The photochemical reactivity of hydrocarbon emission is considerably lower with propane than with gasoline.

Jan 1, 1972