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By Y Zhu, D J. Williams, M O’Neill, C Zhang, X Lei

A cover of inert material overlain by topsoil is required over compacted, seawater-neutralised red mud, a waste product from the refining of bauxite to produce alumina. The cover is to be revegetated, and it is necessary to demonstrate that the potential evapotranspirative-driven uptake of salts from the seawater-neutralised red mud will not impact the revegetation. An instrumented column was designed and constructed to test the evaporation-driven uptake of salts from compacted red mud into an overlying cover material with a thickness limited to 600 mm. The PVC column is 1.2 m high, with a 200 mm internal diameter. The column is instrumented with up to ten of each of moisture, suction, salinity and temperature sensors, together with a data logger, designed and manufactured at The University of Queensland (UQ) in Brisbane, Australia. The sensors were installed through the wall of the column at various depth intervals, with each set of sensors located at quarter points around the circumference of the column. Two pressure transducers were installed in the column to monitor the change of water level due to rainfall and evaporation. The column was filled with compacted red mud to a depth of 600 mm overlain by 600 mm of cover material, both sourced from the Queensland Alumina Limited (QAL) site in Gladstone, Queensland, Australia. The column is installed on a building roof at UQ, alongside a weather station, and will be subjected to the prevailing weather conditions for up to 1 year in the first instance, during which time the weather conditions and sensor responses will be continuously monitored. This paper reports on the instrumented column set-up and the early results obtained from the test.CITATION:Zhang, C, Williams, D J, Lei, X, Zhu, Y and O’Neill, M, 2018. Instrumented column testing of salt uptake from compacted red mud into a cover, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 220–226 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By E. Yalçin

The data set often contains one or more secondary variables. These secondary variables are usually spatially cross correlated with the primary variable. The addition of the cross-correlated information reduces the variance of the estimation error by using the cokriging method. The grade estimation results of ordinary kriging and cokriging methods are evaluated and it was found that the estimation variance of cokriging method is slightly lower than ordinary kriging. The effect of variation of block dimension on the estimation results is also investigated and it was seen that the cokriging estimation variance values also decrease as the block dimension increases.

Jan 1, 2005

By M. L. Holzworth, Philip R. Sperry, Paul A. Beck

INTRODUCTION THE basic work of Z. Jeffries1,2,3 has long ago established the main features of grain growth in the presence of a dispersed second phase. Working with sintered specimens of initially fine grained tungsten, to which various amounts of thoria have been added, Jeffries found that grain growth was inhabited, that is, practically prevented, up to a certain annealing temperature. When this temperature, which increased with the thoria content, was exceeded, extremely large grains developed abruptly from the fine grained matrix. Such a "coarsening temperature" was later found by Gross mann13,14 in certain types of steel, while Bain showed" that in other steels grain growth was gradual, without inhibition and abrupt coarsening. Later work16,17,18,19,21 demonstrated the connection between coarsening and aluminum additions. The viewpoint that the direct cause of inhibition and coarsening in aluminum killed steels is a fine dispersion of aluminum oxide21 appears to be held quite generally, although some doubts have been voiced even very recently.20 In steels with Ti additions the titanium carbide phase is considered responsible for the inhibition effects found.20 The coarsening temperature increases, with the titanium content. That coarsening may occur, as a result of certain heat treatments, even in low carbon rimmed sheet steel, was shown by Samuels,22 He also detected coarsening in a steel ingot of similar composition, after giving it the same heat treatment as that used by him for the sheet material, In this instance the identity of the inhibiting phase has not been determined, However, Tangerding found 23 that even the few small carbide particles, which occur in carbonyl iron, have a very marked inhibitive effect. As a result of an oxidizing anneal at 850°C, large grains begin to form at the surface of the carbonyl iron specimen, and gradually grow inward as the subsurface oxidation of the carbide particles progresses and eliminates the obstruction, The carbide particles can be removed also by annealing in hydrogen, with similar results. But if the oxidizing anneal of 10 hr at 850°C in air, is followed by annealing in hydrogen for 75 hr at the same temperature, grain growth is more spectacular; usually the whole specimen is transformed into a single crystal (approx. 1,5 cm X 5 cm). The reversed procedure, that is, hydrogen annealing followed by oxidizing annealing leads to smaller grains. Tangerding arrived at the logical conclusion that there must have been in his specimens some additional obstruction to grain growth resulting from a minor impurity, other than carbon. It seems likely that this obstruction was caused by an oxide formed during the oxidizing anneal and gradually reduced during the subsequent hydrogen-annealing. Other instances of grain growth inhibition of varying severity, associated with a dispersed second phase, have been described by several authors. Notable examples: lead with 0.06 pct Cu or Ni,24 cartridge brass with 0.12 pct Cr,25 or with up to 0.15

Jan 1, 1948

By Richard D. Short

The Pseudo Static Pile Load Test, PLT, is a rapid method for determining pile capacity. Pile design is usually based on theoretical calculations of ultimate load capacity using soil data from a field investigation. The pile capacity is confirmed during construction by analysis of blow counts using dynamic formulae, dynamic pile monitoring, and load testing. Load testing is the most direct and reliable method of determining the actual capacity of a pile. Conventional load testing procedures, however, are time consuming and expensive. A typical load test requires installation of two to four reaction piles, construction of a high-capacity steel test frame, hydraulic jacks, and dial gauges, and will typically take one to three days per pile. Costs for load tests range from $10,000 to $20,000 per test. The Pile Load Test machine features a 25-tonne weight mounted on a mobile test frame. PLT load tests can be performed in a matter of minutes once the equipment has been mobilized to the site. This paper examines three test sites where the PLT test method was used and compares the results to conventional load test results and theoretical capacity calculations.

Jan 1, 2000

By Helmut Hass, Marco Ziller

"Abstract: 1 Sophia Spoortunnel Marco Ziller, Trevi S.p.A.:For the construction of 14 cross passages connecting the twin tunnels of the Sophiaspoortunnel the Artificial Ground Freezing technique was applied as temporary soil improvement. AGF by Brine and Liquid Nitrogen was implemented. Automatic data acquisition and recording systems were installed to monitor the variation of the temperatures in the soil during the freezing intervention in order to control the behaviour and the efficacy of the treatment.IntroductionThe Sophia rail tunnel is a bored tunnel with a length of 4.24 km, comprising two separate parallel tubes with an outside diameter of 9.45 m. The twin tunnels were excavated by a TBM equipped with hydroshield. Seven service shafts, approximately 30 m deep, were constructed in between the tunnels. From each shaft two cross passages were constructed connecting the shaft with both tubes, for a total of 14 cross passages.The Artificial Ground Freezing technique utilizing both the Brine and Liquid Nitrogen methods was used for temporary waterproofing and soil support to allow the excavation of the cross passages. The natural soil to be frozen was consisting in loose sand and clay under a hydrostatic pressure up to 250 kPa.For the measurement of the ground temperature. Automatic data acquisition and recording systems were installed to monitor the variation of the temperatures in the soil and at the contact with the tunnel lining. Furthermore, a comprehensive computerized system of sensors and cryogenic valves was designed and implemented in order to manage the whole Nitrogen process.Soil Main CharacteristicsThe soil stratigraphy is generally consisting in Clay (Holocene) from ground level to -15 m depth, followed by Pleistocenic Sand, from -15 to -25 m, and Clay below -25 m."

Jan 1, 2014

By J. Bigu

Use has been made of several theoretical models to predict radiation levels in underground uranium mines. The models used are the Evans model, the Thomas-Epps mine model, the isolated mine model, the mine tunnel with no air flow and the mine tunnel with air flow (Beckman and Holub). Calculations based on the above models have been extended to include thoron gas and its progeny, a common occurrence in some Canadian uranium mines. Theoretical predictions include radon and thoron progenies WLs and concentrations, and some ratios of great practical interest. The main differences between the models are pointed out and comparison is made with experimental data gathered during the last three years in several Canadian underground uranium mines.

Jan 1, 1981

By J. Brent Hiskey

Recently basic concepts of semiconductor electrochemistry and solid-state electronic structure theory have been applied to the dissolution of mineral electrodes. In this paper, fundamental aspects of semiconductor electro- chemistry and interfacial charge-transfer processes are reviewed. Information regarding the electronic and semiconductor properties of chalcopyrite is summarized. The electrochemical response of chalcopyrite in acidic solution is analyzed in terms of initial dissolution processes. The initial charge- transfer reaction involves the consumption of holes. It has been shorn that Fermi level pinning is consistent with observed electrochemical and dissolution behavior. Semiconductor electrochemistry has proved helpful in explaining the formation of intermediate surface films produced during the initial stages of chalcopyrite dissolution

Jan 1, 1993

By J. Y. Tian

In view of the fact that many domestic iron ore-dressing plant applying flotation cells in the re-verse flotation, to improve the technical level of magnetite reverse flotation, we apply such a technological process of one stage rougher and two stages scavenger flotation column respectively. The middling from the two stage scavenger process are returned to magnetic separation for condensing. By contrast, the technological process of one stage rougher and one stage cleaning flotation cells is made up of by multi-magnetic separation and magnetic middling regrinding separations. It has been proved that the flotation column we offer can simplify the technological process structure, obtain advanced technical indexes, run the system smoothly, reduce energy consumption, and be environ-mental friendly.

Jan 1, 2014

By J Stiefenhofer

"*This is an abstract only*Construction of geological models for kimberlites has historically largely been based on visual volcanic textures and features, with chemical data only collected on an ad-hoc basis depending on the level of perceived complexity observed in the geological data. The focus of this paper is a high-level view of the impact an initial absence (or lack) of relevant chemical data had on two kimberlite resource models as well as how the magnitude of the problem increased once the resource estimation process commenced (Stiefenhofer, 2013). The impact of ignoring chemical data on a project assessment where micro-diamond estimation techniques are employed, is also discussed. Resource estimates based on micro-diamond data are critically dependent on the use of the correct geological model since stationarity of the size frequency distribution is key to the generation of correct grade estimates. A multilevel approach is advocated where the volcanological/visual model is verified using chemical data and both are in turn verified by the diamond data.CITATION:Stiefenhofer, J, 2013. The use of chemical and metallurgical parameters to enhance the economic value of kimberlite resource models, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013, pp 101-104 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 29, 2013

By John R. McDonnell

The Valle Vidal Unit comprises 100,000 acres In Taos and Colfax: Counties, New Mexico. The unit was donated to the American public In 1982 by the Pennzoll Co. and is administered by the U.S. Department of Agriculture Forest Service as an addition to the Carson National Forest. During 1990-1991, the Bureau of Mines conducted a mineral Investigation of the unit as authorized by an Interagency Agreement (1987) Intended to assist the Forest Service to incorporate mineral resource data In forest plans. The Bureau reviewed literature and records concerning mineral resources and mining activity, and performed a field examination of mines, prospects, and mineral occurrences in and near the Valle Vidal Unit. The La Belle mining district encompasses most of the western part of the Valle Vidal Unit. The district was most active between 1893 and 1902, after the land grant was opened to prospecting and gold discoveries were reported. The discoveries were low grade, and eventually were abandoned. The Bureau's appraisal of the district determined that lode gold occurs primarily in fissure veins in volcanic rocks, and placer gold occurs In weakly cemented sedimentary rocks and alluvial sediments; but at a grade that is currently considered subeconomic. If the price of gold increases in the future, prospecting and exploration in the area may be renewed, but the activity would likely be limited due to "acquired land status" restrictions, which require mineral leasing and prohibit claim location in the Valle Vidal Unit.

Jan 1, 1992

By Y. Jeong, K. Kim

Excess water can lead to instability and even failure in tailings storage facilities (TSFs). Simply reducing the amount of water in TSFs could be the best way to ensure the safety of nearby communities. In this case study we investigated the effects of reducing the water content in tailings slurry at a copper-cobalt-zinc mine in Mexico. An environmentally friendly polymer was used as a drag reduction agent (DRA) to offset the increase in solids percentage. The potential effects of the increased solids concentration on the tailings transportation system were also assessed. A series of ‘what if’ studies was conducted to assess whether adding the polymer would allow the solids concentration to be increased without changing the pressure loss in the tailings pipeline. The studies entailed conducting pipe loop tests to investigate these changes under various solids/ polymer concentrations and then constructing a computational fluid dynamics (CFD) simulation model using the test results. The validated model was used to determine the optimal polymer percentages needed to maintain the same pressure loss under baseline (30% solids) conditions, and to assess the potential risks (clogging, increased erosion rates) to the pipelines. The potential water savings were found to be significant, varying from about 1.852 Mm3/a at 35% solids to 3.915 Mm3/a at 45% solids.

Dec 13, 2023

By J. A. SINGMASTERN

THE New Jersey Zinc Co.'s vertical retort plants are believed to have been in continuous operation through the whole year. At Palmerton metal purer than that made from the same ore in the old plant has been produced and has been able to compete successfully with very pure electrolytic metal in die castings and other special uses where extreme purity is worth money. A new plant using this process was put in production by the Grasselli Chemical Co. at Meadowbrook, W. Va., early in the summer. It is said to be working very satisfactorily. It is understood that this plant will not produce high-grade metal. Two patents issued to Bunce and Mahler (Nos. 1,749,126 and 1,749,127) describe a method of operating the vertical retort so that practically lead-free metal can be obtained from ores containing consider- able lead. The zinc vapors and other gases leaving the reaction zone are filtered through a column of material maintained at a temperature high enough to prevent much zinc from condensing. The filtering medium is either periodically or continuously changed.

Jan 1, 1931

By C. E. Golson

Modern concrete technology emphasizes the basic qualities required of an acceptable aggregate: it must be clean, sound, homogeneous, and of a size gradation resulting in a concrete of the desired physical qualities at a minimum cost. In the case of coarse aggregates, crushing, scrubbing, and screening will usually provide the required material, although beneficiation is often necessary in order to eliminate unsound or deleterious fractions. Beneficiation is also applicable to fine aggregates,( but the processes most often employed are washing, classification, and dewatering.

Jan 1, 1959

By C. Y. Sun

China is a country with abundant resources of tungsten, taking one of the world?s top-positions regarding both the total reserve and the amount of industrial production. China?s tungsten resources occur mostly in multi-metallic deposits rather than in single-metallic deposits. China?s multi-metallic tungsten ores have the characteristics of coexistence with other valuable components such as molybdenum, bismuth, copper, sulfur and fluorite. These ores are usually low in grade and difficult to process. The technological challenge in mineral processing lies in separation of multi-metallic components in these complex ores and a comprehensive utilization of natural resource. Several cases of industrial practice of processing China?s typical multi-metallic tungsten ores are presented.

Jan 1, 2014

By George W. Leney

The iron ore industry might justifiably claim to have originated the science of geophysical prospecting. Their use of geophysical methods was probably the first application of these scientific techniques to the search for economic materials although the exact origin is undoubtedly lost in the unrecorded observations of. some prospector experimenting with compasses or bits of lodestone. Since 1879 when Thalen published "On the Examination of Iron Ore Deposits by Magnetic Measurements" these methods have been a standard supplement to other prospecting techniques. However, many of the great ore bodies of the Precambrian iron ranges were not particularly suitable for geophysical work. The ores were oxidized and enriched through leaching of silica so that they were nearly non-magnetic and other physical properties which distinguished them from the wall rocks were largely destroyed. With the gradual exhaustion of these high grade direct shipping ores, and ores that could be beneficiated by simple means, the iron ore industry turned initially toward the importation of similar high grade foreign ores. At the same time, new processes for concentrating lower grade materials were being developed and older ones improved upon. These concentrates' when pelletized produced such important savings in blast furnace hot metal costs that they now command a premium in the iron ore market and have weakened the competitive position of the remaining high grade ores. The ore bodies now being sought are usually unoxidized and frequently they are also metamorphosed.

Jan 1, 1965

By A. C. Richardson

[During the past two and a half sears the U. S. Bureau of Mines and the University of Alabama, with the cooperation of the different coal operators, have been making an extensive studs of coal preparation in the State of Alabama. Considerable time has been devoted to the studs of the washing characteristics of the Mars Lee bed and the various methods used In preparing from it a low-ash coal suitable for the manufacture of metallurgical coke. One of the phases of this problem is the utilization of middlings products from the washing plants. This paper gives the results of treating jig middlings on a coal-washing table at the Bureau of Mines laboratory at Tuscaloosa, Ala. The sample used was secured from the Sayreton washery of the Republic Steel Corporation, Sayreton, Ala. WASHERY PRACTICE The Mary Lee bed is very bony, and operators find it difficult to produce from this bed a washed coal much under 10 per cent ash. Experience has shown that in the preparation of a coking coal from the Mary Lee bed it is best to use a process which permits the recovery of a middlings product. Middlings are desirable because separation according to specific gravity is never perfect, and a middlings product makes possible a low ash in the primary warned coal without excessive losses of combustible in the refuse. The general washery practice on the Mary Lee bed is to crush the run-of-mine coal through some maximum screen size and wash it upon some one type of jig without re-treatment of any of the products made. The maximum size treated varies from 3 inch to J inch. The middlings product from multiple-cell jigs is usually termed "boiler fuel" and when possible is utilized as such. At present the production of boiler fuel is often in excess of power requirements, and the surplus, due to its high ash content, becomes waste.]

Jan 1, 1931

By Rollyn P. Jacobson

THE town of Pacific, in Jefferson County, Mo., is 127 miles west of St. Louis. Since the area lies entirely on the flood plain of a cutoff meander of the Meramac River, it was considered a likely environment for accumulation of commercial quantities of sand and gravel. Excellent transportation facilities are afforded by two major railways to St. Louis, and ample water supply for washing and separation is assured by the proximity of the river. As a large washing and separation plant was planned, the property was evaluated in detail to justify the high initial expenditure. An intensive testing program using both geophysical and drilling methods was designed and carried out. The prospect was surveyed topographically and a 200-ft grid staked on which electrical resistivity depth profiles were observed at 130 points. The Wenner 4-electrode configuration and earth resistivity apparatus" were used. In all but a few cases, the electrode spacing, A, was increased in increments of 11/2 ft to a spread of 30 ft and in increments of 3 ft thereafter. Initial drilling was done with a rig designated as the California Earth Boring Machine, which uses a bucket-shaped bit and produces a hole 3 ft in diam. Because of excessive water conditions and lack of consolidation in the gravel there was considerable loss of hole with this type of equipment. A standard churn drill was employed, therefore, to penetrate to bedrock. Eighteen bucket-drill holes and eight churn-drill holes were drilled at widely scattered locations on the grill. The depth to bedrock and the configuration will not be discussed, as this parameter is not the primary concern. Thickness of overburden overlying the gravel beds or lenses became the important economic criterion of the prospect.** The wide variety and gradational character of the geologic conditions prevailing in this area are illustrated by sample sections on Fig. 2. Depth profiles at stations E-3 and J-7 are very similar in shape and numerical range, but as shown by drilling, they are measures of very different geologic sequences. At 5-7 the gravel is overlain by 15 ft of overburden, but at E-3 bedrock is overlain by about 5 ft of soil and mantle. Stations L-8 and H-18 are representative of areas where gravel lies within 10 ft of surface. In most profiles of this type it was very difficult to locate the resistivity breaks denoting the overburden-gravel interface. In a number of cases, as shown by stations M-4 and H-18, the anomaly produced by the water table or the moisture line often obscured the anomaly due to gravel or was mistaken for it. In any case, the precise determination of depth to gravel was prevented by the gradual transition from sand to sandy gravel to gravel. In spite of these difficulties, errors involved in the interpretation were not greatly out of order. However, results indicated that the prospect was very nearly marginal from an economic point of view, and to justify expenditures for plant facilities a more precise evaluation was undertaken. The most favorable sections of the property were tested with hand augers. The original grid was followed. In all, 46 hand auger holes were drilled to gravel or refusal and the results made available to the writer for further analysis and interpretation. When data for this survey was studied, it immediately became apparent that a very definite correlation existed between the numerical value of the apparent resistivity at some constant depth and the thickness of the overburden. Such a correlation is seldom regarded in interpretation in more than a very qualitative way, except in the various theoretical methods developed by Hummel, Tagg (Ref. 1, pp. 136-139), Roman (Ref. 2, pp. 6-12), Rosenzweig (Ref. 3, pp. 408-417), and Wilcox (Ref. 4, pp. 36-46). Various statistical procedures were used to place this relationship on a quantitative basis. The large amount of drilling information available made such an approach feasible. The thickness of overburden was plotted against the apparent resistivity at a constant depth less than the depth of bedrock for the 65 stations where drilling information was available. A curve of best fit was drawn through these points and the equation of the curve determined. For this relationship the curve was found to be of the form p = b D where p is the apparent resistivity, D the thickness of overburden, and b a constant. The equation is of the power type and plots as a straight line on log-log paper. The statistical validity of this equation was analyzed by computation of a parameter called Pearson's correlation coefficient for several different depths of measurements, see Ref. 5, pp. 196-241. In all but those measurements taken at relatively shallow depths, the correlation as given by this general equation was found to have a high order of validity on the basis of statistical theory.

Jan 1, 1956

By David G. Almond

"Economies of scale and the variable characteristics of many large ore deposits have resulted in grinding installations having large SAG mills fitted with variable speed drives. Problems associated with effective operation of this equipment has created the need for better operator knowledge of mill load behavior and the need for new instrumentation capable of providing accurate information about load movement and composition. This paper discusses two performance enhancing instruments available to address these needs.INTRODUCTIONThe economic demands of new mining projects has resulted in increased equipment sizes and this is particularly evident in milling where there are now many SAG mills operating in the range of 28’ – 40’ diameter with installed powers of 8 – 22 MW. These mills are designed to process very high capacities of ore daily2 and the variable characteristics of many of the deposits mined results in the need to vary the mill speed during processing to cater for the changes in ore hardness. Mill speed changes often result in operational problems associated with high-energy impacts striking the mill liners reducing energy efficiency as well as degrading the grinding media through breakage, accelerating liner wear and in extreme cases even breaking liners. These operational problems have given rise to the need to have instruments aimed at providing operators with accurate information in real time about the load composition and movement within SAG mills.The original concepts for operating SAG mills were derived from past experience of operation of conventional fixed speed ball mills. However, the relatively stable conditions that applies with fixed speed and constant ball charge in ball mills supports theoretical approaches to the grinding process based on energy calculations such as Bond’s Work Index concept. Later a set of parameters Si and Bij were used for describing load kinetics, but all of these methods neglect the details of load movement and how the energy is actually used inside of the mill. It is now commonly accepted as a basic rule that SAG mills grind by impact whilst ball mills grind by attrition and consequently SAG mills are designed and operated to generate a large amount of impacts by the cataracting load without paying sufficient attention to where these impacts are actually occurring. Many mills are operated on the basis that as long as the mill is consuming the expected power there is little attention given to the class of bodies using this energy and this often results in the inefficient use of energy."

Jan 1, 2005

By B. V. Cooper

The word "research" has been used in the title of my presentation somewhat against my better judgement. There are many definitions of the word. But the one I like best comes from Webster's New World Dictionary. It reads: "Careful, systematic, patient study and investigation in some field of knowledge, undertaken to discover or establish facts or principles. ..." I like that. In only 9 words, the definition conveys to me the very essence of what should be going on either in or for the coal industry. Unfortunately, not enough coal-related research is going on. And much of what is being done is, in my view, not really as effective as it might be.

Jan 1, 1983

By S. A. Lever, R. Hultgren

The solidus is usually the least satisfactorily determined portion of a phase diagram. Cooling curves, which succeed well with the liquidus, show the solidus inaccurately or not at all because of segregation which occurs during freezing. Heating curves of carefully homogenized alloys might be expected to indicate accurately the solidus, but they are seldom used. Dynamic methods involving heating or cooling are never completely satisfactory because of uncertainty as to whether equilibrium is attained. A static method in which the specimen may be allowed hours, days, or even weeks to attain equilibrium is to be preferred. In a static method a solid solution, for example, is first made thoroughly homogeneous, then heated to successively higher temperatures. After sufficient time at each temperature to assure equilibrium, some property is measured which should alter strikingly when melting begins. Microscopic examination can be used to detect the beginning of melting, but the method is tedious since the specimen must be quenched, sectioned, polished, and etched before each examination. Of all the physical properties which change on melting, electrical resistance is probably the most satisfactory to measure. The measurement may be made while the specimen is at temperature without damage to the specimen. It may be repeated indefinitely to ascertain when equilibrium has been achieved. Measurements may be made on a single specimen over the whole range of temperature. Most metals approximately double their resistance on melting. Since an accuracy of a few tenths of a percent is easy to achieve, the method is highly sensitive to the beginning of melting. In spite of these advantages, which have been perceived for a long time,l,2 a reasonable search of the literature has failed to reveal a single case in which the method has been satisfactorily applied in practice to the determination of solidus temperatures. The use of electrical resistance measurements appears to have been confined in practice to changes in the solid state. In the work described in the following pages we have applied the electrical resistance method to the solidus of the lead-tin system. We have found the method to be convenient, reproducible, and highly sensitive. We chose the lead-tin system because it leads to few technical difficulties. Furthermore, a number of determinations of solidus have been made in this system by various methods and results could be checked against them. However, all published results are not in good agreement with one another, so this work should help in determining the solidus more precisely. The Lead-tin Diagram Because of its commercial importance, there have been numerous investigations of the lead-tin diagram. The results of the most recent work on the solidus are indicated in Fig 7, as well as the results of the present work. The works of Honda and Abe3 and of Stockdale4 agree fairly well with each other and with the present work. Jeffery's5 data indicate the solidus to be about 50°C lower. Honda and Abe3 used differential thermal analysis on both heating and cooling cycles. Stockdale4 used the microscopic method and also differential heating curves. Stockdale's results were about 4" higher than those of Honda and Abe at low tin contents and lower at higher tin contents. These results also agree with those of Rosen-hain and Tucker.= Jeffery5 used electrical resistance measurements of the alloy as it was being heated or cooled. Apparently he did not attain equilibrium as his results are about 40°C lower than those of Stockdale4 or Honda and Abe.3 MATERIALS AND METHODS The lead and tin used were of high purity. They were supplied by the American Smelting and Refining Co., who gave the following analyses: Lead: silver, 0.0016 oz per ton; copper, 0.0008 pct; cadmium, 0.0007 pct; zinc, 0.0002 pct; arsenic, 0.0003 pct; antimony, 0.0002 pct; bismuth, 0.0005 pct; tin, 0.0001 pct; iron, 0.0020 pct; lead (by difference), 99.995 pct. Tin: antimony, 0.037 pct; arsenic, 0.020 pct; bismuth, 0.004 pct; cadmium, trace; copper, 0.025 pct; iron, 0.004 pct; lead, 0.020 pct; nickel and cobalt, 0.005 pct; silver, 0.0005 pct; sulphur, 0.005 pct; tin (by .-difference). 99.88 pct. One hundred grams of metal with the desired proportions of lead and tin was weighed out to the nearest one-tenth of a milligram. The mixture was placed in a silica crucible, covered with charcoal, and melted in a reducing atmosphere in a gas-fired furnace. The alloy was well stirred. Chemical analysis of two of the alloys checked closely with the weighed portions. The compositions of the remainder of the alloys were taken directly from the weighings, without chemical analysis.

Jan 1, 1950